CN108017126A - A kind of improver of water quality used for aquiculture - Google Patents
A kind of improver of water quality used for aquiculture Download PDFInfo
- Publication number
- CN108017126A CN108017126A CN201711041113.6A CN201711041113A CN108017126A CN 108017126 A CN108017126 A CN 108017126A CN 201711041113 A CN201711041113 A CN 201711041113A CN 108017126 A CN108017126 A CN 108017126A
- Authority
- CN
- China
- Prior art keywords
- parts
- water quality
- improver
- vitamin
- extract
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/10—Animals; Substances produced thereby or obtained therefrom
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Virology (AREA)
- Feed For Specific Animals (AREA)
Abstract
The present invention relates to a kind of improver of water quality, specifically discloses a kind of improver of water quality used for aquiculture.Improver of water quality used for aquiculture of the present invention includes the raw material components of following parts by weight：9 11 parts of four sodium of iminodisuccinic acid (IDS), 18 22 parts of attapulgite, 46 parts of aluminium polychloride, 6 10 parts of calper calcium peroxide, 15~25 parts of cod-liver oil extract, 3~5 parts of natural VE, 20~26 parts of vitamin D extract, 8~12 parts of alliin.The situation of water quality deterioration in aquaculture can be effectively solved using the improver of water quality of the present invention, in the case where improving water quality, correspondingly reduce the incidence of fish, so as to reduce the frequency of use of antibiotic etc., the product quality of aquiculture animal is improved, survival rate is up to 95%, while surprisingly finds that its moisture significantly reduces by experiment, its storage stability greatly improves, and significantly reduces condition of storage.
Description
Technical field
The present invention relates to a kind of improver of water quality, and in particular to a kind of improver of water quality used for aquiculture.
Background technology
As China's aquaculture develops rapidly, proportion of the aquaculture in aquaculture continues to increase, since market needs
The continuous expansion asked, the cultivation density at aquaculture family are also continuously increased.Cultivation density increases, and accelerates water quality aging, water quality
Deteriorate the cycle.The water quality index such as ammonia nitrogen, nitrite, hydrogen sulfide, dissolved oxygen amount in water body are not easily controlled, and are become plus weather
Change as rained, coolant-temperature gage change and salinity altercation caused by stormy weather make cultivated animals occur seeing through pressure it is uneven, should
Swash, immunity degradation, easily trigger outburst venereal bacteria infection dead, cause cultivation to fail.Aquaculture family largely used in the past
Antibiotic is prevented, and the abuse of antibiotic more accelerates water quality deterioration, cause cultivated animals secondary by stress, disease control is brought
The difficulty of bigger, easily causes cultivated animals explosive dead and influences cultivated animals quality.Export impacted, human body is made
Into indirect hazard.Therefore regulation and control water quality, increase cultivate the problem of success rate becomes culture fishery sustainable development in time.
At present in culture environment of aquatic products control, microorganism formulation is greatly paid close attention to.Its safe, user
Just, cost is low, control effect is good, but when causal organism amount reproduction in water body because influenced by biological competition and effect not
It is good.And in cause of disease control, current major measure is still disinfectant and antibiotic, although with certain effect, is existed
Risk hidden danger.Therefore build it is a kind of it is easy to use, safe it is harmless, have concurrently microorganism formulation water purification and antibacterial antistress function in
One, can in a short time fast purification water quality, recover aquatic livestock physiological function, improve immune improver of water quality.
The content of the invention
The present invention the first invention purpose be to provide a kind of improver of water quality used for aquiculture, can effectively solve water
The situation of water quality deterioration, in the case where improving water quality, correspondingly reduces the incidence of fish, so as to reduce in production cultivation
The frequency of use of antibiotic etc., improves the product quality of aquiculture animal, and survival rate is up to 95%, while by real
Test and surprisingly find that its moisture significantly reduces, its storage stability greatly improves, and significantly reduces condition of storage.
To realize the first invention purpose of the present invention, the technical scheme is that：
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
9-11 parts of sodium (IDS), 18-22 parts of attapulgite, 4-6 parts of aluminium polychloride, 6-10 parts of calper calcium peroxide, cod-liver oil extract
15~25 parts, 3~5 parts of natural VE, 20~26 parts of vitamin D extract, 8~12 parts of alliin.
