CN109095950A - A kind of dental zirconium oxide ceramics screening color liquid and its preparation method and application - Google Patents
A kind of dental zirconium oxide ceramics screening color liquid and its preparation method and application Download PDFInfo
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- CN109095950A CN109095950A CN201810974678.8A CN201810974678A CN109095950A CN 109095950 A CN109095950 A CN 109095950A CN 201810974678 A CN201810974678 A CN 201810974678A CN 109095950 A CN109095950 A CN 109095950A
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- 239000007788 liquid Substances 0.000 title claims abstract description 95
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 title description 99
- 229910001928 zirconium oxide Inorganic materials 0.000 title description 99
- 239000011224 oxide ceramic Substances 0.000 title description 75
- 238000012216 screening Methods 0.000 title description 30
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000008367 deionised water Substances 0.000 claims abstract description 35
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000000919 ceramic Substances 0.000 claims abstract description 23
- 239000000654 additive Substances 0.000 claims abstract description 13
- 230000000996 additive effect Effects 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract 7
- 239000011259 mixed solution Substances 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 14
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 claims description 14
- 229940012189 methyl orange Drugs 0.000 claims description 14
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims description 14
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 235000012730 carminic acid Nutrition 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000007943 implant Substances 0.000 claims 3
- 235000010208 anthocyanin Nutrition 0.000 claims 1
- 239000004410 anthocyanin Substances 0.000 claims 1
- 229930002877 anthocyanin Natural products 0.000 claims 1
- 150000004636 anthocyanins Chemical class 0.000 claims 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims 1
- 235000012756 tartrazine Nutrition 0.000 claims 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 claims 1
- 239000004149 tartrazine Substances 0.000 claims 1
- 229960000943 tartrazine Drugs 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000004088 simulation Methods 0.000 abstract 1
- 238000005245 sintering Methods 0.000 description 33
- 230000001680 brushing effect Effects 0.000 description 31
- 239000011347 resin Substances 0.000 description 21
- 229920005989 resin Polymers 0.000 description 21
- 238000004506 ultrasonic cleaning Methods 0.000 description 16
- 235000015895 biscuits Nutrition 0.000 description 14
- 239000011324 bead Substances 0.000 description 9
- 244000248349 Citrus limon Species 0.000 description 7
- 235000005979 Citrus limon Nutrition 0.000 description 7
- 230000009286 beneficial effect Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 4
- 229910020451 K2SiO3 Inorganic materials 0.000 description 3
- 229930014669 anthocyanidin Natural products 0.000 description 3
- 150000001452 anthocyanidin derivatives Chemical class 0.000 description 3
- 235000008758 anthocyanidins Nutrition 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 241000220317 Rosa Species 0.000 description 2
- 229910020489 SiO3 Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- 229910052845 zircon Inorganic materials 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000006112 glass ceramic composition Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Inorganic materials [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 1
- LBVWQMVSUSYKGQ-UHFFFAOYSA-J zirconium(4+) tetranitrite Chemical compound [Zr+4].[O-]N=O.[O-]N=O.[O-]N=O.[O-]N=O LBVWQMVSUSYKGQ-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5007—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
- C04B41/5009—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing containing nitrogen in the anion, e.g. nitrites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dental Preparations (AREA)
- Dental Prosthetics (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
本发明公开了一种牙科氧化锆陶瓷用遮色液，包括遮色剂、颜色指示剂、添加剂和去离子水；其能够有效的降低牙齿修复体内部的透明度、却不影响修复体外部的颜色效果；同时本发明还公开了一种牙科氧化锆陶瓷用遮色液的制备方法，具有过程简单、制作成本低、重复性能好的显著优点；并且，本发明还公开了一种牙科氧化锆陶瓷用遮色液的应用和应用方法，能够显著改善牙科氧化锆陶瓷存在的内部透明度过高的问题，使最终得到的牙齿修复体能够呈现自然仿真的效果。The invention discloses a color-masking liquid for dental zirconia ceramics, which comprises a color-masking agent, a color indicator, an additive and deionized water; it can effectively reduce the transparency inside a dental restoration without affecting the color of the exterior of the restoration effect; at the same time, the present invention also discloses a preparation method of a dental zirconia ceramic opacifying liquid, which has the remarkable advantages of simple process, low production cost and good repeatability; and, the present invention also discloses a dental zirconia ceramic The application and application method of the opacifying liquid can significantly improve the problem of excessive internal transparency of dental zirconia ceramics, so that the final dental restoration can present a natural simulation effect.
Description
Technical field
The present invention relates to dental polishing technical field, more particularly to a kind of dental zirconium oxide ceramics screening color liquid
And its preparation method and application.
