CN108430434A

CN108430434A - Aerosol type hair dyeing is used or hair decoloration applies some make up

Info

Publication number: CN108430434A
Application number: CN201680074383.4A
Authority: CN
Inventors: 野尻昌良; 堀江优
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 2015-12-28
Filing date: 2016-12-27
Publication date: 2018-08-21
Also published as: CN117017797A; TW201726028A; JP2021121643A; JP7215818B2; WO2017115823A1; JP2017119697A; TWI717445B

Abstract

The aerosol type hair dyeing of the present invention is used or hair decoloration applies some make up and has following outer container, the outer container stores the first content and second inner container, filled with first dose containing alkaline agent in the first content, filled with second dose containing hydrogen peroxide in second inner container, and, the propellant of 0.2~0.8MPa of internal pressure is filled in space between outer container and each inner pressurd vessel, first and second inner pressurd vessel is to be bonded 0.15~3.0gfcm of flexural rigidity that innermost layer is polyolefin resin layer²The multi-layer sheet of/cm and formed, (flexural rigidity of the sheet material of the first content)/(flexural rigidity of the sheet material of second inner container)=0.3~5, (first dose of viscosity)/(second dose of viscosity)=0.5~1.5, (second dose of quality)/(first dose of quality)=0.8 are less than 1.2.

Description

Aerosol type hair dyeing is used or hair decoloration applies some make up

Technical field

It is used the present invention relates to a kind of hair dyeing of aerosol type or hair decoloration applies some make up.

Background technology

Dual structure container as described below (hereinafter referred to as " separation filling-while spray of pressurizeing are proposed in the prior art Go out the dual structure container of type "), have and first dose of hair cosmetic composition and second dose are separated into filling, and utilizes same The structure that a pressurization ejection system sprays simultaneously.Such as such separation is disclosed in patent document 1 and patent document 2 and is filled out Fill-while squirt-type of pressurizeing dual structure container.

The dual structure container of these separation fillings-while squirt-type of pressurizeing is usually while spraying same amount of be filled in First dose in pocket with second dose of design, it is also with mass ratio 1 to be filled in first dose therein with second dose：1 equivalent Ground carries out mixing after spraying and is applied to hair.

However, for separation filling-while the dual structure container for squirt-type of pressurizeing, since it is using identical The ejection pressure of propellant and spray the structure of first dose and second dose simultaneously, so, especially when first dose of hair cosmetic composition and Second dose in the case of relatively highly viscous creams shape preparation, if cannot suitably adjust first dose with second dose it is respective Rheological behavior (ejection caused by flowing when by pressurizeing) then actually cannot achieve the equivalent spray of first dose and second dose Go out.When equivalent ejection is damaged certain degree or more, cannot achieve first dose and second dose of filling to dual structure container In made of hair cosmetic composition the hair dyeing performance originally set.

Further, when being, for example, the hair dyes such as oxide hair dye or the hair decolorising agent of double-formulation in hair cosmetics, It is at least combined with alkaline agent (and oxidation dye) in first dose, oxidant is combined in second dose.Due to by this composition On limitation, if first dose and second dose cannot equally be sprayed from beginning to end, can due to first dose it is mixed with second dose The variation of composition and division in a proportion and tone can be made to change, to cannot achieve sufficient hair dyeing effect.In addition, the ratio of the spray volume must It must pass through at any time and steadily realize, other than first dose with second dose of rheological behavior, also to confirm which kind of group carried out These effects could be realized at design, Vessel Design etc., are understood these and are very difficult.

It discloses, is obtained by adjusting rheological behavior to the half for the loading for spraying second dose in patent document 3 Equivalent ejection until amount.However, present situation is, the deviation of the equivalent ejection of latter half is very big, can not achieve to most Equivalent ejection until end.In this way, in the research only for rheological behavior, present situation can't be realized until final Equivalent ejection.

(patent document 1) Japanese Patent Laid-Open 2012-229318 bulletins

(patent document 2) Japanese Patent Laid-Open 2013-043659 bulletins

(patent document 3) Japanese Patent Laid-Open 2015-010087 bulletins

Invention content

A kind of aerosol type hair dyeing of present invention offer is used or hair decoloration applies some make up, and has following outer container, this is outer Container stores the first content and second inner container, and first dose containing alkaline agent, second inner container are filled in the first content In filled with second dose containing hydrogen peroxide, also,

In space between the outer container and each inner pressurd vessel, to press to 0.2MPa or more and 0.8MPa at 30 DEG C Mode below is filled with propellant,

The first content and second inner container are to be bonded innermost layer to have the multilayered structure of polyolefin resin layer respectively Sheet material and formed, the flexural rigidity E of the flexural rigidity E (f) of the sheet material of the first content and the sheet material of the second inner container (s) it is respectively 0.15gfcm²/ cm or more and 3.0gfcm²/ cm is hereinafter, ratio E (f)/E (s) of E (f) and E (s) is 0.3 Above and 5 hereinafter,

The ratio between this first dose viscosity V (f) at 30 DEG C and this second dose viscosity V (s) at 30 DEG C V (f)/V (s) are 0.5 or more and 1.5 hereinafter,

The ratio between first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container M (s)/M (f) is 0.8 less than 1.2.

Specific implementation mode

Therefore, it is used the present invention relates to a kind of hair dyeing of aerosol type or hair decoloration applies some make up, using separation filling- Pressurize the dual structure container of squirt-type simultaneously, and equivalent is maintained from beginning to end with second dose of spray volume by first dose, and with Time is by being also maintained equivalent.

The present inventor studies through making great efforts, as a result, it has been found that：Using pair for having separation filling-while squirt-type of pressurizeing Hair dyeing use or the hair decoloration of weight structure container apply some make up, by by the material of the pressure of propellant, inner bag material, bending Rigidity and flexural rigidity than and first dose be adjusted to specific range respectively with second dose of ratio of viscosities, can realize from beginning To whole equivalent ejection, and at any time by also realizing the equivalent ejection.

In the present specification, so-called to refer to " in first dose and the content in second dose of mixture ", by first dose with Second dose accurately with mass ratio 1：1 mixed in the case of mixture in content.

[outer container]

The aerosol type hair dyeing of the present invention is used or hair decoloration applies some make up and has following outer container, outer container storage the One inner pressurd vessel and second inner container, filled with first dose containing alkaline agent in the first content, filled with containing in second inner container There is second dose of hydrogen peroxide.

The outer container can use the synthesis trees such as metals or polyethylene terephthalate, polyarylate such as aluminium, tin plate Fat.

