[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN107997974A - 含有一种多羟基化合物的洗涤剂组合物 - Google Patents

含有一种多羟基化合物的洗涤剂组合物 Download PDF

Info

Publication number
CN107997974A
CN107997974A CN201711260326.8A CN201711260326A CN107997974A CN 107997974 A CN107997974 A CN 107997974A CN 201711260326 A CN201711260326 A CN 201711260326A CN 107997974 A CN107997974 A CN 107997974A
Authority
CN
China
Prior art keywords
acid
detergent composition
polyol
peg
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711260326.8A
Other languages
English (en)
Inventor
吴海龙
雷秋芬
李泽勇
汤仲标
户献雷
郭守彬
张利萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Tinci Materials Technology Co Ltd
Original Assignee
Guangzhou Tinci Materials Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Tinci Materials Technology Co Ltd filed Critical Guangzhou Tinci Materials Technology Co Ltd
Priority to CN201711260326.8A priority Critical patent/CN107997974A/zh
Publication of CN107997974A publication Critical patent/CN107997974A/zh
Priority to PCT/CN2018/116731 priority patent/WO2019109804A1/zh
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0073—Anticorrosion compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A61K2800/524—Preservatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Molecular Biology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

本发明涉及一种洗涤剂组合物，包括如下组分：(a)占组合物质量分数3‑50％的表面活性剂；(b)占组合物质量分数0.01‑10％的功能助剂；(c)占组合物质量分数0.1‑25％的多羟基化合物；(d)占组合物质量分数40‑96％的溶剂；其中多羟基化合物具有如下结构