Background technique
Currently, dental polishing refers to glass ceramic material and product for dental treatment and reparation, belong to medical instrument
Scope.Zirconia ceramics has excellent mechanical property, and bending strength is more than 1000MPa, and relatively thin thickness can reach very
High intensity is ideal dental prosthetic material.In Dental Erosion treatment, dummy in addition to need to have certain intensity,
Wearability, corrosion resistance and biocompatibility should also have good aesthetic characteristic.Especially in recent years, with national life water
The requirement of flat progress, degree of closeness of the patient to dental prosthesis with natural tooth in appearance is higher and higher.And zirconium oxide is made pottery
Porcelain is closest with natural tooth due to excellent translucency, so paying close attention to by people.
But there are still significant as the dental prosthesis material of most rationality for discovery zirconia ceramics in practical applications
Defect: firstly, in use if abutment color relatively depth or having planted metal base station, zirconium oxide all-ceramic crown can appear abutment
Color or appear the black of metal base station, to cause that the effect of nature emulation cannot be presented away from larger with adjacent teeth colour-difference；
Secondly, the method complexity in the prior art dyed to dental zirconium oxide ceramics, raw material complicated composition, cost of material height.
Therefore it provides it is those skilled in the art that a kind of dental zirconium oxide ceramics, which hide color liquid and its preparation method and application,
The problem of urgent need to resolve.
Summary of the invention
Color liquid is hidden in view of this, using the present invention provides a kind of dental zirconium oxide ceramics, the raw material used is simple, easy
, preparation method is simple, can largely repeat, and is applied to dental zirconium oxide ceramics, can be realized reduction zirconia ceramics
The transparency of inside, the effect for not influencing zirconium oxide exterior color but.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of dental zirconium oxide ceramics screening color liquid, which is characterized in that the component including following mass parts: 1~50 part of screening
Toner, 0.01~0.2 part of color indicator, 5~20 parts of additives and 100 parts of deionized waters；The opaque resin is in hiding color liquid
Molar concentration be 0.02~2mol/L.
The beneficial effect of above-mentioned optimal technical scheme is: a kind of dental zirconium oxide biscuit ceramics screening color disclosed by the invention
Liquid, raw material composition is simple, cost of material is low, and preparation method and application method are relatively easy；Meanwhile being applied to dentistry oxygen
The transparency inside dental prosthesis can be effectively reduced by changing zircon ceramic, not influence the color effects outside dummy but.
Preferably, the opaque resin includes Al (NO3)3·9H2O、Zr(NO3)4〃5H2O、KOH、NaOH、Na2SiO3·
9H2O、K2SiO3With one or both of KH-570 mixing.
The beneficial effect of above-mentioned optimal technical scheme is: the above-mentioned opaque resin that the present invention uses can be adsorbed on zirconium oxide element
Base surface forms interstitial solid solution by 1400-1600 DEG C of high-temperature calcination, so as to reduce the transparency of zirconium surface, with
Achieve the effect that hide color, so that dental zirconium oxide ceramics use process meets aesthetic.
Preferably, the color indicator include that methyl orange, anthocyanidin, famille rose, lemon yellow, tender leaf be green or sunset yellow its
One or both of mixing.
The beneficial effect of above-mentioned optimal technical scheme is: color indicator that the present invention uses and opaque resin, additive and
Deionized water, which cooperates, can achieve the effect that change the color for hiding color liquid, so as to intuitively show to apply brushing effects,
So that the position brushed is more accurate, easy to use.
Preferably, described additive packet PEG400, PEG600 or PEG1000 be one such or two kinds of mixing.
The beneficial effect of above-mentioned optimal technical scheme is: additive that the present invention uses and opaque resin, color indicator and
Deionized water is used cooperatively, and the effect for increasing system viscosity may be implemented, to prevent opaque resin downward from zirconium oxide biscuit surface
Infiltration is too deep and influences integral color effect；And it is possible to the surface tension of mixed system be reduced, more in zirconium oxide biscuit
External coating forms uniform opaque resin coating.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, which is characterized in that specifically comprise the following steps:
(1) each raw material is weighed with color liquid is hidden according to a kind of dental zirconium oxide ceramics as described above, it is spare；
(2) first opaque resin is add to deionized water, is uniformly mixed, is completely dissolved opaque resin, obtains mixed solution；
(3) state then up and color indicator and additive be added in mixed solution, be uniformly mixed, make color indicator and
A kind of dental zirconium oxide ceramics screening color liquid can be obtained in additive uniform dissolution.