Especially, in the case of using synthetic resin as outer container, it is however preferred to have the synthetic resin material of translucency. About the outer container of this synthetic resin, it can be formed and obtain in the following way, that is, for by the extrusion molding by The semi-finished product of obtained bottomed tube are implemented to internally while axially stretching to be blown into twin shaft drawing that air makes it expand Stretch blow molding.Alternatively, it is also possible to be formed by direct blow molding, that is, so that the semi-finished product of tubular is expanded, under cutting Portion simultaneously bond and form bottom.In addition, about outer container, carbon, aluminium oxide, silica etc. can also be made to become gas Shape, to which evaporation film be arranged in inner surface and/or outer surface.

[inner pressurd vessel]

Inner pressurd vessel in the present invention is to be bonded the sheet material of multilayered structure of the innermost layer with vistanex and formed.Make For the inner pressurd vessel, can enumerate：Two sheets are overlapped, bag made of being bonded edge part by thermal welding or ultrasonic welding etc. (pouch).As the vistanex of innermost layer, polyvinyl resin (PE), acrylic resin (PP) etc. can be enumerated, from easy shape At the viewpoint of inner bag, reduce the viewpoint of first dose and second dose of surplus in each inner pressurd vessel for, preferably polyethylene tree Fat.

The flexural rigidity E of the flexural rigidity E (f) of the sheet material of the first content in the present invention and the sheet material of second inner container (s) it is 0.15gfcm²/ cm or more and 3.0gfcm²/ cm is hereinafter, from from beginning to end by first dose and second dose of spray volume Be maintained the viewpoint of equivalent, until final for the viewpoint that each inner pressurd vessel sprays first dose and second dose, preferably 0.2gf·cm²/ cm or more, more preferably 0.3gfcm²/ cm or more, further preferably 0.4gfcm²/ cm or more, into one Step is preferably 0.5gfcm²/ cm or more, further preferably 0.6gfcm²/ cm or more, in addition, from the spray with content Go out operation and make inner pressurd vessel follow deform viewpoint for, preferably 2.8gfcm²/ cm is hereinafter, more preferably 2.5gfcm²/ Cm is hereinafter, further preferably 2.4gfcm²/ cm is hereinafter, further preferably 2.2gfcm²/ cm is hereinafter, further preferably For 2.0gfcm²/ cm or less.

In addition, ratio E (f)/E (s) of E (f) and E (s) are 0.3 or more and 5 hereinafter, from from beginning to end by first dose and the Two doses of spray volume is maintained the viewpoint of equivalent, the viewpoint for reducing by first dose and second dose of surplus in each inner pressurd vessel, just For the excellent viewpoint of phase spray volume, preferably 0.4 or more, more preferably 0.5 or more, further preferably 1.0 or more, into one Step preferably 1.3 or more, additionally, it is preferred that for 4.5 hereinafter, more preferably 4 hereinafter, further preferably 3.33 hereinafter, further Preferably 3 or less.

About the flexural rigidity of sheet material, KES (Kawabata Evaluation System, river end evaluation system can be used System) Apparatus for Bending at low-temp etc. (such as multi-functional pure bending test machine KES-FB2-S (manufacture of Kato Tech companies)) surveyed It is fixed.

For the innermost layer for constituting the first content has the sheet material of multilayered structure of polyolefin resin layer, preferably have There are outermost layer and middle layer.

As outermost layer, polyester such as the polyamide such as nylon (NY), polyethylene terephthalate (PET) etc. can be enumerated.Make For middle layer, it is preferable to use metal foil can enumerate the light metals such as aluminium foil (Al foils) as the metal foil.

The combination of the outermost layer, middle layer, innermost layer of sheet material as the first content, can suitably select according to content It selects, for example, according to the sequence of outermost layer/middle layer/innermost layer, can enumerate：PE/Al foils/PE, PP/Al foil/PE, PET/Al foil/ PE, NY/Al foil/PE etc..In addition, the sheet material of the first content can also be that outermost double-layer structure is omitted, can also be It is further provided with four layers or more of structure of middle layer.

The sheet material about the innermost layer for constituting second inner container with the multilayered structure of polyolefin resin layer, from taking into account sheet material Appropriateness flexural rigidity and low damage viewpoint for, preferably there is outermost layer and middle layer.

As outermost layer, in the same manner as the sheet material of the first content, the polyamide such as nylon (NY), poly- terephthaldehyde can be enumerated Polyester such as sour second diester (PET) etc..As middle layer, the polyamides such as ethylene-vinyl alcohol copolymer (EVOH), nylon (NY) can be enumerated Amine etc. has the synthetic resin layer of barrier properties for gases and chemical resistance or silica is deposited in outermost layer or innermost layer (SiOX) non-metallic layers such as vapor deposition layer such as.

The combination of the outermost layer, middle layer, innermost layer of sheet material as second inner container, can suitably select according to content It selects, for example, according to the sequence of outermost layer/middle layer/innermost layer, can enumerate：PE/EVOH/PE、PP/EVOH/PE、PET/EVOH/ PE、PE/NY/PE、PP/NY/PE、PET/NY/PE、PE/SiOX/PE、PP/SiOX/PE、PET/SiOX/PE、PE/Al₂O₃/PE Deng.For taking into account viewpoint of the easiness to be formed with low damage, more preferably synthetic resin layer is used in middle layer.Separately Outside, the sheet material of second inner container can also be that outermost double-layer structure is omitted, and can also be and is further arbitrarily provided with Four layers or more of structure of synthetic resin layer or nonmetallic gas-barrier layer.In addition, the case where outer container is set as translucency Under, second inner container is also preferably set as translucency.

[internal pressure]

Into the space between outer container and each inner pressurd vessel, with press to 0.2MPa or more at 30 DEG C and 0.8MPa with Under mode fill propellant.About the internal pressure, from being maintained equivalent with second dose of spray volume by first dose from beginning to end For the viewpoint of viewpoint, first dose of reduction and second dose of surplus in each inner pressurd vessel, preferably 0.3MPa or more, more preferably For 0.4MPa or more, further preferably 0.5MPa or more, in addition, from the spray volume for maintaining first dose and second dose from beginning to end Ratio viewpoint, inhibit high temperature under outer container risk of rupture viewpoint for, preferably 0.75MPa hereinafter, more preferably For 0.7MPa or less.

In addition, internal pressure when about 30 DEG C, it is, for example, possible to use Bourdon tube pressure gauge, strain gage pressure gauge, flat Neat diaphragm (flush diaphragm) U-tube manometer etc. (specifically, instrument recorded in embodiment) is measured.

