CN109024041A - A kind of dewatering of pulp auxiliary agent - Google Patents
A kind of dewatering of pulp auxiliary agent Download PDFInfo
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- CN109024041A CN109024041A CN201810879296.7A CN201810879296A CN109024041A CN 109024041 A CN109024041 A CN 109024041A CN 201810879296 A CN201810879296 A CN 201810879296A CN 109024041 A CN109024041 A CN 109024041A
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- auxiliary agent
- pulp
- dewatering
- peach gum
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-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/18—De-watering; Elimination of cooking or pulp-treating liquors from the pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
Abstract
The present invention discloses a kind of dewatering of pulp auxiliary agent, raw material including following parts by weight proportion: 77-96 parts of atlapulgite, 3-7 parts of acrylyl oxy-ethyl-trimethyl salmiac, 40-62 parts of sepiolite fibre, 35-50 parts of peach gum, 11-14 parts of four acicular type zinc oxide crystal whisker, 10-20 parts of titanium dioxide, 22-24 parts of pollen pini, 2-6 parts of Gluten, 7-10 parts of oxidized starch, 30-40 parts of crystalline aluminosilicate compound, 20-23 parts of sodium carboxymethyl starch, 10-13v parts of microcrystalline cellulose, 3-7 parts and nanometer calcium carbonate 10-12 parts of water-based zinc stearate, the negative effect caused by the papery of manufactured paper is less even if component residue is in paper pulp for the dewatering of pulp auxiliary agent.
Description
Technical field
The present invention relates to a kind of dewatering of pulp auxiliary agents.
Background technique
Paper pulp is using plant fiber as raw material, through fibrous material made from different processing methods.It can be according to processing method
It is divided into mechanical pulp, chemical pulp and chemimechanical pulp;Wood pulp, straw pulp, jute pulp, reed can also be divided into according to fibrous raw material used
Slurry, sugarcane slurry, bamboo pulp, rag stock etc..Refined pulp, bleached pulp, unbleached pulp, high yield pulp1 can be divided into according to different purity again
Paper pulp, semi-chemical pulp etc..Generally it is chiefly used in manufacturing paper and cardboard.Refined pulp is except for also usually making in addition to manufacturing speciality paper
For the raw material of the cellulose derivatives such as manufacture cellulose esters, cellulose ether.Dehydrating agent can reduce moisture or removing in material
The crystallization water in compound molecule.Dehydrating agent can be divided into medicine or nursing class often uses dehydrating agent and industrial dehydrating agent.Industrially have
Many chemical synthesis dehydrating agents, including paper industry.
However when using desiccant to dewatering of pulp, physical dryness agent tends to residual in paper pulp with paper pulp frictional impact
There are the ingredients of desiccant, so that papery is easy by large effect.
Summary of the invention
The technical problem to be solved in the present invention is to provide one kind component residue is in paper pulp to manufactured paper
Less dewatering of pulp auxiliary agent is negatively affected caused by papery.
To solve the above problems, the present invention adopts the following technical scheme:
A kind of dewatering of pulp auxiliary agent, the raw material including following parts by weight proportion: 77-96 parts of atlapulgite, acrylyl oxy-ethyl
3-7 parts of trimethyl ammonium chloride, 40-62 parts of sepiolite fibre, 35-50 parts of peach gum, 11-14 parts of four acicular type zinc oxide crystal whisker, dioxy
Change titanium 10-20 parts, 22-24 parts of pollen pini, 2-6 parts of Gluten, 7-10 parts of oxidized starch, crystalline aluminosilicate compound 30-
40 parts, 20-23 parts of sodium carboxymethyl starch, 10-13 parts of microcrystalline cellulose, 3-7 parts of water-based zinc stearate and nanometer calcium carbonate 10-12
Part.
Further, the raw material including following parts by weight proportion: 77 parts of atlapulgite, acrylyl oxy-ethyl-trimethyl chlorine
Change 3 parts of ammonium, 40 parts of sepiolite fibre, 35 parts of peach gum, 11 parts of four acicular type zinc oxide crystal whisker, 10 parts of titanium dioxide, 22 parts of pollen pini,
2 parts of Gluten, 7 parts of oxidized starch, 30 parts of crystalline aluminosilicate compound, 20 parts of sodium carboxymethyl starch, microcrystalline cellulose 10
Part, 3 parts of water-based zinc stearate and 10 parts of nanometer calcium carbonate.
