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CN108660517A - The energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind and its production technology - Google Patents

The energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind and its production technology Download PDF

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Publication number
CN108660517A
CN108660517A CN201710828910.2A CN201710828910A CN108660517A CN 108660517 A CN108660517 A CN 108660517A CN 201710828910 A CN201710828910 A CN 201710828910A CN 108660517 A CN108660517 A CN 108660517A
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Prior art keywords
ammonia
liquefied ammonia
water
ramie
keen
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曾庆福
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Individual
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Priority to CN201710828910.2A priority Critical patent/CN108660517A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C1/00Treatment of vegetable material
    • D01C1/04Bacteriological retting
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01BMECHANICAL TREATMENT OF NATURAL FIBROUS OR FILAMENTARY MATERIAL TO OBTAIN FIBRES OF FILAMENTS, e.g. FOR SPINNING
    • D01B1/00Mechanical separation of fibres from plant material, e.g. seeds, leaves, stalks
    • D01B1/10Separating vegetable fibres from stalks or leaves
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C1/00Treatment of vegetable material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • D06B19/0005Fixing of chemicals, e.g. dyestuffs, on textile materials
    • D06B19/0029Fixing of chemicals, e.g. dyestuffs, on textile materials by steam
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • D06B23/205Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for adding or mixing constituents of the treating material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • D06B23/22Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for heating
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/02Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • D06P3/66Natural or regenerated cellulose using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Mechanical Engineering (AREA)
  • Coloring (AREA)

Abstract

The invention discloses collection degummings, denaturation, it is modified, dye the energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind in one, mainly including ramee without useless degumming system, ammonia bath denaturation coloring system, liquefied ammonia dyeing residual liquid evaporates recovery system, NH_3 leakage security system and drawing-off washing are at a system, ammonia bath denaturation coloring system is mainly by refrigerated constant temperature system, feeding cycle system, keep the temperature liquefied ammonia dye vat and control system composition, liquefied ammonia dyeing residual liquid evaporates recovery system mainly by raffinate evaporator, refrigeration coil, freezer, refrigeration machine and liquefied ammonia storage cylinder fitted composition, drawing-off washing is at system by into numb crawler belt, roll, upper antiwind water knife, under antiwind water knife, hold in the palm fishplate bar, sink, crawler type dryer, loose formula winding mechanism, roller motor and control system composition.The invention also discloses the production technology of above-mentioned energy saving and environment friendly keen-witted and capable ramie stripes production system, the invention is at low cost, efficient and good spinnability, energy conservation and environmental protection.

Description

The energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind and its production technology
Technical field
The invention belongs to technical field of textile processing, are related to degummed ramie fiber production and processing, specifically a kind of energy conservation and environmental protection The keen-witted and capable ramie stripes production system of type and its production technology.
Background technology
The production of ramie item refers to ramie by degumming, strikes fiber crops, washes the multiple working procedures such as fiber crops, bleaching, washing, drying by degummed ramie It is processed into staple in bulk.
In existing degumming technology, chemical Degumming technology has forbidden producing because seriously polluted;Biological bacteria degumming lack of homogeneity, it is residual Glue rate is high, and the time is long;Biological enzyme degumming is then of high cost, and strength damage is big, and single technique is difficult to meet a point fine requirement;Bioid Learning combination degumming, then water consumption is big, of high cost, and pollution is big.
In existing degummed ramie production technology, it is essential process to strike fiber crops, and striking fiber crops makes fiber point fibre, but fibre damage Greatly, different in size, fiber is disorderly and unsystematic, and labor intensity is big, and working environment is severe, and efficiency is low, strikes fiber crops to follow-up comb fiber crops etc. It makes troubles, chaotic fiber is easy struck wound, broken, and causes card yield low.
Existing ramie staple in bulk alkaline denaturation technology can improve the soft right degree of ramee, improve spinnability and stainability, But since alkali consumption is big, soda is difficult, and energy consumption water consumption is high, and pollution is big.
Since viscosity and surface tension the ratio water of liquefied ammonia are low, great penetration, it is easy to which penetrating into fiber makes fiber knot Brilliant degree changes, while not damaging fiber again, and can rapidly and easily ooze out, and improves fiber flexibility, alternative alkali silk Light technology, more is used in cotton fabric final finishing.Existing liquid ammonia mercerization and liquid ammonia finishing technology open body in air It is handled in system, but since liquefied ammonia is toxic, evaporation rate is fast at room temperature, liquefied ammonia is lumped together rapidly with air, is needed closed Reaction and retracting device, production equipment is very huge, and very expensive, and input and operating cost are very high.
