CN107903680A - Aerogel-containing environment-friendly coating and preparation method thereof - Google Patents
Aerogel-containing environment-friendly coating and preparation method thereof Download PDFInfo
- Publication number
- CN107903680A CN107903680A CN201711198717.1A CN201711198717A CN107903680A CN 107903680 A CN107903680 A CN 107903680A CN 201711198717 A CN201711198717 A CN 201711198717A CN 107903680 A CN107903680 A CN 107903680A
- Authority
- CN
- China
- Prior art keywords
- parts
- uniformly mixed
- environmental protection
- temperature
- coating material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 63
- 238000000576 coating method Methods 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000004964 aerogel Substances 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 77
- 229920001661 Chitosan Polymers 0.000 claims abstract description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 30
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 28
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 28
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 26
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 26
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 26
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 19
- 239000000945 filler Substances 0.000 claims abstract description 17
- 108010010803 Gelatin Proteins 0.000 claims abstract description 15
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 15
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 15
- 239000008273 gelatin Substances 0.000 claims abstract description 15
- 229920000159 gelatin Polymers 0.000 claims abstract description 15
- 235000019322 gelatine Nutrition 0.000 claims abstract description 15
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 15
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 15
- 239000011976 maleic acid Substances 0.000 claims abstract description 15
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 15
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 15
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 claims abstract description 15
- 239000004814 polyurethane Substances 0.000 claims abstract description 15
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- 239000010936 titanium Substances 0.000 claims abstract description 15
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 15
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims abstract description 14
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 14
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 229920002545 silicone oil Polymers 0.000 claims abstract description 9
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract 3
- 230000007613 environmental effect Effects 0.000 claims description 53
- 238000003756 stirring Methods 0.000 claims description 46
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 32
- 229910000077 silane Inorganic materials 0.000 claims description 32
- 239000000654 additive Substances 0.000 claims description 29
- 230000000996 additive effect Effects 0.000 claims description 29
- 238000010792 warming Methods 0.000 claims description 26
- 239000003153 chemical reaction reagent Substances 0.000 claims description 23
- 230000008878 coupling Effects 0.000 claims description 23
- 238000010168 coupling process Methods 0.000 claims description 23
- 238000005859 coupling reaction Methods 0.000 claims description 23
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 16
- -1 methyl Hydroxy-ethyl Chemical group 0.000 claims description 15
- 239000000839 emulsion Substances 0.000 claims description 14
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 14
- 229920001296 polysiloxane Polymers 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 9
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229940043237 diethanolamine Drugs 0.000 claims description 8
- 235000019197 fats Nutrition 0.000 claims description 8
- 239000012188 paraffin wax Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- 239000003240 coconut oil Substances 0.000 claims description 7
- 235000019864 coconut oil Nutrition 0.000 claims description 7
- 235000019359 magnesium stearate Nutrition 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 4
- 239000012279 sodium borohydride Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 2
- 244000269722 Thea sinensis Species 0.000 claims 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 235000016804 zinc Nutrition 0.000 claims 1
- 241001122767 Theaceae Species 0.000 abstract description 24
- 230000004048 modification Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 abstract description 4
- 239000006087 Silane Coupling Agent Substances 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 16
- 230000000845 anti-microbial effect Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 239000003925 fat Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- NXQNMWHBACKBIG-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCCC(O)(O)O Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCCC(O)(O)O NXQNMWHBACKBIG-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 229920000137 polyphosphoric acid Polymers 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 241000737241 Cocos Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000255964 Pieridae Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000006197 hydroboration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- DKXULEFCEORBJK-UHFFFAOYSA-N magnesium;octadecanoic acid Chemical compound [Mg].CCCCCCCCCCCCCCCCCC(O)=O DKXULEFCEORBJK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an aerogel-containing environment-friendly coating and a preparation method thereof, wherein the aerogel-containing environment-friendly coating comprises the following raw materials: polyurethane, polyacrylate, hydroxyethyl methacrylate, propylene glycol diacrylate, trimethylolpropane triacrylate, phthalic acid, trimellitic anhydride, maleic acid, trimethylolpropane triacrylate, polyvinyl alcohol, emulsified silicone oil, nano antimony-doped tin dioxide powder, titanium liquid, zinc stearate, gelatin, Arabic gum, a stain-resistant modification auxiliary agent, polyoxyethylene polyoxypropylene pentaerythritol ether, polyacrylic acid, octyl isothiazolinone, chitosan, tea polyphenol, ammonium polyphosphate and a silane coupling agent KH-570, the environment-friendly coating containing the aerogel is prepared by the steps of preparing a base material and a modified filler, and then mixing the base material, the modified filler and other auxiliary raw materials. The environment-friendly coating disclosed by the invention is strong in adhesive force, free of volatilization of harmful substances, and excellent in stain resistance and antibacterial performance.
Description
【Technical field】
The invention belongs to technical field of paint preparation, and in particular to a kind of to contain the environmental protection coating material of aeroge and its preparation side
Method.
【Background technology】
With the development of construction industry, the demand of coating is growing day by day.Coating is a kind of material, and this material can be used
Different construction technologies is coated in object surface, is formed and adhered to firmly, with some strength, continuous solid film, such shape
Into film be generally called film, also known as paint film or coating.
