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CN108250614A - A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening - Google Patents

A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening Download PDF

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Publication number
CN108250614A
CN108250614A CN201711489778.3A CN201711489778A CN108250614A CN 108250614 A CN108250614 A CN 108250614A CN 201711489778 A CN201711489778 A CN 201711489778A CN 108250614 A CN108250614 A CN 108250614A
Authority
CN
China
Prior art keywords
parts
pvc
unleaded
toughening
fishery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711489778.3A
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Chinese (zh)
Inventor
孙建忠
代军喜
陈金
王丽娟
毛璐洁
方燕飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Tianlong Derivatives Co Ltd
Original Assignee
Zhejiang Tianlong Derivatives Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Tianlong Derivatives Co Ltd filed Critical Zhejiang Tianlong Derivatives Co Ltd
Priority to CN201711489778.3A priority Critical patent/CN108250614A/en
Publication of CN108250614A publication Critical patent/CN108250614A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a kind of unleaded PVC U fishery cultivating water transferring lines of toughening, including following production stage:A) prepare raw material:Raw material includes following components and the quality proportioning of each component is:PVC U resins:100 parts, inorganic filler:5~8 parts, plasticized modifier:6~9 parts, ACR:0.5~1 part, without lead stabilizer:3~4 parts, titanium dioxide:1.2~2 parts and highly-efficient lubricant:1.0~1.8 parts;B) batch mixing:The raw material prepared in a) step addition high-speed mixer is mixed, first carries out high temperature batch mixing, then carry out low temperature batch mixing, high temperature mixing procedure is:After raw material is warming up to 125 degree with high-speed mixer high-speed friction, low temperature mixing procedure after material temperature drops to 55 degree, compared with prior art, can have good ring stiffness and toughness, pollution-free to cultivation object nonhazardous.

