CN108706964A - Self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof - Google Patents
Self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof Download PDFInfo
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- CN108706964A CN108706964A CN201810404466.6A CN201810404466A CN108706964A CN 108706964 A CN108706964 A CN 108706964A CN 201810404466 A CN201810404466 A CN 201810404466A CN 108706964 A CN108706964 A CN 108706964A
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- entire body
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- 239000011449 brick Substances 0.000 title claims abstract description 39
- 238000005299 abrasion Methods 0.000 title claims abstract description 25
- 238000004140 cleaning Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000004927 clay Substances 0.000 claims abstract description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000004575 stone Substances 0.000 claims abstract description 12
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 11
- 239000010453 quartz Substances 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000454 talc Substances 0.000 claims abstract description 11
- 235000012222 talc Nutrition 0.000 claims abstract description 11
- 229910052623 talc Inorganic materials 0.000 claims abstract description 11
- 235000019738 Limestone Nutrition 0.000 claims abstract description 8
- 239000010459 dolomite Substances 0.000 claims abstract description 8
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 8
- 239000010433 feldspar Substances 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006028 limestone Substances 0.000 claims abstract description 8
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 8
- 239000010456 wollastonite Substances 0.000 claims abstract description 8
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 8
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical group [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 35
- 239000003086 colorant Substances 0.000 claims description 16
- 239000004744 fabric Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000000428 dust Substances 0.000 claims description 9
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 7
- 239000007767 bonding agent Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 239000002270 dispersing agent Substances 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 5
- 238000007688 edging Methods 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- -1 One or more of drier Substances 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 4
- 239000000919 ceramic Substances 0.000 description 16
- 239000010410 layer Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 235000013495 cobalt Nutrition 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 238000005245 sintering Methods 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000007665 sagging Methods 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000022 bacteriostatic agent Substances 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QGBLCIBATKETJC-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;manganese(2+) Chemical compound [Mn+2].O1B([O-])OB2OB([O-])OB1O2 QGBLCIBATKETJC-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002928 artificial marble Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- FUPMSLTYEIZSLZ-UHFFFAOYSA-N cobalt;naphthalene-1-carboxylic acid Chemical compound [Co].C1=CC=C2C(C(=O)O)=CC=CC2=C1 FUPMSLTYEIZSLZ-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000003872 feeding technique Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- ZPPSOOVFTBGHBI-UHFFFAOYSA-N lead(2+);oxido(oxo)borane Chemical compound [Pb+2].[O-]B=O.[O-]B=O ZPPSOOVFTBGHBI-UHFFFAOYSA-N 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/001—Applying decorations on shaped articles, e.g. by painting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/048—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers by spraying or projecting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B17/00—Details of, or accessories for, apparatus for shaping the material; Auxiliary measures taken in connection with such shaping
- B28B17/04—Exhausting or laying dust
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof, the polished bricks, including green body and glaze layer above, green body includes following raw material by weight：Quartz:10-15 parts, flint clay:15-20 parts, clay:20-30 parts, magnesia mud:3-5 parts, talcum:2-3 parts and porcelain stone:10-15 parts, the toner of 5-10wt% is also added in green body；Glaze layer includes ground-coat enamel and overglaze, contains following raw material by weight in overglaze：Feldspar:40-50 parts, kaolin:10-15 parts, dolomite:5-10 parts, lime stone:5-10 parts, matt fused block:25-30 parts, wollastonite:5-10 parts and zinc oxide:3-5 parts.There is entire body texture, high abrasion, high resistant inside polished bricks obtained, and there is automatically cleaning and sterilizing function.
Description
Technical field
The invention belongs to polished bricks field, specially a kind of self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof.
Background technology
The surface of all-body tile green body belongs to one kind of all-body tile by a kind of brick of light made of polishing.Opposite all-body tile
For, polished bricks surface wants much bright and clean.Polished bricks hard wear resistant is suitble to other than toilet, kitchen etc. to make in the interior spaces
With.On the basis of with colored technology is oozed, polished bricks can make various imitative stones, imitation wood effect.
Invention content
It is an object of the invention to provide a kind of self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof, polished bricks obtained
Inside has entire body texture, high abrasion, high resistant, and has automatically cleaning and sterilizing function.
