CN108603140B - 增白组合物 - Google Patents
增白组合物 Download PDFInfo
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- CN108603140B CN108603140B CN201680081663.8A CN201680081663A CN108603140B CN 108603140 B CN108603140 B CN 108603140B CN 201680081663 A CN201680081663 A CN 201680081663A CN 108603140 B CN108603140 B CN 108603140B
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- laundry detergent
- detergent composition
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- surfactant
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- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- LTEHWCSSIHAVOQ-UHFFFAOYSA-N tripropyl borate Chemical compound CCCOB(OCCC)OCCC LTEHWCSSIHAVOQ-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- ZUCXUTRTSQLRCV-UHFFFAOYSA-K trisodium;1-amino-4-[3-[[4-chloro-6-(3-sulfonatoanilino)-1,3,5-triazin-2-yl]amino]-2,4,6-trimethyl-5-sulfonatoanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].CC1=C(S([O-])(=O)=O)C(C)=C(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)C(C)=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S([O-])(=O)=O)=C1 ZUCXUTRTSQLRCV-UHFFFAOYSA-K 0.000 description 1
- VZPXDCIISFTYOM-UHFFFAOYSA-K trisodium;1-amino-4-[4-[[4-chloro-6-(3-sulfonatoanilino)-1,3,5-triazin-2-yl]amino]-3-sulfonatoanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC(C=C1S([O-])(=O)=O)=CC=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S([O-])(=O)=O)=C1 VZPXDCIISFTYOM-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
- RGVQNSFGUOIKFF-UHFFFAOYSA-N verdyl acetate Chemical compound C12CC=CC2C2CC(OC(=O)C)C1C2 RGVQNSFGUOIKFF-UHFFFAOYSA-N 0.000 description 1
- YEIGUXGHHKAURB-UHFFFAOYSA-N viridine Natural products O=C1C2=C3CCC(=O)C3=CC=C2C2(C)C(O)C(OC)C(=O)C3=COC1=C23 YEIGUXGHHKAURB-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
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- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
本发明提供一种家用洗衣清洁组合物。
Description
技术领域
本发明涉及清洁洗衣组合物的用途。
背景技术
在家庭洗衣期间保持和改善纺织品的清洁是期望的。
蛋白酶用于洗衣洗涤剂制剂中以从织物上除去含蛋白质的污渍。蛋白酶在低温和短洗涤时间下表现不佳。
需要增加含有蛋白酶的洗衣制剂中的污渍去除，以进行低温快速洗涤。
发明内容
需要在含有蛋白酶的洗衣制剂中增加污渍去除的技术。
我们已经发现，当与蛋白酶一起掺入洗衣洗涤剂中时，所选择的烷氧基化取代酚(ASP)分散剂增加了污渍去除。
在一个方面，本发明提供一种洗衣洗涤剂组合物，其包含：
(i)0.5至20重量％，优选1至10重量％，最优选2至6重量％的具有下列结构的烷氧基化取代酚分散剂：
其中，
X选自：乙氧基；以及乙氧基和丙氧基的混合物，其中乙氧基的数量大于丙氧基的数量，并且其中n为6至70，优选8至34；最优选n选自14；15；16；17；18；19；20；21；22；23；24；25；26；27；28；29；30；31；和32；
优选地，X是乙氧基；