Description

A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening
【Technical field】
The present invention relates to a kind of technical field of fishery cultivating water-supply-pipe, particularly a kind of unleaded PVC-U fishery of toughening Cultivate water transferring line.
【Background technology】
As the improvement of people's living standards, the demand for seafood increasingly increases, and then derive and repaiied on islands and reefs Standardization aquaculture pond is built, carries out industry as sea cucumber cultivation.The industry draws island on seawater using PVC pipeline, carries out scientific Cultivation, can effectively avoid the unexpected incidents such as typhoon, red tide, also referred to as " greenhouse seafood ".PVC drain pipe material is excellent good resistance to because of its Corrosivity, resistance to chemical reagents are excellent, and excellent is acidproof, alkaline-resisting, corrosion-resistant, are not influenced by moist moisture content and soil acidity or alkalinity, and Seawater fishery cultivating system is widely used in, higher requirement is proposed to the physical properties of pipe-line system.It is big at present It measures common PVC drainpipe and is occurring the problems such as discoloration, partially crisp during fishery cultivating use.And high tenacity fishery cultivating water-supply-pipe Material meets some to toughness than high requirement field using the heat stabilizer of asepsis environment-protecting and using excellent toughening formula Use.
Since it is desired that sea-farming, pipe-line system is inevasible has used water transferring line for whole cultivation.The pipeline be by Pumping for water pump is delivered to aquaculture pond to water tower, then by water tower by gravity hydraulic pressure, therefore it is other than needing pressure-bearing, in transmission process In be also subjected to certain external pressure, to prevent transmission process from " inhale flat " phenomenon occur.Again because it is used for culturing marine products, therefore its It requires " unleaded " simultaneously.
【Invention content】
The purpose of the present invention is exactly to solve the problems of the prior art, proposes a kind of unleaded PVC-U fishery cultivatings of toughening Water transferring line can have good ring stiffness, pollution-free to cultivation object nonhazardous.
To achieve the above object, the present invention proposes a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening, including with Lower production stage:
A) prepare raw material:Raw material includes following components and the quality proportioning of each component is:PVC-U resins:100 parts, it is inorganic Filler:5~8 parts, plasticized modifier:6~9 parts, ACR:0.5~1 part, without lead stabilizer:3~4 parts, titanium dioxide:1.2~2 parts And highly-efficient lubricant:1.0~1.8 parts;
B) batch mixing:The raw material prepared in a) step addition high-speed mixer is mixed, first carries out high temperature batch mixing, then Low temperature batch mixing is carried out, high temperature mixing procedure is:After raw material is warming up to 110~125 degree with high-speed mixer high-speed friction, release former Expect stirring at low speed tank, low temperature mixing procedure is:By material stirring at low speed after material temperature drops to 45~55 degree, release raw material and send Toward double screw extruder;
C) it squeezes out:Material in b) step is added in into twin-screw pipe extruder, is then squeezed out from die head, twin-screw tubing squeezes The operating temperature for going out machine is:185~190 DEG C, the temperature of die head is:180~185 DEG C, host vacuum is:0.08MPa;
D) it cools down:The formed pipe of extrusion in c) step is first passed through into one section of room temperature cooling, is then determined with flowing water cooling Type;
E) the tube body spray printing shaped in d) step is identified, cutting.
Preferably, the raw material includes following components and the quality proportioning of each component is:PVC-U resins:100 parts, nothing Machine filler:6.5 parts, plasticized modifier:7.5 parts, ACR:0.8 part, without lead stabilizer:3.5 parts, titanium dioxide:1.6 parts and efficient profit Lubrication prescription:1.4 part.
Preferably, the operating temperature of the twin-screw pipe extruder is:188 DEG C, the temperature of die head is:183℃.
Preferably, the plasticized modifier is ROHM AND HAAS EXL2620.
Preferably, the ACR is ROHM AND HAAS K-400P.
Preferably, the inorganic filler is superfine nano calcium.
Preferably, the highly-efficient lubricant is SX-105 highly-efficient lubricants.
Preferably, the no lead stabilizer is calcium zinc stabilizer.
Beneficial effects of the present invention:1st, leadless environment-friendly reaches asepsis environment-protecting effect;2nd, plasticized modifier tries by a certain percentage Formula is tested, reaches tubing and meets product processing and high tenacity physical property requirements;3rd, it is good so that tubing has for plasticized modifier Ring stiffness and toughness, even if being filtered using vacuum pump, can still keep fixing form well, it is unlikely inhale it is flat;4、 Plasticized modifier and the application of inorganic filler so that tubing has good rolling resistance performance, even if truck rolled, tubing is still Do not break, and can partial reduction reply, do not influence to use.
【Specific embodiment】
A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening of the present invention, includes the following steps:
A) prepare raw material:Raw material includes following components and the quality proportioning of each component is:PVC-U resins:100 parts, it is inorganic Filler:5~8 parts, plasticized modifier:6~9 parts, ACR:0.5~1 part, without lead stabilizer:3~4 parts, titanium dioxide:1.2~2 parts And highly-efficient lubricant:1.0~1.8 parts;
B) batch mixing:The raw material prepared in a) step addition high-speed mixer is mixed, first carries out high temperature batch mixing, then Low temperature batch mixing is carried out, high temperature mixing procedure is:After raw material is warming up to 110~125 degree with high-speed mixer high-speed friction, release former Expect stirring at low speed tank, low temperature mixing procedure is:By material stirring at low speed after material temperature drops to 45~55 degree, release raw material and send Toward double screw extruder;
C) it squeezes out:Material in b) step is added in into twin-screw pipe extruder, is then squeezed out from die head, twin-screw tubing squeezes The operating temperature for going out machine is:185~190 DEG C, the temperature of die head is:180~185 DEG C, host vacuum is:0.08MPa;
D) it cools down:The formed pipe of extrusion in c) step is first passed through into one section of room temperature cooling, is then determined with flowing water cooling Type;
E) the tube body spray printing shaped in d) step is identified, cutting.
Preferably, the raw material includes following components and the quality proportioning of each component is:PVC-U resins:100 parts, nothing Machine filler:6.5 parts, plasticized modifier:7.5 parts, ACR:0.8 part, without lead stabilizer:3.5 parts, titanium dioxide:1.6 parts and efficient profit Lubrication prescription:1.4 part.
The operating temperature of the twin-screw pipe extruder is:188 DEG C, the temperature of die head is:183℃.
The plasticized modifier is ROHM AND HAAS EXL2620.
The ACR is ROHM AND HAAS K-400P.
The inorganic filler is superfine nano calcium.
The highly-efficient lubricant is SX-105 highly-efficient lubricants.
The no lead stabilizer is calcium zinc stabilizer.
Its contrast verification test result:
Above-described embodiment is the description of the invention, is not limitation of the invention, it is any to simple transformation of the present invention after Scheme all belong to the scope of protection of the present invention.

