CN108636356A - A kind of cornstalk biological charcoal and restorative procedure that can repair nitrogen phosphorus pollution of area source - Google Patents
A kind of cornstalk biological charcoal and restorative procedure that can repair nitrogen phosphorus pollution of area source Download PDFInfo
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- 239000003610 charcoal Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 36
- 230000008439 repair process Effects 0.000 title claims abstract description 12
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 title abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 111
- 240000008042 Zea mays Species 0.000 claims abstract description 111
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 111
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 60
- 239000010902 straw Substances 0.000 claims abstract description 30
- 238000009825 accumulation Methods 0.000 claims abstract description 28
- 230000000813 microbial effect Effects 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 16
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 10
- 230000001580 bacterial effect Effects 0.000 claims abstract 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 109
- 235000005822 corn Nutrition 0.000 claims description 109
- 229910052698 phosphorus Inorganic materials 0.000 claims description 61
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 56
- 239000011574 phosphorus Substances 0.000 claims description 54
- 210000003608 fece Anatomy 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 16
- 239000012634 fragment Substances 0.000 claims description 14
- 239000010871 livestock manure Substances 0.000 claims description 14
- 238000003763 carbonization Methods 0.000 claims description 13
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 11
- 241000196324 Embryophyta Species 0.000 claims description 9
- 241000894006 Bacteria Species 0.000 claims description 8
- 239000003673 groundwater Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 241000193830 Bacillus <bacterium> Species 0.000 claims description 5
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 5
- 230000000593 degrading effect Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- 239000010907 stover Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 abstract description 19
- 230000005012 migration Effects 0.000 abstract description 4
- 238000013508 migration Methods 0.000 abstract description 4
- 230000009471 action Effects 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- 244000005700 microbiome Species 0.000 abstract description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 abstract 2
- 235000009973 maize Nutrition 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 230000000717 retained effect Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 12
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 10
- 230000003247 decreasing effect Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 244000144977 poultry Species 0.000 description 4
- 241000194107 Bacillus megaterium Species 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 239000002054 inoculum Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 description 2
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000193744 Bacillus amyloliquefaciens Species 0.000 description 1
- UCUJUFDOQOJLBE-UHFFFAOYSA-N [Cl].[Ca] Chemical compound [Cl].[Ca] UCUJUFDOQOJLBE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 238000003895 groundwater pollution Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
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- B09C1/00—Reclamation of contaminated soil
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2220/00—Aspects relating to sorbent materials
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- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
- B01J2220/4825—Polysaccharides or cellulose materials, e.g. starch, chitin, sawdust, wood, straw, cotton
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
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Abstract
Description
技术领域technical field
本发明属于面源污染修复技术领域,具体涉及一种能修复氮磷面源污染的玉米秸秆生物炭及修复方法。The invention belongs to the technical field of non-point source pollution restoration, and in particular relates to corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution and a restoration method.
背景技术Background technique
氮磷是重要的生命元素,是生命支持系统不可替代的成分,也是促进农业持续发展的根本要素。但是其也有两面性,土壤中过度的氮磷肥料投入,或者养殖场中禽兽粪便的长时间堆积,不仅造成氮磷元素的损失浪费,而且会导致土壤和地下水污染,甚至造成河流和湖泊水质的富营养化,破坏水生生物的正常生长条件,引起鱼类死亡,同时也将严重危害人类健康。Nitrogen and phosphorus are important life elements, irreplaceable components of life support systems, and fundamental elements for sustainable agricultural development. However, it also has two sides. Excessive input of nitrogen and phosphorus fertilizers in the soil, or long-term accumulation of animal manure in farms will not only cause loss and waste of nitrogen and phosphorus elements, but also lead to soil and groundwater pollution, and even cause water quality in rivers and lakes to deteriorate. Nutritization destroys the normal growth conditions of aquatic organisms, causes fish death, and will seriously endanger human health.
当污染点产生后,从产生点开始,随着水流途径可迁移至不同的区域,形成面源污染。针对面源污染的迁移过程,国内外主要采取的治理措施有:(1)源头控制,即合理控制肥料施用量,避免过度施肥;(2)污染物截留,即通过设置生态沟渠、制备缓冲带等措施,控制并阻断污染物迁移途径,缩小污染面积;(3)内源治理,一旦污染迁移至河流、湖泊等水体中,即使采用清除底泥等措施,降低水体富营养化产生的风险。比如中国专利CN101555071A公开了一种利用缓冲带控制平原感潮河网地区农业面源污染的方法,该专利提出选择农田和河道之间的河岸为缓冲带,依径流流向种植不同植物,形成制备缓冲带,利用植物对径流中营养物质的截留、吸收功能取得较好的净化效果。又如中国专利CN102839632B公开了一种基于生物强化截留清除面源污染的生态护坡的方法,该专利将河流传统生态修复与面源污染控制相结合,运用生物强化技术,实现对面源污染中难降解有机物的去除。When the pollution point is generated, it can migrate to different areas along the water flow path from the point of generation, forming non-point source pollution. For the migration process of non-point source pollution, the main control measures adopted at home and abroad are: (1) source control, that is, to reasonably control the amount of fertilizer application, to avoid excessive fertilization; (2) pollutant interception, that is, to set up ecological ditches and prepare buffer zones (3) Internal source control, once the pollution migrates to rivers, lakes and other water bodies, even if measures such as removing sediment are adopted to reduce the risk of eutrophication in the water body . For example, Chinese patent CN101555071A discloses a method for controlling agricultural non-point source pollution in plain tidal river network areas by using a buffer zone. The patent proposes to select the river bank between the farmland and the river as a buffer zone, and plant different plants according to the runoff direction to form a preparation buffer. belt, using plants to intercept and absorb nutrients in the runoff to achieve a better purification effect. Another example is the Chinese patent CN102839632B, which discloses an ecological slope protection method based on bio-enhanced interception and removal of non-point source pollution. This patent combines traditional ecological restoration of rivers with non-point source pollution control, and uses bio-augmentation technology to achieve refractory degradation in non-point source pollution. removal of organic matter.
