CN108978264A - A kind of vegetation dye formula and its colouring method - Google Patents
A kind of vegetation dye formula and its colouring method Download PDFInfo
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- CN108978264A CN108978264A CN201810912821.0A CN201810912821A CN108978264A CN 108978264 A CN108978264 A CN 108978264A CN 201810912821 A CN201810912821 A CN 201810912821A CN 108978264 A CN108978264 A CN 108978264A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
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Abstract
A kind of vegetation dye formula and its colouring method, the invention belongs to dye production technical field, including vegetable dye and mordant, mordant includes one or both of chromic salts, aluminium salt, molysite, alkaline solution, mantoquita and tannic acid.Mordant and vegetable dye cooperation are dyed.Vegetable colour is boiled by cold water soak plant, then by plant boiling, and boiling is cooled to dyeing temperature after boiling and is prepared.Vegetation dye formula is single to cloth dyeing colour developing, and colour fixation is significant.
Description
Technical field
The invention belongs to dye production technical field, formula and its colouring method are contaminated in particular to a kind of vegetation.
Background technique
Vegetation dye is that natural pigment is extracted from vegetation, then uses it to a kind of technique dyed, Zao Shang
All people have just grasped the relevant technologies.For modern times dyeing and finishing industry serious for pollution, vegetation dye health, environmental protection,
Environmental pollution is small, is conducive to the balance and sound development of ecology.
However traditional vegetation dye has largely exited business stage, has faded out people's under the impact of present chemistry dye
Sight.It is on the one hand that vegetation dying-stable performance is poor, chemical dye is far not achieved in colour fixation to find out its cause, mainly there is two aspects
Material.Second is that vegetation dye raw material sources can not be stablized, many Materials Plant costs are prohibitively expensive, the safflower such as incarnadined, contaminate purple purple
Grass etc..Some reasons Just because of this, vegetation dyeing technique is although long-standing, but is but difficult to push away extensively in modern society
Extensively, although her environment-friendly and green, environmental pollution is small, but if do not solve the problems, such as it is more above-mentioned, just forever can not and the modern life
It is synchronous.
Research is dedicated to developing the stable vegetation dye of fixation, and raw material supply is stablized cheap vegetation dyeing technique, come with this
Solve the commercialized problem of current social vegetation dyeing technique.
Want solves the problems, such as more than, it is necessary to emphatically study vegetation contaminate mordant dyeing technology.Traditional vegetation dyeing technique, substantially
Using the natural mordant such as plant ash, vinegar, salt and alum, or mordant is not used, this is also to cause color stability difference
Reason, therefore, to solve the problems, such as fixation, it is necessary to start with from mordant dyeing technology.
Summary of the invention
One of the objects of the present invention is to provide a kind of vegetation dyes to be formulated, and having keeps colour fixation after substance stain more excellent
It is different.
The second object of the present invention is to provide a kind of vegetation dye colouring method, so that the substance color stability contaminated
Significantly.
The present invention is implemented as follows:
The embodiment provides a kind of vegetation dyes to be formulated, including vegetable dye and mordant, mordant include chromium
One or both of salt, aluminium salt, molysite, alkaline solution, mantoquita and tannic acid.
A kind of vegetation dye colouring method is dyed using the vegetation dye formula of any of the above-described.
Above scheme the utility model has the advantages that chromic salts provided in an embodiment of the present invention, aluminium salt, molysite, alkaline solution, mantoquita and
One or both of tannic acid, mordant and the obtained substance colour fixation of dyestuff cooperation dyeing are significant, and dyeing colour system is wider, full
Colorful multiplicity life in the sufficient modern life.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, rather than
Whole embodiments.Therefore, the detailed description of the embodiment of the present invention of offer is not intended to limit below claimed
The scope of the present invention, but it is merely representative of selected embodiment of the invention.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
One of the objects of the present invention is to provide a kind of vegetation dyes to be formulated, including vegetable dye and mordant, mordant packet
Include one or both of chromic salts, aluminium salt, molysite, alkaline solution, mantoquita and tannic acid.
It finds during the experiment, mordant is with a kind of or 2 kinds are used together as benefit, when using more than two kinds of mordants
It is dyed, the color effect finally presented the still most colouring effect of latter two mordant, such as potassium chromium sulfate+caustic soda+
Tannic acid+alum, the effect of final mordant dyeing are still tannic acid+alum effect.
