CN108300017A - A method of producing crystal white glue with vinyl using lotion - Google Patents
A method of producing crystal white glue with vinyl using lotion Download PDFInfo
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- CN108300017A CN108300017A CN201710947809.9A CN201710947809A CN108300017A CN 108300017 A CN108300017 A CN 108300017A CN 201710947809 A CN201710947809 A CN 201710947809A CN 108300017 A CN108300017 A CN 108300017A
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- degree
- vinyl
- white glue
- emulsifier
- crystal
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
- C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids
- C08F263/04—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids on to polymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Cosmetics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to paint field more particularly to a kind of methods producing crystal white glue with vinyl using lotion.Polyvinyl acetate 900, fluorescent powder 100, vinylacetate 330, polyvinyl alcohol 130, dibutyl phthalate 85, diethylene glycol dibenzoate 30, titanium dioxide nanoparticle 300, isopropanol 37, allyl methacrylate 19, ethyleneglycol dimethyacrylate 8, toluene di-isocyanate(TDI) 5, sodium bicarbonate 41, water 1460, emulsifier 46, initiator 8, hydroxymethyl acrylamide 27, waxy corn starch 13, sodium hypochlorite 5；Industrial crystal powder；Fluorescent powder is beautiful after white glue with vinyl is whitewashed a wall, and goes back noctilucence, the effect that industrial crystal powder has crystal glittering under light illumination；Titanium dioxide nanoparticle part can absorb formaldehyde, environmental protection in the later stage.The whole value for embodying coating U.S..
Description
Technical field
The present invention relates to paint field more particularly to a kind of methods producing crystal white glue with vinyl using lotion.
Background technology
White glue with vinyl be by vinyl acetate monomer under initiator effect a kind of thermoplastic bonded prepared by aggregated reaction
Agent.White glue with vinyl/Polyvinyl acetate adhesive is by acetic acid and ethylene synthase polyvinyl acetate.It is normal temperature solidified, solidification it is very fast, viscous
It is higher to connect intensity, adhesive linkage has preferable toughness and durability and non-aging.White glue with vinyl is a kind of water soluble adhesive, is
By vinyl acetate monomer under initiator effect a kind of thermoplastic adhesives prepared by aggregated reaction.Commonly referred to as white glue with vinyl
Or abbreviation PVAC lotions, chemical name Polyvinyl acetate adhesive, it is that titanium dioxide is added by acetic acid and ethylene synthase vinyl acetate
（Low-grade just adds fine particle calcium carbonate, talcum powder to wait powders）Again through milky glop made of emulsion polymerization.Fast drying, tack
It is good, operational good；Bonding force is strong, compression strength is high；Heat resistance is strong.
But the decoration performance of current white glue with vinyl is bad, also often generates formaldehyde.Such as 201510045195.6.
Invention content
The purpose of invention：In order to provide a kind of method that effect preferably utilizes lotion to produce crystal white glue with vinyl, specific mesh
See specific implementation part multiple substantial technological effects.
In order to reach purpose as above, the present invention adopts the following technical scheme that：
A method of producing crystal white glue with vinyl using lotion, which is characterized in that
The crystal white glue with vinyl is grouped as by each group of following parts by weight：
Polyvinyl acetate 900, fluorescent powder 100, vinylacetate 330, polyvinyl alcohol 130, dibutyl phthalate
85, diethylene glycol dibenzoate 30, titanium dioxide nanoparticle 300, isopropanol 37, allyl methacrylate 19, double first
Base acrylic acid glycol ester 8, toluene di-isocyanate(TDI) 5, sodium bicarbonate 41, water 1460, emulsifier 46, initiator 8, hydroxyl
Methacrylamide 27, waxy corn starch 13, sodium hypochlorite 5；Industrial crystal powder 130；
Step 1 under stirring condition, takes the water and polyvinyl alcohol of 50-73% weight percent, mixes, is warming up to 88-95
Degree so that polyvinyl alcohol is completely dissolved, and 1 hour is kept the temperature under 70-80 degree, and it is 8-9 to adjust p H, obtains solution A；
Step 2, takes the emulsifier of 30-40% weight percent, and under stirring condition, the emulsifier and remaining water are added
Into solution A, then it is slowly added into the vinylacetate of 40-50% weight percent and drawing for 40-50% weight percent
Agent is sent out, 88-95 degree is warming up to, keeps the temperature 0.3-0.5 hours；It is cooled to 60-70 degree；It is slowly added into again later remaining
Vinylacetate and remaining initiator；It is warming up to 88-95 degree, keeps the temperature 0.2-0.4 hours；
Step 3 is added the emulsifier and polyvinyl acetate of 30-40% weight percent, 0.2- is kept the temperature under 88-95 degree
0.4 hour, it is subsequently cooled to 40-50 degree；
Under stirring condition, sodium bicarbonate is added in step 4, dibutyl phthalate, diethylene glycol dibenzoate, and octanol is different
Propyl alcohol is uniformly mixed, obtains solution B；
Step 5, is added remaining emulsifier into solution B, allyl methacrylate, ethyleneglycol dimethyacrylate,
Toluene di-isocyanate(TDI), hydroxymethyl acrylamide, waxy corn starch, sodium hypochlorite are uniformly mixed, and 40-50 degree keeps the temperature 0.1-
0.3 hour, be cooled to room temperature to get；
Step 6 is finally mixed into 100 parts of fluorescent powder, 300 parts of titanium dioxide nanoparticle, industrial 130 parts of crystal powder.