然而,这些现有技术都是基于农田与河流、湖泊的相接处进行处理的,目前针对禽兽养殖场中的动物粪便造成的氮磷面源污染仍缺乏有效的控制方法。However, these existing technologies are all based on the connection between farmland, rivers and lakes. At present, there is still no effective control method for the non-point source pollution of nitrogen and phosphorus caused by animal manure in poultry farms.
发明内容Contents of the invention
本发明的目的是提供一种能修复氮磷面源污染的玉米秸秆生物炭及修复方法,从土壤本身出发有效控制污染源的扩散,解决了禽兽养殖场中的动物粪便氮磷面源污染源问题。The purpose of the present invention is to provide a corn stalk biochar and repair method capable of repairing nitrogen and phosphorus non-point source pollution, effectively control the spread of pollution sources from the soil itself, and solve the problem of animal feces nitrogen and phosphorus non-point source pollution sources in poultry farms.
本发明提供了一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭50~200份、微生物菌剂0.1~0.5份;所述微生物菌剂为酵母菌粉剂、解磷功能菌粉剂或者二者的混合物;The invention provides corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution, which is made of the following raw material components in parts by weight: 50-200 parts of corn stalk charcoal, 0.1-0.5 parts of microbial agent; The agent is yeast powder, phosphorus-dissolving functional bacteria powder or a mixture of the two;
所述玉米秸秆炭是按照以下方法制成的:将玉米秸秆粉碎成秸秆碎段,加入质量分数5%的氯化钙溶液中浸泡36~48h,过滤后烘干秸秆碎段,然后进行炭化,得到玉米秸秆炭;The corn stalk charcoal is made according to the following method: crush corn stalks into straw fragments, add 5% calcium chloride solution for soaking for 36-48 hours, filter and dry the straw fragments, and then carbonize. Obtain corn stover charcoal;
所述解磷功能菌为具有降解磷功能的芽孢杆菌。The phosphate-solubilizing functional bacterium is a bacillus having the function of degrading phosphorus.
优选的,上述能修复氮磷面源污染的玉米秸秆生物炭,所述炭化采用管式炉进行炭化,炭化时通入氮气进行气氛保护,加热速率为25℃/min,达到650℃后维持1h,冷却至室温。Preferably, the above-mentioned corn stalk biochar that can repair nitrogen and phosphorus non-point source pollution, the carbonization is carried out in a tube furnace, and nitrogen gas is introduced for atmosphere protection during carbonization. The heating rate is 25°C/min, and it is maintained for 1 hour after reaching 650°C. , cooled to room temperature.
本发明还提供了一种利用上述玉米秸秆生物炭修复氮磷面源污染的方法,包括以下步骤:The present invention also provides a method for repairing nitrogen and phosphorus non-point source pollution by utilizing the above-mentioned corn stalk biochar, comprising the following steps:
S1,按以下重量份称取各原料组分:玉米秸秆炭50~200份、微生物菌剂0.1~0.5份;将称取的各组分混合,得到玉米秸秆生物炭;S1, weighing each raw material component according to the following parts by weight: 50-200 parts of corn stalk charcoal, 0.1-0.5 part of microbial agent; mixing the weighed components to obtain corn stalk biochar;
S2,施用玉米秸秆生物炭S2, application of corn stalk biochar
S21,在养殖场中选择一片区域作为粪便堆积区,在粪便堆积区以及养殖场周围农田中挖沟渠,沟渠内填充玉米秸秆生物炭;S21, select an area in the farm as a manure accumulation area, dig ditches in the manure accumulation area and the farmland around the farm, and fill the ditches with corn stalk biochar;
S22,在粪便堆积区以及养殖场周围农田中未挖沟渠的区域内均匀撒入玉米秸秆生物炭,翻耕,翻耕深度≥20cm;S22中,玉米秸秆生物炭的用量按照以下方式变化:4年为一个循环;每个循环中的第1年用量每亩20~40kg,第2~4年中每年用量为上一年用量的1/2;S22, spread corn straw biochar evenly in the manure accumulation area and the farmland around the farm without digging ditches, and plow till the depth of plowing is ≥ 20cm; in S22, the amount of corn straw biochar is changed in the following way: 4 The year is a cycle; the dosage in the first year of each cycle is 20-40kg per mu, and the dosage in the second to fourth years is 1/2 of the dosage in the previous year;
S3,在粪便堆积区内堆积粪便,并在养殖场周围农田中种植作物,进行氮磷面源污染的修复。S3, pile up feces in the feces accumulation area, and plant crops in the farmland around the farm to remediate nitrogen and phosphorus non-point source pollution.
优选的,利用上述玉米秸秆生物炭修复氮磷面源污染的方法,所述沟渠的宽度为5~10cm,深度为100~200cm。Preferably, in the method for repairing nitrogen and phosphorus non-point source pollution by using the above-mentioned corn stalk biochar, the width of the ditch is 5-10 cm, and the depth is 100-200 cm.
优选的,所述沟渠沿与地下水径流方向垂直的方向延伸,所有的沟渠沿地下水径流方向间隔排列设置,间隔距离为5~50m。Preferably, the ditches extend in a direction perpendicular to the direction of groundwater runoff, and all ditches are arranged at intervals along the direction of groundwater runoff, with an interval of 5-50 m.
与现有技术相比,本发明提供的一种能修复氮磷面源污染的玉米秸秆生物炭及修复方法,具有以下有益效果:Compared with the prior art, the present invention provides a corn straw biochar and repair method capable of repairing nitrogen and phosphorus non-point source pollution, which has the following beneficial effects:
针对禽兽粪便造成的氮磷污染以及养殖场周边农田污染的问题,本发明提供了能修复氮磷面源污染的玉米秸秆生物炭,采用了新的玉米秸秆炭制备方法和生物炭配方,利用氯化钙溶液对对玉米秸秆进行预处理,增加其吸附性能,被吸附至秸秆上的氮元素和磷元素在微生物菌剂以及土壤中微生物的作用下集中处理降解掉,从而达到高效修复氮磷面源污染的目的。Aiming at the problems of nitrogen and phosphorus pollution caused by poultry and animal feces and farmland pollution around farms, the invention provides corn stalk biochar that can repair nitrogen and phosphorus non-point source pollution, adopts a new corn stalk charcoal preparation method and biochar formula, and utilizes chlorine Calcium solution pretreats corn stalks to increase its adsorption performance. The nitrogen and phosphorus elements adsorbed to the stalks are degraded under the action of microbial agents and microorganisms in the soil, so as to achieve efficient repair of nitrogen and phosphorus surfaces. purpose of source pollution.