Preferably, it is uniformly mixed in the step (2) specifically: opaque resin is added in deionized water, is subsequently placed in super
In sound wave washer, setting ultrasonic vibration power is 100W~300W, and the ultrasonic vibration time is 30min~50min.
Preferably, it is uniformly mixed in the step (3) specifically: face will be added comprising the solution of opaque resin and deionized water
Color indicator and additive, are subsequently placed in ultrasonic cleaner, and setting ultrasonic vibration power is 100W~300W, ultrasonic vibration
Time is 10min~30min.
The beneficial effect of above-mentioned optimal technical scheme is: preparation method process disclosed by the invention is simple, low manufacture cost,
Repeatability is good；Raw material can be uniformly mixed, so that the screening color fluidity matter stable homogeneous being prepared, convenient transportation, preservation
With use, and can guarantee that raw material never degenerates in preparation process, so that the screening color liquid being prepared can reduce zirconia ceramics
Internal transparency does not influence color outside zirconium oxide but.
A kind of application as described above hiding color liquid in the biscuits such as dental zirconium oxide plantation, interior hat, complete crown, crossover.
The beneficial effect of above-mentioned optimal technical scheme is: a kind of screening color liquid disclosed above is applied to dentistry oxygen by the present invention
Change zircon ceramic, can significantly improve inner transparent existing for dental zirconium oxide ceramics and spend high problem, so that being prepared by it
To dental prosthesis can present nature emulation effect.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, which is characterized in that will first hide color liquid as described above
The inner surface for brushing the biscuit of hat, zirconium oxide complete crown or zirconium oxide crossover in zirconium oxide planting body, zirconium oxide, then passes through
1400-1600 DEG C of high temperature sintering 2h can form white coating in the inner surface of planting body, interior hat, complete crown or crossover.
The beneficial effect of above-mentioned optimal technical scheme is: application method disclosed by the invention can be in dental zirconium oxide ceramics
Inner surface forms stable white coating, and the dental prosthesis made shows good service performance in application process,
Not only have the characteristics that color is naturally beautiful, but also there is excellent physical mechanical strength, wearability, corrosion resistance and biofacies
Capacitive.
It can be seen via above technical scheme that compared with prior art, the present disclosure provides a kind of dental zirconium oxides
Ceramics are reduced the principle of zirconium oxide transparency using opaque resin, can be effectively reduced inside dental prosthesis with color liquid is hidden
Transparency does not influence color effects outside dummy but；The invention also discloses a kind of screenings of dental zirconium oxide ceramics simultaneously
The preparation method of color liquid, the remarkable advantage simple with process, low manufacture cost, Repeatability are good；Also, invention additionally discloses
A kind of dental zirconium oxide ceramics apply and methods for using thems with hide color liquid, can significantly improve existing for dental zirconium oxide ceramics
Inner transparent spends high problem, enables and the effect that nature emulates is presented by the dental prosthesis that it is prepared.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
The embodiment of the present invention 1 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including Al (NO3)3〃9H2O 1.0g, methyl orange indicator 0.08g,
PEG400 10g and deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) 1.0gAl (NO is weighed3)3〃9H2O, 0.08g methyl orange and 10g PEG400, and it is standby to measure 100g deionized water
With；
(2) first by Al (NO3)3〃9H2O is add to deionized water, and then whole mixed system is added to ultrasonic cleaning
It is 300W that ultrasonic vibration power is arranged in device, is mixed by 30min ultrasonic vibration, until opaque resin is completely dissolved to obtain
0.027mol/L mixed solution；
(3) methyl orange and PEG400 are then added into above-mentioned mixed solution, continues that ultrasound is arranged in ultrasonic cleaning machine
Vibration power is 300W, is mixed by 10min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color liquid can be obtained.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1450 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 2
The embodiment of the present invention 2 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including Al (NO3)3〃9H2O 20g, lemon yellow indicator 0.12g,
PEG400 15g and deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) 20g Al (NO is weighed3)3〃9H2O, 0.12g lemon yellow and 15g PEG400, and it is standby to measure 100g deionized water
With；
(2) first by Al (NO3)3〃9H2O is add to deionized water, and then whole mixed system is added to ultrasonic cleaning
It is 200W that ultrasonic vibration power is arranged in device, is mixed by 50min ultrasonic vibration, until opaque resin is completely dissolved to obtain 0.53mol/
L mixed solution；
(3) lemon yellow and PEG400 are then added into above-mentioned mixed solution, continues that ultrasound is arranged in ultrasonic cleaning machine
Vibration power is 200W, is mixed by 30min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color liquid can be obtained.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1500 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 3