Preferably, include the raw material components of following parts by weight：10 parts of four sodium of iminodisuccinic acid (IDS), concave convex rod
20 parts of soil, 5 parts of aluminium polychloride, 8 parts of calper calcium peroxide, 20 parts of cod-liver oil extract, 4 parts of natural VE, vitamin D carries
Take 23 parts of thing, 10 parts of alliin.
Preferably, the cod-liver oil method for preparing extractive is：By saturated fatty acid solidification point higher than unsaturation
Aliphatic acid, makes cod-liver oil slowly be as cold as 0 DEG C using this characteristic, separates out saturated fatty acid Step crystallization, passes through sheet frame pressure
Filter place to go tristearin to obtain the final product.
Preferably, the alliin preparation method is：Freeze-dried garlic powder is raw material, every kilogram of freeze-dried garlic powder with 1000 to
20000 milliliters of 60% to 90% ethanol carries out diacolation as solvent, and gained percolate carried out to be concentrated into no liquid
Concentrate is obtained untill outflow, alcohol precipitation is then carried out to concentrate using 95% ethanol or absolute ethyl alcohol, at 0~10 DEG C
It is lower place 6~12 it is small when, supernatant is poured out, concentrated extract is obtained untill be concentrated into no liquid outflow；Second step
Isolated alliin is carried out using silica gel column chromatography, wherein, above-mentioned concentrated extract mixes sample using silica white and obtains garlic silica gel
Powder, fills column, using dry column-packing or wet method dress post, mobile phase is matched somebody with somebody using normal propyl alcohol and water using the silica gel of 160~200 mesh
Than for 9 to 1, being obtained untill obtained alliin fraction is carried out being concentrated into no liquid outflow.
Preferably, the preparation method of the vitamin D extract is：First by 1: 0.3-3 weight ratio by vitamin D
Photochemical oil is substantially soluble in adsorption solvent, is injected in the chromatographic column of built-in aluminium oxide；Elution separation is carried out with eluting solvent, point
Section is collected, and pure vitamin D components are tracked with thin layer chromatography, until vitamin D washes out completely；The pure vitamin D that will be collected into
Component is removed under reduced pressure solvent, adds recrystallisation solvent, the freezing and crystallizing at a temperature of -5-10 °, after being filtered when 10-16 is small, vacuum
It is drying to obtain.
Cod-liver oil extract main component is vitamin A and vitamin D, can supplement abundant aliphatic acid and vitamin,
Contained vitamin has the function that to provide immunity cod-liver oil in itself；A kind of critically important vasodilator of natural VE
And anticoagulant, there is protection alveolar cell, reduce lung and respiratory system suffers infected probability；Alliin reducing blood lipid,
Improve body immunity, sterilization, antibacterial, anti-flu, anti-aging, promote blood circulation, cancer-resisting etc. effect it is notable.
It has inhibitory or killing effect to a variety of pathogens, is natural phytocide, it is to pathogenic staphylococcus, pyococcus, dysentery
Shigella, Escherichia coli, typhoid bacillus, tubercle bacillus, corynebacterium diphtheriae, carbon maggot bacillus, hay bacillus, paratyphosum Bacterium, meninx
Scorching and diplococcus, comma bacillus, streptococcus, staphylococcus albus, trichophyton schoenleini etc., have obvious antibacterial and sterilization to make
With；To many bacillary, fungoids and anti-protozoal infection, there are treatment and prevention to be worth.
The second object of the present invention is a kind of preparation method of improver of water quality used for aquiculture of offer.