A kind of Chinese patent application document " environmental protection coating material containing aeroge and preparation method thereof (application publication number:
CN106928795A) " disclose a kind of water conservation coating and contain environmental protection coating material of aeroge and preparation method thereof, including by weight
The component of number ratio, 100 parts of film forming agent, 30-110 parts of filler, 3-10 parts of fire resistance fibre, the filler include aerogel microball 40-
90 parts, 1-20 parts of vacuum ceramic microballoon, auxiliary agent include 2-5 parts of thickener, 2-7 parts of dispersant, 1-10 parts of polyacrylic acid and polyoxy
1-5 parts of ethene polyoxypropylene pentaerythrite ether.The environmental protection coating material containing aeroge of the invention, environmentally friendly, pollution-free, water resistance
Good, manufacture craft is simple, but it forms the three-dimensional netted hollow knot to be linked together by closing microballoon on architectural chamber surface
Structure, the more empty network structures of the very thin nanometer of such aeroge and nano-hollow silicon microballoon form the still air of a folded folder
Group, although being passed to many good prevention heats, has good heat-resisting effect, three-dimensional netted hollow-core construction is easily detained
Spot and grow bacterium, Paint Falling yellowing can be caused for a long time, can not meet routine use, grow the wall of bacterium also easily on
It is mould, influence aesthetics.
【The content of the invention】
The present invention provides a kind of environmental protection coating material containing aeroge and preparation method thereof, to solve in Chinese patent application text
Offer a kind of " environmental protection coating material containing aeroge and preparation method thereof (application publication number:CN106928795A it is) " disclosed to contain gas
The problem of environmental protection coating material of gel is easily detained spot and grows bacterium.
To solve above technical problem, the present invention uses following technical scheme:
A kind of environmental protection coating material containing aeroge, including following raw material:Polyurethane, polyacrylate, hydroxyethyl methacrylate
Ethyl ester, propylene glycol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid,
Trimethylolpropane trimethacrylate, polyvinyl alcohol, silicone emulsion, nanometer antimony-doped stannic oxide powder, titanium liquid, zinc stearate,
Gelatin, Arabic gum, resistant modified additive, polyoxyethylene polyoxypropylene pentaerythrite ether, polyacrylic acid, Octylisothiazoline
Ketone, chitosan, tea polyphenols, ammonium polyphosphate and Silane coupling reagent KH-570；
Octylisothiazolinone, chitosan, tea polyphenols, ammonium polyphosphate and the Silane coupling reagent KH-570 weight ratio be
(4-8):(5-15):(3-6):(10-20):(2-6)。
Further, resistant modified additive is prepared by following technique:By trbasic zinc phosphate, zinc powder, sodium borohydride, stearic acid
Magnesium and the sulfuric acid solution that mass fraction is 15-35% are uniformly mixed, and are heated up, are kept the temperature, stirring, is subsequently added into silane coupling agent KH-
550th, neopelex and methyl methacrylate are uniformly mixed, and continue to heat up, and insulation, then adds Kynoar
It is uniformly mixed with polyethylene glycol, stirs, be subsequently added into paraffin methyl-silicone oil and coconut oil fat acyl diethanol amine is uniformly mixed, is risen
Temperature, keeps the temperature, stirring, dry to constant weight, is cooled to room temperature to obtain resistant modified additive.
Further, resistant modified additive is prepared by following technique:By weight by 5-15 parts of trbasic zinc phosphates, 4-8 parts
The sulfuric acid solution that zinc powder, 3-6 part sodium borohydride, 2-5 parts of magnesium stearates and 1-6 parts of mass fractions are 15-35% is uniformly mixed, and is risen
Temperature keeps the temperature 20-40min to 60-70 DEG C, stirs 1-2h in 450-650r/min rotating speeds, is subsequently added into 4-8 parts of silane coupling agents
KH-550,3-9 parts of neopelexes and 2-5 parts of methyl methacrylates are uniformly mixed, and are continuously heating to 80-90 DEG C,
2-3h is kept the temperature, then 1-6 parts of Kynoar is added and 3-5 parts of polyethylene glycol is uniformly mixed, stirred in 650-850r/min rotating speeds
20-40min is mixed, 2-6 parts of paraffin methyl-silicone oils is subsequently added into and 1-5 parts of coconut oil fat acyl diethanol amine is uniformly mixed, be warming up to
90-120 DEG C, 1-2h is kept the temperature, 30-50min is stirred in 1200-1400r/min rotating speeds, it is dry to constant weight, it is cooled to room temperature to obtain
Resistant modified additive.
Further, in units of parts by weight, including following raw material:60-80 parts of polyurethane, 5-15 parts of polyacrylate,
4-9 parts of hydroxyethyl methacrylate, 2-6 parts of propylene glycol diacrylate, 3-9 parts of trimethylolpropane trimethacrylate, adjacent benzene
2-5 parts of dioctyl phthalate, 1-5 parts of trimellitic anhydride, 4-8 parts of maleic acid, 3-6 parts of trimethylolpropane trimethacrylate, polyethylene
1-5 parts of alcohol, 4-8 parts of silicone emulsion, 3-6 parts of nanometer antimony-doped stannic oxide powder, 4-8 parts of titanium liquid, 3-6 parts of zinc stearate, gelatin
2-5 parts, 1-5 parts of Arabic gum, 12-16 parts of resistant modified additive, 5-15 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, poly- third
2-6 parts of olefin(e) acid, 4-8 parts of octylisothiazolinone, 5-15 parts of chitosan, 3-6 parts of tea polyphenols, 10-20 parts of ammonium polyphosphate, silane are even
Join KH-5702-6 parts of agent.