基于同一种发明构思,本发明还采用了新的修复方法,首先选择粪便堆积区,将粪便集中堆积,降低扩散风险;接着采用本发明制备的玉米秸秆生物炭将粪便堆积区以及粪便堆积区周围农田土壤分块截留,降低氮元素和磷元素在土壤中的迁移速度,降低污染源的扩散速度,从土壤源头上解决污染问题。具体试验研究证明,利用本发明的修复方法,在一定范围内可使试验农田附近池塘水中的氮元素和磷元素含量得到有效控制。吸附实验数据显示,6h内对氮和磷的去除率可达97%以上,效果显著。Based on the same inventive concept, the present invention also adopts a new restoration method. First, the feces accumulation area is selected, and the feces are concentrated and accumulated to reduce the risk of diffusion; Farmland soil is intercepted in blocks, reducing the migration speed of nitrogen and phosphorus elements in the soil, reducing the diffusion speed of pollution sources, and solving the pollution problem from the source of the soil. Specific experimental studies have proved that the restoration method of the present invention can effectively control the contents of nitrogen and phosphorus in the pond water near the test farmland within a certain range. The adsorption experiment data shows that the removal rate of nitrogen and phosphorus can reach more than 97% within 6 hours, and the effect is remarkable.
具体实施方式Detailed ways
下面结合具体实施方式对本发明进行详细说明,但应当理解本发明的保护范围并不受具体实施方式的限制。下列实施例中未注明具体条件的试验方法,通常按照常规条件操作,未注明的实验材料来源均为市售,由于不涉及发明点,故不对其步骤进行详细描述。The present invention will be described in detail below in conjunction with specific embodiments, but it should be understood that the protection scope of the present invention is not limited by specific embodiments. The test methods that do not indicate specific conditions in the following examples are usually operated according to conventional conditions, and the sources of unindicated experimental materials are commercially available. Since they do not involve the invention point, the steps are not described in detail.
下述实施例1~3及实验中,所述酵母菌粉剂为济宁市金益菌生物科技有限公司所有酵母菌粉;所述解磷功能菌为具有解磷功能的巨大芽孢杆菌粉,购自山东绿陇生物技术有限公司。In the following examples 1 to 3 and experiments, the yeast powder is all yeast powder of Jining Jinyijun Biotechnology Co., Ltd.; Shandong Lvlong Biotechnology Co., Ltd.
本发明提供了一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭50~200份、微生物菌剂0.1~0.5份;所述微生物菌剂为酵母菌粉剂、解磷功能菌粉剂或者二者的混合物;The invention provides corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution, which is made of the following raw material components in parts by weight: 50-200 parts of corn stalk charcoal, 0.1-0.5 parts of microbial agent; The agent is yeast powder, phosphorus-dissolving functional bacteria powder or a mixture of the two;
所述玉米秸秆炭是按照以下方法制成的:将玉米秸秆粉碎成秸秆碎段,加入质量分数5%的氯化钙溶液中浸泡36~48h,过滤后烘干秸秆碎段,然后进行炭化,得到玉米秸秆炭;The corn stalk charcoal is made according to the following method: crush corn stalks into straw fragments, add 5% calcium chloride solution for soaking for 36-48 hours, filter and dry the straw fragments, and then carbonize. Obtain corn stover charcoal;
所述解磷功能菌为具有降解磷功能的芽孢杆菌。The phosphate-solubilizing functional bacterium is a bacillus having the function of degrading phosphorus.
基于同一种发明构思,本发明还提供了一种利用所述玉米秸秆生物炭修复氮磷面源污染的方法,包括以下步骤:Based on the same inventive concept, the present invention also provides a method for using the corn stalk biochar to repair nitrogen and phosphorus non-point source pollution, comprising the following steps:
S1,按以下重量份称取各原料组分:玉米秸秆炭50~200份、微生物菌剂0.1~0.5份;将称取的各组分混合,得到玉米秸秆生物炭;S1, weighing each raw material component according to the following parts by weight: 50-200 parts of corn stalk charcoal, 0.1-0.5 part of microbial agent; mixing the weighed components to obtain corn stalk biochar;
S2,施用玉米秸秆生物炭S2, application of corn stalk biochar
S21,在养殖场中选择一片区域作为粪便堆积区,在粪便堆积区以及养殖场周围农田中挖沟渠,沟渠内填充玉米秸秆生物炭;S21, select an area in the farm as a manure accumulation area, dig ditches in the manure accumulation area and the farmland around the farm, and fill the ditches with corn stalk biochar;
S22,在粪便堆积区以及养殖场周围农田中未挖沟渠的区域内均匀撒入玉米秸秆生物炭,翻耕,翻耕深度≥20cm;S22中,玉米秸秆生物炭的用量按照以下方式变化:4年为一个循环;每个循环中的第1年用量每亩20~40kg,第2~4年中每年用量为上一年用量的1/2;S22, spread corn straw biochar evenly in the manure accumulation area and the farmland around the farm without digging ditches, and plow till the depth of plowing is ≥ 20cm; in S22, the amount of corn straw biochar is changed in the following way: 4 The year is a cycle; the dosage in the first year of each cycle is 20-40kg per mu, and the dosage in the second to fourth years is 1/2 of the dosage in the previous year;
S3,在粪便堆积区内堆积粪便,并在养殖场周围农田中种植作物,进行氮磷面源污染的修复。S3, pile up feces in the feces accumulation area, and plant crops in the farmland around the farm to remediate nitrogen and phosphorus non-point source pollution.