The embodiment of the present invention 3 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including Al (NO3)3〃9H2O 50g, methyl orange indicator 0.1g, cyanine
Plain indicator 0.1g, PEG400 20g and deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) 50g Al (NO is weighed3)3〃9H2O, 0.1g methyl orange, 0.1g anthocyanidin and 20g PEG400, and measure 100g
Deionized water is spare；
(2) first by Al (NO3)3〃9H2O is add to deionized water, and then whole mixed system is added to ultrasonic cleaning
It is 100W that ultrasonic vibration power is arranged in device, is mixed by 45min ultrasonic vibration, until opaque resin is completely dissolved to obtain 1.33mol/
L mixed solution；
(3) methyl orange, anthocyanidin and PEG400 are then added into above-mentioned mixed solution, continuation is set in ultrasonic cleaning machine
Setting ultrasonic vibration power is 200W, is mixed by 25min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color can be obtained
Liquid.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1530 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 4
The embodiment of the present invention 4 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including Na2SiO3〃9H2O 18g, carmine indicator 0.18g,
PEG600 13g and deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) 18gNa is weighed2SiO3〃9H2O, 0.18g famille rose indicator and 13g PEG600, and measure 100g deionization
Water is spare；
(2) first by Na2SiO3〃9H2O is add to deionized water, and then whole mixed system is added to ultrasonic cleaning machine
Middle setting ultrasonic vibration power is 260W, is mixed by 45min ultrasonic vibration, until opaque resin is completely dissolved to obtain 0.63mol/L
Mixed solution；
(3) carmine indicator and PEG600 are then added into above-mentioned mixed solution, continuation is set in ultrasonic cleaning machine
Setting ultrasonic vibration power is 100W, is mixed by 30min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color can be obtained
Liquid.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1580 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 5
The embodiment of the present invention 5 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including the green indicator 0.06g of KH-570 7g, tender leaf, PEG600 13g
With deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) 7g KH-570, the green indicator of 0.06g tender leaf and 13g PEG600 are weighed, and it is standby to measure 100g deionized water
With；
(2) first KH-570 is add to deionized water, then whole mixed system is added and is set into ultrasonic cleaning machine
Setting ultrasonic vibration power is 260W, is mixed by 50min ultrasonic vibration, until opaque resin is completely dissolved to obtain 0.28mol/L mixing
Solution；
(3) the green indicator of tender leaf and PEG600 are then added into above-mentioned mixed solution, continuation is set in ultrasonic cleaning machine
Setting ultrasonic vibration power is 100W, is mixed by 30min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color can be obtained
Liquid.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1470 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 6
The embodiment of the present invention 6 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics with hiding color liquid, including KOH 5.3g, sunset yellow indicator 0.18g, PEG400 10g,
PEG600 5g and deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) 5.3gKOH, 0.18g sunset yellow, 10g PEG400 and 5g PEG600 are weighed, and it is standby to measure 100g deionized water
With；
(2) first KOH is add to deionized water, it is super that setting is then added into ultrasonic cleaning machine in whole mixed system
Acoustic vibration power is 190W, is mixed by 50min ultrasonic vibration, until opaque resin is completely dissolved to obtain 0.94mol/L mixed solution；
(3) sunset yellow indicator and PEG400, PEG600 are then added into above-mentioned mixed solution, continuation is being cleaned by ultrasonic
It is 100W that ultrasonic vibration power is arranged in device, is mixed by 30min ultrasonic vibration, and a kind of dental zirconium oxide ceramics use can be obtained
Hide color liquid.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1480 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 7
The embodiment of the present invention 7 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including K2SiO330.9g, lemon yellow indicator 0.03g, PEG1000
10g and deionized water 100g.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) K is weighed2SiO330.9g, lemon yellow indicator 0.03g, PEG1000 10g and deionized water 100g are spare；
(2) first by K2SiO3It is add to deionized water, then whole mixed system is added and is arranged into ultrasonic cleaning machine
Ultrasonic vibration power is 220W, is mixed by 37min ultrasonic vibration, until to be completely dissolved to obtain 2.00mol/L mixing molten for opaque resin
Liquid；
(3) lemon yellow indicator and PEG1000 are then added into above-mentioned mixed solution, continuation is set in ultrasonic cleaning machine
Setting ultrasonic vibration power is 260W, is mixed by 23min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color can be obtained
Liquid.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1520 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 8
The embodiment of the present invention 8 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics screening color liquid, including Zr (NO3)4〃5H2O 10g, methyl orange indicator 0.2g,
PEG1000 15g and 100g deionized water.