Further, the raw material including following parts by weight proportion: 96 parts of atlapulgite, acrylyl oxy-ethyl-trimethyl chlorine
Change 7 parts of ammonium, 62 parts of sepiolite fibre, 50 parts of peach gum, 14 parts of four acicular type zinc oxide crystal whisker, 20 parts of titanium dioxide, 24 parts of pollen pini,
6 parts of Gluten, 10 parts of oxidized starch, 40 parts of crystalline aluminosilicate compound, 23 parts of sodium carboxymethyl starch, microcrystalline cellulose 13
Part, 7 parts of water-based zinc stearate and 12 parts of nanometer calcium carbonate.
Further, the raw material including following parts by weight proportion: 85 parts of atlapulgite, acrylyl oxy-ethyl-trimethyl chlorine
Change 5 parts of ammonium, 50 parts of sepiolite fibre, 45 parts of peach gum, 13 parts of four acicular type zinc oxide crystal whisker, 15 parts of titanium dioxide, 23 parts of pollen pini,
5 parts of Gluten, 8 parts of oxidized starch, 35 parts of crystalline aluminosilicate compound, 22 parts of sodium carboxymethyl starch, microcrystalline cellulose 12
Part, 5 parts of water-based zinc stearate and 11 parts of nanometer calcium carbonate.
Another technical problem to be solved by the present invention is that providing a kind of preparation method of dewatering of pulp auxiliary agent, including following step
It is rapid:
1) 35-50 parts of peach gum are poured into pulverizer and carry out pulverization process, crushing mesh number is 325-400 mesh, and peach gum powder is made
End, it is spare;
2) by 77-96 parts of atlapulgite, 3-7 parts of acrylyl oxy-ethyl-trimethyl salmiac, 40-62 parts of sepiolite fibre, four needles
11-14 parts of shape ZnOw, 10-20 parts of titanium dioxide, 22-24 parts of pollen pini, 2-6 parts of Gluten, 7-10 parts of oxidized starch,
30-40 parts of crystalline aluminosilicate compound, 20-23 parts of sodium carboxymethyl starch, 10-13 parts of microcrystalline cellulose, aqueous stearic acid
Peach gum powder made from 3-7 parts of zinc, 10-12 parts of nanometer calcium carbonate and step 1), which is poured into together in dryer, is dried place
Reason, wherein the temperature of drying process is 35-45 DEG C, drying time 1-2h, and dried object is made, spare;
3) dried object made from step 2 is poured into together in three-dimensional motion mixer and carries out mixed processing, wherein three maintenance and operations
The speed of mainshaft of dynamic mixing machine is 10-13r/min, incorporation time 3-5h, and mixture is made;
4) mixture made from step 3) is poured into pelletizer and carries out granulation processing, wherein when being granulated processing in machine barrel
Temperature is 50-60 DEG C, and granular auxiliary agent is made.
The beneficial effects of the present invention are: not only can effectively adsorb the moisture in paper pulp, and ingredient drops into paper pulp
In it is advantageous to papermaking;Using granular structure and possess preferable intensity, addition and dosage are easy to control, it is only necessary to pour into
Into wet paper pulp, auxiliary agent is separated with paper pulp again after mixing water suction, it is easy to use.
The characteristics of being the principle of dewatering of pulp auxiliary agent below or effect:
Atlapulgite: be with clay being raw material, handles through inorganic acidifying or salt or other methods, then is made through water rinsing, drying
Adsorbent, appearance is off-white powder, and odorless, tasteless, nontoxic, absorption property is very strong, due to for off-white powder, to paper pulp
Color influences it is less.
Acrylyl oxy-ethyl-trimethyl salmiac: being a kind of chemicals, and molecular formula is, for producing water process flocculation
Agent, antistatic coating, paper making additive, chemicals, textile auxiliary agent etc. are finely from molecule product.