具体包括以下实施例。下述实施例中试验污染农田的选取位置为禽兽养殖场及其周边农田。Specifically include the following examples. In the following examples, the selected locations for testing polluted farmland are poultry farms and their surrounding farmlands.
实施例1Example 1
一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭50份、微生物菌剂0.1份;所述微生物菌剂为酵母菌粉剂;所述玉米秸秆炭是按照以下方法制成的:将玉米秸秆粉碎成1~2cm的秸秆碎段,加入质量分数5%的氯化钙溶液中浸泡36h,过滤后105℃烘干(水分含量≤10%)秸秆碎段,然后进行炭化,得到玉米秸秆炭。所述炭化采用管式炉进行炭化,炭化时通入氮气进行气氛保护,加热速率为25℃/min,达到650℃后维持1h,冷却至室温。A corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution is made of the following raw material components in parts by weight: 50 parts of corn stalk charcoal, 0.1 part of microbial agent; the microbial agent is yeast powder; the Corn stalk charcoal is made according to the following method: crush corn stalks into 1-2 cm straw fragments, add 5% mass fraction of calcium chloride solution to soak for 36 hours, filter and dry at 105°C (moisture content ≤ 10% ) straw fragments, and then carbonized to obtain corn straw charcoal. The carbonization is carried out in a tube furnace, and nitrogen gas is introduced to protect the atmosphere during carbonization. The heating rate is 25°C/min. After reaching 650°C, it is maintained for 1 hour and cooled to room temperature.
利用实施例1所述玉米秸秆生物炭修复氮磷面源污染的方法,包括以下步骤:The method for remediating nitrogen and phosphorus non-point source pollution by using corn stalk biochar described in Example 1 may further comprise the steps:
S1,按以下重量份称取各原料组分:玉米秸秆炭50份、微生物菌剂0.1份;将称取的各组分混合,得到玉米秸秆生物炭;S1, weighing each raw material component according to the following parts by weight: 50 parts of corn stalk charcoal, 0.1 part of microbial inoculant; mixing the weighed components to obtain corn stalk biochar;
S2,施用玉米秸秆生物炭S2, application of corn stalk biochar
S21,在养殖场中选择一片40平方米的区域作为粪便堆积区,在粪便堆积区以及养殖场周围农田中挖沟渠,所述沟渠的宽度为5cm,深度为100cm,沟渠内填充玉米秸秆生物炭,填充至与农田土壤齐平;S21, select an area of 40 square meters in the farm as the excrement accumulation area, dig ditches in the excrement accumulation area and the farmland around the farm, the width of the ditches is 5 cm, the depth is 100 cm, and corn stalk biochar is filled in the ditches , filled to be flush with the farmland soil;
S22,在粪便堆积区以及养殖场周围农田中未挖沟渠的区域内均匀撒入玉米秸秆生物炭,翻耕,翻耕深度20cm;S22中,玉米秸秆生物炭的用量按照以下方式变化:4年为一个循环;每个循环中的第1年用量每亩20kg,第2年中每年用量每亩10kg,第3年中每年用量每亩5kg,第4年中每年用量每亩2.5kg;In S22, corn stalk biochar was evenly sprinkled in the manure accumulation area and the farmland around the farm without ditches, and plowed to a depth of 20cm; in S22, the amount of corn stalk biochar was changed in the following way: 4 years It is a cycle; in each cycle, the dosage in the first year is 20kg per mu, the annual dosage in the second year is 10kg per mu, the annual dosage in the third year is 5kg per mu, and the annual dosage in the fourth year is 2.5kg per mu;
S3,在粪便堆积区内堆积粪便,并在养殖场周围农田中种植作物小麦,构建成生态修复田,进行氮磷面源污染的修复。S3, pile up feces in the feces accumulation area, and plant crop wheat in the farmland around the farm to build an ecological restoration field for the restoration of nitrogen and phosphorus non-point source pollution.
实施例1的方法撒入玉米秸秆生物炭1年后,100cm深度层土壤中N含量由350.01mg/kg降低至125.56mg/kg,P含量由223.50mg/kg降低至103.74mg/kg。养殖场100米外的农田中N、P含量未增加。After the method of Example 1 was sprinkled with corn stalk biochar for one year, the N content in the 100cm depth layer soil decreased from 350.01 mg/kg to 125.56 mg/kg, and the P content decreased from 223.50 mg/kg to 103.74 mg/kg. The content of N and P in the farmland 100 meters away from the farm did not increase.
实施例2Example 2
一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭200份、微生物菌剂0.5份;所述微生物菌剂为具有解磷功能的巨大芽孢杆菌粉;所述玉米秸秆炭是按照以下方法制成的:将玉米秸秆粉碎成1~2cm的秸秆碎段,加入质量分数5%的氯化钙溶液中浸泡36h,过滤后105℃烘干(水分含量≤10%)秸秆碎段,然后进行炭化,得到玉米秸秆炭。所述炭化采用管式炉进行炭化,炭化时通入氮气进行气氛保护,加热速率为25℃/min,达到650℃后维持1h,冷却至室温。A kind of corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution, made of the following raw material components in parts by weight: 200 parts of corn stalk charcoal, 0.5 part of microbial agent; the microbial agent is a huge Bacillus powder; the corn stalk charcoal is made according to the following method: crush the corn stalks into 1-2 cm straw fragments, add 5% mass fraction of calcium chloride solution to soak for 36 hours, filter and dry at 105°C (moisture content≤10%) straw fragments, and then carbonize to obtain corn straw charcoal. The carbonization is carried out in a tube furnace, and nitrogen gas is introduced to protect the atmosphere during carbonization. The heating rate is 25°C/min. After reaching 650°C, it is maintained for 1 hour and cooled to room temperature.
