CN107830520A - A kind of burning-point burner - Google Patents
A kind of burning-point burner Download PDFInfo
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- CN107830520A CN107830520A CN201710889668.XA CN201710889668A CN107830520A CN 107830520 A CN107830520 A CN 107830520A CN 201710889668 A CN201710889668 A CN 201710889668A CN 107830520 A CN107830520 A CN 107830520A
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- stirred reactor
- mechanically stirred
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/34—Burners specially adapted for use with means for pressurising the gaseous fuel or the combustion air
- F23D14/36—Burners specially adapted for use with means for pressurising the gaseous fuel or the combustion air in which the compressor and burner form a single unit
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/46—Details, e.g. noise reduction means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/061—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
- F23G7/065—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2203/00—Gaseous fuel burners
- F23D2203/10—Flame diffusing means
- F23D2203/104—Grids, e.g. honeycomb grids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2207/00—Ignition devices associated with burner
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A kind of burning-point burner, the left end in horizontal air channel have elbow；The lower end of pneumatic nested regulating valve and the upper end of elbow are connected, and grating floor is pneumatically provided between nested regulating valve and elbow；The upper end connection combuster of pneumatic nested regulating valve；Flame rings are installed in the middle part of combustion chamber, and its upper surface is provided with multiple flame spray remolten ports；Flame rings are fixedly connected with one end of gas service pipe；The other end combustion gas regulation rotary valve of gas service pipe is connected with the mixed outlet side for handing over room of microwave；Microwave is mixed to hand over interior to be provided with microwave oscillator；The mixed inlet end for handing over room of microwave is connected with Pneumatic booster pump；High-voltage metallized pulse capacitor is located at combustion chamber bottom；Riser is installed in the surface of flame rings；Vortex flame pilot fence is fixedly arranged on the top of tubaeform wind outlet section；Isolation type safety screen is hingedly connected with the top of combustion chamber.The burner small volume, rational in infrastructure, compactness is high, suitable for the processing to chlorination carbon.
Description
Technical field
The present invention relates to technical field of environment protection equipment, and in particular to a kind of burning-point burner.
Background technology
Carbon tetrachloride (CCl4) is a kind of organic chlorohydrocarbon of artificial synthesized low boiling (proportion 1.591g/cm3, boiling point 77
DEG C), it is slightly soluble in water.Foreign study shows：Carbon tetrachloride belongs to typical hepatotoxic agent, is influence maincenter first during high concentration
Nervous system, then influence liver, kidney.It has persistence, extended residual and a bioconcentration in the environment, therefore from 1979
Year has been included in " pollutant of priority acccess control in underground water containing carbon tetrachloride " by U.S. EPA, has also been included in 68 kinds " in water by China
The pollutant of priority acccess control " list.
Eighties of last century the seventies cause some regional underground water by carbon tetrachloride due to a large amount of manufactures and using agricultural chemicals
Pollution, as the water-bearing layer near the Michigan water-bearing layer in the U.S. and Canadian Ottawa by the polluting of carbon tetrachloride (
It exists with nonaqueous phase (NAPL) more in water-bearing layer).
At present, the various equipment for carbon tetrachloride processing continue to bring out.The burner carbon tetrachloride important as one
The equipment of processing has also obtained certain development.But the existing burner volume for carbon tetrachloride processing is big, structure not
Rationally, compactness is not high, and it is undesirable to gaseous carbon tetrachloride treatment effect, is not suitable for the place of carbon tetrachloride systematization
Reason.
The content of the invention
In view of the above-mentioned problems of the prior art, the present invention provides a kind of burning-point burner, the burner small volume, knot
Structure is reasonable, compactness is high, its ideal treatment effect to chlorination carbon, suitable for the processing of carbon tetrachloride systematization.