The present invention also provides a kind of preparation method of the environmental protection coating material containing aeroge, comprise the following steps:
It is S1, polyurethane, polyacrylate and polyvinyl alcohol is uniform, in the stirring of 4000-6000r/min rotating speeds it is lower plus
Enter nanometer antimony-doped stannic oxide powder, titanium liquid and zinc stearate, stir 10-15min, add polyoxyethylene polyoxypropylene season penta
Four alcohol ethers and polyacrylic acid are uniformly mixed, and are warming up to 80-90 DEG C, keep the temperature 1-2h, and 1-2h is stirred in 650-850r/min rotating speeds, cold
But base-material is obtained to room temperature；
S2, after mixing resistant modified additive, tea polyphenols, chitosan and Silane coupling reagent KH-570, be warming up to 60-80
DEG C, 1-3h is kept the temperature, does not stop to stir during insulation, then ammonium polyphosphate is added and octylisothiazolinone is uniformly mixed, after
It is continuous to be warming up to 80-90 DEG C, 5-15min is dispersed with stirring in 300-350r/min rotating speeds, obtains modified filler；
S3, in closed blender, by base-material, modified filler, gelatin, Arabic gum, hydroxyethyl methacrylate, third
Omega-diol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid, trihydroxy methyl
Propane triacrylate and silicone emulsion are uniformly mixed, and are warming up to 120-140 DEG C, 1-3h are kept the temperature, then in 4000-6000r/
Min rotating speeds stir 1-2h, are cooled to room temperature to obtain the environmental protection coating material containing aeroge.
The invention has the advantages that:
(1) by the data of embodiment 1-3 and comparative example 7 as it can be seen that containing the environmental protection coating material of aeroge using embodiment 1-3
Resistant and anti-microbial property significantly improve；At the same time by the data of embodiment 1-3 as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-6 as it can be seen that octylisothiazolinone, chitosan, tea polyphenols, polyphosphoric acid
Ammonium and Silane coupling reagent KH-570 play synergistic effect in the environmental protection coating material containing aeroge is prepared, collaboration improve containing
The resistant and anti-microbial property of the environmental protection coating material of aeroge, this is probably:Octylisothiazolinone, chitosan, tea polyphenols and poly- phosphorus
Sour ammonium is added as environment-friendly materials, meets the requirement of environmental protection coating material, and the hydroxy radical content on chitosan surface is more, even in silane
Under the action of joining agent KH-570, effective antibacterial for combining, not only further increasing ammonium polyphosphate to ammonium polyphosphate is realized
Resistance to soiling, due to the modifying function of Silane coupling reagent KH-570 so that octylisothiazolinone and tea polyphenols being capable of firm attachments
On chitosan, the resistant and anti-microbial property of coating are further increased.Octylisothiazolinone, chitosan, tea polyphenols, poly- phosphorus
Sour ammonium and Silane coupling reagent KH-570 are applied to as a modified reinforcement system in the environmental protection coating material of the present invention, pungent by controlling
Base isothiazolinone, chitosan, tea polyphenols, ammonium polyphosphate and Silane coupling reagent KH-570 weight ratio are (4-8):(5-15):(3-
6):(10-20):(2-6) so that primary raw material of the ammonium polyphosphate as modified reinforcement system, chitosan is as graft modification
Secondly filler its dosage, the hydroxyl enriched can be provided for graft modification, is ammonium polyphosphate, octylisothiazolinone and tea polyphenols
Grafting provide abundance attachment site further such that graft modification more fully efficiently, further such that modified reinforcing body
System is applied in the environmental protection coating material of the present invention, can play more effective reinforcement modified effect, is effectively improved environmental protection of the invention and is applied
The resistant and anti-microbial property of material.
(3) by the data of embodiment 1-3 and comparative example 7 as it can be seen that the environmental protection coating material containing aeroge of embodiment 1-3 it is resistance to
Dirty anti-microbial property is significantly higher than the resistant and anti-microbial property of comparative example 7.
(4) for the environmental protection coating material containing aeroge of the invention relative to the prior art, resistant and anti-microbial property are excellent, solve
The problem of environmental protection coating material containing aeroge is easily detained spot and grows bacterium.
【Embodiment】
For ease of more fully understanding the present invention, it is illustrated by following instance, these examples belong to the protection of the present invention
Scope, but do not limit the scope of the invention.
In embodiment, the environmental protection coating material containing aeroge, in units of parts by weight, including following raw material:Polyurethane 60-
80 parts, 5-15 parts of polyacrylate, 4-9 parts of hydroxyethyl methacrylate, 2-6 parts of propylene glycol diacrylate, trihydroxy methyl third
3-9 parts of alkane triacrylate, 2-5 parts of phthalic acid, 1-5 parts of trimellitic anhydride, 4-8 parts of maleic acid, trimethylolpropane
3-6 parts of triacrylate, 1-5 parts of polyvinyl alcohol, 4-8 parts of silicone emulsion, 3-6 parts of nanometer antimony-doped stannic oxide powder, titanium liquid 4-8
Part, 3-6 parts of zinc stearate, 2-5 parts of gelatin, 1-5 parts of Arabic gum, 12-16 parts of resistant modified additive, polyoxyethylene polyoxypropylene
5-15 parts of pentaerythrite ether, 2-6 parts of polyacrylic acid, 4-8 parts of octylisothiazolinone, 5-15 parts of chitosan, 3-6 parts of tea polyphenols,
10-20 parts of ammonium polyphosphate, 2-6 parts of Silane coupling reagent KH-570.
Resistant modified additive is prepared by following technique:By weight by 5-15 parts of trbasic zinc phosphates, 4-8 parts of zinc powders, 3-6 parts
The sulfuric acid solution that sodium borohydride, 2-5 part magnesium stearate and 1-6 parts of mass fractions are 15-35% is uniformly mixed, and is warming up to 60-70
DEG C, 20-40min is kept the temperature, 1-2h is stirred in 450-650r/min rotating speeds, is subsequently added into 4-8 parts of silane resin acceptor kh-550s, 3-9
Part neopelex and 2-5 parts of methyl methacrylates are uniformly mixed, and are continuously heating to 80-90 DEG C, keep the temperature 2-3h, so
Add 1-6 parts of Kynoar afterwards and 3-5 parts of polyethylene glycol be uniformly mixed, 20-40min is stirred in 650-850r/min rotating speeds,
It is subsequently added into 2-6 parts of paraffin methyl-silicone oils and 1-5 parts of coconut oil fat acyl diethanol amine is uniformly mixed, be warming up to 90-120 DEG C, protects
Warm 1-2h, 30-50min is stirred in 1200-1400r/min rotating speeds, dry to constant weight, is cooled to room temperature to obtain resistant to be modified and is helped
Agent.