利用实施例2所述玉米秸秆生物炭修复氮磷面源污染的方法,包括以下步骤:The method for remediating nitrogen and phosphorus non-point source pollution by using corn stalk biochar described in Example 2 comprises the following steps:
S1,按以下重量份称取各原料组分:玉米秸秆炭200份、微生物菌剂0.5份;将称取的各组分混合,得到玉米秸秆生物炭;S1, weighing each raw material component according to the following parts by weight: 200 parts of corn stalk charcoal, 0.5 part of microbial inoculant; mixing the weighed components to obtain corn stalk biochar;
S2,施用玉米秸秆生物炭S2, application of corn stalk biochar
S21,在养殖场中选择一片30平方米的区域作为粪便堆积区,在粪便堆积区以及养殖场周围农田中挖沟渠,所述沟渠的宽度为10cm,深度为200cm,沟渠内填充玉米秸秆生物炭,填充至与农田土壤齐平;S21, select an area of 30 square meters in the farm as the excrement accumulation area, dig ditches in the excrement accumulation area and the farmland around the farm, the width of the ditches is 10 cm, the depth is 200 cm, and corn stalk biochar is filled in the ditches , filled to be flush with the farmland soil;
S22,在粪便堆积区以及养殖场周围农田中未挖沟渠的区域内均匀撒入玉米秸秆生物炭,翻耕,翻耕深度25cm;S22中,玉米秸秆生物炭的用量按照以下方式变化:4年为一个循环;每个循环中的第1年用量每亩40kg,第2年中每年用量每亩20kg,第3年中每年用量每亩10kg,第4年中每年用量每亩5kg;In S22, corn stalk biochar was evenly sprinkled in the manure accumulation area and the farmland around the farm without ditches, and plowed to a depth of 25 cm; in S22, the amount of corn stalk biochar was changed in the following way: 4 years It is a cycle; in each cycle, the dosage is 40kg per mu in the first year, 20kg per mu in the second year, 10kg per mu in the third year, and 5kg per mu in the fourth year;
S3,在粪便堆积区内堆积粪便,并在养殖场周围农田中种植作物小麦,构建成生态修复田,进行氮磷面源污染的修复。S3, pile up feces in the feces accumulation area, and plant crop wheat in the farmland around the farm to build an ecological restoration field for the restoration of nitrogen and phosphorus non-point source pollution.
实施例2的方法撒入玉米秸秆生物炭1年后,100cm深度层土壤中N含量由425.69mg/kg降低至220.12mg/kg,P含量由255.30mg/kg降低至140.75mg/kg。养殖场100米外的农田中N、P含量未增加。After the method of Example 2 was sprinkled with corn stalk biochar for one year, the N content in the 100cm deep layer soil decreased from 425.69 mg/kg to 220.12 mg/kg, and the P content decreased from 255.30 mg/kg to 140.75 mg/kg. The content of N and P in the farmland 100 meters away from the farm did not increase.
实施例3Example 3
一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭100份、微生物菌剂0.2份;所述微生物菌剂为酵母菌粉和具有解磷功能的巨大芽孢杆菌粉按照1:1的质量比例混合后的混合物;所述玉米秸秆炭是按照以下方法制成的:将玉米秸秆粉碎成1~2cm的秸秆碎段,加入质量分数5%的氯化钙溶液中浸泡48h,过滤后105℃烘干(水分含量≤10%)秸秆碎段,然后进行炭化,得到玉米秸秆炭。所述炭化采用管式炉进行炭化,炭化时通入氮气进行气氛保护,加热速率为25℃/min,达到650℃后维持1h,冷却至室温。A corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution is made of the following raw material components in parts by weight: 100 parts of corn stalk charcoal, 0.2 parts of microbial agent; the microbial agent is yeast powder and has a solution The mixture of Bacillus megaterium powder with phosphorus function in a mass ratio of 1:1; the corn stalk charcoal is made according to the following method: crush corn stalks into 1-2 cm straw fragments, add 5% mass fraction Soak in the calcium chloride solution for 48 hours, filter and dry at 105° C. (moisture content ≤ 10%) straw fragments, and then carbonize to obtain corn straw charcoal. The carbonization is carried out in a tube furnace, and nitrogen gas is introduced to protect the atmosphere during carbonization. The heating rate is 25°C/min. After reaching 650°C, it is maintained for 1 hour and cooled to room temperature.
利用实施例2所述玉米秸秆生物炭修复氮磷面源污染的方法,包括以下步骤:The method for remediating nitrogen and phosphorus non-point source pollution by using corn stalk biochar described in Example 2 comprises the following steps:
S1,按以下重量份称取各原料组分:玉米秸秆炭100份、微生物菌剂0.2份;将称取的各组分混合,玉米秸秆生物炭;S1, weighing each raw material component according to the following parts by weight: 100 parts of corn stalk charcoal, 0.2 part of microbial inoculant; mixing the weighed components to make corn stalk biochar;
S2,施用玉米秸秆生物炭S2, application of corn stalk biochar
S21,在养殖场中选择一片20平方米的区域作为粪便堆积区,在粪便堆积区以及养殖场周围农田中挖沟渠,所述沟渠的宽度为10cm,深度为150cm,沟渠内填充玉米秸秆生物炭,填充至与农田土壤齐平;S21, select an area of 20 square meters in the farm as the excrement accumulation area, dig ditches in the excrement accumulation area and the farmland around the farm, the width of the ditches is 10 cm, the depth is 150 cm, and corn stalk biochar is filled in the ditches , filled to be flush with the farmland soil;
S22,在粪便堆积区以及养殖场周围农田中未挖沟渠的区域内均匀撒入玉米秸秆生物炭,翻耕,翻耕深度25cm;S22中,玉米秸秆生物炭的用量按照以下方式变化:4年为一个循环;每个循环中的第1年用量每亩30kg,第2年中每年用量每亩15kg,第3年中每年用量每亩7.5kg,第4年中每年用量每亩3.75kg;In S22, corn stalk biochar was evenly sprinkled in the manure accumulation area and the farmland around the farm without ditches, and plowed to a depth of 25 cm; in S22, the amount of corn stalk biochar was changed in the following way: 4 years It is a cycle; in each cycle, the dosage in the first year is 30kg per mu, the annual dosage in the second year is 15kg per mu, the annual dosage in the third year is 7.5kg per mu, and the annual dosage in the fourth year is 3.75kg per mu;
S3,在粪便堆积区内堆积粪便,并在养殖场周围农田中种植作物小麦,构建成生态修复田,进行氮磷面源污染的修复。S3, pile up feces in the feces accumulation area, and plant crop wheat in the farmland around the farm to build an ecological restoration field for the restoration of nitrogen and phosphorus non-point source pollution.