In order to solve the above technical problems, the technical solution adopted in the present invention is：The self-cleaning polished bricks of entire body texture high abrasion,
Glaze layer including green body and above, green body include following raw material by weight：Quartz:10-15 parts, flint clay:15-20
Part, clay:20-30 parts, magnesia mud:3-5 parts, talcum:2-3 parts and porcelain stone:10-15 parts, also it is added with 5-10wt%'s in green body
Toner；Glaze layer includes ground-coat enamel and overglaze, contains following raw material by weight in overglaze：Feldspar:40-50 parts, kaolin:
10-15 parts, dolomite:5-10 parts, lime stone:5-10 parts, matt fused block:25-30 parts, wollastonite:5-10 parts and zinc oxide:3-
5 parts.
Further, it is additionally provided with ink jet layer in the glaze layer, finishing impression ink is added in the ink used in ink jet layer, it is described
Finishing impression ink is made of inorganic non-metallic pigment, solvent, dispersant, bonding agent and surfactant.
Further, the grain size of the inorganic non-metallic pigment is less than 1 micron.
Further, one kind in ink pH adjusting agent, drier, preservative or several is also contained in the finishing impression ink
Kind.
Further, the toner includes cobalt black and/or black 0.5-1 parts gorgeous, 0.5-1 parts of cobalt blue, 3-5 parts of praseodymium yellow and dark brown
1-3 parts.
Further, 10-15 parts of quartz, 2-3 parts of talcum and high-al clay are also contained in the glaze:10-15 parts.
The invention further relates to the methods for preparing the polished bricks, include the following steps：
1）Blank raw material is subjected to ball milling, is dusted, to material powder carry out grading, the toner of different colours is delivered to respectively
Feed bin, be delivered to corresponding spare feed bin after other basic powders mixing in addition to toner, then pattern as needed is adopted
Successively entire body cloth is carried out with corresponding apparatus for distributing, is suppressed to obtain green body using press after completing entire body pattern；
2）It carries out applying ground-coat enamel and overglaze processing after body drying；
3）Ink jet printer print pattern on glaze is used after glazing, when print pattern, the ink channel in addition to ordinary color is arranged
Outside, increase setting finishing impression ink channel, the ink of ordinary color ink channel and finishing impression ink are sprayed on glaze simultaneously；Into
Calcining kiln is sintered, and can be obtained the self-cleaning polished bricks of entire body texture high abrasion after finally carrying out mechanical polishing and edging
Further, material powder grade timing, >=20 be 0.5%, and the purpose of 20 mesh~40 is 50%, and the purpose of 40 mesh~60 is 38%,
The purpose of 60 mesh~80 is 5%, and≤80 purposes are 6.5%.
Further, the ink channel of the ordinary color is respectively cyan, red, yellow and black.
Further, the high temperature hot gas in the calcining kiln, which is adopted, is piped to drying kiln, and green body is obtained for suppressing
Drying；Cleaner is set, and the post that dust is generated to production is dusted, and obtained dust recycles profit through water treatment deposition
With.
The invention has the advantages that：
1, by studying multitube Strand Feeding Technique, each pipe configures different colours raw material, according to the pattern cloth being pre-designed, in halftone
Upper automation cloth, and operated by successively entire body cloth so that in addition to surface has texture, ceramics are internal also to be had ceramic product
There is entire body texture.
2, in inkjet printing pattern on Ceramic glaze, increase finishing impression ink channel, spray finishing impression ink, by ink from
Porcelain surface layer is penetrated by son group, is allowed to act on color development with the colorant in ink, forms sagging striped, visually has more solid
Effect.
3, by increasing sintering aid in ceramic glaze so that existing higher mullite crystalline phase content after sintering carries
High-wearing feature, while thering is enough glass mutually to fill stomata again, improve resistance to soiling.To have both the height of ceramic construction ceramic body
Wearability, and have the high resistance to soiling of glaze layer.
4, by during overglaze glazing, introducing nanometer Ag2O and/or ZnO material so that overglaze has nanometer fraction
Phase structure and from sterilizing ability so that ceramic has both automatically cleaning and sterilizing function while not influencing intensity.
