CN109109408A - Special glass and its preparation process - Google Patents
Special glass and its preparation process Download PDFInfo
- Publication number
- CN109109408A CN109109408A CN201811074464.1A CN201811074464A CN109109408A CN 109109408 A CN109109408 A CN 109109408A CN 201811074464 A CN201811074464 A CN 201811074464A CN 109109408 A CN109109408 A CN 109109408A
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- Prior art keywords
- layer
- glass
- adhesive layer
- glassy
- glassy layer
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- 239000011521 glass Substances 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000010410 layer Substances 0.000 claims abstract description 153
- 239000012790 adhesive layer Substances 0.000 claims abstract description 36
- 238000005516 engineering process Methods 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims description 27
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 26
- 238000002834 transmittance Methods 0.000 claims description 22
- 238000004140 cleaning Methods 0.000 claims description 17
- 238000009413 insulation Methods 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 12
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 229910003437 indium oxide Inorganic materials 0.000 claims description 8
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000010412 perfusion Effects 0.000 claims description 8
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 8
- 229910001887 tin oxide Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 238000007790 scraping Methods 0.000 claims description 4
- 238000004382 potting Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 230000003670 easy-to-clean Effects 0.000 abstract description 3
- 239000012634 fragment Substances 0.000 abstract description 3
- 239000004417 polycarbonate Substances 0.000 description 42
- 239000004814 polyurethane Substances 0.000 description 33
- 238000004026 adhesive bonding Methods 0.000 description 27
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 26
- 230000005540 biological transmission Effects 0.000 description 19
- 239000003292 glue Substances 0.000 description 11
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000003678 scratch resistant effect Effects 0.000 description 8
- 238000001035 drying Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002985 plastic film Substances 0.000 description 6
- 229920006255 plastic film Polymers 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- 239000005340 laminated glass Substances 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- -1 that is Substances 0.000 description 3
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000005336 safety glass Substances 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 230000000739 chaotic effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001153 fluoro group Chemical class F* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Classifications
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- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10064—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising at least two glass sheets, only one of which being an outer layer
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- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10752—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polycarbonate
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- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/10816—Making laminated safety glass or glazing; Apparatus therefor by pressing
- B32B17/10871—Making laminated safety glass or glazing; Apparatus therefor by pressing in combination with particular heat treatment
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
- B32B17/10908—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin in liquid form
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/1099—After-treatment of the layered product, e.g. cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/114—Deposition methods from solutions or suspensions by brushing, pouring or doctorblading
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Fluid Mechanics (AREA)
- Thermal Sciences (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The present invention relates to special glass technology fields, and in particular to it is a kind of with higher bulletproof effect can power generating glass and its preparation process.Glass of the present invention includes the first glassy layer, the second glassy layer and burster course, and it is the second adhesive layer between the second glassy layer and burster course that it is the first adhesive layer between first glassy layer and the second glassy layer that second glassy layer, which is chip coated glass layer,.The burster course includes third glassy layer, the first PC layers and the 2nd PC layers, and the third glassy layer and the first is third adhesive layer between PC layers, and the first PC layer and the 2nd be the 4th adhesive layer between PC layers.Preparation process of the present invention is simple, and not only generating efficiency is high for product, indoor light is adjusted, volume is lighter, and surface is easy to clean, while bulletproof effect is more preferable, and fragment is effectively prevent to splash.
Description
Technical field
The present invention relates to special glass technology fields, and in particular to it is a kind of with higher bulletproof effect can power generating glass and
Its preparation process.
Background technique
Bulletproof glass has high intensity and toughness, can bear intense impact and destruction as a kind of transparent material,
Cartridge shooting is resisted while meeting translumination observation requirement without being pierced, and has extensive purposes in terms of security protection,
It is usually used in the door and window position on the ground such as bank, valuables showcase, prison, to protect personal safety to the greatest extent, for reality
Existing bulletproof function, the standing layer structure for being calculated as multilayer of bulletproof glass.
Notification number is that the utility model of 206968122 U of CN discloses a kind of bulletproof glass, including compound glass and one layer
Polycarbonate Layer is bonded by PVB film.