Y选自：R1；OR1；COOR5；F；Cl；Br；I；CN；和NO2，其中R1是C1至C4直链或支链烷基，并且其中R5是C1至C18直链或支链烷基，优选R5是C1至C4直链或支链烷基，最优选R5是甲基；优选Y选自甲基，乙基，甲氧基，乙氧基，最优选甲氧基或甲基；
R2和R3选自：C1至C3直链或支链烷基芳基；和芳基；优选R2和R3选自苯乙烯基和枯基，最优选苯乙烯基，优选R2和R3两者在–O-[X]n-T基团的邻位；
T选自：H；CH3；SO3 -；CH2COO-；PO3 2-；C2H5；正丙基；异丙基；正丁基；叔丁基；和磺基琥珀酸酯盐，T优选为H；
(ii)0至50重量％的除所述烷氧基化取代酚分散剂以外的表面活性剂；优选地，表面活性剂选自：阴离子和非离子表面活性剂，优选地，表面活性剂的水平为4至40重量％，更优选6至30重量％，最优选8至20重量％；优选地，非离子表面活性剂/阴离子表面活性剂的重量分数为0至0.3，优选0至0.15，最优选0.05至0.12；和，
(iii)0.0005至0.2重量％，优选0.002至0.05重量％的蛋白酶。
蛋白酶在本发明的洗衣组合物中的水平是纯蛋白的水平。
优选地，组合物另外包含0.0001至0.5重量％的荧光剂和/或0.0001重量％至0.1重量％的调色染料。
洗衣洗涤剂组合物优选选自颗粒状洗涤剂粉末；和水性洗衣液体洗涤剂；最优选地，洗衣洗涤剂组合物是水性洗衣液体洗涤剂组合物。
另一方面，本发明提供一种处理纺织品的家用方法，所述方法包括以下步骤：
(i)用烷氧基化取代酚分散剂的水溶液处理纺织品，所述水溶液包含10ppm至5000ppm，更优选100ppm至1000ppm的如本文所定义的烷氧基化取代酚分散剂；0.01至1ppm的蛋白酶；和0至6g/L，优选0.2至1g/L的除所述烷氧基化取代酚分散剂以外的表面活性剂；和，
(ii)任选地漂洗和干燥所述纺织品。
在该方法中，水溶液中蛋白酶的水平更优选为0.02至0.2ppm。
在该方法中，表面活性剂是本文优选的类型。
在该方法中，水溶液中香料的水平优选为0.1至100ppm，更优选1至10ppm。
在本发明的方法方面，所用表面活性剂优选为如本发明的组合物方面所优选的。
家用方法优选在家用洗衣机中或通过手洗进行。洗涤温度优选为285至313K。主洗时间优选为5至30分钟。
纺织品优选是衣服、床上用品或桌布的物品。优选的衣服物品是含棉衬衫、裤子、内衣和套头衫。
具体实施方式
烷氧基化取代酚
在本发明的上下文中，烷氧基化取代酚(ASP)不被认为是表面活性剂，并且不会在数值上贡献于如本文所定义的表面活性剂。
最优选的芳基是苯基和取代的苯基。
C1至C3直链或支链烷基芳基是被芳族基团取代的C1至C3直链或支链烷基，例如：苯乙烯基，枯基，苄基。
苯乙烯基是-CH(CH3)Ph；枯基是-C(CH3)2Ph；苄基是CH2Ph，其中Ph是苯基。
值n是烷氧基的摩尔平均数。n的值可以使用NMR测量。
磺基琥珀酸酯盐(sulfoccinate)具有以下结构，描绘为Na盐：
本发明的ASP的结构的实例是：
最优选的ASP结构是：
ASP结合蛋白酶增强污渍去除并减少污垢再沉积，其两者增强织物的白度。
表面活性剂
洗衣组合物可包含阴离子和非离子表面活性剂(其包括它们的混合物)。
表面活性剂体系的非离子和阴离子表面活性剂可以选自“Surface ActiveAgents”，卷1，Schwartz&Perry，Interscience 1949；卷2，Schwartz,Perry&Berch，Interscience 1958；Manufacturing Confectioners Company出版的“McCutcheon'sEmulsifiers and Detergents”的当前版本，或“Tenside-Taschenbuch”，H.Stache，第2版，Carl Hauser Verlag，1981，或Helmut W.Stache编辑的Anionic Surfactants:OrganicChemistry(Marcel Dekker 1996)中描述的表面活性剂。
可以使用的合适的阴离子洗涤剂化合物通常是具有含约8至约22个碳原子的烷基的有机硫酸和磺酸的水溶性碱金属盐，术语烷基用于包括较高级烷基的烷基部分。
合适的合成阴离子洗涤剂化合物的实例是烷基硫酸钠和烷基硫酸钾，特别是通过使例如由牛油或椰油制得的较高级C8至C18醇硫酸化而获得的那些；烷基C9至C20苯磺酸钠和钾，特别是直链仲烷基C10至C15苯磺酸钠；以及烷基甘油醚硫酸钠，特别是衍生自牛油或椰油的较高级醇和衍生自石油的合成醇的那些醚。
阴离子表面活性剂优选选自：直链烷基苯磺酸盐；烷基硫酸盐；烷基醚硫酸盐；烷基醚羧酸；皂；烷基(优选甲基)酯磺酸盐及其混合物。
最优选的阴离子表面活性剂选自：直链烷基苯磺酸盐；烷基硫酸盐；烷基醚硫酸盐及其混合物。优选地，烷基醚硫酸盐是具有平均1至3个EO(乙氧基化物)单元的C12-C14正烷基醚硫酸盐。月桂基醚硫酸钠(SLES)是特别优选的。优选地，直链烷基苯磺酸盐是C11至C15烷基苯磺酸钠。优选地，烷基硫酸盐是直链或支链C12至C18烷基硫酸钠。十二烷基硫酸钠(SDS，也称为伯烷基硫酸盐)是特别优选的。
洗衣组合物中阴离子表面活性剂的水平优选为4至40重量％，更优选6至30重量％，最优选8至20重量％。
优选地，存在两种或更多种阴离子表面活性剂，例如，直链烷基苯磺酸盐与烷基醚硫酸盐一起。
优选地，除阴离子表面活性剂以外，洗衣组合物还包含烷基乙氧基化非离子表面活性剂。
可以使用的合适的非离子洗涤剂化合物包括，特别地，具有脂肪族疏水基团和反应性氢原子的化合物(例如脂族醇、酸或酰胺)与尤其是环氧乙烷(单独或与环氧丙烷一起)的反应产物。具体的非离子洗涤剂化合物是脂肪族C8至C18直链或支链伯或仲醇与环氧乙烷的缩合产物。