When two kinds of mordants are dyed, two kinds of mordants can be made to mixing Mordant solution soaking and dyeing, can also be incited somebody to action
Two kinds of mordants are separately successively impregnated the substance.Mixed solution is made in two kinds of mordants, can save soaking time, but hold
It is also easy to produce precipitating, causes to waste.
Dyeing to cell and tissue, sometimes only can not be possible with dye solution dyeing.Can be used at this time makes cell, group
Knit with pigment combine drug solution go to handle, can make material dye, this drug solution be mordant.It also refers to that dyestuff passes through
It is contaminated in certain medium and reaches the substance used of dyeing purpose, mainly bichromate, aluminium salt, mantoquita and cobalt in substance
Salt.
In preferred embodiments of the present invention, chromic salts include potassium chromium sulfate, chromic nitrate potassium, chromic acetate, potassium bichromate and
At least one of sodium dichromate；Preferably, chromic salts includes potassium chromium sulfate, chromic nitrate potassium, chromic acetate, potassium bichromate and dichromic acid
Sodium is one of；It is highly preferred that chromic salts selects potassium chromium sulfate；Bichromate price is more expensive, therefore preferred price in actual production
The cheap not poor potassium chromium sulfate of colour fixation simultaneously.
And/or aluminium salt is at least one of aluminum aluminum sulfate, alchlor and aluminum sulfate；Preferably, aluminium salt is aluminum sulfate
Potassium, alchlor and aluminum sulfate are one of；It is highly preferred that aluminium salt is to select aluminum aluminum sulfate；Aluminum aluminum sulfate price is more just
Preferably, it is preferable to use aluminum aluminum sulfate.It should be noted that optional weakly acidic solution, which is used as, helps matchmaker when aluminum aluminum sulfate is as mordant
Stain helps mordant that oxalic acid, hydrochloric acid, sulfuric acid, formic acid, lactic acid can be selected one such, it is preferable that selects oxalic acid.
And/or molysite is at least one of ferrous sulfate, frerrous chloride and ferrous acetate；Preferably, molysite is sulfuric acid
Ferrous, frerrous chloride and ferrous acetate are one of；It is highly preferred that molysite selects ferrous sulfate；Ferrous salt color is shallower, and three
Valence molysite then obtains the deeper color of color as mordant, preferentially uses ferrous salt in the embodiment of the present invention, uses molysite
Also within the scope of the present invention.
And/or alkaline solution is at least one of sodium hydroxide, potassium hydroxide and ammonium hydroxide；Preferably, alkaline solution is
Sodium hydroxide, potassium hydroxide and ammonium hydroxide are one of；It is highly preferred that alkaline solution selects sodium hydroxide；Alkaline solution can also
To be substituted with edible salting liquid, it is the solution of alkalinity that solution ph is preferentially selected in some embodiments of the present invention, it is contemplated that valence
Lattice and the factors such as easy to operate are, it is preferable to use sodium hydroxide solution.
And/or mantoquita is at least one of copper sulphate, basic copper sulfate and copper nitrate；Preferably, mantoquita is sulfuric acid
Copper, basic copper sulfate and copper nitrate are one of；It is highly preferred that mantoquita selects copper sulphate.
In preferred embodiments of the present invention, the weight of mordant for its contaminated substance weight 1-10%, it is preferable that
Mordant for its contaminated substance weight 2-7%.Mordant account for substance weight percentage that it is contaminated it is too small if then dye effect
Fruit is unobvious, and colour fixation is also unstable, if to account for the substance weight percentage that it is contaminated too big for mordant, wastes mordant dyeing
Agent, when mordant concentration reaches a timing, specific gravity is excessively high can not to be obviously improved colour fixation, and economic benefit reduces.Therefore compared with
It is in 2-7% that range mordant weight, which is contaminated substance weight by it, in good embodiment.
