CN108893985A - A kind of no fluorine-type waterproofing agent and preparation method thereof - Google Patents
A kind of no fluorine-type waterproofing agent and preparation method thereof Download PDFInfo
- Publication number
- CN108893985A CN108893985A CN201810597996.7A CN201810597996A CN108893985A CN 108893985 A CN108893985 A CN 108893985A CN 201810597996 A CN201810597996 A CN 201810597996A CN 108893985 A CN108893985 A CN 108893985A
- Authority
- CN
- China
- Prior art keywords
- acrylate
- emulsion
- fluorine
- type waterproofing
- waterproofing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sealing Material Composition (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The present invention provides a kind of no fluorine-type waterproofing agents and preparation method thereof.Wherein the floride-free type waterproofing agent includes according to mass fraction：Inorganic SiO2Modified acrylate emulsion 80% ~ 99% and water repellency small molecule filler 1% ~ 20%.The wherein no fluorine-type waterproofing agent of the present invention, compared to traditional fluorine-containing water repellent due to being free of PFOS and PFOA, thus more environmentally-friendly.And in high molecular inorganic SiO2Water repellency small molecule filler is filled in modified acrylate emulsion, so that the fabric arranged by it while there is good spray waterproof performance and anti-siphon performance.
Description
Technical field
The present invention relates to a kind of auxiliary agents that textile dyeing and finishing industry uses, especially, one such waterproofing agent and its preparation
Method.
Background technique
With the continuous improvement of people's living standards, making public higher and higher to the quality requirements of textile.It spins simultaneously
The fabric of fabric is no longer limited to the cotton fabric of traditional one-component.In recent years, all kinds of blended yarn weaved fabrics based on cotton have been
It is increasingly becoming the mainstream fabric in market.This blended yarn weaved fabric generally comprises the types such as polyester cotton, cotton/brocade, cotton/nitrile/viscous.
And increasing with textile fabric type, corresponding industry have developed phase also for different types of textile fabric
The waterproofing agent of type is answered, is applied in fabric post-treatment, to assign fabric excellent soft feel, and makes it have good
Lint breakage and waterproof performance.
But these waterproofing agents that industry is developed and used, usually fluorine element type waterproofing agent, interior component contain PFOS and
PFOA substance.Both substances are difficult to degrade, and environmental pollution environment is big, and the requirement with today's society to environmental protection is increasingly
It is high, it is evident that its requirement for not met era development.
Therefore, it is necessory to develop a kind of novel no fluorine-type waterproofing agent, to overcome defect in the prior art.
Summary of the invention
It is environmentally protective the purpose of the present invention is to provide a kind of no fluorine-type waterproofing agent, without any PFOS and PFOA.
To achieve the goals above, the technical solution adopted by the present invention is as follows：
A kind of no fluorine-type waterproofing agent, includes following component according to mass fraction：
Inorganic SiO2Modified acrylate emulsion：80%~99%；And
Water repellency small molecule filler：1%~20%；
The wherein inorganic SiO2Modified acrylate emulsion includes by mass fraction：
Compound emulsifying agent：0.5%~5%；
Mix monomer：10%~40%；
Initiator：0.01%~1%；
Deionized water：45%~90%；And
The hydrophilic SiO of inorganic nano2：0.5%~5%.
Further, in different embodiments, wherein the compound emulsifying agent includes compound with nonionic by cation
Made of emulsifier.
Further, in different embodiments, wherein the initiator includes water soluble starter.
Further, in different embodiments, wherein the water soluble starter includes ammonium persulfate, potassium peroxydisulfate,
At least one of azo diisobutyl amidine hydrochloride.
Further, in different embodiments, wherein the mix monomer includes according to mass fraction：
Octadecyl acrylate：20%~50%；
Process Conditions of Cetane Acrylate：10%~50%；
Dodecyl acrylate：10%~40%；
Isooctyl acrylate monomer：10%~35%；And
Hydroxypropyl acrylate：0.5%~10%.
