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CN108494380A - SAW filter materials and preparation method thereof - Google Patents

SAW filter materials and preparation method thereof Download PDF

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Publication number
CN108494380A
CN108494380A CN201810220554.0A CN201810220554A CN108494380A CN 108494380 A CN108494380 A CN 108494380A CN 201810220554 A CN201810220554 A CN 201810220554A CN 108494380 A CN108494380 A CN 108494380A
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CN
China
Prior art keywords
film
silica
base
piezoelectric monocrystal
saw filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810220554.0A
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Chinese (zh)
Inventor
王为标
毛宏庆
陆增天
李壮
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WUXI HAODA ELECTRONIC CO Ltd
Original Assignee
WUXI HAODA ELECTRONIC CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by WUXI HAODA ELECTRONIC CO Ltd filed Critical WUXI HAODA ELECTRONIC CO Ltd
Priority to CN201810220554.0A priority Critical patent/CN108494380A/en
Priority to PCT/CN2018/083262 priority patent/WO2019174097A1/en
Publication of CN108494380A publication Critical patent/CN108494380A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/08Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of resonators or networks using surface acoustic waves
    • H03H3/10Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of resonators or networks using surface acoustic waves for obtaining desired frequency or temperature coefficient
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/08Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of resonators or networks using surface acoustic waves
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
    • H03H9/02Details
    • H03H9/02535Details of surface acoustic wave devices
    • H03H9/02543Characteristics of substrate, e.g. cutting angles
    • H03H9/02574Characteristics of substrate, e.g. cutting angles of combined substrates, multilayered substrates, piezoelectrical layers on not-piezoelectrical substrate
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/01Manufacture or treatment
    • H10N30/07Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base
    • H10N30/072Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by laminating or bonding of piezoelectric or electrostrictive bodies
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/704Piezoelectric or electrostrictive devices based on piezoelectric or electrostrictive films or coatings
    • H10N30/706Piezoelectric or electrostrictive devices based on piezoelectric or electrostrictive films or coatings characterised by the underlying bases, e.g. substrates

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  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Surface Acoustic Wave Elements And Circuit Networks Thereof (AREA)
  • Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)

Abstract

The invention discloses a kind of SAW filter materials and preparation method thereof, belong to SAW filter materials field.The SAW filter materials include silicon base, the silica-base film on silicon base and the piezoelectric monocrystal film on silica-base film;Piezoelectric monocrystal film is lithium tantalate piezoelectric monocrystal film or lithium niobate piezoelectric monocrystal thin films;Being made on the bonding face of silica-base film or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base has groove structure array;The bonding face of silica-base film, the bonding face of piezoelectric monocrystal film, silicon base bonding face be burnishing surface;It solves existing multilayer bonding piezoelectric material body wave action surface acoustic wave, leads to the problem of the high-end inhibition difference of SAW filter;Reach the application range for expanding multilayer bonding piezoelectric material, ensures the effect of the performance of SAW filter.

Description

SAW filter materials and preparation method thereof
Technical field
The present embodiments relate to SAW filter materials field, more particularly to a kind of SAW filter materials and its making side Method.
Background technology
Surface acoustic wave is to generate and propagate on piezoelectric substrate materials surface, and amplitude increases with the depth for going deep into substrate material And the elastic wave of rapid reduction.The basic structure of SAW filter is on the substrate material burnishing surface with piezoelectric property Two acoustic-electrical transducers are made, operation principle is that electric signal is become acoustical signal by input energy converter, and acoustical signal is passed along plane of crystal Defeated, the acoustical signal received is become electric signal output by output transducer again.
Lithium niobate and lithium tantalate in piezoelectric material have the larger coefficient of coup, are usually used in making SAW filter, But the temperature coefficient of lithium niobate and lithium tantalate is sent to so that manufactured SAW filter at different temperatures frequency cheaply compared with Greatly, the performance of surface acoustic wave and application are affected.Influence caused by order to overcome temperature coefficient, uses temperature in the related technology The smaller silicon chip of coefficient and the bonding of lithium niobate or lithium tantalate, to inhibit influence of the temperature to lithium niobate or lithium tantalate material.
However, there is boundary in actual use in the multilayer bonding piezoelectric material bonded together to form by silicon chip and surface layer piezoelectric material The interference of face bulk wave, the high-end inhibition of filter are deteriorated.
