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CN108248150A - A kind of Anti-corrosion composite metal material - Google Patents

A kind of Anti-corrosion composite metal material Download PDF

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Publication number
CN108248150A
CN108248150A CN201810089389.XA CN201810089389A CN108248150A CN 108248150 A CN108248150 A CN 108248150A CN 201810089389 A CN201810089389 A CN 201810089389A CN 108248150 A CN108248150 A CN 108248150A
Authority
CN
China
Prior art keywords
corrosion
composite metal
metal material
corrosion composite
silicon carbide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810089389.XA
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Chinese (zh)
Inventor
曹凌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baoji University of Arts and Sciences
Original Assignee
Baoji University of Arts and Sciences
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Filing date
Publication date
Application filed by Baoji University of Arts and Sciences filed Critical Baoji University of Arts and Sciences
Priority to CN201810089389.XA priority Critical patent/CN108248150A/en
Publication of CN108248150A publication Critical patent/CN108248150A/en
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/18—Layered products comprising a layer of metal comprising iron or steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/208—Magnetic, paramagnetic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/302—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion

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  • Soft Magnetic Materials (AREA)

Abstract

The invention discloses a kind of Anti-corrosion composite metal materials, are including weight percent shared by following component and each component：Ti0.5 1.1%, Al22 29%, Ru1.1 2.1%, Mn0.5 1.1%, Ni3.2 6%, Y1.5 3%, Cu2.0 3.5%, V0.01 0.03%, Zn3 9%, Sn1 6%, silicon carbide 0.05 0.5%, Sb0.2 0.4%, remaining is Fe.The material is based on iron, carbon is to improve the intensity of material and toughness in other compositions, and silicon is to deoxidation, and manganese is improving toughness of material, nickel is improving magnetic characteristic, antimony is to improve the tension of material surface and viscosity, the cooperation of Determination of multiple metal elements, improves the electric conductivity and thermal conductivity of material, reduce hardenability, intensity is high, anti-oxidant, corrosion-resistant, heat-resisting, mechanical performance and good mechanical performance.