To realize the second object of the present invention, the technical scheme is that：
A kind of preparation method of improver of water quality used for aquiculture, comprises the following steps：
(1) cod-liver oil extract is prepared：
Unrighted acid is higher than by saturated fatty acid solidification point, cod-liver oil is slowly as cold as 0 using this characteristic
DEG C, separate out saturated fatty acid Step crystallization, to obtain the final product by plate and frame filter press place to go tristearin；
(2) vitamin D extract is prepared
First the photochemical oil of vitamin D is substantially soluble in adsorption solvent by 1: 0.3-3 weight ratio, injects built-in aluminium oxide
Chromatographic column in；Elution separation is carried out with eluting solvent, Fractional Collections, tracks pure vitamin D components, directly with thin layer chromatography
Washed out completely to vitamin D；Solvent is removed under reduced pressure in the pure vitamin D components being collected into, recrystallisation solvent is added, at -5-10 °
At a temperature of freezing and crystallizing, when 10-16 is small filter after, be dried in vacuo to obtain the final product；
(3) alliin is prepared
Freeze-dried garlic powder is raw material, every kilogram of freeze-dried garlic powder by the use of 1000 to 20000 milliliters of 60% to 90% ethanol as
Solvent carries out diacolation, and gained percolate be concentrated into untill no liquid flows out and obtains concentrate, then uses
95% ethanol or absolute ethyl alcohol carries out alcohol precipitation to concentrate, and when placement 6~12 is small at 0~10 DEG C, supernatant is poured out,
Concentrated extract is obtained untill carrying out being concentrated into no liquid outflow；Second step is carried out isolated using silica gel column chromatography
Alliin, wherein, above-mentioned concentrated extract mixes sample using silica white and obtains garlic silica white, and column is filled using the silica gel of 160~200 mesh,
Using dry column-packing or wet method dress post, mobile phase uses the proportioning of normal propyl alcohol and water as 9:1, by obtained alliin fraction
Obtained untill carrying out being concentrated into no liquid outflow；
(4) finished product is prepared
Four sodium of iminodisuccinic acid (IDS) is weighed respectively by matching, attapulgite, aluminium polychloride, calper calcium peroxide,
Cod-liver oil extract, natural VE, vitamin D extract and alliin, mix after crushing, sieve for the first time, then
It is added to the water, stirring, first time is dry after mixing, and finished product is obtained after second of sieving, drying.
Preferably, the first time sieving in the step (4) was 120 mesh sieves, second of sieving is 200 mesh sieves.
Preferably, when holding 3~4 is small under the conditions of drying for the first time is 65 DEG C in the step (4), described second
When holding 1~2 is small under the conditions of drying is 110 DEG C.
Preferably, it is characterized in that, described in the step (4) stirring be with 500~600r/min stirring 40~
50min。
Beneficial effects of the present invention are：
(1) improver of water quality of the invention collect disinfection, deodorization detoxification, improve the multi-efficiency such as water quality and substrate in
One, using a variety of chemical compositions harmless to aquaculture organisms, acted on by chemical oxidation, suction-operated, decomposition
The oxidation-reduction potential for improving breeding water body quick with oxygenation effect etc., increase water body dissolved oxygen content, effectively kill the micro- life of cause of disease
Thing, degraded or the various harmful components of conversion, remove excessive algae, improve the transparency of water body, and construction is conducive to aquaculture organism
Existence and the water ecological setting of growth.
(2) improver of water quality of the present invention uses rear quick and effect stability, can significantly reduce ammonia nitrogen in water body, Asia
The content of the harmful substances such as nitrate, hydrogen sulfide, COD, increases water body dissolved oxygen, reduces algae density, kills and suppression cause of disease is micro-
Biology, enhances the transparency, and improves water quality and the environmental quality of substrate, improves aquaculture organism life condition, effectively prevents cultivation from giving birth to
Thing disease and sudden death, improve the yield and quality of aquaculture organism.
(3) improver of water quality provided by the invention, can effectively improve anti-bacteria and anti-virus effect of aquatic biological, show
The immunity for improving aquatic biological body is write, effectively prevents aquaculture thing disease and occurs so that the survival rate of aquatic biological
Up to 95%.
(4) improver of water quality preparation method of the present invention is simple, and by dry twice and setting of sieving so that its water content
Significantly reduce to less than 0.02%, be conducive to improve its stability so that the stability of product significantly improves.
Embodiment
The invention discloses a kind of improver of water quality used for aquiculture and preparation method thereof, those skilled in the art can
To use for reference present disclosure, technological parameter realization is suitably modified.In particular, all similar substitutions and modifications pair
It is it will be apparent that they are considered as being included in the present invention for those skilled in the art.The method of the invention has been led to
Preferred embodiment is crossed to be described, related personnel substantially can not depart from present invention, in spirit and scope to this paper institutes
The composition and preparation method stated are modified or suitably change with combining, to realize and using the technology of the present invention.
With reference to embodiment, the present invention is further explained.