5, the high temperature hot gas of sintering kiln is sent to drying kiln, for building by air blower by using heat preservation heat pipe
Ceramic idiosome drying is built, realizes that waste heat recycles, reaches energy saving purpose.And full-automatic intermittent cleaner is set, sense is utilized
Mode is answered, the post of dust is generated in edging or production, can start cleaner when generating dust by induction, will generate
Dust inhalation device in, and after water process, be sent into recycling in setting mud pit, reach and save emission reduction effect, between realization
Formula of having a rest dedusting.
The present invention has entire body texture high-wearing feature architectural pottery by technological innovation, exploitation, solves polishing building at present
Ceramics and the technology short slab problem for throwing glaze architectural pottery, while being tackled key problems by the relevant technologies, product performance attractive in appearance is improved, energy is reduced
It is difficult to solve the industries common technologies such as current Building Ceramics Industry high energy consumption, pollution is big, added value of product is low for consumption and environmental pollution
Topic promotes Building Ceramics Industry supply side structural reform, realizes architectural pottery product upgrading.
Description of the drawings
Fig. 1 is the photo of the self-cleaning polished bricks of entire body texture high abrasion provided by the invention.
Fig. 2 is the photo of the self-cleaning polished bricks of entire body texture high abrasion provided by the invention.
Fig. 3 is the photo of the self-cleaning polished bricks of entire body texture high abrasion provided by the invention.
Specific implementation mode
It is further illustrated the present invention with reference to embodiment, but the scope of protection of present invention is not limited to implement
The range of example statement.
Embodiment 1：
The self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above.
By weight, wherein green body includes
Basic powder：Quartz:10 parts, flint clay:15 parts, clay:20 parts, magnesia mud:3 parts, talcum:2 parts and porcelain stone:10 parts；
It further include colorant：Black, grey：Cobalt black, gorgeous black addition are the 0.5wt% of basic powder, blue：Cobalt blue addition is base
The 0.5wt% of plinth powder, yellow:Praseodymium yellow addition is the 3wt% of basic powder, coffee：Dark brown addition is the 1wt% of basic powder.
Glaze uses formula as below：Feldspar:40 parts, kaolin:10 parts, dolomite:5 parts, lime stone:5 parts, matt it is molten
Block:25 parts, wollastonite:5 parts and zinc oxide:3 parts.
Embodiment 2：
The self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above.
By weight, wherein green body includes
Basic powder：Quartz:15 parts, flint clay:20 parts, clay:30 parts, magnesia mud:5 parts, talcum:3 parts and porcelain stone:15 parts；
It further include colorant：Black, grey：Cobalt black, gorgeous black addition are the 1wt% of basic powder, blue：Based on cobalt blue addition
The 1wt% of powder, yellow:Praseodymium yellow addition is the 5wt% of basic powder, coffee：Dark brown addition is the 3wt% of basic powder.
Glaze uses formula as below：Feldspar:50 parts, kaolin:15 parts, dolomite:10 parts, lime stone:10 parts, matt it is molten
Block:30 parts, wollastonite:10 parts and zinc oxide:5 parts.
Embodiment 3：
The self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above.
By weight, wherein green body includes
Basic powder：Quartz:12 parts, flint clay:18 parts, clay:25 parts, magnesia mud:4 parts, talcum:3 parts and porcelain stone:12 parts；
It further include colorant：Black, grey：Cobalt black, gorgeous black addition are the 0.8wt% of basic powder, blue：Cobalt blue addition is base
The 0.8wt% of plinth powder, yellow:Praseodymium yellow addition is the 4wt% of basic powder, coffee：Dark brown addition is the 2wt% of basic powder.
Glaze uses formula as below：Feldspar:45 parts, kaolin:12 parts, dolomite:8 parts, lime stone:8 parts, matt it is molten
Block:28 parts, wollastonite:8 parts and zinc oxide:4 parts.
Embodiment 4：
The self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above.
