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CN107954620A - A kind of Application way to sludge in sewage treatment plant - Google Patents

A kind of Application way to sludge in sewage treatment plant Download PDF

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Publication number
CN107954620A
CN107954620A CN201711319819.4A CN201711319819A CN107954620A CN 107954620 A CN107954620 A CN 107954620A CN 201711319819 A CN201711319819 A CN 201711319819A CN 107954620 A CN107954620 A CN 107954620A
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CN
China
Prior art keywords
sludge
parts
oxide
sintering
sewage treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711319819.4A
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Chinese (zh)
Inventor
祁芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Yu Rui Environmental Protection Construction Co Ltd
Original Assignee
Anhui Yu Rui Environmental Protection Construction Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Yu Rui Environmental Protection Construction Co Ltd filed Critical Anhui Yu Rui Environmental Protection Construction Co Ltd
Priority to CN201711319819.4A priority Critical patent/CN107954620A/en
Publication of CN107954620A publication Critical patent/CN107954620A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/027Lightweight materials

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The present invention relates to sewage treatment project technical field, disclose a kind of Application way to sludge in sewage treatment plant, to the sludge after sewage plant processing as raw material, the processing of porous ceramics powder is carried out using adjuvant, using the organic matter in sludge as the foaming agent in sintering process, and heavy metal is fixedly arranged in haydite, eliminate the pollution problem of Heavy Metals in Sludge, process obtained light ceramics loose structure, resistance to activity, resistance to acid and alkali is fabulous, can be as the raw material of production and processing building materials, roadbed can also be used as, road surface, the lining private school material of aggregate and underground piping, reduce potential threat of the sludge to human lives, not only dispose sludge but also improve ecological environment.