Embodiment 1
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
10 parts of sodium (IDS), 20 parts of attapulgite, 5 parts of aluminium polychloride, 8 parts of calper calcium peroxide, 20 parts of cod-liver oil extract, natural dimension
Raw E4 parts of element, 23 parts of vitamin D extract, 10 parts of alliin；Preparation method includes the following steps：
(1) cod-liver oil extract is prepared：
Unrighted acid is higher than by saturated fatty acid solidification point, cod-liver oil is slowly as cold as 0 using this characteristic
DEG C, separate out saturated fatty acid Step crystallization, to obtain the final product by plate and frame filter press place to go tristearin；
(2) vitamin D extract is prepared
First the photochemical oil of vitamin D is substantially soluble in adsorption solvent by 1: 0.3-3 weight ratio, injects built-in aluminium oxide
Chromatographic column in；Elution separation is carried out with eluting solvent, Fractional Collections, tracks pure vitamin D components, directly with thin layer chromatography
Washed out completely to vitamin D；Solvent is removed under reduced pressure in the pure vitamin D components being collected into, recrystallisation solvent is added, at -5-10 °
At a temperature of freezing and crystallizing, when 10-16 is small filter after, be dried in vacuo to obtain the final product；
(3) alliin is prepared
Freeze-dried garlic powder is raw material, every kilogram of freeze-dried garlic powder by the use of 1000 to 20000 milliliters of 60% to 90% ethanol as
Solvent carries out diacolation, and gained percolate be concentrated into untill no liquid flows out and obtains concentrate, then uses
95% ethanol or absolute ethyl alcohol carries out alcohol precipitation to concentrate, and when placement 6~12 is small at 0~10 DEG C, supernatant is poured out,
Concentrated extract is obtained untill carrying out being concentrated into no liquid outflow；Second step is carried out isolated using silica gel column chromatography
Alliin, wherein, above-mentioned concentrated extract mixes sample using silica white and obtains garlic silica white, and column is filled using the silica gel of 160~200 mesh,
Using dry column-packing or wet method dress post, mobile phase uses the proportioning of normal propyl alcohol and water as 9:1, by obtained alliin fraction
Obtained untill carrying out being concentrated into no liquid outflow；
(4) finished product is prepared
Four sodium of iminodisuccinic acid (IDS) is weighed respectively by matching, attapulgite, aluminium polychloride, calper calcium peroxide,
Cod-liver oil extract, natural VE, vitamin D extract and alliin, mix after crushing, cross 120 mesh sieves for the first time,
Then it is added to the water, 500~600r/min stirs 40~50min., after mixing when holding 3~4 is small under the conditions of 65 DEG C
Carry out it is dry for the first time, by cross for second 200 mesh sieves, keep under the conditions of 110 DEG C 1~2 it is small when drying after finished product.
Embodiment 2
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
9 parts of sodium (IDS), 18 parts of attapulgite, 4 parts of aluminium polychloride, 6 parts of calper calcium peroxide, 15 parts of cod-liver oil extract, natural dimension
Raw E3 parts of element, 20 parts of vitamin D extract, 8 parts of alliin；Preparation method is the same as embodiment 1.
Embodiment 3
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
11 parts of sodium (IDS), 22 parts of attapulgite, 6 parts of aluminium polychloride, 10 parts of calper calcium peroxide, 25 parts of cod-liver oil extract, naturally
5 parts of vitamin E, 26 parts of vitamin D extract, 12 parts of alliin；Preparation method is the same as embodiment 1.
Embodiment 4
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
9 parts of sodium (IDS), 20 parts of attapulgite, 4 parts of aluminium polychloride, 10 parts of calper calcium peroxide, 20 parts of cod-liver oil extract, natural dimension
Raw E3 parts of element, 23 parts of vitamin D extract, 12 parts of alliin；Preparation method is the same as embodiment 1.
Embodiment 5
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
11 parts of sodium (IDS), 18 parts of attapulgite, 6 parts of aluminium polychloride, 8 parts of calper calcium peroxide, 20 parts of cod-liver oil extract, natural dimension
Raw E5 parts of element, 20 parts of vitamin D extract, 10 parts of alliin；Preparation method is the same as embodiment 1.
