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CN108272656A - A kind of water-soluble nail polish and preparation method thereof - Google Patents

A kind of water-soluble nail polish and preparation method thereof Download PDF

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Publication number
CN108272656A
CN108272656A CN201810031087.7A CN201810031087A CN108272656A CN 108272656 A CN108272656 A CN 108272656A CN 201810031087 A CN201810031087 A CN 201810031087A CN 108272656 A CN108272656 A CN 108272656A
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CN
China
Prior art keywords
water
weight
parts
nail polish
aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810031087.7A
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Chinese (zh)
Inventor
叶志勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
An Official Polytron Technologies Inc
Original Assignee
An Official Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by An Official Polytron Technologies Inc filed Critical An Official Polytron Technologies Inc
Priority to CN201810031087.7A priority Critical patent/CN108272656A/en
Publication of CN108272656A publication Critical patent/CN108272656A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00Manicure or pedicure preparations
    • A61Q3/02Nail coatings

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

A kind of water-soluble nail polish of present invention offer and preparation method thereof, including waterborne polyurethane modified acrylic acid composite emulsion, coalescents, aqueous dispersion wetting agent, aqueous substrate wetting agents, thickener, adhesion promoter, pigment, other auxiliary agents and water, under 800~900 revs/min of rotating speed, waterborne polyurethane modified acrylic acid composite emulsion is added, coalescents are added with the speed of 6~8L/h, aqueous wetting dispersing agent is added after 25~30 minutes in dispersion, aqueous substrate wetting agents, pigment is added again after continuing dispersion 10~15 minutes, adhesion promoter and other auxiliary agents, after stirring evenly viscosity is adjusted with thickener and the water of surplus, it is filtered and packaged with 150 mesh filter screens.The water-soluble nail polish of the present invention uses the waterborne polyurethane modified acrylic acid Core-Shell Type Hybrid Emulsions of special construction, and grain size is thin, and film forming is good, strong adhesive force, and water resistance is high, and glossiness height and anti-after tack are strong.