To achieve these goals, the present invention provides a kind of burning-point burner, including horizontal air channel, high-voltage metallized pulse
Capacitor, pneumatic nested regulating valve, flame rings, riser and vortex flame pilot fence；
The left end in the horizontal air channel is folded upward at forming elbow；The lower end of the pneumatic nested regulating valve and the elbow
Upper end connection, pneumatically junction between nested regulating valve and elbow be provided with grating floor, grating floor is cell structure；
The upper end connection combuster of pneumatic nested regulating valve；
The flame rings are fixedly installed on the middle part of combustion chamber, and flame rings are made up of the metal material of hollow tubular, thereon
Surface is circumferentially equably fixedly connected with multiple and its intracavity inter-connection flame spray remolten port；The one of flame rings and gas service pipe
End is fixedly connected, and the intracavity inter-connection of the two；The other end of the gas service pipe is adjusted after passing combustion chamber by combustion gas
Rotary valve is connected with the mixed outlet side for handing over room of microwave；The microwave is mixed to hand over interior to be provided with microwave oscillator；The mixed friendship room of microwave
Inlet end is connected with Pneumatic booster pump；
The High-voltage metallized pulse capacitor is arranged on the combustion chamber bottom and positioned at the inner side of flame rings, high pressure gold
Categoryization impulse capacitor is made up of high voltage power supply and electric discharge device；
The riser be fixedly installed on the surface of flame rings and with bottom straight length and top it is tubaeform go out
Wind section；
The vortex flame pilot fence is fixedly installed on the top of tubaeform wind outlet section, and vortex flame pilot fence is lattice
Grid structure；
Isolation type safety screen is hingedly connected with the top of combustion chamber, isolation type safety screen is cell structure.
In the technical scheme, rotary valve is adjusted by combustion gas and is arranged between horizontal air channel and combustion chamber, can be with convenient
Flow of the ground control into the pending gas of combustion chamber；, can be to entering combustion chamber by the setting of Pneumatic booster pump
Fuel gas is sufficiently pressurized, and then can provide more fully fuel gas, in order to promote to burn, and can be obtained higher
Burning-point, so as to improve flame at higher temperature.The setting of High-voltage metallized pulse capacitor can improve stable pulse electricity
Release, quickly to light fuel gas.Flame rings are made up of the metal material of hollow tubular when can ensure that it has longer
Between service life, and can high temperature resistant, high pressure resistant.Microwave oscillator is arranged on the mixed friendship interior of microwave can be to the gas of its inside
Realize sufficiently mix, so as to so that combustion process more fully and thoroughly.The setting of the straight wall section of riser can be to flame
The lifting of height is carried out, the setting of tubaeform wind outlet section can promote the discharge of tail gas.Vortex flame pilot fence can guide
The direction arranged outside tail gas and flame.The burner small volume, rational in infrastructure, compactness is high, its reason for the treatment of effect to chlorination carbon
Think, suitable for the processing of carbon tetrachloride systematization.
Further, in order to improve the service life of grating floor, the grating floor is matched somebody with somebody in parts by weight by following components
Than composition：
249~474 parts of softened water, 41~83 parts of disodium alkyl polyoxyethylene sulfosuccinate, butanedioic acid
44~153 parts of (ethylhexyl) sodium sulfonate, 40~57 parts of N- butyl para toluene sulfonamide, N- ethyl-N- butyl -2,6- dinitros
43~100 parts of base -4- 5-trifluoromethylanilines, 1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydros -9,10-
46~107 parts of dioxo anthracene -2- sulfonate sodiums, 1,5- 43~66 parts of diamino-anthraquinone -2- sulfonic acid, 3,5- syringol 40
~85 parts, 48~103 parts of barium nanoparticle, the bromo- 1- methylaminos anthraquinones 41 of 4- that mass concentration is 44.7ppm~274.2ppm~
83 parts, 2,5- bis- chloro- 4- [4- [[3- [(ethylphenyl amino) sulfonyl] -4- aminomethyl phenyls] azo] -4,5- dihydro -3- first
Base -5- oxygen -1H- pyrazol-1-yls] 31~74 parts of benzene sulfonic acid, 32~68 parts of melissyl phosphate (salt), (the 2- ethyls of N, N- bis-
Hexyl) 43~83 parts of -1H- BTA -1- methylamines, 50~94 parts of 4- methyl tetrahydro phthalic anhydrides, mass concentration be 40.6ppm~
73~127 parts of 307.4ppm Monododecylphosphate potassium；The 1- amino that mass concentration is 40.25ppm~220.27ppm-
50.53~75.23 parts of 4- bromo anthraquinone -2- sulfonic acid；36.78~65.36 parts of 2- ethyl -1,3- hexylene glycols.