Sepiolite fibre: silicate mineral of the sepiolite as a kind of layer of chain, in structure among two layers of oxygen-octahedron
One layer of magnesia octahedron is pressed from both sides, the layered structure unit of 2: 1 types is formed.Its tetrahedral layer is continuous, the direction of active oxygen in layer
Periodically reverse.Octahedral layer forms the spaced channel of upper and lower level.The orientation in channel is consistent with fiber axis, allows
Hydrone, metal cation, small organic molecule etc. enter wherein it is possible to play outstanding water sorption, while as reinforcing agent,
Whole intensity can be promoted, product can be prevented because water swelling is the case where leading to be easy to appear abrasion and fall off, and
Due to its Filamentous fibre structure, drop into also less on the influence of the papery for the paper made in paper pulp.
Peach gum: being peach naturally secret, and can absorb water the hair that rises, and can play the role of water suction, while using again as binder.
Four acicular type zinc oxide crystal whisker: its three-dimensional crystalline structure dispersion plays skeleton function, unique three-dimensional space in the base
Between structure keep it bigger with the gripping power of matrix, reinforcing effect is more significant, obviously increases tensile strength, and horizontal and vertical
Tensile strength numerical value is essentially identical, isotropically reinforces the mechanical performance of basis material, improves matrix strength significantly and adds
Work performance.Intensity can effectively be promoted by compounding with sepiolite fibre, prevent product from leading to be easy to appear mill because of water swelling
The case where damaging and falling off mixes with paper pulp and can be promoted the mechanical property of paper pulp since it is with outstanding reinforcing effect, right
The negative effect that paper pulp is made into is few.
Titanium dioxide: the amphoteric oxide of white powder has hydrophily and hygroscopicity, and titanium dioxide is that the world is more white
Thing, especially bleached paper less to the Color influences of paper.
Pollen pini: pollen pini not has very strong water imbibition, non-stimulated to skin, and undesirable shadow will not be caused to human body
It rings.
Gluten: being the native protein extracted from wheat, water imbibition, liposuction and good mechanical performance,
Glutenin molecule is threadiness, and molecular weight is larger, has elasticity, but extensibility is small, crude, at the same in paper pulp
Plant is similar, and biggish side effect will not be generated ingredient drops into paper pulp.
Oxidized starch: make a kind of converted starch obtained from starch oxidation.Product colour is pure white, be widely used in weaving,
Papermaking, food and Fine Chemical.In paper industry, be used as Cypres, coating binder, wet end additive, watt
Corrugated paper board adhesive.Starch water swelling can play good drying effect to paper pulp, and dropping into paper pulp can be with
Play preferable beneficial effect.
Crystalline aluminosilicate compound: having regular and uniform duct in its crystal structure, rate of moisture absorption is exceedingly fast, in pole
A large amount of moisture content are absorbed in the short time.
Sodium carboxymethyl starch: white powder is added in filler and is used as stabilizer, thickening cementation is played, with peach gum, sea
Afrodite fiber and four acicular type zinc oxide crystal whisker compounding, can effectively promote whole stability, and dropping into paper pulp can
So that paper gloss is bright-coloured, improve the printing performance of paper, enhances the toughness and wearability of paper.
Microcrystalline cellulose: being the cellulose of a kind of purifying, part depolymerization, white, odorless, tasteless, by small porous particle group
At crystalline powder can play the role of absorbing moisture since it is with porous structure.Simultaneously microcrystalline cellulose molecule it
Between there are hydrogen bond, hydrogen bond association when compression, therefore the compressibility with height, be often used as can be improved particle in binder
Hardness.The heat resistance for improving oxidized starch, to promote yield rate.
Water-based zinc stearate: it has wide range of applications, and can be used as release agent, color preserving agent, lubricant, interleaving agent etc., can be with
Reduce the friction between auxiliary agent finished product and paper pulp.
Nanometer calcium carbonate: it is good with resin compatible, it can effectively improve or adjust the rigid of product, toughness, finish and curved
Qu Qiangdu;Improve processing performance, improve product rheological property, dimensional stability, heat-resistant stability have filling and enhancing,
The effect of toughening.Also there is excellent ink absorption and high drying property, can ink is preferably attached in paper pulp
On plant fiber, beneficial effect is caused to paper.
Specific embodiment
Technical solution of the present invention is described below, it is clear that described embodiment is only present invention a part
Embodiment, instead of all the embodiments, to those skilled in the art, in the premise not made the creative labor
Under, other embodiments can also be obtained according to these embodiments.
