CN108359285A - High-performance green waterproof rubber cement and preparation method thereof - Google Patents
High-performance green waterproof rubber cement and preparation method thereof Download PDFInfo
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- CN108359285A CN108359285A CN201810162333.2A CN201810162333A CN108359285A CN 108359285 A CN108359285 A CN 108359285A CN 201810162333 A CN201810162333 A CN 201810162333A CN 108359285 A CN108359285 A CN 108359285A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/06—Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
- C04B40/0641—Mechanical separation of ingredients, e.g. accelerator in breakable microcapsules
- C04B40/065—Two or more component mortars
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Analytical Chemistry (AREA)
- Structural Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to building material fields, and in particular to arrives a kind of High-performance green waterproofing slurry and preparation method thereof.A kind of High-performance green waterproofing slurry is grouped as by two kinds of groups of waterproof powder and water-proof emulsion, and wherein the weight proportion of waterproof powder and water-proof emulsion is 0.8~1.3：1；The wherein waterproof powder includes at least following components in parts by weight：70~100 parts of cement, 5~20 parts of nano-particle, 0.1~0.5 part of water-reducing agent；The wherein water-proof emulsion includes at least following components in parts by weight：30~70 parts of polymer emulsion, 5~20 parts of polychloroprene latex, 1~10 part of water；The polymer emulsion is acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
Description
Technical field
The present invention relates to building material fields, and in particular to arrives a kind of High-performance green waterproofing slurry and its preparation side
Method.
Background technology
Architectural waterproof material refers to being applied to play moisture-proof, leakproof in building and structures, protects building and constructs
Object and its component are not lost a kind of construction material of destruction by water logging.Moisture-proof role refers to the salt prevented in underground water or ground
The corrosive substance that grades penetrates into the inside of building element.Leakproof effect refers to preventing rainwater, snow-broth from roof, metope or coagulation
The outside leakage of water etc. inside building element and in water storage structure is leaked between the seam of native component.
The development experience of architectural waterproof material rigidity water-proofing material pea gravel concreten, waterproof roll pitch class coiled material, height
Polymerized asphalt felt, synthesis macromolecule coiled material to waterproofing slurry three phases.Pea gravel concreten is simple in structure, cost warp
Ji, construction and easy to maintenance is but easy to crack and more sensitive to temperature change and malformation, construction technical requirement compared with
It is high.Waterproofing slurry has many advantages, such as easy construction, easy to operate, quality controllable compared with waterproof roll.Since it is applied for liquid
Work, so integral waterproofing effect is good, to needing the variously-shaped basal plane of waterproof that can form continuous integral waterproofing layer, these advantages
It is that waterproof roll is unable to reach.
It includes liquid material (polymer emulsion and additive), powder that polymer cement waterproof slurry, i.e. JS waterproofing slurries, which are a kind of,
The bi-component waterborne water-repellent paint for expecting (cement, inorganic filler and auxiliary agent), is the waterproof material of the Ministry of Construction of China's keypoint recommendation
One of, belong to the environmental type product that country advocates energetically., with its high tensile flexible, cohesive force is strong for it, freeze thawing resistance, and high temperature resistant is resistance to
Corrosion, cold construction, can wet construction, construction is simple is nontoxic, the specialities such as environmentally protective and obtained rapid development, become
One of the hot spot of water-repellent paint development in recent years.But presently, there are polymer cement waterproof slurry there is also water resistances
Difference, and the problems such as long-time stability are bad.
Invention content
In order to solve the above-mentioned technical problem, the first aspect of the invention provides a kind of High-performance green waterproofing slurry,
It is grouped as by two kinds of groups of waterproof powder and water-proof emulsion, wherein the weight proportion of waterproof powder and water-proof emulsion is 0.8~1.3：
1；The wherein waterproof powder includes at least following components in parts by weight：70~100 parts of cement, nano-particle 5~20
Part, 0.1~0.5 part of water-reducing agent；The wherein water-proof emulsion includes at least following components in parts by weight：Polymer emulsion
30~70 parts, 5~20 parts of polychloroprene latex, 1~10 part of water；The polymer emulsion is acrylic acid ester emulsion；The neoprene
Latex is organic imvite modified polychloroprene latex.
As a kind of preferred technical solution of the present invention, the cement is selected from portland cement, aluminate cement, sulphur aluminium
Acid salt cement, ferrous aluminate cement, fluoroaluminate cement, ferrophosphorus acid salt cement any one or more of.
As a kind of preferred technical solution of the present invention, the nano-particle is selected from nano silicon dioxide, nano-silica
Change titanium, nano-aluminium oxide, nano zirconium dioxide, nano zine oxide, nano mica powder, nano-calcium carbonate, nano-silicon magnesia
Any one or more of.
As a kind of preferred technical solution of the present invention, it is high that the water-reducing agent is selected from naphthalene series high-efficiency water-reducing agent, aliphatic
Imitate any one of water-reducing agent, aminosulfonate-based superplasticizer, high performance water reducing agent of polyocarboxy acid.
As a kind of preferred technical solution of the present invention, the acrylic acid ester emulsion is pure-acrylic emulsion, described pure third
Lotion by acrylic acid, ethyl acrylate, butyl acrylate, methacrylic acid, methyl methacrylate, ethyl methacrylate,
The polymer emulsion that any one or more polymerization in butyl methacrylate obtains.
As a kind of preferred technical solution of the present invention, organo montmorillonite in the organic imvite modified polychloroprene latex
Content be 5~25wt%.
Further include helping for 0.1~3 parts by weight in the water-proof emulsion as a kind of preferred technical solution of the present invention
Agent, the auxiliary agent be Antisepticize and mildew preventive, wetting dispersing agent, antifoaming agent, plasticizer, thixotropic agent, any one of thickener or
A variety of mixing.