Further, in order to improve the service life of grating floor, the particle diameter of the barium nanoparticle is 48.6 μm~58.9 μ
m。
Further, in order that the more reliable performance of grating floor, the grating floor are prepared by following steps：
1st step：In mechanically stirred reactor, softened water and AEO sulfosuccinic acid monoesters two are added
Sodium salt, start the mixer in mechanically stirred reactor, setting speed is 42rpm~88rpm, is started in mechanically stirred reactor
Double heating furnace, temperature is risen to 57.9 DEG C~58.1 DEG C, add butanedioic acid (ethylhexyl) sodium sulfonate and stir, carry out
Halo decarboxylation is reacted 34~45 minutes, adds N- butyl para toluene sulfonamides, it is 33.383m to be passed through flow3/ min~
74.180m3/ min xenon 0.4~0.1 hour；N- ethyl-N- butyl -2,6- two is added in mechanically stirred reactor afterwards
Nitro -4- 5-trifluoromethylanilines, the Double heating furnace being again started up in mechanically stirred reactor, make temperature rise to 74.9 DEG C~
107.1 DEG C, 34~45 minutes are incubated, adds 1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydros -9,10-
Dioxo anthracene -2- sulfonate sodiums, the pH value for adjusting solution in mechanically stirred reactor are 4.8~8.9, are incubated 34~274 minutes；
2nd step：Barium nanoparticle separately is taken, by barium nanoparticle at power is ultrasonic wave under 5.748KW~11.189KW
Reason 0.4~0.1 hour；Barium nanoparticle is added in another mechanically stirred reactor, addition mass concentration is 44.7ppm
~274.2ppm bromo- 1- methylaminos the anthraquinones of 4- disperse barium nanoparticle, start the Double heating furnace in mechanically stirred reactor,
Make solution temperature between 4.83 × 10 DEG C~8.91 × 10 DEG C, start the mixer in mechanically stirred reactor, and with 4.89
×102Rpm~8.94 × 102Rpm speed stirring, adjustment pH value is between 4.8~8.9, insulated and stirred 0.5~1.1 hour；
Stop reaction afterwards and stand 5.7 × 10~11.1 × 10 minutes, go the removal of impurity；Suspension is added into N, (the 2- ethyl hexyls of N- bis-
Base) -1H- BTA -1- methylamines, for adjustment pH value between 1.3~2.1, formation sediment passes through centrifugation with water elution is softened
Machine is in rotating speed 4.399 × 103Rpm~9.674 × 103Solid content is obtained under rpm, 2.226 × 102DEG C~3.45 × 102DEG C temperature
The lower drying of degree, crosses 420~520 mesh sieves after grinding, standby；
3rd step：It is another take 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- syringol and the processing of the 2nd step after barium nanometer it is micro-
Grain, irradiated after being well mixed using 60Co external exposures, the energy that 60Co external exposures irradiate is 31.363MeV~59.126MeV, agent
It is 43~68 minutes to measure as 79.90kGy~119.270kGy, irradiation time, obtains 1, the 5- diamino-anthraquinones -2- of character change
Sulfonic acid, 3,5- syringol and barium nanoparticle mixture；By 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- dimethoxys
Phenol and barium nanoparticle mixture are placed in another mechanically stirred reactor, start the dual-heated in mechanically stirred reactor
Stove, 42.5 DEG C~88.1 DEG C of design temperature, start the mixer in mechanically stirred reactor, rotating speed is 34rpm~429rpm, pH
It is adjusted between 4.8~8.9, is dehydrated 43~57 minutes, it is standby；
4th step：1,5- diamino-anthraquinone -2- sulfonic acid that the character that 3rd step is obtained changes, 3,5- syringol and