Embodiment 1:
A kind of dewatering of pulp auxiliary agent, the raw material including following parts by weight proportion: 77 parts of atlapulgite, acrylyl oxy-ethyl front three
3 parts of ammonium chloride, 40 parts of sepiolite fibre, 35 parts of peach gum, 11 parts of four acicular type zinc oxide crystal whisker, 10 parts of titanium dioxide, pollen pini
22 parts, 2 parts of Gluten, 7 parts of oxidized starch, 30 parts of crystalline aluminosilicate compound, 20 parts of sodium carboxymethyl starch, microcrystalline cellulose
10 parts of element, 3 parts of water-based zinc stearate and 10 parts of nanometer calcium carbonate.
A kind of preparation method of dewatering of pulp auxiliary agent the following steps are included:
1) 35 parts of peach gum are poured into pulverizer and carry out pulverization process, crushing mesh number is 325 mesh, and peach gum powder is made, spare;
2) by 77 parts of atlapulgite, 3 parts of acrylyl oxy-ethyl-trimethyl salmiac, 40 parts of sepiolite fibre, four-needle-like zinc oxide
11 parts of whisker, 10 parts of titanium dioxide, 22 parts of pollen pini, 2 parts of Gluten, 7 parts of oxidized starch, crystalline aluminosilicate compound 30
Part, 20 parts of sodium carboxymethyl starch, 10 parts of microcrystalline cellulose, 3 parts of water-based zinc stearate, 10 parts of nanometer calcium carbonate and step 1) are made
Peach gum powder be poured into dryer be dried together, wherein the temperature of drying process is 35 DEG C, and drying time is
Dried object is made in 1h, spare;
3) dried object made from step 2 is poured into together in three-dimensional motion mixer and carries out mixed processing, wherein three maintenance and operations
The speed of mainshaft of dynamic mixing machine is 10r/min, incorporation time 3h, and mixture is made;
4) mixture made from step 3) is poured into pelletizer and carries out granulation processing, wherein when being granulated processing in machine barrel
Temperature is 50 DEG C, and granular auxiliary agent is made.
In the present embodiment, the granulation partial size of auxiliary agent is 1cm.
Embodiment 2:
A kind of dewatering of pulp auxiliary agent, the raw material including following parts by weight proportion: 96 parts of atlapulgite, acrylyl oxy-ethyl front three
7 parts of ammonium chloride, 62 parts of sepiolite fibre, 50 parts of peach gum, 14 parts of four acicular type zinc oxide crystal whisker, 20 parts of titanium dioxide, pollen pini
24 parts, 6 parts of Gluten, 10 parts of oxidized starch, 40 parts of crystalline aluminosilicate compound, 23 parts of sodium carboxymethyl starch, crystallite fibre
13 parts of dimension element, 7 parts of water-based zinc stearate and 12 parts of nanometer calcium carbonate.
A kind of preparation method of dewatering of pulp auxiliary agent, comprising the following steps:
1) 50 parts of peach gum are poured into pulverizer and carry out pulverization process, crushing mesh number is 400 mesh, and peach gum powder is made, spare;
2) by 96 parts of atlapulgite, 7 parts of acrylyl oxy-ethyl-trimethyl salmiac, 62 parts of sepiolite fibre, four-needle-like zinc oxide
14 parts of whisker, 20 parts of titanium dioxide, 24 parts of pollen pini, 6 parts of Gluten, 10 parts of oxidized starch, crystalline aluminosilicate compound
40 parts, 23 parts of sodium carboxymethyl starch, 13 parts of microcrystalline cellulose, 7 parts of water-based zinc stearate, 12 parts of nanometer calcium carbonate and step 1) system
The peach gum powder obtained is poured into dryer together to be dried, wherein the temperature of drying process is 45 DEG C, drying time
For 2h, dried object is made, it is spare;
3) dried object made from step 2 is poured into together in three-dimensional motion mixer and carries out mixed processing, wherein three maintenance and operations
The speed of mainshaft of dynamic mixing machine is 13r/min, incorporation time 5h, and mixture is made;
4) mixture made from step 3) is poured into pelletizer and carries out granulation processing, wherein when being granulated processing in machine barrel
Temperature is 60 DEG C, and granular auxiliary agent is made.
In the present embodiment, the granulation partial size of auxiliary agent is 0.8cm.