Invention content
The purpose of the present invention is to provide a kind of energy saving and environment friendly keen-witted and capable ramie stripes production system and its production technologies, will be without useless Biological degumming technology, ammonia bath alkaline denaturation technology and drawing-off washing process are combined, and integrate degumming, denaturation, modification, dyeing, The relevant issues proposed in background technology are solved, row yielding height, energy-saving and environment-friendly keen-witted and capable ramie stripes production technology and method are formed.
To achieve the above object, the present invention provides the following technical solutions:
A kind of energy saving and environment friendly keen-witted and capable ramie stripes production system includes mainly ramee without useless degumming system, ammonia bath denaturation At a system, the ramie is fine for coloring system, liquefied ammonia dyeing residual liquid evaporation recovery system, NH_3 leakage security system and drawing-off washing Dimension includes large capacity storage bacterium pond, retted fibre cylinder, rinsing cylinder and biological treatment of waste water system, the ammonia bath denaturation dye without the degumming system that gives up Colour system system is mainly made of refrigerated constant temperature system, feeding cycle system, heat preservation liquefied ammonia dye vat and control system, the liquefied ammonia dye Color raffinate evaporation recovery system is mainly made of raffinate evaporator, refrigeration coil, freezer, refrigeration machine and liquefied ammonia storage cylinder fitted, The NH_3 leakage security system mainly by ammonia leakage alarm, pressure release with overvoltage protective system, spray-absorption system and Accident pool is constituted, drawing-off washing at system by into numb crawler belt, roll, upper antiwind water knife, under antiwind water knife, support connect Plate, sink, crawler type dryer, loose formula winding mechanism, roller motor and control system composition.
As a further solution of the present invention:The ramee stores up bacterium pond and retted fibre without the large capacity in useless degumming system Cylinder is coupled with pipeline and mud stick, bacterium solution closed cycle, and rinsing cylinder is connected with pipeline and water pump with biological treatment of waste water system.
As further scheme of the invention:Refrigerated constant temperature system in ammonia bath denaturation coloring system by freezer, Refrigeration coil, evaporation liquefied ammonia surge tank and refrigeration unit at;Freezer is connected by stainless steel pipes with evaporation liquefied ammonia surge tank, then It is connect with liquefied ammonia dye vat;Safety valve is installed, refrigeration coil and heat sink pipe are installed in freezer above liquefied ammonia surge tank.
As further scheme of the invention:Feeding cycle system ammonia pump in ammonia bath denaturation coloring system, Material bucket and valve pipe composition;It is connected with liquefied ammonia dye vat by stainless steel pipes at the top of material bucket.
As further scheme of the invention:In drawing-off washing sett frame antiwind water knife by booster pump, can revolve Turn flat burner and pipeline composition;Antiwind water knife is tangentially mounted on the upper and lower of rubber roller.
A kind of production technology based on above-mentioned energy saving and environment friendly keen-witted and capable ramie stripes production system, steps are as follows:
S1, ramee are without useless degumming
1) superior complex strain is built:Dominant microflora in concentrate after being impregnated 30 days with fresh raw ramie, it is simultaneous with hemp skin boon The dominant microflora mixing that aerobe fermentation generates, then to add part white-rot fungi compound, most does culture medium domestication culture through raw ramie afterwards, with The pond accumulation of large capacity storage bacterium stores for future use.
2) retting is macerated:Raw ramie fills basket, lifting enter impregnate plus bacterium retted fibre cylinder (or pond) in, mixed bacteria liquid is added to complete Flaxen fiber is submerged, is heated up to 40 DEG C or so, is maintained 4-8 hours, interior cycle is kept the temperature;Then, stop heat preservation, open retted fibre cylinder and storage Bacterium pond cross over pipe starts outer circulation 4-16 hours with small flow, and degumming raffinate is then all discharged into storage bacterium pond, and add-back is washed with water It washs once, and washing raffinate is discharged into storage bacterium pond again.
3) it rinses:Flaxen fiber basket lifts in rinsing cylinder after retting will be macerated, abundant with recycle-water after biological wastewater treatment Washing, waste water is discharged into wastewater equalization pond after washing, and closed cycle is realized with biological treatment of waste water system;After primary wash, add Enter hydrogen peroxide bleaching liquor, drift is soaked with room temperature or high-temperature boiling is bleached;Then after being washed with recycle-water, water squeezing is dried.