Description

A kind of Application way to sludge in sewage treatment plant
Technical field
The invention belongs to sewage treatment project technical field, and in particular to a kind of utilization side to sludge in sewage treatment plant Method.
Background technology
Sludge is the product after sewage disposal, is that one kind is made of organic debris, microorganism, inorganic particle, colloid etc. Extremely complex heterogeneous body.The key property of sludge is moisture content height(Up to more than 99%), high organic content, holds Easily degenerate smelly, and particle is thinner, and proportion is smaller, jelly liquid.It is the concentrated thing between liquid and solid, can To be transported with pump, but it is difficult to carry out separation of solid and liquid by settling.The component of sludge includes protein, lipid, urea, fiber Element, nitrogen phosphorus, metal oxide, heavy metal and mineral matter etc..
There is scholar the 1960s to ensure that sludge treatment proposes safely a kind of i.e. sludge sanitary landfills of technological means. Nowadays, sludge Sanitary Landfill Technology has tended to be ripe, is widely applied in practice.Although Sludge landfill is required basic Threshold is low so that and the cost of sludge treatment is low, quick, method is simple etc., but in this process, Sludge landfill technology Shortcoming is also gradually exposed.For example, erosion and other extraneous factors due to rainwater, the poisonous and harmful substance in sludge occurs The leakage meeting gas such as polluted underground water environment, the methane of release is easy to set off an explosion and burn.Sludge landfill can produce largely Methane gas, and methane gas produces atmospheric warming tremendous influence as greenhouse gases, or even can serious destruction ozone Layer.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided a kind of Application way to sludge in sewage treatment plant, Reduce potential threat of the sludge to human lives, not only disposed sludge but also improved ecological environment.
The present invention is achieved by the following technical solutions:
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 3.5-4.0% will be added in sludge, covered, stood using plastic foil after stirring evenly It is placed in 115-125 DEG C of baking oven and is dried to water content in 3-5% scopes when 10-12 is small, is further ground to particle size and exists 200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 25-28:20-24:The ratio mixing of 3-5, is ground to 0.2- 0.4 micron, when sintering 3-4 is small at 1200-1300 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is dirt The 14-18% of shale amount;
(3)Electric furnace is preheated to 220-240 DEG C, adds the sludge material of mixing, first section is heated to 400-600 DEG C, and insulation stops 800-1000 DEG C, when insulation stop 1-2 is small is heated to after when 2-3 is small, adds the auxiliary agent that mass fraction accounts for 2-3%, into sintering rank Section, sintering temperature is in 1100-1200 DEG C of scope, and sintering time is after 20-25 minutes scopes, sintering with 30-35 DEG C/min Speed cooling, Temperature fall after being reduced to 280-300 DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group Into:45-50 parts of hydrogen peroxide, 25-30 parts of zinc oxide, 15-20 parts of manganese oxide, 12-15 parts of calcium hydroxide, two maleic acid of dibutyl alkene 10-12 parts of ester, 8-10 parts of borax, 5-8 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation Calcium, ferrous oxide are according to 30-35:21-23:18-20:11-14:What the ratio of 7-9 was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection Gas, nitrogen flow rate are maintained at 350-400 ml/mins.
The present invention has the following advantages compared with prior art:In order to solve the Treatment of Sludge produced in existing sewage treatment plant The problem of mode is unreasonable, the present invention provides a kind of Application way to sludge in sewage treatment plant, is handled using sewage plant Sludge afterwards carries out the processing of porous ceramics powder, using the organic matter in sludge as the foaming in sintering process as raw material Agent, and heavy metal is fixedly arranged in haydite, the pollution problem of Heavy Metals in Sludge is eliminated, the light ceramics processed are porous Structure, resistance to activity, resistance to acid and alkali are fabulous, can also be used as roadbed, road surface, concrete as the raw material of production and processing building materials The lining private school material of aggregate and underground piping, reduces potential threat of the sludge to human lives, has not only disposed sludge but also improved Ecological environment.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 3.5% will be added in sludge, covered after stirring evenly using plastic foil, it is small to stand 10 When be placed in 115 DEG C of baking ovens and dry to water content in 3-5% scopes, be further ground to particle size in 200-240 mesh models Enclose;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 25:20:3 ratio mixing, is ground to 0.2 micron, When sintering 3 is small at 1200 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is the 14% of sludge quality;
(3)Electric furnace is preheated to 220 DEG C, adds the sludge material of mixing, first section is heated to 400 DEG C, insulation stop 2 it is small when after plus Heat is to 800 DEG C, when insulation stop 1 is small, adds the auxiliary agent that mass fraction accounts for 2%, into sintering stage, sintering temperature is in 1100- 1200 DEG C of scopes, sintering time are cooled down after 20-25 minutes scopes, sintering with 30 DEG C/min of speed, are reduced to 2800 Temperature fall after DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group Into:45 parts of hydrogen peroxide, 25 parts of zinc oxide, 15 parts of manganese oxide, 12 parts of calcium hydroxide, 10 parts of dibutyl alkene dimaleate, borax 8 Part, 5 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation Calcium, ferrous oxide are according to 30:21:18:11:What 7 ratio was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection Gas, nitrogen flow rate are maintained at 350 ml/mins.
Embodiment 2
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 3.8% will be added in sludge, will be covered after stirring evenly using plastic foil, when standing 11 is small It is placed in 120 DEG C of baking ovens and dries to water content in 3-5% scopes, is further ground to particle size in 200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 26:22:4 ratio mixing, is ground to 0.3 micron, When sintering 3.5 is small at 1250 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is the 16% of sludge quality;
(3)Electric furnace is preheated to 230 DEG C, adds the sludge material of mixing, first section is heated to 500 DEG C, insulation stop 2.5 it is small when after 900 DEG C, when insulation stop 1.5 is small are heated to, adds the auxiliary agent that mass fraction accounts for 2.5%, into sintering stage, sintering temperature exists 1100-1200 DEG C of scope, sintering time are cooled down after 20-25 minutes scopes, sintering with 33 DEG C/min of speed, are reduced Temperature fall after to 290 DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group Into:48 parts of hydrogen peroxide, 28 parts of zinc oxide, 18 parts of manganese oxide, 13 parts of calcium hydroxide, 11 parts of dibutyl alkene dimaleate, borax 9 Part, 6 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation Calcium, ferrous oxide are according to 33:22:19:12:What 8 ratio was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection Gas, nitrogen flow rate are maintained at 380 ml/mins.
Embodiment 3
A kind of Application way to sludge in sewage treatment plant, comprises the following steps:
(1)The cleanser that mass fraction is 4.0% will be added in sludge, will be covered after stirring evenly using plastic foil, when standing 12 is small It is placed in 125 DEG C of baking ovens and dries to water content in 3-5% scopes, is further ground to particle size in 200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 28:24:5 ratio mixing, is ground to 0.4 micron, When sintering 4 is small at 1300 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is the 18% of sludge quality;
(3)Electric furnace is preheated to 240 DEG C, adds the sludge material of mixing, first section is heated to 600 DEG C, insulation stop 3 it is small when after plus Heat is to 1000 DEG C, when insulation stop 2 is small, adds the auxiliary agent that mass fraction accounts for 3%, into sintering stage, sintering temperature is in 1100- 1200 DEG C of scopes, sintering time are cooled down after 20-25 minutes scopes, sintering with 35 DEG C/min of speed, are reduced to 300 Temperature fall after DEG C.
As further improvement of these options, step(1)The cleanser is in parts by weight by following component group Into:50 parts of hydrogen peroxide, 30 parts of zinc oxide, 20 parts of manganese oxide, 15 parts of calcium hydroxide, 12 parts of dibutyl alkene dimaleate, borax 10 parts, 8 parts of barium stearate.
As further improvement of these options, step(3)The auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, oxidation Calcium, ferrous oxide are according to 35:23:20:14:What 9 ratio was mixed to get.
As further improvement of these options, the step(3)Nitrogen is used in the sintering process as protection Gas, nitrogen flow rate are maintained at 400 ml/mins.