Reference examples 1：The improver of water quality with reference to made from 201610826081.X methods
Reference examples 2：The improver of water quality with reference to made from 201710418278.4 methods
Reference examples 3：The improver of water quality with reference to made from 201710426812.6 methods
Reference examples 4：The improver of water quality with reference to made from 201310067555.3 methods
Reference examples 5：The improver of water quality with reference to made from 201310514021.0 methods
Reference examples 6：The improver of water quality with reference to made from 201310744581.5 methods
Reference examples 7：The improver of water quality with reference to made from 201710391600.9 methods
Reference examples 8：It is made with reference to following method
A kind of improver of water quality used for aquiculture, includes the raw material components of following parts by weight：Iminodisuccinic acid four
10 parts of sodium (IDS), 20 parts of attapulgite, 5 parts of aluminium polychloride, 8 parts of preparation methods of calper calcium peroxide：Asia is weighed respectively by proportioning
Four sodium of amino disuccinic acid (IDS), attapulgite, aluminium polychloride, calper calcium peroxide, mixes after crushing, crosses 120 mesh for the first time
Sieve, is then added to the water, and 500~600r/min stirs 40~50min., holding 3~4 is small under the conditions of 65 DEG C after mixing
Shi Jinhang is dry for the first time, by cross for second 200 mesh sieves, keep under the conditions of 110 DEG C 1~2 it is small when drying after finished product.
Influence of 1 product of experimental example to fish seedling percent
Experiment is divided into test group and control group, and every group of aquaculture area is identical, i.e., puts 1000 3~4cm mandarin fish in a suitable place to breed per acre
Fish, introduces identical water quality and is raised, and spills the improver of water quality of 1.5KG after putting in a suitable place to breed per acre, and the cultivation of fry uses the present invention
The improver of water quality of improver of water quality and control group is fished for 600 fishes and is observed at random after 2 months.
The influence experimental result of mandarin fish shoot survival percent is as follows：
The influence experimental result of 1 mandarin fish shoot survival percent of table
| Index | Initial number of live vaccine (tail) | Into number of live vaccine (tail) | Seedling body grows (cm) | Survival rate (%) |
| Embodiment 1 | 600 | 570 | 9-10 | 95% |
| Embodiment 2 | 600 | 540 | 8-9 | 90% |
| Embodiment 4 | 600 | 552 | 8-9 | 92% |
| Reference examples 1 | 600 | 326 | 4-5 | 54.3% |
| Reference examples 2 | 600 | 456 | 5-6 | 76% |
| Reference examples 3 | 600 | 390 | 5-6 | 65% |
| Reference examples 4 | 600 | 375 | 3-4 | 62.5% |
| Reference examples 5 | 600 | 348 | 5-6 | 58% |
| Reference examples 6 | 600 | 457 | 6-7 | 76.2% |
| Reference examples 7 | 600 | 421 | 5-6 | 70.2% |
| Reference examples 8 | 600 | 492 | 8-9 | 82% |
By experimental data as can be seen that the survival rate average out to of the improver of water quality fry using the present invention
92.33%, it is significantly higher than reference examples, substantially increases the survival rate of fry, and fry is after raising after a while, this
The entire length of invention group seedling body is also longer than control group.
Influence of 2 product of experimental example to juvenile river crab survival rate
Experiment is divided into test group and control group, and every group of aquaculture area is identical, i.e., puts 1000 river crabs in a suitable place to breed per acre, draw
Enter identical water quality to be raised, spill the improver of water quality of 2.5KG after putting in a suitable place to breed per acre, introduce identical water quality and raised, river
The cultivation of juvenile crab using the improver of water quality of improver of water quality of the present invention and control group fish at random after 2 months 500 river crabs into
Row observation.
The influence experimental result of juvenile river crab survival rate is as follows：
The influence experimental result of 2 juvenile river crab survival rate of table
| Index | Initial number of live vaccine (only) | Into number of live vaccine (only) | Survival rate (%) |
| Embodiment 1 | 500 | 460 | 92% |
| Embodiment 2 | 500 | 450 | 90% |
| Embodiment 4 | 500 | 450 | 90% |
| Reference examples 1 | 500 | 280 | 56% |
| Reference examples 2 | 500 | 363 | 72.6% |
| Reference examples 3 | 500 | 331 | 66.2% |
| Reference examples 4 | 500 | 300 | 60% |
| Reference examples 5 | 500 | 300 | 60% |
| Reference examples 6 | 500 | 402 | 80.4% |
| Reference examples 7 | 500 | 330 | 66% |
| Reference examples 8 | 500 | 410 | 82% |
By experimental data as can be seen that the survival rate average out to of the improver of water quality juvenile river crab using the present invention
90.67%, it is significantly higher than reference examples, substantially increases the survival rate of juvenile river crab.