Invention content
In order to solve problems in the prior art, an embodiment of the present invention provides a kind of SAW filter materials and its making sides Method.The technical solution is as follows:
In a first aspect, provide a kind of SAW filter materials, including silicon base, the silica-base film on silicon base, with And the piezoelectric monocrystal film on silica-base film;
Piezoelectric monocrystal film is lithium tantalate piezoelectric monocrystal film or lithium niobate piezoelectric monocrystal thin films;
Being made on the bonding face of silica-base film or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base has groove knot Structure array;
The bonding face of silica-base film, the bonding face of piezoelectric monocrystal film, silicon base bonding face be burnishing surface.
Optionally, groove structure array is produced on the bonding face of silica-base film;
Silica-base film making has the one side of groove structure array to be bonded with piezoelectric monocrystal film, and silica-base film is grown in silicon substrate On bottom.
Optionally, groove structure array is produced on the bonding face of piezoelectric monocrystal film;
Silica-base film has in the making of piezoelectric monocrystal film under the one side of groove structure array.
Optionally, groove structure array is produced on the bonding face of silicon base;
Silica-base film is grown in silicon base and makes the one side for having groove structure array.
Optionally, in groove structure array the bonding face transmission side of fluting direction and the piezoelectric monocrystal film of groove angle For any angle between 0 ° to 90 °.
Second aspect, provides a kind of production method of SAW filter materials, and this method includes:
Photolithography plate is made, is provided with groove array figure on photolithography plate, groove array figure includes several groove figures;
Clean piezoelectric monocrystal film and silicon base;Piezoelectric monocrystal film is lithium tantalate piezoelectric monocrystal film or lithium niobate piezoelectric Monocrystal thin films;
Using photolithography plate, groove structure array is made on piezoelectric monocrystal film or silicon base;In piezoelectric monocrystal film or Silica-base film is grown in silicon base;Or, growing silica-base film on a silicon substrate;Using photolithography plate, ditch is made on silica-base film Slot structure array;
Bonding generates SAW filter materials;
Wherein, in SAW filter materials, piezoelectric monocrystal film is above silica-base film, and silica-base film is on a silicon substrate Side.
Optionally, when making groove structure array on a silicon substrate using photolithography plate, in piezoelectric monocrystal film or silicon substrate Silica-base film is grown on bottom, including:
Making on a silicon substrate has the one side growth silica-base film of groove structure array;
Bonding generates SAW filter materials, including:
Silica-base film is bonded with piezoelectric monocrystal film, generates SAW filter materials;
Wherein, the angle on the bonding face of the fluting direction of groove and piezoelectric monocrystal film transmission side is in groove structure array Any angle between 0 ° to 90 °.
Optionally, when making groove structure array on piezoelectric monocrystal film using photolithography plate, in piezoelectric monocrystal film Or silica-base film is grown in silicon base, including:
Silica-base film is grown on a silicon substrate;
Bonding generates SAW filter materials, including:
There is the one side of groove structure array to be bonded with making on piezoelectric monocrystal film silica-base film, generates surface acoustic wave material Material;
Wherein, the angle on the bonding face of the fluting direction of groove and piezoelectric monocrystal film transmission side is in groove structure array Any angle between 0 ° to 90 °.
Optionally, when making groove structure array on piezoelectric monocrystal film using photolithography plate, in piezoelectric monocrystal film Or silica-base film is grown in silicon base, including:
Being made on piezoelectric monocrystal film has the one side growth silica-base film of groove structure array;
Bonding generates SAW filter materials, including:
Silica-base film is bonded with silicon base, generates SAW filter materials;
Wherein, the angle on the bonding face of the fluting direction of groove and piezoelectric monocrystal film transmission side is in groove structure array Any angle between 0 ° to 90 °.
Optionally, when growing silica-base film on a silicon substrate, bonding generates SAW filter materials, including:
Silica-base film is bonded with piezoelectric monocrystal film, generates SAW filter materials;
Wherein, the angle on the bonding face of the fluting direction of groove and piezoelectric monocrystal film transmission side is in groove structure array Any angle between 0 ° to 90 °.
The advantageous effect that technical solution provided in an embodiment of the present invention is brought is:
By making photolithography plate, photolithography plate deletes the forming array figure being provided with including several groove figures, cleaning pressure Electric monocrystal thin films and silicon base;Using photolithography plate, in the bonding face of silicon base or the bonding face or silicon base of piezoelectric monocrystal film Bonding face make groove structure array, bonding generate material sequence be piezoelectric monocrystal film, silica-base film, silicon base sound table Surface wave material;Using the generation of propagation and interface reflected body wave of the groove structure array effects bulk wave in crystalline material, solve Existing multilayer is bonded piezoelectric material body wave action surface acoustic wave, leads to the problem of the high-end inhibition difference of SAW filter;It reaches The application range for expanding multilayer bonding piezoelectric material has been arrived, has ensured the effect of the performance of SAW filter.