Barium nanoparticle is well mixed, and is added in the 1- amino -4- bromo anthraquinone -2- sulfonic acid that mass concentration is 40.2ppm~220.2ppm,
Cocurrent is added in the mechanically stirred reactor of the 1st step, and flow acceleration is 179.6mL/min~907.9mL/min；Start machinery to stir
Reaction mechanical stirrer is mixed, setting speed is 48rpm~88rpm；Stirring 4~8 minutes；Add chloro- 4- [the 4- [[3- of 2,5- bis-
[(ethylphenyl amino) sulfonyl] -4- aminomethyl phenyls] azo] -4,5- dihydro -3- methyl -5- oxygen -1H- pyrazol-1-yls] benzene
Sulfonic acid, start the Double heating furnace in mechanically stirred reactor, be warming up to 78.1 DEG C~115.2 DEG C, pH is adjusted to 4.8~8.9
Between, it is 33.221m to be passed through xenon throughput3/ min~74.283m3/ min, insulation stand 68~98 minutes；It is again started up machine
Tool stirring reaction mechanical stirrer, rotating speed are 43rpm~88rpm, add melissyl phosphate (salt), make the hydrophilic of its reaction solution
Lipophile balance critical value is 5.748~11.189, and pH is adjusted between 4.8~8.9, and insulation stands 67~107 minutes；
5th step：Start mechanically stirred reactor in mixer, setting speed is 40rpm~107rpm, while stirring to
2- ethyl -1,3- hexylene glycols are added in mechanically stirred reactor, start the Double heating furnace in mechanically stirred reactor, set machine
Temperature in tool stirred reactor is 4.990 × 102DEG C~9.811 × 102DEG C, after being incubated 67~107 minutes, add 4- methyl
THPA, halo decarboxylation are reacted 34~45 minutes；Monododecylphosphate potassium is added afterwards, starts mechanic whirl-nett reaction
Double heating furnace in device, the temperature in mechanically stirred reactor is set as 118.9 DEG C~174.8 DEG C, pH adjusted to 4.8~
Between 8.9, pressure is 0.441MPa~0.479MPa, and the reaction time is 0.4~0.9 hour；0MPa is depressurized to afterwards, is cooled to
54.4 DEG C~59.4 DEG C discharge into molding press, that is, obtain grating floor.
Further, in order to improve the injection pressure of flame, and the temperature of flame can be lifted, the number of the flame spray remolten port
Measure as 20-30, flame spray remolten port is made up of manganese steel, and it is in up-small and down-big frustum type.
Further, in order to improve guiding effect, the distance of vortex flame pilot fence to tubaeform wind outlet section upper end is 20-
30mm, vortex flame pilot fence are made of manganese steel.
Further, grating floor is disc, and diameter 50-60mm, the quantity 20-30 of Turbogrid plates are individual.
Further, in order to lift the height of flame, the distance between riser and flame rings are 20-30mm.
Further, in order to improve the temperature of flame, and there can be longer service life, flame rings and gas service pipe are equal
It is made of brass.
Brief description of the drawings
Fig. 1 is the structural representation in the present invention.
In figure：3-1, horizontal air channel, 3-2, grating floor, 3-3, High-voltage metallized pulse capacitor, 3-4, pneumatic nesting
Regulating valve, 3-5, tubaeform wind outlet section, 3-6, vortex flame pilot fence, 3-7, isolation type safety screen, 3-8, riser, 3-
9th, flame spray remolten port, 3-10, gas service pipe, 3-11, combustion gas regulation rotary valve, 3-12, Pneumatic booster pump, 3-13, microwave
It is mixed to hand over room, 3-14, flame rings, 3-15, combustion chamber.
Embodiment
The invention will be further described below.