It should be noted that in some embodiments of the invention, the weight of mordant accounts for its contaminated substance weight percentage
Number can be 1-200%, it might even be possible to reach 650%.Such as in some embodiments of the invention, sodium hydroxide and sulfuric acid
In the compound mordant of chromium potassium composition, the weight of sodium hydroxide can for its contaminated substance weight 650%, 400%, 200%,
150%, 100%, 50%, 10%, 7%, 6%, 5%, 4%, 3%, 2%, 1%.The weight of potassium chromium sulfate can be contaminated by it
200%, 150%, 100%, 50%, 10%, 7%, 6%, 5%, 4%, 3%, 2%, the 1% of substance weight.Sodium hydroxide is pressed
Successively decrease according to the deal of potassium chromium sulfate, colouring effect can be red to purplish grey, fixation from prune to grey violet with successively decreasing for formula
Effect is successively decreased as the quality of mordant is successively decreased.When reaching the maximum value of formulation weight, colour fixation is best.
In preferred embodiments of the present invention, the ratio between Mordant solution and its material mass contaminated are 10-30:1；Matchmaker
Stain accounts for the material mass percentage that it is contaminated and first determines, rear to determine the ratio between Mordant solution and its contaminated substance weight, such as matchmaker
The ratio between dye solution and substance weight are excessive, then it is lower to lead to fix obtained Mordant solution concentration, dyeing effect and
No doubt effect is poor, fails to meet production requirements, if the ratio between Mordant solution and substance weight are too small, leads to Mordant solution
Concentration is larger, not significant for promoting colour fixation, causes the waste of mordant instead.
Preferably, the ratio between Mordant solution and its material mass contaminated are 15-25:1.
The embodiments of the present invention also provide a kind of vegetations to contaminate formula colouring method, and the vegetation of any of the above-described is contaminated formula
It is dyed.
Colouring method uses one such with bath mordant dyeing, prechrome process and after chrome process；Preferably, it selects
Prechrome process.It is deeper that pre- mordant dyeing obtains color；Mordant dyeing can keep the cleaning of dyestuff afterwards, but it is shallower to obtain color；It is easy to make a tree, used in making timber for boats of reviving with mordant dyeing
Dye liquor generates precipitating.Used herein is pre- mordant dyeing, it is possible to use rear mordant dyeing, but rear one suboptimum of mordant dyeing mordant dyeing, so if
Using rear mordant dyeing, then the mixed solution of a kind of mordant or two kinds of mordants is preferred.
Being immersed in the time in Mordant solution in, substance in preferred embodiments of the present invention is 1-30h.
In preferred embodiments of the present invention, the colour system that mordant and dyestuff cooperate dyeing that can provide includes red colour system, purple
Colour system, yellow class, green system and black system.
In preferred embodiments of the present invention, dye material be selected from Soviet Union a tree, used in making timber for boats, madder, birchleaf pear, safflower, wild pepper, lotus leaf and
Tea is one such；Preceding cheap on the market and controllable source dye material is Soviet Union's a tree, used in making timber for boats, therefore studies the method for incarnadining using Soviet Union's a tree, used in making timber for boats,
More there are market prospects.Soviet Union's a tree, used in making timber for boats pigment is not necessarily to that color can also be dyed with mordant, but washing is easily fallen, therefore in view of fixation is imitated
Fruit, it is also necessary to use and arrive mordant.
The pigment that contains is known as a tree, used in making timber for boats element of reviving in Soviet Union's a tree, used in making timber for boats, and Soviet Union's a tree, used in making timber for boats disposition matter is more active, therefore in an experiment, Su Fang, madder,
Birchleaf pear, safflower, wild pepper and different mordants combine, and can show from light red to sauce red, from grey violet to purple black, from it is orange to
Pale brown equal colors, other than the difference in colour developing, colour fixation is also different, however can color firmness of the strong mistake without mordant dyeing.
In addition to a tree, used in making timber for boats of reviving, traditional red colour system dyestuff raw material are also selected from madder, birchleaf pear, safflower and wild pepper.
Tealeaves can be with direct staining, and after iron mordant dyeing, pure ash can be presented to bronzing chromatography in the general yellowish-brown that presents
Color is to black system chromatography, this is because catechin tannin and iron chemical combination in tealeaves, generate ferric tannate, thus generate grey and
The precipitating of black, is bonded on fiber.The decoration method of gambiered Guangdong gauze in ancient method covers pollutant with rich chalybeate soil, to reach
Decoration method to black effect is this principle.