Description

A kind of Anti-corrosion composite metal material
Technical field
The present invention relates to technical field of metal material, more particularly to a kind of Anti-corrosion composite metal material.
Background technology
Composite material is a kind of mixture.Very big effect is all played in many fields, instead of many traditional materials Material.Composite material by its composition be divided into metal and metallic composite, it is nonmetallic with metallic composite, it is nonmetallic with it is nonmetallic Composite material.With common single enhancing phase composite materials ratio, impact strength, fatigue strength and fracture toughness significantly improve, and have There is special hot expansibility.Be divided into interlaminar hybrid, interlayer mixes, sandwich mixes, in layer/interlayer mixes and surpasses hybrid composite manner material Material.It composite material sixties, to meet the needs of the sophisticated technologies material therefor such as aerospace, successively develops and produces with height Performance fibers are the composite material of reinforcing material.In order to be distinguished with first generation galss fiber reinforced resin composite material, by this Kind composite material is known as advanced composite material.Advanced composite material also acts as functional material, still in addition to as structural material These material corrosion resistances are poor.
Invention content
The object of the present invention is to provide a kind of Anti-corrosion composite metal material, to solve mentioned above in the background art ask Topic.
The present invention provides a kind of Anti-corrosion composite metal material, including weight percent shared by following component and each component For：Ti0.5-1.1%, Al 22-29%, Ru 1.1-2.1%, Mn 0.5-1.1%, Ni 3.2-6%, Y 1.5-3%, Cu2.0-3.5%, V0.01-0.03%, Zn3-9%, Sn1-6%, silicon carbide 0.05-0.5%, Sb 0.2-0.4%, remaining is Fe。
Preferably, it is including weight percent shared by following component and each component：Ti0.65-0.9%, Al24-26%, Ru 1.35-1.85%, Mn 0.65-0.85%, Ni 4.5-5.5%, Y 2.0-2.5%, Cu2.5-3.0%, V0.015- 0.025%th, Zn4.5-7.5%, Sn2.5-4.5%, silicon carbide 0.15-0.4%, Sb0.25-0.35%, remaining is Fe.
Preferably, further including 2~10% nano-particles, the nano-particle includes nano nickle granules and nanometer zirconium particle.
Preferably, further including resin layer, the resin layer is arranged on the surface layer of corrosion-resistant complex metal layer.
Preferably, the resin layer is polyethylene, polyvinyl chloride, polystyrene, polypropylene one kind therein.
The beneficial effects of the invention are as follows：
A kind of Anti-corrosion composite metal material provided by the invention, using iron as main component, carbon is carrying in other compositions The intensity and toughness of high material, silicon is to deoxidation, and manganese is to improve toughness of material, and nickel is to improve magnetic characteristic, and antimony is improving The tension and viscosity of material surface, the cooperation of Determination of multiple metal elements improve the electric conductivity and thermal conductivity of material, reduce quenching Property, intensity is high, anti-oxidant, corrosion-resistant, heat-resisting, mechanical performance and good mechanical performance.
Specific embodiment
Using furnace melting, processing step is a kind of Anti-corrosion composite metal material of the present invention：
(1) furnace melting：Fe, Al, Mn, Ni, Zn, Sn are added in smelting furnace melting, graphite rod stirring 15 under nitrogen protection After~25min, it is temperature melting into alloy molten solution to add in Ti, Ru, Y, Cu, V, silicon carbide and Sb raisings；
(2) converter refining：Alloy molten solution is transferred to refining furnace, is refined 10~12 hours at 1050~1250 DEG C, treats miscellaneous gas After the complete emersion melt liquid level of dregs, it is filtered to remove impurity；
(3) cast molding：The alloy molten solution refined after cleaning is cast into rotor parison；
(4) it is heat-treated：The metal material was obtained in 1.5~2.5 hours in 1650~1800 DEG C of heat treatments to rotor parison.
Embodiment 1
The present invention is made of following weight percent composition, Ti0.5%, Al 22%, Ru 1.1%, Mn 0.5%, Ni 3.2%th, Y 1.5%, Cu2.0%, V0.01%, Zn3%, Sn1%, silicon carbide 0.05%, Sb 0.2%, remaining is Fe.
Embodiment 2
Ti1.1%, Al29%, Ru 2.1%, Mn 1.1%, Ni 6%, Y 3%, Cu3.5%, V0.03%, Zn3- 9%th, Sn6%, silicon carbide 0.5%, Sb 0.4%, remaining is Fe.
Embodiment 3
Ti0.65%, Al 24%, Ru 1.4%, Mn 0.7%, Ni 4.5%, Y 1.8%, Cu2.4%, V0.015%, Zn5.0%, Sn3.5%, silicon carbide 0.25%, Sb 0.25%, remaining is Fe.
Embodiment 4
Ti0.85%, Al 27%, Ru 1.8%, Mn 0.9%, Ni 5.5%, Y 2.5%, Cu3.0%, V0.025%, Zn7.0%, Sn5.5%, silicon carbide 0.45%, Sb 0.35%, remaining is Fe.
Embodiment 5
Ti0.7%, Al 25.5%, Ru 1.6%, Mn 0.8%, Ni 5.0%, Y 2.0%, Cu2.7%, V0.02%, Zn6.0%, Sn4.0%, silicon carbide 0.30%, Sb 0.30%, remaining is Fe.
Embodiment 6 is Fe for the raw material of the Anti-corrosion composite metal material
Following table is Anti-corrosion composite metal material parameter
From above-mentioned table 1 as can be seen that using Anti-corrosion composite metal material made from 1-5 methods of the embodiment of the present invention Indices are better than the 6th group of material, illustrate that corrosion resistance and wearability are good using material made from raw material of the present invention, Intensity and toughness height, ductility are good.
In conclusion a kind of Anti-corrosion composite metal material provided in an embodiment of the present invention, using iron as main component, other Carbon is to improve the intensity of material and toughness in ingredient, and silicon is to deoxidation, and for manganese to improve toughness of material, nickel is special to improve magnetic Property, for antimony to improve the tension of material surface and viscosity, the cooperation of Determination of multiple metal elements improves electric conductivity and the heat conduction of material Property, hardenability is reduced, intensity is high, anti-oxidant, corrosion-resistant, heat-resisting, mechanical performance and good mechanical performance.
Disclosed above is only several specific embodiments of the present invention, and still, the embodiment of the present invention is not limited to this, is appointed What what those skilled in the art can think variation should all fall into protection scope of the present invention.

