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CN108675694A - A kind of morning weather-proof geo-polymer pervious concrete by force - Google Patents

A kind of morning weather-proof geo-polymer pervious concrete by force Download PDF

Info

Publication number
CN108675694A
CN108675694A CN201810492744.8A CN201810492744A CN108675694A CN 108675694 A CN108675694 A CN 108675694A CN 201810492744 A CN201810492744 A CN 201810492744A CN 108675694 A CN108675694 A CN 108675694A
Authority
CN
China
Prior art keywords
parts
pervious concrete
geo
proof
force
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810492744.8A
Other languages
Chinese (zh)
Inventor
刘裕
刘明乐
孙文
候双双
辛继宝
王凯
黄亚林
罗建
张杰辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENZHEN GANGCHUANG BUILDING MATERIAL CO Ltd
Original Assignee
SHENZHEN GANGCHUANG BUILDING MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENZHEN GANGCHUANG BUILDING MATERIAL CO Ltd filed Critical SHENZHEN GANGCHUANG BUILDING MATERIAL CO Ltd
Priority to CN201810492744.8A priority Critical patent/CN108675694A/en
Publication of CN108675694A publication Critical patent/CN108675694A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2023Resistance against alkali-aggregate reaction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention discloses a kind of morning, and weather-proof geo-polymer pervious concrete, in parts by weight meter include by force:40 50 parts of slag, 25 45 parts of blast-furnace cinder, 10 20 parts of zeolite, 5 10 parts of silicon ash, 15 parts of nano-calcium carbonate, 0.1 0.5 parts of water-reducing agent, 36 parts of exciting agent, 400 500 parts of stone, 33 40 parts of water.Pervious concrete early strength of the present invention is high, and 3d compression strength plays 60% or more, and 28d compression strength is more than 30MPa, meets the requirement of C25 pervious concretes.The present invention not only has excellent water penetration, and early strength is high, also relatively low to curing condition requirement, avoids the drawbacks such as dusting;Accumulation of salt in the surface soil problem existing for geo-polymer is inhibited to a certain extent simultaneously.The present invention quickly propels offer technical support for " sponge city ".