Contain chlorophyll and lutein in lotus leaf, can be used to yellow colouration and green.There are many yellow plant of tradition dye, commonly
Including cape jasmine, turmeric, sophora flower, cork tree etc..Lotus leaf is more rare in the yellow plant of tradition dye, but the pigment stability in lotus leaf
Preferably, raw material sources are stablized, cheap, therefore have good development prospect.
Lotus leaf can direct yellow colouration, however after having used mordant, the brown bright and beautiful degree of color fastness is dramatically increased.Due to lotus
Pigment in leaf is relatively stable, little to the reaction of mordant, therefore at present in experiment, only discovery is to ferrous sulfate, aluminum sulfate
Potassium has obvious reaction.Mordant between lotus leaf is relatively simple, therefore can pre- mordant dyeing, rear mordant dyeing and the mode with mordant dyeing
It can use.Here pre- mordant dyeing is selected.
Dye material is extracted pigment and carried out in the following manner: dye material is immersed in 10-40 DEG C of water 20-30h, so
20-40min is boiled into dye material boiling afterwards, is cooled to 40-60 DEG C of obtained dyestuff.Dyestuff raw material first impregnate 20- in cold water
30 hours purposes are the cell expansions in order to make raw material, and boiling water bubble, which boils 20-40 minutes, can disposably extract raw material
Left and right pigment, the pigment extracted is also more balanced, does not also waste material.
In preferred embodiments of the present invention, dyestuff impregnates substance 0.5-1.5h, and temperature is 80-100 DEG C.It should be noted that
, in other embodiments of the invention, dyeing temperature can also be 50-80 DEG C when dyeing.
One of chromic salts, aluminium salt, molysite, alkaline solution, mantoquita and tannic acid provided in an embodiment of the present invention or two
Kind, mordant and the obtained substance colour fixation of dyestuff cooperation dyeing are significant, and dyeing colour system is wider, meets colorful more in the modern life
Sample life.
Embodiment 1
Selection aluminum aluminum sulfate is mordant, and aluminum aluminum sulfate is the 5% of its contaminated substance weight, and is added in Mordant solution
Enter to help mordant oxalic acid, weight is the 3% of substance weight, and the bath raio of substance and Mordant solution is 1:20.It is molten in aluminum aluminum sulfate
Oxalic acid is added in liquid, temperature 60 C impregnates the substance time 60 minutes.
A tree, used in making timber for boats of reviving is immersed in 10 DEG C of water 30h using Soviet Union's a tree, used in making timber for boats by dye material, and 40min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed 60 minutes in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 80 DEG C, and it is red in lotus root to obtain material color
System.
Embodiment 2
Selecting aluminum aluminum sulfate and tannic acid is mordant, and aluminum aluminum sulfate is the 3% of its contaminated substance weight, and tannic acid is
The bath raio of the 3% of its contaminated substance weight, substance and Mordant solution is 1:15.Mordant dyeing sequence is that substance is put into tannic acid solution
It is taken out after impregnating 12 hours, places into after aluminum potassium sulfate solution impregnates 60 minutes and take out, mordant dyeing temperature is 30 DEG C.
A tree, used in making timber for boats of reviving is immersed in 15 DEG C of water 28h using Soviet Union's a tree, used in making timber for boats by dye material, and 35min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 0.7h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 85 DEG C, obtains material color in large red
System.
Embodiment 3
Selecting aluminum aluminum sulfate and potassium chromium sulfate is mordant, aluminum aluminum sulfate for its contaminated substance weight 6%, tannin
Acid is the 6% of its contaminated substance weight, and the bath raio of substance and Mordant solution is 1:18.Mordant dyeing sequence is that substance is put into chromium sulfate
Potassium solution takes out after impregnating 15 hours, places into after aluminum potassium sulfate solution impregnates 90 minutes and takes out, and mordant dyeing temperature is 20 DEG C.
A tree, used in making timber for boats of reviving is immersed in 20 DEG C of water 26h using Soviet Union's a tree, used in making timber for boats by dye material, and 30min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 0.9h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 90 DEG C, obtains material color in purplish red
System.
