CN107954620A - A kind of Application way to sludge in sewage treatment plant - Google Patents
A kind of Application way to sludge in sewage treatment plant Download PDFInfo
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- CN107954620A CN107954620A CN201711319819.4A CN201711319819A CN107954620A CN 107954620 A CN107954620 A CN 107954620A CN 201711319819 A CN201711319819 A CN 201711319819A CN 107954620 A CN107954620 A CN 107954620A
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- Prior art keywords
- sludge
- parts
- oxide
- sintering
- sewage treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
Abstract
The present invention relates to sewage treatment project technical field, disclose a kind of Application way to sludge in sewage treatment plant, to the sludge after sewage plant processing as raw material, the processing of porous ceramics powder is carried out using adjuvant, using the organic matter in sludge as the foaming agent in sintering process, and heavy metal is fixedly arranged in haydite, eliminate the pollution problem of Heavy Metals in Sludge, process obtained light ceramics loose structure, resistance to activity, resistance to acid and alkali is fabulous, can be as the raw material of production and processing building materials, roadbed can also be used as, road surface, the lining private school material of aggregate and underground piping, reduce potential threat of the sludge to human lives, not only dispose sludge but also improve ecological environment.
Description
Technical field
The invention belongs to sewage treatment project technical field, and in particular to a kind of utilization side to sludge in sewage treatment plant
Method.
Background technology
Sludge is the product after sewage disposal, is that one kind is made of organic debris, microorganism, inorganic particle, colloid etc.
Extremely complex heterogeneous body.The key property of sludge is moisture content height(Up to more than 99%), high organic content, holds
Easily degenerate smelly, and particle is thinner, and proportion is smaller, jelly liquid.It is the concentrated thing between liquid and solid, can
To be transported with pump, but it is difficult to carry out separation of solid and liquid by settling.The component of sludge includes protein, lipid, urea, fiber
Element, nitrogen phosphorus, metal oxide, heavy metal and mineral matter etc..
There is scholar the 1960s to ensure that sludge treatment proposes safely a kind of i.e. sludge sanitary landfills of technological means.
Nowadays, sludge Sanitary Landfill Technology has tended to be ripe, is widely applied in practice.Although Sludge landfill is required basic
Threshold is low so that and the cost of sludge treatment is low, quick, method is simple etc., but in this process, Sludge landfill technology
Shortcoming is also gradually exposed.For example, erosion and other extraneous factors due to rainwater, the poisonous and harmful substance in sludge occurs
The leakage meeting gas such as polluted underground water environment, the methane of release is easy to set off an explosion and burn.Sludge landfill can produce largely
Methane gas, and methane gas produces atmospheric warming tremendous influence as greenhouse gases, or even can serious destruction ozone
Layer.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided a kind of Application way to sludge in sewage treatment plant,
Reduce potential threat of the sludge to human lives, not only disposed sludge but also improved ecological environment.
The present invention is achieved by the following technical solutions:
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 3.5-4.0% will be added in sludge, covered, stood using plastic foil after stirring evenly
It is placed in 115-125 DEG C of baking oven and is dried to water content in 3-5% scopes when 10-12 is small, is further ground to particle size and exists
200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 25-28:20-24:The ratio mixing of 3-5, is ground to 0.2-
0.4 micron, when sintering 3-4 is small at 1200-1300 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is dirt
The 14-18% of shale amount;
(3)Electric furnace is preheated to 220-240 DEG C, adds the sludge material of mixing, first section is heated to 400-600 DEG C, and insulation stops
800-1000 DEG C, when insulation stop 1-2 is small is heated to after when 2-3 is small, adds the auxiliary agent that mass fraction accounts for 2-3%, into sintering rank
Section, sintering temperature is in 1100-1200 DEG C of scope, and sintering time is after 20-25 minutes scopes, sintering with 30-35 DEG C/min
Speed cooling, Temperature fall after being reduced to 280-300 DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group
Into:45-50 parts of hydrogen peroxide, 25-30 parts of zinc oxide, 15-20 parts of manganese oxide, 12-15 parts of calcium hydroxide, two maleic acid of dibutyl alkene
10-12 parts of ester, 8-10 parts of borax, 5-8 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation
Calcium, ferrous oxide are according to 30-35:21-23:18-20:11-14:What the ratio of 7-9 was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection
Gas, nitrogen flow rate are maintained at 350-400 ml/mins.
