CN107892809B - Scratch-resistant grain lettering film and manufacturing method thereof - Google Patents
Scratch-resistant grain lettering film and manufacturing method thereof Download PDFInfo
- Publication number
- CN107892809B CN107892809B CN201711282671.1A CN201711282671A CN107892809B CN 107892809 B CN107892809 B CN 107892809B CN 201711282671 A CN201711282671 A CN 201711282671A CN 107892809 B CN107892809 B CN 107892809B
- Authority
- CN
- China
- Prior art keywords
- layer
- scratch
- film
- grain
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000003678 scratch resistant effect Effects 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000010410 layer Substances 0.000 claims abstract description 99
- 239000011347 resin Substances 0.000 claims abstract description 44
- 229920005989 resin Polymers 0.000 claims abstract description 44
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 22
- 239000010456 wollastonite Substances 0.000 claims abstract description 22
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 21
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 20
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 20
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000008117 stearic acid Substances 0.000 claims abstract description 20
- 239000004831 Hot glue Substances 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 8
- -1 polysiloxane Polymers 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims description 27
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000465 moulding Methods 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 12
- 238000007639 printing Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 9
- 238000007765 extrusion coating Methods 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 abstract description 18
- 230000007547 defect Effects 0.000 abstract description 3
- 235000013339 cereals Nutrition 0.000 description 39
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 10
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 10
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 238000010023 transfer printing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- 229910052918 calcium silicate Inorganic materials 0.000 description 3
- 239000000378 calcium silicate Substances 0.000 description 3
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000020985 whole grains Nutrition 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/06—Polyurethanes from polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/41—Base layers supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
- B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to the application field of TPU (thermoplastic polyurethane) materials, and provides a scratch-resistant grain lettering film and a manufacturing method thereof, which solve the problem of poor scratch resistance of the grain lettering film in the prior art, wherein the scratch-resistant grain lettering film consists of five parts, namely a hot melt adhesive layer, a grain layer, a resin forming layer, a release layer and a release film; the resin forming layer comprises 60-70 wt% of TPU, 5-15 wt% of ABS, 10-20 wt% of stearic acid modified wollastonite powder, 1-5 wt% of compatilizer, 1-5 wt% of polysiloxane and 0-2 wt% of flatting agent. The scratch-resistant grain lettering film has high scratch resistance, is applied to zipper films and some shoe and clothes heat transfer products requiring scratch resistance, and overcomes the defect that the existing grain lettering film on the market is not scratch-resistant.
Description
Technical Field
The invention relates to the field of TPU material application, in particular to a scratch-resistant grain lettering film made of a TPU material and a manufacturing method thereof.
Background
The grain lettering film is a heat transfer printing product, and its principle is that the transfer printing film with grain is directly contacted with printing stock, and the grain layer on the transfer printing film is transferred onto the printing stock by means of heating and pressurizing action of heat transfer printing equipment, and generally is formed from four portions of hot-melt adhesive layer, grain layer, resin forming layer and release film, in which the resin forming layer can be used for forming and protecting pattern of finished product after transfer printing, and mainly determines the performance and forming effect of product, and has the important action for quality of whole grain lettering film.
The existing grain lettering film is mostly made by adopting a PET film, a PVC film, a PC film and the like as release films and forming a resin molding layer, a grain layer and a hot melt adhesive layer through coating by a coating process. Due to the performance limitation of the colloid of the resin molding layer, the lettering film has the defects of poor molding, scratch resistance and the like, and can not meet the requirements of zipper films and some shoe and clothes products which need scratch resistance.
Patent document CN 102936476B discloses a method for manufacturing a thermal transfer adhesive film, which is equivalent to the method for manufacturing a lettering film in practical application, and improves a hot melt adhesive layer without improving a resin molding layer, so that the overall quality of the lettering film is not improved.
The TPU (thermoplastic polyurethane elastomer) is a thermoplastic elastomer, has the characteristics of wear resistance, high elasticity, good impact property and the like, but has the defects of low surface hardness and poor formability, and the TPU film is soft and is easily scratched by a strong external force.
