CN108547159A - A kind of light solidifying coating furniture artificial polyvinyl chloride leather and preparation method thereof - Google Patents
A kind of light solidifying coating furniture artificial polyvinyl chloride leather and preparation method thereof Download PDFInfo
- Publication number
- CN108547159A CN108547159A CN201810462244.XA CN201810462244A CN108547159A CN 108547159 A CN108547159 A CN 108547159A CN 201810462244 A CN201810462244 A CN 201810462244A CN 108547159 A CN108547159 A CN 108547159A
- Authority
- CN
- China
- Prior art keywords
- polyvinyl chloride
- coating
- light solidifying
- stabilizer
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
- D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
- D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/0045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by applying a ready-made foam layer; obtained by compressing, crinkling or crushing a foam layer, e.g. Kaschierverfahren für Schaumschicht
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0081—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments by wave energy or particle radiation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
- D06N3/08—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/2055—Improving load capacity
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
A kind of light solidifying coating furniture artificial polyvinyl chloride leather of the present invention and preparation method thereof, including coating and glue-line, according to mass percent, coating material includes：Photoinitiator 3 4%, polyurethane double methacrylate 30 60%, tetra functional polyester acrylate 20 30%, NVP 5 10%, TMPTMA 5 10%, plasticizer 10 15%, silica 0 4%；According to mass fraction, glue-line includes foaming layer and nonfoamed layer, and foaming layer includes：Polyvinyl chloride resin SG 5 100, DOP 60 90, stabilizer 14, AC foaming agents 0.5 2, surfactant 0.5 2, calcium carbonate 60 100, ACR 02, stearic acid 0.2 0.6；Nonfoamed layer includes：Polyvinyl chloride resin SG 3 100, DOP 60 90, epoxidized soybean oil 13, stabilizer 14, calcium carbonate 0 30, ACR 02, stearic acid 0.2 1.Production process VOC emission can be reduced using light solidifying coating.With aqueous coating ratio, there is higher production efficiency.With common light solidifying coating ratio, product has preferable anti-tortuosity, lower smell.
Description
Technical field
The present invention relates to artificial leathers, specifically, be related to a kind of light solidifying coating furniture artificial polyvinyl chloride leather and its
Preparation method.
Background technology
Alternative materials of the artificial leather as natural leather, quickly grow in China, and especially artificial leather synthetic leather in the world's produces
Industry center continues to shift to China, and China's artificial leather synthetic leather industry is promoted to achieve faster development.
Artificial leather is exactly a kind of plastic products of leather-like.Usually using fabric as base, one is coated with or pasted on it
Layer resin compound, then heating are allowed to be plasticized, and flatten or be embossed to get product through rolling.It is similar to natural leather, has
The features such as soft, wear-resisting.It is different according to the type of covering, there are artificial polyvinyl chloride leather (PVC), polyurethane artificial leather (PU)
Deng.It can almost be replaced using the occasion of leather any, for making daily necessities and industrial goods.It is sent out according to coating
Whether bubble, it is divided into foamed leather and common artificial leather.There are shoes artificial leather, luggage artificial leather etc. according to purposes.
But existing artificial leather loss of properties on aging, service life is short, and VOC emission in coating material production, gives air
Environment brings pollution.
Invention content
The present invention overcomes the disadvantages of the prior art, provides a kind of light solidifying coating furniture artificial polyvinyl chloride leather
And preparation method thereof, product has preferable anti-tortuosity, lower smell, and ageing-resistant performance is good, extends making for artificial leather
Use the service life.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of light solidifying coating furniture artificial polyvinyl chloride leather, including coating and glue-line,
According to mass percent, coating material includes：Photoinitiator 3-4%, polyurethane double methacrylate 30-60%, four
Degree of functionality polyester acrylate 20-30%, NVP 5-10%, TMPTMA 5-10%, plasticizer 10-15%, silica 0-
4%；
According to mass fraction, glue-line includes foaming layer and nonfoamed layer, and foaming layer includes：Polyvinyl chloride resin SG-5 100, DOP
60-90, stabilizer 1-4, AC foaming agent 0.5-2, surfactant 0.5-2, calcium carbonate 60-100, ACR 0-2, stearic acid 0.2-0.6；
Nonfoamed layer includes：Polyvinyl chloride resin SG-3 100, DOP 60-90, epoxidized soybean oil 1-3, stabilizer 1-4, calcium carbonate 0-30,
ACR0-2, stearic acid 0.2-1.
Further, according to mass percent, the coating material includes：Photoinitiator 3.5%, polyurethane double methacrylate
40%, tetra functional polyester acrylate 25%, NVP 7%, TMPTMA 8%, plasticizer 12%, silica 2%.