S2, ammonia bath denaturation dyeing
1) first the ramee basket after biological bacteria retted fibre, degumming, bleaching is lifted in liquefied ammonia dye vat, sealing vacuumizes de- Water.
2) fibre weight 1 is pressed:10 to 1:20 bath raio is pumped into liquefied ammonia to fiber and is completely submerged in liquefied ammonia bath, recycles 2-5 Minute, maintain temperature between -35 DEG C to -45 DEG C.
3) the NaOH aqueous solutions of 150-300g/L are pumped into, addition maintains temperature to exist between the 2-10% of fibre weight It 35 DEG C -45 DEG C, recycles 10-40 minutes.
4) modifying agent is added in liquefied ammonia denaturation staining jar, is recycled 5-30 minutes.
5) according to finished product coloration requirements, adaptable aqueous dye solutions are added, recycle 5-30 minutes.
6) raffinate that liquefied ammonia is denaturalized in staining jar is all drained into liquefied ammonia dyeing residual liquid and evaporates recovery system, and vacuumized Remove the ammonia of fiber surface absorption.
7) air is injected, ammonia to the ammonia spray absorber for extracting fiber surface absorption again absorbs ammonia.
8) it opens liquefied ammonia and is denaturalized staining jar, ramee basket is moved into decatize 20-40 minutes, then 90 DEG C in boiling steam box Above hot water, which boils, to be washed 20-40 minutes, is boiled the hot waste water after washing and is discharged into after heat exchange in air supporting or coagulative precipitation tank and handles Afterwards, supernatant is discharged into biological treatment of waste water system.
9) ramee basket is hung out, sett frame is washed into ramee beam splitting feeding drawing-off.
S3, drawing-off washing are at item
1) the ramee beam splitting after bleachinging and dyeing be laid in drawing-off washing sett frame on numb crawler belt, overlap end to end, phase Press 30cm or so.
2) ramee of beam splitting tiling enters rubber roller extruding, and antiwind water knife prevents flaxen fiber from winding rubber roller While, hydroblasting flaxen fiber, ramee gold feeds next group of rubber roller through support fishplate bar, then through squeezing, antiwind water Knife hydroblasting so repeats 5-10 groups;Speed per next group of rubber roller than upper one group of rubber roller improves 5%-10%. Last group of rubber roller does not use antiwind water knife and uses brush roll antiwind.
3) the ramie item that moisture is extracted through last group of rubber roller is fallen in crawler type dryer on numb crawler belt, is entered Drying chamber is dried.
4) the ramie item after drying is through loose formula up- coiler clot.
As a further solution of the present invention:The drawing-off washes sett frame breadth between 80cm-1200cm.
Compared with prior art, the beneficial effects of the invention are as follows:
1, compared with existing biological degumming technology, bacterium is stored up with large capacity storage bacterium pond so that the compound bacteria of retted fibre cylinder is added The vigor of group is relatively uniform, to keep degumming etc. relatively controllable, has not only given storage bacterium pond to provide culture medium, but also give waste water treatment system Reduce load;Water scouring water and biological wastewater treatment system closed cycle have not only saved and have used water, but also realize pollution zero-emission It puts.
2, compared with existing alkaline denaturation technology, ammonia bath alkaline denaturation can be reduced with alkali 90% or so, and once plus alkali, three kinds Purposes, i.e. alkali degumming, alkaline denaturation, reactive dyeing.The composite waste amount of generation is small, and is easy to through air supporting or coagulating sedimentation Processing, thus greatly reduces disposal of pollutants.
3, compared with numb technology is struck in existing degumming, sett frame is washed in drawing-off using the present invention, and fiber length is uniform, point fibre Thoroughly, row yielding is high, is easy to comb system, spinning, and washing efficiency is high.
4, compared with existing liquid ammonia mercerization and liquid ammonia finishing technology, ammonia of the invention bath denaturation dyeing course is closed It maintains in container and is run under -35 DEG C to -45 DEG C of low-temperature condition, in ammonia bath, degumming is realized with a bath the more footwork, is become Property, modification, multiple purposes such as dyeing, No leakage, no air enters.Temperature range of the special liquefied ammonia raffinate recovery system at 10 DEG C Recycling cycle that is interior, realizing the evaporation of liquefied ammonia raffinate and condense again, and the evaporation of recovery system, condensation process can be with freezer systems The heat dissipation of cooling system, process of refrigerastion carry out heat transfer coupling, further decrease recycling operating cost.