ABS (acrylonitrile-butadiene-styrene) is a common thermoplastic resin with excellent performance and has the advantages of balanced mechanical properties, excellent processability, high surface hardness and the like.
Disclosure of Invention
Therefore, in order to solve the above problems, the present invention provides a scratch-resistant grain lettering film and a manufacturing method thereof, which solve the problem of poor scratch resistance of the grain lettering film in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
the scratch-resistant grain lettering film comprises, from bottom to top, a release film, a release layer, a resin molding layer, a grain layer and a hot melt adhesive layer in sequence, and is characterized in that the resin molding layer comprises, by weight, 60% -70% of TPU, 5% -15% of ABS, 10% -20% of sodium stearate modified wollastonite, 1% -5% of a compatilizer, 1% -5% of polysiloxane and 0% -2% of a flatting agent. Stearic acid modified wollastonite powder (calcium silicate), wherein a stearic acid end is well combined with ABS and TPU polar ends, and a wollastonite end forms a rigid filling core which is uniformly dispersed in a resin blend to form a stable structure, so that the surface hardness of the blended resin is obviously enhanced, and the scratch resistance is improved; the compatibilizer can act as a bridge for the calcium silicate to link with the TPU or ABS; the surface lubrication effect of the polysiloxane can reduce the surface friction coefficient so as to improve the surface scratch resistance of the material; leveling agents improve the flow properties of the blend.
The further improvement is that: the TPU is a polyester polyurethane elastomer, and the Shore A hardness of the TPU is 65-80; the wear resistance, tear resistance and tensile and tear strength of the polyester polyurethane are superior to those of polyether polyurethane.
The further improvement is that: the stearic acid modified wollastonite powder (calcium silicate) has an average particle size of 4-6 μm, has a large specific surface area, can be better combined with resin, and has better dispersibility.
The further improvement is that: the preparation method of the stearic acid modified wollastonite comprises the following steps: adding stearic acid accounting for 1.0-1.2% of the weight of the wollastonite powder, stirring at the speed of 900-1000r/min, at the temperature of 80-120 ℃ for 20-30min, cooling, and removing larger particles to obtain stearic acid modified wollastonite powder.
The further improvement is that: the compatilizer is ABS grafted maleic anhydride (ABS-G) or styrene-maleic anhydride copolymer (SMA) or methacrylic acid-butadiene-styrene (MBS), and the compatibility and the mechanical strength of the blending material are further improved.
The further improvement is that: the leveling agent is an acrylic leveling agent, and can improve the leveling effect, increase smoothness and improve the scratch resistance.
A novel scratch-resistant grain lettering film manufacturing method comprises the following steps:
1) preparing a release film (commonly used PET, PVC, PC and the like);
2) coating a layer of silicone oil on the release film to serve as a release layer, wherein the release layer is used for enabling the release film to be easily separated from the resin forming layer in the use process of the lettering film;
3) coating the resin molding layer material of the invention on the release layer by using an extrusion coating method; the resin forming layer determines the forming effect and the scratch resistance of the scratch-resistant grain lettering film;
4) printing a line layer on the resin molding layer;
5) coating hot melt adhesive on the grain layer to form a hot melt adhesive layer, and manufacturing a scratch-resistant grain lettering film; the hot melt adhesive layer has higher adhesive force with the surface of the printing stock, so that the grain layer is firmly combined with the surface of the printing stock, and the hot melt adhesive layer must be matched with a printing material and selected according to different printing stocks.
The further improvement is that; the thickness of the release film is 5c-10 c.
The further improvement is that: the resin molding layer adopts an extrusion coating process, a double screw is used in an extrusion stage, the temperature of each section of an extruder is 180-240 ℃, and the rotating speed of the screw is 200-400 r/min; coating the wet film with the thickness of 20c-30c, drying in a 12-section oven at 60-115 ℃ at the speed of 75-100 m/min.
The further improvement is that: and heating and drying the scratch-resistant grain lettering film at the temperature of 80-100 ℃ for 5-8 minutes to ensure that the surface of the scratch-resistant grain lettering film is dry by touch, so that the viscosity is reduced.