3 water quality improvement effect experiment of experimental example
Improver of water quality of the present invention and reference examples improver of water quality are thrown to length in the pond of the young age mandarin fish of 3~4cm
The pool carries out application test, the relevant parameter of periodic detection water body, result of the test such as table 3：Unit (mg/L).
3 fry phase of table aquatic livestock application test
After using improver of water quality of the present invention as can be seen from Table 1, water quality has more significant improvement.
4 stability experiment of experimental example
The present invention and reference examples improver of water quality are placed at 25 DEG C under the conditions of relative humidity (90 ± 5) %
After ten days, repeat the experimental result that influence experiment of the product to fish seedling percent obtains and be shown in Table 4：
The influence experimental result of 4 mandarin fish shoot survival percent of table
From above-mentioned experimental result, improver of water quality of the present invention is good in high humidity environment stability inferior, and the prior art
The stability of improver of water quality is very poor, the survival rate of fish seedling is influenced very big.
Claims (9)
- A kind of 1. improver of water quality used for aquiculture, it is characterised in that：Include the raw material components of following parts by weight：Imino-diacetic 9-11 parts of four sodium of butanedioic acid (IDS), 18-22 parts of attapulgite, 4-6 parts of aluminium polychloride, 6-10 parts of calper calcium peroxide, cod-liver oil 15~25 parts of extract, 3~5 parts of natural VE, 20~26 parts of vitamin D extract, 8~12 parts of alliin.
- 2. improver of water quality used for aquiculture according to claim 1, it is characterised in that：Include the original of following parts by weight Expect component：10 parts of four sodium of iminodisuccinic acid (IDS), 20 parts of attapulgite, 5 parts of aluminium polychloride, 8 parts of calper calcium peroxide, cod 20 parts of cod-liver oil extract, 4 parts of natural VE, 23 parts of vitamin D extract, 10 parts of alliin.
- 3. improver of water quality used for aquiculture according to claim 1, it is characterised in that the cod-liver oil extract Preparation method is：Unrighted acid is higher than by saturated fatty acid solidification point, makes cod-liver oil slowly cold using this characteristic To 0 DEG C, separate out saturated fatty acid Step crystallization, to obtain the final product by plate and frame filter press place to go tristearin.
- 4. improver of water quality used for aquiculture according to claim 1, it is characterised in that the alliin preparation method For：Freeze-dried garlic powder is raw material, every kilogram of freeze-dried garlic powder by the use of 1000 to 20000 milliliters of 60% to 90% ethanol as solvent into Row diacolation, and obtain concentrate untill be concentrated into no liquid outflow by gained percolate, then using 95% second Alcohol or absolute ethyl alcohol carry out alcohol precipitation to concentrate, when placement 6~12 is small at 0~10 DEG C, supernatant are poured out, is concentrated into Do not have to obtain concentrated extract untill liquid outflow；Second step carries out isolated alliin using silica gel column chromatography, wherein, Above-mentioned concentrated extract mixes sample using silica white and obtains garlic silica white, column is filled using the silica gel of 160~200 mesh, using dry column-packing Or wet method dress post, mobile phase use the proportioning of normal propyl alcohol and water to be concentrated into obtained alliin fraction not for 9 to 1 Have untill liquid outflow and obtain.
- 5. improver of water quality used for aquiculture according to claim 1, it is characterised in that the vitamin D extract Preparation method be：First the photochemical oil of vitamin D is substantially soluble in adsorption solvent by 1: 0.3-3 weight ratio, injects built-in oxygen In the chromatographic column for changing aluminium；Elution separation is carried out with eluting solvent, Fractional Collections, pure vitamin D components are tracked with thin layer chromatography, Until vitamin D washes out completely；Solvent is removed under reduced pressure in the pure vitamin D components being collected into, recrystallisation solvent is added, at -5-10 ° At a temperature of freezing and crystallizing, when 10-16 is small filter after, be dried in vacuo to obtain the final product.
