CN108046598A - A kind of doubling glass and its processing technology - Google Patents
A kind of doubling glass and its processing technology Download PDFInfo
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- CN108046598A CN108046598A CN201711361591.5A CN201711361591A CN108046598A CN 108046598 A CN108046598 A CN 108046598A CN 201711361591 A CN201711361591 A CN 201711361591A CN 108046598 A CN108046598 A CN 108046598A
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- glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The invention discloses a kind of doubling glass and its processing technology, including glassy layer and hollow layer, it is characterised in that:Glassy layer includes the first glassy layer and the second glassy layer, hollow layer is provided between first glassy layer and the second glassy layer, glue is filled with inside the hollow layer, the glassy layer is made of 85% batch and 15% cullet, and the batch includes the component of following ratio meter by weight:52.5~57.5 parts of quartz sand, 15.6~16.6 parts of soda ash, 5.5~6.1 parts of saltcake, 9.8~10.8 parts of lime stone, 4.2~4.8 parts of fluorite, 2.6~3.2 parts of sodium nitrate, 0.3~0.9 part of nickel oxide and 4.5~5.1 parts of charcoal powder;The present invention also provides a kind of processing technology of the doubling glass, concrete operation step is:Step 1:Prepare glass:1st, batch and cullet are stirred evenly using batch mixer.While the present invention provides glass formula, manufacture craft is also simplified, substantially increases production efficiency, it is easy to spread.
Description
Technical field
The present invention relates to glass production manufacturing technology field, more particularly to a kind of doubling glass and its processing technology.
Background technology
Glass is fused together by silica and other chemical substances, and contiguous network structure is formed in melting, cold
But process medium viscosity gradually increases and hardens the silicates nonmetallic materials that it is caused to crystallize, and is widely used in daily production life
Every aspect living.At present, doubling glass is that current building and automotive field are widely used " safety glass ", typically two
One common PVB (Polyvinylbutyral, polyvinyl butyral) film of clamping among sheet glass.Doubling glass it is excellent
Point is can be antitheft, explosion-proof, shellproof and to stop ultraviolet light etc., and shortcoming is cannot to stop that infrared ray penetrates in doubling glass, is caused
Energy-saving effect is poor.
Therefore, it is necessary to solve the above problems that a kind of doubling glass and its processing technology are invented.
The content of the invention
It is an object of the invention to provide a kind of doubling glass and its processing technology, to solve to propose in above-mentioned background technology
The problem of.
To achieve the above object, the present invention provides following technical solution:A kind of doubling glass, including glassy layer and hollow
Layer, the glassy layer include the first glassy layer and the second glassy layer, are provided between first glassy layer and the second glassy layer
Hollow layer, the hollow layer inside is filled with glue, and the glassy layer is made of 85% batch and 15% cullet, institute
Stating batch includes the component of following ratio meter by weight:52.5~57.5 parts of quartz sand, 15.6~16.6 parts of soda ash,
5.5~6.1 parts of saltcake, 9.8~10.8 parts of lime stone, 4.2~4.8 parts of fluorite, 2.6~3.2 parts of sodium nitrate, 0.3
~0.9 part of nickel oxide and 4.5~5.1 parts of charcoal powder;
The present invention also provides a kind of processing technology of the doubling glass, concrete operation step is:
Step 1:Prepare glass:
(1) batch and cullet are stirred evenly using batch mixer;
(2) raw material after being sufficiently mixed is poured into melt stove be heated to molten state heat preservation it is spare;
(3) melting charge is imported and glass plate is made in mold slots;
(4) annealing cooling is carried out to the formed glass plate in mold slots;
(5) rounded corner processing is carried out to the just angle of formed glass plate after cooling;
Step 2:Prepare doubling glass glue:Polyvinyl butyral resin, coupling agent and plasticizer are sufficiently mixed
Viscous liquid is made;
Step 3:Fixed glass:The formed glass plate Boards wall in step 1 is taken, and makes two pieces of glass plates relatively flat
Row is set;
Step 4:Edge sealing:Edge sealing is carried out to the surrounding of glass plate with adhesive tape, makes to form cavity between two pieces of glass plates;
Step 5:It vacuumizes:A gum-injecting port is opened in the top adhesive tape between connecting two pieces of glass plates, and pass through will be interior
Portion's cavity is evacuated;
Step 6:Encapsulating:Glass glue in step 2 is injected into the vacuum chamber between glass plate, fills up cavity;
Step 7:Sealing cures:Gum-injecting port is sealed with adhesive tape, then cures light irradiation encapsulating glass plate with shadowless glue;
Step 8:Remaining glue processing:The glue for overflowing glass plate corner location after adhesive tape is removed to handle
Preferably, mixture homogeneity >=98% of the batch and cullet.