Further, in different embodiments, wherein the water repellency small molecule filler includes chlorinated paraffin, stone
At least one of wax, stearic acid and polyamines quasi polymer.
Another embodiment of the invention provides a kind of for manufacturing the no fluorine-type waterproofing agent of the present invention
Preparation method includes the following steps：
S1）Prepare the inorganic SiO2Mix monomer in modified acrylate emulsion；
S2）Compound emulsifying agent and deionized water are added into the mix monomer obtained, inorganic SiO is prepared2Modified third
Olefin(e) acid ester pre-emulsion；
S3）To the inorganic SiO obtained2The water repellency small molecule filler is added in modification acrylate pre-emulsion, makes
It is standby to obtain no fluoro water proofing agent pre-emulsion；
S4）The initiator is dissolved into the aqueous solution that mass fraction is 10% with deionized water；
S5）The no fluoro water proofing agent pre-emulsion obtained is warming up to 70 DEG C ~ 85 DEG C, the initiator obtained is added dropwise thereto
Aqueous solution, 1.5 ~ 2.5h are added dropwise, and control reaction temperature at 70 DEG C ~ 85 DEG C, keep the temperature 3 ~ 5h；
S6）It is down to room temperature, up to the no fluorine-type waterproofing agent after filtering.
Further, in different embodiments, wherein preparing the mix monomer for the mix monomer and including
Octadecyl acrylate, Process Conditions of Cetane Acrylate, dodecyl acrylate, Isooctyl acrylate monomer, hydroxypropyl acrylate and inorganic nano
Hydrophilic SiO2It is separately added into a reaction kettle, is warming up to 40 DEG C ~ 70 DEG C, stir 20min ~ 50min, after stirring, i.e.,
10% ~ 40% mix monomer can be made.
Further, in different embodiments, wherein preparing the inorganic SiO2Modification acrylate pre-emulsion be to
Compound emulsifying agent is added in the mix monomer obtained, is warming up to 40 DEG C ~ 70 DEG C, 45% ~ 90% deionized water is added dropwise and stirs
20min ~ 50min is stirred, and can be prepared by the inorganic SiO2Modification acrylate pre-emulsion.
Further, in different embodiments, wherein preparing the no fluoro water proofing agent pre-emulsion is to obtained described
Inorganic SiO2The water repellency small molecule filler is added in modification acrylate pre-emulsion, at 40 DEG C ~ 70 DEG C, stirring 20min ~
50min is stirred, and under 20 ~ 40 kilograms of pressure, homogeneous twice, it is pre- to can be prepared by the no fluoro water proofing agent respectively
Lotion.
Compared with the existing technology, the beneficial effects of the invention are as follows：The no fluorine-type waterproofing agent of the present invention, inside not
It is environmentally protective containing any PFOS and PFOA.And because it includes the inorganic SiO of macromolecule2In modified acrylate emulsion
It is filled with water repellency small molecule filler, so that the fabric arranged by it not only has good spray waterproof performance, but also
It is provided with anti-siphon performance, also so as to make fabric preferably reach the required waterproof requirement of people's life.
Specific embodiment
Below with reference to embodiment, to a kind of technical solution of no fluorine-type waterproofing agent of the present invention and preparation method thereof
It is described in further detail.
Wherein in the present invention, all raw material used be it is conventional use of, can be bought from market.In this hair
It in bright, is refered in particular to Ru non-, all amounts, percentage, part are unit of weight.
Embodiment 1
The present embodiment discloses a kind of no fluorine-type waterproofing agent and preparation method thereof, the raw material being related to due to the no fluorine-type waterproofing agent
And dosage, it is specifically related in the implementation steps of following preparation method, to avoid unnecessary repetition, is not repeated herein
It is bright.
Wherein the preparation method comprises the following steps：
S1）Respectively by octadecyl acrylate：35g, Process Conditions of Cetane Acrylate：25g, dodecyl acrylate：20g, Isooctyl acrylate monomer：
15g, hydroxypropyl acrylate：4g, nano-hydrophilic SiO2：1g is added in a reaction kettle, is warming up to 50 DEG C, stirs 30min, sufficiently
Stir evenly obtained mix monomer.