Claims (5)

1. a kind of Anti-corrosion composite metal material, which is characterized in that be including weight percent shared by following component and each component： Ti0.5-1.1%, Al 22-29%, Ru 1.1-2.1%, Mn 0.5-1.1%, Ni 3.2-6%, Y 1.5-3%, Cu2.0- 3.5%th, V0.01-0.03%, Zn3-9%, Sn1-6%, silicon carbide 0.05-0.5%, Sb 0.2-0.4%, remaining is Fe.
2. Anti-corrosion composite metal material as described in claim 1, which is characterized in that including shared by following component and each component Weight percent is：Ti0.65-0.9%, Al 24-26%, Ru 1.35-1.85%, Mn 0.65-0.85%, Ni 4.5- 5.5%th, Y 2.0-2.5%, Cu2.5-3.0%, V0.015-0.025%, Zn4.5-7.5%, Sn2.5-4.5%, silicon carbide 0.15-0.4%, Sb0.25-0.35%, remaining is Fe.
3. Anti-corrosion composite metal material as described in claim 1, which is characterized in that further include 2~10% nano-particles, institute It states nano-particle and includes nano nickle granules and nanometer zirconium particle.
4. Anti-corrosion composite metal material as described in claim 1, which is characterized in that further include resin layer, the resin layer It is arranged on the surface layer of corrosion-resistant complex metal layer.
5. Anti-corrosion composite metal material as claimed in claim 4, which is characterized in that the resin layer is polyethylene, polychlorostyrene Ethylene, polystyrene, polypropylene one kind therein.
CN201810089389.XA 2018-01-30 2018-01-30 A kind of Anti-corrosion composite metal material Pending CN108248150A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810089389.XA CN108248150A (en) 2018-01-30 2018-01-30 A kind of Anti-corrosion composite metal material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810089389.XA CN108248150A (en) 2018-01-30 2018-01-30 A kind of Anti-corrosion composite metal material

Publications (1)

Publication Number Publication Date
CN108248150A true CN108248150A (en) 2018-07-06

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102899570A (en) * 2011-07-27 2013-01-30 株式会社神户制钢所 Steel material with excellent corrosion resistance for tank upper deck of crude oil tanker or for hold of bulk carrier
CN103562428A (en) * 2011-05-25 2014-02-05 新日铁住金株式会社 Cold-rolled steel sheet and method for producing same
CN105401030A (en) * 2015-11-10 2016-03-16 太仓捷公精密金属材料有限公司 Anti-corrosion titanium-magnesium alloy material
CN105441803A (en) * 2015-12-30 2016-03-30 太仓卡斯特姆新材料有限公司 Corrosion-resistant composite metal material
CN106739285A (en) * 2016-11-23 2017-05-31 重庆动沃机车产业有限公司 A kind of composite material
CN106868354A (en) * 2017-02-24 2017-06-20 玉林博飞商贸有限公司 A kind of Anti-corrosion composite metal material and preparation method thereof
CN107034419A (en) * 2017-06-21 2017-08-11 合肥博创机械制造有限公司 A kind of corrosion-resistant metal materials and its production technology

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103562428A (en) * 2011-05-25 2014-02-05 新日铁住金株式会社 Cold-rolled steel sheet and method for producing same
CN102899570A (en) * 2011-07-27 2013-01-30 株式会社神户制钢所 Steel material with excellent corrosion resistance for tank upper deck of crude oil tanker or for hold of bulk carrier
CN105401030A (en) * 2015-11-10 2016-03-16 太仓捷公精密金属材料有限公司 Anti-corrosion titanium-magnesium alloy material
CN105441803A (en) * 2015-12-30 2016-03-30 太仓卡斯特姆新材料有限公司 Corrosion-resistant composite metal material
CN106739285A (en) * 2016-11-23 2017-05-31 重庆动沃机车产业有限公司 A kind of composite material
CN106868354A (en) * 2017-02-24 2017-06-20 玉林博飞商贸有限公司 A kind of Anti-corrosion composite metal material and preparation method thereof
CN107034419A (en) * 2017-06-21 2017-08-11 合肥博创机械制造有限公司 A kind of corrosion-resistant metal materials and its production technology

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Application publication date: 20180706