Preferably, the melting temperature of (2) is arranged to 1400~1500 DEG C in the step 1.
Preferably, the annealing cooling temperature of (4) is arranged to 530~580 DEG C in the step 1.
Preferably, the coupling agent is using titanate esters or chromium complex, and the plasticizer is using triethylene glycol two
Tricaprylate.
Preferably, what the shadowless glue cure lamp was launched is ultraviolet light of the wavelength between 320~400nm.
Preferably, the adhesive tape is made of soft rubber.
The technique effect and advantage of the present invention:
1st, using shadowless glue cure lamp launch to be wavelength irradiate encapsulating glass plate between the ultraviolet light of 320~400nm,
Curing rate can be greatly speeded up, it is only necessary to curing can be completed within several seconds to tens seconds, and solidification temperature is low, greatlys save the energy and disappears
Consumption;
2nd, vacuumize process is carried out to doubling glass hollow layer before injecting glue, the gas in hollow layer can be excluded to injecting glue quality
Influence, so as to improve the degree of adhesion between glue and glassy layer;
3rd, the sulfur dioxide generated during preparing sodium metasilicate using saltcake and quartz sand reaction carries out glass solution
Decoloration, with reinforcing glass product translucency;
4th, by adding in fluorite in batch, due to fluorite crystal structure exist " cavity ", it is easy to by other from
Son filling can combine the coloured ion in dispensing, so that glass carries various colors, improve the aesthetic feeling of glassware;
5th, by adding in nickel oxide in batch, available for absorbing infrared ray and some visible light, to prevent strong light, strong
Heat or radiation transparent and protect personal safety.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention;
Fig. 2 is the process flow chart of the present invention;
In figure:1 glassy layer, 11 first glassy layers, 12 second glassy layers, 2 hollow layers.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work
Embodiment belongs to the scope of protection of the invention.
Embodiment 1:
A kind of doubling glass according to figure 1, including glassy layer 1 and hollow layer 2, the glassy layer 1 includes the first glass
11 and second glassy layer 12 of glass layer is provided with hollow layer 2 between 11 and second glassy layer 12 of the first glassy layer, described hollow
2 inside of layer is filled with glue, and the glassy layer 1 is made of 85% batch and 15% cullet, and the batch includes
The component of following ratio meter by weight:52.5 parts of quartz sand, 16.6 parts of soda ash, 6.1 parts of saltcake, 10.8 parts of lime
Stone, 4.8 parts of fluorite, 3.2 parts of sodium nitrate, 0.9 part of nickel oxide and 5.1 parts of charcoal powder.
According to a kind of processing technology of doubling glass shown in Fig. 2, concrete operation step is:
Step 1:Prepare glass:
(1) batch and cullet are stirred evenly using batch mixer, and the mixture homogeneity of batch and cullet >=
98%, to improve the quality of glassware;
(2) raw material after being sufficiently mixed is poured into melt stove, temperature is controlled at 1400 DEG C, makes mixed material heating extremely
Molten state heat preservation is spare;
(3) melting charge is imported and glass plate is made in mold slots;
(4) temperature is controlled at 530 DEG C, annealing cooling then is carried out to the formed glass plate in mold slots;
(5) rounded corner processing is carried out to the just angle of formed glass plate after cooling, avoids later stage sealing and the processing of remaining glue
Occurs situation about scratching in the process, to improve the upper safety of the people of operating personnel;
Step 2:Prepare doubling glass glue:Polyvinyl butyral resin, coupling agent and plasticizer are sufficiently mixed
Viscous liquid is made, wherein coupling agent, so as to reduce the viscosity of synthetic resin, improves using titanate esters or chromium complex
The dispersion degree of filler is to improve processing performance, and plasticizer can make the soft of glue using two tricaprylate of triethylene glycol
Toughness enhances, and easy to process;
Step 3:Fixed glass:The formed glass plate Boards wall in step 1 is taken, and makes two pieces of glass plates relatively flat
Row is set;
Step 4:Edge sealing:Adhesive tape carries out edge sealing to the surrounding of glass plate made of soft rubber, to ensure in hollow layer
Air-tightness, make to form cavity between two pieces of glass plates;
Step 5:It vacuumizes:A gum-injecting port is opened in the top adhesive tape between connecting two pieces of glass plates, and pass through will be interior
Portion's cavity is evacuated, and can exclude influence of the gas to injecting glue quality in hollow layer 2, so as to improve glue and glassy layer 1 it
Between degree of adhesion;
Step 6:Encapsulating:Glass glue in step 2 is injected into the vacuum chamber between glass plate, fills up cavity;
Step 7:Sealing cures:Gum-injecting port is sealed with adhesive tape, then with shadowless glue cure lamp launch be wavelength be situated between
Encapsulating glass plate is irradiated in the ultraviolet light of 320~400nm, curing rate can be greatly speeded up, it is only necessary to several seconds to tens seconds can be complete
Into curing, and solidification temperature is low, greatlys save energy consumption;
Step 8:Remaining glue processing:It removes the glue for overflowing glass plate corner location after adhesive tape to handle, to improve glass
The overall aesthetics of glass product.