Publication No. be the application for a patent for invention of 106273909 A of CN disclose it is a kind of can intelligent dimming bulletproof glass, packet
Multilayer bearing course, middle layer, protective layer and the adjustable light modulation film of dimming ratio are included, adjusts light modulation film by being switched off or on power supply
Light transmittance.
Traditional bulletproof glass can not generate electricity, and cannot adjust indoor light, while in order to reach the bulletproof effect of needs, it is necessary to
Bulletproof glass is formed using compound glass and PVB film, it is overall heavier, it is higher for bearing frame and installation power demand, simultaneously
Since the light distortion effect of the more generation of glass level has seriously affected transparent effect, glass surface is easily dirty, hardly possible cleaning to
It influences beautiful.
Summary of the invention
The present invention is intended to provide a kind of glass and its preparation process, not only generating efficiency is high, and indoor light, volume is adjusted
Relatively light, surface is easy to clean, while bulletproof effect is more preferable, and fragment is effectively prevent to splash.
The present invention provides a kind of glass, and the glass successively includes the first glassy layer, the second glassy layer and burster course, described
Second glassy layer is chip coated glass layer, is the first adhesive layer, the second glass between first glassy layer and the second glassy layer
It is the second adhesive layer between glass layer and burster course.
Further, the chip coated glass layer is with a thickness of 3-6mm, light transmittance 20%-50%.
Further, first adhesive layer and the second adhesive layer are thick using any one in PVB, SGP, PU film
Degree is 0.38-2.28mm, 90% or more light transmittance.
Further, first adhesive layer and the second adhesive layer are used through heat insulation nano antimony doped tin oxide or heat insulation nano
The heat-insulated film of PVB of tin-doped indium oxide processing.
Further, the burster course successively includes third glassy layer, the first PC layers and the 2nd PC layers, the third glass
Layer and the first is third adhesive layer between PC layer, the first PC layers and the 2nd be the 4th adhesive layer between PC layers.
Further, the third glassy layer is wire glass layer, with a thickness of 3-6mm.
Further, first PC plate and the second PC plate are with a thickness of 2-6mm, 90% or more light transmittance.
Further, the third adhesive layer and the 4th adhesive layer are that glue bonding layer is perfused in PU, and thickness after adhesive curing is perfused in PU
Degree is 1-2mm.
Further, it is provided with self-cleaning coat on the outside of first glassy layer, is provided with preventing from scraping film on the outside of burster course.
Further, the self-cleaning coat thickness of dry film is 50-500 μm.
Further, the described first PC layers and the 2nd PC layer using high light transmission PC material.
The present invention provides a kind of preparation process of above-mentioned glass, the preparation process the following steps are included:
(1) coevaporation technology depositing photovoltaic chip coating is used, and different chip coating intervals is delineated using laser method
Size and arrangement density, obtain second glassy layer with different light transmittances；
(2) from top to bottom by the first glassy layer, the first adhesive layer, the second glassy layer, the second adhesive layer and wire glass layer
It is sequentially overlapped conjunction piece, precompressed obtains composite sample；
(3) composite sample of step (2) is put into autoclave, high pressure composite sample is made in high-temperature high-pressure；
(4) the high pressure composite sample of step (3) is laminated Nian Jie with the first PC layers of progress PU perfusion in wire glass, it is cold
But third adhesive layer is obtained after solidifying；It is laminated Nian Jie with the 2nd PC layers of progress PU perfusion in the first PC, it is obtained after cooling and solidifying
4th adhesive layer.
Further, step (2) precompressed in roll squeezer, keeping glass surface temperature after roll-in is 70 DEG C or so, cooling
It is spare, obtain precompressed composite sample.
Further, step (3) precompressed composite sample is put into autoclave, and increasing temperature and pressure is to 120-140 DEG C, 1-
1.5MPa keeps 30-60min, after be cooled to 40 DEG C hereinafter, rear slow release, opens autoclave and obtain high pressure composite sample.