Description

含有一种多羟基化合物的洗涤剂组合物
技术领域
本发明涉及日用化学品技术领域，特别是涉及含有一种多羟基化合物的洗涤剂组合物。
背景技术
目前洗涤组合物为了阻止微生物繁殖，达到必要的保质期，必须使用防腐剂。额外添加现有防腐剂会提高洗涤组合物的刺激性，降低使用温和性。目前常用的现有防腐剂有尼泊金酯类、卡松、DMDM乙内酰脲等。
这类常用的现有防腐剂的缺点有：配方使用限制条件多、增加产品的刺激性、增加使用者过敏风险、存在累积危害性、致病性、致癌性。
目前具有功能杀菌的洗涤剂组合物，要达到其功能，必须使用额外的现有杀菌剂。额外的杀菌剂除了对洗涤配方的复配性能提出了更高的要求，还会提高洗涤组合物的刺激性，降低使用温和性。目前常用的现有功能杀菌剂有吡硫鎓锌、甘宝素、吡罗克酮乙醇胺盐、酮康唑、氯咪巴唑或己脒定二(羟乙基磺酸)盐、对氯间二甲苯酚(PCMX)、双氯苯双胍己烷、苯扎氯铵等。
专利CN201180066751.8使用吡硫鎓锌类物质作为杀菌去屑剂，该去屑剂需要配方具有悬浮能力，并且不能把配方做成透明状态。
专利CN201210377379.9使用中药组合提取物作为杀菌去屑剂，该去屑剂生产复杂，成分稳定性控制要求高，洗发水配方稳定性难度高。
专利CN201210404271.4使用吡硫鎓锌或甘宝素作为杀菌去屑剂，吡硫鎓锌去屑剂需要配方具有悬浮能力，并且不能把配方做成透明状态；甘宝素去屑剂气味大，配方刺激性强。
这类常用的现有功能杀菌剂的缺点有：配方使用限制条件多、增加产品的刺激性、增加使用者过敏风险、存在累积危害性、致病性、致癌性。
发明内容
基于此，本发明的目的是提供一种含有多羟基化合物的洗涤剂组合物，该多羟基化合物同时提供了防腐、功能杀菌、调理、保湿的能力。
具体的技术方案如下：
一种洗涤剂组合物，包括如下组分：
(a)占组合物质量分数3-50％的表面活性剂；
(b)占组合物质量分数0.01-10％的功能助剂；
(c)占组合物质量分数0.1-25％的多羟基化合物；
(d)占组合物质量分数40-96％的溶剂(以上组分含量的总和为100％)。
在其中一些实施例中，所述多羟基化合物结构如下：
其中R1任选自C6-C20的烷基酰胺丙基、C6-C20的烷基酰胺乙基、C6-C20的烷基酰氧乙基、C6-C20的烷基酰氧丙基、C6-C20的烷基酰氧异丙基或H(OCH2CH2)n-，2≤n≤20；R2、R3分别任选自羟乙基、C1-C20的烷基、C6-C20的烷基酰胺丙基、C6-C20的烷基酰胺乙基、C6-C20的烷基酰氧乙基、C6-C20的烷基酰氧丙基、C6-C20的烷基酰氧异丙基或H(OCH2CH2)m-，2≤m≤20，R4为-OCH2CH(OH)CH2(OH)，X为Cl或Br。
在其中一些实施例中，所述表面活性剂选自：
(a)阴离子表面活性剂，十二烷基硫酸铵、月桂基聚氧乙烯醚硫酸铵、月桂基硫酸三乙基胺、月桂基聚氧乙烯醚硫酸三乙基胺、烷基苯磺酸钠、烷基苯磺酸铵、脂肪基甲基牛磺酸钠、月桂基硫酸三乙醇胺、月桂基聚氧乙烯醚硫酸三乙醇胺、月桂基硫酸单乙醇胺、月桂基聚氧乙烯醚硫酸单乙醇胺、月桂基硫酸二乙醇胺、月桂基聚氧乙烯醚硫酸二乙醇胺、月桂酸甘油单酯硫酸钠、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、脂肪酸、月桂基硫酸钾、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、肌氨酸月桂酯、脂肪醇甘油醚磺酸盐、椰油基肌氨酸、椰油基硫酸铵、十二烷酰基硫酸铵、椰油基硫酸钠、脂肪醇醚羧酸盐、月桂酰硫酸钠、椰油基硫酸钾、月桂基硫酸钾、月桂基硫酸三乙醇胺、月桂基硫酸三乙醇胺、椰油基硫酸单乙醇胺、月桂基硫酸单乙醇胺，上述硫酸根、羟乙基磺酸根、磺酸根、磺基琥珀酸根以外，可用于阴离子表面活性剂中的其它可能的阴离子还包括膦酸根、磷酸根和羧酸根；