As the propellant filled, can enumerate：The compressed gas such as nitrogen, compressed air, carbon dioxide, nitrous oxide Body, liquid gas such as liquefied petroleum gas, HF hydrocarbon etc..

[viscosity]

Exist about second dose in viscosity V (f) of first dose in the first content at 30 DEG C and second inner container Viscosity V (s) at 30 DEG C, it is excellent from first dose of reduction and the viewpoint of second dose of surplus in each inner pressurd vessel, initial stage spray volume Different viewpoint prevents when by first dose being maintained the viewpoint of equivalent with second dose of spray volume from beginning to end, being applied on hair For the sagging viewpoint of preparation, it is respectively preferably 8,000mPas or more, more preferably 10,000mPas or more, further Preferably 12,000mPas or more, further preferably 15,000mPas or more, in addition, from reducing first dose and second dose The excellent viewpoint of the viewpoint of surplus in each inner pressurd vessel, initial stage spray volume, from beginning to end by first dose and second dose of spray Output is maintained the viewpoint of equivalent, is easy when being applied on hair for the viewpoint for making preparation extend, preferably 160, 000mPas hereinafter, more preferably 120,000mPas hereinafter, further preferably 100,000mPas hereinafter, further Preferably 80,000mPas hereinafter, further preferably 50,000mPas hereinafter, further preferably 45,000mPas Hereinafter, further preferably 40,000mPas is hereinafter, further preferably 35,000mPas or less.

In addition, the ratio between V (f) and V (s) V (f)/V (s) are 0.5 or more and 1.5 hereinafter, from from beginning to end by first dose and the Two doses of spray volume is maintained the viewpoint of equivalent, the viewpoint for reducing by first dose and second dose of surplus in each inner pressurd vessel, just For the excellent viewpoint of phase spray volume, preferably 0.55 or more, more preferably 0.6 or more, further preferably 0.7 or more, into One step is preferably 0.8 or more, additionally, it is preferred that for 1.4 hereinafter, more preferably 1.3 hereinafter, further preferably 1.10 hereinafter, into One step is preferably 1.07 hereinafter, further preferably 1.05 hereinafter, further preferably 1.04 hereinafter, further preferably 1.02 Below.

About the first dose and second dose viscosity at 30 DEG C, can be measured using Brookfield viscometer.In addition, about First dose in the first content and second dose of viscosity at 30 DEG C in second inner container can be taken out from outer container in each Container, and after taking out first dose and second dose in each inner pressurd vessel, be measured using Brookfield viscometer.In addition, specifically, It can be measured by method recorded in embodiment.

[mass ratio]

About first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container it Than M (s)/M (f), for maintaining first dose of viewpoint with the ratio of second dose of spray volume from beginning to end, M (s)/M (f) is 0.80 or more, preferably 0.85 or more, more preferably 0.90 or more, in addition, less than 1.2, preferably 1.15 hereinafter, more preferably 1.10 following.

[alkaline agent]

Contain alkaline agent in first dose.As alkaline agent, can enumerate：Ammonia and its salt (such as ammonium hydrogen carbonate)；It is monoethanolamine, different Alkanolamines and its salt such as Propanolamine, 2- amino-2-methyls propyl alcohol, 2- amino butanols；The alkane such as 1,3- propane diamine diamines and its salt； Carbonate such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium bicarbonate, saleratus etc..For these alkaline agents, can also and with two kinds More than.About the content of the alkaline agent in first dose, from make the abundant swelling of hair and for obtaining the viewpoint of hair dyeing effect, preferably 0.1 mass % or more, more preferably 0.2 mass % or more, further preferably 0.4 mass % or more, in addition, from hair is reduced Damage or scalp irritation viewpoint for, preferably 14 mass % hereinafter, more preferably 12 mass % hereinafter, further preferably 8 mass % or less.About the content of the alkaline agent in first dose of mixture with second dose, from the viewpoint of sufficient hair dyeing effect and Speech, preferably 0.05 mass % or more, more preferably 0.1 mass % or more, further preferably 0.2 mass % or more, into one Step is preferably 0.5 mass % or more, further preferably 1 mass % or more, in addition, from hair damages or scalp irritation is reduced For viewpoint, preferably 7 mass % hereinafter, more preferably 6 mass % hereinafter, further preferably 5 mass % hereinafter, further Preferably 4 mass % or less.

[hydrogen peroxide]

Contain hydrogen peroxide in second dose.About the content of the hydrogen peroxide in second dose, from decomposition hair melanin And for ensuring the coupling reaction of oxidation dye and obtaining the viewpoint of sufficient hair dyeing effect, preferably 1 mass % or more, more Preferably 3 mass % or more, in addition, for the viewpoint for reducing hair damages or scalp irritation, preferably 9 mass % hereinafter, More preferably 6 mass % or less.About the content of the hydrogen peroxide in first dose of mixture with second dose, preferably 1 matter Measure % or more, more preferably 2 mass % or more, additionally, it is preferred that for 6 mass % hereinafter, more preferably 5 mass % or less.

[surfactant]

It can contain surfactant in first dose, any one of second dose or both.It, can as surfactant It enumerates：Cationic surfactant, nonionic surfactant, amphoteric surfactant and anion surfactant.These Among, for the viewpoint of the stability of formula composition, preferably anion surfactant, nonionic surfactant.

As anion surfactant, can enumerate：Alkylbenzene sulfonate, alkyl ether sulfate, alkenyl ether sulfates, alkane Base sulfate, alkenyl sulfate, alkene sulfonate, alkane sulfonate, saturation or unsaturated fatty acid salt, alkyl ether carboxy acid salt, Alkenyl ether carboxylate, alpha-sulfo-fatty acid salt, N- acyl aminos hydrochlorate, phosphate monoester or di-phosphate ester, sulfosuccinate etc.. As alkyl ether sulfate, polyoxyethylene alkyl ether sulfate salt can be enumerated.Anion as these anion surfactants The gegenion (counter ion) of property group, can enumerate：The alkali metal ions such as sodium ion, potassium ion；Calcium ion, magnesium ion Equal alkaline-earth metal ions；Ammonium ion；Alkanolamine (such as monoethanolamine with the silane alcohol base that 1~3 carbon atom number is 2 or 3 Salt, diethanolamine salt, triethanolamine salt, triisopropanolamine salt etc.).

