CN108588792A - A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing - Google Patents
A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing Download PDFInfo
- Publication number
- CN108588792A CN108588792A CN201810852282.6A CN201810852282A CN108588792A CN 108588792 A CN108588792 A CN 108588792A CN 201810852282 A CN201810852282 A CN 201810852282A CN 108588792 A CN108588792 A CN 108588792A
- Authority
- CN
- China
- Prior art keywords
- steel wire
- room temperature
- ultrasonic
- wire drawing
- electrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/36—Phosphatising
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/005—Apparatus specially adapted for electrolytic conversion coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/06—Wires; Strips; Foils
- C25D7/0607—Wires
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Extraction Processes (AREA)
Abstract
The present invention relates to a kind of room temperature ultrasonic electrolysis parkerizing methods and device for before steel wire drawing, this method mainly carries out at normal temperatures, by connection anode inert metal graphite and connection cathode anticipated between disk steel wire apply DC voltage carry out electrolysis processing, and it is equipped with supersonic generator in the bottom of Phosphating Slot, assists the alramenting of steel wire to react by the cavitation of ultrasonic wave.The present invention has the advantages that the phosphating reaction time is short, it is good hardly to generate precipitation, energy conservation and environmental protection, film-formation result.
Description
Technical field
The present invention provides a kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, belongs to phosphatization
Technical field.
Background technology
Metal surface phosphating refers to being surface-treated to metal with phosphorization reagent, one layer uniform, thin in its Surface Creation
The process of close, wear-resisting, corrosion resistant phosphating coat.
It is mainly used for the alramenting of iron and steel parts in practical applications, but non-ferrous metal is as the workpiece such as aluminium, zinc also can be into
Row phosphorating treatment.
It carries out phosphorating treatment before steel wire drawing to be primarily due to, the phosphating coat that steel wire surface is formed can improve lubrication effect
Rate is generated under very high pressure condition all in metal surface as zinc phosphating film can react with stearate lubricant
It is the zinc stearate of fabulous lubriation material, drawing speed can be greatly improved, extend die life, improves finished product rate.
There is many defects for traditional phosphating process：
1, traditional most of phosphating process needs to carry out at a relatively high temperature, and the parkerized time also compares
It is long, the loss of the energy and the increase of sediment can be caused in this way；
2, traditional room temperature, low temperature phosphor processing need that some other accelerating agents such as oxidant, neutralizer etc. are added to accelerate into
Film speed improves phosphorization film quality in turn, therefore a series of side reaction can be caused to occur, and keeps film forming procedure complicated and makes phosphatization
Liquid generates a large amount of precipitations；
3, traditional phosphating process often will produce environmentally harmful substance in process of production, to working for a long time in the occasion
The life security of worker there is huge threats.
Room temperature electrolytic phosphating process reaction speed is fast, low energy consumption, but the phosphating coat Film Thickness Ratio high temperature chemistry phosphatization formed
Phosphating coat want thin, the steel wire than high temperature chemistry phosphatization is more easy to occur fracture of wire and overproof during the drawing process.
Invention content
The object of the present invention is to provide a kind of working environment that can be overcome drawbacks described above, worker can be improved, at normal temperatures
A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing that can be reacted.Its technology contents is
：
A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, including supersonic generator, ultrasound
Wave transducer, ultrasonic variable amplitude bar, Phosphating Slot, cross-over block, inert electrode graphite, DC power supply and holder, it is characterised in that：
Phosphating Slot is fixed on holder, and the bottom of Phosphating Slot is fixedly connected through amplitude transformer with energy converter, the wiring termination of ultrasonic transducer
The power output end of supersonic generator；Workpiece is connected on the cathode of DC power supply as cathode in Phosphating Slot, and graphite is as sun
Pole is connected on the anode of DC power supply.
A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, ultrasonic amplitude transformer
Top and bottom and the connection of Phosphating Slot and ultrasonic transducer are tightly fastened using epoxy resin and screw two ways.
A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, the bottom of Phosphating Slot
Using cross-over block.
A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, ultrasonic transducer
Vibration frequency is 20KHz ~ 40KHz.