By adopting the technical scheme, the invention has the beneficial effects that:
1. the ABS added in the formula of the resin molding layer has the advantage of higher surface hardness, and the scratch resistance and the moldability of the resin molding layer are improved while the texture of TPU is maintained.
2. The structure formed by using the sodium stearate modified wollastonite as the filler is stable, and the surface scratch resistance of the TPU base material is obviously improved.
3. The compatilizer ABS is grafted with maleic anhydride (ABS-G) or styrene-maleic anhydride copolymer (SMA) or methacrylic acid-butadiene-styrene (MBS), so that the compatibility of TPU and ABS and the mechanical strength of a mixed material are improved, and the scratch resistance of a resin molding layer is further improved.
4. The polysiloxane has a surface lubricating effect, and can reduce the surface friction coefficient so as to further improve the scratch resistance of the resin molding layer.
5. The acrylic leveling agent can improve the leveling effect, increase the smoothness, improve the scratch resistance and further improve the scratch resistance of the resin molding layer.
6. By adopting the extrusion coating process, the coating has good uniformity and can obtain a coating with ideal thickness.
7. The grain lettering film manufactured by the method has clear grains, retains the advantage of good hand feeling of TPU, improves the scratch resistance, and has wide market value and social value particularly in the zipper film industry and the shoe and clothes industry.
Drawings
FIG. 1 is a view showing the structure of a scratch-resistant type grain marking film of example 1 of the present invention.
FIG. 2 is a production flow chart of example 1 of the present invention.
Detailed Description
The following detailed description will be provided for the embodiments of the present invention with reference to specific embodiments, so that how to apply the technical means to solve the technical problems and achieve the technical effects can be fully understood and implemented.
Unless otherwise indicated, the technical means employed in the examples are conventional means well known to those skilled in the art, and the reagents and products employed are commercially available.
Example 1
The utility model provides a scratch-resistant type line membrane of carving characters, as shown in figure 1, from bottom to top in proper order for PET to leave type membrane 1, silicon oil from type layer 2, resin shaping layer 3, line layer 4, hot melt adhesive layer 5, resin shaping layer raw materials component is polyester TPU60 KG, ABS15KG, stearic acid modified wollastonite powder 20KG (average particle diameter 4 mu m-6 mu m), ABS-G3 KG, polysiloxane 1KG, acrylic acid flatting agent 1 KG.
The preparation method of the stearic acid modified wollastonite powder comprises the following steps: adding 0.25KG stearic acid into wollastonite powder 25KG with average particle size of 4-6 microns, stirring at 900r/min and 80 ℃ for 20min, cooling to room temperature, and removing larger particles to obtain stearic acid modified wollastonite powder.
Referring to fig. 2, the method for preparing the scratch-resistant grain lettering film comprises the following steps:
coating a layer of silicone oil on a PET release film 1 with the width of 1000mm and the thickness of 10c to form a release layer 2; fully mixing the raw material components of the resin molding layer to obtain a mixture, feeding the mixture into a double-screw extruder, fully fusing the materials under the shearing, mixing and conveying of a screw to form coating liquid, and extruding the coating liquid from a gap of an extrusion nozzle under the conditions that the temperature of each section of the double-screw extruder is 180-200 ℃ and the rotating speed of the screw is 400 r/min; coating the extrusion coating liquid on a release layer 2 to form a resin forming layer 3, wherein the thickness of a coated wet film is 20c, the speed of the coating is 75m/min, the section of an oven is 12, and the drying temperature is 115 ℃; printing a grain layer 4 on the resin molding layer 3; and (3) coating a hot melt adhesive film 5 on the grain layer 4, heating and drying for 5 minutes at 100 ℃ to ensure that the surface of the grain layer is dry by touch, and reducing the viscosity to prepare the scratch-resistant grain lettering film.
Example 2
The utility model provides a resistant type line membrane of carving characters, is PET from type membrane, silicone oil from type layer, resin shaping layer, line layer, hot melt adhesive layer by supreme down in proper order, resin shaping layer raw materials component is polyester TPU60 KG, ABS5KG, stearic acid modified wollastonite powder 10KG, ABS-G1 KG, polysiloxane 1KG, acrylic acid flatting agent 5 KG.