5, degummed ramie ramie stripes production technology of the invention integrates degumming, denaturation, modification, dyeing, ammonia alkali collaboration denaturation Ramee is set fully to expand, Xie Jing, disorientation reduces fiber rigidity, improves spinnability, dye-uptake, reduces Yarn filoplume;Liquid Ammonia bath dyeing, dyestuff hydrolysis is few, and upper dye is uniform, and modified dose of fiber is modified, and absorption property and reactivity worth greatly improve, After vapour steaming colour fixing, unadsorbed upper dye, non-fixing dyes are few, and therefore, dye dosage is small, and tinctorial yield is high, and contaminated wastewater is substantially It reduces;The fine washing of tension draft point is washed at item without striking, and point fine effect, washing efficiency is high, applies softening agent, substitution before drying The linen softening oil of the prior art, fiber is more compliant, convenient for combing and spinning.
The technology of the present invention realizes recovery ammonia, and water reuse, alkali, dyestuff and dyeing assistant dosage be greatly reduced, be it is a kind of it is low at This, the environmental protection dyeing degummed ramie ramie stripes production technology of high-quality.
Description of the drawings
Fig. 1 is the technique stream that liquefied ammonia is denaturalized coloring system in energy saving and environment friendly keen-witted and capable ramie stripes production system and its production technology Cheng Tu;
Fig. 2 is that the structure of liquefied ammonia denaturation coloring system in energy saving and environment friendly keen-witted and capable ramie stripes production system and its production technology is shown It is intended to;
Fig. 3 is that liquefied ammonia dyeing residual liquid evaporates recovery system in energy saving and environment friendly keen-witted and capable ramie stripes production system and its production technology Structural schematic diagram;
Fig. 4 is the side view that sett frame is washed in drawing-off in energy saving and environment friendly keen-witted and capable ramie stripes production system and its production technology;
Fig. 5 is the vertical view that sett frame is washed in drawing-off in energy saving and environment friendly keen-witted and capable ramie stripes production system and its production technology.
In figure:1- freezers;2- refrigeration machines;3- refrigeration coils;4- radiator coil tubes;5- liquefied ammonia storage cylinder fitteds;6- liquefied ammonia dye vats; 7- fiber crops frames;8- pressure gauges;9- vacuum pumps;10- ammonia pumps;11- material buckets;12- evaporates liquefied ammonia surge tank;13- raffinate evaporators; 14- sewage draining exits;15- is into numb crawler belt;16- rolls;The upper antiwind water knives of 17-;18- sinks;Antiwind water knife under 19-;20- supports connect Plate;The antiwind hairbrush of 21-;22- crawler type dryers;23- drying chambers;24- roller motors;25- thermometers;26- pine formula up- coilers Structure;The evaporation of 27- ammonias absorbs perforated pipe.
Specific implementation mode
Technical scheme of the present invention is described in more detail With reference to embodiment.
- 5 are please referred to Fig.1, a kind of energy saving and environment friendly keen-witted and capable ramie stripes production system includes mainly ramee without useless degumming system System, ammonia bath denaturation coloring system, liquefied ammonia dyeing residual liquid evaporation recovery system, NH_3 leakage security system, boiling steam box and drawing-off water Wash into a system.
The ramee includes large capacity storage bacterium pond, retted fibre cylinder, rinsing cylinder and biological wastewater treatment without useless degumming system System, large capacity storage bacterium pond are coupled with retted fibre cylinder with pipeline and mud stick, bacterium solution closed cycle;Large capacity storage bacterium pond volume ratio is macerated Big 100 times of numb cylinder or more;Rinsing cylinder is connected with pipeline and water pump with biological treatment of waste water system, and rinsing cylinder water outlet is discharged into waste water life Regulating reservoir in object processing system, secondary clarifier effluent is used as rinsing water after filtering in biological treatment of waste water system..
Ammonia bath denaturation coloring system mainly by refrigerated constant temperature system, feeding cycle system, heat preservation liquefied ammonia dye vat and Control system forms, and the refrigerated constant temperature system is made of freezer 1, refrigeration coil 3, evaporation liquefied ammonia surge tank 12 and refrigeration machine 2; The feeding cycle system ammonia pump 10, material bucket 11 and valve pipe composition, freezer 1 pass through stainless steel pipes and evaporation liquefied ammonia Surge tank 12 is connected, then is connect with liquefied ammonia dye vat 6;12 top of liquefied ammonia surge tank is installed by safety valve, the automatic release of overvoltage to liquefied ammonia Spray absorber;Refrigeration coil 3 and heat sink pipe 4 are installed in freezer, and the top of material bucket 11 by stainless steel pipes with Liquefied ammonia dye vat 6 is connected, and the dye liquor of material bucket can be not only pumped into liquefied ammonia dye vat by ammonia pump 10, furthermore, it is possible to realize liquefied ammonia The closed cycle of dye liquor in dye vat.