(b)两性表面活性剂,椰油基氨基丙酸钠、椰油基氨基二丙酸钠、椰油酰两性基乙酸钠、椰油酰两性基羟丙基磺酸钠、椰油酰两性基丙酸钠、玉米油酰两性基丙酸钠、月桂氨基丙酸钠、月桂酰两性基乙酸钠、月桂酰两性基羟丙基磺酸钠、月桂酰两性基丙酸钠、玉米油酰两性基丙酸钠、月桂亚氨基二丙酸钠、椰油基氨基丙酸铵、椰油基氨基二丙酸铵、椰油酰两性基乙酸铵、椰油酰两性基羟丙基磺酸铵、椰油酰两性基丙酸铵、玉米油酰两性基丙酸铵、月桂氨基丙酸铵、月桂酰两性基乙酸铵、月桂酰两性基羟丙基磺酸铵、月桂酰两性基丙酸铵、玉米油酰两性基丙酸铵、月桂亚氨基二丙酸铵、椰油基氨基丙酸三乙醇胺、椰油基氨基二丙酸三乙醇胺、椰油酰两性基乙酸三乙醇胺、椰油酰两性基羟丙基磺酸三乙醇胺、椰油酰两性基丙酸三乙醇胺、玉米油酰两性基丙酸三乙醇胺、月桂氨基丙酸三乙醇胺、月桂酰两性基乙酸三乙醇胺、月桂酰两性基羟丙基磺酸三乙醇胺、月桂酰两性基丙酸三乙醇胺、玉米油酰两性基丙酸三乙醇胺、月桂亚氨基二丙酸三乙醇胺、椰油酰两性基二丙酸、癸酰两性基二乙酸二钠、癸酰两性基二丙酸二钠、辛酰两性基二乙酸二钠、辛酰两性基二丙酸二钠、椰油酰两性基羧乙基羟丙基磺酸二钠、椰油酰两性基二乙酸二钠、椰油酰两性基二丙酸二钠、二羧乙基椰油基丙二胺二钠、月桂基聚氧乙烯醚-5羧基两性基二乙酸二钠、月桂亚氨基二丙酸二钠、月桂酰两性基二乙酸二钠、月桂酰两性基二丙酸二钠、油基两性基二丙酸二钠、PPG-2-异癸醇聚醚-7羧基两性基二乙酸二钠、月桂基氨基丙酸、月桂酰两性基二丙酸、月桂基氨丙基甘氨酸、月桂基二亚乙二氨基甘氨酸、椰油酰两性基二乙酸钠、月桂酰两性基二乙酸钠、椰油酰胺基乙基甜菜碱、椰油酰胺基丙基氧化胺、椰油酰胺基丙基甜菜碱、椰油酰胺基丙基二甲基氨基羟丙基水解胶原、椰油酰胺基丙基二甲基铵羟丙基水解胶原、椰油酰胺基丙基羟基磺基甜菜碱、椰油甜菜碱酰胺基两性基丙酸盐、椰油基甜菜碱、椰油基羟基磺基甜菜碱、椰油基/油基酰胺丙基甜菜碱、椰油基磺基甜菜碱、月桂酰胺基丙基甜菜碱、月桂基甜菜碱、月桂基羟基磺基甜菜碱、月桂基磺基甜菜碱、椰油基磺基甜菜碱；
(c)非离子表面活性剂,椰油酰胺、椰油酰胺甲基MEA、椰油酰胺DEA、椰油酰胺MEA、椰油酰胺MIPA、月桂酰胺DEA、月桂酰胺MEA、月桂酰胺MIPA、十四酰胺DEA、十四酰胺MEA、PEG-20椰油酰胺MEA、PEG-2椰油酰胺、PEG-3椰油酰胺、PEG-4椰油酰胺、PEG-5椰油酰胺、PEG-6椰油酰胺、PEG-7椰油酰胺、PEG-3月桂酰胺、PEG-5月桂酰胺、PEG-3油酰胺、PPG-2椰油酰胺、PPG-2羟乙基椰油酰胺、脂肪醇聚氧乙烯醚、脂肪醇、烷基糖苷；
(d)阳离子表面活性剂，烷基三甲基氯化铵、烷基三甲基溴化铵、烷基三甲基硫酸甲酯、烷基二甲基乙基硫酸乙酯铵、脂肪酰胺丙基三甲基氯化铵、脂肪酰胺丙基三甲基溴化铵、脂肪酰胺丙基三甲基硫酸甲酯铵、脂肪酰胺丙基二甲基乙基硫酸乙酯铵、烷基二羟乙基甲基氯化铵、烷基二羟乙基甲基溴化铵、烷基二羟乙基甲基硫酸甲酯铵、烷基二羟乙基乙基硫酸乙酯铵、脂肪酰胺丙基二羟乙基甲基氯化铵、脂肪酰胺丙基二羟乙基甲基溴化铵、脂肪酰胺丙基二羟乙基甲基硫酸甲酯铵、脂肪酰胺丙基二羟乙基乙基硫酸乙酯铵、脂肪酰胺乙基三甲基氯化铵、脂肪酰胺乙基三甲基溴化铵、脂肪酰胺乙基三甲基硫酸甲酯铵、脂肪酰胺乙基二甲基乙基硫酸乙酯铵、脂肪酰胺乙基二羟乙基甲基氯化铵、脂肪酰胺乙基二羟乙基甲基溴化铵、脂肪酰胺乙基二羟乙基甲基硫酸甲酯铵、脂肪酰胺乙基二羟乙基乙基硫酸乙酯铵中一种或几种。
在其中一些实施例中，所述功能助剂选自维生素、螯合剂、香料、增白剂、酶、调理剂、增稠剂、引诱剂、染料、颜料、漂白剂以及珠光剂中的一种或几种。
在其中一些实施例中，所述溶剂选自水、乙醇、甘油、丙二醇、聚乙二醇、异丙醇中一种或几种。
