CN108641628A - A kind of waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof - Google Patents
A kind of waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof Download PDFInfo
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- CN108641628A CN108641628A CN201810386142.4A CN201810386142A CN108641628A CN 108641628 A CN108641628 A CN 108641628A CN 201810386142 A CN201810386142 A CN 201810386142A CN 108641628 A CN108641628 A CN 108641628A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J121/00—Adhesives based on unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of non-bituminous self-adhesion sizing materials of waterproof roll, comprise the following raw materials by weight percent：C5/C9 copolymer resins 10 ~ 25%, polyisobutene 2 ~ 14%, naphthenic rubber oil 10 ~ 25%, SIS rubber 2 ~ 12%, butadiene-styrene rubber 3 ~ 14%, filler 15 ~ 35%, pigment 0.5 ~ 2.5%, auxiliary agent 4 ~ 6%.Compared with the prior art, non-bituminous base self-adhesion sizing material provided by the present invention formula design in, for the selection of PIB and C5/C9 copolymer resins ensure that coiled material in water-fast, heat-proof aging, corrosion-resistant, UV resistant performance is more excellent；Also using the SIS of high-isoprene content and the butadiene-styrene rubber of high-glue content in formula designs simultaneously can ensure that coiled material has stronger cohesive force.
Description
Technical field
The present invention relates to buildings waterproof fields, and in particular to a kind of waterproof roll non-bituminous self-adhesion sizing material and its preparation side
Method.
Background technology
Adhesive waterproof coil is not required to brush in base in construction without heating, the self-adhesive coiled material of especially wet application
Base treatment agent, construction safety is environmentally friendly, is developed in recent years than a kind of faster waterproof roll.Now answer in the market
Adhesive waterproof coil is broadly divided into asphaltic base adhesive waterproof coil and non-bituminous base adhesive waterproof coil.Asphaltic base self-adhesion is anti-
Caking property is poor under cryogenic for water coiled material；And the weatherability and water resistance of general non-bituminous base waterproof roll are poor, together
When the phenomenon that can be easily separated there is also polymer base material and adhesive polymer glue, especially remove and shows after heat ageing in coiled material
As more obvious.
Application No. is 201610462603.2 Chinese invention patents to pass through the side of addition polar resin in macromolecular sheet material
Method improves the peel strength of non-bituminous polymer membranes, changes specifically by low density polyethylene (LDPE), maleic anhydride grafting
Property polyethylene, by the precipitated calcium carbonate of silane coupling agent surface treatment, ultra-violet absorber, primary antioxidant, auxiliary anti-oxidant, hard
Macromolecular sheet material, then the melting extrusion SIS pressure-sensitive hot melt adhesives on macromolecular sheet material are arrived in the raw materials such as resin acid and iron white powder basis, most
After be covered with protective layer, so obtain non-bituminous polymer membranes.Raising of the program for the peel strength of waterproof roll
Mainly by improving polar resin --- modified by maleic acid anhydride graft polyethylene, raw material and processing cost are higher.
Invention content
To overcome existing technological deficiency, high novel of peel strength that the present invention provides a kind of between macromolecular sheet material
Waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof.
To achieve the purpose of the present invention, it is achieved using following technical scheme：
A kind of non-bituminous self-adhesion sizing material of waterproof roll, comprises the following raw materials by weight percent：C5/C9 copolymer resins
10~25%, polyisobutene 2~14%, naphthenic rubber oil 10~25%, SIS rubber 2~12%, butadiene-styrene rubber 3~14%,
Filler 15~35%, pigment 0.5~2.5%, auxiliary agent 4~6%.
Wherein, the C5/C9 copolymerized petroleum resin softening points are 90~110 DEG C, and coloration adds hydrogen C5/C9 less than No. 5
Copolymerized petroleum resin；The polyisobutene is the polyisobutene of molecular weight 1000~5000；The SIS rubber is isoamyl two
SIS rubber of the alkene content 80% or more；The butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5%
Butylbenzene solid powder rubber；Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent
For organo montmorillonite, base montmorillonite is preferably received.Red-brown powder iron oxide red may be used in the pigment, plays material dyeing and makees
With.
C5/C9 copolymerized petroleum resins are as tackifier set C5 in the formula of non-bituminous self-adhesion sizing material provided by the invention
The advantages of hydrogenation resin and C9 resins, can improve bonding force, acid resistance, alkali resistance and the water resistance of sizing material, and can
It is effectively reduced production cost；The present invention selects the polyisobutene (PIB) of specified molecular weight section, the PIB of this section to have preferably
Heat-resisting, oxytolerant, weather-proof, UV resistant, acidproof and alkali resistance；The SIS of high-isoprene content is also used in the design of this formula
The butadiene-styrene rubber of rubber and high-glue content can further improve non-bituminous self-adhesion sizing material in low temperature flexibility and adhesive property.