实施例3的方法撒入玉米秸秆生物炭1年后,100cm深度层土壤中N含量由389.32mg/kg降低至120.78mg/kg,P含量由251.40mg/kg降低至110.65mg/kg。养殖场100米外的农田中N、P含量未增加。After the method of Example 3 was sprinkled with corn stalk biochar for one year, the N content in the 100cm deep layer soil decreased from 389.32 mg/kg to 120.78 mg/kg, and the P content decreased from 251.40 mg/kg to 110.65 mg/kg. The content of N and P in the farmland 100 meters away from the farm did not increase.
对比例1Comparative example 1
使用玉米秸秆生物炭时省略掉S21步骤,其余操作同实施例1。When corn stalk biochar is used, step S21 is omitted, and the rest of the operations are the same as in Example 1.
实施例1的方法撒入玉米秸秆生物炭1年后,100cm深度层土壤中N含量由354.86mg/kg降低至218.35mg/kg,P含量由224.50mg/kg降低至146.21mg/kg。养殖场100米外的农田中N、P分别含量增加了2.1%和2.3%。After the method of Example 1 was sprinkled with corn stalk biochar for one year, the N content in the soil at a depth of 100 cm decreased from 354.86 mg/kg to 218.35 mg/kg, and the P content decreased from 224.50 mg/kg to 146.21 mg/kg. The content of N and P in the farmland 100 meters away from the farm increased by 2.1% and 2.3%, respectively.
为了证明本发明玉米秸秆生物炭去除氮磷的效果,我们进行了以下实验。In order to prove the effect of the corn stalk biochar of the present invention on removing nitrogen and phosphorus, we conducted the following experiments.
一、不同实验组的设置:1. Settings of different experimental groups:
实验组1:一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭50份、微生物菌剂0.1份;所述微生物菌剂为酵母菌粉剂;按重量份比例称取各组分,混合,制成玉米秸秆生物炭。玉米秸秆炭的制备方法同实施例1。Experimental group 1: a corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution, made of the following raw material components in parts by weight: 50 parts of corn stalk charcoal, 0.1 part of microbial agent; the microbial agent is yeast Powder: weighing each component according to the weight ratio, and mixing to prepare corn stalk biochar. The preparation method of corn stalk charcoal is the same as in Example 1.
实验组2:一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭50份、微生物菌剂0.1份;所述微生物菌剂为具有解磷功能的巨大芽孢杆菌粉;按重量份比例称取各组分,混合,制成玉米秸秆生物炭。玉米秸秆炭的制备方法同实施例1。Experimental group 2: a corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution, made of the following raw material components in parts by weight: 50 parts of corn stalk charcoal, 0.1 part of microbial agent; Bacillus megaterium powder with phosphorus function; each component is weighed in proportion by weight and mixed to make corn stalk biochar. The preparation method of corn stalk charcoal is the same as in Example 1.
实验组3:一种能修复氮磷面源污染的玉米秸秆生物炭,由以下重量份的原料组分制成:玉米秸秆炭50份、微生物菌剂0.1份;所述微生物菌剂为酵母菌粉和具有解磷功能的巨大芽孢杆菌粉按照1:1的质量比例混合后的混合物;按重量份比例称取各组分,混合,制成玉米秸秆生物炭。玉米秸秆炭的制备方法同实施例1。Experimental group 3: a corn stalk biochar capable of repairing nitrogen and phosphorus non-point source pollution, made of the following raw material components in parts by weight: 50 parts of corn stalk charcoal, 0.1 part of microbial agent; the microbial agent is yeast powder and Bacillus megaterium powder with phosphorus-solubilizing function in a mass ratio of 1:1; each component is weighed in proportion by weight and mixed to make corn stalk biochar. The preparation method of corn stalk charcoal is the same as in Example 1.
实验组4:玉米秸秆炭的制备方法如下:将玉米秸秆粉碎成秸秆碎段,105℃烘干秸秆碎段,然后进行炭化,得到玉米秸秆炭;所述炭化采用管式炉进行炭化,炭化时通入氮气进行气氛保护,加热速率为25℃/min,达到650℃后维持1h,冷却至室温;不使用微生物菌剂;其余操作同实验组1。Experimental group 4: The preparation method of corn stalk charcoal is as follows: crush corn stalks into straw fragments, dry the straw fragments at 105°C, and then carbonize to obtain corn straw charcoal; the carbonization uses a tube furnace for carbonization. Introduce nitrogen for atmosphere protection, heating rate is 25°C/min, maintain 1h after reaching 650°C, and cool to room temperature; no microbial agent is used; other operations are the same as experimental group 1.
实验组5:将氯化钙溶液的浸泡时间改为60h,其余操作同实验组1。Experimental group 5: Change the soaking time of calcium chloride solution to 60h, and the rest of the operations are the same as experimental group 1.
实验组6:不使用微生物菌剂,其余操作同实验组1。Experimental group 6: No microbial agent was used, and other operations were the same as experimental group 1.
二、吸附实验2. Adsorption experiment
(1)磷吸附实验操作:本实验在室温条件下进行,将4g的生物炭加入到12mg/L的磷酸二氢钾溶液中,吸附48h,分别测定30min、6h、12h时溶液中残留P含量,计算P去除率=(原始P含量-残留P含量)×100%/原始P含量。(1) Phosphorus adsorption experiment operation: This experiment was carried out at room temperature, 4g of biochar was added to 12mg/L potassium dihydrogen phosphate solution, adsorbed for 48h, and the residual P content in the solution was measured at 30min, 6h, and 12h respectively , Calculation of P removal rate = (original P content - residual P content) × 100% / original P content.