Further, 2000 turns/min of step (4) PU glue major ingredient and curing agent is uniformly mixed, will after vacuum defoamation
The high pressure composite sample prepared in step 3 is laminated Nian Jie with the first PC layers of progress PU perfusion in wire glass, after cooling and solidifying
Third adhesive layer is obtained, it is laminated Nian Jie with the 2nd PC layers of progress PU perfusion in the first PC, the 4th bonding is obtained after cooling and solidifying
Layer.
Further, preventing from scraping film is the scratch-resistant plastic film of thickness 1mm.
Further, the preparation process can also include step (5) and step (6), specifically include:
(5) in one side bonds preventing from scraping film of the 2nd PC layer；
(6) self-cleaning coat is coated with by spraying, blade coating or roll coating model in the first glass layer.
Further, mixing vessel, high speed 2000 is added in fluorocarbon resin substrate, age resister and curing agent by step (6)
Turn/after min is uniformly mixed, pass through spraying, blade coating, roller coating side in the first glass layer of composite sample prepared by step 5
Formula is coated with fluorine carbon self-cleaning coating wet film, then above-mentioned sample is placed in air dry oven, 80-100 DEG C of drying 1-5min of high temperature,
Drying at room temperature obtains self-cleaning coat.
Beneficial effect
Compared with prior art, the beneficial effects of the present invention are:
1, glass of the present invention and its preparation process, by introducing PC and wire glass, not only product quality is lighter,
Be conducive to install, while product bulletproof effect is more preferable, and fragment is effectively prevent to splash；
2, different light transmittances, therefore adjustable indoor light is presented after chip glass laser grooving and scribing simultaneously；
3, surface introduces self-cleaning fluorine class coating, and product is easy to clean, and is not easy to remain dirty.
Other features and advantages of the present invention will be illustrated in the following description, also, partly becomes from specification
It obtains it is clear that understand through the implementation of the invention.The objectives and other advantages of the invention can be by specification, right
Specifically noted structure is achieved and obtained in claim and attached drawing.
Detailed description of the invention
Attached drawing is used to provide to further understand technical solution of the present invention, and constitutes part of specification, with this
The specific embodiment of application technical solution for explaining the present invention together, does not constitute the limit to technical solution of the present invention
System.
Fig. 1 is glass material composed structure schematic diagram described in the embodiment of the present invention 1.
It is fluorine carbon self-cleaning coating 1, glassy layer 2, PVB glue bonding layer 3, chip coated glass layer 4, PVB glue bonding layer 5, wired
Glue bonding layer 9, high light transmission PC layer 10, scratch-resistant plastic film is perfused in glassy layer 6, PU perfusion glue bonding layer 7, high light transmission PC layer 8, PU
11
Specific embodiment
The present invention is described in more detail below with reference to accompanying drawings, which show the preferred embodiment of the present invention,
It should be understood that those skilled in the art can modify invention described herein and still realize beneficial effects of the present invention.Cause
This, following description should be understood as the widely known of those skilled in the art, and be not intended as limitation of the present invention.
Term PC, that is, polycarbonate (English: Polycarbonate is abbreviated as PC) refers to and contains carbonate group in strand
High molecular polymer, the multiple types such as aliphatic, aromatic series, aliphatic-aromatic can be divided into according to the structure of ester group, due to
Particularity on polycarbonate structure, it has also become the most fast general engineering plastic of growth rate in five large-engineering plastics.
Polymer refers to the polymerizable compound prepared and being polymerize the monomer of whether identical or different class.It is logical
It thus include homopolymer (generally referring to by a kind of unique polymer of monomer preparation) and interpretation with term polymer.
Term PVB, that is, polyvinyl butyral (English: Polyvinyl Butyral is abbreviated as PVB).PVB film is half
Transparent membrane has fine cohesive force to unorganic glass, has the characteristics such as transparent, heat-resisting, cold-resistant, mechanical strength is high, is manufacture folder
The optimum adhesion material of layer glass.PVB film can absorb impact energy, not generate flinders, and this safety glass is answered extensively
For automobile, skyscraper, bank counter, various bulletproof glasses etc..While with security performance, there are also it is excellent every
Sound, light-operated, heat preservation, heat-insulated, the performances such as shockproof are optimal safety glass rapidoprints in the world.