优选地，烷基乙氧基化非离子表面活性剂是具有7EO至9EO单元的平均乙氧基化的C8至C18伯醇。
优选地，所用的表面活性剂是饱和的。
同样适用的是表面活性剂，如EP-A-328 177(Unilever)中描述的表现出耐盐析性的那些，EP-A-070 074中描述的烷基多糖苷表面活性剂，和烷基单糖苷。
助洗剂或络合剂
助洗剂材料可以选自1)钙螯合剂材料，2)沉淀材料，3)钙离子交换材料，及4)其混合物。
钙螯合剂助洗剂材料的实例包括碱金属聚磷酸盐，如三聚磷酸钠，和有机螯合剂，如乙二胺四乙酸。
沉淀助洗剂材料的实例包括正磷酸钠和碳酸钠。
钙离子交换助洗剂材料的实例包括各种类型的水不溶性晶体或无定形铝硅酸盐，其中沸石是最有名的代表，例如沸石A、沸石B(也称为沸石P)、沸石C、沸石X、沸石Y以及在EP-A-0,384,070中描述的沸石P型。
组合物还可以含有0至65％的助洗剂或络合剂，如乙二胺四乙酸、二亚乙基三胺五乙酸、烷基或烯基琥珀酸、次氮基三乙酸，或下文所述的其他助洗剂。许多助洗剂因其络合金属离子的能力而同样是漂白稳定剂。
沸石和碳酸盐(碳酸盐(包括碳酸氢盐和倍半碳酸盐))是优选的助洗剂，碳酸盐是特别优选的。
组合物可以含有晶体铝硅酸盐，优选碱金属铝硅酸盐，更优选铝硅酸钠作为助洗剂。这通常以小于15重量％的水平存在。铝硅酸盐是具有以下通式的材料：
0.8-1.5M2O·Al2O3·0.8-6SiO2
其中M是一价阳离子，优选钠。这些材料含有一些结合水并需要具有至少50mgCaO/g的钙离子交换容量。优选的铝硅酸钠在上式中含有1.5-3.5个SiO2单元。它们可以通过硅酸钠与铝酸钠之间的反应容易地制备，如文献中所充分描述的。表面活性剂与铝硅酸盐(存在时)的比率优选大于5:2，更优选大于3:1。
替代性地，或除铝硅酸盐助洗剂以外地，可以使用磷酸盐助洗剂。在本领域中术语“磷酸盐”包括二磷酸盐、三磷酸盐和膦酸盐种类。助洗剂的其他形式包括硅酸盐，例如可溶性硅酸盐、偏硅酸盐、层状硅酸盐(例如来自Hoechst的SKS-6)。
优选地，洗衣洗涤剂制剂是非磷酸盐助洗的洗衣洗涤剂制剂，即含有少于1重量％的磷酸盐。优选地，粉末洗衣洗涤剂制剂主要是碳酸盐助洗的。粉末，应优选给出使用中pH为9.5至11。
最优选地，洗衣洗涤剂是水性液体洗衣洗涤剂，优选pH为7至9。
在水性液体洗衣洗涤剂中，优选单丙二醇以1至30重量％，最优选2至18重量％的水平存在，以提供具有适当的、可倾倒的粘度的制剂。
荧光剂
组合物优选地包含荧光剂(光学增亮剂)。荧光剂是众所周知的，并且许多这样的荧光剂是可商购的。通常，这些荧光剂以其碱金属盐，例如钠盐的形式供应和使用。
优选的荧光剂类别是：二苯乙烯基联苯化合物，如Tinopal(商标)CBS-X；二胺二苯乙烯二磺酸化合物，如Tinopal DMS pure Xtra和Blankophor(商标)HRH；以及吡唑啉化合物，如Blankophor SN。
优选的荧光剂是：2(4-苯乙烯基-3-磺苯基)-2H-萘酚[1,2-d]三唑钠、4,4'-双{[(4-苯胺基-6-(N甲基-N-2羟乙基)氨基1,3,5-三嗪-2-基)]氨基}二苯乙烯-2,2'二磺酸二钠、4,4'-双{[(4-苯胺基-6-吗啉基-1,3,5-三嗪-2-基)]氨基}二苯乙烯-2-2'二磺酸二钠，和4,4'-双(2-磺苯乙烯基)联苯二钠。
用于组合物中的一种或多种荧光剂的总量优选为0.0001至0.5重量％，更优选0.005至2重量％，最优选0.05至0.25重量％。
用于该方法的水溶液具有荧光剂存在。荧光剂存在于用于该方法的水溶液中，优选在0.0001g/l至0.1g/l，更优选0.001至0.02g/l的范围内。
香料
组合物优选包含香料。香料优选地在0.001至3重量％，更优选0.05至0.5重量％，最优选0.1至1重量％范围内。香料的许多合适的实例在由CFTA Publications出版的CTFA(Cosmetic,Toiletry and Fragrance Association)1992International Buyers Guide和由Schnell Publishing Co.出版的OPD 1993Chemicals Buyers Directory 80th AnnualEdition中提供。
优选地，香料包含以下的至少一种香型(note)(化合物)：α-异甲基紫罗酮，水杨酸苄酯；香茅醇；香豆素；己基肉桂醛；芳樟醇；2-甲基戊酸乙基酯；辛醛；乙酸苄酯；3,7-二甲基-1,6-辛二烯-3-醇3-乙酸酯；2-(1,1-二甲基乙基)-环己醇1-乙酸酯；δ-大马酮(damascone)；β-紫罗酮；乙酸三环癸烯酯(verdyl acetate)；十二醛；己基肉桂醛(hexylcinnamic aldehyde)；环十五内酯；苯乙酸2-苯基乙基酯；水杨酸戊酯；β-石竹烯；十一碳烯酸乙酯；邻氨基苯甲酸香叶酯；α-鸢尾酮；β-苯基乙基苯甲酸酯；α-檀香醇；雪松醇；乙酸柏木酯；甲酸柏木酯(cedry formate)；水杨酸环己酯；γ-十二内酯，和β-苯乙基苯基乙酸酯。
香料的可用组分包括天然和合成来源二者的材料。它们包括单一化合物和混合物。这样的组分的具体实例可见于现有文献，例如，Fenaroli's Handbook of FlavorIngredients，1975，CRC Press；Synthetic Food Adjuncts，1947，M.B.Jacobs著，VanNostrand编辑；或Perfume and Flavor Chemicals，S.Arctander著，1969，Montclair,N.J.(USA)中。