As cationic surfactant, for the viewpoint for assigning excellent sense of touch to the hair after hair dyeing, preferably Monoalkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride, monoalkyl trimethyl ammonium bromide, wherein more preferably stearyl Trimethyl ammonium chloride (Steartrimonium chloride), cetyl trimethyl ammonium chloride (Cetrimonium Chloride), lauryl trimethyl ammonium chloride (Lauryl Trimonium chloride), preferably also will be two or more mixed It closes.

As nonionic surfactant, can enumerate：Polyoxyalkylene alkyl, polyoxyalkylene alkenyl ether, higher fatty acids It is sucrose ester, polyglyceryl fatty acid ester, higher fatty acids single ethanol amide or higher fatty acids diglycollic amide, polyethylene glycol hydrogenated Castor oil, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol aliphatic ester, alkyl carbohydrate, alkyl oxidation Amine, alkylamide amine oxide etc..Among these, preferably polyoxyalkylene alkyl, Crodaret, alkyl candy Class, more preferably polyxyethylated (12~14) ether, alkyl polyglucoside.

As amphoteric surfactant, can enumerate：Imidazoline, carbobetaine, amide betaine, sulfobetaines, hydroxyl Base sulfobetaines, amide sulfo betaine etc., more preferably alkyl dimethyl oxyneurine, fatty amide propyl sweet tea The beet alkali surface activators such as dish alkali, further preferably fattyamidopropyl betaine.

These surfactants can be used alone it is any, or by it is two or more combination and use.About first dose with The content of surfactant in second dose of mixture, for good sense of touch, the viewpoint of emulsifiability, preferably 0.1 Quality % or more, more preferably 0.2 mass % or more, further preferably 0.5 mass % or more, in addition, from obtaining adequately For the viewpoint of hair dyeing effect, preferably 30 mass % hereinafter, more preferably 25 mass % hereinafter, further preferably 20 matter % is measured hereinafter, further preferably 10 mass % are hereinafter, further preferably 5 mass % or less.

[higher alcohol]

It can contain higher alcohol in first dose, any one of second dose or both.It, can be under use as higher alcohol State the compound represented by general formula (1).

R-OH(1)

[in formula, R indicates that carbon atom number is the alkyl of 12 or more and 24 linear chain or branched chains below.]

As higher alcohol, can enumerate：Laruyl alcohol, myristyl alcohol, cetanol, stearyl alcohol, isooctadecanol, arachidic alcohol, behenyl Alcohol, tetracosanol, oleyl alcohol etc..It for higher alcohol, can be used alone, or two or more combinations used.

About higher alcohol, for the viewpoint for the viscosity change for inhibiting to pass through at any time, preferably (1a) above-mentioned general formula (1) In R be higher alcohol that carbon atom number is 12 or more and 18 straight chained alkyls below, be carbon with the R in (1b) above-mentioned general formula (1) Atomicity is the combination of the higher alcohol of 20 or more and 24 straight chained alkyls below, and the more preferably R in (1a) above-mentioned general formula (1) is Carbon atom number is the higher alcohol of 14 or more and 18 straight chained alkyls below, is that carbon atom number is with the R in (1b) above-mentioned general formula (1) The combination of the higher alcohol of 20 or more and 22 straight chained alkyls below.Mass ratio [(1a) about ingredient (1a) and ingredient (1b)： (1b)], for the viewpoint for the viscosity change for inhibiting to pass through at any time, preferably 0.5：9.5~9.5：0.5, more preferably 1：9 ~9：1, further preferably 1.5：8.5~8.5：1.5, further preferably 1：4~4：1.

About the content of the higher alcohol in first dose of mixture with second dose, conduct is set as from by the viscosity after rigid manufacture The viewpoint of hair dye and range appropriate, for inhibiting the viewpoint of the viscosity change passed through at any time, preferably 3 mass % with On, more preferably 4 mass % or more, further preferably 5 mass % or more, in addition, becoming from the viscosity for inhibiting to pass through at any time For the viewpoint of change, preferably 12 mass % hereinafter, more preferably 11 mass % hereinafter, further preferably 10 mass % with Under, further preferably 9 mass % or less.

[hydrocarbon]

It can contain hydrocarbon in first dose, any one of second dose or both.It about hydrocarbon, can be used alone, or will It is two or more combination and use.As the hydrocarbon of the present invention, can enumerate：Liquid paraffin, liquid isoalkane, lightweight isoalkane, lightweight Liquid isoalkane, heavy liquid isoalkane, saualane etc..Among these, from the viewpoint for the viscosity change for inhibiting to pass through at any time For, preferably liquid paraffin.

About the content of the hydrocarbon in first dose of mixture with second dose, the brightness after improving hair dyeing or hair decoloration Viewpoint for, preferably 1 mass % or more, more preferably 2 mass % or more, further preferably 3 mass % or more, separately Outside, preferably 20 mass % hereinafter, more preferably 15 mass % hereinafter, further preferably 10 mass % hereinafter, further it is excellent It is selected as 8 mass % or less.

[ester oil]

It can contain ester oil in first dose, any one of second dose or both.About ester oil, can be used alone, Or two or more combinations are used.As the ester oil of the present invention, can enumerate：Myristic acid octyldodecyl alcohol ester, nutmeg The different tridecane alcohol ester of isopropyl propionate, isopropyl isostearate, isononyl isononanoate, isononanoic acid, butyl stearate, oleyl oleate, Ricinoleic acid octyldodecyl alcohol ester, two capric acid neopentyl glycol ester, two isooctadecanol ester of malic acid, octyl hydroxystearate, Australia Continent macadamia nut oil, olive oil, castor oil, Jojoba Oil, avocado oil, sunflower oil, two isostearic acid polyglycerol esters, three isostearic acids Polyglycerol ester, two glyceryl isostearates, three glyceryl isostearates, three (caprylic/capric) glyceride, three (2 ethyl hexanoic acids) Glyceride, Pentaerythrityl tetraoctanoate etc..Among these, for the higher viewpoint of emulsion stability, it is preferably belonging to be saturated The following substance of the branch alcohol ester of aliphatic acid：It is isopropyl myristate, isopropyl isostearate, two different stearyl ester of malic acid, different The different nonyl ester of n-nonanoic acid, isononanoic acid isotridecyl ester, palmitic acid 2- ethylhexyls, myristic acid octyldodecyl alcohol ester, oleic acid are pungent Base dodecane alcohol ester, sinapic acid octyldodecyl alcohol ester etc..