The second part of the present invention provides the preparation method of the High-performance green waterproofing slurry, the preparation
Method at least includes the following steps：
A. the preparation of waterproof powder：By weight, each component of the waterproof powder is weighed, successively by cement, nanometer
10~20min is stirred in particle, water-reducing agent input dispersator, obtains waterproof powder；
B. the preparation of water-proof emulsion：By weight, each component for weighing the water-proof emulsion, first by polymer emulsion
It is added in reactor, is slowly added to polychloroprene latex while stirring, continue 5~10min of stirring after the completion of being added, it is then added
His component, continues 10~15min of stirring, obtains water-proof emulsion.
The third part of the present invention provides the application method of the High-performance green waterproofing slurry, in construction,
By waterproof powder and water-proof emulsion by weight ratio 0.8~1.3：1 mixing, and stirring 5~30min makes it uniformly mix, you can
Knife-coat application.
The 4th part of the present invention provides High-performance green waterproofing slurry the answering in construction waterproofing engineering
With.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to following detailed description.
The water-proof emulsion in High-performance green waterproofing slurry in the present invention has excellent stability, high property of the invention
Adhesive property between waterproof slurry and base material is good, and film tensile strength is big, and uvioresistant stability is good, and also has preferable
Impermeability and water resistance.
Specific implementation mode
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with fields of the present invention
The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements
Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or
Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this
Phrase will make claim be closed, so that it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body,
It is only limited to the element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this, which should be understood as, specifically discloses by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise range intention includes its end
Value and all integers and score in the range.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " arbitrary
It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to indicate that the present invention is not limited to this
Quantity further includes the modified part of the acceptable change without lead to related basic function close to the quantity.Phase
It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, range limits can be with
Combination and/or exchange, these ranges include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component
(i.e. occurrence number) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number
The element or component of form also include plural form, unless the apparent purport of the quantity refers to singulative.
" polymer " means the polymerizable compound prepared by the monomer by the identical or different type of polymerization.Generic term
" polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " copolymer ".
" copolymer " means the polymer prepared by polymerizeing at least two different monomers.Generic term " copolymer " includes
(it is general with term " terpolymer " for term " copolymer " (its generally to refer to the polymer prepared by two kinds of different monomers)
To refer to the polymer prepared by three kinds of different monomers).It also includes the polymerization manufactured by polymerization four or more monomer
Object." blend " means the polymerization that two or more polymer is formed by mixing jointly by physics or chemical method
Object.
In order to solve the above-mentioned technical problem, the first aspect of the invention provides a kind of High-performance green waterproofing slurry,
It is grouped as by two kinds of groups of waterproof powder and water-proof emulsion, wherein the weight proportion of waterproof powder and water-proof emulsion is 0.8~1.3：
1；The wherein waterproof powder includes at least following components in parts by weight：70~100 parts of cement, nano-particle 5~20
Part, 0.1~0.5 part of water-reducing agent；The wherein water-proof emulsion includes at least following components in parts by weight：Polymer emulsion
30~70 parts, 5~20 parts of polychloroprene latex, 1~10 part of water；The polymer emulsion is acrylic acid ester emulsion；The neoprene
Latex is organic imvite modified polychloroprene latex.
As a kind of preferred technical solution of the present invention, the High-performance green waterproofing slurry by waterproof powder and is prevented
Two kinds of groups of aqueous emulsion are grouped as, and wherein the weight proportion of waterproof powder and water-proof emulsion is 0.8~1.3：1；Wherein described is anti-
Pigment body includes at least following components in parts by weight：85 parts of cement, 18 parts of nano-particle, 0.3 part of water-reducing agent；It is wherein described
Water-proof emulsion, in parts by weight, include at least following components：65 parts of polymer emulsion, 17 parts of polychloroprene latex, 7 parts of water；It is described
Polymer emulsion be acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
Cement
Cement be it is a kind of mix and stir into water plasticity slurry and can the suitable materials such as agglutination sand, stone, in air, wet environment
In and water in harden, and keep increase intensity powdery hydraulic cementing materials.Cement occupies important in cementitious material
Status is widely used in the engineerings such as civil construction, water conservancy, national defence.The various types of cement, by its main mineral hydraulic name
Title can be divided into silicate cement, aluminate-series cement, aluminium sulfate series cement, ferrous aluminate cement, fluoroaluminate cement, phosphorus
Acid salt cement and using volcanic ash or latent hydraulicity material and other active materials as multiple series such as the cement of key component
Kind.
Cement is not only simply to dose relationship in polymer emulsion, it can send out with the moisture in polymer emulsion
Raw hydration reaction, obtained hydrated product form stable system with polymer emulsion, and the forming process of this system is substantially such as
Under：
A. when polymer emulsion is with cement mixing, cement is uniformly dispersed in polymer emulsion (with acrylate breast
For liquid), occur hydration reaction immediately, the chemical equation of essential mineral is as follows in cement：
3CaO·SiO2(or 3CaOSiO2)+H2O→C-S-H+Ca(OH)2→Ca2++2OH-
B. in acrylic acid ester emulsion contain a large amount of ester group COO-, when with Ca (OH)2When contact, the Ca (OH) of dissolving2's
OH- promotes hydrolysis of ester group, and following chemical reaction occurs：
C. the carboxylic acid ion RCOO- generated after hydrolysis of ester group can be with Ca2+It is combined with ionic bond, in C-S-H gel surfaces
Or Ca (OH)2Plane of crystal reacts, and generates with Ca2+For bridge, the friendship formed with the macromolecular system that ionic bond is connected
The reticular structure knitted not only enhances the interface cohesion of polymer phase and cement phase, enhances the density of waterproof material.
In the hydration process of cement, Ca (OH)2Reach saturation in liquid phase within the extremely short time as hydrated product, third
Olefin(e) acid ester just with OH-, Ca2+React the macromolecular network pilotaxitic texture for generating and being combined with ionic bond, and with hydration age
Extension, degree of hydration is higher, and the amount of this reaction product is bigger.
