CN108374223A - Renewable temperature sensitive textile fabric of one kind and preparation method thereof - Google Patents
Renewable temperature sensitive textile fabric of one kind and preparation method thereof Download PDFInfo
- Publication number
- CN108374223A CN108374223A CN201810209601.1A CN201810209601A CN108374223A CN 108374223 A CN108374223 A CN 108374223A CN 201810209601 A CN201810209601 A CN 201810209601A CN 108374223 A CN108374223 A CN 108374223A
- Authority
- CN
- China
- Prior art keywords
- temperature sensitive
- renewable
- textile fabric
- fiber
- dispersant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000004744 fabric Substances 0.000 title claims abstract description 36
- 239000004753 textile Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000835 fiber Substances 0.000 claims abstract description 57
- 239000002270 dispersing agent Substances 0.000 claims abstract description 32
- 239000000725 suspension Substances 0.000 claims abstract description 23
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims abstract description 22
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 18
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 18
- 241001330002 Bambuseae Species 0.000 claims abstract description 18
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 18
- 239000011425 bamboo Substances 0.000 claims abstract description 18
- 239000007822 coupling agent Substances 0.000 claims abstract description 18
- 229920000742 Cotton Polymers 0.000 claims abstract description 13
- 230000003115 biocidal effect Effects 0.000 claims abstract description 13
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 13
- 239000002121 nanofiber Substances 0.000 claims abstract description 13
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 12
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 11
- 229920002101 Chitin Polymers 0.000 claims abstract description 11
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 11
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 11
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 11
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000008777 kaempferol Nutrition 0.000 claims abstract description 11
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000473 propyl gallate Substances 0.000 claims abstract description 11
- 229940075579 propyl gallate Drugs 0.000 claims abstract description 11
- 235000010388 propyl gallate Nutrition 0.000 claims abstract description 11
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 239000012790 adhesive layer Substances 0.000 claims abstract description 6
- 238000009987 spinning Methods 0.000 claims description 43
- 238000001035 drying Methods 0.000 claims description 19
- 238000004321 preservation Methods 0.000 claims description 15
- 239000000376 reactant Substances 0.000 claims description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 238000004132 cross linking Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 9
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 229920001732 Lignosulfonate Polymers 0.000 claims description 5
- 239000008346 aqueous phase Substances 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 239000003610 charcoal Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000005345 coagulation Methods 0.000 claims description 5
- 230000015271 coagulation Effects 0.000 claims description 5
- 230000005684 electric field Effects 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- BHTJEPVNHUUIPV-UHFFFAOYSA-N pentanedial;hydrate Chemical compound O.O=CCCCC=O BHTJEPVNHUUIPV-UHFFFAOYSA-N 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 5
- -1 (aminoethyl) 3- aminopropyl Chemical group 0.000 claims description 4
- 238000007872 degassing Methods 0.000 claims description 4
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- 235000012241 calcium silicate Nutrition 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 3
- 229960003656 ricinoleic acid Drugs 0.000 claims description 3
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 3
- KGOWZJIRYKHZFE-UHFFFAOYSA-N NCCC(C(OCC)(OCC)OCC)O[Si](OCC)(OCC)CCCN Chemical class NCCC(C(OCC)(OCC)OCC)O[Si](OCC)(OCC)CCCN KGOWZJIRYKHZFE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims 2
- 235000021314 Palmitic acid Nutrition 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000000265 homogenisation Methods 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 abstract description 5
- 230000004927 fusion Effects 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 16
- 239000006185 dispersion Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 8
- 230000007246 mechanism Effects 0.000 description 8
- 230000006641 stabilisation Effects 0.000 description 8
- 238000011105 stabilization Methods 0.000 description 8