Claims (8)

1. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening, it is characterised in that:Include the following steps:
A) prepare raw material:Raw material includes following components and the quality proportioning of each component is:PVC-U resins:100 parts, inorganic filler: 5~8 parts, plasticized modifier:6~9 parts, ACR:0.5~1 part, without lead stabilizer:3~4 parts, titanium dioxide:1.2~2 parts and efficiently Lubricant:1.0~1.8 parts;
B) batch mixing:The raw material prepared in a) step addition high-speed mixer is mixed, first carries out high temperature batch mixing, then carry out Low temperature batch mixing, high temperature mixing procedure are:Raw material is warming up to 110~125 degree with high-speed mixer high-speed friction, is released to low speed and stirs It mixes in mixing machine;Low temperature mixing procedure is:It is stirred in low speed mixer, after material temperature drops to 45~55 degree, discharging is sent to Production equipment;
C) it squeezes out:Clinker in b) step is added in into twin-screw pipe extruder, is then squeezed out from die head, twin-screw tube extrusion The operating temperature of machine is:185~190 DEG C, the temperature of die head is:180~185 DEG C, host vacuum is:0.08MPa;
D) it cools down:The formed pipe of extrusion in c) step is first passed through into one section of room temperature cooling, then with circulating water cooling and shaping;
E) the tube body spray printing shaped in d) step is identified, cutting.
2. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening as described in claim 1, it is characterised in that:
The raw material includes following components and the quality proportioning of each component is:PVC-U resins:100 parts, inorganic filler:6.5 parts, Plasticized modifier:7.5 parts, ACR:0.8 part, without lead stabilizer:3.5 part, titanium dioxide:1.6 parts and highly-efficient lubricant:1.4 part.
3. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening as described in claim 1, it is characterised in that:
The operating temperature of the twin-screw pipe extruder is:188 DEG C, the temperature of die head is:183℃.
4. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening as described in claim 1, it is characterised in that:
The plasticized modifier is ROHM AND HAAS EXL2620.
5. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening as described in claim 1, it is characterised in that:
The ACR is ROHM AND HAAS K-400P.
6. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening as described in claim 1, it is characterised in that:
The inorganic filler is superfine nano calcium.
7. a kind of unleaded PVC-U fishery cultivatings water transferring line of toughening as described in claim 1, it is characterised in that:
The highly-efficient lubricant is SX-105 highly-efficient lubricants.
8. the unleaded PVC-U fishery cultivatings water transferring line of a kind of toughening as described in any one of claim 1 to 7, feature It is:The no lead stabilizer is calcium zinc stabilizer.
CN201711489778.3A 2017-12-29 2017-12-29 A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening Pending CN108250614A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711489778.3A CN108250614A (en) 2017-12-29 2017-12-29 A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening

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Application Number Priority Date Filing Date Title
CN201711489778.3A CN108250614A (en) 2017-12-29 2017-12-29 A kind of unleaded PVC-U fishery cultivatings water transferring line of toughening

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698733A (en) * 2009-10-28 2010-04-28 河南康泰塑业科技有限公司 Hard polyethylene pipe with high impact resistance
CN104448612A (en) * 2014-11-25 2015-03-25 新疆西部节水科技股份有限公司 High-impact-resistant modified polyvinyl chloride pipe for water supply and preparation method thereof
CN105255048A (en) * 2015-10-30 2016-01-20 永高股份有限公司 Preparation method of high-performance environment-friendly U-PVC (unplasticized-polyvinyl chloride) pipe
CN105778355A (en) * 2016-05-12 2016-07-20 临沂东立塑胶建材有限公司 Low-density anti-impact modified polyvinyl chloride pipe and production process thereof
CN107057224A (en) * 2017-05-04 2017-08-18 南京联塑科技实业有限公司 A kind of high-weatherability energy PVC U drainpipes and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698733A (en) * 2009-10-28 2010-04-28 河南康泰塑业科技有限公司 Hard polyethylene pipe with high impact resistance
CN104448612A (en) * 2014-11-25 2015-03-25 新疆西部节水科技股份有限公司 High-impact-resistant modified polyvinyl chloride pipe for water supply and preparation method thereof
CN105255048A (en) * 2015-10-30 2016-01-20 永高股份有限公司 Preparation method of high-performance environment-friendly U-PVC (unplasticized-polyvinyl chloride) pipe
CN105778355A (en) * 2016-05-12 2016-07-20 临沂东立塑胶建材有限公司 Low-density anti-impact modified polyvinyl chloride pipe and production process thereof
CN107057224A (en) * 2017-05-04 2017-08-18 南京联塑科技实业有限公司 A kind of high-weatherability energy PVC U drainpipes and preparation method thereof

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Application publication date: 20180706

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