Term SGP (Sentry Glas Plus) intermediate coat is researched and developed by E.I.Du Pont Company, the folder with significant innovation technology
Layer middle membrane of glass.SGP has surmounted the prior art, has expanded laminated glass performance significantly.The tearing strength of SGP is common PVB
5 times degree, hardness is 100 times of common PVB.High intensity, high transparency, durability, various structures and the flexible installation of SGP,
The newest most stringent of requirement of current construction market can be adapted to easily.Relatively common laminated glass, SGP laminated glass can mention
The performance of high bulletproof glass can reduce the thickness of laminated glass to a certain extent.
Term PU, that is, Polyurethane (English: Polyurethane is abbreviated as PU) refers to special containing carbamate in main chain
A kind of macromolecule of unit is levied, this high molecular material is widely used in binder, coating, low speed tire, washer, the industry such as car cushion
Field.
For clarity, not describing whole features of practical embodiments.In the following description, it is not described in detail well known function
And structure, because they can make the present invention chaotic due to unnecessary details.It will be understood that opening in any practical embodiments
In hair, it is necessary to make a large amount of implementation details to realize the specific objective of developer.
To be clearer and more comprehensible the purpose of the present invention, feature, a specific embodiment of the invention is made with reference to the accompanying drawing
Further instruction.It should be noted that attached drawing is all made of very simplified form and using non-accurate ratio, it is only used for
Purpose that is convenient, clearly aiding in illustrating the embodiment of the present invention.
Embodiment 1
The method of being prepared as follows prepares the present embodiment:
(1) after being cleaned and dried the glassy layer of thickness 3mm, coevaporation technology depositing photovoltaic chip is used in upper surface
Coating, and delineated using laser method, the chip coating size of space and arrangement density are adjusted, to obtain the chip of light transmittance 50%
Coated glass layer 4；
It (2) upward by the chip coating of the chip coated glass layer 4 of light transmittance 50%, will after glassy layer 2 being cleaned and dried
Glassy layer 2, PVB glue bonding layer 3, chip coated glass layer 4, PVB glue bonding layer 5 and wire glass layer 6 are successively folded from top to bottom
Adduction piece is put into precompressed in the roll squeezer after preheating, and keeping glass surface temperature after roll-in is 70 DEG C or so, and cooling is spare, obtains
To precompressed composite sample；
(3) precompressed composite sample prepared by step (2) is put into autoclave, increasing temperature and pressure is kept to 120 DEG C, 1MPa
60min, after be cooled to 40 DEG C hereinafter, rear slow release, opens autoclave and obtain high pressure composite sample；
(4) 2000 turns/min of PU glue major ingredient and curing agent is uniformly mixed, after vacuum defoamation, by preparation in step (3)
Composite sample in 6 one side of wire glass layer and high light transmission PC layer 8 to carry out the encapsulating of PU glue Nian Jie, PU is obtained after cooling and solidifying and is perfused
Glue bonding layer 7；
(5) 2000 turns/min of PU glue major ingredient and curing agent is uniformly mixed, after vacuum defoamation, by preparation in step (4)
Composite sample in 8 one side of high light transmission PC layer and high light transmission PC layer 10 to carry out the encapsulating of PU glue Nian Jie, PU is obtained after cooling and solidifying and is filled
Injecting glue adhesive layer 9；
(6) composite sample for preparing step (5), in 10 side adhesive thickness 1mm scratch-resistant plastic film of high light transmission PC layer；
(7) mixing vessel is added in fluorocarbon resin substrate, age resister and curing agent, 2000 turns/min of high speed is stirred
After uniformly, fluorine carbon self-cleaning coating wet film is coated with by spraying method in 2 surface of composite sample glassy layer of step (6) preparation, so
Above-mentioned sample is placed in air dry oven afterwards, 80 DEG C of drying 5min of high temperature, drying at room temperature obtains fluorine carbon self-cleaning coating 1.