- 230000004913 activation Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000007667 floating Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 150000004702 methyl esters Chemical class 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000000518 rheometry Methods 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229940012185 zinc palmitate Drugs 0.000 description 2
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 2
- OEHPGDCQKGYZQG-UHFFFAOYSA-N NCC[Si](OC(OCC)(OCC)OCC)(OC)CCCN Chemical class NCC[Si](OC(OCC)(OCC)OCC)(OC)CCCN OEHPGDCQKGYZQG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/10—Bamboo
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of renewable temperature sensitive textile fabrics and preparation method thereof, and the fabric is made of warp and weft, and warp or weft include bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, temperature sensitive antibiotic property nanofiber, acid fiber by polylactic；The warp or weft form temperature sensitive adhesive layer after temperature sensitive mixed liquor impregnates and is dried, and the temperature sensitive mixed liquor includes chitin, acrylic fiber, propylgallate, ammonium polyphosphate, Kaempferol, methyl acrylate, coupling agent, dispersant, heat stabilizer and antistatic suspension.The present invention can realize the fusion of renewable fabric by bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, the mixing of temperature sensitive antibiotic property nanofiber, cooperation coupling agent, dispersant and heat stabilizer etc., meanwhile, also realize the function of fire-retardant and temperature sensitive adjusting.Moreover, by antistatic suspension, the antistatic effect of fabric can be realized.Reasonable design of the present invention is suitble to promote the use of.
Description
Technical field
The present invention relates to Garment Technology fields, and in particular to the renewable temperature sensitive textile fabric of one kind and its preparation side
Method.
Background technology
In existing fabric, most of is all to use chemical industry fabric, not only pollutes environment, but also have wound to human body
Evil, there is also non-renewable problems；So renewable fabric occurs therewith, but since these classes regenerate fabric, fire-retardant effect
Fruit is poor, will not be adjusted according to environment temperature, and this reduces the practicabilities of renewable fabric.
Invention content
The present invention is above-mentioned in order to overcome the shortcomings of, provides a kind of renewable, antistatic, fire-retardant and can be according to environment temperature
Adjustable renewable temperature sensitive textile fabric and preparation method thereof.
The present invention is achieved through the following technical solutions above-mentioned purpose：
A kind of renewable temperature sensitive textile fabric, it is characterised in that：The fabric is made of warp and weft, warp or latitude
Line includes bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, temperature sensitive antibiotic property nanofiber, acid fiber by polylactic；The warp or
Weft forms temperature sensitive adhesive layer after temperature sensitive mixed liquor impregnates and is dried, and the temperature sensitive mixed liquor includes chitin, nitrile
Synthetic fibre fiber, propylgallate, ammonium polyphosphate, Kaempferol, methyl acrylate, coupling agent, dispersant, heat stabilizer and anti-quiet
Electrically floating liquid.
Preferably, the coupling agent is selected from 3 acrylic acid base propyl trimethoxy silicane, N-2 (aminoethyl) 3- aminopropyl first
Base dimethoxysilane, N-2 (aminoethyl) 3- aminopropyltriethoxies trimethoxy silane, N-2 (aminoethyl) 3- aminopropyltriethoxies three
One or more of Ethoxysilane.
Preferably, the dispersant includes polyacrylamide and lignosulfonates, mass ratio 1-2:0.5-1.
Preferably, the one kind of the heat stabilizer in zinc palmitate, moon calcium silicates, barium naphthanate and ricinoleic acid cadmium
Or it is several.
Preferably, it is 18- that the antistatic suspension adds the dispersant of 0.5-2wt% to be made into mass fraction by AZO powders
23% AZO suspension liquid of aqueous phase, ball milling 3-5h are made；
AZO particle diameter distributions are concentrated mainly on 160-180nm in antistatic suspension, and dispersant can be with nanometer AZO particle tables
The hydroxy combining in face when being attracted to polymer particle surface, increases intergranular repulsion, can effectively play stable dispersion
Effect, dissociating the small ion come makes the ionic strength of decentralized medium change, and changes the thickness of electric double layer, enhances electric double layer
Stability, there is spatial stability mechanism and electrostatic stabilization mechanism, system has better dispersion stabilization.