S2）To S1）Compound emulsifying agent is added in obtained mix monomer：10g, wherein octadecyl trimethyl chlorination
Ammonium：7g, paregal O -15:3g is warming up to 50 DEG C, and side is added dropwise 250g deionization waterside and stirs 30min, stirs, and makes
Obtain inorganic SiO2Modification acrylate pre-emulsion.
S3）To S2）Obtained inorganic SiO2Water repellency small molecule filler is added in modification acrylate pre-emulsion：52
Chlorinated paraffin 20g is spent, temperature 50 C stirs 30min, stirs, under 20,30 kilograms of pressure, difference homogeneous two
It is secondary, obtain no fluoro water proofing agent pre-emulsion.
S4）The azo-bis-isobutyrate hydrochloride of 1g is dissolved into the aqueous solution that mass fraction is 10% with deionized water.
S5）By S3）Obtained pre-emulsion is warming up to 75 DEG C, and S4 is added dropwise thereto）Obtained initiator solution, 2h
It is added dropwise, controls reaction temperature at 80 DEG C, keep the temperature 4h.
S6）It is down to room temperature, filtering, barrelling obtain the no fluorine-type waterproofing agent that the present embodiment is related to.
Embodiment 2
The present embodiment discloses another without fluorine-type waterproofing agent and preparation method thereof, the original being related to due to the no fluorine-type waterproofing agent
Material and dosage, are specifically related in the implementation steps of following preparation method, to avoid unnecessary repetition, are not repeated herein
Explanation.
Wherein the preparation method comprises the following steps：
S1）Respectively by octadecyl acrylate：35g, Process Conditions of Cetane Acrylate：25g, dodecyl acrylate：20g, Isooctyl acrylate monomer：
15g, hydroxypropyl acrylate：4g, nano-hydrophilic SiO2：1g is added in a reaction kettle, is warming up to 50 DEG C, stirs 30min, sufficiently stirs
Mix uniformly obtained mix monomer.
S2）To S1）Compound emulsifying agent is added in obtained mix monomer：10g, wherein octadecyl trimethyl chlorination
Ammonium：7g, paregal O -15:3g is warming up to 50 DEG C, and side is added dropwise 250g deionization waterside and stirs 30min, stirs, and makes
Obtain inorganic SiO2Modification acrylate pre-emulsion.
S3）To S2）Obtained inorganic SiO2Water repellency small molecule filler is added in modification acrylate pre-emulsion：Two
Ethylene triamine is modified stearic acid 20g, and temperature 50 C stirs 30min, stirs, under 20,30 kilograms of pressure, point
Other homogeneous twice, obtains no fluoro water proofing agent pre-emulsion.
S4）The azo-bis-isobutyrate hydrochloride of 1g is dissolved into the aqueous solution that mass fraction is 10% with deionized water.
S5）By S3）Obtained pre-emulsion is warming up to 75 DEG C, and S4 is added dropwise thereto）Obtained initiator solution, 2h
It is added dropwise, controls reaction temperature at 80 DEG C, keep the temperature 4h.
S6）It is down to room temperature, is filtered, barrelling obtains the no fluorine-type waterproofing agent that the present embodiment is related to.
The no fluorine-type waterproofing agent of the present invention, it is interior without any PFOS and PFOA, it is environmentally protective.
And because it includes the inorganic SiO of macromolecule2Water repellency small molecule is filled in modified acrylate emulsion to fill out
Object is filled, so that the fabric arranged by it not only has good spray waterproof performance, but also is provided with anti-siphon performance, from
And waterproof requirement needed for fabric can be made preferably to reach people's life.
Technical scope of the invention is not limited solely to the content in above description, and those skilled in the art can not take off
Under the premise of from technical thought of the invention, many variations and modifications are carried out to above-described embodiment, and these deformations and modification should all
When within the scope of the present invention.
