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CN109056379A - A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology - Google Patents

A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology Download PDF

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Publication number
CN109056379A
CN109056379A CN201810883590.5A CN201810883590A CN109056379A CN 109056379 A CN109056379 A CN 109056379A CN 201810883590 A CN201810883590 A CN 201810883590A CN 109056379 A CN109056379 A CN 109056379A
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CN
China
Prior art keywords
thickener
printing
fabric
pretreatment
wool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810883590.5A
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Chinese (zh)
Inventor
查小刚
李玉梅
肖建波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU LIANHONG TEXTILE CO Ltd
Original Assignee
JIANGSU LIANHONG TEXTILE CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU LIANHONG TEXTILE CO Ltd filed Critical JIANGSU LIANHONG TEXTILE CO Ltd
Priority to CN201810883590.5A priority Critical patent/CN109056379A/en
Publication of CN109056379A publication Critical patent/CN109056379A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491(Thio)urea or (cyclic) derivatives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/14Wool
    • D06P3/148Wool using reactive dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of wool fabric reactive dye digit printing pretreatment slurries, raw material including following specific gravity: sodium alginate thickener 1.5 ~ 2%, RS-001 thickener 0.2 ~ 0.5%, urea 12 ~ 15%, anhydrous sodium sulphate 1 ~ 3%, sodium bicarbonate, 0.5 ~ 1.5%, penetrant JFC-2 0.5 ~ 1.5% and deionized water 78 ~ 80%, by allotment pretreatment fluid, starching, digital ink-jet printed, decatize and washing, the stamp of wool fabric is completed.By the above-mentioned means, wool fabric reactive dye digit printing pretreatment slurry of the present invention and printing technology, compound in thickener and contain converted starch, it is good at paste rheological characteristic, it is small to lag thixotropy, is more suitable for printing fine decorative pattern, and thickener readily washes off, fabric feeling is influenced smaller, the wool PRINTED FABRIC tinctorial yield printed out is higher, and decorative pattern profile entirety clarity is higher, and de- paste is functional, fabric feeling is influenced smaller, it is ensured that the feel of wool fabric script.