As shown in Figure 1, it is manufactured in the present embodiment with higher bulletproof effect can power generating glass material, from top to bottom successively
For fluorine carbon self-cleaning coating 1, glassy layer 2, PVB glue bonding layer 3, chip coated glass layer 4, PVB glue bonding layer 5, wire glass layer
6, PU is perfused glue bonding layer 7, high light transmission PC layer 8, PU and glue bonding layer 9, high light transmission PC layer 10, scratch-resistant plastic film 11 is perfused.
Fluorine carbon self-cleaning coating 1 is with a thickness of 50 μm；PVB glue bonding layer 3 is greater than 90% with a thickness of 1.05mm, light transmittance；Chip
Coated glass layer 4 is with a thickness of 3mm, light transmittance 50%；PVB glue bonding layer 5 is greater than 90% with a thickness of 2.28mm, light transmittance；It is wired
Glassy layer 6 is with a thickness of 3mm；Glue bonding layer 7 is perfused with a thickness of 1mm in PU；With a thickness of 2mm, light transmittance is greater than high light transmission PC layer 8
90%；Glue bonding layer 9 is perfused with a thickness of 1.5mm in PU；High light transmission PC layer 10 is greater than 90% with a thickness of 4.5mm, light transmittance；Scratch resistant modeling
Expect film 11 with a thickness of 1mm.
Embodiment 2
The method of being prepared as follows prepares the present embodiment:
(1) after being cleaned and dried the glassy layer of thickness 6mm, coevaporation technology depositing photovoltaic chip is used in upper surface
Coating, and delineated using laser method, the chip coating size of space and arrangement density are adjusted, to obtain the chip of light transmittance 20%
Coated glass layer 4；
It (2) upward by the chip coating of the chip coated glass layer 4 of light transmittance 20%, will after glassy layer 2 being cleaned and dried
Glassy layer 2, the heat-insulated glue bonding layer 3 of PVB handled through heat insulation nano antimony doped tin oxide or heat insulation nano tin-doped indium oxide, chip plate
Film glass layer 4, the heat-insulated glue bonding layer 5 of PVB and folder handled through heat insulation nano antimony doped tin oxide or heat insulation nano tin-doped indium oxide
Silk glassy layer 6 is sequentially overlapped conjunction piece from top to bottom, and precompressed in the roll squeezer after being put into preheating keeps glass surface temperature after roll-in
It is 70 DEG C or so, cooling is spare, obtains precompressed composite sample；
(3) precompressed composite sample prepared by step (2) is put into autoclave, increasing temperature and pressure is protected to 140 DEG C, 1.5MPa
Hold 30min, after be cooled to 40 DEG C hereinafter, rear slow release, opens autoclave and obtain high pressure composite sample；
(4) 2000 turns/min of PU glue major ingredient and curing agent is uniformly mixed, after vacuum defoamation, by preparation in step (3)
Composite sample in 6 one side of wire glass layer and high light transmission PC layer 8 to carry out the encapsulating of PU glue Nian Jie, PU is obtained after cooling and solidifying and is perfused
Glue bonding layer 7；
(5) 2000 turns/min of PU glue major ingredient and curing agent is uniformly mixed, after vacuum defoamation, by preparation in step (4)
Composite sample in 8 one side of high light transmission PC layer and high light transmission PC layer 10 to carry out the encapsulating of PU glue Nian Jie, PU is obtained after cooling and solidifying and is filled
Injecting glue adhesive layer 9；
(6) composite sample for preparing step (5), in 10 side adhesive thickness 1mm scratch-resistant plastic film of high light transmission PC layer；
(7) mixing vessel is added in fluorocarbon resin substrate, age resister and curing agent, 2000 turns/min of high speed is stirred
After uniformly, fluorine carbon self-cleaning coating wet film is coated with by blade coating mode in 2 surface of composite sample glassy layer of step (6) preparation, so
Above-mentioned sample is placed in air dry oven afterwards, 100 DEG C of drying 1min of high temperature, drying at room temperature obtains fluorine carbon self-cleaning coating 1.