A kind of described room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, DC power supply it is defeated
It is 0 ~ 30V to go out voltage range, and current range is 0 ~ 10A.
Its working principle is that：Zinc phosphating solution is filled in Phosphating Slot, and the steel wire after ultrasonic degreasing, derusting is put into phosphatization
In slot, supersonic generator is opened, the frequency of supersonic generator is adjusted, steel wire is accessed to the cathode of DC power supply, by graphite
The anode for accessing DC power supply applies ultrasonic vibration to Phosphating Slot, at the same time connects DC power supply, and then in steel wire matrix table
One layer of phosphating coat is formed on face.In the whole process, supersonic generator exports high frequency electrical signal, is changed into ultrasonic transducer
Mechanical oscillation, and then play the role of quickly stirring to phosphatization tank liquor, it is also turned on DC power supply, electricity is carried out to workpiece steel wire
Solution realizes the ultrasonic electrolysis phosphatization to steel wire surface.
Compared with prior art, the present invention its advantage is that：
1, the bottom of Phosphating Slot can not only play phosphating solution stirring action added with supersonic generator keeps phosphating reaction quick
It carries out, and the cavitation of ultrasonic wave can achieve the effect that heating；
2, ultrasonic auxiliary electric solution phosphating reaction can make the phosphating reaction speed of steel wire surface faster, phosphating coat it is more smooth, thin
Close, uniform, consistency higher.
Description of the drawings
Fig. 1 is the structural schematic diagram of the embodiment of the present invention.
In figure：1, ultrasonic transducer 2, ultrasonic variable amplitude bar 3, leakage fluid dram 4, cavitation bubbles 5, oxygen 6,
Inert electrode graphite 7, Phosphating Slot 8, DC power supply 9, steel wire cathode 10, hydrogen 11, Zinc phosphating solution 12, absolutely
Edge cushion block 13, supersonic generator 14, holder.
Specific implementation mode
Below by way of specific embodiment, the present invention will be further described, but is not intended to limit protection scope of the present invention.
（1）Technological process：Degreasing → clear water washes → and pickling → clear water washes → surface adjustment → ultrasonic electrolysis phosphatization → saponification
→ distillation washing → drying.
（2）Phosphating operation step：
1, degreasing：Workpiece is immersed into the degreaser that trench bottom is equipped with supersonic generator first（PH：12-14）At middle progress degreasing
Reason is rinsed 2 ~ 3 times after taking-up with clear water, after material surface is in uniform water film；
2, pickling：It puts the workpiece in pickle of the trench bottom equipped with supersonic generator and carries out processing of rust removing, work as workpiece surface
After forming uniform color and luster, taking-up is rinsed 2 ~ 3 times with clear water（If workpiece surface moisture film is uneven, need to re-start degreasing acid
It washes）；
3, table tune：Surface adjustment is carried out using oxalic acid or colloid peptide, is carried out under room temperature, processing time is 1min or so, and PH is kept
7.5 ~ 10, preferably between 8 ~ 9；
4, phosphatization：The workpiece handled well is hung in phosphating solution immediately, as shown in structural schematic diagram.In bottom added with ultrasonic wave
In the Phosphating Slot of generator, workpiece is accessed to the cathode of DC power supply, graphite accesses the anode of DC power supply, reacts 30 after energization
~ 60s can take out workpiece；（Workpiece is placed on the intermediate position of solution as possible, naked can not be exposed on the external, also not accessible to hold
The bottom of device and chamber wall）
5, saponification：Workpiece after phosphating reaction is hung in ultrasonic wave saponification liquor, is taken out with distilled water flushing 2 ~ 3 after reacting 2min
It is secondary；
6, dry：The moisture of workpiece surface remnants is dried using dryer, prevents and returns rust.
Claims (5)
1. a kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing, including（1）Ultrasonic transducer,
（2）Ultrasonic variable amplitude bar,（6）Inert electrode graphite,（7）Phosphating Slot,（8）DC power supply,（9）Workpiece,（12）Cross-over block,
（13）Supersonic generator and（14）Holder, it is characterised in that：Phosphating Slot（7）It is fixed on holder（14）On, Phosphating Slot（7）Bottom
Portion is through amplitude transformer（2）With energy converter（1）It is fixedly connected, ultrasonic transducer（1）Wiring terminate supersonic generator（13）Electricity
Source output terminal；In Phosphating Slot（7）Interior workpiece（9）It is connected on DC power supply as cathode（8）Cathode, graphite（6）It is connect as anode
In DC power supply（8）Anode.