Preferably, the fire resistance fibre includes bamboo charcoal fiber and glass fibre.
A kind of preparation method of renewable temperature sensitive textile fabric, includes the following steps：
(1) renewable fiber is made：Bamboo fibre, wood-fibred and cotton fiber are mixed, is soaked in 3% hydrogen peroxide and sterilizes
Activation, after impregnating 2-3h, in 65-70 DEG C of drying, Ultrasonic Pulverization 30min, ultrasonic power 200-250kW；
(2) by acid fiber by polylactic, chitin, acrylic fiber, propylgallate, ammonium polyphosphate, Kaempferol, acrylic acid
Reaction kettle is added in methyl esters, coupling agent, stirs and evenly mixs, and is heated to 230-280 DEG C, stirring heat preservation 30min, mixing speed 250-
300r/min；
(3) by the reactant of crushed material, step (2) in step (1) and fire resistance fibre, that dispersant sequentially adds high pressure is even
Matter machine, is mixed evenly, and is heated to 210 DEG C, is filled with vapor, and heat preservation stands 30min；
(4) mixture of step (3) is depressurized to consistent with external atmosphere pressure, is heated to 280 DEG C, continue to keep the temperature 15min；
(5) temperature sensitive antibiotic property nanofiber is attached directly under electric field force effect on the mixture of step (4), is heated to
210 DEG C, it is filled with vapor, heat preservation stands 30min；
(6) it by reactant spinning under closed environment in step (5), is handled by drawing；
(7) spinning solution is prepared：The antistatic suspension of 1-5wt%, 0.1-0.5wt% is added into polyacrylonitrile matrix
Modified polyorganosiloxane, and dispersant is added, 8-10h is stirred under the conditions of 800-1000r/min, 55-65 DEG C, then 55-65
Discontinuous degassing 45-50h under the conditions of DEG C, the nanometer AZO particles in spinning solution cannot have big reunion and be uniformly dispersed, and spinning solution is in
Existing shear thinning, is not much different with the rheology of polyacrylonitrile matrix, has good spinnability；
(8) spinning solution is used for the spinning process in step (6) through spinning head, after drawing-off, winding, spinning has anti-
Electrostatic capacity, total draft multiple is 8-10 times in spinning process, and coagulation bath temperature is 5-10 DEG C, and one to lead temperature be 55-65 DEG C, two
It is 90-100 DEG C to lead temperature；
(9) deaerate drying, is cooled to room temperature and gets product.
Preferably, in step (5), obtained reactant carries out glutaraldehyde steam crosslinking Treatment, glutaraldehyde water solution
Mass concentration be 25-55%, time of the glutaraldehyde steam crosslinking Treatment is 0.5-1h.
Preferably, in step (9), drying temperature is 70-75 DEG C, drying time 1-2h.
The beneficial effects of the invention are as follows：Compared with the existing technology, the present invention passes through bamboo fibre, wood-fibred, cotton fiber, fire-retardant
Fiber, the mixing of temperature sensitive antibiotic property nanofiber, cooperation coupling agent, dispersant and heat stabilizer etc., can realize renewable fabric
Fusion, meanwhile, also realize the function of fire-retardant and temperature sensitive adjusting；Moreover, by antistatic suspension, face can be realized
The antistatic effect of material.
Specific implementation mode
The present invention is described in further detail now.
Embodiment 1：
A kind of renewable temperature sensitive textile fabric, it is characterised in that：The fabric is made of warp and weft, warp or latitude
Line includes bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, temperature sensitive antibiotic property nanofiber, acid fiber by polylactic；The warp or
Weft forms temperature sensitive adhesive layer after temperature sensitive mixed liquor impregnates and is dried, and the temperature sensitive mixed liquor includes chitin, nitrile
Synthetic fibre fiber, propylgallate, ammonium polyphosphate, Kaempferol, methyl acrylate, coupling agent, dispersant, heat stabilizer and anti-quiet
Electrically floating liquid.