- 6. a kind of preparation method of improver of water quality used for aquiculture, it is characterised in that comprise the following steps：(1) cod-liver oil extract is preparedUnrighted acid is higher than by saturated fatty acid solidification point, cod-liver oil is slowly as cold as 0 DEG C using this characteristic, makes Saturated fatty acid Step crystallization separates out, by plate and frame filter press place to go tristearin to obtain the final product；(2) vitamin D extract is preparedFirst the photochemical oil of vitamin D is substantially soluble in adsorption solvent by 1: 0.3-3 weight ratio, injects the chromatography of built-in aluminium oxide In column；Elution separation is carried out with eluting solvent, Fractional Collections, tracks pure vitamin D components, until vitamin with thin layer chromatography D is washed out completely；Solvent is removed under reduced pressure in the pure vitamin D components being collected into, recrystallisation solvent is added, is freezed at a temperature of -5-10 ° Crystallization, after being filtered when 10-16 is small, is dried in vacuo to obtain the final product；(3) alliin is preparedFreeze-dried garlic powder is raw material, and every kilogram of freeze-dried garlic powder is used as solvent by the use of 1000 to 20000 milliliters of 60% to 90% ethanol Diacolation is carried out, and gained percolate be concentrated into untill no liquid flows out and obtains concentrate, then using 95% Ethanol or absolute ethyl alcohol carry out alcohol precipitation to concentrate, when placement 6~12 is small at 0~10 DEG C, supernatant are poured out, is concentrated Concentrated extract is obtained untill no liquid flows out；Second step carries out isolated alliin using silica gel column chromatography, its In, above-mentioned concentrated extract mixes sample using silica white and obtains garlic silica white, fills column using the silica gel of 160~200 mesh, is filled using dry method Column or wet method dress post, mobile phase use the proportioning of normal propyl alcohol and water as 9:1, obtained alliin fraction is concentrated into not Have untill liquid outflow and obtain；(4) finished product is preparedFour sodium of iminodisuccinic acid (IDS), attapulgite, aluminium polychloride, calper calcium peroxide, gadus liver are weighed respectively by proportioning Oil extract, natural VE, vitamin D extract and alliin, mix after crushing, sieve for the first time, then add water In, stir, first time is dry after mixing, and finished product is obtained after second of sieving, drying.
- 7. the preparation method of improver of water quality used for aquiculture according to claim 6, it is characterised in that the step (4) the first time sieving in was 120 mesh sieves, and second of sieving is 200 mesh sieves.
- 8. the preparation method of improver of water quality used for aquiculture according to claim 6, it is characterised in that the step (4) in it is dry for the first time be 65 DEG C under the conditions of keep 3~4 it is small when, described second dry be 110 DEG C under the conditions of keep 1~2 small When.
- 9. the preparation method of improver of water quality used for aquiculture according to claim 6, it is characterised in that the step (4) stirring described in is to stir 40~50min with 500~600r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711041113.6A CN108017126A (en) | 2017-10-30 | 2017-10-30 | A kind of improver of water quality used for aquiculture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711041113.6A CN108017126A (en) | 2017-10-30 | 2017-10-30 | A kind of improver of water quality used for aquiculture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108017126A true CN108017126A (en) | 2018-05-11 |
Family
ID=62079624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711041113.6A Pending CN108017126A (en) | 2017-10-30 | 2017-10-30 | A kind of improver of water quality used for aquiculture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108017126A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273969A (en) * | 2000-01-22 | 2000-11-22 | 陈坚 | Process for extracting alliin from garlic |
| CN1709869A (en) * | 2005-05-31 | 2005-12-21 | 台州市海盛化工有限公司 | Vitamin D separating, purifying and crystallizing method |
| US20070036875A1 (en) * | 2003-03-27 | 2007-02-15 | Stone Isalnd Holdings Ltd. | Use of allicin as preservative, as disinfectant, as antimicrobial or as biocidal agent |