By weight, wherein green body includes
Basic powder：Quartz:12 parts, flint clay:18 parts, clay:25 parts, magnesia mud:4 parts, talcum:3 parts and porcelain stone:12 parts；
It further include colorant：Black, grey：Cobalt black, gorgeous black addition are the 0.8wt% of basic powder, blue：Cobalt blue addition is base
The 0.8wt% of plinth powder, yellow:Praseodymium yellow addition is the 4wt% of basic powder, coffee：Dark brown addition is the 2wt% of basic powder.Toner
Also it can be allocated according to the requirement of the polished bricks of production.
Glaze uses formula as below：Feldspar:45 parts, kaolin:12 parts, dolomite:8 parts, lime stone:8 parts, matt it is molten
Block:28 parts, wollastonite:8 parts and zinc oxide:4 parts, 12 parts of quartz, 3 parts of talcum and high-al clay:12 parts.The material used is with natural
Based on ore raw materials, the high product of wearability is formed using the combination of formula so that existing higher not next after fabric sintering
Stone crystal content improves wearability, while having enough glass mutually to fill stomata again, improves resistance to soiling.It is built to have both porcelain
The high-wearing feature of ceramic body is built, and has the high resistance to soiling of glaze layer.
Abrasion resistance is tested：Up to super abrasive IV5 or more, it is suitble in corridor, airport, the public places such as station.
Embodiment 5：
The self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above.
By weight, wherein green body includes
Basic powder：Quartz:12 parts, flint clay:18 parts, clay:25 parts, magnesia mud:4 parts, talcum:3 parts and porcelain stone:12 parts；
It further include colorant：Black, grey：Cobalt black, gorgeous black addition are the 0.8wt% of basic powder, blue：Cobalt blue addition is base
The 0.8wt% of plinth powder, yellow:Praseodymium yellow addition is the 4wt% of basic powder, coffee：Dark brown addition is the 2wt% of basic powder.
Glaze uses formula as below：Feldspar:45 parts, kaolin:12 parts, dolomite:8 parts, lime stone:8 parts, matt it is molten
Block:28 parts, wollastonite:8 parts and zinc oxide:4 parts.Wherein zinc oxide can also select nanometer Ag as bacteriostatic agent, bacteriostatic agent2O
Or nanometer Ag2The composite material of O and nano-ZnO.
The self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above.
（1）Further, it is additionally provided with ink jet layer in the glaze layer, finishing impression ink is added in the ink used in ink jet layer,
The finishing impression ink is made of inorganic non-metallic pigment, solvent, dispersant, bonding agent and surfactant.Pass through finishing impression ink
Colorant is introduced in water, using high-precision ink-jet technology, ion cluster is penetrated into ceramic glaze surface layer one and reacted by spray infiltration ink
Afterwards, it is allowed to act on color development with colorant, forms sagging striped, visually have more stereoscopic effect.
Wherein inorganic non-metallic pigment (colorant, glaze) is main core material, it is desirable that grain size is less than 1 micron, particle ruler
It is very little to want narrow, there cannot be strong agglomeration, have good stability, be wanted small by solvent effect.
Dispersant：It helps non-metallic pigments to be uniformly distributed in a solvent, does not reunite before ensureing early printing.Mainly one
A little water-soluble and oil-soluble high score subclass benzoic acid and its derivative class polyacrylic acid and its copolymer etc..
Bonding agent：The ceramic body or colorant for ensureing printing have certain intensity, while adjusting ink flow performance, usually
Resin can play a dual role of bonding agent and dispersant.
Surfactant：The surface tension of ink is controlled in OK range.
Other auxiliary materials have ink pH adjusting agent, drier, preservative etc..
It is exemplified below the formula of one group of specific finishing impression ink, blue ink proportioning:
Cobalt ions raw material（Cobalt oxide is ground into 1 micron of fineness raw material of nanoscale < through excessively high fineness）10-20wt%；
Solvent:80-90%, for water-soluble or oil-soluble high score subclass benzoic acid and its derivative class polyacrylic acid and its copolymer
Deng；
Dispersant: 1-2%；Such as enuatrol C17H33COONa, carboxylate, sulfuric acid（R—O—SO3Na）, sulfonate（R—
SO3Na）Deng.
Bonding agent:1-2%, resin can play a dual role of bonding agent and dispersant.
Surfactant:1-3% is (hydroxyl, sulfonic acid, carboxylic acid) hydrophilic group because of activating agent etc.