Description

A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology
Technical field
The present invention relates to Size Technology fields, pre-process and starch more particularly to a kind of wool fabric reactive dye digit printing Material and printing technology.
Background technique
Since 21st century, digital printing technology is very rapid in China's development, in cotton, silk, synthetic fibers It is used widely on equal fabrics, but wool printing textile is comparatively rare.According to data, wool stamp in recent years The yield of textile is about annual 100 myriametre, only accounts for stamp wool textile total amount 10% or so.This is primarily due to traditional wool The printing technology process complexity of textile is cumbersome, the higher cost in small lot production, it is difficult to adapt to adding for high-grade clothing fabric Work, additionally due to wool surface, there is special Microstructure of epidermal scale, dyestuff is relatively difficult to dye.
It is ink-jet printed have the characteristics that stamp precision it is high, it is environmentally protective, can small lot multi items flexibly produce, be wool etc. High added value printing textile brings good opportunity to develop.
Energy is concentrated on mentioning for ink-jet decorating machine print speed by many people of research in terms of ink-jet printed at present It rises, in terms of the development of ink-jet printed special-purpose ink and the research and development of ink-jet printed color separation software.It required is used to ink-jet printed The research report of thickener and process aspect is more rare.In the ink-jet printed production process of reactive dye, different pastes is used Expect the pretreatment fluid prepared will directly affect apparent the color depth of pattern, decorative pattern contour sharpness, osmotic effect, color is uniform The printing qualities indexs such as degree.It therefore, is also a vital step in digit printing production to the pretreatment link of fabric.
Compared to the fabrics such as cotton, silk, synthetic fibers are played, wool fabric surface is more coarse, and ink is not easy in fabric surface It sprawls, and fiber surface has special Microstructure of epidermal scale, dyestuff is relatively difficult to dye, therefore shallower through printing fabric color.By Relatively thick in wool fabric, print penetration is poor, and the printing textiles such as scarf are difficult to reach when higher for tonicity requirements To requirement.
Starching mode, which is generally divided into pad, should be noted wool fabric when scraping slurry according to sieve starching with sieve starching The subtle villus in surface is docile, otherwise easily occurs the problems such as staining when ink-jet printed.As it can be seen that the used slurry pair in starching There is extremely important influence in the printing effect of wool PRINTED FABRIC.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of wool fabric reactive dye digit printing pretreatment slurries And printing technology promotes decorative pattern profile entirety clarity and de- paste performance, it is ensured that knit so that wool PRINTED FABRIC tinctorial yield is higher Object feel.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of wool fabric activity dye is provided Expect digit printing pretreatment slurry and printing technology, the raw material including following specific gravity:
Sodium alginate thickener 1.5 ~ 2%
RS-001 thickener 0.2 ~ 0.5%
Urea 12 ~ 15%
Anhydrous sodium sulphate 1 ~ 3%
Sodium bicarbonate 0.5 ~ 1.5%
Penetrant JFC-2 0.5 ~ 1.5%
Deionized water 78 ~ 80%.
In a preferred embodiment of the present invention, the specific gravity of each raw material are as follows:
Sodium alginate thickener 1.8%
RS-001 thickener 0.4%
Urea 14%
Anhydrous sodium sulphate 2%
Sodium bicarbonate 1%
Penetrant JFC-2 1%
Deionized water 79.8%.
In order to solve the above technical problems, another technical solution used in the present invention is: a kind of printing technology is provided, including Following steps:
(1) pretreatment fluid is deployed, is sufficiently stirred to obtain uniform pretreatment slurries, wherein the specific method of configuration pretreatment slurries Are as follows:
A. plus water: required deionized water being added in beater tub;
B. plus anhydrous sodium sulphate: under deionized water stirring, anhydrous sodium sulphate being added into beater tub, forms mixed solution;
Plus urea c.: when in solution to be mixed without insoluble matter, load weighted urea is added in the swirl center slowly formed to stirring, Continue to stir;
D. plus thickener: sodium alginate thickener and RS-001 thickener being added under stirring, continues to stir;
E. plus remaining auxiliary agent: after mixing evenly to thickener, sodium bicarbonate and penetrant JFC-2 is added, stirs evenly;
F. it stands: in slurry to be pre-treated after grainless substance, to sodium alginate thickener extruding, making each within inactive slurry eight hours Component is uniformly mixed;
(2) starching: technique initialization is an immersing and rolling, pressure 3KG, and liquid carrying rate 80% ~ 100% is dried completely after textile sizing, It can inkjet printing;
(3) digital ink-jet printed: during number printing, keeping room temperature is 20 ~ 25 DEG C;
(4) decatize: after steamer is preheated half an hour, fabric steams 30 minutes under 102 DEG C of saturated vapors;
(5) wash: cold water is impregnated with, then hot water wash twice 10min, and soap 1min, and warm water cleans 5min, last drying and shaping.
It in a preferred embodiment of the present invention,, need to be by the fabric after starching if printing not in time in the slashing step It is sealed under dry room temperature.
In a preferred embodiment of the present invention, in the digital ink-jet printed step, keeping indoor humidity is 45 ~ 50%.
In a preferred embodiment of the present invention, in the water-washing step, the water temperature of hot water wash twice is 70 ~ 80 DEG C, soap The temperature washed is 100 DEG C, and 2 ~ 8g/L soaping agent is contained in solution of soaping, and the water temperature of warm water cleaning is 30 ~ 50 DEG C.
The beneficial effects of the present invention are: a kind of wool fabric reactive dye digit printing pretreatment slurry that the present invention points out And printing technology, it compounds in thickener and contains converted starch, good at paste rheological characteristic, lag thixotropy is small, is more suitable for printing fine flower Line, and thickener readily washes off, smaller on fabric feeling influence, the wool PRINTED FABRIC tinctorial yield printed out is higher, decorative pattern wheel Wide entirety clarity is higher, and de- paste is functional, influences on fabric feeling smaller, it is ensured that the feel of wool fabric script.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The embodiment of the present invention includes:
A kind of technique carrying out wool fabric stamp using wool fabric reactive dye digit printing pretreatment slurry, including it is following Step:
(1) pretreatment fluid is deployed, is sufficiently stirred to obtain uniform pretreatment slurries, wherein the specific method of configuration pretreatment slurries Are as follows:
A. plus water: the deionized water of 79.8kg being added in beater tub;
B. plus anhydrous sodium sulphate: under deionized water stirring, 2kg anhydrous sodium sulphate being added into beater tub, forms mixed solution;
Plus urea c.: when in solution to be mixed without insoluble matter, 14kg urea is added in the swirl center slowly formed to stirring, is continued Stirring;
D. plus thickener: 1.8kg sodium alginate thickener and 0.4kgRS-001 thickener being added under stirring, continues to stir;
E. plus remaining auxiliary agent: after mixing evenly to thickener, 1kg sodium bicarbonate and 1kg penetrant JFC-2 is added, stirs evenly;
F. it stands: in slurry to be pre-treated after grainless substance, to sodium alginate thickener extruding, making each within inactive slurry eight hours Component is uniformly mixed;
(2) starching: technique initialization is an immersing and rolling, pressure 3KG, and liquid carrying rate 80% ~ 100% is dried completely after textile sizing, Can inkjet printing the fabric after starching need to be sealed under dry room temperature if printing not in time;
(3) digital ink-jet printed: number printing during, keep room temperature be 20 ~ 25 DEG C, keep indoor humidity be 45 ~ 50%;
(4) decatize: after steamer is preheated half an hour, fabric steams 30 minutes under 102 DEG C of saturated vapors;
(5) wash: cold water is impregnated with, then hot water wash twice 10min, and the water temperature of hot water is 70 ~ 80 DEG C, and soap 1min, soaps molten Contain 2 ~ 8g/L soaping agent in liquid, the temperature for solution of soaping is 100 DEG C, and then warm water cleans 5min, and the water temperature of warm water is 30 ~ 50 DEG C, last drying and shaping.
Fabric is tested using following methods:
(1) apparent shade depth K/S value
In digit printing, K/S value is generally used for measuring the index of textile color depth after printing, and can intuitively reflect fabric Shade, wherein K be coloring matter absorptivity, S be testee scattered colour system number show if K/S value is bigger Printing textile color is deeper, is seen using 650 Computer color testing of Datacolor color matching instrument in D65 light source and 10 ° in this test Tetra- color color lump of PRINTED FABRIC CMYK is tested under Cha Jiao, is placed on Datacolor for sample folding multilayer is opaque On TOOLS chromatic measuring system, 5 different locations are chosen on the fabric and are tested, taking its average value is K/S value;
(2) color fastness
Reference standard " GB/T 3921-2008 textile color stability tests fastness to soaping " and " GB/T 3920- respectively 2008 textile color stabilities test colour fastness to rubbing " soap resistance to wool PRINTED FABRIC survey with colour fastness to rubbing Examination;
(3) viscosity
Interior friction can be generated between fluid molecule when the fluid is flowing, this property is known as the viscosity of fluid, is generally determined with viscosity Amount indicates the size of viscosity, and in printing in textiles, the viscosity relationship of printing effect and slurry is close.It is easily caused if viscosity is excessive Textile sizing is irregular, and imbibition easily occurs for the too low floral designs of viscosity, therefore slurry must have appropriate and relatively stable viscosity, this survey In examination, pretreatment fluid system viscosity is tested, test method are as follows: match the rotor of good suitable range, gradually by rotor It immerses in pretreatment slurry, measures viscosity number under certain revolving speed;
(4) permeability
PRINTED FABRIC permeance property refers specifically to the mill base of fabric surface to the diffusion of fibrous inside, wettability, in this survey Stamp original is measured using this index of permeability in examination and pastes permeance property, permeability can be calculated using following formula:
(5) paste rate is taken off
It takes Subtraction method to take off paste rate to PRINTED FABRIC in this experiment to test, takes a certain size fabric drying to be printed to perseverance Weight, weight is denoted as W0 at this time, fabric it is preprocessed it is ink-jet printed after drying to constant weight, weighing is denoted as W1, then after decatize, washing Drying to constant weight, is denoted as W2, is calculated later by formula:
By taking wool fabric as an example, starching pretreatment is carried out to fabric, four color tinctorial yield of wool PRINTED FABRIC respectively reaches 23.6454,22.152,15.8637,23.6454, ink-jet printed tetra- color of fabric dry fastness CMYK of wool can reach four Grade, fastness to wet rubbing can reach three-level in addition to black, and fastness to soaping can reach level Four in addition to magenta.
In conclusion a kind of wool fabric reactive dye digit printing pretreatment slurry that the present invention points out and printer Skill, compared with common slurry, the tinctorial yield after wool fabric stamp is higher, and pattern is also more clear, good hand touch.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (6)

