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CN108181286A - Water tank with real-time pesticide monitoring function by adopting three-dimensional fluorescence technology - Google Patents

Water tank with real-time pesticide monitoring function by adopting three-dimensional fluorescence technology Download PDF

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Publication number
CN108181286A
CN108181286A CN201810105273.0A CN201810105273A CN108181286A CN 108181286 A CN108181286 A CN 108181286A CN 201810105273 A CN201810105273 A CN 201810105273A CN 108181286 A CN108181286 A CN 108181286A
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CN
China
Prior art keywords
dimensional fluorescence
water
detection device
real
connect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810105273.0A
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Chinese (zh)
Inventor
李军
倪永炯
陈涛
钱佩忠
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Zhejiang University of Technology ZJUT
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Zhejiang University of Technology ZJUT
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Priority to CN201810105273.0A priority Critical patent/CN108181286A/en
Publication of CN108181286A publication Critical patent/CN108181286A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64Fluorescence; Phosphorescence
    • G01N21/6402Atomic fluorescence; Laser induced fluorescence
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation

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  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Optics & Photonics (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

A water tank with a real-time pesticide monitoring function by adopting a three-dimensional fluorescence technology comprises a support frame and a tank body, wherein the tank body is arranged on the support frame, and the water tank also comprises a real-time pesticide monitoring system and an automatic control device; the real-time pesticide monitoring system comprises a sampling device, a pretreatment device, a three-dimensional fluorescence detection device, a discharge device, a back washing device and a result feedback device, wherein the sampling device, the pretreatment device, the three-dimensional fluorescence detection device, the discharge device, the back washing device and the result feedback device are all connected with the automatic control device, and the result feedback device comprises a display and a sound alarm which are arranged on a support frame. The invention provides a water tank which is efficient, rapid and low-cost and has a real-time pesticide monitoring function by adopting a three-dimensional fluorescence technology.