It is manufactured in the present embodiment with higher bulletproof effect can power generating glass material, be followed successively by fluorine carbon self-cleaning from top to bottom
Coating 1, glassy layer 2, the heat-insulated glue bonding layer 3 of PVB handled through heat insulation nano antimony doped tin oxide or heat insulation nano tin-doped indium oxide,
Chip coated glass layer 4, the heat-insulated glue bonding layer of PVB handled through heat insulation nano antimony doped tin oxide or heat insulation nano tin-doped indium oxide
5, glue bonding layer 9, high light transmission PC layer 10, scratch resistant modeling is perfused in wire glass layer 6, PU perfusion glue bonding layer 7, high light transmission PC layer 8, PU
Expect film 11.
Fluorine carbon self-cleaning coating 1 is with a thickness of 500 μm；It is handled through heat insulation nano antimony doped tin oxide or heat insulation nano tin-doped indium oxide
The heat-insulated glue bonding layer 3 of PVB with a thickness of 0.38mm, light transmittance is greater than 90%；Chip coated glass layer 4 is with a thickness of 6mm, light transmittance
20%；The heat-insulated glue bonding layer 5 of PVB handled through heat insulation nano antimony doped tin oxide or heat insulation nano tin-doped indium oxide with a thickness of
1.5mm, light transmittance are greater than 90%；Wire glass layer 6 is with a thickness of 6mm；Glue bonding layer 7 is perfused with a thickness of 2mm in PU；PC layers of high light transmission
8 are greater than 90% with a thickness of 6mm, light transmittance；Glue bonding layer 9 is perfused with a thickness of 1.1mm in PU；High light transmission PC layer 10 is with a thickness of 2mm, thoroughly
Light rate is greater than 90%；Scratch-resistant plastic film 11 is with a thickness of 1mm.
The foregoing describe the preferred embodiment for the present invention, and however, it is not to limit the invention.Those skilled in the art couple
Embodiment disclosed herein can carry out the improvements and changes without departing from scope and spirit.
Claims (10)
1. a kind of glass successively includes the first glassy layer, the second glassy layer and burster course, which is characterized in that second glass
Layer is chip coated glass layer, is the first adhesive layer between first glassy layer and the second glassy layer, the second glassy layer and anti-
It is the second adhesive layer between bullet layer.
2. glass according to claim 1, which is characterized in that the chip coated glass layer is with a thickness of 3-6mm, light transmittance
For 20%-50%.
3. glass according to claim 2, which is characterized in that first adhesive layer and the second adhesive layer using PVB,
Any one or a few in SGP, PU film, with a thickness of 0.38-2.28mm, 90% or more light transmittance.
4. glass according to claim 3, which is characterized in that first adhesive layer and the second adhesive layer are used through heat-insulated
Nano antimony doped tin oxide or the heat-insulated film of PVB of heat insulation nano tin-doped indium oxide processing.
5. glass according to claim 1, which is characterized in that the burster course successively includes third glassy layer, the first PC
Layer and the 2nd PC layer, the third glassy layer and the first is third adhesive layer between PC layers, the first PC layers and the 2nd between PC layers
For the 4th adhesive layer.
6. glass according to claim 5, which is characterized in that the third glassy layer is wire glass layer, with a thickness of 3-
6mm。
7. glass according to claim 5, which is characterized in that first PC plate and the second PC plate are with a thickness of 2-6mm, thoroughly
90% or more light rate.
8. glass according to claim 5, which is characterized in that the third adhesive layer and the 4th adhesive layer are PU potting compound
Adhesive layer, PU are perfused after adhesive curing with a thickness of 1-2mm.
9. glass according to claim 1, which is characterized in that be provided with self-cleaning coat on the outside of first glassy layer, prevent
Preventing from scraping film is provided on the outside of bullet layer.
10. the preparation method of any one of -9 glass according to claim 1, the preparation method comprises the following steps:
(1) coevaporation technology depositing photovoltaic chip coating is used, and the different chip coating size of space is delineated using laser method
And arrangement density, obtain second glassy layer with different light transmittances；
(2) from top to bottom successively by the first glassy layer, the first adhesive layer, the second glassy layer, the second adhesive layer and wire glass layer
Piece is closed in superposition, and precompressed obtains composite sample；
(3) high pressure composite sample is made in the composite sample high-temperature high-pressure of step (2)；
(4) the high pressure composite sample of step (3) is laminated Nian Jie with the first PC layers of progress PU perfusion in wire glass, it is cooling solid
Third adhesive layer is obtained after change；It is laminated Nian Jie with the 2nd PC layers of progress PU perfusion in the first PC, the 4th is obtained after cooling and solidifying
Adhesive layer.