Further, according to mass fraction, glue-line includes foaming layer and nonfoamed layer, and foaming layer includes：Polyvinyl chloride resin SG-5
100, DOP 70, stabilizer 2, AC foaming agents 1, surfactant 1, calcium carbonate 70, ACR 1, stearic acid 0.4.
Further, according to mass fraction, nonfoamed layer includes：Polyvinyl chloride resin SG-3 100, DOP 70, epoxidized soybean oil 2,
Stabilizer 2, calcium carbonate 15, ACR1, stearic acid 0.6.
Photoinitiator is 1- hydroxycyclohexyl phenyl ketones, and plasticizer is dioctyl azelate, and stabilizer is stablized for calcium zinc
Agent, surfactant are dimethicone.
A kind of preparation method of light solidifying coating furniture artificial polyvinyl chloride leather, includes the following steps：
Step 1, mixture is formed after the raw material of the proportioning being mixed；
Step 2, heat is mixed：Mixture in step 1 is put into be stirred in the mixed machine of heat and is mixed to get the first product, wherein
Mixing time is 12-16min, and temperature is 120-130 DEG C, and stirring blade rotating speed is 1000-1500r/min；
Step 3, cold mixed：Product in step 2 is put into be stirred in the mixed machine of heat and is mixed to get the second product, wherein stirring
It is 28-32min to mix the time, and temperature is 25-30 DEG C, and stirring blade rotating speed is 700-800r/min；
Step 4, plasticizing squeezes out：The second product obtained in step 3 is put into plasticizing in extruder and squeezes out to obtain third product,
Fusion time is 2-3min, screw speed 500-600r/min；
Step 5, roll：Third product is put into calendering on calender and obtains PVC sheet；
Step 6, it foams；
Step 7, coating light consolidates material；
Step 8：Carry out curing of coatings.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of light solidifying coating furniture artificial polyvinyl chloride leather of the present invention and preparation method thereof, is applied using photocuring
Layer can reduce production process VOC emission.With aqueous coating ratio, there is higher production efficiency.With common light solidifying coating ratio, production
Product have preferable anti-tortuosity, lower smell.
Description of the drawings
Attached drawing is used to provide further understanding of the present invention, and is used to explain the present invention together with embodiments of the present invention,
It is not construed as limiting the invention, in the accompanying drawings：
Fig. 1 is a kind of preparation method of light solidifying coating furniture artificial polyvinyl chloride leather of the present invention.
Specific implementation mode
Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings, it should be understood that preferred reality described herein
Apply example only for the purpose of illustrating and explaining the present invention and is not intended to limit the present invention.
A kind of light solidifying coating furniture artificial polyvinyl chloride leather, including coating and glue-line, it is described according to mass percent
Coating material includes：Photoinitiator 3.5%, polyurethane double methacrylate 40%, tetra functional polyester acrylate 25%, NVP
(n-vinyl pyrrolidone) 7%, TMPTMA (trimethylol-propane trimethacrylate) 8%, plasticizer 12%, titanium dioxide
Silicon 2%.
According to mass fraction, glue-line includes foaming layer and nonfoamed layer, and foaming layer includes：Polyvinyl chloride resin SG-5 100, DOP
(dioctyl phthalate) 70, stabilizer 2, AC foaming agents 1, surfactant 1, calcium carbonate 70, the ACR (high scores of esters of acrylic acid
Sub- copolymer) 1, stearic acid 0.4.
According to mass fraction, nonfoamed layer includes：Polyvinyl chloride resin SG-3 100, DOP (dioctyl phthalate) 70, ring
Oxygen soybean oil 2, stabilizer 2, calcium carbonate 15 (high-molecular copolymer of esters of acrylic acid), (macromolecule of esters of acrylic acid is total by ACR
Polymers) 1, stearic acid 0.6.
As shown in Figure 1, a kind of preparation method of light solidifying coating furniture artificial polyvinyl chloride leather, includes the following steps：
Step 1, mixture is formed after the raw material of the proportioning being mixed；
Step 2, heat is mixed：Mixture in step 1 is put into be stirred in the mixed machine of heat and is mixed to get the first product, wherein
Mixing time is 12-16min, and temperature is 120-130 DEG C, and stirring blade rotating speed is 1000-1500r/min；
Step 3, cold mixed：Product in step 2 is put into be stirred in the mixed machine of heat and is mixed to get the second product, wherein stirring
It is 28-32min to mix the time, and temperature is 25-30 DEG C, and stirring blade rotating speed is 700-800r/min；
Step 4, plasticizing squeezes out：The second product obtained in step 3 is put into plasticizing in extruder and squeezes out to obtain third product,
Fusion time is 2-3min, screw speed 500-600r/min；
Step 5, roll：Third product is put into calendering on calender and obtains PVC sheet；
Step 6, it foams；
Step 7, coating light consolidates material；
Step 8：Carry out curing of coatings.