Description

A kind of sink using three-dimensional fluorescence technology with real-time pesticide monitoring function
Technical field
The invention belongs to environmental monitorings, are monitored more particularly, to a kind of using three-dimensional fluorescence technology with real-time pesticide The sink of function.
Background technology
With the continuous social and economic development, problem of environmental pollution getting worse, requirement of the people to living environment are more next Higher, especially food-safe problem is increasingly paid attention to.Pesticide residue is always the emphasis of environmental monitoring and field of food safety. The development of agriculture industrialization makes the production of agricultural product be increasingly dependent on the allogenic materials such as pesticide, antibiotic and hormone.China's agriculture Medicine remains high in the dosage of agricultural product, and the unreasonable use of these substances will cause the pesticide residue in agricultural product to surpass Mark, influences consumer's edible safety, and consumer can be made to cause a disease when serious, develop abnormal or even directly result in and be poisoned to death.Mesh Before, more and more researchs are just unfolded in the field, and the technology that exploitation safely and fast carries out Detecting Pesticide is increasingly urgent.
The correlation technique type for carrying out Detecting Pesticide at present is various, studies carefully and two major class are broadly divided into for its principle:It is raw Change measuring method and chromatographic detection.Detection method such as gas chromatography-mass spectrography, chemical fast determining method, immunoassay traditional at present Some test in laboratory methods such as method, enzyme inhibition, In vivo detection method accurate can measure persticide residue and type, but There is also all kinds of problems such as of high cost, detection time length, are only suitable only for preferable, in profession in conditions such as laboratories It can be just detected under technical staff's operation, and these methods generate sample damage or to consume other a large amount of auxiliary materials Material.Fluorescent technique principle is after Cucumber is excited by the light of certain wavelength, (10 in very short time-8Second) wavelength can be launched More than the light of excitation wavelength, this light is known as fluorescence, these fluorescence can be detected acquisition and record.Theoretically each fluorescence Substance has specific launch wavelength and excitation wavelength, and the type of substance is may determine that according to fluorescence peak position and fluorescence intensity And content.Three-dimensional fluorescence technology be exactly according to parametric synthesis such as excitation wavelength, launch wavelength, fluorescence intensities and come one kind it is novel Fluorescent technique, have the characteristics that it is quick, lossless, without material consumption, at present in necks such as oil exploration, food and medicine analysis, drinks identifications Domain, which has been carried out, widely applies and achieves preferable effect.Research shows that a large amount of pesticide is fluorescence organic matter, have apparent Fluorescent characteristics.
Invention content
For the time-consuming, specialized of the residual monitoring of existing agriculture is overcome to require the realistic problems such as high, of high cost, the present invention provides one kind Efficiently, the sink using three-dimensional fluorescence technology with real-time pesticide monitoring function quickly, inexpensive.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of sink using three-dimensional fluorescence technology with real-time pesticide monitoring function, it is described including supporting rack and groove body Groove body is arranged on support frame as described above, and the sink further includes real-time pesticide monitoring system and automaton;
The real-time pesticide monitoring system includes sampler, pretreatment unit, three-dimensional fluorescence detection device, discharge dress It puts, back purge system and result feedback device, the sampler, pretreatment unit, three-dimensional fluorescence detection device, discharge fill Put, back purge system and result feedback device are connect with the automaton, the result feedback device include setting Display and voice guard on supporting rack;
The bottom of the groove body is equipped with and washes rear water sampling mouth and water-trough outlet, the water-trough outlet and sink drain Connection, described to wash rear water sampling mouth and connect by water inlet pipe with the sampler, the sampler pre-processes dress with described Connection is put, the pretreatment unit is connect with the three-dimensional fluorescence detection device, and the three-dimensional fluorescence detection device is filled with discharge Connection is put, the tapping equipment is connect by outlet pipe with the sink drain;The back purge system and the pretreatment Device, the connection of three-dimensional fluorescence detection device;
Sampler automatic sampling, and water sample is sent to pretreatment unit and is pre-processed, three-dimensional is delivered to after pretreatment Fluorescence detection device is detected, and is discharged after water sample detection by tapping equipment, and the back purge system is after each sample detection Floating cuvette and its related pipeline to pretreatment unit, three-dimensional fluorescence detection device are rinsed;Detection data passes through certainly Dynamic control device is analyzed and processed and by result feedback device feedback result.
Further, the sampler includes sampling pump and sampling line, and the pretreatment unit includes 0.45 micron of mistake Filter membrane and small peristaltic pump, three-dimensional fluorescence detection device include fluorescence detecting system and floating cuvette, are set on floating cuvette There are one water inlets and a water outlet, the water inlet of the floating cuvette to connect with the small peristaltic pump, the flowing The water outlet of cuvette is connect with tapping equipment, and water sample is transported to after the pretreatment of 0.45 Mm filter film by small peristaltic pump It floating cuvette and is detected by fluorescence detecting system;
The back purge system includes backwashing pump and water purification storage bottle, and the water purification storage bottle connects with the backwashing pump It connects, the backwashing pump is connect with the floating cuvette of 0.45 Mm filter film, three-dimensional fluorescence detection device;Backwashing pump utilizes Water in water purification storage bottle rushes the floating cuvette of pretreatment unit, three-dimensional fluorescence detection device and its related pipeline It washes.
Further, the sampler, pretreatment unit, three-dimensional fluorescence detection device, tapping equipment, back purge system It is integrated in automaton in a babinet.
The present invention technical concept be:
Sink be people life in common life tool, be washing, clean vegetables indispensable tool, by sink and Pesticides Testing Technology combines, and effectively can easily and efficiently ensure food safety in daily life;Three-dimensional fluorescence technology can be fast Speed measures the content of the substance with fluorescence property, and most of existing pesticide has fluorescent characteristic, can be examined by three-dimensional fluorescence It surveys and captures;Three-dimensional fluorescence technology is a kind of non-destructive testing technology, does not introduce other chemical detection medicaments, will not be to this life of food It generates and destroys or increase food safety hazard;Real-time display testing result and sending out voice alarm can allow people intuitive The clean level and edible safety that judge food.
Beneficial effects of the present invention are mainly manifested in:
(1) it is easy to operate, it is at low cost, it only needs to be cleaned the step of routinely cleaning food, it is numerous and diverse not to increase other Highly professional operation;
(2) it is at low cost, securely and reliably, other chemical detection medicaments are not introduced, three-dimensional fluorescence, will not be right as non-destructive testing Food generates any destruction or increase food safety hazard;
(3) integrated level is high, feed back it is readable strong, without professional knowledge, detection data by automaton at Reason, and pass through Relational database and be compared and judge, the result of feedback is readable strong, and only common everyday knowledge can be made Judge.
Description of the drawings
Fig. 1 is the structure diagram of the present invention
Fig. 2 is the functional flow diagram of the present invention
Specific embodiment
The invention will be further described below in conjunction with the accompanying drawings.
Referring to Figures 1 and 2, a kind of sink using three-dimensional fluorescence technology with real-time pesticide monitoring function, including groove body 4th, supporting rack 5, real-time pesticide monitoring system and automaton, rear water sampling mouth 41 is washed in 4 bottom of the groove body setting, described Real-time pesticide monitoring system is anti-by sampler, pretreatment unit, monitoring system body, tapping equipment, back purge system, result Compositions, the samplers such as feedback device are made of sampling pump and attached sampling line, and the pretreatment unit is by 0.45 micron Filter membrane, small peristaltic pump and attached pipeline composition, the monitoring system body is by three-dimensional fluorescence detection device, floating cuvette It is made of with attached pipeline composition, the back purge system backwashing pump, water purification storage bottle and attached pipeline, the result feedback Device is made of the display 8, voice guard 7 and accessory being arranged on supporting rack 5, the sampler, pretreatment Device, monitoring system body, tapping equipment, back purge system are integrated in babinet 6.Water after food cleaning passes through water inlet pipe 1 It pre-processed, detected after into integrating device, being discharged etc. after processes by outlet pipe 2 by being arranged outside sink drain 3, detection knot Fruit is handled by internal automaton and passes through result feedback device feedback result.Water after extra food cleaning is by water The water-trough outlet 42 of trench bottom is discharged through sink drain 3.
The display and voice guard of the result feedback device make feedback according to pesticide residue value height is measured.Institute Automaton is stated to be automatically controlled and information processing by the cruise Control Module completion comprising Pesticides Testing identification database.
The time that real-time pesticide monitoring system carries out one-time detection is within 2-3 minutes.
Specific test result:It using the cowpea of market stochastic buying, is cleaned using the sink of the present invention, in routinely cleaning the The exceeded prompting of pesticide is obtained during one time and second time, and passes through voice guard and display is alarmed, Pesticide prompting up to standard is shown when cleaning third time.
The present invention realizes quick, lossless, inexpensive food pesticide monitoring, has ensured food security.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that:Not In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, this The range of invention is limited by claim and its equivalent.