(2)氮吸附实验操作:本实验在室温条件下进行,将4g的生物炭加入到12mg/L的氯化铵溶液中,吸附48h,分别测定30min、6h、12h时溶液中残留N含量,计算N去除率=(原始N含量-残留N含量)×100%/原始N含量。(2) Nitrogen adsorption experiment operation: this experiment was carried out at room temperature, 4g of biochar was added to 12mg/L ammonium chloride solution, adsorbed for 48h, and the residual N content in the solution was measured at 30min, 6h, and 12h respectively. Calculate N removal rate=(original N content-residual N content)×100%/original N content.
(3)复合离子吸附实验操作:本实验在室温条件下进行,将4g的生物炭加入到1L的复合离子溶液中,1L复合离子溶液中添加6mg的氯化铵、6mg的磷酸二氢钾;吸附48h,分别测定30min、6h、12h时溶液中残留N、P量,分别计算N、P去除率。(3) Composite ion adsorption experiment operation: This experiment was carried out at room temperature, 4g of biochar was added to 1L of composite ion solution, and 6mg of ammonium chloride and 6mg of potassium dihydrogen phosphate were added to 1L of composite ion solution; After adsorption for 48 hours, measure the amount of N and P remaining in the solution at 30 minutes, 6 hours and 12 hours respectively, and calculate the removal rates of N and P respectively.
上述实验组各做三个平行,取其平均值,实验结果如表1所示,由表1的数据可知,不管是单一磷或氮吸附实验还是复合离子吸附实验,实验组1~3在12h时P去除率和N去除率均较好,说明实施例1~3的玉米生物炭均具有良好的吸附氮、磷效果,12h后去除率可达95%以上,可用于修复氮磷面源污染。实验组4因为采用的是未经氯化钙处理的秸秆,故吸附效果差,去除率不足5%。实验组5延长了氯化钙溶液的浸泡时间,但是去除效果比实验组1~3差,说明并非浸泡时间越长越好。实验组6的去除效果也比实验组1~3差,微生物菌剂对氮和磷的降解具有一定功效。Each of the above-mentioned experimental groups did three parallels, and the average value was taken. The experimental results are shown in Table 1. From the data in Table 1, it can be seen that no matter whether it is a single phosphorus or nitrogen adsorption experiment or a composite ion adsorption experiment, the experimental groups 1 to 3 were in 12h. The P removal rate and N removal rate are good, indicating that the corn biochar in Examples 1-3 has good adsorption nitrogen and phosphorus effects, and the removal rate can reach more than 95% after 12 hours, which can be used to repair nitrogen and phosphorus non-point source pollution. . Experimental group 4 used straw without calcium chloride treatment, so the adsorption effect was poor, and the removal rate was less than 5%. Experimental group 5 prolonged the immersion time of calcium chloride solution, but the removal effect was worse than that of experimental groups 1-3, indicating that the longer the immersion time, the better. The removal effect of experimental group 6 was also worse than that of experimental groups 1-3, and the microbial agent had certain effects on the degradation of nitrogen and phosphorus.
经吸附量试验研究发现,实施例1~3(即实验组1~3)制备的玉米秸秆炭对PO3-的最大吸附量可达48.1mg/g;对NH4+的最大吸附量可达45.2mg/g。The adsorption capacity test found that the corn stalk charcoal prepared in Examples 1-3 (i.e. experimental groups 1-3) had a maximum adsorption capacity of 48.1 mg/g for PO 3- ; a maximum adsorption capacity for NH 4+ of up to 45.2 mg/g.
表1不同实验组的N、P去除率数据Table 1 N, P removal rate data of different experimental groups
需要说明的是,为了提高修复污染的效率,所述沟渠沿与地下水径流方向垂直的方向延伸,所有的沟渠沿地下水径流方向间隔设置,间隔距离为5~50m。因为此时玉米秸秆生物炭与地下水径流方向垂直,可在一定深度内有效阻挡氮元素和磷元素的横向迁移。当沟渠内填充玉米秸秆生物炭达到吸附平衡后,将其挖出重新填充新的玉米秸秆生物炭;而挖出的玉米秸秆生物炭当做有机肥施用在土壤氮磷缺乏的地区,作为缓释肥料施用;也可将挖出的玉米秸秆生物炭用水充分清洗,烘干,使秸秆生物炭重新活化,然后重新用于修复氮磷面源污染。It should be noted that, in order to improve the efficiency of remediating pollution, the ditches extend in a direction perpendicular to the direction of groundwater runoff, and all ditches are arranged at intervals along the direction of groundwater runoff, with an interval of 5-50 m. Because the corn straw biochar is perpendicular to the runoff direction of groundwater at this time, it can effectively block the lateral migration of nitrogen and phosphorus within a certain depth. When the ditch is filled with corn stalk biochar and reaches the adsorption equilibrium, it is dug out and refilled with new corn stalk biochar; and the dug out corn stalk biochar is used as organic fertilizer in areas where the soil is deficient in nitrogen and phosphorus, as a slow-release fertilizer Application; the excavated corn stalk biochar can also be fully washed with water, dried to reactivate the straw biochar, and then reused to repair nitrogen and phosphorus non-point source pollution.
需要说明的是,本发明中所述解磷功能菌为具有降解磷功能的芽孢杆菌;所述的酵母菌和解磷功能菌只要是无致病性的菌株均可,比如酿酒酵母菌菌株,或者具有解磷功能的解淀粉芽孢杆菌,由于使用方法相同,故仅以上述实施例为例进行说明。It should be noted that the phosphorus-solubilizing functional bacteria described in the present invention are Bacillus with the function of degrading phosphorus; the yeast and the phosphorus-solubilizing functional bacteria can be non-pathogenic strains, such as Saccharomyces cerevisiae strains, or The Bacillus amyloliquefaciens with phosphorus-solubilizing function has the same method of use, so only the above examples are used as an example for illustration.