The liquefied ammonia dyeing residual liquid evaporation recovery system is mainly by raffinate evaporator 13, refrigeration coil 3, freezer 1, refrigeration Machine 2 and liquefied ammonia storage cylinder fitted 5 form.
The NH_3 leakage security system is mainly inhaled by ammonia leakage alarm, pressure release and overvoltage protective system, spray Receipts system and accident pool are constituted.
Drawing-off washing at system by into numb crawler belt 15, roll 16, upper antiwind water knife 17, under antiwind water knife 18, fishplate bar 20, sink 18, crawler type dryer 22, loose formula winding mechanism 26, roller motor 24 and control system composition is ask to prevent Winding water knife is by booster pump, rotatable flat burner, the compositions such as pipeline;Antiwind water knife is tangentially mounted on rubber roller Upper and lower.
One kind being based on above-mentioned energy saving and environment friendly keen-witted and capable ramie stripes production system, and steps are as follows:
S1, ramee are without useless degumming
1) superior complex strain is built:Dominant microflora in concentrate after being impregnated 30 days with fresh raw ramie, it is simultaneous with hemp skin boon The dominant microflora mixing that aerobe fermentation generates, then to add part white-rot fungi compound, most does culture medium domestication culture through raw ramie afterwards, with The pond accumulation of large capacity storage bacterium stores for future use.
2) retting is macerated:Raw ramie fills basket, lifting enter impregnate plus bacterium retted fibre cylinder (or pond) in, mixed bacteria liquid is added to complete Flaxen fiber is submerged, is heated up to 40 DEG C or so, is maintained 4-8 hours, interior cycle is kept the temperature;Then, stop heat preservation, open retted fibre cylinder and storage Bacterium pond cross over pipe starts outer circulation 4-16 hours with small flow, and degumming raffinate is then all discharged into storage bacterium pond, and add-back is washed with water It washs once, and washing raffinate is discharged into storage bacterium pond again.
3) it rinses:Flaxen fiber basket lifts in rinsing cylinder after retting will be macerated, abundant with recycle-water after biological wastewater treatment Washing, waste water is discharged into wastewater equalization pond after washing, and closed cycle is realized with biological treatment of waste water system.
After primary wash, hydrogen peroxide bleaching liquor is added, drift is soaked with room temperature or high-temperature boiling is bleached.
It is 15-25 DEG C (room temperature), 0.5g/L-5g/L hydrogen peroxide (H that room temperature, which soaks drift condition,2O2) and stabilizer, detergent Deng circulation immersion 4-8 hours.
It is 90-100 DEG C that high-temperature boiling, which floats condition, 0.5g/L-3g/L hydrogen peroxide (H2O2), pH is 10.5 or so, is added and stablizes Agent, detergent etc. boil drift 0.5-2 hours.
Then after being washed with recycle-water, water squeezing is dried.
S2, ammonia bath denaturation dyeing
1) first the ramee basket after biological bacteria retted fibre, degumming, bleaching is lifted in liquefied ammonia dye vat 6, sealing vacuumizes Dehydration.
2) fibre weight 1 is pressed:10 to 1:20 bath raio is pumped into liquefied ammonia to fiber and is completely submerged in liquefied ammonia bath, recycles 2-5 Minute, maintain temperature between -35 DEG C to -45 DEG C.
3) the NaOH aqueous solutions of 150-300g/L are pumped into, addition maintains temperature to exist between the 2-10% of fibre weight It 35 DEG C -45 DEG C, recycles 10-40 minutes.
4) modifying agent is added in liquefied ammonia denaturation staining jar, is recycled 5-30 minutes.
5) according to finished product coloration requirements, adaptable aqueous dye solutions are added, recycle 5-30 minutes.
6) raffinate that liquefied ammonia is denaturalized in staining jar is all drained into liquefied ammonia dyeing residual liquid and evaporates recovery system, and vacuumized Remove the ammonia of fiber surface absorption.