Description of the drawings
To describe the technical solutions in the embodiments of the present invention more clearly, make required in being described below to embodiment Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for For those of ordinary skill in the art, without creative efforts, other are can also be obtained according to these attached drawings Attached drawing.
Fig. 1 is the structural schematic diagram according to a kind of SAW filter materials shown in an exemplary embodiment of the invention;
Fig. 2 is the structural schematic diagram according to a kind of silica-base film shown in an exemplary embodiment of the invention;
Fig. 3 is a kind of structural schematic diagram of SAW filter materials shown according to another exemplary embodiment of the present invention;
Fig. 4 is a kind of structural schematic diagram of SAW filter materials shown according to another exemplary embodiment of the present invention;
Fig. 5 is a kind of structural schematic diagram of piezoelectric monocrystal film shown according to another exemplary embodiment of the present invention;
Fig. 6 is a kind of structural schematic diagram of SAW filter materials shown according to another exemplary embodiment of the present invention;
Fig. 7 is a kind of structural schematic diagram of silicon base shown according to another exemplary embodiment of the present invention;
Fig. 8 is a kind of flow chart of the production method for SAW filter materials that an exemplary embodiment of the invention provides;
Fig. 9 is a kind of flow chart of the production method for SAW filter materials that another exemplary embodiment of the present invention provides;
Figure 10 is a kind of flow chart of the production method for SAW filter materials that another exemplary embodiment of the present invention provides;
Figure 11 is a kind of flow chart of the production method for SAW filter materials that another exemplary embodiment of the present invention provides;
Figure 12 is a kind of flow chart of the production method for SAW filter materials that another exemplary embodiment of the present invention provides.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with attached drawing to embodiment party of the present invention Formula is described in further detail.
An embodiment of the present invention provides a kind of SAW filter materials, the SAW filter materials include silicon base, silica-base film, Piezoelectric monocrystal film.
Silica-base film is on silicon base.
Optionally, silica-base film passes through CVD (Chemical Vapor Deposition, chemical vapor deposition) or PVD (Physical Vapor Depositio, physical vapor deposition) technique precipitates on a silicon substrate, or, passing through thermal oxide work Skill is grown on a silicon substrate.
Optionally, silica-base film is silica or silicon nitride.
Piezoelectric monocrystal film is on silica-base film.Piezoelectric monocrystal film is lithium tantalate piezoelectric monocrystal film or lithium niobate pressure Electric monocrystal thin films.
The bonding face of piezoelectric monocrystal film is burnishing surface.Optionally, piezoelectric monocrystal film is twin polishing or single-sided polishing.
Wherein, being made on the bonding face of the bonding face or silicon base of the bonding face of silica-base film or piezoelectric monocrystal film has ditch Slot structure array.
Groove structure array is made of several groove structures.The fluting size and shape of groove are true according to actual needs It is fixed.The depth of groove is no more than the thickness for the material layer for making groove.
Optionally, each groove structure is identical in groove structure array.
Optionally, the groove in groove structure array is arranged in parallel.
Optionally, the groove in groove structure array is equidistantly arranged in parallel.
Optionally, being made on the bonding face of silica-base film has groove structure array.
Optionally, being made on the bonding face of piezoelectric monocrystal film has groove structure array.
Optionally, being made on the bonding face of silicon base has groove structure array.
The bonding face of silicon base is burnishing surface.Optionally, silicon base is single-sided polishing or twin polishing.
The bonding face of silica-base film is burnishing surface.
Fig. 1 schematically illustrates a kind of structural representation of SAW filter materials shown in an exemplary embodiment of the invention Figure.
Piezoelectric monocrystal film 11 is bonded on silica-base film 12, and silica-base film 12 is on silicon base 13.
Groove structure array 121 is produced on the bonding face of silica-base film 12, as shown in Figure 2.
The making of silica-base film 12 has the one side of groove structure array 121 to be bonded with piezoelectric monocrystal film 11, silica-base film 12 It is grown on silicon base 13.
The bonding face of silica-base film 12 and piezoelectric monocrystal film 11 is burnishing surface.
Fig. 3, Fig. 4 schematically illustrate a kind of SAW filter materials shown in an exemplary embodiment of the invention respectively Structural schematic diagram.
Groove structure array 111 is produced on the bonding face of piezoelectric monocrystal film 11, as shown in Figure 5.
