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CN107938324A - Wear-resistant ribbon and preparation method thereof - Google Patents

Wear-resistant ribbon and preparation method thereof Download PDF

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Publication number
CN107938324A
CN107938324A CN201711393028.6A CN201711393028A CN107938324A CN 107938324 A CN107938324 A CN 107938324A CN 201711393028 A CN201711393028 A CN 201711393028A CN 107938324 A CN107938324 A CN 107938324A
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CN
China
Prior art keywords
weight
parts
preparation
ribbon
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711393028.6A
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Chinese (zh)
Inventor
桑国海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Performance Number Electronic Science And Technology Co Ltd
Original Assignee
Wuhu Performance Number Electronic Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201711393028.6A priority Critical patent/CN107938324A/en
Publication of CN107938324A publication Critical patent/CN107938324A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/09Cellulose ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/11Starch or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)

Abstract

The invention discloses a kind of wear-resistant ribbon and preparation method thereof, wherein, the preparation method includes:1) nano-calcium carbonate, graphene and nano-titanium dioxide is placed in acid solution after soaking and taken out, particulate matter M1 is made;2) under the conditions of existing for water, drying and grinding after vermiculite is mixed with starch, is made powder M2;3) polyurethane resin, particulate matter M1, powder M2 and sodium carboxymethylcellulose are mixed, applicator M3 is made;4) applicator M3 is coated on ribbon surface, wear-resistant ribbon is made.Nano-calcium carbonate, graphene and nano-titanium dioxide are placed in acid solution by the present invention to be soaked, drying and grinding after again mixing vermiculite and starch under the conditions of existing for water, further, ribbon surface is coated on after polyurethane resin, above-mentioned particulate matter, powder and sodium carboxymethylcellulose are mixed, so that there are good abrasion resistance properties by ribbon made from the above method, its performance is greatly improved.