Preferably, the coupling agent is selected from 3 acrylic acid base propyl trimethoxy silicane.
Preferably, the dispersant includes polyacrylamide and lignosulfonates, mass ratio 1:0.5.
Preferably, the heat stabilizer is selected from zinc palmitate.
Preferably, it is 23% that the antistatic suspension adds the dispersant of 2wt% to be made into mass fraction by AZO powders
AZO suspension liquid of aqueous phase, ball milling 5h are made；
AZO particle diameter distributions are concentrated mainly on 160-180nm in antistatic suspension, and dispersant can be with nanometer AZO particle tables
The hydroxy combining in face when being attracted to polymer particle surface, increases intergranular repulsion, can effectively play stable dispersion
Effect, dissociating the small ion come makes the ionic strength of decentralized medium change, and changes the thickness of electric double layer, enhances electric double layer
Stability, there is spatial stability mechanism and electrostatic stabilization mechanism, system has better dispersion stabilization.
Preferably, the fire resistance fibre includes bamboo charcoal fiber and glass fibre.
A kind of preparation method of renewable temperature sensitive textile fabric, includes the following steps：
(1) renewable fiber is made：Bamboo fibre, wood-fibred and cotton fiber are mixed, is soaked in 3% hydrogen peroxide and sterilizes
Activation, after impregnating 3h, in 65-70 DEG C of drying, Ultrasonic Pulverization 30min, ultrasonic power 250kW；
(2) by acid fiber by polylactic, chitin, acrylic fiber, propylgallate, ammonium polyphosphate, Kaempferol, acrylic acid
Reaction kettle is added in methyl esters, coupling agent, stirs and evenly mixs, and is heated to 230-280 DEG C, stirring heat preservation 30min, mixing speed 300r/
min；
(3) by the reactant of crushed material, step (2) in step (1) and fire resistance fibre, that dispersant sequentially adds high pressure is even
Matter machine, is mixed evenly, and is heated to 210 DEG C, is filled with vapor, and heat preservation stands 30min；
(4) mixture of step (3) is depressurized to consistent with external atmosphere pressure, is heated to 280 DEG C, continue to keep the temperature 15min；
(5) temperature sensitive antibiotic property nanofiber is attached directly under electric field force effect on the mixture of step (4), is heated to
210 DEG C, it is filled with vapor, heat preservation stands 30min；
(6) it by reactant spinning under closed environment in step (5), is handled by drawing；
(7) spinning solution is prepared：The modification that the antistatic suspension, 0.5wt% of 5wt% are added into polyacrylonitrile matrix is poly-
Siloxanes, and dispersant is added, 8-10h is stirred under the conditions of 1000r/min, 65 DEG C, then static de- under the conditions of 55-65 DEG C
45-50h is steeped, the nanometer AZO particles in spinning solution there cannot be big reunion and be uniformly dispersed, and it is existing that shear thinning is presented in spinning solution
As being not much different with the rheology of polyacrylonitrile matrix, there is good spinnability；
(8) spinning solution is used for the spinning process in step (6) through spinning head, after drawing-off, winding, spinning has anti-
Electrostatic capacity, total draft multiple is 10 times in spinning process, and coagulation bath temperature is 5-10 DEG C, and one to lead temperature be 55-65 DEG C, and two lead
Temperature is 90-100 DEG C；
(9) deaerate drying, is cooled to room temperature and gets product.
Preferably, in step (5), obtained reactant carries out glutaraldehyde steam crosslinking Treatment, glutaraldehyde water solution
Mass concentration be 25-55%, time of the glutaraldehyde steam crosslinking Treatment is 0.5-1h.
Preferably, in step (9), drying temperature is 70-75 DEG C, drying time 2h.