Description

A kind of morning weather-proof geo-polymer pervious concrete by force
Technical field
The present invention relates to concrete field, more particularly to weather-proof geo-polymer pervious concrete by force of a kind of morning.
Background technology
Pervious concrete is a kind of special concrete, is generally made of bonding agent, coarse aggregate, water and additive, through special Inside prepared by technique includes continuous aperture and the engineering material with high water seepage function, can be used for Water warfare, permeable road Face, acoustic absorption and other civil engineerings.Currently, pervious concrete is divided into cement pervious concrete and the permeable coagulation of macromolecule Soil:(1) cement pervious concrete is made simply, at low cost, durability is good, is current using portland cement as cementitious material The maximum a kind of pervious concrete of dosage, but the hydration and hardening of cement is strong to humidity, the temperature dependency of maintenance, and it is permeable mixed For solidifying soil due to porous structure characteristic, water holding capacity is poor, the low strength in the case where maintenance should not ensure, it is difficult to solve intensity and Contradiction between coefficient of permeability;Simultaneously portland cement resources of production, energy consumption is big, environmental pollution is serious, from environmentally friendly angle Degree considers, needs to find more suitably cementitious material and cement is replaced to make pervious concrete.(2) macromolecule pervious concrete be with Macromolecule is as cementitious material.The pervious concrete includes mainly pitch pervious concrete, two kinds of resin pervious concrete.Pitch Permeable concrete is compared with cement pervious concrete, this kind of pervious concrete intensity is high, but pitch is as organic cementitious material It is poor to the adaptability of weather, it is easier aging under the influence of air, especially when temperature is promoted, the permeable coagulation of pitch Soil can soften, and bituminous liquids can be caused to flow out, and the intensity and water penetration for eventually leading to pervious concrete all reduce, in addition cost phase To higher;Resin permeable concrete is compared with pitch pervious concrete, cement pervious concrete, its more water proof and wearable, but Its is of high cost, while easy to aging.
It can be seen that a kind of significance of research and development novel morning weather-proof geo-polymer pervious concrete by force, base of the present invention It is researched and developed in this.
Invention content
For the existing limitation of traditional pervious concrete (cement pervious concrete, macromolecule pervious concrete) and insufficient, In conjunction with the characteristics of mineral polymer and advantage, the present invention proposes a kind of morning weather-proof geo-polymer pervious concrete by force, with alkali Excitation steel slag polymer is cementitious material, is the technical thought gathered materials and prepare pervious concrete with simple grain grade aggregate, it is intended to solve Pervious concrete curing condition requires height, and early strength is low, is easy to dusting, and the technical barriers such as weatherability difference are " sponge city " Offer technical support is be provided.
To realize that above-mentioned target, the specific technical solution of the present invention are as follows:
A kind of morning, weather-proof geo-polymer pervious concrete, in parts by weight meter included by force:40-50 parts of slag, Blast Furnace Ore 25-45 parts of slag, 10-20 parts of zeolite, 5-10 parts of silicon ash, 1-5 parts of nano-calcium carbonate, 0.1-0.5 parts of water-reducing agent, 3-6 parts of exciting agent, 400-500 parts of stone, 33-40 parts of water.
Preferably, concrete 3d compression strength plays 60% or more, and 28d compression strength is more than 30MPa.
Preferably, the slag is after grinding, specific surface area 330m2/ kg or more, blast-furnace cinder grade are S95 grades, SiO in silicon ash2Content at least 85%.
Preferably, the nano-calcium carbonate particle size range is between 20-60nm.
Preferably, the zeolite is 5A zeolites, is to use Ca2+Na during exchange 4A is zeolite structured+It is obtained that there is the apertures 5A Type A zeolite.
Preferably, the exciting agent is waterglass, can adjust modulus by alkali metal hydroxide.
Preferably, the stone is single particle size rubble.
Preferably, the water-reducing agent is naphthalene system or polycarboxylate water-reducer, 15% or more water-reducing rate.
The present invention uses main raw material(s) of the slag as pervious concrete, effectively improves the utilization of trade waste Value, alleviates environmental pressure;The incorporation of zeolite, reduces the degree of the geo-polymer accumulation of salt in the surface soil, and high-silicon high aluminium contributes to The promotion of water coagulation soil intensity;The incorporation of silicon ash improves the density of concrete;Nano-calcium carbonate can not only be accelerated to react Process improves early strength, can also be effectively increased whole consistency, reduces cement amount.The permeation coefficient of permeable concrete is high, The features such as early strength is big, low to curing condition requirement, and later strength is high, reducing causes since pervious concrete maintenance is not in place Dusting, the problems such as intensity is low.
Using the above scheme, the invention has the advantages that:
Early strength is high, and 3d compression strength plays 60% or more, and 28d compression strength is more than 30MPa, and it is permeable mixed to meet C25 Coagulate the requirement of soil.The present invention not only has excellent water penetration, and early strength is high, also relatively low to curing condition requirement, has avoided The drawbacks such as sand;Accumulation of salt in the surface soil problem existing for geo-polymer is inhibited to a certain extent simultaneously.The present invention is " sponge city " Offer technical support is be provided.
Specific implementation mode
Below in conjunction with specific embodiment, the present invention is further described.
A kind of weather-proof geo-polymer pervious concrete by force of morning provided by the invention, component include slag, blast-furnace cinder, Zeolite, silicon ash, nano-calcium carbonate, water-reducing agent, exciting agent, single particle size rubble, water.
Water-reducing agent, exciting agent and half water are poured into ultrasonic cleaning machine, ultrasonic 30s, are made mixed liquor, while by steel Slag, blast-furnace cinder, zeolite, silicon ash are put into agitated kettle stir 60s in proportion, mixed liquor are poured into agitated kettle stirring, residue Water pour into and stir 120s in pot, mixture is die-filling, 2MPa hydrostatic profiles, conserves form removal after 20-24h, and natural curing is to providing Age.
Embodiment 1-3 (corresponding serial number 1-3) is as follows:
1 embodiment match ratio of table
Above-mentioned selection specific surface area is 330m2The slag of/kg;S95 grades of blast-furnace cinder;Specific surface area is 1150m2/ kg's 5A zeolites;Specific surface area is 20m2The silicon ash of/g;Average grain diameter is the nano-calcium carbonate of 30nm;Exciting agent is waterglass and alkali gold Belong to the mixture of hydroxide, modulus is 1.0 moulds;Water-reducing agent is pulvis naphthalene water reducer, and diminishing efficiency is 20%;Particle size range For the single particle size stone of 5~10mm;Water is use for laboratory tap water.
2 experimental result of table
Pervious concrete early strength height of the present invention is can be seen that by the data comparison of table 1-2,3d compression strength plays 60% or more, 28d compression strength are more than 30MPa, meet the requirement of C25 pervious concretes.
The foregoing is merely the preferred embodiment of the present invention, are not intended to limit the scope of the invention, every at this Under the inventive concept of invention, using equivalent structure transformation made by present specification, or directly/it is used in other indirectly Relevant technical field is included in the scope of patent protection of the present invention.