1. a kind of wool fabric reactive dye digit printing pretreatment slurry, which is characterized in that the raw material including following specific gravity:
Sodium alginate thickener 1.5 ~ 2%
RS-001 thickener 0.2 ~ 0.5%
Urea 12 ~ 15%
Anhydrous sodium sulphate 1 ~ 3%
Sodium bicarbonate 0.5 ~ 1.5%
Penetrant JFC-2 0.5 ~ 1.5%
Deionized water 78 ~ 80%.
2. wool fabric reactive dye digit printing pretreatment slurry according to claim 1, which is characterized in that each raw material Specific gravity are as follows:
Sodium alginate thickener 1.8%
RS-001 thickener 0.4%
Urea 14%
Anhydrous sodium sulphate 2%
Sodium bicarbonate 1%
Penetrant JFC-2 1%
Deionized water 79.8%.
3. printer of the one kind based on any wool fabric reactive dye digit printing pretreatment slurry of claim 1 ~ 2 Skill, which comprises the following steps:
(1) pretreatment fluid is deployed, is sufficiently stirred to obtain uniform pretreatment slurries, wherein the specific method of configuration pretreatment slurries Are as follows:
A. plus water: required deionized water being added in beater tub;
B. plus anhydrous sodium sulphate: under deionized water stirring, anhydrous sodium sulphate being added into beater tub, forms mixed solution;
Plus urea c.: when in solution to be mixed without insoluble matter, load weighted urea is added in the swirl center slowly formed to stirring, Continue to stir;
D. plus thickener: sodium alginate thickener and RS-001 thickener being added under stirring, continues to stir;
E. plus remaining auxiliary agent: after mixing evenly to thickener, sodium bicarbonate and penetrant JFC-2 is added, stirs evenly;
F. it stands: in slurry to be pre-treated after grainless substance, to sodium alginate thickener extruding, making each within inactive slurry eight hours Component is uniformly mixed;
(2) starching: technique initialization is an immersing and rolling, pressure 3KG, and liquid carrying rate 80% ~ 100% is dried completely after textile sizing, It can inkjet printing;
(3) digital ink-jet printed: during number printing, keeping room temperature is 20 ~ 25 DEG C;
(4) decatize: after steamer is preheated half an hour, fabric steams 30 minutes under 102 DEG C of saturated vapors;
(5) wash: cold water is impregnated with, then hot water wash twice 10min, and soap 1min, and warm water cleans 5min, last drying and shaping.
4. printing technology according to claim 3, which is characterized in that in the slashing step, if printing not in time, need by Fabric after starching is sealed under dry room temperature.
5. printing technology according to claim 3, which is characterized in that in the digital ink-jet printed step, keep indoor Humidity is 45 ~ 50%.
6. printing technology according to claim 3, which is characterized in that in the water-washing step, the water temperature of hot water wash twice It is 70 ~ 80 DEG C, the temperature soaped is 100 DEG C, and 2 ~ 8g/L soaping agent is contained in solution of soaping, and the water temperature of warm water cleaning is 30 ~ 50 ℃。
CN201810883590.5A 2018-08-06 2018-08-06 A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology Pending CN109056379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810883590.5A CN109056379A (en) 2018-08-06 2018-08-06 A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology

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Application Number Priority Date Filing Date Title
CN201810883590.5A CN109056379A (en) 2018-08-06 2018-08-06 A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology

Publications (1)

Publication Number Publication Date
CN109056379A true CN109056379A (en) 2018-12-21

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Cited By (6)

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CN109853268A (en) * 2019-01-21 2019-06-07 上海菲姿服饰有限公司 A kind of processing and treating method of wool digit printing fabric
CN111519450A (en) * 2020-04-02 2020-08-11 上海法布雷新面料有限公司 Alkali-free pretreatment slurry for wet transfer printing of wool fabric and printing process
CN111607989A (en) * 2020-05-27 2020-09-01 山东黄河三角洲纺织科技研究院有限公司 Digital printing method for textile in wet state
CN112111983A (en) * 2020-08-26 2020-12-22 浙江真爱毯业科技有限公司 Preparation method of digital printing blanket
CN113774695A (en) * 2021-10-08 2021-12-10 绍兴柯桥利冠数码印花科技有限公司 Environment-friendly digital printing process
CN114016314A (en) * 2021-11-22 2022-02-08 天泓环境科技有限责任公司 Digital printing process for wool fabric

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109853268A (en) * 2019-01-21 2019-06-07 上海菲姿服饰有限公司 A kind of processing and treating method of wool digit printing fabric
CN111519450A (en) * 2020-04-02 2020-08-11 上海法布雷新面料有限公司 Alkali-free pretreatment slurry for wet transfer printing of wool fabric and printing process
CN111607989A (en) * 2020-05-27 2020-09-01 山东黄河三角洲纺织科技研究院有限公司 Digital printing method for textile in wet state
CN112111983A (en) * 2020-08-26 2020-12-22 浙江真爱毯业科技有限公司 Preparation method of digital printing blanket
CN113774695A (en) * 2021-10-08 2021-12-10 绍兴柯桥利冠数码印花科技有限公司 Environment-friendly digital printing process
CN114016314A (en) * 2021-11-22 2022-02-08 天泓环境科技有限责任公司 Digital printing process for wool fabric

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