The present invention has the following advantages compared with prior art:In order to solve the Treatment of Sludge produced in existing sewage treatment plant
The problem of mode is unreasonable, the present invention provides a kind of Application way to sludge in sewage treatment plant, is handled using sewage plant
Sludge afterwards carries out the processing of porous ceramics powder, using the organic matter in sludge as the foaming in sintering process as raw material
Agent, and heavy metal is fixedly arranged in haydite, the pollution problem of Heavy Metals in Sludge is eliminated, the light ceramics processed are porous
Structure, resistance to activity, resistance to acid and alkali are fabulous, can also be used as roadbed, road surface, concrete as the raw material of production and processing building materials
The lining private school material of aggregate and underground piping, reduces potential threat of the sludge to human lives, has not only disposed sludge but also improved
Ecological environment.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 3.5% will be added in sludge, covered after stirring evenly using plastic foil, it is small to stand 10
When be placed in 115 DEG C of baking ovens and dry to water content in 3-5% scopes, be further ground to particle size in 200-240 mesh models
Enclose;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 25:20:3 ratio mixing, is ground to 0.2 micron,
When sintering 3 is small at 1200 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is the 14% of sludge quality;
(3)Electric furnace is preheated to 220 DEG C, adds the sludge material of mixing, first section is heated to 400 DEG C, insulation stop 2 it is small when after plus
Heat is to 800 DEG C, when insulation stop 1 is small, adds the auxiliary agent that mass fraction accounts for 2%, into sintering stage, sintering temperature is in 1100-
1200 DEG C of scopes, sintering time are cooled down after 20-25 minutes scopes, sintering with 30 DEG C/min of speed, are reduced to 2800
Temperature fall after DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group
Into:45 parts of hydrogen peroxide, 25 parts of zinc oxide, 15 parts of manganese oxide, 12 parts of calcium hydroxide, 10 parts of dibutyl alkene dimaleate, borax 8
Part, 5 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation
Calcium, ferrous oxide are according to 30:21:18:11:What 7 ratio was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection
Gas, nitrogen flow rate are maintained at 350 ml/mins.
Embodiment 2
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 3.8% will be added in sludge, will be covered after stirring evenly using plastic foil, when standing 11 is small
It is placed in 120 DEG C of baking ovens and dries to water content in 3-5% scopes, is further ground to particle size in 200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 26:22:4 ratio mixing, is ground to 0.3 micron,
When sintering 3.5 is small at 1250 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is the 16% of sludge quality;
(3)Electric furnace is preheated to 230 DEG C, adds the sludge material of mixing, first section is heated to 500 DEG C, insulation stop 2.5 it is small when after
900 DEG C, when insulation stop 1.5 is small are heated to, adds the auxiliary agent that mass fraction accounts for 2.5%, into sintering stage, sintering temperature exists
1100-1200 DEG C of scope, sintering time are cooled down after 20-25 minutes scopes, sintering with 33 DEG C/min of speed, are reduced
Temperature fall after to 290 DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group
Into:48 parts of hydrogen peroxide, 28 parts of zinc oxide, 18 parts of manganese oxide, 13 parts of calcium hydroxide, 11 parts of dibutyl alkene dimaleate, borax 9
Part, 6 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation
Calcium, ferrous oxide are according to 33:22:19:12:What 8 ratio was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection
Gas, nitrogen flow rate are maintained at 380 ml/mins.
Embodiment 3
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 4.0% will be added in sludge, will be covered after stirring evenly using plastic foil, when standing 12 is small
It is placed in 125 DEG C of baking ovens and dries to water content in 3-5% scopes, is further ground to particle size in 200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 28:24:5 ratio mixing, is ground to 0.4 micron,
When sintering 4 is small at 1300 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is the 18% of sludge quality;
(3)Electric furnace is preheated to 240 DEG C, adds the sludge material of mixing, first section is heated to 600 DEG C, insulation stop 3 it is small when after plus
Heat is to 1000 DEG C, when insulation stop 2 is small, adds the auxiliary agent that mass fraction accounts for 3%, into sintering stage, sintering temperature is in 1100-
1200 DEG C of scopes, sintering time are cooled down after 20-25 minutes scopes, sintering with 35 DEG C/min of speed, are reduced to 300
Temperature fall after DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group
Into:50 parts of hydrogen peroxide, 30 parts of zinc oxide, 20 parts of manganese oxide, 15 parts of calcium hydroxide, 12 parts of dibutyl alkene dimaleate, borax
10 parts, 8 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation
Calcium, ferrous oxide are according to 35:23:20:14:What 9 ratio was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection
Gas, nitrogen flow rate are maintained at 400 ml/mins.