Description

A kind of water-soluble nail polish and preparation method thereof
Technical field
The invention belongs to cosmetic technical fields, and in particular to a kind of water-soluble nail polish and preparation method thereof.
Background technology
Conventional nails oil is NC Nitroncellulose or other UV-cured resins as film forming binder, the former is due to a large amount of The presence of organic solvent is larger to nail and human body harm, and the latter needs ultraviolet radiation-curable to form a film, and is used for a long time to skin It is still harmful to, and manicure tedious process.There are also some water-based nail polish products of some patent reports.
CN200910119825.4 discloses a kind of water-soluble high-hardness antibacterial nail polish applied to nail salon industry And preparation method thereof, have the characteristics that hardness height, antibacterial, strong adhesive force.But it is outer addition antiseptic, base-material itself does not resist Bacterium and water-soluble resin is still higher as film forming matter hydrotropy agent content itself.And not water-fast flushing, retention time are shorter.
CN201310513545.8 discloses a kind of preparation method of environmentally-frieaqueous aqueous nail polish, without acetone, ethyl acetate Equal toxic organic solvents do not generate penetrating odor to nail fanout free region.But it is as nail polish adhesive force, water-fast flushing Ability, antibiotic property are poor, and the retention time is shorter.
CN201410554219.6 discloses a kind of flash of light quick-dry type water-based nail polish, it has good wearability, resistance to Aqueous, richness etc..But its water-fast washing, adhesive force and antibacterial effect are poor, the retention time is short.
CN201510672793.6 discloses a kind of cation water-based acrylic ester type environmentally-frieaqueous aqueous nail polish and its preparation Method, wherein:Compared to conventional aqueous acrylic emulsion, the rate of drying of cation-type water-thinned acrylate is relatively slow, The features such as hardness is not high enough, cost is slightly higher and weatherability is not fine.
Invention content
It is a kind of stable, small to human nails and skin irritation with filming performance the purpose of the invention is to provide, The water-soluble nail polish and its system of the features such as excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after tack Preparation Method.
In order to achieve the object of the present invention, the technical solution adopted is that:
The present invention provides a kind of water-soluble nail polish, including following component:
Waterborne polyurethane modified acrylic acid composite emulsion:70-80 parts by weight
Coalescents:2.5-4.5 parts by weight
Aqueous dispersion wetting agent:0.3-0.6 parts by weight
Aqueous substrate wetting agents:0.2-0.6 parts by weight
Thickener:1-5 parts by weight
Adhesion promoter:0.2-1 parts by weight
Pigment:0-5 parts by weight
Other auxiliary agents:0-3 parts by weight
Water:Surplus.
Preferably:The coalescents are alcohol ester 12 (YT-12), dipropylene glycol methyl ether (Tao Shi DPM), dipropylene glycol fourth One or more mixtures in ether (Tao Shi DPnB).
Preferably:The dispersion moisture agent is one or more in FX600, Tech-654.
Preferably:The substrate wetting agents are Tego-wet 270, one or more in BYK-345.
Preferably:The thickener be department draw it is a kind of in oronain hectorite, silica, hydroxyethyl cellulose, polyacrylic acid or It is a variety of.
Preferably:The adhesion promoter is DOW CORNING Z-6040 aqueous silane coupling agents.
Preferably:The pigment is one or more in inorganic pigment, organic pigment, pearl mica, colour PET paillettes.
Preferably:Other described auxiliary agents are one or more in preservative, ultra-violet absorber, antifreezing agent, essence.
The present invention also provides a kind of preparation methods of water-soluble nail polish, including step:In 800~900 revs/min of rotating speed Under, the waterborne polyurethane modified acrylic acid composite emulsion of 70-80 parts by weight is added, with the speed addition 2.5-4.5 weights of 6~8L/h The coalescents of part are measured, aqueous wetting dispersing agent, the 0.2-0.6 weight of 0.3-0.6 parts by weight is added in dispersion after 25~30 minutes Part aqueous substrate wetting agents, added again after continuing dispersion 10~15 minutes the pigment of 0-5 parts by weight, 0.2-1 parts by weight it is attached Adhesion promoter and 0-3 parts by weight other auxiliary agents, it is glutinous with the thickener of 1-5 parts by weight and the adjustment of the water of surplus after stirring evenly Degree, is filtered and packaged with 150 mesh filter screens.
Preferably:The waterborne polyurethane modified acrylic acid Core-Shell Type Hybrid Emulsions, using core-shell emulsion polymerization technology, with Aqueous polyurethane dispersion is kernel, and surface cladding acrylic emulsion forms.Conventional aqueous acrylic emulsion has dry speed The features such as degree is fast, hardness is high, at low cost and good weatherability.Aqueous polyurethane dispersion has excellent wearability, water resistance, soft Toughness, durability and chemical resistance.Shell core emulsion polymerization technology can be substantially reduced lotion minimum film formation temperature (MFFT) and Improve anti-after tack.Therefore the waterborne polyurethane modified acrylic acid Core-Shell Type Hybrid Emulsions selected of the present invention have film forming it is good, The features such as strong adhesive force, water resistance is high, glossiness height and strong anti-after tack.
Compared with prior art, beneficial effects of the present invention are as follows:
Using above-mentioned technical proposal, water-soluble nail polish of the invention uses the waterborne polyurethane modified propylene of special construction Sour Core-Shell Type Hybrid Emulsions, grain size is thin, and film forming is good, strong adhesive force, and water resistance is high, and glossiness height and anti-after tack are strong;It is water-soluble Property nail polish in use coalescents, film forming speed and film forming efficiency greatly reinforce;Asepsis environment-protecting is used in water-soluble nail polish Essence makes it have the fragrance of similar perfume;Adhesion promoter is used in water-soluble nail polish, further strengthens coating attachment Power.The water-soluble nail polish has low smell and addition essence can also obtain the fragrance of similar perfume, to human nails It is small with skin irritation, the features such as excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after tack.
Specific implementation mode
In order to which technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects It encloses.
It is following that the present invention will be further described in conjunction with specific embodiments.
Embodiment 1:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion is uniformly mixed the red nail polish that rose scent is made after above each ingredient weighs.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
Embodiment 2:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made white nail polish.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
Embodiment 3:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made colored paillette nail polish.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
Embodiment 4:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made pineapple taste red pearl mica nail polish.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
Embodiment 5:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made nail polish bottom/gloss varnish.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
Embodiment 6:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made rose taste black nail polish.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
Embodiment 7:A kind of water-soluble nail polish of the present invention, the ingredient of parts by weight:
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made rose taste red pearl mica colour PET paillettes Nail polish.
The nail polish that the present invention obtains has no irritating odor, and is tested through human skin nail, no calcination, redness stimulation. It is detected using the prior art, which has an excellent quick-drying, adhesive force, wearability, water resistance, glossiness and anti-after-tacks Property.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest range caused.