在其中一些实施例中，所述的螯合剂选自：乙二胺四乙酸、氨基三乙酸、二亚乙基三胺五乙酸及其盐、柠檬酸、酒石酸和葡萄糖酸、羟乙基乙二胺三乙酸、二羟乙基甘氨酸、有机多元膦酸、聚丙烯酸、聚甲基丙烯酸、水解聚马来酸酐或富马酸-丙烯磺酸共聚体中一种或几种。
在其中一些实施例中，所述调理剂选自：阳离子瓜尔胶聚合物、阳离子非瓜尔胶半乳甘露聚糖聚合物、阳离子改性淀粉聚合物、丙烯酰胺单体与阳离子单体的阳离子共聚物、阳离子纤维素聚合物、聚硅氧烷或阳离子决明胶聚合物中一种或几种。
在其中一些实施例中，所述增稠剂选自：改性的羟乙基纤维素、疏水改性的聚丙烯酸酯、疏水改性的聚丙烯酸、疏水改性的聚丙烯酰胺、PEG-120甲基葡萄糖二油酸酯、PEG-40脱水山梨糖醇四油酸酯、PEG-60脱水山梨糖醇四油酸酯、PEG-150季戊四醇四硬脂酸酯、PEG-55丙二醇油酸酯或PEG-150二硬脂酸酯中一种或几种。
在其中一些实施例中，所述的珠光剂选自：硬脂酸乙二醇双酯、硬脂酸乙二醇单酯中一种或两种。
上述洗涤剂组合物采用该多羟基化合物，具有防腐的效果，无需额外添加现有防腐剂，洗涤组合物刺激性低，温和性高；上述洗涤剂组合物采用该多羟基化合物，能够有效的杀灭马拉色菌、痤疮丙酸杆菌，洗涤剂组合物具有去屑、祛痘的效果；上述洗涤剂组合物采用该多羟基化合物，洗涤剂组合物同时具有调理、保湿的功能。
附图说明
图1为实施例1与对比例1志愿者洗发测试结果。
具体实施方式
为了便于理解本发明，下面将对本发明进行更全面的描述。但是，本发明可以以许多不同的形式来实现，并不限于本文所描述的实施例。相反地，提供这些实施例的目的是使对本发明的公开内容的理解更加透彻全面。
除非另有定义，本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的，不是旨在于限制本发明。本文所使用的术语“和/或”包括一个或多个相关的所列项目的任意的和所有的组合。
实施例1
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，加入B相继续加热搅拌溶解均匀。
c、B相溶解均匀后，降温到常温，加入C相，搅拌均匀即可。
实施例2
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，加入B相继续加热搅拌溶解均匀。
c、B相溶解均匀后，降温到常温，加入C相，搅拌均匀即可。
实施例3
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，加入B相继续加热搅拌溶解均匀。
c、B相溶解均匀后，降温到常温，加入C相，搅拌均匀即可。
实施例4
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，加入B相继续加热搅拌溶解均匀。
c、B相溶解均匀后，降温到常温，加入C相，搅拌均匀即可。
实施例5
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，加入B相继续加热搅拌溶解均匀。
c、B相溶解均匀后，降温到常温，加入C相，搅拌均匀即可。
实施例6
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，降温到常温，加入B相，搅拌均匀即可。
实施例7
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，降温到常温，加入B相，搅拌均匀即可。
实施例8
本实施例，含有一种多羟基化合物的洗涤剂组合物制备：
(1)配方组分
(2)配方工艺
a、将A相加热搅拌溶解均匀。
b、A相溶解均匀后，降温到常温，加入B相，搅拌均匀即可。
对比例1
对比例1洗涤剂组合物配方与实施例1相比区别在于不含有多羟基化合物。对比例1与实施例1志愿者洗发测试结果见图1。
志愿者洗发测试方法如下：