Cement is a kind of material that expression activitiy is big, although there is 85% or more cement to be not engaged in molding coating
Aquation, functions only as filler, and 15% part of aquation plays key effect in being molded flexible material.Hydrated cementitious at salt
Especially aluminium salt generates crosslinked action with the active group in polymer emulsion, to change the shaping speed of water-repellent paint,
The performance of water resistance, weatherability, acidproof, alkaline-resisting, salt tolerant of polymer etc. is set to have great raising simultaneously.Cement itself
And the material that a kind of weatherability, water resistance are splendid, but its brittleness is big, density is bad, just utilizes flexible macromolecule water-fast
Property splendid material makes up the deficiency of cement.And both cement and polymer can mutually improve respective performance.With regard to cement
Kind for, in contrast, white cement be used as polymer cement waterproof paint can be better than Portland cement, mainly because
It is usually high alumina cement for white cement, general protosalt is more in Portland cement, and high-valency metal salt aluminium salt is the same as poly-
The crosslinked action closed between the active group in object can be stronger, more preferable to the modification of high molecular polymer.Certainly in polymer water
The content of cement determines that the dosage of cement must consider forming and hardening product nor The more the better in mud water-repellent paint
Tensile strength and fracture elongation.In addition, we are also contemplated that in polymer cement waterproof paint if cement uses to obtain mistake
It is more, can cracking be generated due to flexibility difference when being molded.
As a kind of preferred technical solution of the present invention, the cement is selected from portland cement, aluminate cement, sulphur aluminium
Acid salt cement, ferrous aluminate cement, fluoroaluminate cement, ferrophosphorus acid salt cement any one or more of.
As a kind of preferred technical solution of the present invention, the nano-particle is selected from nano silicon dioxide, nano-silica
Change titanium, nano-aluminium oxide, nano zirconium dioxide, nano zine oxide, nano mica powder, nano-calcium carbonate, nano-silicon magnesia
Any one or more of.
As a kind of preferred technical solution of the present invention, the nano-particle is Polystyrene nano-particle.
As a kind of preferred technical solution of the present invention, the preparation method of the Polystyrene nano-particle, until
Include the following steps less：
A. the reaction kettle with mechanical agitation and nitrogen protection is heated to 100 DEG C, the sky in reaction kettle is displaced with nitrogen
Gas keeps state to the reaction kettle for being passed through nitrogen to be cooled to room temperature, sequentially adds styrene, pentamethyl diethylenetriamine and bromine
Change cuprous, the mass ratio of styrene, five methyl diethylentriamine and cuprous bromide is 200：1：1, it stirs in the presence of nitrogen
30min forms stable light green complex compound.Initiator ethyl α bromoisobutyrate, ethyl α bromoisobutyrate and bromine are injected with syringe
It is 1 to change cuprous mass ratio：1,100 DEG C are warming up to, stops reaction after reacting 4h under stiring, is cooled to room temperature.Tetrahydrochysene is added
Furans dissolves, and column chromatography for separation removes catalyst, and then reaction solution is slowly added dropwise into absolute methanol, is stirred when being added dropwise
It mixes, is filtered to remove supernatant, 60 DEG C obtained of product, which is dried under vacuum to constant weight, obtains product a.
B. the reaction kettle with mechanical agitation and nitrogen protection is heated to 100 DEG C, the sky in reaction kettle is displaced with nitrogen
Gas keeps state to the reaction kettle for being passed through nitrogen to be cooled to room temperature, and the mass fraction for sequentially adding hydroxyethyl methacrylate is
35% cyclohexanone solution, five methyl diethylentriamine and cuprous bromide, hydroxyethyl methacrylate, pentamethyl diethylidene
The mass ratio of triamine and cuprous bromide is 140：1：1, stirring 30min forms stable light green complex compound.Then step a is added
Obtained product is synthesized, is warming up to 60 DEG C, stops reaction after continuing same nitrogen reaction 3h under stiring.Column chromatography removes catalysis
Then agent reaction solution is slowly added dropwise into n-hexane, stirred when being added dropwise, be filtered to remove supernatant, the product that will be obtained
40 DEG C are dried under vacuum to constant weight and obtain product b.
C. product b is dissolved in tetrahydrofuran, nano-particle, the product b, tetrahydrofuran, nano-particle is added
Mass ratio be 5：100：1, it seals, nano-particle is taken out after concussion 40min in earthquake shaking table, after natural drying, at 90 DEG C
It is dried in baking oven half an hour, a period of time is then heated in 120 DEG C of baking ovens, it is then molten with tetrahydrofuran in Soxhlet extractor
Liquid elutes 48h, dry, obtains Polystyrene nano-particle.
Styrene, CAS：100-42-5 is purchased from Shanghai Aladdin biochemical technology limited liability company.
Five methyl diethylentriamine, CAS：3030-47-5 is purchased from Tianjin Zhong Xinkaitai Chemical Co., Ltd.s.
Cuprous bromide, CAS：7787-70-4 is purchased from Shanghai Aladdin biochemical technology limited liability company.
Ethyl α bromoisobutyrate, CAS：600-00-0 is purchased from Shanghai Mike's woods biochemical technology Co., Ltd.
Tetrahydrofuran, CAS：109-99-9 is purchased from traditional Chinese medicines chemical reagent Co., Ltd.
Hydroxyethyl methacrylate, CAS：868-77-9 is purchased from Shanghai Aladdin biochemical technology limited liability company.
Cyclohexanone, CAS：108-94-1 is purchased from traditional Chinese medicines chemical reagent Co., Ltd.
Water-reducing agent
Water-reducing agent is a kind of under conditions of maintaining concrete slump to be basically unchanged, and can reduce the coagulation of mixing water amount
Native additive.Belong to anion surfactant mostly.There is peptizaiton to cement granules after concrete mix is added, can change
It is apt to its workability, reduces unit consumption of water, improve the mobility of concrete mix；Or unit cement consumption is reduced, save water
Mud.
As a kind of preferred technical solution of the present invention, it is high that the water-reducing agent is selected from naphthalene series high-efficiency water-reducing agent, aliphatic
Imitate any one of water-reducing agent, aminosulfonate-based superplasticizer, high performance water reducing agent of polyocarboxy acid.