7) air is injected, ammonia to the ammonia spray absorber for extracting fiber surface absorption again absorbs ammonia.
8) it opens liquefied ammonia and is denaturalized staining jar, ramee basket is moved into decatize 20-40 minutes, then 90 DEG C in boiling steam box Above hot water, which boils, to be washed 20-40 minutes, is boiled the hot waste water after washing and is discharged into after heat exchange in air supporting or coagulative precipitation tank and handles Afterwards, supernatant is discharged into biological treatment of waste water system.
9) ramee basket is hung out, sett frame is washed into ramee beam splitting feeding drawing-off.
S3, drawing-off washing are at item
1) the ramee beam splitting after bleachinging and dyeing be laid in drawing-off washing sett frame on numb crawler belt, overlap end to end, phase Press 30cm or so.
2) ramee of beam splitting tiling enters rubber roller extruding, and antiwind water knife prevents flaxen fiber from winding rubber roller While, hydroblasting flaxen fiber, ramee gold feeds next group of rubber roller through support fishplate bar, then through squeezing, antiwind water Knife hydroblasting so repeats 5-10 groups;Speed per next group of rubber roller than upper one group of rubber roller improves 5%-10%. Last group of rubber roller does not use antiwind water knife and uses brush roll antiwind.
3) the ramie item that moisture is extracted through last group of rubber roller is fallen in crawler type dryer on numb crawler belt, is entered Drying chamber is dried.
4) the ramie item after drying is through loose formula up- coiler clot.
5) drawing-off washing sett frame breadth is preferred between 80cm-1200cm.
The operation principle of the present invention is that:
Raw ramie beam splitting frames up into numb frame 7, and numb frame 7 is lifted in retted fibre cylinder, and bacterium is extracted from large capacity storage bacterium pond Liquid is added in retted fibre cylinder to flaxen fiber is flooded completely, and after retted fibre to residual gum content is 10% or so, numb frame 7 is lifted into rinsing Cylinder, injects hydrogen peroxide and auxiliary agent carries out bleaching washing, until residual gum content reaches 6~8%, after draining, the dress of numb frame 7 is lifted into liquefied ammonia In dye vat 6, after closed liquefied ammonia dye vat 6, starts vacuum pump 9 and vacuumize dehydration, then, liquefied ammonia is extracted from liquefied ammonia storage steel bottle 5 It is flooded completely to flaxen fiber in numb basket 7 in injection liquefied ammonia dye vat 6, numb frame 7 and flaxen fiber in cooling liquefied ammonia dye vat 6;Heat absorption is steamed The liquefied ammonia of hair is entered by evaporating liquefied ammonia surge tank 12 in the radiator coil tube in freezer 1, the liquid being condensed in freezer 1 Ammonia is restored again into liquefied ammonia storage steel bottle 5, and the liquefied ammonia of evaporation is added from material bucket 11, to maintain the temperature of liquefied ammonia dye vat 6- Between 33 DEG C~-40 DEG C;After pure liquefied ammonia recycles 5-10 minutes in liquefied ammonia dye vat, by flaxen fiber weight in loading liquefied ammonia dye vat 6 5%-10% be added, in the NaOH aqueous solutions to material bucket 11 of 150-300g/L, from liquefied ammonia dye vat 6 extracting liquefied ammonia is added to In material bucket 11, after being mixed with the lye in material bucket 11, it is pumped into liquefied ammonia dye vat 6 through ammonia pump 10, so recycles 5-10 Minute to the lye taken away completely in material bucket 11, closes in the connecting pipe of ammonia pump 10 and material bucket 11 and liquefied ammonia dye vat 6 Valve;Then, dye solution is added in material bucket 11, is then turned on the company of ammonia pump 10 and liquefied ammonia dye vat 6 and material bucket 11 Port valve door extracts after liquefied ammonia and lye in liquefied ammonia dye vat 6 mixes with the dyestuff in material bucket 11, passes through the general of liquefied ammonia ammonia pump 10 Dye liquor is pumped into liquefied ammonia dye vat 6, so cycle 10-20 minutes;Uniformly after upper dye, the dyeing residual night in liquefied ammonia dye vat 6 (is contained into alkali And liquefied ammonia) be all discharged into raffinate evaporator 13, then, liquefied ammonia dye vat 6 is vacuumized, flaxen fiber in removal liquefied ammonia dye vat 6 The ammonia of adsorption, the ammonia extracted drain into ammonia spray absorber;Air is injected, is extracted repeatedly to flaxen fiber surface without ammonia After gas loss, liquefied ammonia dye vat 6 is opened, numb frame 7 is hung out into boiling steam box.Manually flaxen fiber beam splitting is taken out from numb frame 7 to be laid in Drawing-off wash sett frame on numb crawler belt 15, squeezed through rubber roller 16, upper antiwind water knife 17, upper antiwind water knife 19 spray Water rinses, and flushing water flows into sink 18;Through asking fishplate bar 20 to enter in next group of rubber roller 16, next group of 16 speed of rubber roller Degree increases 5-10% than upper one group of rubber roller 16, squeezes drawing-off washing through 5-10 groups rubber roller 16, then through last group of rubber Glue roll 16 is extracted, antiwind through antiwind hairbrush 21, and ramie stripes is fallen enters drying chamber 23,90-100 on crawler type dryer 22 DEG C drying;Finally, coiled through loose formula winding mechanism 26.