Product quality is shown in Table 1.
Table 1
Finally it should be noted that：It these are only the preferred embodiment of the present invention, be not intended to restrict the invention, although
With reference to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned
Technical solution recorded in each embodiment is modified or equivalent replacement of some of the technical features, but it is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in the protection of the present invention
Within the scope of.
Claims (6)
1. a kind of light solidifying coating furniture artificial polyvinyl chloride leather, which is characterized in that including coating and glue-line,
According to mass percent, coating material includes：Photoinitiator 3-4%, polyurethane double methacrylate 30-60%, tetrafunctional
Spend polyester acrylate 20-30%, NVP 5-10%, TMPTMA 5-10%, plasticizer 10-15%, silica 0-4%；
According to mass fraction, glue-line includes foaming layer and nonfoamed layer, and foaming layer includes：Polyvinyl chloride resin SG-5 100, DOP 60-
90, stabilizer 1-4, AC foaming agent 0.5-2, surfactant 0.5-2, calcium carbonate 60-100, ACR 0-2, stearic acid 0.2-0.6；It is non-
Foaming layer includes：Polyvinyl chloride resin SG-3 100, DOP 60-90, epoxidized soybean oil 1-3, stabilizer 1-4, calcium carbonate 0-30, ACR
0-2, stearic acid 0.2-1.
2. a kind of light solidifying coating furniture artificial polyvinyl chloride leather according to claim 1, which is characterized in that according to quality
Percentage, the coating material include：Photoinitiator 3.5%, polyurethane double methacrylate 40%, tetra functional polyester acrylic
Ester 25%, NVP 7%, TMPTMA 8%, plasticizer 12%, silica 2%.
3. a kind of light solidifying coating furniture artificial polyvinyl chloride leather according to claim 2, which is characterized in that according to quality
Score, glue-line include foaming layer and nonfoamed layer, and foaming layer includes：Polyvinyl chloride resin SG-5 100, DOP 70, stabilizer 2, AC hairs
Infusion 1, surfactant 1, calcium carbonate 70, ACR 1, stearic acid 0.4.
4. a kind of light solidifying coating furniture artificial polyvinyl chloride leather according to claim 3, which is characterized in that according to quality
Score, nonfoamed layer include：Polyvinyl chloride resin SG-3 100, DOP 70, epoxidized soybean oil 2, stabilizer 2, calcium carbonate 15, ACR1, firmly
Resin acid 0.6.
5. a kind of light solidifying coating furniture artificial polyvinyl chloride leather according to claim 1, which is characterized in that photoinitiator
For 1- hydroxycyclohexyl phenyl ketones, plasticizer is dioctyl azelate, and stabilizer is calcium zinc stabilizer, and surfactant is dimethyl
Silicone oil.
6. a kind of preparation method of light solidifying coating furniture artificial polyvinyl chloride leather, feature exist according to claim 1
In including the following steps：Step 1, mixture is formed after the raw material of the proportioning being mixed；
Step 2, heat is mixed：Mixture in step 1 is put into be stirred in the mixed machine of heat and is mixed to get the first product, wherein stirring
Time is 12-16min, and temperature is 120-130 DEG C, stirring blade rotating speed 1000-1500r/min；
Step 3, cold mixed：Product in step 2 is put into be stirred in the mixed machine of heat and is mixed to get the second product, wherein when stirring
Between be 28-32min, temperature be 25-30 DEG C, stirring blade rotating speed be 700-800r/min；
Step 4, plasticizing squeezes out：The second product obtained in step 3 is put into plasticizing in extruder and squeezes out to obtain third product, is plasticized
Time is 2-3min, screw speed 500-600r/min；
Step 5, roll：Third product is put into calendering on calender and obtains PVC sheet；
Step 6, it foams；
Step 7, coating light consolidates material；
Step 8：Carry out curing of coatings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810462244.XA CN108547159A (en) | 2018-05-15 | 2018-05-15 | A kind of light solidifying coating furniture artificial polyvinyl chloride leather and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810462244.XA CN108547159A (en) | 2018-05-15 | 2018-05-15 | A kind of light solidifying coating furniture artificial polyvinyl chloride leather and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108547159A true CN108547159A (en) | 2018-09-18 |
Family
ID=63494869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810462244.XA Pending CN108547159A (en) | 2018-05-15 | 2018-05-15 | A kind of light solidifying coating furniture artificial polyvinyl chloride leather and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108547159A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109367459A (en) * | 2018-12-10 | 2019-02-22 | 3M中国有限公司 | Enclose silk pad and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103669021A (en) * | 2013-12-27 | 2014-03-26 | 四川大学 | Low energy consumption ecological leatheroid preparation method |