As shown in Figure 3, Figure 4, silica-base film 12 has in the making of piezoelectric monocrystal film 11 under the one side of groove structure, silicon substrate Film 12 is on silicon base 13.
Optionally, piezoelectric monocrystal film 11, which makes, has the one side growth of groove structure array 111 to have silica-base film 12, silicon substrate Film 12 is bonded with silicon base 13, as shown in Figure 3.Silica-base film 12 and the bonding face of silicon base 13 are burnishing surface.
Optionally, silica-base film 12 is grown on silicon base 13, and the making of piezoelectric monocrystal film 11 has groove structure array 111 one side is bonded with silica-base film 12, as shown in Figure 4.The bonding face of piezoelectric monocrystal film 11 and silica-base film 12 is polishing Face.
The structure that Fig. 6 schematically illustrates a kind of SAW filter materials shown in another exemplary embodiment of the present invention is shown It is intended to.
Groove structure array 131 is produced on the bonding face of silicon base 13, as shown in Figure 7.
Silica-base film 12 is grown in the one side that groove structure array 131 is provided in silicon base 13, piezoelectric monocrystal film 11 It is bonded with silica-base film 12.
The bonding face of silica-base film 12 and piezoelectric monocrystal film 11 is burnishing surface.
In the alternative embodiment based on Fig. 1 or Fig. 3 or Fig. 4 or embodiment illustrated in fig. 6, groove in groove structure array The angle on the bonding face of fluting direction and piezoelectric monocrystal film transmission side is any angle between 0 ° to 90 °.
It should be noted that can be according to the thickness requirements of actual product, the piezoelectric monocrystal film to SAW filter materials Piezoelectric material layer and/or silicon base carry out attenuated polishing.
In conclusion SAW filter materials provided in an embodiment of the present invention, including silicon base, the silicon substrate on silicon base Film, the piezoelectric monocrystal film on silica-base film, piezoelectric monocrystal film are monocrystalline lithium tantalate film or lithium niobate piezoelectric list Being made on brilliant film, the bonding face of silica-base film or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base has groove structure Array, the bonding of silica-base film, the bonding face of piezoelectric monocrystal film, silicon base bonding face be burnishing surface;Utilize groove knot The generation of propagation and interface reflected body wave of the structure array effects bulk wave in crystalline material solves existing multilayer bonding piezoelectricity Material bodies wave action surface acoustic wave leads to the problem of the high-end inhibition difference of SAW filter;Expansion multilayer bonding piezoelectricity is reached The application range of material ensures the effect of the performance of SAW filter.
The production method that Fig. 8 schematically illustrates a kind of SAW filter materials that an exemplary embodiment of the invention provides Flow chart, as shown in figure 8, the production method of the SAW filter materials includes:
Step 801, photolithography plate is made, groove array figure is provided on photolithography plate.
Groove array figure includes several groove figures.
According to the shape and size of groove, it is spare to prepare corresponding photolithography plate.
Step 802, piezoelectric monocrystal film and silicon base are cleaned.
Piezoelectric monocrystal film is monocrystalline lithium tantalate film or lithium niobate piezoelectric monocrystal thin films.
Silicon base and piezoelectric monocrystal film are cleaned with acetone, deionized water and ethanol solution respectively in ultra-clean chamber, And it dries.
Step 803, using photolithography plate, groove structure array is made on piezoelectric monocrystal film or silicon base.
Groove structure array is made on piezoelectric monocrystal film using photolithography plate;Alternatively, on a silicon substrate using photolithography plate Make groove structure array.
In groove structure array the angle on the bonding face transmission side of the fluting direction of groove and piezoelectric monocrystal film be 0 ° extremely Any angle between 90 °.
Groove structure array is made of several groove structures.The fluting size and shape of groove are true according to actual needs It is fixed.The depth of groove is no more than the thickness for the material layer for making groove.Such as:The spacing of groove is 1 to 2000um, the depth of groove Degree is 0.1um to 20um.
Optionally, each groove structure is identical in groove structure array.
Optionally, the groove in groove structure array is arranged in parallel.
Optionally, the groove in groove structure array is equidistantly arranged in parallel.
Step 804, silica-base film is grown on piezoelectric monocrystal film or silicon base.
Silica-base film is grown on piezoelectric monocrystal film;Alternatively, growing silica-base film on a silicon substrate.
Step 805, bonding generates SAW filter materials.
It is bonded in the SAW filter materials generated, piezoelectric monocrystal film is above silica-base film, and silica-base film is in silicon base Top.