Claims (9)

1. a kind of water-soluble nail polish, which is characterized in that including following component:
Waterborne polyurethane modified acrylic acid composite emulsion:70-80 parts by weight
Coalescents:2.5-4.5 parts by weight
Aqueous dispersion wetting agent:0.3-0.6 parts by weight
Aqueous substrate wetting agents:0.2-0.6 parts by weight
Thickener:1-5 parts by weight
Adhesion promoter:0.2-1 parts by weight
Pigment:0-5 parts by weight
Other auxiliary agents:0-3 parts by weight
Water:Surplus.
2. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that the coalescents are alcohol ester ten Two, one or more mixtures in dipropylene glycol methyl ether, dipropylene.
3. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that the dispersion moisture agent be FX600, It is one or more in Tech-654.
4. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that the substrate wetting agents are Tego- It is one or more in wet270, BYK-345.
5. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that the thickener is that oronain water draws in department It is one or more in pyroxene, silica, hydroxyethyl cellulose, polyacrylic acid.
6. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that the adhesion promoter is road health Peaceful Z-6040 aqueous silane coupling agents.
7. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that the pigment is inorganic pigment, has It is one or more in machine pigment, pearl mica, colour PET paillettes.
8. according to a kind of water-soluble nail polish described in claim 1, which is characterized in that other described auxiliary agents be preservative, It is one or more in ultra-violet absorber, antifreezing agent, essence.
9. a kind of preparation method of water-soluble nail polish, which is characterized in that including step:Under 800~900 revs/min of rotating speed, The waterborne polyurethane modified acrylic acid composite emulsion of 70-80 parts by weight is added, 2.5-4.5 weight is added with the speed of 6~8L/h Aqueous wetting dispersing agent, the 0.2-0.6 parts by weight of 0.3-0.6 parts by weight are added in the coalescents of part, dispersion after 25~30 minutes Aqueous substrate wetting agents, the attachment of the pigment, 0.2-1 parts by weight of 0-5 parts by weight is added after continuing dispersion 10~15 minutes again Power accelerating agent and 0-3 parts by weight other auxiliary agents, it is glutinous with the thickener of 1-5 parts by weight and the adjustment of the water of surplus after stirring evenly Degree, is filtered and packaged with 150 mesh filter screens.
CN201810031087.7A 2018-01-12 2018-01-12 A kind of water-soluble nail polish and preparation method thereof Pending CN108272656A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810031087.7A CN108272656A (en) 2018-01-12 2018-01-12 A kind of water-soluble nail polish and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810031087.7A CN108272656A (en) 2018-01-12 2018-01-12 A kind of water-soluble nail polish and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108272656A true CN108272656A (en) 2018-07-13

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN108272656A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112791012A (en) * 2021-01-11 2021-05-14 金华市科维思日化有限公司 High-light-transmission safe water-based nail polish and preparation method thereof
CN112957278A (en) * 2021-02-19 2021-06-15 杭州协合医疗用品有限公司 Chitin whisker modified water-based nail polish and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112791012A (en) * 2021-01-11 2021-05-14 金华市科维思日化有限公司 High-light-transmission safe water-based nail polish and preparation method thereof
CN112957278A (en) * 2021-02-19 2021-06-15 杭州协合医疗用品有限公司 Chitin whisker modified water-based nail polish and preparation method thereof
CN112957278B (en) * 2021-02-19 2022-11-08 杭州协合医疗用品有限公司 Chitin whisker modified water-based nail polish and preparation method thereof

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Application publication date: 20180713

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