As shown in figure 1, a kind of burning-point burner, including it is horizontal air channel 3-1, High-voltage metallized pulse capacitor 3-3, pneumatic
Nested regulating valve 3-4, flame rings 3-14, riser 3-8 and vortex flame pilot fence 3-6；
The left end of the horizontal air channel 3-1 is folded upward at forming elbow；The lower end of the pneumatic nested regulating valve 3-4 and institute
The upper end connection of elbow is stated, pneumatically the junction between nested regulating valve 3-4 and elbow is provided with grating floor 3-2, grid bottom
Plate 3-2 is cell structure；Pneumatic nested regulating valve 3-4 upper end connection combuster 3-15；
The flame rings 3-14 is fixedly installed on combustion chamber 3-15 middle part, flame rings 3-14 by hollow tubular metal material
Material is made, and its upper surface is circumferentially equably fixedly connected with multiple and its intracavity inter-connection flame spray remolten port 3-9；Flame rings 3-
14 are fixedly connected with gas service pipe 3-10 one end, and the intracavity inter-connection of the two；The gas service pipe 3-10's is another
End is connected after passing combustion chamber 3-15 by combustion gas regulation rotary valve 3-11 with the mixed outlet side for handing over room 3-13 of microwave；Combustion gas is adjusted
Rotary valve 3-11 realizes the controllable adjustment to combustion gas, and mixed hand in the 3-13 of room of the microwave is provided with microwave oscillator, microwave oscillation
Device selects HGY-1 type microwave oscillators, to realize the mixing to gas, can specifically realize that methane gas refers to sulfur dioxide
The property shown gas mixes according to a certain percentage；The mixed inlet end for handing over room 3-13 of microwave is connected with Pneumatic booster pump 3-12；Microwave is mixed to be handed over
Room 3-13 inlet end is connected with methane gas with the hybrid gas source of the indicative gas of sulfur dioxide, and Pneumatic booster pump 3-12 is used
In the supercharging to fuel gas.
The High-voltage metallized pulse capacitor 3-3 is arranged on the combustion chamber 3-15 bottoms and positioned at flame rings 3-14's
Inner side, High-voltage metallized pulse capacitor 3-3 are made up of high voltage power supply and electric discharge device, High-voltage metallized pulse capacitor 3-3
Using BSMJ0.45-30-3 high-voltage pulse capacitors, the upper end of the electric discharge device is set close to flame spray remolten port 3-9；
The riser 3-8 is fixedly installed on flame rings 3-14 surface and straight length and the loudspeaker on top with bottom
Shape wind outlet section 3-5, tubaeform wind outlet section 3-5 promotes the outer row of tail gas；
The vortex flame pilot fence 3-6 is fixedly installed on tubaeform wind outlet section 3-5 top, vortex flame pilot grid
Column 3-6 is cell structure；Vortex flame pilot fence 3-6 guides the direction of motion arranged outside tail gas and flame.
Isolation type safety screen 3-7, isolating safety grid are hingedly connected with combustion chamber 3-15 top gas outlet
Plate 3-7 is cell structure, and its diameter is equivalent with gas outlet, adjustable with gas outlet hinged design, opening angle, it is possible to achieve to going out
The totally-enclosed and full open of gas port.
Rotary valve is adjusted by combustion gas to be arranged between horizontal air channel and combustion chamber, can easily be controlled into combustion chamber
Pending gas flow；By the setting of Pneumatic booster pump, the fuel gas for entering combustion chamber can be carried out abundant
Supercharging, and then more fully fuel gas can be provided, in order to promote to burn, and higher burning-point can be obtained, so as to carry
High flame at higher temperature.The setting of High-voltage metallized pulse capacitor can improve the release of stable pulse electricity, with quick point
Fire fuel gas.Flame rings are made up of the metal material of hollow tubular can ensure that it has the service life of long period, and
Can high temperature resistant, high pressure resistant.Microwave oscillator is arranged on indoor can be realized to the gas of its inside of the mixed friendship of microwave and sufficiently mixed,
So as to so that combustion process more fully and thoroughly.The straight wall section of riser sets the lifting that height can be carried out to flame,
The setting of tubaeform wind outlet section can promote the discharge of tail gas.Vortex flame pilot fence can guide what is arranged outside tail gas and flame
Direction.The burner small volume, rational in infrastructure, compactness is high, its ideal treatment effect to chlorination carbon, suitable for carbon tetrachloride
The processing of systematization.