Liquefied ammonia dye vat 6, raffinate evaporator 13, freezer 1 are installed concentratedly in a workshop, in this workshop installation NH_3 leakage peace Insurance system.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (7)

1. a kind of energy saving and environment friendly keen-witted and capable ramie stripes production system, which is characterized in that include mainly ramee without useless degumming system, Ammonia bath denaturation coloring system, liquefied ammonia dyeing residual liquid evaporation recovery system, NH_3 leakage security system and drawing-off washing are at a system, institute It includes large capacity storage bacterium pond, retted fibre cylinder, rinsing cylinder and biological treatment of waste water system, the ammonia that ramee, which is stated, without useless degumming system Bath denaturation coloring system is mainly made of refrigerated constant temperature system, feeding cycle system, heat preservation liquefied ammonia dye vat and control system, institute It states liquefied ammonia dyeing residual liquid evaporation recovery system and steel is mainly stored by raffinate evaporator, refrigeration coil, freezer, refrigeration machine and liquefied ammonia Bottle composition, the NH_3 leakage security system is mainly by ammonia leakage alarm, pressure release and overvoltage protective system, spray-absorption System and accident pool are constituted, the drawing-off washing at system by into numb crawler belt, roll, upper antiwind water knife, under antiwind water Knife, support fishplate bar, sink, crawler type dryer, loose formula winding mechanism, roller motor and control system composition.
2. the energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind according to claim 1, which is characterized in that the ramie is fine Dimension is coupled with retted fibre cylinder with pipeline and mud stick without the large capacity storage bacterium pond in the degumming system that gives up, and bacterium solution closed cycle rinses cylinder It is connected with biological treatment of waste water system with pipeline and water pump.
3. the energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind according to claim 1, which is characterized in that the ammonia bath becomes Property coloring system in refrigerated constant temperature system by freezer, refrigeration coil, evaporation liquefied ammonia surge tank and refrigeration unit at;Freezer passes through Stainless steel pipes are connected with evaporation liquefied ammonia surge tank, then are connect with liquefied ammonia dye vat;Safety valve, refrigeration are installed above liquefied ammonia surge tank Coil pipe and heat sink pipe are installed in freezer.
4. the energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind according to claim 1, which is characterized in that the ammonia bath becomes Property coloring system in feeding cycle system ammonia pump, material bucket and valve pipe composition;Pass through stainless steel tube at the top of material bucket Road is connected with liquefied ammonia dye vat.
5. the energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind according to claim 1, which is characterized in that the drawing-off water Antiwind water knife in sett frame is washed to be made of booster pump, rotatable flat burner and pipeline;Antiwind water knife is tangentially pacified Mounted in the upper and lower of rubber roller.
6. a kind of production technology based on any energy saving and environment friendly keen-witted and capable ramie stripes production systems of claim 1-5, will be without useless Biological degumming technology, ammonia bath alkaline denaturation technology and drawing-off washing process are combined, and integrate degumming, denaturation, modification, dyeing , row yielding is high, energy-saving and environment-friendly keen-witted and capable ramie stripes production technology and method;It is characterized in that, steps are as follows:
S1, ramee are without useless degumming
1) superior complex strain is built:Dominant microflora in concentrate after being impregnated 30 days with fresh raw ramie is sent out with hemp skin boon and oxygen The dominant microflora mixing that ferment generates, then to add part white-rot fungi compound, most culture medium domestication culture is done through raw ramie afterwards, with great Rong The pond accumulation of amount storage bacterium stores for future use.