Water-reducing agent used in the present invention is commercial product.
Polymer emulsion
The High-performance green waterproofing slurry of the present invention is a very important kind in building water-proof paint system, as
The polymer emulsion main Types of its primary raw material include：Vinyl acetate-ethylene copolymer emulsion (VAE lotions), pure acrylic acid
Ester lotion (pure-acrylic emulsion), interpolymer latex of polystyrene and acrylic ester (styrene-acrylic emulsion), butadiene-styrene latex, neoprene etc..Wherein most
The most commonly used is VAE lotions and acrylic acid ester emulsion (pure-acrylic emulsion, styrene-acrylic emulsion, silicone acrylic emulsion).
As a kind of preferred technical solution of the present invention, the acrylic acid ester emulsion is selected from pure-acrylic emulsion, styrene-acrylic emulsion
Or any one of silicone acrylic emulsion.
Acrylate is the general name of acrylic acid and its homologue esters, including acrylic acid, methyl acrylate, acrylic acid second
Ester, butyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate etc..Acrylate being capable of autohemagglutination
Or it is copolymerized with other monomers.Acrylate is the primary raw material for producing acrylic acid ester emulsion.Acrylic acid ester emulsion refers to acrylic acid
Esters monomer passes through lotion prepared by emulsion copolymerization method.
The aggregated reaction of double bond in acrylate monomer generates acrylate, its main chain is carbon carbon bond, is had
Very strong light, thermally and chemically stability, so the coating made from acrylate has good weatherability, anti-pollution
The performances such as property, acidproof, alkaline-resisting.Its application range is mainly water-repellent paint, exterior coating and interior wall top grade decorative paint.Acrylic acid
The performance of the performance ratio VAE lotions of ester lotion is far better, especially in use, then more can on new cement or lime metope
Embody its advantage.This is because to meet saponification generated calcium salt not soluble in water for the film of acrylic acid ester emulsion, and VAE lotions
The polyvinyl alcohol that saponification is generated is water-soluble, and water resistance is poor.A variety of different acrylate monomers can be not only total to
It is poly-, but also can be copolymerized with other monomers such as styrene, vinyl acetates, the former is known as pure-acrylic emulsion, and the latter is then known as phenylpropyl alcohol
Lotion and vinyl acetate emulsion.Pure-acrylic emulsion and styrene-acrylic emulsion are that China is most common currently used for prepared polymer cement waterproof paint
One of lotion.
As a kind of preferred technical solution of the present invention, the acrylic acid ester emulsion is pure-acrylic emulsion, described pure third
Lotion by acrylic acid, ethyl acrylate, butyl acrylate, methacrylic acid, methyl methacrylate, ethyl methacrylate,
The polymer emulsion that any one or more polymerization in butyl methacrylate obtains.
Polychloroprene latex
Polychloroprene latex is by 2- chloro-1,3-butadienes through rubber latex prepared by emulsion polymerization, referred to as CRL.Neoprene
Latex is since with excellent comprehensive performance, such as stronger bonding force, filming performance is preferable, and wet gel and dry glue film are with higher
Intensity, and have the performances such as oil resistant, solvent resistant, heat-resisting, resistance to ozone aging again, thus be widely used.But polychloroprene latex also has
Certain deficiencies, if cold resistance is poor, at room temperature be mobility liquid, be cooled to 10 DEG C once i.e. viscosity increases, close at 0 DEG C at cream
Shape, 0 DEG C or less latex freeze, and emulsifier is destroyed, solidified, reheating can not be restored to original state.Occur at present
Modified Polychloroprene latex, as chlorobutadiene with it is a small amount of it is styrene copolymerized made from cold resistance polychloroprene latex.The insulation of polychloroprene latex
Performance is slightly lower, and bin stability is also not good enough.Polychloroprene latex can improve the performance of resistance to aromatic solvent with acrylonitrile compolymer, with
Carboxylic chloroprene rubber latex can be made in acrylic compounds tool, have good caking property, elasticity and film forming.
As a kind of preferred technical solution of the present invention, organo montmorillonite in the organic imvite modified polychloroprene latex
Content be 5~25wt%.
As a kind of preferred technical solution of the present invention, the preparation method of the organic imvite modified polychloroprene latex,
It at least includes the following steps：
Organo montmorillonite deionized water dissolving is taken, the wherein mass ratio of organo montmorillonite and deionized water is 1：4, stirring
30min, then re-ultrasonic dispersion 15min, obtains corresponding suspension.It weighs the suspension and is added to cationic neoprene
In breast, first stirred 2 hours with high speed dispersor, then 20~60min of ultrasonic disperse, obtains organic imvite modified cation
Polychloroprene latex, the content of organo montmorillonite is 5~25wt% in the organic imvite modified cationic chloroprene latex.
The organo montmorillonite is purchased from NANOCOR companies of the U.S., and the trade mark isI.44PA。
The cationic chloroprene latex is purchased from Industrial Co., Ltd. in upper marial rocks, is that Chongqing long service life work Limited Liability is public
The trade mark that department produces is the cationic chloroprene latex of CRL-50LK.
Further include helping for 0.1~3 parts by weight in the water-proof emulsion as a kind of preferred technical solution of the present invention
Agent, the auxiliary agent are selected from any one of Antisepticize and mildew preventive, wetting dispersing agent, antifoaming agent, plasticizer, thixotropic agent, thickener
Or it is a variety of.
As a kind of preferred technical solution of the present invention, the Antisepticize and mildew preventive be selected from sodium benzoate, zinc pyrithione,
Penta sodium pentachlorophenate, zinc sulfate, sodium pyrithione, isothiazolinone, benzoisothiazolinone class, formaldehyde releaser, organic amine,
Send appointing in triazines, thiabendazole, carbendazim, o-phenyl phenol, Bravo, isothiazoline, dehydroacetic acid, salicylanilide
It is one or more.
As a kind of preferred technical solution of the present invention, the wetting dispersing agent is selected from wetting agent W-205, wetting agent
SILCO WET 065, wetting agent SN-WET992, AMP-95, DP518 any one or more of.