Claims (10)
1. a kind of no fluorine-type waterproofing agent；It is characterized in that, including following component according to mass fraction：
Inorganic SiO2Modified acrylate emulsion：80%~99%；And
Water repellency small molecule filler：1%~20%；
The wherein inorganic SiO2Modified acrylate emulsion includes by mass fraction：
Compound emulsifying agent：0.5%~5%；
Mix monomer：10%~40%；
Initiator：0.01%~1%；
Deionized water：45%~90%；And
The hydrophilic SiO of inorganic nano2：0.5%~5%.
2. no fluorine-type waterproofing agent according to claim 1, which is characterized in that wherein the compound emulsifying agent include by sun from
The emulsifier that son is combined with nonionic.
3. no fluorine-type waterproofing agent according to claim 1, which is characterized in that wherein the initiator includes water-soluble causes
Agent.
4. no fluorine-type waterproofing agent according to claim 3, which is characterized in that wherein the water soluble starter includes over cure
Sour ammonium, potassium peroxydisulfate, at least one of azo diisobutyl amidine hydrochloride.
5. no fluorine-type waterproofing agent according to claim 1, which is characterized in that wherein the mix monomer is according to mass fraction
Including：
Octadecyl acrylate：20%~50%；
Process Conditions of Cetane Acrylate：10%~50%；
Dodecyl acrylate：10%~40%；
Isooctyl acrylate monomer：10%~35%；And
Hydroxypropyl acrylate：0.5%~10%.
6. no fluorine-type waterproofing agent according to claim 1, which is characterized in that the wherein water repellency small molecule filler packet
Include at least one of chlorinated paraffin, paraffin, stearic acid and polyamines quasi polymer.
7. a kind of preparation method for being used to prepare no fluorine-type waterproofing agent described in claim 1, which is characterized in that including following step
Suddenly：
S1）Prepare the inorganic SiO2Mix monomer in modified acrylate emulsion；
S2）Compound emulsifying agent and deionized water are added into the mix monomer obtained, inorganic SiO is prepared2Modified propylene
Acid esters pre-emulsion；
S3）To the inorganic SiO obtained2The water repellency small molecule filler is added in modification acrylate pre-emulsion, prepares
Obtain no fluoro water proofing agent pre-emulsion；
S4）The initiator is dissolved into the aqueous solution that mass fraction is 10% with deionized water；
S5）The no fluoro water proofing agent pre-emulsion obtained is warming up to 70 DEG C ~ 85 DEG C, the initiator obtained is added dropwise thereto
Aqueous solution, 1.5 ~ 2.5h are added dropwise, and control reaction temperature at 70 DEG C ~ 85 DEG C, keep the temperature 3 ~ 5h；
S6）It is down to room temperature, up to the no fluorine-type waterproofing agent after filtering.
8. preparation method according to claim 7, which is characterized in that wherein preparing the mix monomer is by the mixing
Octadecyl acrylate that monomer includes, Process Conditions of Cetane Acrylate, dodecyl acrylate, Isooctyl acrylate monomer, hydroxypropyl acrylate with
And the hydrophilic SiO of inorganic nano2It is separately added into a reaction kettle, is warming up to 40 DEG C ~ 70 DEG C, stir 20min ~ 50min, be sufficiently stirred
After uniformly, 10% ~ 40% mix monomer can be prepared by.
9. preparation method according to claim 7, which is characterized in that wherein prepare the inorganic SiO2Modification acrylate
Pre-emulsion is that compound emulsifying agent is added into the mix monomer obtained, is warming up to 40 DEG C ~ 70 DEG C, be added dropwise 45% ~ 90% go from
Sub- water simultaneously stirs 20min ~ 50min, stirs, and can be prepared by the inorganic SiO2Modification acrylate pre-emulsion.