2. a kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing as claimed in claim 1,
It is characterized in that：Ultrasonic amplitude transformer（2）Top and bottom and Phosphating Slot（7）And ultrasonic transducer（1）Connection use ring
Oxygen resin and screw two ways are tightly fastened, ultrasonic transducer（1）Using piezoelectric ceramic transducer.
3. a kind of room temperature ultrasonic electrolysis parkerizing method and dress for before steel wire drawing according to claim 1,
It sets, it is characterised in that：Phosphating Slot（7）Bottom use cross-over block（12）.
4. a kind of room temperature ultrasonic electrolysis parkerizing method and dress for before steel wire drawing according to claim 1,
It sets, it is characterised in that：Ultrasonic transducer（1）Vibration frequency be 20KHz ~ 40KHz.
5. a kind of room temperature ultrasonic electrolysis parkerizing method and dress for before steel wire drawing according to claim 1,
It sets, it is characterised in that：DC power supply（8）Output voltage range be 0 ~ 30V, output current scope be 0 ~ 10A.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810852282.6A CN108588792A (en) | 2018-07-30 | 2018-07-30 | A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810852282.6A CN108588792A (en) | 2018-07-30 | 2018-07-30 | A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108588792A true CN108588792A (en) | 2018-09-28 |
Family
ID=63618455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810852282.6A Pending CN108588792A (en) | 2018-07-30 | 2018-07-30 | A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108588792A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111197162A (en) * | 2018-11-20 | 2020-05-26 | 天津市银丰钢绞线股份有限公司 | Pretreatment process for steel bar wire drawing |
| CN115262288A (en) * | 2022-07-19 | 2022-11-01 | 永发（江苏）模塑包装科技有限公司 | Ultrasonic-enhanced dehydration mold for pulp molding and use method |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10158302A1 (en) * | 2000-11-16 | 2002-07-25 | Univ Berlin Tech | Electrolytic coating of metal implants with bio-active materials containing calcium phosphate, maintains implant cathodic in aqueous calcium phosphate |
| CN102586838A (en) * | 2012-03-26 | 2012-07-18 | 南通高罕金属设备科技有限公司 | On-line low temperature electrolysis phosphating method for steel wires |
| CN103088374A (en) * | 2013-02-27 | 2013-05-08 | 大连理工大学 | Ultrasound-assisted electroforming method for improving thickness uniformity of micro-electroforming coating |
| CN103243338A (en) * | 2013-05-15 | 2013-08-14 | 山东威斯特车业有限公司 | Acid cleaning and phosphorizing method of electromobile frame |
| CN103572344A (en) * | 2013-09-29 | 2014-02-12 | 杭州电子科技大学 | Ultrasonic wave precise electroplating device |
| CN203842945U (en) * | 2014-01-28 | 2014-09-24 | 威海银兴预应力线材有限公司 | Device for producing steel stranded wires |
| CN105382357A (en) * | 2015-11-27 | 2016-03-09 | 扬州大学 | Ultrasonic-frequency vibrating combined micro-electrical discharge and electrolysis machining device |
| CN107712379A (en) * | 2017-11-17 | 2018-02-23 | 广西雷村蛇场蛇业有限公司 | Special feed for meat cobras and preparation method thereof |
-
2018
- 2018-07-30 CN CN201810852282.6A patent/CN108588792A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10158302A1 (en) * | 2000-11-16 | 2002-07-25 | Univ Berlin Tech | Electrolytic coating of metal implants with bio-active materials containing calcium phosphate, maintains implant cathodic in aqueous calcium phosphate |
| CN102586838A (en) * | 2012-03-26 | 2012-07-18 | 南通高罕金属设备科技有限公司 | On-line low temperature electrolysis phosphating method for steel wires |
| CN103088374A (en) * | 2013-02-27 | 2013-05-08 | 大连理工大学 | Ultrasound-assisted electroforming method for improving thickness uniformity of micro-electroforming coating |
| CN103243338A (en) * | 2013-05-15 | 2013-08-14 | 山东威斯特车业有限公司 | Acid cleaning and phosphorizing method of electromobile frame |