Further, above-mentioned waterproof roll is comprised the following raw materials by weight percent with non-bituminous self-adhesion sizing material：C5/C9
Copolymer resins 15~22%, polyisobutene 5~12%, naphthenic rubber oil 15~22%, SIS rubber 5~10%, butadiene-styrene rubber
5~10%, filler 20~30%, pigment 1~2%, auxiliary agent 3~5%.
Further, above-mentioned waterproof roll is comprised the following raw materials by weight percent with non-bituminous self-adhesion sizing material：C5/C9
Copolymer resins 17~20%, polyisobutene 7~10%, naphthenic rubber oil 17~21%, SIS rubber 7~9%, butadiene-styrene rubber 7
~9%, filler 25~27%, pigment 1.3~1.7%, auxiliary agent 3.5~4.5%.
The preparation method of above-mentioned non-bituminous self-adhesion sizing material, specifically includes following steps：
S1：The naphthenic rubber oil and polyisobutene of formula rate are added to the first reaction kettle, is then turned on stirring, heats up
To 150 DEG C of addition C5/C9 copolymer resins；
S2：After temperature rise is dissolved completely to 160 DEG C and C5/C9 copolymer resins, SIS rubber and butadiene-styrene rubber is added,
Continue to be warming up to 178~182 DEG C, then whip modified 2.5h at this temperature；
S3：The modified materials of step S2 are transferred in high shear grinding dispersion machine, high shear grinding dispersion machine is passed through
Enter the second reaction kettle after grinding distribution 40-50min, pigment, filler and auxiliary agent is added in the second reaction kettle, 160~165
Non-bituminous base self-adhesion sizing material is obtained after stirring 40~60min at DEG C.
A kind of non-bituminous base adhesive waterproof coil, using above-mentioned non-bituminous self-adhesion sizing material as self-adhesive layer.
Compared with the prior art, in the formula design of non-bituminous base self-adhesion sizing material provided by the present invention, for PIB and
The selection of C5/C9 copolymer resins ensure that coiled material in water-fast, heat-proof aging, corrosion-resistant, UV resistant performance is more excellent；Simultaneously
The SIS of high-isoprene content and the butadiene-styrene rubber of high-glue content are also used in formula designs can ensure that coiled material has more
Strong cohesive force.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, embodiment of the present invention is made below further
It explains in detail.
Embodiment 1
A kind of non-bituminous self-adhesion sizing material is present embodiments provided, is comprised the following raw materials by weight percent：
C5/C9 copolymer resins 10%, polyisobutene 14%, naphthenic rubber oil 25%, SIS rubber 12%, butadiene-styrene rubber
14%, filler 16.5%, pigment 2.5%, auxiliary agent 6%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
The preparation method of above-mentioned non-bituminous base self-adhesion sizing material is specially：
S1：The naphthenic rubber oil and polyisobutene of formula rate are added to the first reaction kettle, is then turned on stirring, heats up
To 150 DEG C of addition C5/C9 copolymer resins；
S2：After temperature rise is dissolved completely to 160 DEG C and C5/C9 copolymer resins, SIS rubber and butadiene-styrene rubber is added,
Continue to be warming up to 178~182 DEG C, then whip modified 2.5h at this temperature；
S3：The modified materials of step S2 are transferred in high shear grinding dispersion machine, high shear grinding dispersion machine is passed through
Enter the second reaction kettle after grinding distribution 40-50min, pigment, filler and auxiliary agent is added in the second reaction kettle, 160~165
Non-bituminous base self-adhesion sizing material is obtained after stirring 40~60min at DEG C.
Embodiment 2
A kind of non-bituminous self-adhesion sizing material is present embodiments provided, is comprised the following raw materials by weight percent：
C5/C9 copolymer resins 25%, polyisobutene 3%, naphthenic rubber oil 25%, SIS rubber 3%, butadiene-styrene rubber
4%, filler 35%, pigment 0.5%, auxiliary agent 4.5%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
The preparation method reference implementation example 1 of above-mentioned non-bituminous base self-adhesion sizing material.
Embodiment 3
A kind of non-bituminous self-adhesion sizing material is present embodiments provided, is comprised the following raw materials by weight percent：
C5/C9 copolymer resins 15%, polyisobutene 12%, naphthenic rubber oil 22%, SIS rubber 6%, butadiene-styrene rubber
10%, filler 28%, pigment 2%, auxiliary agent 5%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is to receive base montmorillonite.