The preparation method of the environmental protection coating material containing aeroge, comprises the following steps:
S1, by polyurethane, polyacrylate and polyvinyl alcohol by weight be uniformly mixed, in 4000-6000r/min rotating speeds
Lower nanometer antimony-doped stannic oxide powder, titanium liquid and the zinc stearate added by weight of stirring, stirs 10-15min, add by
The polyoxyethylene polyoxypropylene pentaerythrite ether and polyacrylic acid of parts by weight are uniformly mixed, and are warming up to 80-90 DEG C, keep the temperature 1-2h,
1-2h is stirred in 650-850r/min rotating speeds, is cooled to room temperature to obtain base-material；
S2, after mixing resistant modified additive, tea polyphenols, chitosan and Silane coupling reagent KH-570 by weight, heat up
To 60-80 DEG C, 1-3h is kept the temperature, does not stop to stir during insulation, then adds ammonium polyphosphate by weight and the different thiophene of octyl group
Oxazoline ketone is uniformly mixed, and is continuously heating to 80-90 DEG C, is dispersed with stirring 5-15min in 300-350r/min rotating speeds, is modified
Filler；
S3, in closed blender, by base-material, modified filler, gelatin, Arabic gum, hydroxyethyl methacrylate, third
Omega-diol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid, trihydroxy methyl
Propane triacrylate and silicone emulsion are uniformly mixed by weight, are warming up to 120-140 DEG C, 1-3h are kept the temperature, then in 4000-
6000r/min rotating speeds stir 1-2h, are cooled to room temperature to obtain the environmental protection coating material containing aeroge.
Below by more specific embodiment, the present invention will be described.
Embodiment 1
A kind of environmental protection coating material containing aeroge of the present invention, in units of parts by weight, including following raw material:Polyurethane 65
Part, 9 parts of polyacrylate, 7 parts of hydroxyethyl methacrylate, 4 parts of propylene glycol diacrylate, trimethylolpropane tris acrylic acid
It is 4 parts of ester, 3 parts of phthalic acid, 2 parts of trimellitic anhydride, 5 parts of maleic acid, 4.5 parts of trimethylolpropane trimethacrylate, poly-
2 parts of vinyl alcohol, 5 parts of silicone emulsion, 5.5 parts of nanometer antimony-doped stannic oxide powder, 5 parts of titanium liquid, 4 parts of zinc stearate, 3 parts of gelatin,
It is 4 parts of Arabic gum, 15 parts of resistant modified additive, 12 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, 3.5 parts of polyacrylic acid, pungent
6 parts of base isothiazolinone, 9 parts of chitosan, 5 parts of tea polyphenols, 17 parts of ammonium polyphosphate, 3.5 parts of Silane coupling reagent KH-570.
Resistant modified additive is prepared by following technique:By weight by 12 parts of trbasic zinc phosphates, 6 parts of zinc powders, 4 parts of hydroborations
The sulfuric acid solution that sodium, 3 parts of magnesium stearates and 2 parts of mass fractions are 20% is uniformly mixed, and is warming up to 65 DEG C, is kept the temperature 28min, in
620r/min rotating speeds stir 1.2h, are subsequently added into 5.5 parts of silane resin acceptor kh-550s, 7 parts of neopelexes and 3.5 parts
Methyl methacrylate is uniformly mixed, and is continuously heating to 85 DEG C, keeps the temperature 2.5h, then adds 4.5 parts of Kynoar and 4 parts poly-
Ethylene glycol is uniformly mixed, and is stirred 30min in 780r/min rotating speeds, is subsequently added into 5 parts of paraffin methyl-silicone oils and 2.5 parts of coconut oil fats
Acyl diethanol amine is uniformly mixed, and is warming up to 100 DEG C, keeps the temperature 1.5h, and 45min is stirred in 1300r/min rotating speeds, is dried to constant weight,
It is cooled to room temperature to obtain resistant modified additive.
The preparation method of the environmental protection coating material containing aeroge, comprises the following steps:
S1, by polyurethane, polyacrylate and polyvinyl alcohol by weight be uniformly mixed, in 5500r/min rotating speeds stir
Nanometer antimony-doped stannic oxide powder, titanium liquid and the zinc stearate of lower addition by weight, stir 12min, add by weight
Polyoxyethylene polyoxypropylene pentaerythrite ether and polyacrylic acid be uniformly mixed, be warming up to 85 DEG C, 1.5h kept the temperature, in 720r/min
Rotating speed stirs 1.5h, is cooled to room temperature to obtain base-material；
S2, after mixing resistant modified additive, tea polyphenols, chitosan and Silane coupling reagent KH-570 by weight, heat up
To 75 DEG C, 2.5h is kept the temperature, does not stop to stir during insulation, then adds ammonium polyphosphate by weight and Octylisothiazoline
Ketone is uniformly mixed, and is continuously heating to 85 DEG C, is dispersed with stirring 12min in 330r/min rotating speeds, obtains modified filler；
S3, in closed blender, by base-material, modified filler, gelatin, Arabic gum, hydroxyethyl methacrylate, third
Omega-diol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid, trihydroxy methyl
Propane triacrylate and silicone emulsion are uniformly mixed by weight, are warming up to 135 DEG C, keep the temperature 2h, are then turned in 5500r/min
Speed stirring 1.5h, is cooled to room temperature to obtain the environmental protection coating material containing aeroge.