1:试用说明：半头试验就是在洗头时左右半头同时洗两种洗发水，通过两只手同时感受在洗头时和洗发后的不同感受。
2：试用感受点说明：在对应时间段评价相应指标：
洗发流程包括：涂抹洗发水、冲水、泡沫冲洗、冲洗完毕以及头发擦干。
涂抹洗发水后，评价泡沫丰富程度；泡沫冲洗过程中评价冲水滑涩感；冲洗完毕后评价湿发时的头发顺滑感以及湿发时的头发柔软度；头发擦干后评价干发时的顺滑感、干发时的滋润感以及干发时的柔软感。
3.结合实际使用情况，根据以下使用效果评价指标，给予客观得分评价；
通过志愿者洗发测试评价结果，从图1雷达图可以表明实施例1的滋润感、柔软感好于对比例1，该多羟基化合物在洗涤组合物中起到调理、保湿作用。
对比例2
对比例2洗涤剂组合物配方与实施例1相比区别在于使用卡松(15ppm添加量)替代多羟基化合物。
对比例3
对比例3洗涤剂组合物配方与实施例1相比区别在于使用等量季铵三羟基二丙醚替代多羟基化合物。
对比例4
对比例4洗涤剂组合物配方与实施例1相比区别在于使用等量季铵三甲基二丙醚替代多羟基化合物。
对比例5
对比例5洗涤剂组合物配方与实施例1相比区别在于使用等量月桂基二甲基羟丙基甘油醚氯化铵替代多羟基化合物。
以USP32方法进行的防腐功效测试数据如下：
表1洗涤剂组合物防腐功效测试对比
表2洗涤剂组合物防腐功效测试对比
含有该多羟基化合物的洗涤组合物可以通过防腐剂功效测试，如实施例1和实施例2防腐功效测试；防腐效果基本等同卡松，见对比例2防腐功效测试；不含该多羟基化合物的洗涤组合物不能通过防腐功效测试，见对比例1防腐功效测试。含有等量的三羟基二丙醚、季铵三甲基二丙醚、月桂基二甲基羟丙基甘油醚氯化铵的洗涤组合物不能通过防腐剂功效测试，见对比例3、对比例4和对比例5防腐功效测试。该多羟基化合物在洗涤组合物中起到防腐剂作用。
对比例6
对比例6洗涤剂组合物配方与实施例1相比区别在于使用吡罗克酮乙醇胺盐(0.9％添加量)替代多羟基化合物。
以QB/T2738-2012(7.3)方法进行的糠秕马拉色菌杀菌、抑菌性能测试数据如下：
表3糠秕马拉色菌杀菌、抑菌测试对比
含有该多羟基化合物的洗涤组合物可以通过糠秕马拉色菌杀菌性能测试，如实施例1和实施例5糠秕马拉色菌杀菌、抑菌性能测试；杀菌效果>99％，基本等同于吡罗克酮乙醇胺，见对比例6糠秕马拉色菌杀菌、抑菌性能测试；不含该多羟基化合物的洗涤组合物不能通过糠秕马拉色菌杀菌、抑菌性能测试，见对比例1糠秕马拉色菌杀菌、抑菌性能测试。含有等量的三羟基二丙醚、季铵三甲基二丙醚、月桂基二甲基羟丙基甘油醚氯化铵的洗涤组合物不能通过糠秕马拉色菌杀菌、抑菌性能测试，见对比例3、对比例4和对比例5糠秕马拉色菌杀菌、抑菌性能测试。该多羟基化合物在洗涤组合物中起到糠秕马拉色菌杀菌作用。
以QB/T2738-2012(7.3)方法进行的痤疮丙酸杆菌杀菌、抑菌性能测试数据如下：
表4痤疮丙酸杆菌杀菌、抑菌性能测试对比
含有该多羟基化合物的洗涤组合物可以通过痤疮丙酸杆菌杀菌性能测试，杀菌效果>99，如实施例1和实施例3痤疮丙酸杆菌杀菌、抑菌性能测试。不含该多羟基化合物的洗涤组合物不能通过痤疮丙酸杆菌杀菌、抑菌测试，见对比例1痤疮丙酸杆菌杀菌、抑菌性能测试。含有等量的三羟基二丙醚、季铵三甲基二丙醚、月桂基二甲基羟丙基甘油醚氯化铵的洗涤组合物不能通过痤疮丙酸杆菌杀菌、抑菌性能测试，见对比例3、对比例4和对比例5痤疮丙酸杆菌杀菌、抑菌性能测试。该多羟基化合物在洗涤组合物中起到痤疮丙酸杆菌杀菌作用。
以上所述实施例的各技术特征可以进行任意的组合，为使描述简洁，未对上述实施例中的各个技术特征所有可能的组合都进行描述，然而，只要这些技术特征的组合不存在矛盾，都应当认为是本说明书记载的范围。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。