Claims (3)

1. a kind of sink using three-dimensional fluorescence technology with real-time pesticide monitoring function, including supporting rack and groove body, the slot Body is arranged on support frame as described above, it is characterised in that:The sink further includes real-time pesticide monitoring system and automaton;
The real-time pesticide monitoring system includes sampler, pretreatment unit, three-dimensional fluorescence detection device, tapping equipment, anti- Flusher and result feedback device, the sampler, pretreatment unit, three-dimensional fluorescence detection device, tapping equipment, recoil Cleaning device and result feedback device are connect with the automaton, and the result feedback device includes being arranged on supporting rack On display and voice guard;
The bottom of the groove body, which is equipped with, washes rear water sampling mouth and water-trough outlet, and the water-trough outlet connects with sink drain It connects, described to wash rear water sampling mouth and connect by water inlet pipe with the sampler, the sampler and the pretreatment unit Connection, the pretreatment unit are connect with the three-dimensional fluorescence detection device, the three-dimensional fluorescence detection device and tapping equipment Connection, the tapping equipment are connect by outlet pipe with the sink drain;The back purge system is filled with the pretreatment It puts, the connection of three-dimensional fluorescence detection device;
Sampler automatic sampling, and water sample is sent to pretreatment unit and is pre-processed, three-dimensional fluorescence is delivered to after pretreatment Detection device is detected, and is discharged after water sample detection by tapping equipment, and the back purge system is after each sample detection to pre- Processing unit, the floating cuvette of three-dimensional fluorescence detection device and its related pipeline are rinsed;Detection data by controlling automatically Device processed is analyzed and processed and by result feedback device feedback result.
2. a kind of sink using three-dimensional fluorescence technology with real-time pesticide monitoring function as described in claim 1, feature It is:The sampler includes sampling pump and sampling line, and the pretreatment unit includes 0.45 Mm filter film and small-sized Peristaltic pump, three-dimensional fluorescence detection device include fluorescence detecting system and floating cuvette, set that there are one intake on floating cuvette Mouth and a water outlet, the water inlet of the floating cuvette are connect with the small peristaltic pump, and the floating cuvette goes out The mouth of a river is connect with tapping equipment, and water sample is transported to floating cuvette after the pretreatment of 0.45 Mm filter film by small peristaltic pump And it is detected by fluorescence detecting system;
The back purge system includes backwashing pump and water purification storage bottle, and the water purification storage bottle is connect with the backwashing pump, The backwashing pump is connect with the floating cuvette of 0.45 Mm filter film, three-dimensional fluorescence detection device;Backwashing pump is using only Water in water storage bottle is rinsed the floating cuvette of pretreatment unit, three-dimensional fluorescence detection device and its related pipeline.
3. a kind of sink using three-dimensional fluorescence technology with real-time pesticide monitoring function as claimed in claim 1 or 2, special Sign is:It the sampler, pretreatment unit, three-dimensional fluorescence detection device, tapping equipment, back purge system and automatically controls Device is integrated in a babinet.
CN201810105273.0A 2018-02-02 2018-02-02 Water tank with real-time pesticide monitoring function by adopting three-dimensional fluorescence technology Pending CN108181286A (en)