Embodiment 3:
A kind of dewatering of pulp auxiliary agent, the raw material including following parts by weight proportion: 85 parts of atlapulgite, acrylyl oxy-ethyl front three
5 parts of ammonium chloride, 50 parts of sepiolite fibre, 45 parts of peach gum, 13 parts of four acicular type zinc oxide crystal whisker, 15 parts of titanium dioxide, pollen pini
23 parts, 5 parts of Gluten, 8 parts of oxidized starch, 35 parts of crystalline aluminosilicate compound, 22 parts of sodium carboxymethyl starch, microcrystalline cellulose
12 parts of element, 5 parts of water-based zinc stearate and 11 parts of nanometer calcium carbonate.
A kind of preparation method of dewatering of pulp auxiliary agent, comprising the following steps:
1) 45 parts of peach gum are poured into pulverizer and carry out pulverization process, crushing mesh number is 400 mesh, and peach gum powder is made, spare;
2) by 85 parts of atlapulgite, 5 parts of acrylyl oxy-ethyl-trimethyl salmiac, 50 parts of sepiolite fibre, four-needle-like zinc oxide
13 parts of whisker, 15 parts of titanium dioxide, 23 parts of pollen pini, 5 parts of Gluten, 8 parts of oxidized starch, crystalline aluminosilicate compound 35
Part, 22 parts of sodium carboxymethyl starch, 12 parts of microcrystalline cellulose, 5 parts of water-based zinc stearate, 11 parts of nanometer calcium carbonate and step 1) are made
Peach gum powder be poured into dryer be dried together, wherein the temperature of drying process is 40 DEG C, and drying time is
Dried object is made in 1.5h, spare;
3) dried object made from step 2 is poured into together in three-dimensional motion mixer and carries out mixed processing, wherein three maintenance and operations
The speed of mainshaft of dynamic mixing machine is 12r/min, incorporation time 4h, and mixture is made;
4) mixture made from step 3) is poured into pelletizer and carries out granulation processing, wherein when being granulated processing in machine barrel
Temperature is 55 DEG C, and granular auxiliary agent is made.
In the present embodiment, the granulation partial size of auxiliary agent is 0.5cm.
The beneficial effects of the present invention are: not only can effectively adsorb the moisture in paper pulp, and ingredient drops into paper pulp
In it is advantageous to papermaking;Using granular structure and possess preferable intensity, addition and dosage are easy to control, it is only necessary to pour into
Into wet paper pulp, auxiliary agent is separated with paper pulp again after mixing water suction, it is easy to use.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of dewatering of pulp auxiliary agent, which is characterized in that the raw material including following parts by weight proportion: 77-96 parts of atlapulgite,
3-7 parts of acrylyl oxy-ethyl-trimethyl salmiac, 40-62 parts of sepiolite fibre, 35-50 parts of peach gum, four acicular type zinc oxide crystal whisker
11-14 parts, 10-20 parts of titanium dioxide, 22-24 parts of pollen pini, 2-6 parts of Gluten, 7-10 parts of oxidized starch, crystal type manosil AS
30-40 parts of salt compound, 20-23 parts of sodium carboxymethyl starch, 10-13 parts of microcrystalline cellulose, 3-7 parts of water-based zinc stearate and nanometer
10-12 parts of calcium carbonate.
2. a kind of dewatering of pulp auxiliary agent as described in claim 1, which is characterized in that the original including following parts by weight proportion
Material: 77 parts of atlapulgite, 3 parts of acrylyl oxy-ethyl-trimethyl salmiac, 40 parts of sepiolite fibre, 35 parts of peach gum, four needle-shaped oxygen
Change 11 parts of zinc whisker, 10 parts of titanium dioxide, 22 parts of pollen pini, 2 parts of Gluten, 7 parts of oxidized starch, crystalline aluminosilicate chemical combination
30 parts of object, 20 parts of sodium carboxymethyl starch, 10 parts of microcrystalline cellulose, 3 parts of water-based zinc stearate and 10 parts of nanometer calcium carbonate.