Embodiment 2
A kind of environmental protection coating material containing aeroge of the present invention, in units of parts by weight, including following raw material:Polyurethane 75
Part, 12 parts of polyacrylate, 6.5 parts of hydroxyethyl methacrylate, 5 parts of propylene glycol diacrylate, trimethylolpropane tris third
8 parts of olefin(e) acid ester, 3.5 parts of phthalic acid, 4.5 parts of trimellitic anhydride, 6.5 parts of maleic acid, trimethylolpropane tris acrylic acid
5 parts of ester, 4 parts of polyvinyl alcohol, 7 parts of silicone emulsion, 4.5 parts of nanometer antimony-doped stannic oxide powder, 7 parts of titanium liquid, 5 parts of zinc stearate,
4 parts of gelatin, 2 parts of Arabic gum, 14 parts of resistant modified additive, 9 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, polyacrylic acid 5
Part, 7 parts of octylisothiazolinone, 13 parts of chitosan, 5.5 parts of tea polyphenols, 18 parts of ammonium polyphosphate, Silane coupling reagent KH-570 3.5
Part.
Resistant modified additive is prepared by following technique:By weight by 13 parts of trbasic zinc phosphates, 7.5 parts of zinc powders, 5 parts of boron hydrogen
Change the sulfuric acid solution that sodium, 3 parts of magnesium stearates and 5 parts of mass fractions are 20% to be uniformly mixed, be warming up to 65 DEG C, keep the temperature 30min, in
570r/min rotating speeds stir 1.5h, are subsequently added into 5.5 parts of silane resin acceptor kh-550s, 7.5 parts of neopelexes and 4.5
Part methyl methacrylate is uniformly mixed, and is continuously heating to 85 DEG C, keeps the temperature 2.5h, then adds 5 parts of Kynoar and 4 parts poly-
Ethylene glycol is uniformly mixed, and is stirred 35min in 770r/min rotating speeds, is subsequently added into 3 parts of paraffin methyl-silicone oils and 4.5 parts of coconut oil fats
Acyl diethanol amine is uniformly mixed, and is warming up to 110 DEG C, keeps the temperature 1.5h, and 40min is stirred in 1300r/min rotating speeds, is dried to constant weight,
It is cooled to room temperature to obtain resistant modified additive.
The preparation method of the environmental protection coating material containing aeroge, comprises the following steps:
S1, by polyurethane, polyacrylate and polyvinyl alcohol by weight be uniformly mixed, in 4900r/min rotating speeds stir
Nanometer antimony-doped stannic oxide powder, titanium liquid and the zinc stearate of lower addition by weight, stir 13min, add by weight
Polyoxyethylene polyoxypropylene pentaerythrite ether and polyacrylic acid be uniformly mixed, be warming up to 85 DEG C, 1.5h kept the temperature, in 6600r/
Min rotating speeds stir 1.5h, are cooled to room temperature to obtain base-material；
S2, after mixing resistant modified additive, tea polyphenols, chitosan and Silane coupling reagent KH-570 by weight, heat up
To 75 DEG C, 2.5h is kept the temperature, does not stop to stir during insulation, then add ammonium polyphosphate and octylisothiazolinone by weight
It is uniformly mixed, is continuously heating to 85 DEG C, is dispersed with stirring 9min in 3400r/min rotating speeds, obtains modified filler；
S3, in closed blender, by base-material, modified filler, gelatin, Arabic gum, hydroxyethyl methacrylate, third
Omega-diol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid, trihydroxy methyl
Propane triacrylate and silicone emulsion are uniformly mixed by weight, are warming up to 125 DEG C, insulation 2, then turns in 4400r/min
Speed stirring 1.5h, is cooled to room temperature to obtain the environmental protection coating material containing aeroge.
Embodiment 3
A kind of environmental protection coating material containing aeroge of the present invention, in units of parts by weight, including following raw material:Polyurethane 65
Part, 9 parts of polyacrylate, 7.5 parts of hydroxyethyl methacrylate, 3.5 parts of propylene glycol diacrylate, trimethylolpropane tris third
7 parts of olefin(e) acid ester, 3 parts of phthalic acid, 4 parts of trimellitic anhydride, 5 parts of maleic acid, trimethylolpropane trimethacrylate 4.5
Part, 2.5 parts of polyvinyl alcohol, 7 parts of silicone emulsion, 5.5 parts of nanometer antimony-doped stannic oxide powder, 7.5 parts of titanium liquid, 5 parts of zinc stearate,
3 parts of gelatin, 2 parts of Arabic gum, 15 parts of resistant modified additive, 12 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, polyacrylic acid 5
Part, 6 parts of octylisothiazolinone, 12 parts of chitosan, 4.5 parts of tea polyphenols, 16 parts of ammonium polyphosphate, 5 parts of Silane coupling reagent KH-570；
Resistant modified additive is prepared by following technique:By weight by 13 parts of trbasic zinc phosphates, 5.5 parts of zinc powders, 4.5 parts of boron
The sulfuric acid solution that sodium hydride, 3.5 parts of magnesium stearates and 5 parts of mass fractions are 30% is uniformly mixed, and is warming up to 65 DEG C, insulation
27min, stirs 1.5h in 560r/min rotating speeds, is subsequently added into 7.5 parts of silane resin acceptor kh-550s, 6.5 parts of detergent alkylate sulphurs
Sour sodium and 4 parts of methyl methacrylates are uniformly mixed, and are continuously heating to 85 DEG C, keep the temperature 2.5h, then add 5 parts of Kynoar
It is uniformly mixed with 4 parts of polyethylene glycol, stirs 35min in 830r/min rotating speeds, be subsequently added into 3 parts of paraffin methyl-silicone oils and 2 portions of coconut palms
Oil and fat acyl diethanol amine is uniformly mixed, and is warming up to 115 DEG C, keeps the temperature 1.5h, stirs 45min in 1300r/min rotating speeds, drying is extremely
Constant weight, is cooled to room temperature to obtain resistant modified additive
The preparation method of the environmental protection coating material containing aeroge, comprises the following steps:
S1, by polyurethane, polyacrylate and polyvinyl alcohol by weight be uniformly mixed, in 5700r/min rotating speeds stir
Nanometer antimony-doped stannic oxide powder, titanium liquid and the zinc stearate of lower addition by weight, stir 14min, add by weight
Polyoxyethylene polyoxypropylene pentaerythrite ether and polyacrylic acid be uniformly mixed, be warming up to 85 DEG C, 1.5h kept the temperature, in 690r/min
Rotating speed stirs 1.5h, is cooled to room temperature to obtain base-material；
S2, after mixing resistant modified additive, tea polyphenols, chitosan and Silane coupling reagent KH-570 by weight, heat up
To 65 DEG C, 2.5h is kept the temperature, does not stop to stir during insulation, then adds ammonium polyphosphate by weight and Octylisothiazoline
Ketone is uniformly mixed, and is continuously heating to 85 DEG C, is dispersed with stirring 9min in 330r/min rotating speeds, obtains modified filler；
S3, in closed blender, by base-material, modified filler, gelatin, Arabic gum, hydroxyethyl methacrylate, third
Omega-diol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid, trihydroxy methyl
Propane triacrylate and silicone emulsion are uniformly mixed by weight, are warming up to 130 DEG C, keep the temperature 2h, are then turned in 5100r/min
Speed stirring 1.5h, is cooled to room temperature to obtain the environmental protection coating material containing aeroge.