Embodiment 2:
A kind of doubling glass according to figure 1, including glassy layer 1 and hollow layer 2, the glassy layer 1 includes the first glass
11 and second glassy layer 12 of glass layer is provided with hollow layer 2 between 11 and second glassy layer 12 of the first glassy layer, described hollow
2 inside of layer is filled with glue, and the glassy layer 1 is made of 85% batch and 15% cullet, and the batch includes
The component of following ratio meter by weight:55.0 parts of quartz sand, 16.1 parts of soda ash, 5.8 parts of saltcake, 10.3 parts of lime
Stone, 4.5 parts of fluorite, 2.9 parts of sodium nitrate, 0.6 part of nickel oxide and 4.8 parts of charcoal powder.
According to a kind of processing technology of doubling glass shown in Fig. 2, concrete operation step is:
Step 1:Prepare glass:
(1) batch and cullet are stirred evenly using batch mixer, and the mixture homogeneity of batch and cullet >=
98%, to improve the quality of glassware;
(2) raw material after being sufficiently mixed is poured into melt stove, temperature is controlled at 1450 DEG C, makes mixed material heating extremely
Molten state heat preservation is spare;
(3) melting charge is imported and glass plate is made in mold slots;
(4) temperature is controlled at 550 DEG C, annealing cooling then is carried out to the formed glass plate in mold slots;
(5) rounded corner processing is carried out to the just angle of formed glass plate after cooling, avoids later stage sealing and the processing of remaining glue
Occurs situation about scratching in the process, to improve the upper safety of the people of operating personnel;
Step 2:Prepare doubling glass glue:Polyvinyl butyral resin, coupling agent and plasticizer are sufficiently mixed
Viscous liquid is made, wherein coupling agent, so as to reduce the viscosity of synthetic resin, improves using titanate esters or chromium complex
The dispersion degree of filler is to improve processing performance, and plasticizer can make the soft of glue using two tricaprylate of triethylene glycol
Toughness enhances, and easy to process;
Step 3:Fixed glass:The formed glass plate Boards wall in step 1 is taken, and makes two pieces of glass plates relatively flat
Row is set;
Step 4:Edge sealing:Adhesive tape carries out edge sealing to the surrounding of glass plate made of soft rubber, to ensure in hollow layer
Air-tightness, make to form cavity between two pieces of glass plates;
Step 5:It vacuumizes:A gum-injecting port is opened in the top adhesive tape between connecting two pieces of glass plates, and pass through will be interior
Portion's cavity is evacuated, and can exclude influence of the gas to injecting glue quality in hollow layer 2, so as to improve glue and glassy layer 1 it
Between degree of adhesion;
Step 6:Encapsulating:Glass glue in step 2 is injected into the vacuum chamber between glass plate, fills up cavity;
Step 7:Sealing cures:Gum-injecting port is sealed with adhesive tape, then with shadowless glue cure lamp launch be wavelength be situated between
Encapsulating glass plate is irradiated in the ultraviolet light of 320~400nm, curing rate can be greatly speeded up, it is only necessary to several seconds to tens seconds can be complete
Into curing, and solidification temperature is low, greatlys save energy consumption;
Step 8:Remaining glue processing:It removes the glue for overflowing glass plate corner location after adhesive tape to handle, to improve glass
The overall aesthetics of glass product.
Embodiment 3:
A kind of doubling glass according to figure 1, including glassy layer 1 and hollow layer 2, the glassy layer 1 includes the first glass
11 and second glassy layer 12 of glass layer is provided with hollow layer 2 between 11 and second glassy layer 12 of the first glassy layer, described hollow
2 inside of layer is filled with glue, and the glassy layer 1 is made of 85% batch and 15% cullet, and the batch includes
The component of following ratio meter by weight:57.5 parts of quartz sand, 15.6 parts of soda ash, 5.5 parts of saltcake, 9.8 parts of lime
Stone, 4.2 parts of fluorite, 2.6 parts of sodium nitrate, 0.3 part of nickel oxide and 4.5 parts of charcoal powder.