2) retting is macerated:Raw ramie fills basket, lifting enter impregnate plus bacterium retted fibre cylinder (or pond) in, mixed bacteria liquid is added to being totally submerged Flaxen fiber is heated up to 40 DEG C or so, maintains 4-8 hours, keeps the temperature interior cycle;Then, stop heat preservation, open retted fibre cylinder and storage bacterium pond Cross over pipe starts outer circulation 4-16 hours with small flow, and degumming raffinate is then all discharged into storage bacterium pond, and add-back is washed with water one It is secondary, and washing raffinate is discharged into storage bacterium pond again.
3) it rinses:Flaxen fiber basket lifts in rinsing cylinder after retting will be macerated, and is fully washed with recycle-water after biological wastewater treatment, Waste water is discharged into wastewater equalization pond after washing, and closed cycle is realized with biological treatment of waste water system;After primary wash, dioxygen is added Water bleaching liquor soaks drift with room temperature or high-temperature boiling is bleached;Then after being washed with recycle-water, water squeezing is dried.
S2, ammonia bath denaturation dyeing
1) first the ramee basket after biological bacteria retted fibre, degumming, bleaching is lifted in liquefied ammonia dye vat, sealing vacuumizes dehydration.
2) fibre weight 1 is pressed:10 to 1:20 bath raio is pumped into liquefied ammonia to fiber and is completely submerged in liquefied ammonia bath, 2-5 points of cycle Clock maintains temperature between -35 DEG C to -45 DEG C.
3) the NaOH aqueous solutions of 150-300g/L are pumped into, addition between the 2-10% of fibre weight, maintain temperature 35 DEG C- It 45 DEG C, recycles 10-40 minutes.
4) modifying agent is added in liquefied ammonia denaturation staining jar, is recycled 5-30 minutes.
5) according to finished product coloration requirements, adaptable aqueous dye solutions are added, recycle 5-30 minutes.
6) raffinate that liquefied ammonia is denaturalized in staining jar is all drained into liquefied ammonia dyeing residual liquid and evaporates recovery system, and vacuumize removal The ammonia of fiber surface absorption.
7) air is injected, ammonia to the ammonia spray absorber for extracting fiber surface absorption again absorbs ammonia.
8) it opens liquefied ammonia and is denaturalized staining jar, ramee basket is moved into decatize 20-40 minutes, then 90 DEG C or more in boiling steam box Hot water boil and wash 20-40 minutes, boil after the hot waste water after washing is discharged into air supporting or coagulative precipitation tank after heat exchange and handles, on Clear liquid is discharged into biological treatment of waste water system.
9) ramee basket is hung out, sett frame is washed into ramee beam splitting feeding drawing-off.
S3, drawing-off washing are at item
1) the ramee beam splitting after bleachinging and dyeing be laid in drawing-off washing sett frame on numb crawler belt, overlap, mutually press end to end 30cm or so.
2) ramee of beam splitting tiling enters rubber roller extruding, and antiwind water knife prevents the same of flaxen fiber winding rubber roller When, hydroblasting flaxen fiber, ramee gold feeds next group of rubber roller through support fishplate bar, then through squeezing, antiwind water knife spray Water rinses, and so repeats 5-10 groups;Speed per next group of rubber roller than upper one group of rubber roller improves 5%-10%.Finally One group of rubber roller does not use antiwind water knife and uses brush roll antiwind.
3) the ramie item that moisture is extracted through last group of rubber roller is fallen in crawler type dryer on numb crawler belt, into drying chamber Drying.
4) the ramie item after drying is through loose formula up- coiler clot.
7. the production technology of the energy saving and environment friendly keen-witted and capable ramie stripes production system according to claim 6, which is characterized in that The drawing-off washes sett frame breadth between 80cm-1200cm.
CN201710828910.2A 2017-09-14 2017-09-14 The energy saving and environment friendly keen-witted and capable ramie stripes production system of one kind and its production technology Pending CN108660517A (en)

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CN109554768A (en) * 2019-01-28 2019-04-02 东华大学 A kind of efficient biological degumming of ramie reaction system
CN110484977A (en) * 2019-07-29 2019-11-22 东华大学 A kind of flaxen fiber aerobe degumming reaction system
CN111663343A (en) * 2020-06-15 2020-09-15 杭州宙富染整有限公司 Disperse dyeing process

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CN111663343A (en) * 2020-06-15 2020-09-15 杭州宙富染整有限公司 Disperse dyeing process

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