The preparation method reference implementation example 1 of above-mentioned non-bituminous base self-adhesion sizing material.
Embodiment 4
A kind of non-bituminous self-adhesion sizing material is present embodiments provided, is comprised the following raw materials by weight percent：
C5/C9 copolymer resins 22%, polyisobutene 8%, naphthenic rubber oil 18%, SIS rubber 10%, butadiene-styrene rubber
8%, filler 30%, pigment 1%, auxiliary agent 3%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
The preparation method reference implementation example 1 of above-mentioned non-bituminous base self-adhesion sizing material.
Embodiment 5
A kind of non-bituminous self-adhesion sizing material is present embodiments provided, is comprised the following raw materials by weight percent：
C5/C9 copolymer resins 20%, polyisobutene 10%, naphthenic rubber oil 21%, SIS rubber 9%, butadiene-styrene rubber
9%, filler 26%, pigment 1.5%, auxiliary agent 4.5%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is to receive base montmorillonite.
The preparation method reference implementation example 1 of above-mentioned non-bituminous base self-adhesion sizing material.
Comparative example 1
This comparative example 1 provides a kind of plain asphalt base adhesive waterproof coil, including main body base material, is overlying on main body base material
Pitch self-adhesion sizing material and isolation film.The asphaltic base self-adhesion sizing material comprises the following raw materials by weight percent：Pitch
45%, base oil 10%, SBS 7%, butadiene-styrene rubber 4%, thickening Petropols 5%, rubber powder：7%, filler 22%.
Wherein, main body base material uses polyethylene composite film.Preferably, the composite membrane of the double-layer polyethylene of selection.
Comparative example 2
This comparative example 2 provides a kind of common non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The asphaltic base self-adhesion sizing material comprises the following raw materials by weight percent：Carbon 5
Hydrogenation resin 30%, naphthenic oil 20%, SIS 20%, filler material 28%, auxiliary agent 2%.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film.
Performance test
The non-bituminous self-adhesion sizing material that Examples 1 to 5 provides is prepared into non-bituminous base adhesive waterproof coil, the non-bituminous base
Adhesive waterproof coil is cross-laminated composite membrane, non-bituminous self-adhesion sizing material and the isolation film being overlying on cross-laminated composite membrane.
By GB/T23457-2009 and GB/T35467-2017 acceptance of the bid alignment requests, novel non-drip is provided to Examples 1 to 5
Green base waterproof roll is tested with the peel strength of cement mortar at different conditions with common adhesive waterproof coil, specific to survey
Test result is as shown in table 1.
Table 1
The above embodiment is merely an example for clearly illustrating the present invention, and is not the embodiment party to the present invention
The restriction of formula.For those of ordinary skill in the art, other differences can also be made on the basis of the above description
The variation or variation of form.There is no necessity and possibility to exhaust all the enbodiments.All spirit and original in the present invention
All any modification, equivalent and improvement made by within then etc., should all be included in the scope of protection of the claims of the present invention.
Claims (10)
1. a kind of non-bituminous self-adhesion sizing material of waterproof roll, which is characterized in that comprise the following raw materials by weight percent：C5/
C9 copolymer resins 10 ~ 25%, polyisobutene 2 ~ 14%, naphthenic rubber oil 10 ~ 25%, SIS rubber 2 ~ 12%, butadiene-styrene rubber 3 ~ 14%,
Filler 15 ~ 35%, pigment 0.5 ~ 2.5%, auxiliary agent 4 ~ 6%.
2. the non-bituminous self-adhesion sizing material of waterproof roll according to claim 1, which is characterized in that by following weight percent
Raw material composition：C5/C9 copolymer resins 15 ~ 22%, polyisobutene 5 ~ 12%, naphthenic rubber oil 15 ~ 22%, SIS rubber 5 ~ 10%,
Butadiene-styrene rubber 5 ~ 10%, filler 20 ~ 30%, pigment 1 ~ 2%, auxiliary agent 3 ~ 5%.
3. the non-bituminous self-adhesion sizing material of waterproof roll according to claim 2, which is characterized in that the non-bituminous self-adhesive
Material comprises the following raw materials by weight percent：C5/C9 copolymer resins 17 ~ 20%, polyisobutene 7 ~ 10%, naphthenic rubber oil 17
~ 21%, SIS rubber 7 ~ 9%, butadiene-styrene rubber 7 ~ 9%, filler 25 ~ 27%, pigment 1.3 ~ 1.7%, auxiliary agent 3.5 ~ 4.5%.
4. according to the non-bituminous self-adhesion sizing material of claim 1 ~ 3 any one of them waterproof roll, which is characterized in that described
C5/C9 copolymerized petroleum resins select softening point be 90 ~ 110 DEG C plus hydrogen C5/C9 copolymerized petroleum resins.