About the content of the ester oil in first dose of mixture with second dose, the light after improving hair dyeing or hair decoloration For the viewpoint of degree, preferably 0.01 mass % or more, more preferably 0.03 mass % or more, in addition, from mixture in hair On sufficient ductility viewpoint for, preferably 5 mass % hereinafter, more preferably 3 mass % hereinafter, further preferably 2 mass % or less.

[organic solvent]

It can contain organic solvent in first dose, any one of second dose or both.As organic solvent, can arrange It lifts：The low-grade alkane alcohols such as ethyl alcohol, 1- propyl alcohol, 2- propyl alcohol；The aromatic alcohols such as benzylalcohol, 2- benzyloxyethanol, phenoxetol；The third two The polyalcohols such as alcohol, 1,3 butylene glycol, diethylene glycol, glycerine；The ethers such as ethoxy ethanol, ethoxydiglycol, methyl cellosolve Alcohol；The N- alkyl pyrrolidones such as N-Methyl pyrrolidone, N- ethyl pyrrolidones；The carbonic acid alkane diester such as propylene carbonate；γ-penta The lactones such as lactone, γ-hexalactone.

These organic solvents can be used alone, or two or more combinations are used, in addition, about it at first dose and Content in second dose of mixture, from the viewpoint for preventing oxidation dye to be precipitated from first dose of mixture with second dose and Speech, preferably 0.1 mass % or more, more preferably 0.5 mass % or more, further preferably 1 mass % or more, in addition, from Mixture is prevented to be separated into aqueous layer with for the viewpoint of oil phase layer, preferably 35 mass % are hereinafter, more preferably 30 mass % Hereinafter, further preferably 25 mass % hereinafter, further preferably 20 mass % hereinafter, further preferably 15 mass % with Under, further preferably 10 mass % or less.

[dyestuff]

It is used or hair decoloration applies some make up in the case of applying some make up for hair dyeing in the hair dyeing of the aerosol type of the present invention, the Contain oxidation dye intermediates or direct dyes in one.

(oxidation dye intermediates)

As oxidation dye intermediates, the well known predecessor usually used in hair dye can be used (precursor) and colour coupler (coupler).As predecessor, such as can enumerate：P-phenylenediamine, Toluene-2,4-diisocyanate, 5- diamines, neighbour Chlorine p-phenylenediamine, 4-aminodiphenylamine, N, bis- (hydroxyethyl) p-phenylenediamine of N-, 3- methyl -4-aminophenol, 2- hydroxyl second Base p-phenylenediamine, para-aminophenol, p-methylaminophenol, 4- amino metacresol, o-aminophenol and their salt etc..

In addition, as colour coupler, such as can enumerate：Resorcinol, 2- methyl resorcinols, 1- naphthols, 1,5- dihydroxy Naphthalene, 5- amino o-cresol, m-phenylene diamine (MPD), o-aminophenol, m-aminophenol, para-aminophenol, 2,4- diamino phenoxy second Alcohol, 2,6- diamino-pyridines, 2- methyl -5- Hydroxy-ethylaminos phenol, 2- amino -3- pyridones and their salt etc..

For predecessor and colour coupler respectively for, can be used alone, or by it is two or more combination and use.First dose In predecessor and the respective content of colour coupler be preferably 0.01 mass % or more, more preferably 0.1 mass % or more, in addition, Preferably 5 mass % are hereinafter, more preferably 4 mass % or less.

(direct dyes)

As direct dyes, can enumerate：Acid dyes, nitro dye, disperse dyes, basic dye etc..More specifically, As acid dyes, can enumerate：Blue 1, purple 401, black 401, No. 205 orange, No. 227 red, red 106 Number, (1) of yellow 202, (2) of yellow 202, yellow 203, acid orange 3 etc., as nitro dye, can enumerate：2- nitre The chloro- 4- nitrophenols of base p-phenylenediamine, 2- amino -6-, 3- nitros are to Hydroxy-ethylamino phenol, 4-nitro-o-phenylenediamine, 4- Amino-3-nitro phenol, 4- hydroxypropylamino -3- nitrophenols, HC indigo plants 2, HC oranges 1, HC be red 1, HC Huangs 2, HC Huangs 4, HC are yellow 5, HC is red 3, N, and bis- (2- hydroxyethyls) -2- nitro p-phenylenediamines of N- etc. as disperse dyes, can enumerate：Disperse violet 1, dispersion Indigo plant 1, dispersion black 9 etc., as basic dye, can enumerate：Alkali blue 99, bismarck brown 16, bismarck brown 17, alkalinity is red 76, basic yellow 76, Basic Orange 31, alkalinity red 51 etc..

It for direct dyes, can be used alone, or two or more combinations used, it can also be with oxidation dye Intermediate is used in combination.The content of direct dyes in first dose is preferably 0.001 mass % or more, more preferably 0.01 mass % with On, additionally, it is preferred that for 5 mass % hereinafter, more preferably 3 mass % or less.

[any other ingredient]

In first dose or second dose that the aerosol type hair dyeing use of the present invention or hair decoloration apply some make up, in addition to above-mentioned Other than ingredient, the other compositions for being typically used as cosmetic material can also be added.As this any ingredient, can enumerate：Finish, Polysiloxane-based, non-volatile hydrophilic solvent, animal and plant fat, natural or synthetic macromolecule, ethers, protein derived Object, aminosal, amino acids, preservative, chelating agent, stabilizer, antioxidant, botanical extract, extracts from crude drugs, Vitamins, fragrance, ultra-violet absorber etc..

[pH value]

First dose of pH value (25 DEG C) is preferably 8 or more and 12 or less.For the viewpoint of the stability of hydrogen peroxide, the Two doses of pH value (25 DEG C) is preferably 2 or more and 5 or less.Further, about first dose with second dose of mixture when in use PH value (25 DEG C), from make hair swelling and for obtaining the viewpoint of sufficient hair dyeing effect, preferably 8.0 or more, more preferably Be 8.5 or more, further preferably 9.0 or more, in addition, for the viewpoint for preventing the stimulation to scalp, preferably 11.5 with Under, more preferably 11.0 hereinafter, further preferably 10.5 or less.In addition, the pH value in the present invention is to make institute using hole field The value that the pH meter F-22 of manufacture is measured under room temperature (25 DEG C).

[hair dyeing tool]

Hair dyeing tool can be used to apply some make up and be applied to hair the aerosol type hair dyeing use of the present invention or hair decoloration On.As hair dyeing tool, it can use and have comb section as recorded in the flat 10-71020 bulletins of Japanese Patent Laid-Open And bristle portion hair dyeing tool or as in Japanese Patent Laid-Open 2006-326081 bulletins it is recorded have comb section and The hair dyeing tool of bristle portion (bristle portion has to keep the recess portion of preparation).