10. preparation method according to claim 7, which is characterized in that wherein preparing the no fluoro water proofing agent pre-emulsion is
To the inorganic SiO obtained2The water repellency small molecule filler is added in modification acrylate pre-emulsion, 40 DEG C ~ 70
DEG C, 20min ~ 50min is stirred, is stirred, under 20 ~ 40 kilograms of pressure, homogeneous twice, be can be prepared by described respectively
Without fluoro water proofing agent pre-emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810597996.7A CN108893985A (en) | 2018-06-12 | 2018-06-12 | A kind of no fluorine-type waterproofing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810597996.7A CN108893985A (en) | 2018-06-12 | 2018-06-12 | A kind of no fluorine-type waterproofing agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108893985A true CN108893985A (en) | 2018-11-27 |
Family
ID=64344666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810597996.7A Withdrawn CN108893985A (en) | 2018-06-12 | 2018-06-12 | A kind of no fluorine-type waterproofing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108893985A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111411515A (en) * | 2019-01-04 | 2020-07-14 | 远东新世纪股份有限公司 | Fluorine-free water repellent agent, preparation method thereof and water repellent fabric |
| CN116623461A (en) * | 2023-04-04 | 2023-08-22 | 远东中乾(厦门)科技集团股份公司 | Fluorine-free oil-proof agent for pulp food container catering utensils and production process thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1010494B (en) * | 1955-01-20 | 1957-06-19 | Ciba Geigy | Process for applying durable, water-repellent coatings to fiber materials |
| GB915759A (en) * | 1960-08-02 | 1963-01-16 | Du Pont | Water-repellency compositions |
| DE3307420A1 (en) * | 1983-03-03 | 1984-09-13 | Bayer Ag, 5090 Leverkusen | TEXTILE EQUIPMENT |
| US20050266753A1 (en) * | 2004-05-26 | 2005-12-01 | Xinggao Fang | Textile treatment and resulting textile |
| WO2008087108A1 (en) * | 2007-01-19 | 2008-07-24 | Basf Se | Method for the production of a coated textile |
| JP2014001252A (en) * | 2012-06-14 | 2014-01-09 | Ipposha Oil Industries Co Ltd | Emulsion, method of producing emulsion, water repellent, water repellent assistant, processing method of repellency, method of producing water repellent fiber product and water repellent fiber product |
| CN104788628A (en) * | 2014-01-20 | 2015-07-22 | 福盈科技化学股份有限公司 | Fluorine-free water-drawing agent, preparation method and application thereof |
| CN106087420A (en) * | 2016-06-07 | 2016-11-09 | 苏州联胜化学有限公司 | A kind of without fluoro water proofing agent and preparation method thereof |
| CN106632875A (en) * | 2016-09-30 | 2017-05-10 | 华南理工大学 | Inorganic nanoparticle-modified fluorinated acrylate hydrophobic emulsion and preparation method thereof |
| CN106894224A (en) * | 2017-03-10 | 2017-06-27 | 吉林大学 | A kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles and fire-retardant self-repairing super hydrophobic fabric |
-
2018
- 2018-06-12 CN CN201810597996.7A patent/CN108893985A/en not_active Withdrawn
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1010494B (en) * | 1955-01-20 | 1957-06-19 | Ciba Geigy | Process for applying durable, water-repellent coatings to fiber materials |
| GB915759A (en) * | 1960-08-02 | 1963-01-16 | Du Pont | Water-repellency compositions |
| DE3307420A1 (en) * | 1983-03-03 | 1984-09-13 | Bayer Ag, 5090 Leverkusen | TEXTILE EQUIPMENT |
| US20050266753A1 (en) * | 2004-05-26 | 2005-12-01 | Xinggao Fang | Textile treatment and resulting textile |
| WO2008087108A1 (en) * | 2007-01-19 | 2008-07-24 | Basf Se | Method for the production of a coated textile |
| JP2014001252A (en) * | 2012-06-14 | 2014-01-09 | Ipposha Oil Industries Co Ltd | Emulsion, method of producing emulsion, water repellent, water repellent assistant, processing method of repellency, method of producing water repellent fiber product and water repellent fiber product |