| CN103572344A (en) * | 2013-09-29 | 2014-02-12 | 杭州电子科技大学 | Ultrasonic wave precise electroplating device |
| CN203842945U (en) * | 2014-01-28 | 2014-09-24 | 威海银兴预应力线材有限公司 | Device for producing steel stranded wires |
| CN105382357A (en) * | 2015-11-27 | 2016-03-09 | 扬州大学 | Ultrasonic-frequency vibrating combined micro-electrical discharge and electrolysis machining device |
| CN107712379A (en) * | 2017-11-17 | 2018-02-23 | 广西雷村蛇场蛇业有限公司 | Special feed for meat cobras and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 牛宗伟 等: "数控超声机械镀设备的开发", 《电镀与精饰》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111197162A (en) * | 2018-11-20 | 2020-05-26 | 天津市银丰钢绞线股份有限公司 | Pretreatment process for steel bar wire drawing |
| CN115262288A (en) * | 2022-07-19 | 2022-11-01 | 永发（江苏）模塑包装科技有限公司 | Ultrasonic-enhanced dehydration mold for pulp molding and use method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100588755C (en) | Magnesium alloy differential arc electrophoresis composite surface treating method | |
| CN101845662A (en) | Magnesium alloy surface treating method and magnesium alloy polished by same | |
| CN104109891A (en) | Method for preparing aluminum alloy anode oxide film by direct-current superposition pulse voltage | |
| CN108588792A (en) | A kind of room temperature ultrasonic electrolysis parkerizing method and device for before steel wire drawing | |
| CN103726093B (en) | A kind of environment-friendly type that adopts contains nickel electrolyte is prepared differential arc oxidation film layer method at Mg alloy surface | |
| CN101956224B (en) | Method for electroplating nano composite plated layer | |
| CN109183126A (en) | A kind of preparation method of Mg alloy surface hydrophobic film layer | |
| CN103526251A (en) | Method for preparing micro-arc oxidation film with photocatalysis function | |
| CN109023197B (en) | Preparation method of environment-friendly zinc-aluminum-magnesium alloy coated steel plate | |
| CN109778166A (en) | The phosphorization treatment process of phosphating solution, the preparation method of phosphating solution and metal wire rod | |
| CN105887178A (en) | Plasma aluminum alloy polishing salt preparation and polishing method | |
| EP2045366B8 (en) | Method for vacuum-compression micro-plasma oxidation and device for carrying out said method | |
| CN102787346B (en) | Plasma cleaning process before clean and environment-friendly plated film | |
| CN112575358B (en) | Aluminum-plated steel surface corrosion-resistant micro-arc oxidation film layer and preparation method and application thereof | |
| CN108707947B (en) | Surface oxidation strengthening method for medical titanium material | |
| CN105316741B (en) | A kind of method for carrying out surface by micro-arc oxidation processing to aluminium alloy using grading current | |
| CN108796576A (en) | A kind of anode processing technique and its oxidation unit for pack alloy | |
| CN103132122B (en) | Steel wire on-line normal-temperature electrolytic phosphatization method | |
| CN104313533A (en) | Ultrasonic frequency induction heating technology based quick hot-dipping aluminizing technology | |
| CN104087889A (en) | Treatment method of successively aluminizing and oxidizing surface of die-casting die and oxidizing device | |
| CN103695876A (en) | Process for chemically plating high-performance non-porous nickel-phosphorus alloy | |
| CN105702466A (en) | Preparation method for high-dielectric-constant formed aluminum foil | |
| RU2736943C1 (en) | Coating method for articles from valve metal or its alloy | |
| CN108677182A (en) | A kind of mechanical deposit cadmium and cadmium alloy coating activator | |
| CN108004577A (en) | A kind of aluminum alloy surface image treatment technique |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180928 |