[dosage form]

About first dose and second dose of dosage form, creams shape, gel, paste etc. can be set as.

[hair is had hair dyed or hair discoloration method]

For the hair dyeing of the aerosol type of the present invention is used or hair decoloration applies some make up, held in the palm to pre-prepd mixing First dose and second dose is sprayed in disk, utilizes hair dyeing work recorded in the flat 10-71020 bulletins of such as Japanese Patent Laid-Open After the bristle portion of tool mixes first dose with second dose, the mixture obtained is applied on hair, it is possible thereby to by hair Dyeing or decoloration.

In addition, for the hair dyeing of the aerosol type of the present invention is used or hair decoloration applies some make up, to such as Japan Patent text First dose and second dose of the recess portion ejection of the bristle portion of hair dyeing tool recorded in special open 2006-326081 bulletins is offered, and The bristle portion is directly used in hair, thus, it is possible to make first dose to be mixed on hair with second dose on one side, it is whole in hair on one side It smears and opens on body, thus by hair-dyeing or decoloration.

About the implementation described above, the preferred embodiment of the present invention is recorded further below.

A kind of aerosol type hair dyeings of 1 ＞ of ＜ are used or hair decoloration applies some make up, wherein have following outer container, the outer appearance Device stores the first content and second inner container, first dose containing alkaline agent is filled in the first content, in second inner container Filled with second dose containing hydrogen peroxide, also,

The hair dyeing of recorded aerosol type is used in 1 ＞ of ＜ 2 ＞ such as ＜ or hair decoloration applies some make up, wherein preferably the The vistanex of one inner pressurd vessel and the innermost layer of second inner container is polyvinyl resin or acrylic resin.

The hair dyeing of recorded aerosol type is used in 2 ＞ of ＜ 3 ＞ such as ＜ 1 ＞ or ＜ or hair decoloration applies some make up, wherein E (f) and E (s) is preferably 0.2gfcm²/ cm or more, more preferably 0.3gfcm²/ cm or more, further preferably 0.4gf cm²/ cm or more, further preferably 0.5gfcm²/ cm or more, further preferably 0.6gfcm²/ cm or more, in addition, excellent It is selected as 2.8gfcm²/ cm is hereinafter, more preferably 2.5gfcm²/ cm is hereinafter, further preferably 2.4gfcm²/ cm hereinafter, Further preferably 2.2gfcm²/ cm is hereinafter, further preferably 2.0gfcm²/ cm or less.

Aerosol type hair dyeings of 4 ＞ of ＜ as recorded in any one of 3 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein E (f)/E (s) is preferably 0.4 or more, more preferably 0.5 or more, further preferably 1.0 or more, further preferably It is 1.3 or more, additionally, it is preferred that for 4.5 hereinafter, more preferably 4 hereinafter, further preferably 3.33 hereinafter, further preferably 3 Below.

Aerosol type hair dyeings of 5 ＞ of ＜ as recorded in any one of 4 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein preferably comprise the multilayered structure of the first content sheet material have outermost layer and middle layer, outermost layer be polyamide or Polyester, middle layer are metal foil.

Aerosol type hair dyeings of 6 ＞ of ＜ as recorded in any one of 5 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein preferably comprise the multilayered structure of second inner container sheet material have outermost layer and middle layer, outermost layer be polyamide or Polyester, middle layer are synthetic resin layer or silica vapor deposition layer with barrier properties for gases and chemical resistance.

Aerosol type hair dyeings of 7 ＞ of ＜ as recorded in any one of 6 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein internal pressure at 30 DEG C is preferably 0.3MPa or more, more preferably 0.4MPa or more, further preferably 0.5MPa with On, additionally, it is preferred that for 0.75MPa hereinafter, more preferably 0.7MPa or less.

Aerosol type hair dyeings of 8 ＞ of ＜ as recorded in any one of 7 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein V (f) and V (s) is respectively preferably 8,000mPas or more, more preferably 10,000mPas or more, further excellent Be selected as 12,000mPas or more, further preferably 15,000mPas or more, additionally, it is preferred that for 160,000mPas with Under, more preferably 120,000mPas hereinafter, further preferably 100,000mPas hereinafter, further preferably 80, 000mPas hereinafter, further preferably 50,000mPas hereinafter, further preferably 45,000mPas hereinafter, into one Step is preferably 40,000mPas hereinafter, further preferably 35,000mPas or less.

Aerosol type hair dyeings of 9 ＞ of ＜ as recorded in any one of 8 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein V (f)/V (s) is preferably 0.55 or more, more preferably 0.6 or more, further preferably 0.7 or more, further excellent Be selected as 0.8 or more, additionally, it is preferred that for 1.4 hereinafter, more preferably 1.3 hereinafter, further preferably 1.10 hereinafter, further it is excellent 1.07 are selected as hereinafter, further preferably 1.05 hereinafter, further preferably 1.04 hereinafter, further preferably 1.02 or less.

Aerosol type hair dyeings of 10 ＞ of ＜ as recorded in any one of 9 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein the ratio between first dose mass M (f) in second dose of mass M (s) and the first content in second inner container M (s)/M (f) is preferably 0.85 or more, and more preferably 0.90 or more, additionally, it is preferred that for 1.15 hereinafter, more preferably 1.10 or less.

Aerosol type hair dyeings of 11 ＞ of ＜ as recorded in any one of 10 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein preferably further contain surfactant in first dose, any one of second dose or both.

The hair dyeing of recorded aerosol type is used in 11 ＞ of ＜ 12 ＞ such as ＜ or hair decoloration applies some make up, wherein first dose Content with the surfactant in second dose of mixture is preferably 0.1 mass % or more, more preferably 0.2 mass % with On, further preferably 0.5 mass % or more, additionally, it is preferred that for 30 mass % hereinafter, more preferably 25 mass % hereinafter, into One step is preferably 20 mass % hereinafter, further preferably 10 mass % are hereinafter, further preferably 5 mass % or less.

Aerosol type hair dyeings of 13 ＞ of ＜ as recorded in any one of 12 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein preferably further contain higher alcohol in first dose, any one of second dose or both.

The hair dyeing of recorded aerosol type is used in 13 ＞ of ＜ 14 ＞ such as ＜ or hair decoloration applies some make up, wherein preferred high Grade alcohol is the compound represented by the following general formula (1),

R-OH(1)

In formula, R indicates that carbon atom number is the alkyl of 12 or more and 24 linear chain or branched chains below.