Claims (8)

1. a kind of weather-proof geo-polymer pervious concrete by force of morning, which is characterized in that meter includes in parts by weight:Slag 40-50 Part, 25-45 parts of blast-furnace cinder, 10-20 parts of zeolite, 5-10 parts of silicon ash, 1-5 parts of nano-calcium carbonate, 0.1-0.5 parts of water-reducing agent swash Send out 3-6 parts of agent, 400-500 parts of stone, 33-40 parts of water.
2. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that concrete 3d is anti- Compressive Strength plays 60% or more, and 28d compression strength is more than 30MPa.
3. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that the slag passes through After grinding, specific surface area 330m2/ kg or more, blast-furnace cinder grade are S95 grades, SiO in silicon ash2Content at least 85%.
4. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that the nano-calcium carbonate Calcium particle size range is between 20-60nm.
5. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that the zeolite is 5A Zeolite is to use Ca2+Na during exchange 4A is zeolite structured+Type A zeolite obtained with the apertures 5A.
6. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that the exciting agent is Waterglass can adjust modulus by alkali metal hydroxide.
7. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that the stone is single One Stone.
8. morning according to claim 1 weather-proof geo-polymer pervious concrete by force, which is characterized in that the water-reducing agent is Naphthalene system or polycarboxylate water-reducer, 15% or more water-reducing rate.
CN201810492744.8A 2018-05-22 2018-05-22 A kind of morning weather-proof geo-polymer pervious concrete by force Pending CN108675694A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810492744.8A CN108675694A (en) 2018-05-22 2018-05-22 A kind of morning weather-proof geo-polymer pervious concrete by force

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810492744.8A CN108675694A (en) 2018-05-22 2018-05-22 A kind of morning weather-proof geo-polymer pervious concrete by force

Publications (1)

Publication Number Publication Date
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110606720A (en) * 2019-10-08 2019-12-24 浙江天地环保科技有限公司 Preparation method of high-content fly ash-based water permeable brick
CN112374811A (en) * 2020-11-09 2021-02-19 湛江宝钢新型建材科技有限公司 Pervious concrete prepared from steel slag and preparation method and application thereof
CN113698170A (en) * 2021-09-08 2021-11-26 纳思同(无锡)科技发展有限公司 High-performance pervious concrete rapid repairing material and preparation method and application thereof
CN114907081A (en) * 2022-05-05 2022-08-16 同济大学 Anti-efflorescence aluminate cement mortar and preparation method thereof
CN115893887A (en) * 2022-12-07 2023-04-04 西北民族大学 Alkali-activated composite industrial waste residue cement mortar test block and preparation method of pervious concrete
CN116903312A (en) * 2023-08-07 2023-10-20 广东工业大学 Low-carbon ultra-high performance engineering geopolymer composite material and preparation method and application thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110606720A (en) * 2019-10-08 2019-12-24 浙江天地环保科技有限公司 Preparation method of high-content fly ash-based water permeable brick
CN112374811A (en) * 2020-11-09 2021-02-19 湛江宝钢新型建材科技有限公司 Pervious concrete prepared from steel slag and preparation method and application thereof
CN113698170A (en) * 2021-09-08 2021-11-26 纳思同(无锡)科技发展有限公司 High-performance pervious concrete rapid repairing material and preparation method and application thereof
CN114907081A (en) * 2022-05-05 2022-08-16 同济大学 Anti-efflorescence aluminate cement mortar and preparation method thereof
CN115893887A (en) * 2022-12-07 2023-04-04 西北民族大学 Alkali-activated composite industrial waste residue cement mortar test block and preparation method of pervious concrete
CN116903312A (en) * 2023-08-07 2023-10-20 广东工业大学 Low-carbon ultra-high performance engineering geopolymer composite material and preparation method and application thereof
CN116903312B (en) * 2023-08-07 2024-01-26 广东工业大学 Low-carbon ultra-high performance engineering geopolymer composite material and preparation method and application thereof

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Application publication date: 20181019