As a kind of preferred technical solution of the present invention, the antifoaming agent is organic silicon defoamer.
As a kind of preferred technical solution of the present invention, the plasticizer is selected from dibutyl phthalate, adjacent benzene two
Formic acid dioctyl ester, trimethylpentanediol diisobutyrate any one or more of.
As a kind of preferred technical solution of the present invention, the thixotropic agent be selected from aerosil, organobentonite,
Rilanit special, polyamide wax any one or more of.
As a kind of preferred technical solution of the present invention, the thickener is selected from vegetable oil, polyacrylamide, polyethylene
Alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, modified paraffin resin, carbomer, butadiene rubber, butadiene-styrene rubber, polyurethane,
Any one of modified polyurea, low-molecular polyethylene wax, ethoxyl methyl cellulose ether, hydroxypropyl methyl cellulose ether are more
Kind.
The second part of the present invention provides the preparation method of the High-performance green waterproofing slurry, the preparation
Method at least includes the following steps：
A. the preparation of waterproof powder：By weight, each component of the waterproof powder is weighed, successively by cement, nanometer
10~20min is stirred in particle, water-reducing agent input dispersator, obtains waterproof powder；
B. the preparation of water-proof emulsion：By weight, each component for weighing the water-proof emulsion, first by polymer emulsion
It is added in reactor, is slowly added to polychloroprene latex while stirring, continue 5~10min of stirring after the completion of being added, it is then added
His component, continues 10~15min of stirring, obtains water-proof emulsion.
The third part of the present invention provides the application method of the High-performance green waterproofing slurry, in construction,
By waterproof powder and water-proof emulsion by weight ratio 0.8~1.3：1 mixing, and stirring 15~60min makes it uniformly mix, you can
Knife-coat application.
The 4th part of the present invention provides High-performance green waterproofing slurry the answering in construction waterproofing engineering
With.
The water-proof emulsion in High-performance green waterproofing slurry in the present invention has excellent stability, high property of the invention
Adhesive property between waterproof slurry and base material is good, and film tensile strength is big, and uvioresistant stability is good, and also has preferable
Impermeability and water resistance.The present inventor guesses the possible reason is the waterproofing slurry of the present invention includes that organo montmorillonite changes
Property polychloroprene latex, the polychloroprene latex be cationic latex, acrylic acid ester emulsion be anionic lotion, organo montmorillonite
Distinctive ion exchangeable and the charge itself carried can be used as compatilizer, so that water-proof emulsion is had fabulous steady
It is qualitative.Polychloroprene latex itself has excellent water proofing property, but property is unstable, and neoprene is enhanced with the compounding of organo montmorillonite
The stability of latex, and the layer structure of organo montmorillonite further enhances the water proofing property of film.
Nano-particle itself exists as filler, but the difference of inorganic material and organic emulsion system property, makes film
There are larger internal stress for inside, influence the property of film.By the modification of polystyrene, nano-particle is made to have with emulsion system
There is a preferable compatibility, and poly hydroxy ethyl acrylate is polar molecule, passes through hydroxyl thereon and nanoparticle surface
Hydroxyl reaction, polystyrene can just be grafted on nanoparticle surface, and polystyrene hydrophobicity is strong, and Polystyrene is received
The presence of rice corpuscles further enhances the water proofing property of film.Poly hydroxy ethyl acrylate is soft segment, is conducive to enhance
The tensile strength and compressive property of film.And there are a variety of polyolefin compounds in system, can induce in the presence of ultraviolet
Further crosslinking occurs, to enhance the tensile property of film.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used
In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field
Some the nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available.
Embodiment 1：
Embodiment 1 provides a kind of High-performance green waterproofing slurry, is grouped as by two kinds of groups of waterproof powder and water-proof emulsion,
Wherein the weight proportion of waterproof powder and water-proof emulsion is 0.8：1；Wherein the waterproof powder at least wraps in parts by weight
Include following components：70 parts of cement, 5 parts of nano-particle, 0.1 part of water-reducing agent；The wherein water-proof emulsion, in parts by weight, until
Include following components less：30 parts of polymer emulsion, 5 parts of polychloroprene latex, 1 part of water；The polymer emulsion is acrylate breast
Liquid；The polychloroprene latex is organic imvite modified polychloroprene latex.
The cement is portland cement, is purchased from Anhui Conch Cement limited liability company, and the trade mark is I type silicate cements
Mud, specification 42.5MPa.The nano-particle is nano silicon dioxide, is purchased from Beijing Deco Dao Jin Science and Technology Ltd.s, grain
Diameter is 30nm.The water-reducing agent is naphthalene series high-efficiency water-reducing agent, is purchased from Qingdao Hong Sha high molecular materials Co., Ltd, model naphthalene
Series high-efficiency water-reducing agent-A.The acrylic acid ester emulsion is the pure-acrylic emulsion purchased from Guangzhou Kuang Xuan Chemical Co., Ltd.s.
The content of organo montmorillonite is 5wt% in the organic imvite modified polychloroprene latex；Organic illiteracy is de-
The preparation method of land reform polychloroprene latex, at least includes the following steps：
Organo montmorillonite deionized water dissolving is taken, the wherein mass ratio of organo montmorillonite and deionized water is 1：4, stirring
30min, then re-ultrasonic dispersion 15min, obtains corresponding suspension.It weighs the suspension and is added to cationic neoprene
In breast, first stirred 2 hours with high speed dispersor, then 20~60min of ultrasonic disperse, obtains organic imvite modified cation
Polychloroprene latex, the content of organo montmorillonite is 5wt% in the organic imvite modified cationic chloroprene latex.
The preparation method of the High-performance green waterproofing slurry, at least includes the following steps：
A. the preparation of waterproof powder：By weight, each component of the waterproof powder is weighed, successively by cement, nanometer
15min is stirred in particle, water-reducing agent input dispersator, obtains waterproof powder；
B. the preparation of water-proof emulsion：By weight, each component for weighing the water-proof emulsion, first by polymer emulsion
It is added in reactor, is slowly added to polychloroprene latex while stirring, continue to stir 10min, other components are then added, continue to stir
15min is mixed, water-proof emulsion is obtained.