Embodiment 2：
A kind of renewable temperature sensitive textile fabric, it is characterised in that：The fabric is made of warp and weft, warp or latitude
Line includes bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, temperature sensitive antibiotic property nanofiber, acid fiber by polylactic；The warp or
Weft forms temperature sensitive adhesive layer after temperature sensitive mixed liquor impregnates and is dried, and the temperature sensitive mixed liquor includes chitin, nitrile
Synthetic fibre fiber, propylgallate, ammonium polyphosphate, Kaempferol, methyl acrylate, coupling agent, dispersant, heat stabilizer and anti-quiet
Electrically floating liquid.
Preferably, the coupling agent is selected from N-2 (aminoethyl) 3- aminopropyltriethoxy triethoxysilanes.
Preferably, the dispersant includes polyacrylamide and lignosulfonates, mass ratio 1:0.5.
Preferably, the heat stabilizer is selected from ricinoleic acid cadmium.
Preferably, it is 18% that the antistatic suspension adds the dispersant of 2wt% to be made into mass fraction by AZO powders
AZO suspension liquid of aqueous phase, ball milling 5h are made；
AZO particle diameter distributions are concentrated mainly on 160-180nm in antistatic suspension, and dispersant can be with nanometer AZO particle tables
The hydroxy combining in face when being attracted to polymer particle surface, increases intergranular repulsion, can effectively play stable dispersion
Effect, dissociating the small ion come makes the ionic strength of decentralized medium change, and changes the thickness of electric double layer, enhances electric double layer
Stability, there is spatial stability mechanism and electrostatic stabilization mechanism, system has better dispersion stabilization.
Preferably, the fire resistance fibre includes bamboo charcoal fiber and glass fibre.
A kind of preparation method of renewable temperature sensitive textile fabric, includes the following steps：
(1) renewable fiber is made：Bamboo fibre, wood-fibred and cotton fiber are mixed, is soaked in 3% hydrogen peroxide and sterilizes
Activation, after impregnating 2h, in 65-70 DEG C of drying, Ultrasonic Pulverization 30min, ultrasonic power 200-250kW；
(2) by acid fiber by polylactic, chitin, acrylic fiber, propylgallate, ammonium polyphosphate, Kaempferol, acrylic acid
Reaction kettle is added in methyl esters, coupling agent, stirs and evenly mixs, and is heated to 230 DEG C, stirring heat preservation 30min, mixing speed 250r/min；
(3) by the reactant of crushed material, step (2) in step (1) and fire resistance fibre, that dispersant sequentially adds high pressure is even
Matter machine, is mixed evenly, and is heated to 210 DEG C, is filled with vapor, and heat preservation stands 30min；
(4) mixture of step (3) is depressurized to consistent with external atmosphere pressure, is heated to 280 DEG C, continue to keep the temperature 15min；
(5) temperature sensitive antibiotic property nanofiber is attached directly under electric field force effect on the mixture of step (4), is heated to
210 DEG C, it is filled with vapor, heat preservation stands 30min；
(6) it by reactant spinning under closed environment in step (5), is handled by drawing；
(7) spinning solution is prepared：The antistatic suspension of 1-5wt%, 0.1-0.5wt% is added into polyacrylonitrile matrix
Modified polyorganosiloxane, and dispersant is added, 8-10h is stirred under the conditions of 800-1000r/min, 55-65 DEG C, then 55-65
Discontinuous degassing 45-50h under the conditions of DEG C, the nanometer AZO particles in spinning solution cannot have big reunion and be uniformly dispersed, and spinning solution is in
Existing shear thinning, is not much different with the rheology of polyacrylonitrile matrix, has good spinnability；
(8) spinning solution is used for the spinning process in step (6) through spinning head, after drawing-off, winding, spinning has anti-
Electrostatic capacity, total draft multiple is 8-10 times in spinning process, and coagulation bath temperature is 5-10 DEG C, and one to lead temperature be 55-65 DEG C, two
It is 90-100 DEG C to lead temperature；
(9) deaerate drying, is cooled to room temperature and gets product.