In conclusion the production method of SAW filter materials provided in an embodiment of the present invention, by making photolithography plate, photoetching Plate deletes the forming array figure being provided with including several groove figures, cleans piezoelectric monocrystal film and silicon base;Utilize photoetching Plate makes groove structure array, key in the bonding face of silicon base or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base Symphysis is at the SAW filter materials that material sequence is piezoelectric monocrystal film, silica-base film, silicon base;Utilize groove structure array shadow The generation for ringing propagation and interface reflected body wave of the bulk wave in crystalline material solves existing multilayer bonding piezoelectric material bulk wave Surface acoustic wave is influenced, the problem of the high-end inhibition difference of SAW filter is caused;Reach and has expanded answering for multilayer bonding piezoelectric material With range, ensure the effect of the performance of SAW filter.
In the alternative embodiment based on Fig. 8 embodiments, step 803, which can be replaced, is embodied as step 8031, and step 804 can It is replaced and is embodied as step 8041, as shown in Figure 9:
Step 8031, silica-base film is grown on a silicon substrate.
Silicon base is put into film deposition equipment, using physical gas-phase deposition or chemical vapor deposition method, Deposited on silicon substrates silica-base film.
The silicon base for having deposited silica-base film is put into the vacuum environment that temperature is 200 to 1000 ° and is made annealing treatment, Annealing time is 2 hours or more, to eliminate the defect and impurity generated in silica-base film deposition process.
Step 8041, groove structure array is made on silica-base film using photolithography plate.
In groove structure array the angle on the bonding face transmission side of the fluting direction of groove and piezoelectric monocrystal film be 0 ° extremely Any angle between 90 °.
The silicon base that grown silica-base film is taken out, corresponding photoresist and spin coating rotating speed are selected according to groove depth; The bonding face of silica-base film presses spin coating rotating speed spin coating photoresist;Mask is done using photolithography plate, photoresist is exposed;Using aobvious Shadow liquid develops, and the photoresist of exposed portion is removed.
Using dry etch process, groove structure battle array is generated on the bonding face of silica-base film for eliminating part photoresist Row, the groove structure array of generation are corresponding with groove array figure on photolithography plate.
Optionally, dry etch process is physical sputter etch or reactive ion etching;When using physical sputter etch, It is performed etching with Ar+ ions;When using reactive ion etching, mainly using SF6, CHF3, CF4 and C3F4 gas as process gas Body performs etching.
It slots alternatively, being corroded using wet processing, such as:Corroded using KOH solution.
After groove structure array completes, using acetone or glue is gone to remove remaining photoresist, then cleaning, drying.
Structure using the SAW filter materials of this kind of production method generation is as shown in Figure 1.In SAW filter materials, pressure For electric monocrystal thin films above silica-base film, silica-base film is square on a silicon substrate.
In bonding, silica-base film is bonded with piezoelectric monocrystal film, specifically, has groove knot by being made on silica-base film The one side of structure array is aligned with the bonding face of piezoelectric monocrystal film, the method by heating, pressurizeing, close to each other by bonding face When the Van der Waals force that generates, make the material layer phase counterdiffusion on bonding face both sides, finally by silica-base film and piezoelectric monocrystal film Bonding face is closely contacted together, generates SAW filter materials.
Figure 10 schematically illustrates a kind of making for SAW filter materials that another exemplary embodiment of the present invention provides The flow chart of method, as shown in Figure 10, the production method of the SAW filter materials includes:
Step 1001, photolithography plate is made, groove array figure is provided on photolithography plate.
Groove array figure includes several groove figures.
The step is expounded in step 801, and which is not described herein again.
Step 1002, piezoelectric monocrystal film and silicon base are cleaned.
The step is expounded in step 802, and which is not described herein again.
Step 1003, groove structure array is made on a silicon substrate using photolithography plate.
In groove structure array the angle on the bonding face transmission side of the fluting direction of groove and piezoelectric monocrystal film be 0 ° extremely Any angle between 90 °.
Silicon base is taken out, corresponding photoresist and spin coating rotating speed are selected according to groove depth;It is pressed in the bonding face of silicon base Spin coating rotating speed spin coating photoresist;Mask is done using photolithography plate, photoresist is exposed;Using developing liquid developing, by exposure portion The photoresist removal divided.
Using dry etch process, groove structure battle array is generated on the bonding face of silicon base for eliminating part photoresist Row, the groove structure array of generation are corresponding with groove array figure on photolithography plate.