Embodiment 4
Selecting sodium hydroxide and potassium chromium sulfate is mordant, sodium hydroxide for its contaminated substance weight 4%, sulfuric acid
Chromium potassium is the 2% of its contaminated substance weight, and the bath raio of substance and Mordant solution is 1:22.Mordant dyeing sequence is that substance is put into sulfuric acid
Chromium potassium solution takes out after impregnating 24 hours, places into after sodium hydroxide solution impregnates 24 hours and takes out, and mordant dyeing temperature is 27 DEG C.
Dye material using Soviet Union's a tree, used in making timber for boats, for 24 hours, is then boiled 25min and is made by the water that a tree, used in making timber for boats of reviving is immersed in 25 DEG C by dye material boiling
Dyestuff.Then above-mentioned substance is dyed into 1.1h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 95 DEG C, obtains material color in aubergine
System.
Embodiment 5
Selection ferrous sulfate is mordant, and ferrous sulfate is the 7% of its contaminated substance weight, substance and Mordant solution
Bath raio is 1:25.Mordant dyeing sequence is to take out after substance is put into ferrous sulfate solution immersion 26 hours, and mordant dyeing temperature is 22 DEG C.
A tree, used in making timber for boats of reviving is immersed in 30 DEG C of water 22h using Soviet Union's a tree, used in making timber for boats by dye material, and 22min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 1.3h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 100 DEG C, obtains material color darkly purple
System.
Embodiment 6
Selection copper sulphate is mordant, and copper sulphate is the 5% of its contaminated substance weight, the bath raio of substance and Mordant solution
For 1:16.Mordant dyeing sequence is to take out after substance is put into copper-bath immersion 10 hours, and mordant dyeing temperature is 25 DEG C.
A tree, used in making timber for boats of reviving is immersed in 32 DEG C of water 21h using Soviet Union's a tree, used in making timber for boats by dye material, and 20min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 1.5h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 95 DEG C, obtains material color in green purple
System.
Embodiment 7
Selecting sodium hydroxide and tannic acid is mordant, and sodium hydroxide is the 4% of its contaminated substance weight, and tannic acid is
The bath raio of the 4% of its contaminated substance weight, substance and Mordant solution is 1:18.It is molten that mordant dyeing sequence is that substance is put into sodium hydroxide
Liquid takes out after impregnating 20 hours, places into after tannic acid solution impregnates 20 hours and takes out, and mordant dyeing temperature is 30 DEG C.
A tree, used in making timber for boats of reviving is immersed in 35 DEG C of water 28h using Soviet Union's a tree, used in making timber for boats by dye material, and 35min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 0.7h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 90 DEG C, obtains material color in meat taro color
System.
Embodiment 8
Selecting tannic acid and potassium chromium sulfate is mordant, and tannic acid is the 5% of its contaminated substance weight, and tannic acid is it
The bath raio of the 3% of contaminated substance weight, substance and Mordant solution is 1:18.Mordant dyeing sequence is that substance is put into potassium chromium sulfate solution
It is taken out after impregnating 15 hours, places into after tannic acid solution impregnates 15 hours and take out, mordant dyeing temperature is 20 DEG C.
A tree, used in making timber for boats of reviving is immersed in 40 DEG C of water 26h using Soviet Union's a tree, used in making timber for boats by dye material, and 30min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 0.9h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 85 DEG C, obtains material color in ripe brown
System.
Embodiment 9
Selection tannic acid is mordant, and tannic acid is the 7% of its contaminated substance weight, the bath raio of substance and Mordant solution
For 1:25.Mordant dyeing sequence is to take out after substance is put into tannic acid solution immersion 20 hours, and mordant dyeing temperature is 22 DEG C.
A tree, used in making timber for boats of reviving is immersed in 15 DEG C of water 22h using Soviet Union's a tree, used in making timber for boats by dye material, and 22min then is boiled in dye material boiling and is made
Dyestuff.Then above-mentioned substance is dyed into 1.3h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 80 DEG C, obtains material color in crocus
System.
Embodiment 10
Selection aluminum aluminum sulfate is mordant, and aluminum aluminum sulfate is the 3% of its contaminated substance weight, substance and Mordant solution
Bath raio is 1:16.Mordant dyeing sequence is to take out after substance is put into aluminum potassium sulfate solution immersion 25 hours, and mordant dyeing temperature is 25 DEG C.