Preferably, in step (5), obtained reactant carries out glutaraldehyde steam crosslinking Treatment, glutaraldehyde water solution
Mass concentration be 25-55%, time of the glutaraldehyde steam crosslinking Treatment is 0.5-1h.
Preferably, in step (9), drying temperature is 70-75 DEG C, drying time 1.5h.
Embodiment 3：
A kind of renewable temperature sensitive textile fabric, it is characterised in that：The fabric is made of warp and weft, warp or latitude
Line includes bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, temperature sensitive antibiotic property nanofiber, acid fiber by polylactic；The warp or
Weft forms temperature sensitive adhesive layer after temperature sensitive mixed liquor impregnates and is dried, and the temperature sensitive mixed liquor includes chitin, nitrile
Synthetic fibre fiber, propylgallate, ammonium polyphosphate, Kaempferol, methyl acrylate, coupling agent, dispersant, heat stabilizer and anti-quiet
Electrically floating liquid.
Preferably, the coupling agent is selected from N-2 (aminoethyl) 3- aminopropyltriethoxy dimethoxysilanes.
Preferably, the dispersant includes polyacrylamide and lignosulfonates, mass ratio 1:0.5.
Preferably, the heat stabilizer is selected from moon calcium silicates.
Preferably, it is 23% that the antistatic suspension adds the dispersant of 0.5-2wt% to be made into mass fraction by AZO powders
AZO suspension liquid of aqueous phase, ball milling 5h is made；
AZO particle diameter distributions are concentrated mainly on 160-180nm in antistatic suspension, and dispersant can be with nanometer AZO particle tables
The hydroxy combining in face when being attracted to polymer particle surface, increases intergranular repulsion, can effectively play stable dispersion
Effect, dissociating the small ion come makes the ionic strength of decentralized medium change, and changes the thickness of electric double layer, enhances electric double layer
Stability, there is spatial stability mechanism and electrostatic stabilization mechanism, system has better dispersion stabilization.
Preferably, the fire resistance fibre includes bamboo charcoal fiber and glass fibre.
A kind of preparation method of renewable temperature sensitive textile fabric, includes the following steps：
(1) renewable fiber is made：Bamboo fibre, wood-fibred and cotton fiber are mixed, is soaked in 3% hydrogen peroxide and sterilizes
Activation, after impregnating 2.5h, in 65-70 DEG C of drying, Ultrasonic Pulverization 30min, ultrasonic power 200-250kW；
(2) by acid fiber by polylactic, chitin, acrylic fiber, propylgallate, ammonium polyphosphate, Kaempferol, acrylic acid
Reaction kettle is added in methyl esters, coupling agent, stirs and evenly mixs, and is heated to 230-280 DEG C, stirring heat preservation 30min, mixing speed 250-
300r/min；
(3) by the reactant of crushed material, step (2) in step (1) and fire resistance fibre, that dispersant sequentially adds high pressure is even
Matter machine, is mixed evenly, and is heated to 210 DEG C, is filled with vapor, and heat preservation stands 30min；
(4) mixture of step (3) is depressurized to consistent with external atmosphere pressure, is heated to 280 DEG C, continue to keep the temperature 15min；
(5) temperature sensitive antibiotic property nanofiber is attached directly under electric field force effect on the mixture of step (4), is heated to
210 DEG C, it is filled with vapor, heat preservation stands 30min；
(6) it by reactant spinning under closed environment in step (5), is handled by drawing；
(7) spinning solution is prepared：The antistatic suspension of 1-5wt%, 0.1-0.5wt% is added into polyacrylonitrile matrix
Modified polyorganosiloxane, and dispersant is added, 8-10h is stirred under the conditions of 800-1000r/min, 55-65 DEG C, then 55-65
Discontinuous degassing 45-50h under the conditions of DEG C, the nanometer AZO particles in spinning solution cannot have big reunion and be uniformly dispersed, and spinning solution is in
Existing shear thinning, is not much different with the rheology of polyacrylonitrile matrix, has good spinnability；
(8) spinning solution is used for the spinning process in step (6) through spinning head, after drawing-off, winding, spinning has anti-
Electrostatic capacity, total draft multiple is 8-10 times in spinning process, and coagulation bath temperature is 5-10 DEG C, and one to lead temperature be 55-65 DEG C, two
It is 90-100 DEG C to lead temperature；
(9) deaerate drying, is cooled to room temperature and gets product.