The further technical solution of the present invention is that the emulsifier is neopelex or enuatrol.
The further technical solution of the present invention is that the initiator is potassium peroxydisulfate or ammonium persulfate.
Using the present invention of technical solution as above, have the advantages that compared with the existing technology：Fluorescent powder makes Virgin's milk
Glue is beautiful after whitewashing a wall, and goes back noctilucence, and the industrial preferred particle diameter of crystal powder is in 10um or so, the effect that has crystal glittering under light illumination
Fruit；300 parts of titanium dioxide nanoparticle can absorb formaldehyde, environmental protection in the later stage.The whole value for embodying coating U.S..
Specific implementation mode
Specific implementation mode below, the present invention is furture elucidated, it should be understood that following specific implementation modes are merely to illustrate this
It invents rather than limits the scope of the invention.
A method of producing crystal white glue with vinyl using lotion, which is characterized in that
The crystal white glue with vinyl is grouped as by each group of following parts by weight：
Polyvinyl acetate 900, fluorescent powder 100, vinylacetate 330, polyvinyl alcohol 130, dibutyl phthalate
85, diethylene glycol dibenzoate 30, titanium dioxide nanoparticle 300, isopropanol 37, allyl methacrylate 19, double first
Base acrylic acid glycol ester 8, toluene di-isocyanate(TDI) 5, sodium bicarbonate 41, water 1460, emulsifier 46, initiator 8, hydroxyl
Methacrylamide 27, waxy corn starch 13, sodium hypochlorite 5；Industrial crystal powder 130；
Step 1 under stirring condition, takes the water and polyvinyl alcohol of 50-73% weight percent, mixes, is warming up to 88-95
Degree so that polyvinyl alcohol is completely dissolved, and 1 hour is kept the temperature under 70-80 degree, and it is 8-9 to adjust p H, obtains solution A；
Step 2, takes the emulsifier of 30-40% weight percent, and under stirring condition, the emulsifier and remaining water are added
Into solution A, then it is slowly added into the vinylacetate of 40-50% weight percent and drawing for 40-50% weight percent
Agent is sent out, 88-95 degree is warming up to, keeps the temperature 0.3-0.5 hours；It is cooled to 60-70 degree；It is slowly added into again later remaining
Vinylacetate and remaining initiator；It is warming up to 88-95 degree, keeps the temperature 0.2-0.4 hours；
Step 3 is added the emulsifier and polyvinyl acetate of 30-40% weight percent, 0.2- is kept the temperature under 88-95 degree
0.4 hour, it is subsequently cooled to 40-50 degree；
Under stirring condition, sodium bicarbonate is added in step 4, dibutyl phthalate, diethylene glycol dibenzoate, and octanol is different
Propyl alcohol is uniformly mixed, obtains solution B；
Step 5, is added remaining emulsifier into solution B, allyl methacrylate, ethyleneglycol dimethyacrylate,
Toluene di-isocyanate(TDI), hydroxymethyl acrylamide, waxy corn starch, sodium hypochlorite are uniformly mixed, and 40-50 degree keeps the temperature 0.1-
0.3 hour, be cooled to room temperature to get；
Step 6 is finally mixed into 100 parts of fluorescent powder, 300 parts of titanium dioxide nanoparticle, industrial 130 parts of crystal powder.
This patent provides a variety of concomitant regimens, in place of different expression, belong to modified scheme based on basic scheme or
It is parallel type scheme.Each scheme has the unique features of oneself.
This patent is unique in that step 6, be finally mixed into 100 parts of fluorescent powder, 300 parts of titanium dioxide nanoparticle,
130 parts of industrial crystal powder.
Fluorescent powder is beautiful after white glue with vinyl is whitewashed a wall, and goes back noctilucence, the industrial preferred particle diameter of crystal powder in 10um or so,
The effect for having crystal glittering under illumination；300 parts of titanium dioxide nanoparticle can absorb formaldehyde, environmental protection in the later stage.Totally
Embody the value of coating U.S..
In a creative way, above each effect is individually present, moreover it is possible to the combination of the above results is completed with a nested structure.
It should be noted that multiple schemes that this patent provides include the basic scheme of itself, independently of each other, not mutually
It restricts, but it can also be combined with each other in the absence of conflict, reach multiple effects and realize jointly.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of this field
Personnel should be recognized that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this hairs
Bright principle, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these variations
It is both fallen in claimed range with improving.