在制剂中存在多种香料组分是常见的。在本发明的组合物中，设想将存在四种或更多种、优选五种或更多种、更优选六种或更多种、或甚至七种或更多种不同的香料组分。
在香料混合物中，优选15至25重量％是头香。头香是由Poucher(Journal of theSociety of Cosmetic Chemists 6(2):80[1955])所定义的。优选的头香选自柑桔油、芳樟醇、乙酸芳樟酯、薰衣草、二氢月桂烯醇、氧化玫瑰和顺-3-己醇。
国际日用香精香料协会已在2011年发布了香氛成分(香料)的清单。(http://www.ifraorg.org/en-us/ingredients#.U7Z4hPldWzk)。
国际日用香料研究所提供了具有安全性信息的香料(香氛)数据库。
香料头香可用于提示本发明的白度和亮度益处。
一些或所有香料可以被包封，有利于包封的典型香料组分包括具有相对低的沸点的那些，优选沸点小于300℃，优选为100-250℃的那些。包封具有低Clog P(即，将具有被分配到水中的更高倾向的那些)，优选具有小于3.0的CLog P的香料组分也是有利的。这些具有相对低沸点和相对低CLog P的材料已经被称为“延迟释香(delayed blooming)”的香料成分，并且包含以下材料中的一种或多种：
己酸烯丙酯、乙酸戊酯、丙酸戊酯、茴香醛、苯甲醚、苯甲醛、乙酸苄酯、苄基丙酮、苯甲醇、甲酸苄酯、异戊酸苄酯、丙酸苄酯、β-γ己烯醇、樟脑胶、左旋-香芹酮、d-香芹酮、肉桂醇、甲酸肉桂酯(cinamyl formate)、顺-茉莉酮、顺-3-己烯基乙酸酯、枯茗醇、cyclal c、二甲基苄基甲醇、二甲基苄基甲醇乙酸酯、乙酸乙酯、乙酰乙酸乙酯、乙基戊基酮、苯甲酸乙酯、丁酸乙酯、乙基己基酮、乙基苯基乙酸酯、桉树脑、丁香酚、乙酸葑酯(fenchylacetate)、flor acetate(三环癸烯基乙酸酯)、frutene(三环癸烯基丙酸酯)、香叶醇、己烯醇、乙酸己烯酯、乙酸己酯、甲酸己酯、龙葵醇(hydratropic alcohol)、羟基香茅醛、茚酮、异戊醇、异薄荷酮、乙酸异胡薄荷酯(isopulegyl acetate)、异喹啉酮、女贞醛、芳樟醇、芳樟醇氧化物、甲酸芳樟酯、薄荷酮、薄荷基苯乙酮(menthyl acetphenone)、甲基戊基酮、邻氨基苯甲酸甲酯、苯甲酸甲酯、甲基苄基乙酸酯(methyl benyl acetate)、甲基丁香酚、甲基庚烯酮、甲基庚炔碳酸酯(methyl heptine carbonate)、甲基庚基酮、甲基己基酮、甲基苯基甲基乙酸酯、水杨酸甲酯、甲基-n-甲基邻氨基苯甲酸酯、橙花醇、辛内酯、辛醇、对甲酚、对甲酚甲基醚、对甲氧基苯乙酮、对甲基苯乙酮、苯氧乙醇、苯基乙醛、苯基乙基乙酸酯、苯基乙基醇、苯基乙基二甲基甲醇、乙酸异戊二烯酯、propyl bornate、胡薄荷酮、氧化玫瑰、黄樟素、4-萜品烯醇(4-terpinenol)、α-萜品烯醇和/或苯乙醛二甲醇缩醛(viridine)。多种香料组分存在于制剂中是常见的。在本发明的组合物中，设想将有来自上文给出的延迟释香香料的给定列表的四种或更多种，优选五种或更多种，更优选六种或更多种，或甚至七种或更多种不同的香料组分存在于香料中。
可以与本发明一起应用的另一组香料是所谓的“芳香疗法”材料。这些包括也用于香水中的许多组分，包括精油的组分，如鼠尾草、桉树、天竺葵、薰衣草、肉豆蔻干皮(Mace)提取物、橙花油、肉豆蔻、留兰香、甜紫罗兰叶和缬草。
优选的是洗衣处理组合物不含过氧漂白剂，例如过碳酸钠，过硼酸钠和过酸。
聚合物
组合物可以含有一种或多种另外的聚合物。实例是羧甲基纤维素、聚(乙二醇)、聚(乙烯醇)、聚羧酸盐如聚丙烯酸盐、马来酸/丙烯酸共聚物和甲基丙烯酸月桂酯/丙烯酸共聚物。
存在以防止染料沉积的聚合物可以存在，例如聚(乙烯基吡咯烷酮)、聚(乙烯基吡啶-N-氧化物)和聚(乙烯基咪唑)。
调色染料
染料在Color Chemistry Synthesis,Properties and Applications ofOrganic Dyes and Pigments(H Zollinger，Wiley VCH，Zürich，2003)和Industrial DyesChemistry,Properties Applications(K Hunger(ed)，Wiley-VCH Weinheim 2003)中描述。
用于洗衣洗涤剂的调色染料优选在可见光范围(400-700nm)中的最大吸收处具有大于5000L mol-1cm-1，优选大于10000L mol-1cm-1的消光系数。染料的颜色是蓝色或紫色。
优选的调色染料发色团是偶氮、吖嗪、蒽醌和三苯甲烷。
偶氮、蒽醌、酞菁和三苯甲烷染料优选带有净阴离子电荷或不带电荷。吖嗪优选带有净阴离子或阳离子电荷。在洗涤过程的洗涤或漂洗步骤期间，蓝色或紫色调色染料沉积到织物上，从而为织物提供可见的色调。在这方面，染料对白色布料赋予蓝色或紫色，色调角为240至345、更优选250至320、最优选250至280。该测试中使用的白色布料是经漂白的、非丝光处理的编织棉片。
调色染料在WO2005/003274，WO2006/032327(Unilever)，WO2006/032397(Unilever)，WO2006/045275(Unilever)，WO2006/027086(Unilever)，WO2008/017570(Unilever)，WO2008/141880(Unilever)，WO2009/132870(Unilever)，WO2009/141173(Unilever)，WO2010/099997(Unilever)，WO2010/102861(Unilever)，WO2010/148624(Unilever)，WO2008/087497(P&G)，WO2011/011799(P&G)，WO2012/054820(P&G)，WO2013/142495(P&G)和WO2013/151970(P&G)中讨论。