Description

Wear-resistant ribbon and preparation method thereof
Technical field
The present invention relates to webbing material field, and in particular, to wear-resistant ribbon and preparation method thereof.
Background technology
It is well known that ribbon, as important braided material, it can be woven to any appropriate product by braider. Thus, the quality of ribbon will largely effect on the performance of obtained product.And it is well known that ribbon is often easily worn, cause The quality of its product woven goes wrong.
Therefore it provides a kind of have good abrasion resistance properties, and then greatly improve the performance of obtained knitting Wear-resistant ribbon and preparation method thereof the problem of being urgent need to resolve of the present invention.
The content of the invention
For the above-mentioned prior art, it is an object of the invention to overcome in the prior art ribbon be often easily worn, lead Cause its quality of product woven to go wrong, thus provide it is a kind of there are good abrasion resistance properties, and then greatly improve system Wear-resistant ribbon of performance of knitting obtained and preparation method thereof.
To achieve these goals, the present invention provides a kind of preparation method of wear-resistant ribbon, wherein, the preparation side Method includes:
1) nano-calcium carbonate, graphene and nano-titanium dioxide is placed in acid solution after soaking and taken out, particulate matter M1 is made;
2) under the conditions of existing for water, drying and grinding after vermiculite is mixed with starch, is made powder M2;
3) polyurethane resin, particulate matter M1, powder M2 and sodium carboxymethylcellulose are mixed, applicator M3 is made;
4) applicator M3 is coated on ribbon surface, wear-resistant ribbon is made.
Present invention also offers a kind of ribbon wear-resistant according to made from preparation method described above.
Through the above technical solutions, nano-calcium carbonate, graphene and nano-titanium dioxide are placed in acid solution and soak by the present invention Bubble, then drying and grinding after vermiculite and starch are mixed under the conditions of existing for water, further, by polyurethane resin, above-mentioned Ribbon surface is coated on after grain thing, powder and sodium carboxymethylcellulose mixing, so that passing through ribbon made from the above method With good abrasion resistance properties, its performance is greatly improved.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The endpoint of disclosed scope and any value are not limited to the accurate scope or value herein, these scopes or Value should be understood to comprising the value close to these scopes or value.For number range, between the endpoint value of each scope, respectively It can be combined with each other between the endpoint value of a scope and single point value, and individually between point value and obtain one or more New number range, these number ranges should be considered as specific open herein.
The present invention provides a kind of preparation method of wear-resistant ribbon, wherein, the preparation method includes:
1) nano-calcium carbonate, graphene and nano-titanium dioxide is placed in acid solution after soaking and taken out, particulate matter M1 is made;
2) under the conditions of existing for water, drying and grinding after vermiculite is mixed with starch, is made powder M2;
3) polyurethane resin, particulate matter M1, powder M2 and sodium carboxymethylcellulose are mixed, applicator M3 is made;
4) applicator M3 is coated on ribbon surface, wear-resistant ribbon is made.
The present invention a kind of preferred embodiment in, in step 1), the acid solution be selected from hydrochloric acid aqueous solution and/or The aqueous solution of nitric acid.
In further preferred embodiment, sour concentration is 1-3mol/L in the acid solution.
In another preferred embodiment of the present invention, in step 1), relative to the nano-calcium carbonate of 10 parts by weight Calcium, the dosage of the graphene is 30-40 parts by weight, and the dosage of the nano-titanium dioxide is 5-15 parts by weight.
In a kind of embodiment being more highly preferred to, in step 2), the mixed process includes:Water and starch are mixed, system Gelatinized corn starch is obtained, drying and grinding after vermiculite mixing is added into gelatinized corn starch.
In another preferred embodiment of the present invention, relative to the vermiculite of 10 parts by weight, the use of the starch Measure as 5-10 parts by weight.
It is described relative to the polyurethane resin of 100 parts by weight in step 3) in further preferred embodiment The dosage of particulate matter M1 is 10-30 parts by weight, and the dosage of the powder M2 is 5-20 parts by weight, the sodium carboxymethylcellulose Dosage is 5-10 parts by weight.
In a kind of preferred embodiment of the present invention, in step 4), the applicator M3 coated on the ribbon surface Thickness be 0.01-0.5mm.
Present invention also offers a kind of ribbon wear-resistant according to made from preparation method described above.
The present invention will be described in detail by way of examples below.
Embodiment 1
1) nano-calcium carbonate of 10 parts by weight, 30 parts by weight of graphite alkene and 5 parts by weight nano-titanium dioxides are placed in concentration To be taken out in the aqueous solution of the hydrochloric acid of 1mol/L after immersion, particulate matter M1 is made;
2) water of 100 parts by weight and 5 weight starch are mixed, gelatinized corn starch is made, 10 parts by weight are added into gelatinized corn starch Vermiculite mixing after drying and grinding, powder M2 is made;
3) by the polyurethane resin of 100 parts by weight, 10 parts by weight particulate matter M1,5 parts by weight of powder M2 and 5 parts by weight carboxylic first Base sodium cellulosate mixes, and applicator M3 is made;
4) it is 0.01mm coated on ribbon surface to the thickness coated by applicator M3, wear-resistant ribbon A1 is made.
Embodiment 2
1) nano-calcium carbonate of 10 parts by weight, 40 parts by weight of graphite alkene and 15 parts by weight nano-titanium dioxides are placed in concentration To be taken out in the aqueous solution of the hydrochloric acid of 3mol/L after immersion, particulate matter M1 is made;
2) water of 100 parts by weight and 10 weight starch are mixed, gelatinized corn starch is made, 10 parts by weight are added into gelatinized corn starch Vermiculite mixing after drying and grinding, powder M2 is made;
3) by the polyurethane resin of 100 parts by weight, 30 parts by weight particulate matter M1,20 parts by weight of powder M2 and 10 parts by weight carboxylics Sodium carboxymethylcellulose pyce mixes, and applicator M3 is made;
4) it is 0.5mm coated on ribbon surface to the thickness coated by applicator M3, wear-resistant ribbon A2 is made.
Embodiment 3
1) nano-calcium carbonate of 10 parts by weight, 35 parts by weight of graphite alkene and 10 parts by weight nano-titanium dioxides are placed in concentration To be taken out in the aqueous solution of the hydrochloric acid of 2mol/L after immersion, particulate matter M1 is made;
2) water of 100 parts by weight and 8 weight starch are mixed, gelatinized corn starch is made, 10 parts by weight are added into gelatinized corn starch Vermiculite mixing after drying and grinding, powder M2 is made;
3) by the polyurethane resin of 100 parts by weight, 20 parts by weight particulate matter M1,10 parts by weight of powder M2 and 8 parts by weight carboxylics Sodium carboxymethylcellulose pyce mixes, and applicator M3 is made;
4) it is 0.3mm coated on ribbon surface to the thickness coated by applicator M3, wear-resistant ribbon A3 is made.
Embodiment 4
It is prepared by the preparation method according to embodiment 1, unlike, the dosage of the graphene is 10 parts by weight, institute The dosage for stating nano-titanium dioxide is 2 parts by weight, and wear-resistant ribbon A4 is made.
Embodiment 5
It is prepared by the preparation method according to embodiment 2, unlike, the dosage of the particulate matter M1 is 5 parts by weight, institute The dosage for stating powder M2 is 2 parts by weight, and the dosage of the sodium carboxymethylcellulose is 2 parts by weight, and wear-resistant ribbon A5 is made.
Comparative example 1
It is prepared by the preparation method according to embodiment 1, unlike, graphene and nano-titanium dioxide are added without, is made Obtain ribbon D1.
Comparative example 2
It is prepared by the preparation method according to embodiment 2, unlike, without step 2), ribbon D2 is made.
Comparative example 3
The ribbon D3 of uncoated any material.
Test case
Above-mentioned A1-A5, D1-D3 are placed on braid abrasion resistance testing machine and tested, obtains that the results are shown in Table 1.
Table 1
The preferred embodiment of the present invention described in detail above, still, during present invention is not limited to the embodiments described above Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should equally be considered as content disclosed in this invention.