需要说明的是,本发明中涉及数值范围时,应理解为每个数值范围的两个端点以及两个端点之间任何一个数值均可选用,由于采用的步骤方法与实施例相同,为了防止赘述,本发明描述了优选的实施例。尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。It should be noted that when the present invention involves a numerical range, it should be understood that the two endpoints of each numerical range and any value between the two endpoints can be selected. Since the steps and methods adopted are the same as those in the embodiments, in order to avoid repeating , the invention describes preferred embodiments. While preferred embodiments of the invention have been described, additional changes and modifications to these embodiments can be made by those skilled in the art once the basic inventive concept is appreciated. Therefore, it is intended that the appended claims be construed to cover the preferred embodiment as well as all changes and modifications which fall within the scope of the invention.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, the present invention also intends to include these modifications and variations.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109315103A (en) * | 2018-10-31 | 2019-02-12 | 曲靖促创科技有限公司 | A kind of preventing control method of farmland nitrogen phosphorus pollution of area source |
CN111206027A (en) * | 2020-02-14 | 2020-05-29 | 湖南创清环境技术有限公司 | Magnetic biochar suitable for loading bacillus and preparation method and application thereof |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103071671B (en) * | 2013-02-01 | 2014-04-09 | 江苏省农业科学院 | Method for reducing nitrogen and phosphorus non-point source pollution of dry land |
HK1213910A1 (en) * | 2013-12-12 | 2016-07-15 | Shanghai hengrui pharmaceutical co ltd | Pd-1 antibody, antigen-binding fragment thereof, and medical application thereof pd-1 |
CN105925507A (en) * | 2016-06-02 | 2016-09-07 | 华南农业大学 | Bacillus cereus with heavy metal passivating and plant growth promoting functions and application of bacillus cereus |
CN106012948A (en) * | 2016-06-16 | 2016-10-12 | 中国农业科学院农业资源与农业区划研究所 | Method for preventing and controlling agricultural non-point source pollution of hilly and mountainous regions through nitrogen and phosphorus interception ditches |
CN106591277A (en) * | 2016-12-07 | 2017-04-26 | 华南农业大学 | Immobilized Bacillus having phosphate dissolving and heavy metal passivation functions and preparation method and application thereof |
CN106867945A (en) * | 2017-04-10 | 2017-06-20 | 上海绿乐生物科技有限公司 | The microorganism passivator and its preparation, purposes of a kind of repairing heavy metal in soil pollution |
CN107189973A (en) * | 2017-07-28 | 2017-09-22 | 南京拜思特环保设备有限公司 | A kind of sewage-treating agent and its preparation method and application |
CN107614424A (en) * | 2015-05-15 | 2018-01-19 | 酷星球能源系统股份有限公司 | The charcoal of enhancing |
CN108043873A (en) * | 2017-12-25 | 2018-05-18 | 谢涛 | A kind of heavy metal-polluted soil biological fixation agent and its application process |
CN108083251A (en) * | 2017-12-04 | 2018-05-29 | 广东省生态环境技术研究所 | It is a kind of to improve Soil Nitrogen, the modification biological charcoal and its preparation method and application of phosphorus absorption property |
-
2018
- 2018-06-05 CN CN201810569396.XA patent/CN108636356A/en active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103071671B (en) * | 2013-02-01 | 2014-04-09 | 江苏省农业科学院 | Method for reducing nitrogen and phosphorus non-point source pollution of dry land |
HK1213910A1 (en) * | 2013-12-12 | 2016-07-15 | Shanghai hengrui pharmaceutical co ltd | Pd-1 antibody, antigen-binding fragment thereof, and medical application thereof pd-1 |
CN107614424A (en) * | 2015-05-15 | 2018-01-19 | 酷星球能源系统股份有限公司 | The charcoal of enhancing |
CN105925507A (en) * | 2016-06-02 | 2016-09-07 | 华南农业大学 | Bacillus cereus with heavy metal passivating and plant growth promoting functions and application of bacillus cereus |
CN106012948A (en) * | 2016-06-16 | 2016-10-12 | 中国农业科学院农业资源与农业区划研究所 | Method for preventing and controlling agricultural non-point source pollution of hilly and mountainous regions through nitrogen and phosphorus interception ditches |
CN106591277A (en) * | 2016-12-07 | 2017-04-26 | 华南农业大学 | Immobilized Bacillus having phosphate dissolving and heavy metal passivation functions and preparation method and application thereof |
CN106867945A (en) * | 2017-04-10 | 2017-06-20 | 上海绿乐生物科技有限公司 | The microorganism passivator and its preparation, purposes of a kind of repairing heavy metal in soil pollution |
CN107189973A (en) * | 2017-07-28 | 2017-09-22 | 南京拜思特环保设备有限公司 | A kind of sewage-treating agent and its preparation method and application |
CN108083251A (en) * | 2017-12-04 | 2018-05-29 | 广东省生态环境技术研究所 | It is a kind of to improve Soil Nitrogen, the modification biological charcoal and its preparation method and application of phosphorus absorption property |
CN108043873A (en) * | 2017-12-25 | 2018-05-18 | 谢涛 | A kind of heavy metal-polluted soil biological fixation agent and its application process |
Non-Patent Citations (1)
Title |
---|
许志茹等: "《活性污泥微生物学与分子生物学》", 31 July 2017 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109315103A (en) * | 2018-10-31 | 2019-02-12 | 曲靖促创科技有限公司 | A kind of preventing control method of farmland nitrogen phosphorus pollution of area source |
CN111206027A (en) * | 2020-02-14 | 2020-05-29 | 湖南创清环境技术有限公司 | Magnetic biochar suitable for loading bacillus and preparation method and application thereof |
CN111206027B (en) * | 2020-02-14 | 2023-09-29 | 湖南创清环境技术有限公司 | Magnetic biochar suitable for loading bacillus and preparation method and application thereof |
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