The hair dyeing of recorded aerosol type is used in 14 ＞ of ＜ 15 ＞ such as ＜ or hair decoloration applies some make up, wherein higher alcohol It with (1b) R be carbon atom number is 20 that preferably (1a) R, which is higher alcohol that carbon atom number is 12 or more and 18 straight chained alkyls below, Above and the combination of the higher alcohol of 24 straight chained alkyls below, more preferably (1a) R be carbon atom number are 14 or more and 18 or less Straight chained alkyl higher alcohol and (1b) R be the higher alcohol that carbon atom number is 20 or more and 22 straight chained alkyls below combination.

The hair dyeing of recorded aerosol type is used in 15 ＞ of ＜ 16 ＞ such as ＜ or hair decoloration applies some make up, wherein ingredient The mass ratio [(1a) of (1a) and ingredient (1b)：(1b)] it is preferably 0.5：9.5~9.5：0.5, more preferably 1：9~9：1, into one Step preferably 1.5：8.5~8.5：1.5, further preferably 1：4~4：1.

Aerosol type hair dyeings of 17 ＞ of ＜ as recorded in any one of 16 ＞ of ＜ 13 ＞ to ＜ is used or hair decoloration Cosmetic, wherein the content of the higher alcohol in first dose of mixture with second dose is preferably 3 mass % or more, more preferably 4 matter Measure % or more, further preferably 5 mass % or more, additionally, it is preferred that for 12 mass % hereinafter, more preferably 11 mass % with Under, further preferably 10 mass % are hereinafter, further preferably 9 mass % or less.

Aerosol type hair dyeings of 18 ＞ of ＜ as recorded in any one of 17 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein preferably contain hydrocarbon in first dose, any one of second dose or both.

The hair dyeing of recorded aerosol type is used in 18 ＞ of ＜ 19 ＞ such as ＜ or hair decoloration applies some make up, wherein first dose Content with the hydrocarbon in second dose of mixture is preferably 1 mass % or more, more preferably 2 mass % or more, further preferably For 3 mass % or more, additionally, it is preferred that for 20 mass % hereinafter, more preferably 15 mass % are hereinafter, further preferably 10 matter % is measured hereinafter, further preferably 8 mass % or less.

Aerosol type hair dyeings of 20 ＞ of ＜ as recorded in any one of 19 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein preferably contain ester oil in first dose, any one of second dose or both.

The hair dyeing of recorded aerosol type is used in 20 ＞ of ＜ 21 ＞ such as ＜ or hair decoloration applies some make up, wherein first dose Content with the ester oil in second dose of mixture is preferably 0.01 mass % or more, more preferably 0.03 mass % or more, separately Outside, preferably 5 mass % hereinafter, more preferably 3 mass % hereinafter, further preferably 2 mass % or less.

Aerosol type hair dyeings of 22 ＞ of ＜ as recorded in any one of 21 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein the content of the alkaline agent in first dose is preferably 0.1 mass % or more, more preferably 0.2 mass % or more, further Preferably 0.4 mass % or more, additionally, it is preferred that for 14 mass % hereinafter, more preferably 12 mass % are hereinafter, further preferably 8 mass % or less.

Aerosol type hair dyeings of 23 ＞ of ＜ as recorded in any one of 22 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup Product, wherein the content of the hydrogen peroxide in second dose is preferably 1 mass % or more, more preferably 3 mass % or more, in addition, excellent 9 mass % are selected as hereinafter, more preferably 6 mass % or less.

[embodiment]

Then, the embodiment of the present invention and comparative example are illustrated.The technical scope of the present invention is not limited to following Examples and Comparative Examples.

According to common method, first dose, the Yi Ji of the formula 1-1~1-11 formed shown in the table 6 of the end of writing are prepared Second dose of the formula 2-1~2-12 formed shown in table 7.These first dose with second dose be emulsification after creams shape system Agent.In each table, indicate that the numerical value of the content of each ingredient is the numerical value of the quality % units in first dose or second dose.

These first dose and second dose is filled with combination shown in table 1~5 to separation filling-while ejection of pressurizeing In the first content and second inner container of the dual structure container of type, and carry out measurement below and evaluation.

[sheet material of the first content and second inner container]

The first content use according to outermost layer/middle layer/innermost layer sequence be PET/Al foils/PE material as piece Material.In addition, second inner container use according to outermost layer/middle layer/innermost layer sequence be PET/NY/PE material as piece Material.In addition, using nitrogen as the propellant of filling.

[viscosimetric analysis]

About first dose be contained in the first content and be contained in second inner container second dose at 30 DEG C Viscosity uses B shapes viscosimeter (manufacture of Dong Ji industry companies, model TVB-10R, the T-BAR STAGE TS- with helical mount 10).Specifically, cutting off outer container using cutter, followed by scissors cut the first content and second inner container, and take Go out first dose and second dose.After obtained first dose and second dose is placed 1 day respectively, then if it is less than 50,000mPas The value after being rotated 1 minute with 12rpm at 30 DEG C using main shaft No.M4 is taken, if it is 50,000mPas or more if takes using leading Axis No.T-C 30 DEG C with 10rpm rotate 1 minute after value.It is measured, is being shown not according to the sequence of main shaft No.M4, T-C Terminate to measure more than indication range and at the time of being measured to, measurement thereafter no longer carries out.

In addition, in each table, " V (f)/V (s) " indicates first dose of the V (f) measured by said determination method and the The value of the ratio " V (f)/V (s) " of two doses of viscosity V (s).

[initial stage spray volume]

Respectively simultaneously by first dose and second dose filling of creams shape recorded in the table of 40g 6~7 to separation filling- In the dual structure container for squirt-type of pressurizeing.Thereafter, it is impregnated 30 minutes in 30 DEG C of thermostat, carry out while spraying first dose Operation 5 seconds with second dose, thus measures each dose of spray volume.

[equivalent ejection]

Respectively simultaneously by first dose and second dose filling of creams shape recorded in the table of 40g 6~7 to separation filling- In the dual structure container for squirt-type of pressurizeing.Thereafter, it is impregnated 30 minutes in 30 DEG C of thermostat, and is repeated while spraying First dose with second dose of operation, when second dose of amount of ejection reaches 25 mass % for the 40g being filled every time, to first dose Spray volume be measured, at the time of the whole amount filled is ejected, stop and meanwhile spray operation.Also, it will be measured First dose of quality criteria spray volume, with the spray volume of measured first dose of quality criteria relative to second dose of matter The ratio for measuring the spray volume of benchmark is shown in " equivalent ejection " column of each table.