Embodiment 2：
Embodiment 2 provides embodiment 1 and provides a kind of High-performance green waterproofing slurry, by waterproof powder and water-proof emulsion
Two kinds of groups are grouped as, and wherein the weight proportion of waterproof powder and water-proof emulsion is 1.3：1；The wherein waterproof powder, with weight
Part meter is measured, following components is included at least：100 parts of cement, 20 parts of nano-particle, 0.5 part of water-reducing agent；The wherein anti-water and milk
Liquid includes at least following components in parts by weight：70 parts of polymer emulsion, 20 parts of polychloroprene latex, 10 parts of water；The polymerization
Object lotion is acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
The cement is aluminate cement, is purchased from Zhengzhou Kang Hui Nai Cai Co., Ltds, model CA-50.Described receives
Rice corpuscles is nano-titanium dioxide, is purchased from the rutile type nano titanium oxide of Beijing Deco Dao Jin Science and Technology Ltd.s, and grain size is
35nm.The water-reducing agent is naphthalene series high-efficiency water-reducing agent, is purchased from Qingdao Hong Sha high molecular materials Co., Ltd, and model naphthalene system is high
Imitate water-reducing agent-C.The acrylic acid ester emulsion is the pure-acrylic emulsion purchased from Guangzhou Kuang Xuan Chemical Co., Ltd.s.
The content of organo montmorillonite is 25wt% in the organic imvite modified polychloroprene latex；Organic illiteracy is de-
The preparation method is the same as that of Example 1 for land reform polychloroprene latex.
The preparation method is the same as that of Example 1 for the High-performance green waterproofing slurry.
Embodiment 3：
Embodiment 3 provides a kind of High-performance green waterproofing slurry, is grouped as by two kinds of groups of waterproof powder and water-proof emulsion,
Wherein the weight proportion of waterproof powder and water-proof emulsion is 1.1：1；Wherein the waterproof powder at least wraps in parts by weight
Include following components：85 parts of cement, 18 parts of nano-particle, 0.3 part of water-reducing agent；The wherein water-proof emulsion, in parts by weight, until
Include following components less：65 parts of polymer emulsion, 17 parts of polychloroprene latex, 2.5 parts of auxiliary agent, 7 parts of water；The polymer emulsion is
Acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
The cement is aluminate cement, is purchased from Zhengzhou Kang Hui Nai Cai Co., Ltds, model CA-60.Described receives
Rice corpuscles is nano-aluminium oxide, is purchased from the anatase type nano titanium oxide of Beijing Deco Dao Jin Science and Technology Ltd.s, grain size
For 20nm.The water-reducing agent is aliphatic high-efficiency water reducing agent, is purchased from Qingdao Hong Sha high molecular materials Co., Ltd, model
HSB (Hong Sha Bing) aliphatic high-efficiency water reducing agent (powder).The acrylic acid ester emulsion is purchased from the spacious pavilion chemical industry in Guangzhou
The pure-acrylic emulsion of Co., Ltd.
The content of organo montmorillonite is 16wt% in the organic imvite modified polychloroprene latex；Organic illiteracy is de-
The preparation method is the same as that of Example 1 for land reform polychloroprene latex.
The preparation method is the same as that of Example 1 for the High-performance green waterproofing slurry.
Embodiment 4：
Embodiment 4 provides a kind of High-performance green waterproofing slurry, is grouped as by two kinds of groups of waterproof powder and water-proof emulsion,
Wherein the weight proportion of waterproof powder and water-proof emulsion is 1.1：1；Wherein the waterproof powder at least wraps in parts by weight
Include following components：85 parts of cement, 18 parts of nano-particle, 0.3 part of water-reducing agent；The wherein water-proof emulsion, in parts by weight, until
Include following components less：65 parts of polymer emulsion, 17 parts of polychloroprene latex, 2.5 parts of auxiliary agent, 7 parts of water；The polymer emulsion is
Acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
The cement is aluminate cement, is purchased from Zhengzhou Kang Hui Nai Cai Co., Ltds, model CA-70.Described receives
Rice corpuscles is nano zine oxide, is purchased from Beijing Deco Dao Jin Science and Technology Ltd.s, grain size 30nm.The water-reducing agent is poly- carboxylic
Sour high-performance water reducing agent is purchased from Qingdao Hong Sha high molecular materials Co., Ltd, model HSC high performance water reducing agent of polyocarboxy acid.Institute
The acrylic acid ester emulsion stated is the pure-acrylic emulsion purchased from Guangzhou Kuang Xuan Chemical Co., Ltd.s.
The content of organo montmorillonite is 16wt% in the organic imvite modified polychloroprene latex；Organic illiteracy is de-
The preparation method is the same as that of Example 1 for land reform polychloroprene latex.
The preparation method is the same as that of Example 1 for the High-performance green waterproofing slurry.
Embodiment 5：
Embodiment 5 provides a kind of High-performance green waterproofing slurry, is grouped as by two kinds of groups of waterproof powder and water-proof emulsion,
Wherein the weight proportion of waterproof powder and water-proof emulsion is 1.1：1；Wherein the waterproof powder at least wraps in parts by weight
Include following components：85 parts of cement, 18 parts of nano-particle, 0.3 part of water-reducing agent；The wherein water-proof emulsion, in parts by weight, until
Include following components less：65 parts of polymer emulsion, 17 parts of polychloroprene latex, 2.5 parts of auxiliary agent, 7 parts of water；The polymer emulsion is
Acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
The cement is aluminate cement, is purchased from Zhengzhou Kang Hui Nai Cai Co., Ltds, model CA-70.Described subtracts
Aqua is high performance water reducing agent of polyocarboxy acid, is purchased from Qingdao Hong Sha high molecular materials Co., Ltd, model HSC poly-carboxylic high-performances
Water-reducing agent.The acrylic acid ester emulsion is the pure-acrylic emulsion purchased from Guangzhou Kuang Xuan Chemical Co., Ltd.s.