Claims (3)
1. a kind of method producing crystal white glue with vinyl using lotion, which is characterized in that the crystal white glue with vinyl is by following parts by weight
Several each groups are grouped as：
Polyvinyl acetate 900, fluorescent powder 100, vinylacetate 330, polyvinyl alcohol 130, dibutyl phthalate
85, diethylene glycol dibenzoate 30, titanium dioxide nanoparticle 300, isopropanol 37, allyl methacrylate 19, double first
Base acrylic acid glycol ester 8, toluene di-isocyanate(TDI) 5, sodium bicarbonate 41, water 1460, emulsifier 46, initiator 8, hydroxyl
Methacrylamide 27, waxy corn starch 13, sodium hypochlorite 5；Industrial crystal powder 130；
Step 1 under stirring condition, takes the water and polyvinyl alcohol of 50-73% weight percent, mixes, is warming up to 88-95
Degree so that polyvinyl alcohol is completely dissolved, and 1 hour is kept the temperature under 70-80 degree, and it is 8-9 to adjust p H, obtains solution A；
Step 2, takes the emulsifier of 30-40% weight percent, and under stirring condition, the emulsifier and remaining water are added
Into solution A, then it is slowly added into the vinylacetate of 40-50% weight percent and drawing for 40-50% weight percent
Agent is sent out, 88-95 degree is warming up to, keeps the temperature 0.3-0.5 hours；It is cooled to 60-70 degree；It is slowly added into again later remaining
Vinylacetate and remaining initiator；It is warming up to 88-95 degree, keeps the temperature 0.2-0.4 hours；
Step 3 is added the emulsifier and polyvinyl acetate of 30-40% weight percent, 0.2- is kept the temperature under 88-95 degree
0.4 hour, it is subsequently cooled to 40-50 degree；
Under stirring condition, sodium bicarbonate is added in step 4, dibutyl phthalate, diethylene glycol dibenzoate, and octanol is different
Propyl alcohol is uniformly mixed, obtains solution B；
Step 5, is added remaining emulsifier into solution B, allyl methacrylate, ethyleneglycol dimethyacrylate,
Toluene di-isocyanate(TDI), hydroxymethyl acrylamide, waxy corn starch, sodium hypochlorite are uniformly mixed, and 40-50 degree keeps the temperature 0.1-
0.3 hour, be cooled to room temperature to get；
Step 6 is finally mixed into 100 parts of fluorescent powder, 300 parts of titanium dioxide nanoparticle, industrial 130 parts of crystal powder.
2. a kind of method producing crystal white glue with vinyl using lotion as described in claim 1, which is characterized in that the emulsification
Agent is neopelex or enuatrol.
3. a kind of method producing crystal white glue with vinyl using lotion as described in claim 1, which is characterized in that the initiation
Agent is potassium peroxydisulfate or ammonium persulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710947809.9A CN108300017A (en) | 2017-10-12 | 2017-10-12 | A method of producing crystal white glue with vinyl using lotion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710947809.9A CN108300017A (en) | 2017-10-12 | 2017-10-12 | A method of producing crystal white glue with vinyl using lotion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108300017A true CN108300017A (en) | 2018-07-20 |
Family
ID=62870059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710947809.9A Pending CN108300017A (en) | 2017-10-12 | 2017-10-12 | A method of producing crystal white glue with vinyl using lotion |
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| Country | Link |
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| CN (1) | CN108300017A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135454A (en) * | 2018-08-28 | 2019-01-04 | 宁波百仕高联合工业有限公司 | A kind of colorful noctilucent emulsion glue and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104629633A (en) * | 2015-01-28 | 2015-05-20 | 海安县紫石涂料有限公司 | Water-resistant white latex |
| CN104673146A (en) * | 2015-01-28 | 2015-06-03 | 海安县中丽化工材料有限公司 | Strong white latex |
| CN105153830A (en) * | 2015-10-28 | 2015-12-16 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional interior-wall latex paint and preparing method thereof |
-
2017
- 2017-10-12 CN CN201710947809.9A patent/CN108300017A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104629633A (en) * | 2015-01-28 | 2015-05-20 | 海安县紫石涂料有限公司 | Water-resistant white latex |
| CN104673146A (en) * | 2015-01-28 | 2015-06-03 | 海安县中丽化工材料有限公司 | Strong white latex |
| CN105153830A (en) * | 2015-10-28 | 2015-12-16 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional interior-wall latex paint and preparing method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 王杏等: "《纳米二氧化钛的生产与应用》", 31 July 2014, 贵州科技出版社 * |
| 苏立荣等: "《建筑涂料配方手册》", 31 March 2008, 机械工业出版社 * |
| 赵志凤等: "《材料化学》", 31 August 2012, 哈尔滨工业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135454A (en) * | 2018-08-28 | 2019-01-04 | 宁波百仕高联合工业有限公司 | A kind of colorful noctilucent emulsion glue and preparation method thereof |
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Application publication date: 20180720 |
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