Claims (9)

1. a kind of preparation method of wear-resistant ribbon, it is characterised in that the preparation method includes:
1) nano-calcium carbonate, graphene and nano-titanium dioxide is placed in acid solution after soaking and taken out, particulate matter M1 is made;
2) under the conditions of existing for water, drying and grinding after vermiculite is mixed with starch, is made powder M2;
3) polyurethane resin, particulate matter M1, powder M2 and sodium carboxymethylcellulose are mixed, applicator M3 is made;
4) applicator M3 is coated on ribbon surface, wear-resistant ribbon is made.
2. preparation method according to claim 1, wherein, in step 1), the acid solution be selected from hydrochloric acid aqueous solution and/or The aqueous solution of nitric acid.
3. preparation method according to claim 1 or 2, wherein, sour concentration is 1-3mol/L in the acid solution.
4. preparation method according to claim 1 or 2, wherein, in step 1), relative to the nano-sized carbon of 10 parts by weight Sour calcium, the dosage of the graphene is 30-40 parts by weight, and the dosage of the nano-titanium dioxide is 5-15 parts by weight.
5. preparation method according to claim 1 or 2, wherein, in step 2), the mixed process includes:By water and shallow lake Powder mixes, and gelatinized corn starch is made, and drying and grinding after vermiculite mixing is added into gelatinized corn starch.
6. preparation method according to claim 5, wherein, relative to the vermiculite of 10 parts by weight, the use of the starch Measure as 5-10 parts by weight.
7. preparation method according to claim 1 or 2, wherein, in step 3), relative to the poly- ammonia of 100 parts by weight Ester resin, the dosage of the particulate matter M1 are 10-30 parts by weight, and the dosage of the powder M2 is 5-20 parts by weight, the carboxylic first The dosage of base sodium cellulosate is 5-10 parts by weight.
8. preparation method according to claim 1 or 2, wherein, in step 4), the applicator coated on the ribbon surface The thickness of M3 is 0.01-0.5mm.
9. wear-resistant ribbon made from the preparation method in a kind of 1-8 according to claim described in any one.
CN201711393028.6A 2017-12-21 2017-12-21 Wear-resistant ribbon and preparation method thereof Pending CN107938324A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711393028.6A CN107938324A (en) 2017-12-21 2017-12-21 Wear-resistant ribbon and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711393028.6A CN107938324A (en) 2017-12-21 2017-12-21 Wear-resistant ribbon and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107938324A true CN107938324A (en) 2018-04-20

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN107938324A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109281171A (en) * 2018-09-28 2019-01-29 安徽省永欣织带有限公司 A kind of preparation method of the anti-breaking silk weaving with coating

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103790023A (en) * 2014-01-20 2014-05-14 南通全技纺织涂层有限公司 Moisture-permeable wear-resistant coating fabric
CN104894874A (en) * 2015-06-29 2015-09-09 宣乐 Preparation method of windproof breathable moisture-permeable coating
CN105802479A (en) * 2016-06-04 2016-07-27 付学勇 Wear-resistant self-cleaning coating and preparation method and application method thereof
US20170253751A1 (en) * 2016-01-22 2017-09-07 Voxel8, Inc. 3d printable composite waterborne dispersions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103790023A (en) * 2014-01-20 2014-05-14 南通全技纺织涂层有限公司 Moisture-permeable wear-resistant coating fabric
CN104894874A (en) * 2015-06-29 2015-09-09 宣乐 Preparation method of windproof breathable moisture-permeable coating
US20170253751A1 (en) * 2016-01-22 2017-09-07 Voxel8, Inc. 3d printable composite waterborne dispersions
CN105802479A (en) * 2016-06-04 2016-07-27 付学勇 Wear-resistant self-cleaning coating and preparation method and application method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109281171A (en) * 2018-09-28 2019-01-29 安徽省永欣织带有限公司 A kind of preparation method of the anti-breaking silk weaving with coating

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Application publication date: 20180420

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