单偶氮染料优选含有杂环，并且最优选是噻吩染料。单偶氮染料优选是烷氧基化的，并且优选在pH＝7时不带电荷或带阴离子电荷。烷氧基化噻吩染料在WO/2013/142495和WO/2008/087497中讨论。噻吩染料的优选实例如下所示：
双偶氮染料优选为磺化双偶氮染料。磺化双偶氮化合物的优选实例是直接紫7，直接紫9，直接紫11，直接紫26，直接紫31，直接紫35，直接紫40，直接紫41，直接紫51，直接紫66，直接紫99及其烷氧基化形式。烷氧基化双偶氮染料在WO2012/054058和WO2010/151906中讨论。
烷氧基化双偶氮染料的实例是：
吖嗪染料优选选自磺化吩嗪染料和阳离子吩嗪染料。优选的实例是酸性蓝98，酸性紫50，CAS号为72749-80-5的染料，酸性蓝59，以及选自以下的吩嗪染料：
其中：
X3选自：-H，-F，-CH3，-C2H5，-OCH3和-OC2H5；
X4选自：-H，-CH3，-C2H5，-OCH3和-OC2H5；
Y2选自：-OH，-OCH2CH2OH，-CH(OH)CH2OH，-OC(O)CH3和C(O)OCH3。
调色染料以0.0001至0.5重量％、优选0.001至0.1重量％的范围存在于组合物中。取决于调色染料的性质，存在取决于调色染料的效力的优选范围，所述调色染料的效力取决于类别和任何特定类别内的具体效力。如上所述，调色染料是蓝色或紫色调色染料。
可以使用调色染料的混合物。
调色染料最优选是与烷氧基化聚乙烯亚胺共价连接的活性蓝色蒽醌染料。烷氧基化优选选自乙氧基化和丙氧基化，最优选丙氧基化。优选地，通过丙氧基化将聚乙烯亚胺中80至95摩尔％的N-H基团替换为异丙醇基团。优选地，在与染料反应和丙氧基化之前，聚乙烯亚胺的分子量为600至1800。
共价连接到丙氧基化聚乙烯亚胺的优选活性蒽醌的实例结构是：
优选的活性蒽醌染料是：活性蓝1，活性蓝2，活性蓝4，活性蓝5，活性蓝6，活性蓝12，活性蓝16，反应性蓝19，活性蓝24，活性蓝27，活性蓝29，活性蓝36，活性蓝44，活性蓝46，活性蓝47，活性蓝49，活性蓝50，活性蓝53，活性蓝55，活性蓝61，活性蓝66，活性蓝68，活性蓝69，活性蓝74，活性蓝86，活性蓝93，活性蓝94，活性蓝101，活性蓝103，活性蓝114，活性蓝117，活性蓝125，活性蓝141，活性蓝142，活性蓝145，活性蓝149，活性蓝155，活性蓝164，活性蓝166，活性蓝177，活性蓝181，活性蓝185，活性蓝188，活性蓝189，活性蓝206，活性蓝208，活性蓝246，活性蓝247，活性蓝258，活性蓝261，活性蓝262，活性蓝263和活性蓝172。
染料根据颜色指数(Society of Dyers and Colourists/American Associationof Textile Chemists and Colorists)分类列出。
蛋白酶
蛋白酶水解肽和蛋白质内的键，在洗衣环境中，这导致对含有蛋白质或肽的污渍的去除增强。合适的蛋白酶家族的实例包括天冬氨酸蛋白酶，半胱氨酸蛋白酶，谷氨酸蛋白酶，天冬酰胺(aspargine)肽裂解酶，丝氨酸蛋白酶和苏氨酸蛋白酶。这样的蛋白酶家族在MEROPS肽酶数据库(http://merops.sanger.ac.uk/)中描述。丝氨酸蛋白酶是优选的。枯草杆菌酶(Subtilase)型丝氨酸蛋白酶是更优选的。根据Siezen等，Protein Engng.4(1991)719-737和Siezen等，Protein Science 6(1997)501-523，术语“枯草杆菌酶”是指丝氨酸蛋白酶的亚组。丝氨酸蛋白酶是特征在于在活性位点具有丝氨酸的蛋白酶的亚组，该丝氨酸与底物形成共价加合物。枯草杆菌酶可以分为6个亚分类，即枯草杆菌蛋白酶(Subtilisin)家族，嗜热蛋白酶(Thermitase)家族，蛋白酶K家族，羊毛硫氨酸抗生素(Lantibiotic)肽酶家族，Kexin家族和Pyrolysin家族。
枯草杆菌酶的实例是源自芽孢杆菌例如在US7262042和WO09/021867中描述的迟缓芽孢杆菌，嗜碱芽孢杆菌，枯草芽孢杆菌，解淀粉芽孢杆菌，短小芽孢杆菌和吉氏芽孢杆菌的那些，以及在WO89/06279中描述的迟缓枯草杆菌蛋白酶(subtilisin lentus)，枯草杆菌蛋白酶Novo，枯草杆菌蛋白酶Carlsberg，地衣芽孢杆菌，枯草杆菌蛋白酶BPN’，枯草杆菌蛋白酶309，枯草杆菌蛋白酶147和枯草杆菌蛋白酶168，以及在WO93/18140中描述的蛋白酶PD138。其它有用的蛋白酶可以是WO92/175177，WO01/016285，WO02/026024和WO02/016547中描述的那些。胰蛋白酶样蛋白酶的实例是WO89/06270，WO94/25583和WO05/040372中描述的胰蛋白酶(例如，猪或牛来源的)和镰刀菌蛋白酶，以及在WO05/052161和WO05/052146中描述的源自纤维单胞菌属(Cellumonas)的糜蛋白酶。