Claims (4)
1. a kind of Application way to sludge in sewage treatment plant, it is characterised in that comprise the following steps:
(1)The cleanser that mass fraction is 3.5-4.0% will be added in sludge, covered, stood using plastic foil after stirring evenly
It is placed in 115-125 DEG C of baking oven and is dried to water content in 3-5% scopes when 10-12 is small, is further ground to particle size and exists
200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 25-28:20-24:The ratio mixing of 3-5, is ground to 0.2-
0.4 micron, when sintering 3-4 is small at 1200-1300 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is dirt
The 14-18% of shale amount;
(3)Electric furnace is preheated to 220-240 DEG C, adds the sludge material of mixing, first section is heated to 400-600 DEG C, and insulation stops
800-1000 DEG C, when insulation stop 1-2 is small is heated to after when 2-3 is small, adds the auxiliary agent that mass fraction accounts for 2-3%, into sintering rank
Section, sintering temperature is in 1100-1200 DEG C of scope, and sintering time is after 20-25 minutes scopes, sintering with 30-35 DEG C/min
Speed cooling, Temperature fall after being reduced to 280-300 DEG C.
A kind of 2. Application way to sludge in sewage treatment plant as claimed in claim 1, it is characterised in that step(1)It is described
Cleanser consists of the following compositions in parts by weight:45-50 parts of hydrogen peroxide, 25-30 parts of zinc oxide, 15-20 parts of manganese oxide, hydrogen
12-15 parts of calcium oxide, 10-12 parts of dibutyl alkene dimaleate, 8-10 parts of borax, 5-8 parts of barium stearate.
A kind of 3. Application way to sludge in sewage treatment plant as claimed in claim 1, it is characterised in that step(3)It is described
Auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, calcium oxide, ferrous oxide according to 30-35:21-23:18-20:11-14:The ratio of 7-9
What example was mixed to get.
A kind of 4. Application way to sludge in sewage treatment plant as claimed in claim 1, it is characterised in that the step(3)
Nitrogen is used in the sintering process, and as protective gas, nitrogen flow rate is maintained at 350-400 ml/mins.
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CN201711319819.4A CN107954620A (en) | 2017-12-12 | 2017-12-12 | A kind of Application way to sludge in sewage treatment plant |
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CN201711319819.4A CN107954620A (en) | 2017-12-12 | 2017-12-12 | A kind of Application way to sludge in sewage treatment plant |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5830380A (en) * | 1981-08-17 | 1983-02-22 | Nittetsu Mining Co Ltd | Treatment for incineration ash of sewage sludge |
CN101234775A (en) * | 2007-12-28 | 2008-08-06 | 袁昧生 | Processing reusing method for industrial sludge solid waste containing aluminum hydroxide |
CN101407383A (en) * | 2008-10-30 | 2009-04-15 | 上海交通大学 | Gel material for consolidating wastes and method for preparing construction material |
CN101914404A (en) * | 2010-08-20 | 2010-12-15 | 长沙达华污泥处理科技有限公司 | Method for preparing solid fuel from sludge of sewage treatment plant |
CN102079851A (en) * | 2010-11-25 | 2011-06-01 | 华南农业大学 | Disposable degradable material produced by using residual active sludge and preparation method thereof |
CN102924066A (en) * | 2012-11-05 | 2013-02-13 | 刘贡友 | Siliceous composite plate, and preparation method and application thereof |
CN105272161A (en) * | 2015-11-09 | 2016-01-27 | 四川环奥污泥处置技术有限公司 | Sludge sintered brick auxiliary and application thereof |
CN105732066A (en) * | 2016-03-09 | 2016-07-06 | 李�杰 | Re-utilizing method of sludge in municipal sewage treatment plant |
-
2017
- 2017-12-12 CN CN201711319819.4A patent/CN107954620A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5830380A (en) * | 1981-08-17 | 1983-02-22 | Nittetsu Mining Co Ltd | Treatment for incineration ash of sewage sludge |
CN101234775A (en) * | 2007-12-28 | 2008-08-06 | 袁昧生 | Processing reusing method for industrial sludge solid waste containing aluminum hydroxide |
CN101407383A (en) * | 2008-10-30 | 2009-04-15 | 上海交通大学 | Gel material for consolidating wastes and method for preparing construction material |
CN101914404A (en) * | 2010-08-20 | 2010-12-15 | 长沙达华污泥处理科技有限公司 | Method for preparing solid fuel from sludge of sewage treatment plant |
CN102079851A (en) * | 2010-11-25 | 2011-06-01 | 华南农业大学 | Disposable degradable material produced by using residual active sludge and preparation method thereof |
CN102924066A (en) * | 2012-11-05 | 2013-02-13 | 刘贡友 | Siliceous composite plate, and preparation method and application thereof |
CN105272161A (en) * | 2015-11-09 | 2016-01-27 | 四川环奥污泥处置技术有限公司 | Sludge sintered brick auxiliary and application thereof |
CN105732066A (en) * | 2016-03-09 | 2016-07-06 | 李�杰 | Re-utilizing method of sludge in municipal sewage treatment plant |
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Application publication date: 20180424 |