Claims (9)

1.一种洗涤剂组合物，其特征在于，包括如下组分：
(a)占组合物质量分数3-50％的表面活性剂；
(b)占组合物质量分数0.01-10％的功能助剂；
(c)占组合物质量分数0.1-25％的多羟基化合物；
(d)占组合物质量分数40-96％的溶剂。
2.根据权利要求1所述的洗涤剂组合物，其特征在于，所述多羟基化合物结构如下：
其中R1任选自C6-C20的烷基酰胺丙基、C6-C20的烷基酰胺乙基、C6-C20的烷基酰氧乙基、C6-C20的烷基酰氧丙基、C6-C20的烷基酰氧异丙基或H(OCH2CH2)n-，2≤n≤20；R2、R3分别任选自羟乙基、C1-C20的烷基、C6-C20的烷基酰胺丙基、C6-C20的烷基酰胺乙基、C6-C20的烷基酰氧乙基、C6-C20的烷基酰氧丙基、C6-C20的烷基酰氧异丙基或H(OCH2CH2)m-，2≤m≤20，R4为-OCH2CH(OH)CH2(OH)，X为Cl或Br。
3.根据权利要求1所述的洗涤剂组合物，其特征在于，所述表面活性剂选自阴离子表面活性剂、两性表面活性剂、非离子表面活性剂或阳离子表面活性剂中的一种或几种。
4.根据权利要求1所述的洗涤剂组合物，其特征在于，所述功能助剂选自维生素、螯合剂、香料、增白剂、酶、调理剂、增稠剂、引诱剂、染料、颜料、漂白剂以及珠光剂中的一种或几种。
5.根据权利要求1所述的洗涤剂组合物，其特征在于，所述溶剂选自水、乙醇、甘油、丙二醇、聚乙二醇、异丙醇中一种或几种。
6.根据权利要求4所述的洗涤剂组合物，其特征在于，所述的螯合剂选自：乙二胺四乙酸、氨基三乙酸、二亚乙基三胺五乙酸及其盐、柠檬酸、酒石酸和葡萄糖酸、羟乙基乙二胺三乙酸、二羟乙基甘氨酸、有机多元膦酸、聚丙烯酸、聚甲基丙烯酸、水解聚马来酸酐或富马酸-丙烯磺酸共聚体中一种或几种。
7.根据权利要求4所述的洗涤剂组合物，其特征在于，所述调理剂选自：阳离子瓜尔胶聚合物、阳离子非瓜尔胶半乳甘露聚糖聚合物、阳离子改性淀粉聚合物、丙烯酰胺单体与阳离子单体的共聚物、阳离子纤维素聚合物、聚硅氧烷或阳离子决明胶聚合物中一种或几种。
8.根据权利要求4所述的洗涤剂组合物，其特征在于，所述增稠剂选自：改性的羟乙基纤维素、疏水改性的聚丙烯酸酯、疏水改性的聚丙烯酸、疏水改性的聚丙烯酰胺、PEG-120甲基葡萄糖二油酸酯、PEG-40脱水山梨糖醇四油酸酯、PEG-60脱水山梨糖醇四油酸酯、PEG-150季戊四醇四硬脂酸酯、PEG-55丙二醇油酸酯或PEG-150二硬脂酸酯中一种或几种。
9.根据权利要求4所述的洗涤剂组合物，其特征在于，所述的珠光剂选自：硬脂酸乙二醇双酯、硬脂酸乙二醇单酯中一种或两种。
CN201711260326.8A 2017-12-04 2017-12-04 含有一种多羟基化合物的洗涤剂组合物 Pending CN107997974A (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201711260326.8A CN107997974A (zh) 2017-12-04 2017-12-04 含有一种多羟基化合物的洗涤剂组合物
PCT/CN2018/116731 WO2019109804A1 (zh) 2017-12-04 2018-11-21 含有一种多羟基化合物的洗涤剂组合物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711260326.8A CN107997974A (zh) 2017-12-04 2017-12-04 含有一种多羟基化合物的洗涤剂组合物