According to a kind of processing technology of doubling glass shown in Fig. 2, concrete operation step is:
Step 1:Prepare glass:
(1) batch and cullet are stirred evenly using batch mixer, and the mixture homogeneity of batch and cullet >=
98%, to improve the quality of glassware;
(2) raw material after being sufficiently mixed is poured into melt stove, temperature is controlled at 1500 DEG C, makes mixed material heating extremely
Molten state heat preservation is spare;
(3) melting charge is imported and glass plate is made in mold slots;
(4) temperature is controlled at 580 DEG C, annealing cooling then is carried out to the formed glass plate in mold slots;
(5) rounded corner processing is carried out to the just angle of formed glass plate after cooling, avoids later stage sealing and the processing of remaining glue
Occurs situation about scratching in the process, to improve the upper safety of the people of operating personnel;
Step 2:Prepare doubling glass glue:Polyvinyl butyral resin, coupling agent and plasticizer are sufficiently mixed
Viscous liquid is made, wherein coupling agent, so as to reduce the viscosity of synthetic resin, improves using titanate esters or chromium complex
The dispersion degree of filler is to improve processing performance, and plasticizer can make the soft of glue using two tricaprylate of triethylene glycol
Toughness enhances, and easy to process;
Step 3:Fixed glass:The formed glass plate Boards wall in step 1 is taken, and makes two pieces of glass plates relatively flat
Row is set;
Step 4:Edge sealing:Adhesive tape carries out edge sealing to the surrounding of glass plate made of soft rubber, to ensure in hollow layer
Air-tightness, make to form cavity between two pieces of glass plates;
Step 5:It vacuumizes:A gum-injecting port is opened in the top adhesive tape between connecting two pieces of glass plates, and pass through will be interior
Portion's cavity is evacuated, and can exclude influence of the gas to injecting glue quality in hollow layer 2, so as to improve glue and glassy layer 1 it
Between degree of adhesion;
Step 6:Encapsulating:Glass glue in step 2 is injected into the vacuum chamber between glass plate, fills up cavity;
Step 7:Sealing cures:Gum-injecting port is sealed with adhesive tape, then with shadowless glue cure lamp launch be wavelength be situated between
Encapsulating glass plate is irradiated in the ultraviolet light of 320~400nm, curing rate can be greatly speeded up, it is only necessary to several seconds to tens seconds can be complete
Into curing, and solidification temperature is low, greatlys save energy consumption;
Step 8:Remaining glue processing:It removes the glue for overflowing glass plate corner location after adhesive tape to handle, to improve glass
The overall aesthetics of glass product.
By the comparison of different embodiments as can be seen that when the component of the batch ratio meter by weight of glassy layer 1 is:
57.5 parts of quartz sand, 15.6 parts of soda ash, 5.5 parts of saltcake, 9.8 parts of lime stone, 4.2 parts of fluorite, 2.6 parts of nitric acid
Sodium, 0.3 part of nickel oxide and 4.5 parts of charcoal powder, while the cullet mixed melting of 85% batch and 15% is made
Glass, and melting temperature is controlled at 1450 DEG C, annealing cooling temperature control is at 550 DEG C, the structural strength of the doubling glass
Greatly, the doubling glass production efficiency and under the same terms is higher.
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention,
Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, still may be used
To modify to the technical solution recorded in foregoing embodiments or carry out equivalent substitution to which part technical characteristic,
Within the spirit and principles of the invention, any modifications, equivalent replacements and improvements are made should be included in the present invention's
Within protection domain.