3. a kind of dewatering of pulp auxiliary agent as described in claim 1, which is characterized in that the original including following parts by weight proportion
Material: 96 parts of atlapulgite, 7 parts of acrylyl oxy-ethyl-trimethyl salmiac, 62 parts of sepiolite fibre, 50 parts of peach gum, four needle-shaped oxygen
Change 14 parts of zinc whisker, 20 parts of titanium dioxide, 24 parts of pollen pini, 6 parts of Gluten, 10 parts of oxidized starch, crystalline aluminosilicate
40 parts of object of conjunction, 23 parts of sodium carboxymethyl starch, 13 parts of microcrystalline cellulose, 7 parts of water-based zinc stearate and 12 parts of nanometer calcium carbonate.
4. a kind of dewatering of pulp auxiliary agent as described in claim 1, which is characterized in that the original including following parts by weight proportion
Material: 85 parts of atlapulgite, 5 parts of acrylyl oxy-ethyl-trimethyl salmiac, 50 parts of sepiolite fibre, 45 parts of peach gum, four needle-shaped oxygen
Change 13 parts of zinc whisker, 15 parts of titanium dioxide, 23 parts of pollen pini, 5 parts of Gluten, 8 parts of oxidized starch, crystalline aluminosilicate chemical combination
35 parts of object, 22 parts of sodium carboxymethyl starch, 12 parts of microcrystalline cellulose, 5 parts of water-based zinc stearate and 11 parts of nanometer calcium carbonate.
5. a kind of preparation method of dewatering of pulp auxiliary agent, which comprises the following steps:
1) 35-50 parts of peach gum are poured into pulverizer and carry out pulverization process, crushing mesh number is 325-400 mesh, and peach gum powder is made
End, it is spare;
2) by 77-96 parts of atlapulgite, 3-7 parts of acrylyl oxy-ethyl-trimethyl salmiac, 40-62 parts of sepiolite fibre, four needles
11-14 parts of shape ZnOw, 10-20 parts of titanium dioxide, 22-24 parts of pollen pini, 2-6 parts of Gluten, 7-10 parts of oxidized starch,
30-40 parts of crystalline aluminosilicate compound, 20-23 parts of sodium carboxymethyl starch, 10-13 parts of microcrystalline cellulose, aqueous stearic acid
Peach gum powder made from 3-7 parts of zinc, 10-12 parts of nanometer calcium carbonate and step 1), which is poured into together in dryer, is dried place
Reason, wherein the temperature of drying process is 35-45 DEG C, drying time 1-2h, and dried object is made, spare;
3) dried object made from step 2 is poured into together in three-dimensional motion mixer and carries out mixed processing, wherein three maintenance and operations
The speed of mainshaft of dynamic mixing machine is 10-13r/min, incorporation time 3-5h, and mixture is made;
4) mixture made from step 3) is poured into pelletizer and carries out granulation processing, wherein when being granulated processing in machine barrel
Temperature is 50-60 DEG C, and granular auxiliary agent is made.
Priority Applications (1)
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CN201810879296.7A CN109024041A (en) | 2018-08-03 | 2018-08-03 | A kind of dewatering of pulp auxiliary agent |
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CN201810879296.7A CN109024041A (en) | 2018-08-03 | 2018-08-03 | A kind of dewatering of pulp auxiliary agent |
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CN101133212A (en) * | 2004-12-29 | 2008-02-27 | 赫尔克里士公司 | Improved retention and drainage in the manufacture of paper |
CN105358765A (en) * | 2013-07-10 | 2016-02-24 | 艺康美国股份有限公司 | Enhancement of sheet dewatering using soy flour or soy protein |
CN105714601A (en) * | 2016-04-27 | 2016-06-29 | 商孝霞 | Papermaking auxiliary agent composition |
CN107254802A (en) * | 2017-06-07 | 2017-10-17 | 常州彤骉贸易有限公司 | A kind of retention aid for paper making |
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US5779859A (en) * | 1996-12-13 | 1998-07-14 | J.M. Huber Corporation | Method of improving filler retention in papermaking |
CN1576460A (en) * | 2003-05-05 | 2005-02-09 | 格尔曼·韦尔加拉·洛佩斯 | Retention and water filtration system for making paper, paperboard, cardboard and the like |
CN101133212A (en) * | 2004-12-29 | 2008-02-27 | 赫尔克里士公司 | Improved retention and drainage in the manufacture of paper |
CN105358765A (en) * | 2013-07-10 | 2016-02-24 | 艺康美国股份有限公司 | Enhancement of sheet dewatering using soy flour or soy protein |
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Application publication date: 20181218 |