Drier:The dry oil of 1-2% cobalts（For lead borate Pb, BOsz, manganese borate Mn, BOsz, extraordinary drying oil tung oil, oxidation flax
Benevolence oil, naphthoic acid cobalt and white spirit etc.）
Preservative:0.5-2%, (polyacrylamide) can be by nonionic addition anion, cation and yin, yang hybrid ionics
And form four type products.
Ink adds finishing impression ink channel using detailed for 4 ordinary ink channels；
1. cyan：Usage amount 1.505ml/ m2
2. red：Usage amount 1.610ml/ m2
3. yellow：0.826 ml/ m of usage amount2
4. black：0.374 ml/ m of usage amount2
5. finishing impression used ink amount is 0.05-0.1ml/ m2
Twice glaze water is applied when operation, the product colour system and finishing impression that debugging needs in laboratory sink after effect, will by ink jet printer
Design needs the colour system presented to spray on glaze.After high temperature firing, nature stone effect of sinking is presented in glaze naturally.
Finishing impression ink is that one of use is further added by ink jet printer channel, is applied together with designed graphic document, usage amount according to
It is controlled according to the demand of designed graphic document, such as crack effect is presented in marble, just only increases finishing impression ink in line portion, makes
Dosage is seldom, only plays the role of decorative.
Fig. 1-3 is the self-cleaning polished bricks of entire body texture high abrasion provided by the invention.Line portion in figure centre circle is to pass through
Increase finishing impression ink treated effect, there is imitated stone material crack effect, and have it is three-dimensional sink and flash effect be presented, closer to
The product of lithotome.
The production method of the self-cleaning polished bricks of entire body texture high abrasion,
1）Cloth is automated, successively entire body cloth on halftone according to the pattern cloth being pre-designed using automation distribution device
Material；So that ceramic product, in addition to surface has texture, ceramics are internal also to have entire body texture；
2）Colorant is introduced in fabric, using high-precision ink-jet technology, ion cluster is penetrated into porcelain surface layer, made by spray infiltration ink
With colorant act on color development, form sagging striped；
3）Sintering aid is added, overglaze glazing is carried out after molding, nanometer Ag is added2The composite material of O and nano-ZnO
Finally sintering obtains the self-cleaning polished bricks of entire body texture high abrasion.
For example produce anti-lithotome（Such as marble）During, apparatus for distributing is developed first（Grid）Pattern, if
The grain effect needed is counted, the sophistication of texture depends on the making in grid, complex procedures, it is necessary to repair original text ability by multiple
It completes and marmorean natural effect.It is carried out at the same time with grid powder in press cloth, through overvoltage after completion entire body pattern
Machine is suppressed, and entire body cloth artificial marble products are completed.
The method for preparing above-mentioned polished bricks, includes the following steps：
1）Blank raw material is subjected to ball milling, is dusted, to material powder carry out grading, the toner of different colours is delivered to respectively
Feed bin, be delivered to corresponding spare feed bin after other basic powders mixing in addition to toner, then pattern as needed is adopted
Successively entire body cloth is carried out with corresponding apparatus for distributing, is suppressed to obtain green body using press after completing entire body pattern；
2）Carry out glazing after body drying, ground-coat enamel be with overglaze twice glaze pouring glaze volume be 450-500g/m altogether2；
3）Ink jet printer print pattern on glaze is used after glazing, when print pattern, the ink channel in addition to ordinary color is arranged
Outside, increase setting finishing impression ink channel, the ink of ordinary color ink channel and finishing impression ink are sprayed on glaze simultaneously；Into
Calcining kiln is sintered, and can be obtained the self-cleaning polished bricks of entire body texture high abrasion after finally carrying out mechanical polishing and edging
Further, material powder grade timing, >=20 be 0.5%, and the purpose of 20 mesh~40 is 50%, and the purpose of 40 mesh~60 is 38%,
The purpose of 60 mesh~80 is 5%, and≤80 purposes are 6.5%.
Further, the high temperature hot gas in the calcining kiln, which is adopted, is piped to drying kiln, and green body is obtained for suppressing
Drying；Cleaner is set, and the post that dust is generated to production is dusted, and obtained dust recycles profit through water treatment deposition
With.