| CN104164788A (en) * | 2014-07-31 | 2014-11-26 | 佛山高明骏腾塑胶有限公司 | PVC calendering foaming artificial leather and preparation method thereof |
| CN106457741A (en) * | 2014-04-18 | 2017-02-22 | 塔吉特Gdl公司 | Actinic radiation cured polyurethane coating for decorative surface coverings |
| CN106977994A (en) * | 2017-04-16 | 2017-07-25 | 珠海东诚光固化新材料股份有限公司 | LED curable water-bornes leather coating and its application |
-
2018
- 2018-05-15 CN CN201810462244.XA patent/CN108547159A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103669021A (en) * | 2013-12-27 | 2014-03-26 | 四川大学 | Low energy consumption ecological leatheroid preparation method |
| CN106457741A (en) * | 2014-04-18 | 2017-02-22 | 塔吉特Gdl公司 | Actinic radiation cured polyurethane coating for decorative surface coverings |
| CN104164788A (en) * | 2014-07-31 | 2014-11-26 | 佛山高明骏腾塑胶有限公司 | PVC calendering foaming artificial leather and preparation method thereof |
| CN106977994A (en) * | 2017-04-16 | 2017-07-25 | 珠海东诚光固化新材料股份有限公司 | LED curable water-bornes leather coating and its application |
Non-Patent Citations (2)
| Title |
|---|
| 屈贞财: "用于PE瓶盖的UV固化油墨的研制", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 齐贵亮: "《压延成型技术疑难问题解答》", 31 January 2017, 文化发展出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109367459A (en) * | 2018-12-10 | 2019-02-22 | 3M中国有限公司 | Enclose silk pad and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103981728B (en) | A kind of low smell high strength permanent seal cooling PVC artificial leather and production method thereof | |
| CN102532747A (en) | Polyvinyl chloride decoration material and preparation method thereof | |
| CN107011788A (en) | Artificial leather inorganic agent, artificial polyvinyl chloride leather, preparation method and the usage | |
| CN110372817A (en) | A kind of preparation method of the modified microspheres of nano-metal-oxide | |
| CN103015218A (en) | PVC artificial leather scrape paint and method of preparing PVC artificial leather with scrape paint | |
| CN105254817A (en) | Preparation method of acrylate foaming regulator with core-shell structure | |
| JP2022529626A (en) | Thermoplastic composite material | |
| CN103627109A (en) | Manufacturing formula of environment-friendly pencil board and technology thereof | |
| CN108547159A (en) | A kind of light solidifying coating furniture artificial polyvinyl chloride leather and preparation method thereof | |
| CN102863934A (en) | Method for preparing heat-resistant modified water-based chloroprene rubber adhesive and application | |
| CN106432950A (en) | Improved stone plastic board base material and production method of stone plastic board | |
| CN108677553A (en) | A kind of discoloration synthetic leather and its production technology | |
| TW201843235A (en) | Synthetic leather of expanded thermoplastic polyurethane (e-TPU), fabrication method therefor and formula preventing the mixture of TPU from being sticking under a melting status | |
| CN108677552A (en) | A kind of artificial polyvinyl chloride leather foamed material | |
| CN108589320A (en) | Flame-proof PVC sunshine membrane and preparation method thereof | |
| KR101154457B1 (en) | Process for the preparation of poly-vinylchloride resin with matte surface | |
| CN103981727B (en) | A kind of vapor-permeable type collagenous fibres/PVC composite artificial leather and production method thereof | |
| CN109228251A (en) | A kind of uniform PVC low ratio foamed plate of bending elastic modulus and preparation method thereof | |
| CN1018622B (en) | Decorative inlaid types of sheet materials | |
| CN114805895A (en) | PVC decorative film and preparation process thereof | |
| CA1231495A (en) | Monomer-plasticized elastomers and process for producing same | |
| CN111057177B (en) | Extinction PVC paste resin and preparation method thereof | |
| CN108517095A (en) | A method of preparing high hardness wear-resisting polyvinyl chloride crust foaming plate material | |
| CN105086249A (en) | PVC (polyvinyl chloride) advertisement board | |
| KR102715046B1 (en) | Aqueous acrylic emulsion adhesive composition and manufacturing methods thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190311 Address after: 528500 No. 1, Yanghe Zhenweitai Road, Cangjiang Industrial Park, Gaoming District, Foshan City, Guangdong Province Applicant after: Foshan Weishida New Materials Co., Ltd. Address before: 528500 Yanghe Zhenweitai Road, Cangjiang Industrial Park, Gaoming District, Foshan City, Guangdong Province Applicant before: Foshan city Gaoming wise Star Plastic Co Ltd |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180918 |
|
| RJ01 | Rejection of invention patent application after publication |