有用的蛋白酶的另一些实例是在WO92/19729，WO96/034946，WO98/20115，WO98/20116，WO99/011768，WO01/44452，WO03/006602，WO04/03186，WO04/041979，WO07/006305，WO11/036263，WO11/036264中描述的变体，特别是具有在使用BPN’编号的以下位置的一个或多个中的置换的变体：3，4，9，15，27，36，57，68，76，87，95，96，97，98，99，100，101，102，103，104，106，118，120，123，128，129，130，160，167，170，194，195，199，205，206，217，218，222，224，232，235，236，245，248，252和274。更优选的枯草杆菌酶变体可以包含以下突变：S3T,V4I,S9R,A15T,K27R,*36D,V68A,N76D,N87S,R,*97E,A98S,S99G,D,A,S99AD,S101G,M,RS103A,V104I,Y,N,S106A,G118V,R,H120D,N,N123S,S128L,P129Q,S130A,G160D,Y167A,R170S,A194P,G195E,V199M,V205I,L217D,N218D,M222S,A232V,K235L,Q236H,Q245R,N252K,T274A(使用BPN’编号)。
最优选地，蛋白酶是枯草杆菌蛋白酶(EC 3.4.21.62)。
枯草杆菌酶的实例是源自芽孢杆菌例如在US7262042和WO09/021867中描述的迟缓芽孢杆菌，嗜碱芽孢杆菌，枯草芽孢杆菌，解淀粉芽孢杆菌，短小芽孢杆菌和吉氏芽孢杆菌的那些，以及在WO89/06279中描述的迟缓枯草杆菌蛋白酶，枯草杆菌蛋白酶Novo，枯草杆菌蛋白酶Carlsberg，地衣芽孢杆菌，枯草杆菌蛋白酶BPN’，枯草杆菌蛋白酶309，枯草杆菌蛋白酶147和枯草杆菌蛋白酶168，以及在WO93/18140中描述的蛋白酶PD138。优选地，枯草杆菌蛋白酶源自芽孢杆菌，优选迟缓芽孢杆菌，嗜碱芽孢杆菌，枯草芽孢杆菌，解淀粉芽孢杆菌，短小芽孢杆菌和吉氏芽孢杆菌，如US 6,312,936B1，US 5,679,630，US 4,760,025，US7,262,042和WO09/021867中所述。最优选地，枯草杆菌蛋白酶源自吉氏芽孢杆菌或迟缓芽孢杆菌。
合适的可商购蛋白酶包括以商品名
DuralaseTM，DurazymTM，
Ultra，
Ultra，
Ultra，
Ultra，
和
销售的那些，所有都可作为
或
(Novozymes A/S)销售。
由Genencor International以商品名
Purafect
Purafect
和Purafect
销售的那些。
以商品名
Purafect
PreferenzTM，Purafect
Purafect
Purafect
EffectenzTM，
和
(Danisco/DuPont)，AxapemTM(Gist-Brocases N.V.)销售的那些。
可获自Henkel/Kemira的那些，即BLAP(在US 5,352,604附图29中示出的序列，具有以下突变：S99D+S101R+S103A+V104I+G159S；在下文中称为BLAP)，BLAP R(具有S3T+V4I+V199M+V205I+L217D的BLAP)，BLAP X(具有S3T+V4I+V205I的BLAP)和BLAP F49(具有S3T+V4I+A194P+V199M+V205I+L217D的BLAP)，所有都来自Henkel/Kemira；以及KAP(具有A230V+S256G+S259N突变的嗜碱芽孢杆菌枯草杆菌蛋白酶)，来自Kao。
另外的酶
一种或多种另外的酶优选存在于本发明的洗衣组合物以及当实施本发明的方法时存在。
优选地，本发明的洗衣组合物中的每个酶的水平为0.0001重量％至0.1重量％蛋白质。
优选地，另外的酶选自：α-淀粉酶；脂肪酶；和纤维素酶，优选蛋白酶。
合适的脂肪酶包括具有细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。有用的脂肪酶的实例包括来自以下的脂肪酶：腐质霉(Humicola)(同义词嗜热真菌(Thermomyces))，例如来自EP 258 068和EP 305 216中所述的H.lanuginosa(T.lanuginosus)或来自WO 96/13580中所述的H.insolens；假单胞菌脂肪酶，例如来自产碱假单胞菌(P.alcaligenes)或假产碱假单胞菌(P.pseudoalcaligenes)(EP 218 272)、洋葱假单胞菌(P.cepacia)(EP 331 376)、施氏假单胞菌(P.stutzeri)(GB 1,372,034)、荧光假单胞菌(P.fluorescens)，假单胞菌菌株SD 705(WO 95/06720和WO 96/27002)、P.wisconsinensis(WO 96/12012)；芽孢杆菌脂肪酶，例如来自枯草芽孢杆菌(B.subtilis)(Dartois等(1993),Biochemica et Biophysica Acta,1131,253-360)、嗜热脂肪芽孢杆菌(B.stearothermophilus)(JP 64/744992)或短小芽孢杆菌(B.pumilus)(WO 91/16422)。其他实例是脂肪酶变体，例如在WO 92/05249、WO 94/01541、EP 407 225、EP 260 105、WO 95/35381、WO 96/00292、WO 95/30744、WO 94/25578、WO 95/14783、WO 95/22615、WO 97/04079和WO 97/07202、WO 00/60063中描述的那些。
优选的可商购脂肪酶包括LipolaseTM和Lipolase UltraTM、LipexTM和LipocleanTM(Novozymes A/S)。
本发明的方法可以在分类为EC 3.1.1.4和/或EC 3.1.1.32的磷脂酶存在下进行。如在本文中所使用的，术语磷脂酶是对磷脂具有活性的酶。