[surplus evaluation test]

Respectively extremely by first dose and second dose filling of creams shape recorded in the table 6~7 of 40g (quality before ejection) In separation filling-while the dual structure container for squirt-type of pressurizeing.It carries out spraying operation until being contained in first dose in container Or second dose can not spray until (full dose ejection), and to full dose spray after first remained in inner pressurd vessel dose and second dose Quality (full dose spray after quality) be measured.Specifically, cutting off outer container using cutter, cut followed by scissors The first content and second inner container are cut, and takes out first dose and second dose remained in each inner pressurd vessel, then quality measurement.Needle To first dose and second dose, the surplus ratio in inner pressurd vessel is calculated by following formula.

Surplus ratio (%)=(quality after full dose ejection)/(quality before ejection) × 100

[inner voltage detecting]

Used as the instrument WGA-710c (manufacture of republicanism utility companies) of adjuster, as small pressure converter Internal pressure when PGM-10KEZ1 (manufacture of republicanism utility companies) is to 30 DEG C is measured.The pressure of small pressure interpreter is imported Portion withstands on separation filling-while the compression bar position of the outer container of the dual structure container for squirt-type of pressurizeing is kept for the stipulated time, at For fixed value when, which is set as internal pressure.

[flexural rigidity measurement]

Under the conditions of 20 DEG C, piece is measured using multi-functional pure bending test machine KES-FB2-S (manufacture of Kato Tech companies) The flexural rigidity of material.Specifically, by the shape that the sheet cutting of the multilayered structure used in inner pressurd vessel is vertical 2cm × horizontal 4cm Shape.The sheet material of the cut-out is sandwiched between the fixed chuck of testing machine and movable chuck.Then, the maximum curvature of testing machine is set It is set to 2.5cm^-1, recurring number is set as 2 times, and is measured.It is respectively 0.5cm according to curvature^-1And 1.5cm^-1When each value ask Go out moment-curvature slope of a curve, and the value is set as flexural rigidity.

Claims

1. a kind of aerosol type hair dyeing is used or hair decoloration applies some make up, wherein

The aerosol type hair dyeing is used or hair decoloration applies some make up and has following outer container, which stores the first content And second inner container, filled with first dose containing alkaline agent in the first content, filled with containing peroxidating in second inner container Second dose of hydrogen, also,

In space between the outer container and each inner pressurd vessel, to press to 0.2MPa or more and 0.8MPa or less at 30 DEG C Mode be filled with propellant,

The first content and second inner container are to be bonded the sheet material for the multi-ply construction that innermost layer has polyolefin resin layer respectively And formed, flexural rigidity E (s) points of the flexural rigidity E (f) of the sheet material of the first content and the sheet material of the second inner container It Wei not 0.15gfcm²/ cm or more and 3.0gfcm²/ cm hereinafter, ratio E (f)/E (s) of E (f) and E (s) be 0.3 or more and 5 hereinafter,

The ratio between this first dose viscosity V (f) at 30 DEG C and this second dose viscosity V (s) at 30 DEG C V (f)/V (s) are 0.5 Above and 1.5 hereinafter,

The ratio between first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container M (s)/M (f) for 0.8 less than 1.2.

2. aerosol type hair dyeing as described in claim 1 is used or hair decoloration applies some make up, wherein

The vistanex of the innermost layer of the first content and second inner container is polyvinyl resin.

3. aerosol type hair dyeing as claimed in claim 1 or 2 is used or hair decoloration applies some make up, wherein

Above-mentioned viscosity V (f) and above-mentioned viscosity V (s) are respectively 8,000mPas or more and 160,000mPas or less.

4. the aerosol type hair dyeing as described in any one of claims 1 to 3 is used or hair decoloration applies some make up, wherein

Further contain surfactant in first dose and/or second dose.

5. aerosol type hair dyeing as claimed in claim 4 is used or hair decoloration applies some make up, wherein

The content of surfactant in first dose of mixture with second dose is 0.1 mass % or more and 30 mass % or less.

6. the aerosol type hair dyeing as described in any one of Claims 1 to 5 is used or hair decoloration applies some make up, wherein

Further contain higher alcohol in first dose and/or second dose.

7. aerosol type hair dyeing as claimed in claim 6 is used or hair decoloration applies some make up, wherein

Higher alcohol is the compound represented by the following general formula (1),

R-OH(1)

8. aerosol type hair dyeing as claimed in claims 6 or 7 is used or hair decoloration applies some make up, wherein

The content of higher alcohol in first dose of mixture with second dose is 3 mass % or more and 12 mass % or less.

9. the aerosol type hair dyeing as described in any one of claim 1~8 is used or hair decoloration applies some make up, wherein

E (f) and E (s) is 0.6gfcm²/ cm or more and 2.0gfcm²/ cm or less.

10. the aerosol type hair dyeing as described in any one of claim 1~9 is used or hair decoloration applies some make up, wherein

E (f)/E (s) is 0.5 or more and 3 or less.

11. the aerosol type hair dyeing as described in any one of claim 1~10 is used or hair decoloration applies some make up, wherein

V (f)/V (s) is 0.6 or more and 1.4 or less.

12. the aerosol type hair dyeing as described in any one of claim 1~11 is used or hair decoloration applies some make up, wherein

Further contain hydrocarbon in first dose, any one of second dose or both.

13. aerosol type hair dyeing as claimed in claim 12 is used or hair decoloration applies some make up, wherein

The content of hydrocarbon in first dose of mixture with second dose is 1 mass % or more and 20 mass % or less.

14. the aerosol type hair dyeing as described in any one of claim 1~13 is used or hair decoloration applies some make up, wherein

Further contain ester oil in first dose, any one of second dose or both.

15. aerosol type hair dyeing as claimed in claim 14 is used or hair decoloration applies some make up, wherein

The content of ester oil in first dose of mixture with second dose is 0.01 mass % or more and 5 mass % or less.

16. the aerosol type hair dyeing as described in any one of claim 1~15 is used or hair decoloration applies some make up, wherein

The content of alkaline agent in first dose is 0.1 mass % or more and 14 mass % or less.

17. the aerosol type hair dyeing as described in any one of claim 1~16 is used or hair decoloration applies some make up, wherein

The content of hydrogen peroxide in second dose is 1 mass % or more and 9 mass % or less.