| CN104788628A (en) * | 2014-01-20 | 2015-07-22 | 福盈科技化学股份有限公司 | Fluorine-free water-drawing agent, preparation method and application thereof |
| CN106087420A (en) * | 2016-06-07 | 2016-11-09 | 苏州联胜化学有限公司 | A kind of without fluoro water proofing agent and preparation method thereof |
| CN106632875A (en) * | 2016-09-30 | 2017-05-10 | 华南理工大学 | Inorganic nanoparticle-modified fluorinated acrylate hydrophobic emulsion and preparation method thereof |
| CN106894224A (en) * | 2017-03-10 | 2017-06-27 | 吉林大学 | A kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles and fire-retardant self-repairing super hydrophobic fabric |
Non-Patent Citations (1)
| Title |
|---|
| 徐丽慧: "《基于杂化纳米SiO2水溶胶构筑纺织品超疏水表面》", 《中国博士学位论文全文数据库》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111411515A (en) * | 2019-01-04 | 2020-07-14 | 远东新世纪股份有限公司 | Fluorine-free water repellent agent, preparation method thereof and water repellent fabric |
| CN116623461A (en) * | 2023-04-04 | 2023-08-22 | 远东中乾(厦门)科技集团股份公司 | Fluorine-free oil-proof agent for pulp food container catering utensils and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101948555B (en) | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder | |
| CN103289010B (en) | Method for preparing core-shell nano SiO2/fluorine-containing polyacrylate soap-free emulsion | |
| CN104418970B (en) | A kind of fluorinated acrylate emulsion of environment-friendly type water and oil repellant and preparation method and application | |
| CN104744642B (en) | The preparation method of nano-titanium dioxide modified color-fixing agent emulsion | |
| CN103628317B (en) | A kind of composition of waterproofing and oil-proof agent and processing method, textiles | |
| CN105131174A (en) | Durable uvioresistant finishing agent applicable to both cotton and terylene and preparation method thereof | |
| CN105111363A (en) | Function prepolymer and preparation method and application thereof | |
| CN106758266A (en) | Microcapsules and its preparation method and application and temperature-regulation fabric for preparing temperature-regulation fabric | |
| CN108893985A (en) | A kind of no fluorine-type waterproofing agent and preparation method thereof | |
| CN104195850B (en) | A kind of terylene is containing slurry fabric single bath process destarch dyeing process and special assistant thereof | |
| CN106637976A (en) | High-efficiency fluorine-free waterproof agent for cotton fabrics subjected to low-temperature dyeing and finishing processing | |
| CN105696377A (en) | Efficient and rapid steaming printing technology adopting reactive dyes | |
| CN110499218A (en) | A kind of efficient and environment-friendly type acid scouring agent and preparation method thereof | |
| CN104558368B (en) | A kind of high temperature resistant wallpaper basement membrane and preparation method thereof | |
| CN106835757A (en) | A kind of blend polyester dyeing fabric technique | |
| CN111171211A (en) | Low-moisture-regain ultrahigh-crosslinking-degree environment-friendly stiffening agent and preparation method thereof | |
| JPH0243210A (en) | Copolymer containing perfluoroalkyl group | |
| DE10008930A1 (en) | Anti-wrinkle treatment of cellulose-containing textiles and laundry detergents | |
| CN108729269A (en) | A kind of active dye fixing agent and preparation method thereof | |
| EP1360365B1 (en) | Composition and method for increasing water and oil repellency of textiles and carpet | |
| CN105862477B (en) | A kind of textile auxiliary and preparation method thereof improving colour fixation | |
| CN105088800A (en) | Low-temperature water-based water-proofing agent and production process thereof | |
| CN108301235A (en) | A kind of resistance to washing and dry burning crock fastness elevator and preparation method thereof | |
| CN101831772B (en) | Fabric finishing technique | |
| CN108299608A (en) | A kind of swollen association thickener of alkali soluble and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181127 |