磷脂，例如卵磷脂或磷脂酰胆碱，由在外部(sn-1)和中间(sn-2)位置被两个脂肪酸酯化，并在第三位置被磷酸酯化的甘油组成；磷酸反过来可以被酯化成氨基醇。磷脂酶是参与磷脂水解的酶。可以区分磷脂酶活性的多种类型，包括磷脂酶A1和A2，其水解一个脂肪酰基(分别在sn-1和sn-2位置)以形成溶血磷脂；和溶血磷脂酶(或磷脂酶B)，其可以水解溶血磷脂中剩余的脂肪酰基。磷脂酶C和磷脂酶D(磷酸二酯酶)分别释放二酰基甘油或磷脂酸。
本发明的方法可以在分类为EC 3.1.1.74的角质酶的存在下进行。根据本发明使用的角质酶可以具有任何来源。优选地，角质酶具有微生物来源，特别是细菌、真菌或酵母来源。
合适的淀粉酶(α和/或β)包括具有细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。淀粉酶包括例如获自芽孢杆菌，如在GB 1,296,839中更详细描述的地衣芽孢杆菌的特殊菌株，或在WO 95/026397或WO 00/060060中公开的芽孢杆菌菌株的α-淀粉酶。可商购的淀粉酶是DuramylTM、TermamylTM、Termamyl UltraTM、NatalaseTM、StainzymeTM、FungamylTM和BANTM(Novozymes A/S)、RapidaseTM和PurastarTM(来自GenencorInternational Inc.)。
合适的纤维素酶包括具有细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。合适的纤维素酶包括来自以下的纤维素酶：芽孢杆菌属、假单胞菌属、腐质霉属、镰刀菌属、梭孢壳属、支顶孢属，例如从公开于US 4,435,307、US 5,648,263、US 5,691,178、US 5,776,757、WO 89/09259、WO 96/029397和WO 98/012307的特异腐质霉、太瑞斯梭孢壳霉、嗜热毁丝霉和尖孢镰刀菌产生的真菌纤维素酶。可商购的纤维素酶包括CelluzymeTM、CarezymeTM、CellucleanTM、EndolaseTM、RenozymeTM(Novozymes A/S)、ClazinaseTM和Puradax HATM(Genencor International Inc.)和KAC-500(B)TM(KaoCorporation)。CellucleanTM是优选的。
合适的过氧化物酶/氧化酶包括具有植物、细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。有用的过氧化物酶的实例包括来自鬼伞属，例如来自灰盖鬼伞的过氧化物酶，及其变体，如在WO 93/24618、WO 95/10602和WO 98/15257中所述的那些。可商购的过氧化物酶包括GuardzymeTM和NovozymTM 51004(Novozymes A/S)
另外的适用的酶在WO2009/087524、WO2009/090576、WO2009/107091、WO2009/111258和WO2009/148983中讨论。
酶稳定剂
存在于组合物中的任何酶可以使用常规的稳定剂稳定化，例如多元醇，如丙二醇或甘油；糖或糖醇；乳酸；硼酸或硼酸衍生物，例如芳族硼酸酯，或苯基硼酸衍生物，如4-甲酰基苯基硼酸，以及可以如例如WO 92/19709和WO 92/19708中所述配制的组合物。
当烷基足够长以形成支链或环状链时，烷基包括支链、环状和直链烷基链。烷基优选是直链或支链的，更优选直链的。
除非另有规定，如本文中所用不定冠词“一个/种(a或an)”及其对应的定冠词“所述/该(the)”指的是至少一个/种，或一个/种或多个/种。
试验
实施例1
制备具有以下制剂的水性液体洗衣洗涤剂：
| 成分 | 重量％ |
| 单丙二醇 | 2.2 |
| 三乙胺 | 1.5 |
| 具有7摩尔环氧乙烷的C<sub>12</sub>-C<sub>15</sub>醇乙氧基化物 | 1.2 |
| 直链烷基苯磺酸盐 | 4.6 |
| 具有1摩尔环氧乙烷的月桂基聚醚硫酸酯钠 | 5.8 |
| 柠檬酸 | 2.0 |
| CaCl<sub>2</sub>二水合物 | 0.2 |
| NaCl | 0.2 |
| Tinopal CBS-X(荧光剂BASF) | 0.3 |
| 氢氧化钠 | 至pH＝8.4 |
| ASP分散剂 | 参见文字 |
| 水 | 余量 |
该制剂用于在设定为200rpm的测试仪(tergotometer)中洗涤8块5×5cm的EMPA117污渍监视物(聚酯棉布上的血液/牛奶/墨水污渍)。在25℃下在800ml的26°法国硬水中进行20分钟洗涤，制剂为2.3g/L。为了模拟油性污垢，将7.2g的SBL2004油性条带(来自Warwick Equest)加入洗涤液中。
洗涤完成后，将棉监视物在400ml清水中漂洗一次，取出干燥并在反射计上测量颜色，并表示为CIE L*a*b*值。
相同制剂，但加入8.7重量％的以下ASP分散剂(n＝20)：
在向洗液添加和不添加枯草杆菌蛋白酶丝氨酸蛋白酶(EC no.232-752-2)的情况下重复实验(
16L，来自Novozymes)。添加酶以向制剂提供0.009重量％纯活性蛋白质。
还从8个监视物的测量值的标准偏差计算95％置信限。
洗涤完成后，将棉监视物在400ml清水中漂洗一次，取出干燥并在反射计上测量颜色，并表示为CIE L*a*b*值。清洁抗再沉积益处表示为ΔL值：
ΔL＝L(分散剂)-L(对照)