Claims (4)

1. a kind of Application way to sludge in sewage treatment plant, it is characterised in that comprise the following steps:
(1)The cleanser that mass fraction is 3.5-4.0% will be added in sludge, covered, stood using plastic foil after stirring evenly It is placed in 115-125 DEG C of baking oven and is dried to water content in 3-5% scopes when 10-12 is small, is further ground to particle size and exists 200-240 mesh scopes;
(2)Using aluminium oxide, silicon nitride, yittrium oxide as raw material, according to 25-28:20-24:The ratio mixing of 3-5, is ground to 0.2- 0.4 micron, when sintering 3-4 is small at 1200-1300 DEG C, it is added to after cooling in the sludge after grinding and mixes, additive amount is dirt The 14-18% of shale amount;
(3)Electric furnace is preheated to 220-240 DEG C, adds the sludge material of mixing, first section is heated to 400-600 DEG C, and insulation stops 800-1000 DEG C, when insulation stop 1-2 is small is heated to after when 2-3 is small, adds the auxiliary agent that mass fraction accounts for 2-3%, into sintering rank Section, sintering temperature is in 1100-1200 DEG C of scope, and sintering time is after 20-25 minutes scopes, sintering with 30-35 DEG C/min Speed cooling, Temperature fall after being reduced to 280-300 DEG C.
A kind of 2. Application way to sludge in sewage treatment plant as claimed in claim 1, it is characterised in that step(1)It is described Cleanser consists of the following compositions in parts by weight:45-50 parts of hydrogen peroxide, 25-30 parts of zinc oxide, 15-20 parts of manganese oxide, hydrogen 12-15 parts of calcium oxide, 10-12 parts of dibutyl alkene dimaleate, 8-10 parts of borax, 5-8 parts of barium stearate.
A kind of 3. Application way to sludge in sewage treatment plant as claimed in claim 1, it is characterised in that step(3)It is described Auxiliary agent is by potassium oxide, sodium oxide molybdena, magnesia, calcium oxide, ferrous oxide according to 30-35:21-23:18-20:11-14:The ratio of 7-9 What example was mixed to get.
A kind of 4. Application way to sludge in sewage treatment plant as claimed in claim 1, it is characterised in that the step(3) Nitrogen is used in the sintering process, and as protective gas, nitrogen flow rate is maintained at 350-400 ml/mins.
CN201711319819.4A 2017-12-12 2017-12-12 A kind of Application way to sludge in sewage treatment plant Pending CN107954620A (en)

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Application Number Priority Date Filing Date Title
CN201711319819.4A CN107954620A (en) 2017-12-12 2017-12-12 A kind of Application way to sludge in sewage treatment plant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5830380A (en) * 1981-08-17 1983-02-22 Nittetsu Mining Co Ltd Treatment for incineration ash of sewage sludge
CN101234775A (en) * 2007-12-28 2008-08-06 袁昧生 Processing reusing method for industrial sludge solid waste containing aluminum hydroxide
CN101407383A (en) * 2008-10-30 2009-04-15 上海交通大学 Gel material for consolidating wastes and method for preparing construction material
CN101914404A (en) * 2010-08-20 2010-12-15 长沙达华污泥处理科技有限公司 Method for preparing solid fuel from sludge of sewage treatment plant
CN102079851A (en) * 2010-11-25 2011-06-01 华南农业大学 Disposable degradable material produced by using residual active sludge and preparation method thereof
CN102924066A (en) * 2012-11-05 2013-02-13 刘贡友 Siliceous composite plate, and preparation method and application thereof
CN105272161A (en) * 2015-11-09 2016-01-27 四川环奥污泥处置技术有限公司 Sludge sintered brick auxiliary and application thereof
CN105732066A (en) * 2016-03-09 2016-07-06 李�杰 Re-utilizing method of sludge in municipal sewage treatment plant

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5830380A (en) * 1981-08-17 1983-02-22 Nittetsu Mining Co Ltd Treatment for incineration ash of sewage sludge
CN101234775A (en) * 2007-12-28 2008-08-06 袁昧生 Processing reusing method for industrial sludge solid waste containing aluminum hydroxide
CN101407383A (en) * 2008-10-30 2009-04-15 上海交通大学 Gel material for consolidating wastes and method for preparing construction material
CN101914404A (en) * 2010-08-20 2010-12-15 长沙达华污泥处理科技有限公司 Method for preparing solid fuel from sludge of sewage treatment plant
CN102079851A (en) * 2010-11-25 2011-06-01 华南农业大学 Disposable degradable material produced by using residual active sludge and preparation method thereof
CN102924066A (en) * 2012-11-05 2013-02-13 刘贡友 Siliceous composite plate, and preparation method and application thereof
CN105272161A (en) * 2015-11-09 2016-01-27 四川环奥污泥处置技术有限公司 Sludge sintered brick auxiliary and application thereof
CN105732066A (en) * 2016-03-09 2016-07-06 李�杰 Re-utilizing method of sludge in municipal sewage treatment plant

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Application publication date: 20180424