Dye material uses lotus leaf, lotus leaf is cut into the bulk of 3x3 ㎝, and be immersed in 32 DEG C of water 21h, then by dyestuff
Raw material boiling boils 20min and dyestuff is made.Then above-mentioned substance is dyed into 1.5h in lotus leaf liquid, dip dyeing temperature is 85 DEG C, is obtained
Material color is in lemon yellow colour system.
Embodiment 11
Selection ferrous sulfate is mordant, and ferrous sulfate is the 6% of its contaminated substance weight, substance and Mordant solution
Bath raio is 1:20.Mordant dyeing sequence is to take out after substance is put into ferrous sulfate solution immersion 25 hours, and mordant dyeing temperature is 25 DEG C.
Dye material uses lotus leaf, lotus leaf is cut into the bulk of 3x3 ㎝, and be immersed in 28 DEG C of water 20h, then by dyestuff
Raw material boiling boils 28min and dyestuff is made.Then above-mentioned substance is dyed into 1.1h in lotus leaf liquid, dip dyeing temperature is 90 DEG C, is obtained
Material color is in blackish green colour system.
Embodiment 12
Selection ferrous sulfate is mordant, and ferrous sulfate is the 7% of its contaminated substance weight, substance and Mordant solution
Bath raio is 1:24.Mordant dyeing sequence is to take out after substance is put into ferrous sulfate solution immersion 22 hours, and mordant dyeing temperature is 25 DEG C.
Dye material uses tealeaves, and is immersed in 25 DEG C of water 25h, 30min then is boiled in dye material boiling, dye is made
Material.Then above-mentioned substance is dyed into 1.3h in tealeaves liquid, dip dyeing temperature is 95 DEG C, obtains material color darkly colour system.
Embodiment 13
Selecting sodium hydroxide and potassium chromium sulfate is mordant, sodium hydroxide for its contaminated substance weight 200%, sulphur
Sour chromium potassium is the 200% of its contaminated substance weight, and the bath raio of substance and Mordant solution is 1:22.Mordant dyeing sequence is put for substance
Enter after potassium chromium sulfate solution impregnates 24 hours and take out, places into after sodium hydroxide solution impregnates 24 hours and take out, mordant dyeing temperature is
27℃。
Dye material using Soviet Union's a tree, used in making timber for boats, for 24 hours, is then boiled 25min and is made by the water that a tree, used in making timber for boats of reviving is immersed in 35 DEG C by dye material boiling
Dyestuff.Then above-mentioned substance is dyed into 1.1h in Soviet Union's a tree, used in making timber for boats liquid, dip dyeing temperature is 80 DEG C, and it is dark purple to obtain material color
System.
Test example 1
It is dyed according to the colouring method of embodiment 1 to embodiment 4 and embodiment 4 to embodiment 12, unlike
It is respectively 7%, 5%, the 2% of its contaminated fabric weight by the weight of mordant.Gained fabric color is shown in Table 1.It particularly, will be real
Apply example 4 and the colouring method of embodiment 13 dyed, unlike potassium chromium sulfate and caustic soda composition mordant in, caustic soda with
The weight of potassium chromium sulfate is respectively 200%, 100%, 50%, 10%, 5%, the 2% of the weight of contaminated substance.As a result such as table 1
It is shown.
The test of 1 coloring material of table
Test example 2
Cloth made from embodiment 1 to embodiment 13 is subjected to solarizing test, alkali resistance test and washing experiment, specifically
Ground, solarizing test: dye object is exposed in strong sunlight 3 hours.Liquid detergent test: dye object soaks in the laundry liquor of 1tw%
It is clean to take out washing for bubble 10 minutes.Decantation test: dye object impregnates 10 minutes in the soap solution of 1tw%, and it is dry to take out washing
Only.The results are shown in Table 2.
2 fixation test result of table
The embodiment of the present invention provides vegetable dye and mordant, mordant include chromic salts, aluminium salt, molysite, alkaline solution, copper
One or both of salt and tannic acid.Mordant and the obtained substance colour fixation of dyestuff cooperation dyeing are significant, and wash resistant is resistance to
The resistance to laundry fluidity of solarization can remarkably and the colour system of dyeing colour developing is wider, meets colorful multiplicity life in the modern life.