The preparation method of the stearic acid modified wollastonite powder comprises the following steps: adding 15KG of wollastonite powder with the average particle size of 4-6 microns into stearic acid, stirring at the speed of 1000r/min and the temperature of 120 ℃ for 30min, cooling to room temperature, and removing larger particles to obtain stearic acid modified wollastonite powder.
The preparation method of the scratch-resistant grain lettering film comprises the following steps:
coating a layer of silicone oil on a PET release film with the width of 1000mm and the thickness of 5c to serve as a release layer; fully mixing the raw material components of the resin molding layer to obtain a mixture, feeding the mixture into a double-screw extruder, fully fusing the materials under the shearing, mixing and conveying of a screw to form coating liquid, and extruding the coating liquid from a gap of an extrusion nozzle under the conditions that the temperature of each section of the double-screw extruder is 220-240 ℃ and the rotating speed of the screw is 200 r/min; coating the extrusion coating liquid on a release layer to form a resin forming layer, wherein the thickness of a coated wet film is 30c, the speed is 100m/min, the section of an oven is 12, and the drying temperature is 60 ℃; printing a grain layer on the resin molding layer; and coating a hot-melt adhesive film on the grain layer, heating and drying for 8 minutes at 80 ℃ to ensure that the surface of the grain layer is dry by touch, and reducing the viscosity to prepare the scratch-resistant grain lettering film.
Example 3
The utility model provides a resistant scratch type line membrane of carving characters, is PET from type membrane, silicone oil from type layer, resin shaping layer, line layer, hot melt adhesive layer by supreme down in proper order, resin shaping layer raw materials component is polyester TPU 70KG, ABS10KG, stearic acid modified wollastonite powder 10KG, ABS-G5 KG, polysiloxane 4.9KG, acrylic acid flatting agent 0.1 KG.
The preparation method comprises the following steps:
coating a layer of silicone oil on a PET release film with the width of 1000mm and the thickness of 7.5c to serve as a release layer; fully mixing the raw material components of the resin molding layer to obtain a mixture, feeding the mixture into a double-screw extruder, fully fusing the materials under the shearing, mixing and conveying of a screw to form coating liquid, and extruding the coating liquid from a gap of an extrusion nozzle under the conditions that the temperature of each section of the double-screw extruder is 200-220 ℃ and the rotating speed of the screw is 300 r/min; coating the extrusion coating liquid on a release layer to form a resin forming layer, wherein the thickness of a coated wet film is 25c, the speed is 90m/min, the section of an oven is 12, and the drying temperature is 80 ℃; printing a grain layer on the resin molding layer; and coating a hot-melt adhesive film on the grain layer, heating and drying for 6 minutes at 90 ℃ to ensure that the surface of the grain layer is dry by touch, and reducing the viscosity to prepare the scratch-resistant grain lettering film.
Experimental example: performance testing
The scratch-resistant grain lettering films of examples 1-3 and the grain lettering film finished products (PE material 4, PVC material 5 and PU material 6) purchased in the market are transferred onto the clothing cloth according to the heat transfer printing temperature of 150 ℃, the time of 10s and the pressure of 6KG to respectively manufacture heat transfer printing finished products 1-6, and the conventional pencil hardness test and the GB/T8629 fabric washing standard water washing resistance test are carried out, and the results are shown in the first table:
watch 1
The experimental results show that the pencil hardness of the examples 1-3 is higher than that of the market products 4-6, the washing resistance experiment has no degumming, and the example 1 with higher ABS and other additives has higher scratch resistance, so that the scratch-resistant grain lettering film disclosed by the invention has higher scratch resistance and can better meet the application requirements of zippers and shoes and clothes under the condition of meeting basic requirements.