Optionally, dry etch process is physical sputter etch or reactive ion etching;When using physical sputter etch, It is performed etching with Ar+ ions;When using reactive ion etching, mainly using SF6, CHF3, CF4 and C3F4 gas as process gas Body performs etching.
It slots alternatively, being corroded using wet processing, such as:Corroded using KOH solution.
After groove structure array completes, using acetone or glue is gone to remove remaining photoresist, then cleaning, drying.
Step 1004, making on a silicon substrate has the one side growth silica-base film of groove structure array.
There is the one side of groove structure array to be put into film deposition equipment, on a silicon substrate upward by being made in silicon base Making has the one side deposition silica-base film of groove structure array, such as silica.
Wherein, physical gas-phase deposition, such as evaporation, sputtering can be used in deposition silica-base film, can also use chemistry Gas-phase deposition, such as:PECVD (plasma enhanced CVD), LPCVD (low pressure chemical vapor deposition).
The silicon base for having deposited silica-base film is put into the vacuum environment that temperature is 200 to 1000 ° and is made annealing treatment, Annealing time is 2 hours or more, to eliminate the defect and impurity generated in silica-base film deposition process.
Step 1005, silica-base film is bonded with piezoelectric monocrystal film, generates SAW filter materials.
The bonding face of silica-base film is aligned with the bonding face of piezoelectric monocrystal film, the method by heating, pressurizeing passes through The Van der Waals force generated when bonding face is close to each other makes the material layer phase counterdiffusion on bonding face both sides, finally by silica-base film and The bonding face of piezoelectric monocrystal film is closely contacted together, generates SAW filter materials, as shown in Figure 6.
In SAW filter materials, for piezoelectric monocrystal film above silica-base film, silica-base film is square on a silicon substrate.
It should be noted that after SAW filter materials complete, change can also be utilized according to the actual demand of product Mechanical milling tech is learned, the top surface and/or bottom surface to SAW filter materials carry out attenuated polishing.
In conclusion the production method of SAW filter materials provided in an embodiment of the present invention, by making photolithography plate, photoetching Plate deletes the forming array figure being provided with including several groove figures, cleans piezoelectric monocrystal film and silicon base;Utilize photoetching Plate makes groove structure array, key in the bonding face of silicon base or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base Symphysis is at the SAW filter materials that material sequence is piezoelectric monocrystal film, silica-base film, silicon base;Utilize groove structure array shadow The generation for ringing propagation and interface reflected body wave of the bulk wave in crystalline material solves existing multilayer bonding piezoelectric material bulk wave Surface acoustic wave is influenced, the problem of the high-end inhibition difference of SAW filter is caused;Reach and has expanded answering for multilayer bonding piezoelectric material With range, ensure the effect of the performance of SAW filter.
Figure 11 schematically illustrates a kind of making for SAW filter materials that another exemplary embodiment of the present invention provides The flow chart of method, as shown in figure 11, the production method of the SAW filter materials includes:
Step 1101, photolithography plate is made, groove array figure is provided on photolithography plate.
Groove array figure includes several groove figures.
The step is expounded in step 801, and which is not described herein again.
Step 1102, piezoelectric monocrystal film and silicon base are cleaned.
The step is expounded in step 802, and which is not described herein again.
Step 1103, groove structure array is made on piezoelectric monocrystal film using photolithography plate.
In groove structure array the angle on the bonding face transmission side of the fluting direction of groove and piezoelectric monocrystal film be 0 ° extremely Any angle between 90 °.
The step is similar with the realization method of step 1003, and those skilled in the art can not have to pay any creative contribution Ground obtains making the concrete methods of realizing of groove structure array on piezoelectric monocrystal film.
It, can also be first with proton exchange, then with dense sulphur it should be noted that when using wet processing corrosion fluting The piezoelectric monocrystal film of the mixed solution of acid and nitric acid corrosion proton exchange part.
Step 1104, silica-base film is grown on a silicon substrate.
The step is expounded in step 8031, and which is not described herein again.
It should be noted that step 1103 and step 1104 may be performed simultaneously, alternatively, step 1104 step 1103 it Preceding execution.
Step 1105, there is the one side of groove structure array to be bonded with making on piezoelectric monocrystal film silica-base film, generate SAW filter materials.
There is the one side of groove structure array to be aligned with making on piezoelectric monocrystal film the bonding face of silica-base film, by adding Heat, the method for pressurization, the Van der Waals force generated when close to each other by bonding face make the material layer on bonding face both sides mutually expand It dissipates, is finally closely contacted the bonding face of silica-base film and piezoelectric monocrystal film together, generate SAW filter materials, such as scheme Shown in 3.