A kind of dental zirconium oxide ceramics preparation method for hiding color liquid, specifically comprises the following steps:
(1) Zr (NO is weighed3)4〃5H2O 10g, methyl orange indicator 0.2g, PEG1000 15g and 100g deionized water are standby
With；
(2) first by Zr (NO3)4〃5H2O is add to deionized water, and then whole mixed system is added to ultrasonic cleaning
It is 230W that ultrasonic vibration power is arranged in device, is mixed by 30min ultrasonic vibration, until opaque resin is completely dissolved to obtain
0.233mol/L mixed solution；
(3) methyl orange indicator and PEG1000 are then added into above-mentioned mixed solution, continuation is set in ultrasonic cleaning machine
Setting ultrasonic vibration power is 300W, is mixed by 10min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color can be obtained
Liquid.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1430 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Embodiment 9
The embodiment of the present invention 9 discloses a kind of dental zirconium oxide ceramics and hides color liquid and its preparation method and application.
A kind of dental zirconium oxide ceramics with hiding color liquid, including NaOH 3.8g, KOH 4g, methyl orange indicator 0.2g,
PEG600 10g and 100g deionized water.
(1) 3.8g NaOH, 4g KOH, 0.2g methyl orange indicator, 10gPEG600 and 100g deionized water are weighed, it is standby
With；
(2) first NaOH and KOH (sequence is unlimited) are add to deionized water, then whole mixed system is added to super
It is 180W that ultrasonic vibration power is arranged in sound washer, mixes by 30min ultrasonic vibration, is mixed until opaque resin is completely dissolved
Close solution；
(3) methyl orange indicator, PEG600 are then added into above-mentioned mixed solution, continuation is arranged in ultrasonic cleaning machine
Ultrasonic vibration power is 250W, is mixed by 10min ultrasonic vibration, and a kind of dental zirconium oxide ceramics screening color liquid can be obtained.
A kind of dental zirconium oxide ceramics application method for hiding color liquid, specific steps are as follows:
(a) a kind of above-mentioned dental zirconium oxide ceramics being prepared first are hidden into the brushing of color liquid in zirconium oxide using glazing pen
Inside the corona of dummy biscuit, brushing sequence is from jaw face to the last brushing bead of tooth cut end；
(b) be subsequently placed in high temperature sintering furnace, setting sintering temperature be 1600 DEG C, sintering time 2h, can be obtained most
Whole dental prosthesis.
Effect detection is carried out with color liquid is hidden to a kind of dental zirconium oxide ceramics that above-described embodiment 1-9 is prepared.Wherein,
The dental prosthesis, small pieces and the intensity item that do not carry out hiding the processing of color liquid are placed in high temperature sintering furnace, setting sintering temperature is
1530 DEG C, sintering time 2h carry out date comprision with embodiment 1-9 as a control group after sintering.
One, the brushing of color liquid is hidden in the one side of small pieces by what above-described embodiment 1-9 was prepared respectively；It is subsequently placed in sintering furnace
In, it is sintered under the conditions of 1530 DEG C；Optical detection finally is carried out to by sintered small pieces, detection obtains light transmittance, as a result
As shown in table 1.
Two, the screening color liquid brushing that above-described embodiment 1-9 is prepared respectively is in six faces of intensity item；It is subsequently placed in burning
In freezing of a furnace, it is sintered under the conditions of 1530 DEG C；Mechanics properties testing finally is carried out to by sintered intensity item, obtains at 3 points and resists
Curved intensity results are as shown in table 1.
Three, above-described embodiment 1-9 dummy being prepared is worn over above black abutment respectively, from apparently seeing tooth
Whether the color of abutment is permeated, and the results are shown in Table 1.
Table 1
It can obviously be learnt by above-mentioned data: compared to control group, screening color liquid energy that 1-9 of the embodiment of the present invention is prepared
The light transmittance of dental zirconium oxide ceramic material is enough significantly reduced, so that the dental prosthesis light transmittance formed reduces, so as to
The color of abutment is avoided to influence whole aesthetics through dental prosthesis；The screening that 1-9 of the embodiment of the present invention is prepared
Color liquid is applied to the dental prosthesis three-point bending resistance intensity still with higher that dental zirconium oxide ceramics obtain, and illustrates the present invention
The screening color liquid being prepared will not influence the service performance of dental zirconium oxide ceramics in use.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with other
The difference of embodiment, the same or similar parts in each embodiment may refer to each other.For device disclosed in embodiment
For, since it is corresponded to the methods disclosed in the examples, so being described relatively simple, related place is said referring to method part
It is bright.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (9)
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