Preferably, in step (5), obtained reactant carries out glutaraldehyde steam crosslinking Treatment, glutaraldehyde water solution
Mass concentration be 25-55%, time of the glutaraldehyde steam crosslinking Treatment is 0.5-1h.
Preferably, in step (9), drying temperature is 70-75 DEG C, drying time 1-2h.
It is above-mentioned according to the present invention be enlightenment, through the above description, relevant staff completely can without departing from
In the range of this invention technological thought, various changes and amendments are carried out.The technical scope of this invention is not limited to
In the content on specification, it is necessary to determine its technical scope according to right.
Claims (9)
1. a kind of renewable temperature sensitive textile fabric, it is characterised in that：The fabric is made of warp and weft, warp or weft
Including bamboo fibre, wood-fibred, cotton fiber, fire resistance fibre, temperature sensitive antibiotic property nanofiber, acid fiber by polylactic；The warp or latitude
Line forms temperature sensitive adhesive layer after temperature sensitive mixed liquor impregnates and is dried, and the temperature sensitive mixed liquor includes chitin, acrylic fibers
Fiber, propylgallate, ammonium polyphosphate, Kaempferol, methyl acrylate, coupling agent, dispersant, heat stabilizer and antistatic
Suspension.
2. renewable temperature sensitive textile fabric according to claim 1, it is characterised in that：The coupling agent is selected from 3 acrylic acid
Base propyl trimethoxy silicane, N-2 (aminoethyl) 3- aminopropyltriethoxies dimethoxysilane, N-2 (aminoethyl) 3- aminopropyl first
One or more of base trimethoxy silane, N-2 (aminoethyl) 3- aminopropyltriethoxy triethoxysilanes.
3. renewable temperature sensitive textile fabric according to claim 1, it is characterised in that：The dispersant includes polyacrylamide
Amine and lignosulfonates, mass ratio 1-2:0.5-1.
4. renewable temperature sensitive textile fabric according to claim 1, it is characterised in that：The heat stabilizer is selected from palmitic acid
One or more of zinc, moon calcium silicates, barium naphthanate and ricinoleic acid cadmium.
5. renewable temperature sensitive textile fabric according to claim 1, it is characterised in that：The antistatic suspension is by AZO
Powder adds the dispersant of 0.5-2wt% to be made into the AZO suspension liquid of aqueous phase that mass fraction is 18-23%, and ball milling 3-5h is made.
6. renewable temperature sensitive textile fabric according to claim 1, it is characterised in that：The fire resistance fibre includes bamboo charcoal fibre
Peacekeeping glass fibre.