Publications (1)

Publication Number Publication Date
CN107997974A true CN107997974A (zh) 2018-05-08

Family

ID=62056514

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711260326.8A Pending CN107997974A (zh) 2017-12-04 2017-12-04 含有一种多羟基化合物的洗涤剂组合物

Country Status (2)

Country Link
CN (1) CN107997974A (zh)
WO (1) WO2019109804A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109010137A (zh) * 2018-09-30 2018-12-18 广州启正化工科技有限公司 一种清爽保湿型无硅油洗发水

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023235369A1 (en) * 2022-06-01 2023-12-07 Lubrizol Advanced Materials, Inc. Dilution thickening surfactant concentrates

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061240A (zh) * 1990-09-28 1992-05-20 普罗格特-甘布尔公司 含有阴离子表面活性剂、多羟基脂肪酸酰胺和一种严格筛选出的泡沫增强剂的洗涤剂组合物
JP2005256152A (ja) * 2004-03-15 2005-09-22 Chuo Kagaku Kk フラックス組成物
KR20070068814A (ko) * 2005-12-27 2007-07-02 주식회사 엘지생활건강 유사-비이온성 복합계면활성제를 이용한 메이크업 클렌징조성물
KR20070074744A (ko) * 2006-01-10 2007-07-18 주식회사 엘지생활건강 양이온성 화합물을 함유하는 염모제 조성물
WO2007094603A1 (en) * 2006-02-15 2007-08-23 Lg Household & Health Care Ltd. Manufacturing method of mixed surfactant system
US20080214849A1 (en) * 1998-08-06 2008-09-04 Max-Planck-Gesellschaft Zur Foerderung Der Wissenshaften E.V. Phospholipids with unsaturated alkyl and acyl chains
KR20080101107A (ko) * 2007-05-16 2008-11-21 주식회사 엘지생활건강 코아세르베이트 컨디셔너 조성물
KR20080103706A (ko) * 2007-05-25 2008-11-28 주식회사 엘지생활건강 양이온성 비닐 공중합체 함유 컨디셔닝 샴푸 조성물
CN101437486A (zh) * 2006-03-07 2009-05-20 荷兰联合利华有限公司 包含季铵三羟基取代的二丙基醚的个人护理组合物
KR20090117081A (ko) * 2008-05-08 2009-11-12 주식회사 엘지생활건강 바이오계면활성제 함유 컨디셔닝 샴푸 조성물
KR20100090894A (ko) * 2009-02-09 2010-08-18 주식회사 엘지생활건강 트랜스글루타미나제를 함유하는 컨디셔닝 샴푸 조성물
CN104945267A (zh) * 2015-06-17 2015-09-30 广州天赐高新材料股份有限公司 一种阳离子季铵盐及其制备方法
KR20150112645A (ko) * 2014-03-28 2015-10-07 주식회사 엘지생활건강 단일막 나노 베지클 및 그의 제조방법
CN105491990A (zh) * 2013-07-31 2016-04-13 花王株式会社 洗净剂组合物

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2645986B1 (en) * 2010-12-02 2015-02-25 Unilever PLC Anti-dandruff shampoo
CN102895151B (zh) * 2012-10-22 2014-04-16 广州立白企业集团有限公司 一种不含硫酸盐的毛发清洁剂及其制备方法