5. according to the non-bituminous self-adhesion sizing material of claim 1 ~ 3 any one of them waterproof roll, which is characterized in that described is poly-
Isobutene is the polyisobutene of molecular weight 1000 ~ 5000.
6. according to the non-bituminous self-adhesion sizing material of claim 1 ~ 3 any one of them waterproof roll, which is characterized in that described
SIS rubber is SIS rubber of the isoprene content 80% or more.
7. according to the non-bituminous self-adhesion sizing material of claim 1 ~ 3 any one of them waterproof roll, which is characterized in that the fourth
Benzene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber.
8. according to any one of claim 1 ~ 3 or the non-bituminous self-adhesion sizing material of waterproof roll described in 5, which is characterized in that described
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；And/or the auxiliary agent is organic
Montmorillonite.
9. according to claim 1 ~ 8 any one of them waterproof roll preparation method of non-bituminous self-adhesion sizing material, feature exists
In specifically including following steps：
S1：The naphthenic rubber oil and polyisobutene of formula rate are added to the first reaction kettle, is then turned on stirring, is warming up to
150 DEG C of addition C5/C9 copolymer resins；
S2：After temperature rise is dissolved completely to 160 DEG C and C5/C9 copolymer resins, SIS rubber and butadiene-styrene rubber is added, continues
178 ~ 182 DEG C are warming up to, then whip modified 2.5h at this temperature；
S3：The modified materials of step S2 are transferred in high shear grinding dispersion machine, are ground by high shear grinding dispersion machine
Enter the second reaction kettle after disperseing 40-50min, pigment, filler and auxiliary agent is added in the second reaction kettle, at 160 ~ 165 DEG C
Non-bituminous base self-adhesion sizing material is obtained after 40 ~ 60min of stirring.
10. a kind of non-bituminous base adhesive waterproof coil, which is characterized in that using according to described in claim 1 ~ 8 it is non-bituminous from
Viscose material is as self-adhesive layer.
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| CN110003808A (en) * | 2019-04-15 | 2019-07-12 | 四川卓邦安新材料科技有限公司 | A kind of high-polymer self-adhesion waterproof coiled material and preparation method thereof |
| CN111662677A (en) * | 2020-06-02 | 2020-09-15 | 岳阳市科兴防水材料有限公司 | Non-asphalt-based self-adhesive waterproof sizing material, and preparation method and application thereof |
| CN112143158A (en) * | 2020-01-23 | 2020-12-29 | 四川新三亚建材科技股份有限公司 | Non-asphalt base chemical corrosion resistant color-bonding waterproof coiled material and production process thereof |
| CN112980362A (en) * | 2021-03-02 | 2021-06-18 | 江苏凯伦建材股份有限公司 | Preparation method of self-adhesive waterproof material |
| CN113004843A (en) * | 2021-03-02 | 2021-06-22 | 江苏凯伦建材股份有限公司 | Novel self-adhesive waterproof material |
| CN114214013A (en) * | 2021-12-30 | 2022-03-22 | 科顺防水科技股份有限公司 | Non-asphalt self-adhesive polymer waterproof coiled material and preparation method thereof |
| CN114479687A (en) * | 2022-02-25 | 2022-05-13 | 湖北华宇防水材料科技股份有限公司 | Preparation process of double-sided self-adhesive non-asphalt-based waterproof roll |
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| CN112143158A (en) * | 2020-01-23 | 2020-12-29 | 四川新三亚建材科技股份有限公司 | Non-asphalt base chemical corrosion resistant color-bonding waterproof coiled material and production process thereof |
| CN111662677A (en) * | 2020-06-02 | 2020-09-15 | 岳阳市科兴防水材料有限公司 | Non-asphalt-based self-adhesive waterproof sizing material, and preparation method and application thereof |
| CN112980362A (en) * | 2021-03-02 | 2021-06-18 | 江苏凯伦建材股份有限公司 | Preparation method of self-adhesive waterproof material |
| CN113004843A (en) * | 2021-03-02 | 2021-06-22 | 江苏凯伦建材股份有限公司 | Novel self-adhesive waterproof material |
| CN114214013A (en) * | 2021-12-30 | 2022-03-22 | 科顺防水科技股份有限公司 | Non-asphalt self-adhesive polymer waterproof coiled material and preparation method thereof |
| CN114214013B (en) * | 2021-12-30 | 2022-06-14 | 科顺防水科技股份有限公司 | Non-asphalt self-adhesive polymer waterproof coiled material and preparation method thereof |
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Application publication date: 20181012 |