Comparative example 1
It is essentially identical with the preparation process of embodiment 1, have only the difference is that preparing the original of the environmental protection coating material containing aeroge
Lack octylisothiazolinone, chitosan, tea polyphenols, ammonium polyphosphate and Silane coupling reagent KH-570 in material.
Comparative example 2
It is essentially identical with the preparation process of embodiment 1, have only the difference is that preparing the original of the environmental protection coating material containing aeroge
Lack octylisothiazolinone in material.
Comparative example 3
It is essentially identical with the preparation process of embodiment 1, have only the difference is that preparing the original of the environmental protection coating material containing aeroge
Lack chitosan in material.
Comparative example 4
It is essentially identical with the preparation process of embodiment 1, have only the difference is that preparing the original of the environmental protection coating material containing aeroge
Lack tea polyphenols in material.
Comparative example 5
It is essentially identical with the preparation process of embodiment 1, have only the difference is that preparing the original of the environmental protection coating material containing aeroge
Lack ammonium polyphosphate in material.
Comparative example 6
It is essentially identical with the preparation process of embodiment 1, have only the difference is that preparing the original of the environmental protection coating material containing aeroge
Lack Silane coupling reagent KH-570 in material.
Comparative example 7
Using a kind of Chinese patent application document " environmental protection coating material containing aeroge and preparation method thereof (application publication number:
CN106928795A) " technique of embodiment 1-6 prepares the environmental protection coating material containing aeroge.
Indices detection, obtained inspection are carried out to the environmental protection coating material containing aeroge of embodiment 1-3 and comparative example 1-7
Survey result such as following table:
Note:It is that the wiping experiment of oil resistivity pen obtains that oil resistivity pen, which wipes number, condition is wiped, by embodiment 1-3 and contrast
Example 1-7 is coated on glass, the film-forming under 1000w ultra violet lamps, and " just " word of 3cm*3cm, room temperature etc. are write with oil pen
Treat to be wiped with non-dust cloth after five minutes, circle statistics are resistance to successively wipes number result.
As seen from the above table:(1) by the data of embodiment 1-3 and comparative example 7 as it can be seen that containing aeroge using embodiment 1-3
Environmental protection coating material resistant and anti-microbial property significantly improve；At the same time by the data of embodiment 1-3 as it can be seen that embodiment 1 is optimal reality
Apply example.
(2) by embodiment 1 and the data of comparative example 1-6 as it can be seen that octylisothiazolinone, chitosan, tea polyphenols, polyphosphoric acid
Ammonium and Silane coupling reagent KH-570 play synergistic effect in the environmental protection coating material containing aeroge is prepared, collaboration improve containing
The resistant and anti-microbial property of the environmental protection coating material of aeroge, this is probably:Octylisothiazolinone, chitosan, tea polyphenols and poly- phosphorus
Sour ammonium is added as environment-friendly materials, meets the requirement of environmental protection coating material, and the hydroxy radical content on chitosan surface is more, even in silane
Under the action of joining agent KH-570, effective antibacterial for combining, not only further increasing ammonium polyphosphate to ammonium polyphosphate is realized
Resistance to soiling, due to the modifying function of Silane coupling reagent KH-570 so that octylisothiazolinone and tea polyphenols being capable of firm attachments
On chitosan, the resistant and anti-microbial property of coating are further increased.
(3) by the data of embodiment 1 and comparative example 7 as it can be seen that the resistant of the environmental protection coating material containing aeroge of embodiment 1-3
Anti-microbial property is significantly higher than the resistant and anti-microbial property of comparative example 7.
Above content is it cannot be assumed that present invention specific implementation is confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of present inventive concept is not departed from, some simple deduction or replace can also be made, all should
When being considered as belonging to the scope of patent protection that is determined by the claims submitted of the present invention.