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061240A (zh) * 1990-09-28 1992-05-20 普罗格特-甘布尔公司 含有阴离子表面活性剂、多羟基脂肪酸酰胺和一种严格筛选出的泡沫增强剂的洗涤剂组合物
US20080214849A1 (en) * 1998-08-06 2008-09-04 Max-Planck-Gesellschaft Zur Foerderung Der Wissenshaften E.V. Phospholipids with unsaturated alkyl and acyl chains
JP2005256152A (ja) * 2004-03-15 2005-09-22 Chuo Kagaku Kk フラックス組成物
KR20070068814A (ko) * 2005-12-27 2007-07-02 주식회사 엘지생활건강 유사-비이온성 복합계면활성제를 이용한 메이크업 클렌징조성물
KR20070074744A (ko) * 2006-01-10 2007-07-18 주식회사 엘지생활건강 양이온성 화합물을 함유하는 염모제 조성물
WO2007094603A1 (en) * 2006-02-15 2007-08-23 Lg Household & Health Care Ltd. Manufacturing method of mixed surfactant system
CN101437486A (zh) * 2006-03-07 2009-05-20 荷兰联合利华有限公司 包含季铵三羟基取代的二丙基醚的个人护理组合物
KR20080101107A (ko) * 2007-05-16 2008-11-21 주식회사 엘지생활건강 코아세르베이트 컨디셔너 조성물
KR20080103706A (ko) * 2007-05-25 2008-11-28 주식회사 엘지생활건강 양이온성 비닐 공중합체 함유 컨디셔닝 샴푸 조성물
KR20090117081A (ko) * 2008-05-08 2009-11-12 주식회사 엘지생활건강 바이오계면활성제 함유 컨디셔닝 샴푸 조성물
KR20100090894A (ko) * 2009-02-09 2010-08-18 주식회사 엘지생활건강 트랜스글루타미나제를 함유하는 컨디셔닝 샴푸 조성물
CN105491990A (zh) * 2013-07-31 2016-04-13 花王株式会社 洗净剂组合物
KR20150112645A (ko) * 2014-03-28 2015-10-07 주식회사 엘지생활건강 단일막 나노 베지클 및 그의 제조방법
CN104945267A (zh) * 2015-06-17 2015-09-30 广州天赐高新材料股份有限公司 一种阳离子季铵盐及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109010137A (zh) * 2018-09-30 2018-12-18 广州启正化工科技有限公司 一种清爽保湿型无硅油洗发水

Also Published As

Publication number Publication date
WO2019109804A1 (zh) 2019-06-13

Similar Documents

Publication Publication Date Title
CN106750361B (zh) 一种木质素磺酸盐改性物及其应用以及包含该改性物的洗发水
JP5615515B2 (ja) 洗浄用組成物
KR101962994B1 (ko) 샴푸 조성물
JPWO2016104692A1 (ja) アシル塩基性アミノ酸誘導体を含有する洗浄剤組成物
CN102920619B (zh) 含少量硫酸盐阴离子表面活性剂的调理香波组合物
JP6911100B2 (ja) 抗菌性組成物
CN112535996B (zh) 一种含有双子季铵盐的表面活性剂组合物
US20200276099A1 (en) Plant-based cosmetic compositions
CN104095771B (zh) 一种氨基酸型表面活性剂自增稠组合物
JP5806526B2 (ja) 増泡剤及びそれを含有する洗浄剤組成物
JP3545372B2 (ja) 皮膚洗浄剤組成物
JP5502408B2 (ja) シャンプー組成物
CN107997974A (zh) 含有一种多羟基化合物的洗涤剂组合物
JP6097639B2 (ja) 洗浄剤組成物及びその使用方法
BR102016002245B1 (pt) Solução aquosa compreendendo aminoalquil betaínas de ácidos graxos
CN108403539A (zh) 一种宠物清洗剂的配方
CN116035933B (zh) 一种个人清洁护理组合物及其制备方法和应用
CN106265167A (zh) 一种组合物和洗发水及其制备方法
CN103251514B (zh) 一种去屑香波组合物
JP5742181B2 (ja) 毛髪洗浄剤組成物
CN105733839A (zh) 一种杀菌防霉柔顺洗衣液及其制作方法
CN104586645A (zh) 一种含烷基醇聚醚羧酸盐的洗涤组合物及含该洗涤组合物的香波
JP6666684B2 (ja) 毛髪洗浄組成物、褪色抑制剤、及びそれらを用いた毛髪の褪色を抑制する方法
JP6454980B2 (ja) 毛髪洗浄剤組成物
CN104095764B (zh) 一种氨基酸型表面活性剂自增稠组合物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180508