The content of organo montmorillonite is 16wt% in the organic imvite modified polychloroprene latex；Organic illiteracy is de-
The preparation method is the same as that of Example 1 for land reform polychloroprene latex.
The nano-particle is Polystyrene nano-particle.
The preparation method of the Polystyrene nano-particle, at least includes the following steps：
A. the reaction kettle with mechanical agitation and nitrogen protection is heated to 100 DEG C, the sky in reaction kettle is displaced with nitrogen
Gas keeps state to the reaction kettle for being passed through nitrogen to be cooled to room temperature, sequentially adds styrene, pentamethyl diethylenetriamine and bromine
Change cuprous, the mass ratio of styrene, five methyl diethylentriamine and cuprous bromide is 200：1：1, it stirs in the presence of nitrogen
30min forms stable light green complex compound.Initiator ethyl α bromoisobutyrate, ethyl α bromoisobutyrate and bromine are injected with syringe
It is 1 to change cuprous mass ratio：1,100 DEG C are warming up to, stops reaction after reacting 4h under stiring, is cooled to room temperature.Tetrahydrochysene is added
Furans dissolves, and column chromatography removes catalyst, and then reaction solution is slowly added dropwise into absolute methanol, is stirred when being added dropwise, mistake
Supernatant is filtered out, 60 DEG C obtained of product, which is dried under vacuum to constant weight, obtains product a.
B. the reaction kettle with mechanical agitation and nitrogen protection is heated to 100 DEG C, the sky in reaction kettle is displaced with nitrogen
Gas keeps state to the reaction kettle for being passed through nitrogen to be cooled to room temperature, and the mass fraction for sequentially adding hydroxyethyl methacrylate is
35% cyclohexanone solution, five methyl diethylentriamine and cuprous bromide, hydroxyethyl methacrylate, pentamethyl diethylidene
The mass ratio of triamine and cuprous bromide is 140：1：1, stirring 30min forms stable light green complex compound.Then step a is added
Obtained product is synthesized, is warming up to 60 DEG C, stops reaction after continuing same nitrogen reaction 3h under stiring.Column chromatography removes catalysis
Then agent reaction solution is slowly added dropwise into n-hexane, stirred when being added dropwise, be filtered to remove supernatant, the product that will be obtained
40 DEG C are dried under vacuum to constant weight and obtain product b.
C. product b is dissolved in tetrahydrofuran, nano-particle, the product b, tetrahydrofuran, nano-particle is added
Mass ratio be 5：100：1, it seals, nano-particle is taken out after concussion 40min in earthquake shaking table, after natural drying, at 90 DEG C
It is dried in baking oven half an hour, a period of time is then heated in 120 DEG C of baking ovens, it is then molten with tetrahydrofuran in Soxhlet extractor
Liquid elutes 48h, dry, obtains Polystyrene nano-particle.
The nano-particle is nano silicon dioxide, is purchased from Beijing Deco Dao Jin Science and Technology Ltd.s, grain size 30nm.
The preparation method is the same as that of Example 1 for the High-performance green waterproofing slurry.
Embodiment 6：
The specific implementation mode of embodiment 6 with embodiment 5, the difference is that, further include 1.2 in the water-proof emulsion
The auxiliary agent of parts by weight, the auxiliary agent are plasticizer phthalic acid dibutyl ester, CAS：84-74-2 gives birth to purchased from Shanghai Aladdin
Change Science and Technology Ltd..
Comparative example 1：
The specific implementation mode of comparative example 1 with embodiment 6, the difference is that, do not include in the water-proof emulsion
The imvite modified polychloroprene latex of machine.
Comparative example 2：
The specific implementation mode of comparative example 2 with embodiment 6, the difference is that, by the organic imvite modified chlorine
Fourth latex such as is changed at the polychloroprene latex of quality.
Comparative example 3：
The specific implementation mode of embodiment 3 with embodiment 6, the difference is that, by the organic imvite modified chlorine
Fourth latex such as is changed at the organo montmorillonite of quality.
Comparative example 4：
The specific implementation mode of comparative example 4 with embodiment 6, the difference is that, by the organic imvite modified chlorine
Fourth latex is changed to imvite modified polychloroprene latex, and the montmorillonite is sodium-based montmorillonite, is purchased from NANOCOR companies of the U.S.,
Model PGW.
Comparative example 5：
The specific implementation mode of comparative example 5 with embodiment 6, the difference is that, by the organic imvite modified chlorine
Fourth latex is changed to the mixture of organo montmorillonite and polychloroprene latex.
Comparative example 6：
The specific implementation mode of comparative example 6 with embodiment 6, the difference is that, do not include poly- in the waterproof powder
Phenylethene modified nano-particle.
Comparative example 7：
The specific implementation mode of comparative example 7 with embodiment 6, the difference is that, the nanometer of the Polystyrene
Do not include step b in the building-up process of particle.
Comparative example 8：
The specific implementation mode of comparative example 8 with embodiment 6, the difference is that, the nanometer of the Polystyrene
Do not include step a in the building-up process of particle.
Performance evaluation：
1. water-proof emulsion stability
By 1mL30wt%CaCl2Aqueous solution is separately added into waterproof made from 10mL Examples 1 to 6 and comparative example 1~8
It in lotion, is sealed in test tube after shaking up, the situation of change of lotion is observed after 6 months, such as find layering, precipitation, flocculation
Phenomenon is recorded as unqualified；Otherwise it is recorded as qualification.
According to weight ratio, the waterproof powder in Example 1~6 and comparative example 1~8 and water-proof emulsion stir 10min
So that it is uniformly mixed, obtain corresponding High-performance green waterproofing slurry, the High-performance green waterproofing slurry is tried in standard
It is placed under the conditions of testing more than for 24 hours.Standard test conditions in the present invention is：Temperature：(23 ± 2) DEG C, relative humidity：(50±
10) %.