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CN201810105273.0A CN108181286A (en) 2018-02-02 2018-02-02 Water tank with real-time pesticide monitoring function by adopting three-dimensional fluorescence technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810105273.0A CN108181286A (en) 2018-02-02 2018-02-02 Water tank with real-time pesticide monitoring function by adopting three-dimensional fluorescence technology

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CN108181286A true CN108181286A (en) 2018-06-19

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110793948A (en) * 2019-11-07 2020-02-14 中国计量大学 Water body heavy metal ion detection system based on graphene quantum dot sensor
CN112014368A (en) * 2020-08-24 2020-12-01 安徽思环科技有限公司 Novel light path system for water quality three-dimensional fluorescence monitoring system

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CN205719950U (en) * 2016-05-05 2016-11-23 潍坊汇海农产品检测有限公司 A kind of food Pesticides Testing instrument
CN206258448U (en) * 2016-12-16 2017-06-16 南京菜宝宝智能科技有限公司 Purification system capable of monitoring and prompting purification efficiency in real time
CN206434231U (en) * 2016-07-13 2017-08-25 佛山市悍高厨具设备有限公司 A kind of purging system of quick detection vegetable pesticide residue

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003126855A (en) * 2001-10-26 2003-05-07 Toshiba Corp Membrane filter system
DE102005048187A1 (en) * 2005-10-02 2007-04-12 Technische Universität Dresden Mechanism for the determination of paracellular and transcellular permeabilities of cell cultures, comprises filter mechanism, fluorescent marker, fluorescence photometer, level measurer, pump, impedance spectrometer and computer system
CN201251569Y (en) * 2008-08-26 2009-06-03 上海雷磁环保工程有限公司 On-line monitoring system of chemical oxygen demand
CN102901721A (en) * 2012-10-17 2013-01-30 中国环境科学研究院 Method for quickly determining flow direction of groundwater polluted by organic matter
CN103245644A (en) * 2013-03-27 2013-08-14 中国科学院安徽光学精密机械研究所 Quick detecting device and method of toxic and harmful organic chemical pollutants in water body
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CN103969235A (en) * 2014-04-30 2014-08-06 浙江工业大学 Quick pre-warning method for organic pollution of surface water
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CN205719950U (en) * 2016-05-05 2016-11-23 潍坊汇海农产品检测有限公司 A kind of food Pesticides Testing instrument
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CN206258448U (en) * 2016-12-16 2017-06-16 南京菜宝宝智能科技有限公司 Purification system capable of monitoring and prompting purification efficiency in real time

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110793948A (en) * 2019-11-07 2020-02-14 中国计量大学 Water body heavy metal ion detection system based on graphene quantum dot sensor
CN110793948B (en) * 2019-11-07 2022-02-15 中国计量大学 Water body heavy metal ion detection system based on graphene quantum dot sensor
CN112014368A (en) * 2020-08-24 2020-12-01 安徽思环科技有限公司 Novel light path system for water quality three-dimensional fluorescence monitoring system

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Application publication date: 20180619

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