In SAW filter materials, for piezoelectric monocrystal film above silica-base film, silica-base film is square on a silicon substrate.
It should be noted that after SAW filter materials complete, change can also be utilized according to the actual demand of product Mechanical milling tech is learned, the top surface and/or bottom surface to SAW filter materials carry out attenuated polishing.
In conclusion the production method of SAW filter materials provided in an embodiment of the present invention, by making photolithography plate, photoetching Plate deletes the forming array figure being provided with including several groove figures, cleans piezoelectric monocrystal film and silicon base;Utilize photoetching Plate makes groove structure array, key in the bonding face of silicon base or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base Symphysis is at the SAW filter materials that material sequence is piezoelectric monocrystal film, silica-base film, silicon base;Utilize groove structure array shadow The generation for ringing propagation and interface reflected body wave of the bulk wave in crystalline material solves existing multilayer bonding piezoelectric material bulk wave Surface acoustic wave is influenced, the problem of the high-end inhibition difference of SAW filter is caused;Reach and has expanded answering for multilayer bonding piezoelectric material With range, ensure the effect of the performance of SAW filter.
Figure 12 schematically illustrates a kind of making for SAW filter materials that another exemplary embodiment of the present invention provides The flow chart of method, as shown in figure 12, the production method of the SAW filter materials includes:
Step 1201, photolithography plate is made, groove array figure is provided on photolithography plate.
Groove array figure includes several groove figures.
The step is expounded in step 801, and which is not described herein again.
Step 1202, piezoelectric monocrystal film and silicon base are cleaned.
The step is expounded in step 802, and which is not described herein again.
Step 1203, groove structure array is made on piezoelectric monocrystal film using photolithography plate.
In groove structure array the angle on the bonding face transmission side of the fluting direction of groove and piezoelectric monocrystal film be 0 ° extremely Any angle between 90 °.
The step is expounded in step 1103, and which is not described herein again.
Step 1204, being made on piezoelectric monocrystal film has the one side growth silica-base film of groove structure array.
There is the one side of groove structure array to be put into film deposition equipment, pressing upward by being made on piezoelectric monocrystal film Being made on electric monocrystal thin films has the one side deposition silica-base film of groove structure array, such as silica.
Wherein, physical gas-phase deposition, such as evaporation, sputtering can be used in deposition silica-base film, can also use chemistry Gas-phase deposition, such as:PECVD (plasma enhanced CVD), LPCVD (low pressure chemical vapor deposition).
The silicon piezoelectric monocrystal film for having deposited silica-base film is put into the vacuum environment that temperature is 200 to 1000 ° and is carried out Annealing, annealing time is 2 hours or more, to eliminate the defect and impurity generated in silica-base film deposition process.
Step 1205, silica-base film is bonded with silicon base, generates SAW filter materials.
The bonding face of silica-base film is aligned with the bonding face of silicon base, the method by heating, pressurizeing passes through bonding face The Van der Waals force generated when close to each other makes the material layer phase counterdiffusion on bonding face both sides, finally by silica-base film and silicon base Bonding face be closely contacted together, generate SAW filter materials, as shown in Figure 4.
In SAW filter materials, for piezoelectric monocrystal film above silica-base film, silica-base film is square on a silicon substrate.
It should be noted that after SAW filter materials complete, change can also be utilized according to the actual demand of product Mechanical milling tech is learned, the top surface and/or bottom surface to SAW filter materials carry out attenuated polishing.
In conclusion the production method of SAW filter materials provided in an embodiment of the present invention, by making photolithography plate, photoetching Plate deletes the forming array figure being provided with including several groove figures, cleans piezoelectric monocrystal film and silicon base;Utilize photoetching Plate makes groove structure array, key in the bonding face of silicon base or the bonding face of piezoelectric monocrystal film or the bonding face of silicon base Symphysis is at the SAW filter materials that material sequence is piezoelectric monocrystal film, silica-base film, silicon base;Utilize groove structure array shadow The generation for ringing propagation and interface reflected body wave of the bulk wave in crystalline material solves existing multilayer bonding piezoelectric material bulk wave Surface acoustic wave is influenced, the problem of the high-end inhibition difference of SAW filter is caused;Reach and has expanded answering for multilayer bonding piezoelectric material With range, ensure the effect of the performance of SAW filter.