ΔL值越大，对炭黑污垢沉积的阻止程度越大。计算基于8个独立棉监视物的95％置信限。在添加和不添加8.7重量％分散剂的情况下制备制剂：
清洁益处表示为ΔL值：
ΔL＝L(测试)-L(对照)
ΔL值越大，对炭黑污垢沉积的阻止程度越大。
| 测试 | ΔL | 95％ |
| 蛋白酶 | 1.55 | 0.60 |
| ASP分散剂 | 1.32 | 0.41 |
| 蛋白酶+ASP分散剂 | 4.05 | 0.44 |
单独的ASP分散剂和单独的蛋白酶增强污渍去除。当组合两者时看到进一步的增加，并且ΔL＝4.05大于通过将个体性能相加所预期的，1.55+1.32＝2.88。
Claims (15)
1.一种洗衣洗涤剂组合物，其包含：
(i)0.5至20重量％的具有以下结构的烷氧基化取代酚分散剂：
其中，
X选自：乙氧基；以及乙氧基和丙氧基的混合物，其中乙氧基的数量大于丙氧基的数量，并且其中n为6至70；
Y选自：R1和OR1，其中R1是C1至C4直链或支链烷基；
R2和R3选自：苯乙烯基和枯基；
T选自：H；CH3；SO3 -；CH2COO-；PO3 2-；C2H5；正丙基；异丙基；正丁基；叔丁基；和磺基琥珀酸酯盐；
(ii)0至50重量％的除所述烷氧基化取代酚以外的表面活性剂；和，
(iii)0.0005至0.2重量％的蛋白酶。
2.根据权利要求1所述的洗衣洗涤剂组合物，其中R2和R3是苯乙烯基，并且R2和R3两者在-O-[X]n-T基团的邻位。
3.根据权利要求1或2所述的洗衣洗涤剂组合物，其中X是乙氧基。
4.根据权利要求1或2所述的洗衣洗涤剂组合物，其中n为8至34。
5.根据权利要求1或2所述的洗衣洗涤剂组合物，其中所述表面活性剂选自：阴离子和非离子表面活性剂，并且表面活性剂的水平为4至40重量％。
6.根据权利要求5所述的洗衣洗涤剂组合物，其中所述阴离子表面活性剂选自：直链烷基苯磺酸盐；烷基硫酸盐；和烷基醚硫酸盐；及其混合物。
7.根据权利要求1或2所述的洗衣洗涤剂组合物，其中非离子表面活性剂/阴离子表面活性剂的重量分数为0至0.3。
8.根据权利要求7所述的洗衣洗涤剂组合物，其中所述阴离子表面活性剂选自：直链烷基苯磺酸盐；烷基硫酸盐；和烷基醚硫酸盐；及其混合物。
9.根据权利要求1或2所述的洗衣洗涤剂组合物，其中所述烷氧基化取代酚分散剂的水平为1至10重量％。
10.根据权利要求1或2所述的洗衣洗涤剂组合物，其中T为H。
11.根据权利要求1或2所述的洗衣洗涤剂组合物，其中Y选自：甲基；乙基；甲氧基；和乙氧基。
12.根据权利要求1所述的洗衣洗涤剂组合物，其中所述烷氧基化取代酚分散剂是：
并且所述蛋白酶是枯草杆菌蛋白酶(EC 3.4.21.62)。
13.根据权利要求1或2所述的洗衣洗涤剂组合物，其中n选自：14；15；16；17；18；19；20；21；22；23；24；25；26；27；28；29；30；31；和32。
14.一种处理纺织品的家用方法，所述方法包括以下步骤：
(i)用烷氧基化取代酚分散剂的水溶液处理纺织品，所述水溶液包含10ppm至5000ppm的前述权利要求中任一项所定义的烷氧基化取代酚分散剂；0.01至1ppm的蛋白酶；和0至6g/L的除所述烷氧基化取代酚分散剂以外的表面活性剂；和，
(ii)任选地漂洗和干燥所述纺织品。
15.根据权利要求14所述的处理纺织品的家用方法，其中在所述方法中，所述蛋白酶是枯草杆菌蛋白酶(EC 3.4.21.62)。
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2023227356A1 (en) * | 2022-05-27 | 2023-11-30 | Unilever Ip Holdings B.V. | Composition containing enzyme |
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2016
- 2016-11-23 CN CN201680081663.8A patent/CN108603140B/zh active Active
- 2016-11-23 WO PCT/EP2016/078515 patent/WO2017140392A1/en active Application Filing
- 2016-11-23 EP EP16798783.3A patent/EP3417040B1/en active Active
- 2016-11-23 BR BR112018016674-0A patent/BR112018016674B1/pt active IP Right Grant
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Also Published As
| Publication number | Publication date |
|---|---|
| CN108603140A (zh) | 2018-09-28 |
| ZA201804919B (en) | 2019-09-25 |
| BR112018016674A2 (pt) | 2018-12-26 |
| BR112018016674B1 (pt) | 2022-06-07 |
| AR107626A1 (es) | 2018-05-16 |
| WO2017140392A1 (en) | 2017-08-24 |
| EP3417040B1 (en) | 2019-09-04 |
| EP3417040A1 (en) | 2018-12-26 |
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