These are only the preferred embodiment of the present invention, is not intended to restrict the invention, for those skilled in the art
For member, the invention may be variously modified and varied.All within the spirits and principles of the present invention, it is made it is any modification,
Equivalent replacement, improvement etc. should all include.
Claims (10)
1. a kind of vegetation dye formula, which is characterized in that including vegetable dye and mordant, the mordant include chromic salts, aluminium salt,
At least one of molysite, alkaline solution, mantoquita and tannic acid,
Preferably, the mordant includes one of chromic salts, aluminium salt, molysite, alkaline solution, mantoquita and tannic acid or two
Kind.
2. vegetation dye formula described in accordance with the claim 1, which is characterized in that the chromic salts is potassium chromium sulfate, chromic nitrate potassium, vinegar
At least one of sour chromium, potassium bichromate and sodium dichromate；Preferably, the chromic salts is potassium chromium sulfate, chromic nitrate potassium, acetic acid
One of chromium, potassium bichromate and sodium dichromate；It is highly preferred that the chromic salts is potassium chromium sulfate；
And/or the aluminium salt is at least one of aluminum aluminum sulfate, alchlor and aluminum sulfate；Preferably, the aluminium salt is
One of which in aluminum aluminum sulfate, alchlor and aluminum sulfate；It is highly preferred that the aluminium salt is aluminum aluminum sulfate；
And/or the molysite is at least one of ferrous sulfate, frerrous chloride and ferrous acetate；Preferably, the molysite
For the one of which in ferrous sulfate, frerrous chloride and ferrous acetate；It is highly preferred that the molysite selects ferrous sulfate；
And/or the alkaline solution is at least one of sodium hydroxide, potassium hydroxide and ammonium hydroxide；Preferably, the alkalinity
Solution is the one of which in sodium hydroxide, potassium hydroxide and ammonium hydroxide；It is highly preferred that the alkaline solution selects hydroxide
Sodium；
And/or the mantoquita is at least one of copper sulphate, basic copper sulfate and copper nitrate；Preferably, the mantoquita is
One of which in copper sulphate, basic copper sulfate and copper nitrate；It is highly preferred that the mantoquita selects copper sulphate.
3. vegetation dye formula described in accordance with the claim 1, which is characterized in that the raw material of the vegetable dye is selected from Soviet Union a tree, used in making timber for boats, madder
Grass, birchleaf pear, safflower, wild pepper, lotus leaf and tea are one such.
4. vegetation described in accordance with the claim 3 dye formula, which is characterized in that the preparation of the vegetable dye in the following manner into
Row: by the raw material soaking of the vegetable dye, boiling boils 20-40min the vegetation is made after 20-30h in 10-40 DEG C of water
Dyestuff.
5. a kind of vegetation contaminates colouring method, which is characterized in that using the described in any item vegetations dyes of claim 1-4 be formulated into
Row dyeing.
6. vegetation contaminates colouring method according to claim 5, which is characterized in that colouring method is with bath mordant dyeing, pre- matchmaker
Decoration method and after chrome process are one such.
7. vegetation contaminates colouring method according to claim 6, which is characterized in that colouring method is prechrome process, by institute
Dye substance dyes 1-30h in the Mordant solution that the mordant is configured to, then by the substance in the vegetable dye
Middle dyeing 0.5-1.5h.
8. vegetation contaminates colouring method according to claim 7, which is characterized in that the dyeing temperature of the vegetable dye is
80-100 DEG C.
9. vegetation contaminates colouring method according to claim 7, which is characterized in that the weight of the mordant is contaminated object by it
The 1-10% of the weight of matter；Preferably, the weight of the mordant for the weight of its contaminated substance 2-7%.
10. according to claim 7 vegetation contaminate colouring method, which is characterized in that the weight of the Mordant solution and its
The weight ratio of contaminated substance is 10-30:1；
Preferably, the weight ratio of the weight of the Mordant solution and the substance is 15-25:1.
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| CN113388263A (en) * | 2021-06-22 | 2021-09-14 | 浙江超凡制衣有限公司 | Green harmless plant dye for thermosensitive clothing material and dyeing method thereof |
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Application publication date: 20181211 |