| CN101333022A (en) * | 2007-09-18 | 2008-12-31 | 唐子林 | Ecological modifying agent for mineral substance water quality |
| US20120279924A1 (en) * | 2011-05-06 | 2012-11-08 | National Chung-Hsing University | Method for mitigating eutrophication in a water body |
| CN103466803A (en) * | 2013-09-02 | 2013-12-25 | 鄂州市广丰生态农业开发有限责任公司 | Ameliorant for water quality of aquatic products and preparation method thereof |
| CN106830435A (en) * | 2017-03-09 | 2017-06-13 | 杭州职业技术学院 | A kind of mercurous sewage water treatment method |
-
2017
- 2017-10-30 CN CN201711041113.6A patent/CN108017126A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273969A (en) * | 2000-01-22 | 2000-11-22 | 陈坚 | Process for extracting alliin from garlic |
| US20070036875A1 (en) * | 2003-03-27 | 2007-02-15 | Stone Isalnd Holdings Ltd. | Use of allicin as preservative, as disinfectant, as antimicrobial or as biocidal agent |
| CN1709869A (en) * | 2005-05-31 | 2005-12-21 | 台州市海盛化工有限公司 | Vitamin D separating, purifying and crystallizing method |
| CN101333022A (en) * | 2007-09-18 | 2008-12-31 | 唐子林 | Ecological modifying agent for mineral substance water quality |
| US20120279924A1 (en) * | 2011-05-06 | 2012-11-08 | National Chung-Hsing University | Method for mitigating eutrophication in a water body |
| CN103466803A (en) * | 2013-09-02 | 2013-12-25 | 鄂州市广丰生态农业开发有限责任公司 | Ameliorant for water quality of aquatic products and preparation method thereof |
| CN106830435A (en) * | 2017-03-09 | 2017-06-13 | 杭州职业技术学院 | A kind of mercurous sewage water treatment method |
Non-Patent Citations (3)
| Title |
|---|
| 上海水产学院: "《鱼病学》", 31 October 1961, 农业出版社 * |
| 李玉环: "《水产品加工技术》", 30 September 2014, 中国轻工业出版社 * |
| 王玉堂: "《渔用饲料加工与质量控制技术》", 30 June 2016, 海洋出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102132767B (en) | Curcumin or curcumin-ramification-containing composite feed additive and use thereof | |
| CN102177868B (en) | Method for pond three-dimensional (3D) culture of Chinese prawns | |
| CN102894186A (en) | Albumen powder richening in antimicrobial peptide fly maggot, preparation method for albumen powder and feed additive of albumen powder | |
| CN102342283A (en) | Combined preparation for killing wild fishes in shrimp and crab pond | |
| CN105393951A (en) | Carp breeding method | |
| CN107439437A (en) | A kind of Urechis uniconctus cultural method | |
| CN106219705B (en) | A kind of pure natural flocculant and preparation method thereof changed for aquaculture pond bottom | |
| CN117618483A (en) | Pharmaceutical composition for preventing and treating comprehensive diseases of Babylonia, and preparation method and application thereof | |
| CN108017126A (en) | A kind of improver of water quality used for aquiculture | |
| CN101946812B (en) | Guava leaf and new application of extract thereof | |
| CN102273456B (en) | Application of beta-dihydro benzoic acid macrolide derivant in preventing and treating harmful spiral shells | |
| CN101559060B (en) | Medicine for preventing fish parasitic crustacean diseases, preparation method and application thereof | |
| CN103891636A (en) | Method for preventing and treating fish diseases | |
| CN115624579A (en) | Traditional Chinese medicine composition for inhibiting aeromonas veronii and application thereof | |
| JP4982649B2 (en) | Method for enhancing life activity of living body in contact with aquatic environment and / or expanding life activity suitable area | |
| CN111789200A (en) | Antidote for aquatic products and preparation method thereof | |
| CN111374076A (en) | Penaeus vannamei feeding method | |
| CN110477218A (en) | A kind of nutrition prescription preventing the Yellow River carp hemorrhage and preparation method | |
| CN110495530B (en) | Floating feed for snakehead juvenile fish period and preparation method thereof | |
| CN111820342B (en) | Application of (2-carboxyethyl) dimethyl sulfonium bromide in preparation of mixture for enhancing skin barrier function of grass carp | |
| RU2755195C1 (en) | Method for increasing the efficiency of growing young nelma | |
| CN116158381B (en) | Method for purifying harmful substances in green crab body of hairy crab | |
| CN108815426A (en) | A kind of antibacterial agent and its preparation method and application containing natural plant extract | |
| CN107362348B (en) | Fishing pesticide and preparation method thereof | |
| CN103493761B (en) | The scientific formula cultural method of Medaka fish |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180511 |