While the invention has been particularly shown and described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (6)
1. The utility model provides a resistant type line membrane of carving characters, is from type membrane, from type layer, resin shaping layer, line layer, hot melt adhesive layer from bottom to top in proper order, its characterized in that: the resin molding layer comprises the following raw material components in percentage by weight: 60% -70% of TPU, 5% -15% of ABS, 10% -20% of stearic acid modified wollastonite powder, 1% -5% of compatilizer, 1% -5% of polysiloxane and 0% -2% of leveling agent, wherein the TPU is a polyester polyurethane elastomer, the Shore A hardness of the TPU is 65-80, the compatilizer is ABS grafted maleic anhydride, the leveling agent is an acrylic leveling agent, and the preparation method of the stearic acid modified wollastonite powder comprises the following steps: adding stearic acid accounting for 1.0-1.2 percent of the weight of the wollastonite powder, stirring at the speed of 900-.
2. The scratch resistant textured lettering film of claim 1, wherein: the stearic acid modified wollastonite powder has an average particle size of 4-6 μm.
3. A method of producing the scratch-resistant textured marking film of any one of claims 1 to 2, wherein: the method comprises the following steps:
1) preparing a release film;
2) coating a layer of silicone oil on the release film to serve as a release layer;
3) coating a resin molding layer material on the release layer using an extrusion coating method;
4) printing a line layer on the resin molding layer;
5) and coating hot melt adhesive on the grain layer to form a hot melt adhesive layer, and manufacturing the scratch-resistant grain lettering film.
4. The method of making a scratch resistant textured lettering film as recited in claim 3, wherein: the thickness of the release film is 5c-10 c.
5. The method of making a scratch resistant textured lettering film as recited in claim 3, wherein: the extrusion coating process of the resin forming layer adopts a double-screw extruder in the extrusion stage, the temperature of each section of the double-screw extruder is 180-240 ℃, the rotating speed of a screw is 200-400 r/min, the total thickness of the coated resin forming layer is 20c-30c, and the resin forming layer is dried by a 12-section oven at 60-115 ℃, and the speed of the vehicle is 75-100 m/min.
6. The method of making a scratch resistant textured lettering film as recited in claim 3, wherein: and heating and drying the scratch-resistant grain lettering film at the temperature of 80-100 ℃ for 5-8 minutes to ensure that the surface of the scratch-resistant grain lettering film is dry by touch, so that the viscosity is reduced.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711282671.1A CN107892809B (en) | 2017-12-07 | 2017-12-07 | Scratch-resistant grain lettering film and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711282671.1A CN107892809B (en) | 2017-12-07 | 2017-12-07 | Scratch-resistant grain lettering film and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107892809A CN107892809A (en) | 2018-04-10 |
| CN107892809B true CN107892809B (en) | 2020-09-08 |
Family
ID=61807395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711282671.1A Active CN107892809B (en) | 2017-12-07 | 2017-12-07 | Scratch-resistant grain lettering film and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107892809B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610997B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method and application method thereof |
| CN111251743A (en) * | 2020-01-17 | 2020-06-09 | 江西赛欧特科新材料有限公司 | Lettering film and preparation method thereof |
| CN111393831B (en) * | 2020-04-16 | 2021-07-20 | 东莞市雄林新材料科技股份有限公司 | Temperature-resistant lettering film and preparation method thereof |
| CN112795175A (en) * | 2021-01-05 | 2021-05-14 | 浙江新远见材料科技股份有限公司 | Manufacturing process of composite floor |
| CN112959579B (en) * | 2021-02-02 | 2022-12-16 | 福建省尤溪县益康制革有限公司 | Lettering film stripping skin and preparation method thereof |
| CN115505257B (en) * | 2022-10-31 | 2023-11-10 | 昆山红苹果塑胶新材料有限公司 | TPU film applied to house-wear manufacturing wall cloth, preparation method thereof and composite wall cloth |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403303A (en) * | 2002-09-06 | 2003-03-19 | 澄海市东田转印有限公司 | Production process and product of transferring film |
| CN1818001A (en) * | 2006-03-13 | 2006-08-16 | 株洲市宏大高分子材料厂 | Modified TPU abrasive sealing materials, production and use thereof |