2. adhesion strength is tested
According to described in GBT16777-2008 7.2 method testing example 1~6 and comparative example 1~8 obtain it is anti-
Adhesive property of the water slurry in dry basal plane.
3. tensile strength is tested
It is obtained according to 7.4.3 and 7.4.7 testing example 1~6 in GBT2023445-2009 and comparative example 1~8 anti-
Water slurry film without processing tensile property and UV treatment post-tensioning intensity.
4. impermeability
According to the waterproofing slurry film of 15 testing example 1~6 and the acquisition of comparative example 1~8 in GBT16777-2008
Impermeability, test condition is：Hydraulic pressure is 0.3MPa, time 1h.Whether there is or not infiltration situations for observation, if there is infiltration situation note
Record is unqualified, is otherwise recorded as qualification.
5. water resistance test
The waterproofing slurry that Examples 1 to 6 and comparative example 1~8 obtain to be poured into mold and is cured, placement demoulds afterwards for 24 hours,
The film that demoulding obtains is immersed in 25 DEG C of tap water 3 months, observes whether its surface phenomena such as bulge occurs.
1 performance characterization of table is tested
As can be seen from Table 1, the water-proof emulsion in the High-performance green waterproofing slurry in the present invention has excellent stabilization
Property, the adhesive property between high performance water proof slurry of the invention and base material is good, and film tensile strength is big, uvioresistant stability
It is good, and also there is preferable water proofing property.
Example above-mentioned is merely illustrative, some features for explaining the method for the invention.Appended right is wanted
The range as wide as possible for being intended to require to be contemplated that is sought, and embodiments as presented herein is only according to all possible implementation
The explanation of the embodiment of the selection of the combination of example.Therefore, the purpose of applicant is that the attached claims are not illustrated this hair
The exemplary selectional restriction of bright feature.Some numberical ranges used also include sub- model in the claims
It encloses, the variation in these ranges should also be construed to be covered by the attached claims in the conceived case.
Claims (10)
1. a kind of High-performance green waterproofing slurry, which is characterized in that it is grouped as by two kinds of groups of waterproof powder and water-proof emulsion, wherein
The weight proportion of waterproof powder and water-proof emulsion is 0.8~1.3：1；Wherein the waterproof powder at least wraps in parts by weight
Include following components：70~100 parts of cement, 5~20 parts of nano-particle, 0.1~0.5 part of water-reducing agent；The wherein water-proof emulsion,
In parts by weight, following components is included at least：30~70 parts of polymer emulsion, 5~20 parts of polychloroprene latex, 1~10 part of water；It is described
Polymer emulsion be acrylic acid ester emulsion；The polychloroprene latex is organic imvite modified polychloroprene latex.
2. High-performance green waterproofing slurry as described in claim 1, which is characterized in that the cement is selected from silicate cement
Any one of mud, aluminate cement, sulphate aluminium cement, ferrous aluminate cement, fluoroaluminate cement, ferrophosphorus acid salt cement or
It is a variety of.
3. High-performance green waterproofing slurry as described in claim 1, which is characterized in that the nano-particle is selected from nanometer two
Silica, nano-titanium dioxide, nano-aluminium oxide, nano zirconium dioxide, nano zine oxide, nano mica powder, nano-sized carbon
Sour calcium, nano-silicon magnesia any one or more of.
4. High-performance green waterproofing slurry as described in claim 1, which is characterized in that the water-reducing agent is selected from naphthalene series high-efficiency
Any one of water-reducing agent, aliphatic high-efficiency water reducing agent, aminosulfonate-based superplasticizer, high performance water reducing agent of polyocarboxy acid.
5. High-performance green waterproofing slurry as described in claim 1, which is characterized in that the acrylic acid ester emulsion is pure third
Lotion, the pure-acrylic emulsion by acrylic acid, ethyl acrylate, butyl acrylate, methacrylic acid, methyl methacrylate,
The polymer emulsion that any one or more polymerization in ethyl methacrylate, butyl methacrylate obtains.
6. High-performance green waterproofing slurry as described in claim 1, which is characterized in that the organic imvite modified neoprene
The content of organo montmorillonite is 5~25wt% in latex.
7. High-performance green waterproofing slurry as described in claim 1, which is characterized in that further include in the water-proof emulsion
The auxiliary agent of 0.1~3 parts by weight, the auxiliary agent are Antisepticize and mildew preventive, wetting dispersing agent, antifoaming agent, plasticizer, thixotropic agent, increasing
The mixing of thick dose of any one or more of.
8. such as the preparation method of claim 1~7 any one of them High-performance green waterproofing slurry, which is characterized in that at least
Include the following steps：
A. the preparation of waterproof powder：By weight, weigh each component of the waterproof powder, successively by cement, nano-particle,
Water-reducing agent, which is put into, stirs 10~20min in dispersator, obtain waterproof powder；
B. the preparation of water-proof emulsion：By weight, each component for weighing the water-proof emulsion, first polymer emulsion is added
Into reactor, it is slowly added to polychloroprene latex while stirring, continues 5~10min of stirring after the completion of being added, other groups is then added
Point, continue 10~15min of stirring, obtains water-proof emulsion.
9. such as the application method of claim 1~7 any one of them High-performance green waterproofing slurry, which is characterized in that applying
Working hour, by waterproof powder and water-proof emulsion by weight ratio 0.8~1.3：1 mixing, and stirring 5~30min makes it uniformly mix,
It can knife-coat application.
10. such as application of the claim 1~7 any one of them High-performance green waterproofing slurry in construction waterproofing engineering.
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| CN114806445A (en) * | 2019-07-22 | 2022-07-29 | 浙江福莱新材料股份有限公司 | Weather-resistant advertisement sticker |
| CN114806445B (en) * | 2019-07-22 | 2024-02-23 | 浙江福莱新材料股份有限公司 | Advertisement car body paste |
| CN116376335A (en) * | 2023-05-09 | 2023-07-04 | 佛山市德堡建材有限公司 | Low-carbon waterproof coating |
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