It should be noted that:The embodiments of the present invention are for illustration only, can not represent the quality of embodiment.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of SAW filter materials, which is characterized in that silica-base film including silicon base, on the silicon base and Piezoelectric monocrystal film on the silica-base film;
The piezoelectric monocrystal film is lithium tantalate piezoelectric monocrystal film or lithium niobate piezoelectric monocrystal thin films;
It is made on the bonding face of the bonding face or the silicon base of the bonding face of the silica-base film or the piezoelectric monocrystal film There is groove structure array;
The bonding face of the silica-base film, the bonding face of the piezoelectric monocrystal film, the silicon base bonding face be polishing Face.
2. SAW filter materials according to claim 1, which is characterized in that the groove structure array is produced on the silicon On the bonding face of base film;
The silica-base film making has the one side of the groove structure array to be bonded with the piezoelectric monocrystal film, and the silicon substrate is thin Film is grown on the silicon base.
3. SAW filter materials according to claim 1, which is characterized in that the groove structure array is produced on the pressure On the bonding face of electric monocrystal thin films;
The silica-base film has in piezoelectric monocrystal film making under the one side of the groove structure array.
4. SAW filter materials according to claim 1, which is characterized in that the groove structure array is produced on the silicon On the bonding face of substrate;
The silica-base film is grown in the silicon base and makes the one side for having the groove structure array.
5. SAW filter materials according to claim 1, which is characterized in that the fluting of groove in the groove structure array The angle on the bonding face of direction and piezoelectric monocrystal film transmission side is any angle between 0 ° to 90 °.
6. a kind of production method of SAW filter materials, which is characterized in that the method includes:
Photolithography plate is made, is provided with groove array figure on the photolithography plate, the groove array figure includes several grooves Figure;
Clean piezoelectric monocrystal film and silicon base;The piezoelectric monocrystal film is lithium tantalate piezoelectric monocrystal film or lithium niobate piezoelectric Monocrystal thin films;
Using the photolithography plate, groove structure array is made on the piezoelectric monocrystal film or the silicon base;In the pressure Silica-base film is grown in electric monocrystal thin films or the silicon base;Or, growing silica-base film in the silicon base;Utilize the light It is mechanical, groove structure array is made on the silica-base film;
Bonding generates the SAW filter materials;
Wherein, in the SAW filter materials, the piezoelectric monocrystal film is above the silica-base film, the silica-base film Above the silicon base.
7. according to the method described in claim 6, it is characterized in that, when making institute in the silicon base using the photolithography plate It is described to grow silica-base film on the piezoelectric monocrystal film or the silicon base when stating groove structure array, including:
Being made in the silicon base has the one side of the groove structure array to grow the silica-base film;
The bonding generates the SAW filter materials, including:
The silica-base film is bonded with the piezoelectric monocrystal film, generates the SAW filter materials;
Wherein, in the groove structure array bonding face transmission side of fluting direction and the piezoelectric monocrystal film of groove folder Angle is any angle between 0 ° to 90 °.
8. according to the method described in claim 6, it is characterized in that, working as using the photolithography plate on the piezoelectric monocrystal film It is described to grow silica-base film on the piezoelectric monocrystal film or the silicon base when making the groove structure array, including:
The silica-base film is grown in the silicon base;
The bonding generates the SAW filter materials, including:
There is the one side of the groove structure array to be bonded with making on the piezoelectric monocrystal film silica-base film, generates institute State SAW filter materials;
Wherein, in the groove structure array bonding face transmission side of fluting direction and the piezoelectric monocrystal film of groove folder Angle is any angle between 0 ° to 90 °.
9. according to the method described in claim 6, it is characterized in that, working as using the photolithography plate on the piezoelectric monocrystal film It is described to grow silica-base film on the piezoelectric monocrystal film or the silicon base when making groove structure array, including:
Being made on the piezoelectric monocrystal film has the one side of the groove structure array to grow the silica-base film;
The bonding generates the SAW filter materials, including:
The silica-base film is bonded with the silicon base, generates the SAW filter materials;
Wherein, in the groove structure array bonding face transmission side of fluting direction and the piezoelectric monocrystal film of groove folder Angle is any angle between 0 ° to 90 °.
10. according to the method described in claim 6, it is characterized in that, when on a silicon substrate grow silica-base film when, the bonding The SAW filter materials are generated, including:
The silica-base film is bonded with the piezoelectric monocrystal film, generates the SAW filter materials;
Wherein, in the groove structure array bonding face transmission side of fluting direction and the piezoelectric monocrystal film of groove folder Angle is any angle between 0 ° to 90 °.
CN201810220554.0A 2018-03-16 2018-03-16 SAW filter materials and preparation method thereof Pending CN108494380A (en)

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