Claims (7)
1. a kind of doubling glass, including glassy layer (1) and hollow layer (2), it is characterised in that:The glassy layer (1) includes first
Glassy layer (11) and the second glassy layer (12) are provided with hollow layer between first glassy layer (11) and the second glassy layer (12)
(2), filled with glue, batch and 15% cullet group of the glassy layer (1) by 85% inside the hollow layer (2)
Into the batch includes the component of following ratio meter by weight:52.5~57.5 parts of quartz sand, 15.6~16.6 parts
Soda ash, 5.5~6.1 parts of saltcake, 9.8~10.8 parts of lime stone, 4.2~4.8 parts of fluorite, 2.6~3.2 parts of nitric acid
Sodium, 0.3~0.9 part of nickel oxide and 4.5~5.1 parts of charcoal powder;
The present invention also provides a kind of processing technology of the doubling glass, concrete operation step is:
Step 1:Prepare glass:
(1) batch and cullet are stirred evenly using batch mixer;
(2) raw material after being sufficiently mixed is poured into melt stove be heated to molten state heat preservation it is spare;
(3) melting charge is imported and glass plate is made in mold slots;
(4) annealing cooling is carried out to the formed glass plate in mold slots;
(5) rounded corner processing is carried out to the just angle of formed glass plate after cooling;
Step 2:Prepare doubling glass glue:Polyvinyl butyral resin, coupling agent and plasticizer are sufficiently mixed and are made
Viscous liquid;
Step 3:Fixed glass:The formed glass plate Boards wall in step 1 is taken, and makes two pieces of glass plates are relatively parallel to set
It puts;
Step 4:Edge sealing:Edge sealing is carried out to the surrounding of glass plate with adhesive tape, makes to form cavity between two pieces of glass plates;
Step 5:It vacuumizes:A gum-injecting port is opened in the top adhesive tape between connecting two pieces of glass plates, and pass through will be internal empty
Chamber is evacuated;
Step 6:Encapsulating:Glass glue in step 2 is injected into the vacuum chamber between glass plate, fills up cavity;
Step 7:Sealing cures:Gum-injecting port is sealed with adhesive tape, then cures light irradiation encapsulating glass plate with shadowless glue;
Step 8:Remaining glue processing:The glue for overflowing glass plate corner location after adhesive tape is removed to handle.
2. a kind of doubling glass according to claim 1 and its processing technology, it is characterised in that:The batch and broken glass
Mixture homogeneity >=98% of glass.
3. a kind of doubling glass according to claim 1 and its processing technology, it is characterised in that:In the step 1 (2)
Melting temperature be arranged to 1400~1500 DEG C.
4. a kind of doubling glass according to claim 1 and its processing technology, it is characterised in that:In the step 1 (4)
Annealing cooling temperature be arranged to 530~580 DEG C.
5. a kind of doubling glass according to claim 1 and its processing technology, it is characterised in that:What the coupling agent used
It is titanate esters or chromium complex, the plasticizer is using two tricaprylate of triethylene glycol.
6. a kind of doubling glass according to claim 1 and its processing technology, it is characterised in that:The shadowless glue cure lamp
What is launched is ultraviolet light of the wavelength between 320~400nm.
7. a kind of doubling glass according to claim 1 and its processing technology, it is characterised in that:The adhesive tape is by soft rubber
Glue is made.
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CN201711361591.5A CN108046598A (en) | 2017-12-18 | 2017-12-18 | A kind of doubling glass and its processing technology |
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CN201711361591.5A CN108046598A (en) | 2017-12-18 | 2017-12-18 | A kind of doubling glass and its processing technology |
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Citations (5)
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---|---|---|---|---|
JPS63100045A (en) * | 1986-05-02 | 1988-05-02 | Mitsubishi Rayon Co Ltd | Adhesive for glass |
CN104086083A (en) * | 2014-07-24 | 2014-10-08 | 芜湖新利德玻璃制品有限公司 | Canned bottle glass and preparation method thereof |
CN105060708A (en) * | 2015-08-05 | 2015-11-18 | 芜湖新利德玻璃制品有限公司 | High-temperature resistant glass and preparation method thereof |
CN106881937A (en) * | 2015-12-15 | 2017-06-23 | 天津市百泰玻璃有限公司 | A kind of preparation technology of heat-insulated doubling glass |
CN107244817A (en) * | 2017-06-08 | 2017-10-13 | 何志铭 | A kind of doubling glass and preparation method thereof |
-
2017
- 2017-12-18 CN CN201711361591.5A patent/CN108046598A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63100045A (en) * | 1986-05-02 | 1988-05-02 | Mitsubishi Rayon Co Ltd | Adhesive for glass |
CN104086083A (en) * | 2014-07-24 | 2014-10-08 | 芜湖新利德玻璃制品有限公司 | Canned bottle glass and preparation method thereof |
CN105060708A (en) * | 2015-08-05 | 2015-11-18 | 芜湖新利德玻璃制品有限公司 | High-temperature resistant glass and preparation method thereof |
CN106881937A (en) * | 2015-12-15 | 2017-06-23 | 天津市百泰玻璃有限公司 | A kind of preparation technology of heat-insulated doubling glass |
CN107244817A (en) * | 2017-06-08 | 2017-10-13 | 何志铭 | A kind of doubling glass and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
中国南玻集团工程玻璃事业部: "《安全玻璃加工技术》", 31 March 2010, 华南理工大学出版社 * |
西北轻工业学院: "《玻璃工艺学》", 31 January 2000, 中国轻工业出版社 * |
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Application publication date: 20180518 |