7. a kind of preparation method according to the renewable temperature sensitive textile fabric of claim 1-6 any one of them, it is characterised in that：
Include the following steps：
(1) renewable fiber is made：Bamboo fibre, wood-fibred and cotton fiber are mixed, is soaked in sterilize in 3% hydrogen peroxide and live
Change, after impregnating 2-3h, in 65-70 DEG C of drying, Ultrasonic Pulverization 30min, ultrasonic power 200-250kW；
(2) by acid fiber by polylactic, chitin, acrylic fiber, propylgallate, ammonium polyphosphate, Kaempferol, acrylic acid first
Reaction kettle is added in ester, coupling agent, stirs and evenly mixs, and is heated to 230-280 DEG C, stirring heat preservation 30min, mixing speed 250-300r/
min；
(3) reactant of crushed material, step (2) in step (1) and fire resistance fibre, dispersant are sequentially added into high pressure homogenization
Machine is mixed evenly, and is heated to 210 DEG C, is filled with vapor, and heat preservation stands 30min；
(4) mixture of step (3) is depressurized to consistent with external atmosphere pressure, is heated to 280 DEG C, continue to keep the temperature 15min；
(5) temperature sensitive antibiotic property nanofiber is attached directly under electric field force effect on the mixture of step (4), is heated to 210
DEG C, it is filled with vapor, heat preservation stands 30min；
(6) it by reactant spinning under closed environment in step (5), is handled by drawing；
(7) spinning solution is prepared：The modification of the antistatic suspension, 0.1-0.5wt% of 1-5wt% is added into polyacrylonitrile matrix
Polysiloxanes, and dispersant is added, 8-10h is stirred under the conditions of 800-1000r/min, 55-65 DEG C, then 55-65 DEG C of item
Discontinuous degassing 45-50h under part；
(8) spinning solution is used for the spinning process in step (6) through spinning head, after drawing-off, winding, spinning has antistatic
Ability, total draft multiple is 8-10 times in spinning process, and coagulation bath temperature is 5-10 DEG C, and one to lead temperature be 55-65 DEG C, and two lead temperature
Degree is 90-100 DEG C；
(9) deaerate drying, is cooled to room temperature and gets product.
8. the preparation method of renewable temperature sensitive textile fabric according to claim 7, it is characterised in that：In step (5),
Obtained reactant carries out glutaraldehyde steam crosslinking Treatment, and the mass concentration of glutaraldehyde water solution is 25-55%, and described penta 2
The time of aldehyde steam crosslinking Treatment is 0.5-1h.
9. the preparation method of renewable temperature sensitive textile fabric according to claim 7, it is characterised in that：In step (9), dry
Dry temperature is 70-75 DEG C, drying time 1-2h.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109056157A (en) * | 2018-10-17 | 2018-12-21 | 南通薇星纺织科技有限公司 | Far infrared fabric |
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| CN104060346A (en) * | 2014-06-24 | 2014-09-24 | 宿迁恒达纺织有限公司 | Hollow fiber for temperature response type curtain |
| CN104073916A (en) * | 2014-06-24 | 2014-10-01 | 宿迁恒达纺织有限公司 | Preparation method of temperature responsive fiber for window curtain |
| CN107022823A (en) * | 2017-03-24 | 2017-08-08 | 东华大学 | A kind of machine-knitted structure flexibility temperature sensor of integrated temperature sensitive fiber |
| CN107217327A (en) * | 2017-07-07 | 2017-09-29 | 苏州市晨彩纺织研发有限公司 | A kind of weaving face fabric added with azelon and preparation method thereof |
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2018
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104060346A (en) * | 2014-06-24 | 2014-09-24 | 宿迁恒达纺织有限公司 | Hollow fiber for temperature response type curtain |
| CN104073916A (en) * | 2014-06-24 | 2014-10-01 | 宿迁恒达纺织有限公司 | Preparation method of temperature responsive fiber for window curtain |
| CN107022823A (en) * | 2017-03-24 | 2017-08-08 | 东华大学 | A kind of machine-knitted structure flexibility temperature sensor of integrated temperature sensitive fiber |
| CN107217327A (en) * | 2017-07-07 | 2017-09-29 | 苏州市晨彩纺织研发有限公司 | A kind of weaving face fabric added with azelon and preparation method thereof |
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| CN109056157A (en) * | 2018-10-17 | 2018-12-21 | 南通薇星纺织科技有限公司 | Far infrared fabric |
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