It obtains in embodiment 5, wearing coefficient anion test in IV5 or more, air is 4000-7000（A/ml）, put
It is 800-1000 that penetrating property, which tests anion number,（A/ml）.
Claims (10)
1. the self-cleaning polished bricks of entire body texture high abrasion, including green body and glaze layer above, which is characterized in that green body includes by weight
The following raw material of part meter：Quartz:10-15 parts, flint clay:15-20 parts, clay:20-30 parts, magnesia mud:3-5 parts, talcum:2-3
Part and porcelain stone:10-15 parts, the toner of 5-10wt% is also added in green body；Glaze layer includes ground-coat enamel and overglaze, contains in overglaze and presses
The following raw material of parts by weight meter：Feldspar:40-50 parts, kaolin:10-15 parts, dolomite:5-10 parts, lime stone:5-10 parts, Asia
Light frit:25-30 parts, wollastonite:5-10 parts and zinc oxide:3-5 parts.
2. polished bricks according to claim 1, it is characterised in that：Ink jet layer is additionally provided in the glaze layer, used in ink jet layer
Ink in be added to finishing impression ink, the finishing impression ink uses inorganic non-metallic pigment, solvent, dispersant, bonding agent and table
Face activating agent is made.
3. polished bricks according to claim 2, it is characterised in that：The grain size of the inorganic non-metallic pigment is less than 1 micron.
4. polished bricks according to claim 2, it is characterised in that：In the finishing impression ink also contain ink pH adjusting agent,
One or more of drier, preservative.
5. polished bricks according to claim 1, it is characterised in that：The toner include cobalt black and/or it is black 0.5-1 parts gorgeous,
0.5-1 parts of cobalt blue, 3-5 parts of praseodymium yellow and 1-3 parts dark brown.
6. polished bricks according to claim 1, it is characterised in that：Also contain 10-15 parts of quartz, talcum 2- in the overglaze
3 parts and high-al clay:10-15 parts.
7. the method for making polished bricks described in claim 1-6 any one, which is characterized in that include the following steps：
1）Blank raw material is subjected to ball milling, is dusted, to material powder carry out grading, the toner of different colours is delivered to respectively
Feed bin, be delivered to corresponding spare feed bin after other basic powders mixing in addition to toner, then pattern as needed is adopted
Successively entire body cloth is carried out with corresponding apparatus for distributing, is suppressed to obtain green body using press after completing entire body pattern；
2）It carries out applying ground-coat enamel and overglaze processing after body drying；
3）Ink jet printer print pattern on glaze is used after glazing, when print pattern, the ink channel in addition to ordinary color is arranged
Outside, increase setting finishing impression ink channel, the ink of ordinary color ink channel and finishing impression ink are sprayed on glaze simultaneously；Into
Calcining kiln is sintered, and can be obtained the self-cleaning polished bricks of entire body texture high abrasion after finally carrying out mechanical polishing and edging.
8. according to the method described in claim 7, it is characterized in that：Material powder grade timing, >=20 be 0.5%, 20 mesh~40
Purpose is 50%, and the purpose of 40 mesh~60 is 38%, and the purpose of 60 mesh~80 is 5%, and≤80 purposes are 6.5%.
9. according to the method described in claim 7, it is characterized in that：The ink channel of the ordinary color is respectively cyan, red
Color, yellow and black.
10. according to the method described in claim 7, it is characterized in that：High temperature hot gas in the calcining kiln uses pipeline
To drying kiln, the drying of green body is obtained for suppressing；Cleaner is set, and the post that dust is generated to production is dusted, and is obtained
To dust recycled through water treatment deposition.
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| CN112225451A (en) * | 2020-10-27 | 2021-01-15 | 佛山欧神诺陶瓷有限公司 | Polished porcelain tile and preparation method thereof |
| CN112552024A (en) * | 2020-12-24 | 2021-03-26 | 马鞍山钢铁股份有限公司 | Coke oven safety channel identification brick and preparation method thereof |
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| CN115594526A (en) * | 2022-12-14 | 2023-01-13 | 佛山市道氏科技有限公司（Cn） | Glaze combination and ceramic tile with latticed concave-convex grain effect |
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