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| CN201811074464.1A CN109109408A (en) | 2018-09-14 | 2018-09-14 | Special glass and its preparation process |
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|---|---|---|---|
| CN201811074464.1A CN109109408A (en) | 2018-09-14 | 2018-09-14 | Special glass and its preparation process |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112165286A (en) * | 2020-09-03 | 2021-01-01 | 成都中建材光电材料有限公司 | Bullet-proof radiation-proof power generation glass capable of shielding electromagnetic signals and preparation method thereof |
| CN112455027A (en) * | 2020-11-27 | 2021-03-09 | 中国建筑材料科学研究总院有限公司 | Laminated glass plate and manufacturing method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4879183A (en) * | 1987-07-08 | 1989-11-07 | Mannheim Jose R | Method to manufacture a blindaged glass |
| CN204354544U (en) * | 2014-11-18 | 2015-05-27 | 大连华鹰玻璃股份有限公司 | A kind of light-duty bulletproof glass |
| WO2015156676A1 (en) * | 2014-04-11 | 2015-10-15 | Aviation Glass & Technology B.V. | Vehicle mirror, and method for manufacturing such a mirror |
| CN105633182A (en) * | 2016-02-18 | 2016-06-01 | 安徽旭能光伏电力有限公司 | Double-glass photovoltaic module |
| CN106129153A (en) * | 2016-08-23 | 2016-11-16 | 江苏亚太新能源科技有限公司 | A kind of solar energy photovoltaic glass |
| CN106957621A (en) * | 2017-03-17 | 2017-07-18 | 深圳市捷源环保科技有限公司 | A kind of PVB films preparation method and applications of nano heat-insulating dispersion |
| CN207489881U (en) * | 2017-08-29 | 2018-06-12 | 程尧环保科技（上海）有限公司 | A kind of photovoltaic glass with silicon dioxide film |
-
2018
- 2018-09-14 CN CN201811074464.1A patent/CN109109408A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4879183A (en) * | 1987-07-08 | 1989-11-07 | Mannheim Jose R | Method to manufacture a blindaged glass |
| WO2015156676A1 (en) * | 2014-04-11 | 2015-10-15 | Aviation Glass & Technology B.V. | Vehicle mirror, and method for manufacturing such a mirror |
| CN204354544U (en) * | 2014-11-18 | 2015-05-27 | 大连华鹰玻璃股份有限公司 | A kind of light-duty bulletproof glass |
| CN105633182A (en) * | 2016-02-18 | 2016-06-01 | 安徽旭能光伏电力有限公司 | Double-glass photovoltaic module |
| CN106129153A (en) * | 2016-08-23 | 2016-11-16 | 江苏亚太新能源科技有限公司 | A kind of solar energy photovoltaic glass |
| CN106957621A (en) * | 2017-03-17 | 2017-07-18 | 深圳市捷源环保科技有限公司 | A kind of PVB films preparation method and applications of nano heat-insulating dispersion |
| CN207489881U (en) * | 2017-08-29 | 2018-06-12 | 程尧环保科技（上海）有限公司 | A kind of photovoltaic glass with silicon dioxide film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112165286A (en) * | 2020-09-03 | 2021-01-01 | 成都中建材光电材料有限公司 | Bullet-proof radiation-proof power generation glass capable of shielding electromagnetic signals and preparation method thereof |
| CN112455027A (en) * | 2020-11-27 | 2021-03-09 | 中国建筑材料科学研究总院有限公司 | Laminated glass plate and manufacturing method thereof |
| CN112455027B (en) * | 2020-11-27 | 2022-09-20 | 中国建筑材料科学研究总院有限公司 | Laminated glass plate and manufacturing method thereof |
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