Claims (5)
1. a kind of environmental protection coating material containing aeroge, it is characterised in that including following raw material:Polyurethane, polyacrylate, methyl
Hydroxy-ethyl acrylate, propylene glycol diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride,
It is maleic acid, trimethylolpropane trimethacrylate, polyvinyl alcohol, silicone emulsion, nanometer antimony-doped stannic oxide powder, titanium liquid, hard
Resin acid zinc, gelatin, Arabic gum, resistant modified additive, polyoxyethylene polyoxypropylene pentaerythrite ether, polyacrylic acid, octyl group are different
Thiazolinone, chitosan, tea polyphenols, ammonium polyphosphate and Silane coupling reagent KH-570；
Octylisothiazolinone, chitosan, tea polyphenols, ammonium polyphosphate and the Silane coupling reagent KH-570 weight ratio is (4-
8):(5-15):(3-6):(10-20):(2-6)。
2. the environmental protection coating material according to claim 1 containing aeroge, it is characterised in that resistant modified additive presses following work
It is prepared by skill:The sulfuric acid solution that trbasic zinc phosphate, zinc powder, sodium borohydride, magnesium stearate and mass fraction are 15-35% is mixed equal
It is even, heat up, keep the temperature, stirring, is subsequently added into silane resin acceptor kh-550, neopelex and methyl methacrylate and mixes
Close uniformly, continue to heat up, keep the temperature, then add Kynoar and polyethylene glycol is uniformly mixed, stir, be subsequently added into paraffin first
Base silicone oil and coconut oil fat acyl diethanol amine are uniformly mixed, and are heated up, and are kept the temperature, stirring, dry to constant weight, are cooled to room temperature to obtain resistance to
Dirty modified additive.
3. the environmental protection coating material according to claim 2 containing aeroge, it is characterised in that resistant modified additive presses following work
It is prepared by skill:By weight by 5-15 parts of trbasic zinc phosphates, 4-8 parts of zinc powders, 3-6 parts of sodium borohydrides, 2-5 parts of magnesium stearates and 1-6
The sulfuric acid solution that part mass fraction is 15-35% is uniformly mixed, and is warming up to 60-70 DEG C, 20-40min is kept the temperature, in 450-650r/
Min rotating speeds stir 1-2h, are subsequently added into 4-8 parts of silane resin acceptor kh-550s, 3-9 parts of neopelexes and 2-5 parts of first
Base methyl acrylate is uniformly mixed, and is continuously heating to 80-90 DEG C, keeps the temperature 2-3h, then adds 1-6 parts of Kynoar and 3-5
Part polyethylene glycol is uniformly mixed, and 20-40min is stirred in 650-850r/min rotating speeds, be subsequently added into 2-6 part paraffin methyl-silicone oils with
1-5 parts of coconut oil fat acyl diethanol amine are uniformly mixed, and are warming up to 90-120 DEG C, 1-2h are kept the temperature, in 1200-1400r/min rotating speeds
30-50min is stirred, it is dry to constant weight, it is cooled to room temperature to obtain resistant modified additive.
4. the environmental protection coating material according to claim 1 containing aeroge, it is characterised in that in units of parts by weight, including
Following raw material:60-80 parts of polyurethane, 5-15 parts of polyacrylate, 4-9 parts of hydroxyethyl methacrylate, propane diols diacrylate
2-6 parts of ester, 3-9 parts of trimethylolpropane trimethacrylate, 2-5 parts of phthalic acid, 1-5 parts of trimellitic anhydride, maleic acid
4-8 parts, 3-6 parts of trimethylolpropane trimethacrylate, 1-5 parts of polyvinyl alcohol, 4-8 parts of silicone emulsion, nano antimony doped titanium dioxide
3-6 parts of glass putty body, 4-8 parts of titanium liquid, 3-6 parts of zinc stearate, 2-5 parts of gelatin, 1-5 parts of Arabic gum, resistant modified additive 12-16
Part, 5-15 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, 2-6 parts of polyacrylic acid, 4-8 parts of octylisothiazolinone, chitosan
5-15 parts, 3-6 parts of tea polyphenols, 10-20 parts of ammonium polyphosphate, 2-6 parts of Silane coupling reagent KH-570.
5. a kind of preparation method for the environmental protection coating material for containing aeroge according to claim 1-4 any one of them, its feature exist
In comprising the following steps:
It is S1, polyurethane, polyacrylate and polyvinyl alcohol is uniform, stir lower addition in 4000-6000r/min rotating speeds and receive
Rice antimony-doped stannic oxide powder, titanium liquid and zinc stearate, stir 10-15min, add polyoxyethylene polyoxypropylene pentaerythrite
Ether and polyacrylic acid are uniformly mixed, and are warming up to 80-90 DEG C, keep the temperature 1-2h, are stirred 1-2h in 650-850r/min rotating speeds, are cooled to
Room temperature obtains base-material；
S2, after mixing resistant modified additive, tea polyphenols, chitosan and Silane coupling reagent KH-570, be warming up to 60-80 DEG C, protects
Warm 1-3h, does not stop to stir during insulation, then adds ammonium polyphosphate and octylisothiazolinone is uniformly mixed, continue to heat up
To 80-90 DEG C, 5-15min is dispersed with stirring in 300-350r/min rotating speeds, obtains modified filler；
S3, in closed blender, by base-material, modified filler, gelatin, Arabic gum, hydroxyethyl methacrylate, propane diols
Diacrylate, trimethylolpropane trimethacrylate, phthalic acid, trimellitic anhydride, maleic acid, trimethylolpropane
Triacrylate and silicone emulsion are uniformly mixed, and are warming up to 120-140 DEG C, keep the temperature 1-3h, are then turned in 4000-6000r/min
Speed stirring 1-2h, is cooled to room temperature to obtain the environmental protection coating material containing aeroge.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711198717.1A CN107903680A (en) | 2017-11-26 | 2017-11-26 | Aerogel-containing environment-friendly coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711198717.1A CN107903680A (en) | 2017-11-26 | 2017-11-26 | Aerogel-containing environment-friendly coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107903680A true CN107903680A (en) | 2018-04-13 |