| CN106700388A (en) * | 2015-11-15 | 2017-05-24 | 合肥杰事杰新材料股份有限公司 | Scratch-resistant and low-temperature impact resistant ABS/TPU alloy material and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202098136U (en) * | 2011-05-30 | 2012-01-04 | 林日胜 | Heat transfer film and transfer product employing same |
-
2017
- 2017-12-07 CN CN201711282671.1A patent/CN107892809B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403303A (en) * | 2002-09-06 | 2003-03-19 | 澄海市东田转印有限公司 | Production process and product of transferring film |
| CN1818001A (en) * | 2006-03-13 | 2006-08-16 | 株洲市宏大高分子材料厂 | Modified TPU abrasive sealing materials, production and use thereof |
| CN106700388A (en) * | 2015-11-15 | 2017-05-24 | 合肥杰事杰新材料股份有限公司 | Scratch-resistant and low-temperature impact resistant ABS/TPU alloy material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 热/UV双重固化涂料作为热转印膜保护层的应用原理及制备工艺的研究;林瀚 等;《广东印刷》;20140228(第1期);第43页第4段 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107892809A (en) | 2018-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107892809B (en) | Scratch-resistant grain lettering film and manufacturing method thereof | |
| EP3789456B1 (en) | Polyamide resin composition having high metal texture and preparation method of polyamide resin composition | |
| CN102838828B (en) | Bright-black functional black masterbatch for ABS engineering plastics and preparation method thereof | |
| CN102492234B (en) | Production method of red mud complexed polyvinyl chloride colorized rigid plastic | |
| CN103772885A (en) | Flat PC/ABS (polycarbonate/acrylonitrile butadiene styrene) automobile dashboard material and preparation method thereof | |
| CN107541045A (en) | One kind plating PC/ABS alloy materials and its production and use | |
| CN105482351A (en) | ABS material with marble imitation decorative effect and preparation method thereof | |
| CN103772973A (en) | High-abrasion-resistance silicon nitride/nylon6 composite nano-material and preparation method thereof | |
| CN109553948B (en) | High-toughness high-hardness composite material and preparation method thereof | |
| CN113683876A (en) | Spraying-free high-flow high-impact flame-retardant PC material with metal texture and preparation method and application thereof | |
| CN104072982A (en) | High-temperature resistant nylon and preparation method thereof | |
| CN109651752A (en) | A kind of 3D printing ABS consumptive material and preparation method thereof | |
| CN103980679B (en) | One can print special anti-adhesion master batch of PET sheet and preparation method thereof | |
| CN101735549A (en) | PMMA/ABS (polymethyl methacrylate/acrylonitrile butadiene styrene) composite material and manufacturing method | |
| CN113388266B (en) | Pearlescent pigment dispersion coating method and pearlescent effect polycarbonate plate | |
| CN109679302B (en) | High-modulus water-washing-resistant PBT zipper material and application thereof | |
| CN102863731A (en) | Acrylonitrile-butadiene-styrene (ABS) composite plastic, and preparation method and application thereof | |
| KR101228347B1 (en) | Thermoplastic resin composition with high gloss and anti-scrach propertis | |
| CN109503971B (en) | SAN/PMMA composite material for bathroom and preparation method thereof | |
| WO2018076968A1 (en) | Use of polyamide as flow promoter to increase glossiness of reinforced aromatic vinyl copolymer composition | |
| CN101284916B (en) | Antisticking smoothing agent for PU leather | |
| CN111363338B (en) | Alloy section containing PET and PC and preparation method thereof | |
| CN103044851B (en) | High-gloss ABS (acrylonitrile-butadiene-styrene) alloy and method for preparing same from matte ABS | |
| CN107033524B (en) | A kind of thermoplastic elastomer (TPE) and preparation method thereof with PETG secondary injection adhering | |
| CN109467810A (en) | A kind of certificate card injection molding filling master batch and its application method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240515 Address after: Building 6, Innovation and Entrepreneurship Center, High tech Zone, No. 7 Xinqiang Road, Hongshan Town, Shishi City, Quanzhou City, Fujian Province, 362712 Patentee after: FUJIAN ANYUAN OPTICAL TECHNOLOGY Co.,Ltd. Country or region after: China Address before: 362700 No.2 Building, Area B, New Clock and Watch City Production Zone, Hongshan Town, Shishi City, Quanzhou City, Fujian Province Patentee before: FUJIAN XINLIYUAN REFLECTIVE MATERIAL Co.,Ltd. Country or region before: China |