Family
ID=61848561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711198717.1A Pending CN107903680A (en) | 2017-11-26 | 2017-11-26 | Aerogel-containing environment-friendly coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107903680A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116463021A (en) * | 2023-06-20 | 2023-07-21 | 富维薄膜（山东）有限公司 | Water-based coating liquid, preparation method and application thereof in non-silicon release film |
| CN117070186A (en) * | 2023-10-18 | 2023-11-17 | 山东景茂新材料有限公司 | Preparation method of alcohol type silicone sealant |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102137900A (en) * | 2007-11-12 | 2011-07-27 | 拜奥洛卡斯股份公司 | Anti-fouling composition comprising an aerogel |
| CN102977721A (en) * | 2012-12-20 | 2013-03-20 | 上海滋普环保科技有限公司 | Multifunctional bacterium-resisting and smell-removing thermal insulation coating |
| CN104725958A (en) * | 2015-03-23 | 2015-06-24 | 苏州市神龙门窗有限公司 | Outdoor door/window thermal insulation coating and preparation method thereof |
| CN105733385A (en) * | 2016-05-08 | 2016-07-06 | 泉州三欣新材料科技有限公司 | Bionic cleaning water-based paint and preparation method thereof |
| CN106928795A (en) * | 2017-03-05 | 2017-07-07 | 江苏华盛节能科技有限公司 | A kind of environmental protection coating material containing aeroge and preparation method thereof |
| CN107057437A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of antibacterial modified antirust agent of high resistant |
-
2017
- 2017-11-26 CN CN201711198717.1A patent/CN107903680A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102137900A (en) * | 2007-11-12 | 2011-07-27 | 拜奥洛卡斯股份公司 | Anti-fouling composition comprising an aerogel |
| CN102977721A (en) * | 2012-12-20 | 2013-03-20 | 上海滋普环保科技有限公司 | Multifunctional bacterium-resisting and smell-removing thermal insulation coating |
| CN104725958A (en) * | 2015-03-23 | 2015-06-24 | 苏州市神龙门窗有限公司 | Outdoor door/window thermal insulation coating and preparation method thereof |
| CN105733385A (en) * | 2016-05-08 | 2016-07-06 | 泉州三欣新材料科技有限公司 | Bionic cleaning water-based paint and preparation method thereof |
| CN106928795A (en) * | 2017-03-05 | 2017-07-07 | 江苏华盛节能科技有限公司 | A kind of environmental protection coating material containing aeroge and preparation method thereof |
| CN107057437A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of antibacterial modified antirust agent of high resistant |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116463021A (en) * | 2023-06-20 | 2023-07-21 | 富维薄膜（山东）有限公司 | Water-based coating liquid, preparation method and application thereof in non-silicon release film |
| CN116463021B (en) * | 2023-06-20 | 2023-09-19 | 富维薄膜（山东）有限公司 | Water-based coating liquid, preparation method and application thereof in non-silicon release film |
| CN117070186A (en) * | 2023-10-18 | 2023-11-17 | 山东景茂新材料有限公司 | Preparation method of alcohol type silicone sealant |
| CN117070186B (en) * | 2023-10-18 | 2023-12-26 | 山东景茂新材料有限公司 | Preparation method of alcohol type silicone sealant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104877484B (en) | Petrochemical industry oil tank aqueous energy-saving heat-insulating thermal insulation coatings and preparation method thereof | |
| CN102850878A (en) | Weather-resistant exterior wall paint and preparation method thereof | |
| CN106590268A (en) | Real-stone paint and preparation method thereof | |
| CN108517154A (en) | A kind of aqueous, floride-free super hydrophobic coating and preparation method | |
| CN102002298A (en) | Aqueous antifouling adhesive preventing coating and production method thereof | |
| CN110330848B (en) | Water-based environment-friendly mould-proof temperature-control building coating and preparation method thereof | |
| CN106189640B (en) | A kind of preparation method of modified aqueous acrylic acid cold coating | |
| CN110016268A (en) | A kind of reflective insulation lacquer and preparation method thereof | |
| CN109825148A (en) | External wall energy-saving coating | |
| CN108264832A (en) | Inorganic modified heat-resisting woodcare paint of aqueous dual-component and preparation method thereof and application method | |
| CN106398405A (en) | Interior wall heat-insulating coating and preparation method and application thereof | |
| CN111500133A (en) | Sand-in-water multicolor paint and preparation method thereof | |
| CN107573791A (en) | A kind of environment-friendly type inner wall face sealing wax | |
| CN107903680A (en) | Aerogel-containing environment-friendly coating and preparation method thereof | |
| CN106243880B (en) | A kind of true mineral varnish of environment-friendly type high life anti-soil | |
| CN106830749A (en) | A kind of color liquid sliver and preparation method thereof | |
| CN103482905B (en) | Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings | |
| CN106916492B (en) | A kind of novel decorative powdery sliver interior wall coating and preparation method thereof | |
| CN105295624A (en) | Dark-color reflective and heat insulation varnish and preparation method thereof | |
| KR100585189B1 (en) | Water-based Ceramic Photocatalyst Paint And Manufacturing Method Thereof | |
| CN108977081A (en) | A kind of efficient energy-saving coating for building and preparation method thereof | |
| CN107286782A (en) | Water-based acrylic acid heat-insulation paint and preparation method thereof | |
| CN104893544A (en) | Fireproof wind-sand-resistant paint for desert environment wood ancient building and preparation method of fireproof wind-sand-resistant paint | |
| CN107189532A (en) | A kind of graphene formaldehyde-removing wallpaper, wall paper and preparation method | |
| AU2016378079A1 (en) | Composition for a pasty filler material, pasty filler, and method for producing a pasty filler material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180413 |
|
| RJ01 | Rejection of invention patent application after publication |