In order to improve the service life of grating floor, the grating floor 3-2 is by following components proportioning group in parts by weight
Into：
249~474 parts of softened water, 41~83 parts of disodium alkyl polyoxyethylene sulfosuccinate, butanedioic acid
44~153 parts of (ethylhexyl) sodium sulfonate, 40~57 parts of N- butyl para toluene sulfonamide, N- ethyl-N- butyl -2,6- dinitros
43~100 parts of base -4- 5-trifluoromethylanilines, 1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydros -9,10-
46~107 parts of dioxo anthracene -2- sulfonate sodiums, 1,5- 43~66 parts of diamino-anthraquinone -2- sulfonic acid, 3,5- syringol 40
~85 parts, 48~103 parts of barium nanoparticle, the bromo- 1- methylaminos anthraquinones 41 of 4- that mass concentration is 44.7ppm~274.2ppm~
83 parts, 2,5- bis- chloro- 4- [4- [[3- [(ethylphenyl amino) sulfonyl] -4- aminomethyl phenyls] azo] -4,5- dihydro -3- first
Base -5- oxygen -1H- pyrazol-1-yls] 31~74 parts of benzene sulfonic acid, 32~68 parts of melissyl phosphate (salt), (the 2- ethyls of N, N- bis-
Hexyl) 43~83 parts of -1H- BTA -1- methylamines, 50~94 parts of 4- methyl tetrahydro phthalic anhydrides, mass concentration be 40.6ppm~
73~127 parts of 307.4ppm Monododecylphosphate potassium；Mass concentration is 40.2ppm~220.2ppm 1- amino -4-
50.53~75.23 parts of bromo anthraquinone -2- sulfonic acid；36~65 parts of 2- ethyl -1,3- hexylene glycols.
In order to improve the service life of grating floor, the particle diameter of the barium nanoparticle is 48.6 μm~58.9 μm.
In order that the more reliable performance of grating floor, the grating floor 3-2 is prepared by following steps：
1st step：In mechanically stirred reactor, softened water and AEO sulfosuccinic acid monoesters two are added
Sodium salt, start the mixer in mechanically stirred reactor, setting speed is 42rpm~88rpm, is started in mechanically stirred reactor
Double heating furnace, temperature is risen to 57.9 DEG C~58.1 DEG C, add butanedioic acid (ethylhexyl) sodium sulfonate and stir, carry out
Halo decarboxylation is reacted 34~45 minutes, adds N- butyl para toluene sulfonamides, it is 33.383m to be passed through flow3/ min~
74.180m3/ min xenon 0.4~0.1 hour；N- ethyl-N- butyl -2,6- two is added in mechanically stirred reactor afterwards
Nitro -4- 5-trifluoromethylanilines, the Double heating furnace being again started up in mechanically stirred reactor, make temperature rise to 74.9 DEG C~
107.1 DEG C, 34~45 minutes are incubated, adds 1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydros -9,10-
Dioxo anthracene -2- sulfonate sodiums, the pH value for adjusting solution in mechanically stirred reactor are 4.8~8.9, are incubated 34~274 minutes；
2nd step：Barium nanoparticle separately is taken, by barium nanoparticle at power is ultrasonic wave under 5.748KW~11.189KW
Reason 0.4~0.1 hour；Barium nanoparticle is added in another mechanically stirred reactor, addition mass concentration is 44.7ppm
~274.2ppm bromo- 1- methylaminos the anthraquinones of 4- disperse barium nanoparticle, start the Double heating furnace in mechanically stirred reactor,
Make solution temperature between 4.83 × 10 DEG C~8.91 × 10 DEG C, start the mixer in mechanically stirred reactor, and with 4.89
×102Rpm~8.94 × 102Rpm speed stirring, adjustment pH value is between 4.8~8.9, insulated and stirred 0.5~1.1 hour；
Stop reaction afterwards and stand 5.7 × 10~11.1 × 10 minutes, go the removal of impurity；Suspension is added into N, (the 2- ethyl hexyls of N- bis-
Base) -1H- BTA -1- methylamines, for adjustment pH value between 1.3~2.1, formation sediment passes through centrifugation with water elution is softened
Machine is in rotating speed 4.399 × 103Rpm~9.674 × 103Solid content is obtained under rpm, 2.226 × 102DEG C~3.45 × 102DEG C temperature
The lower drying of degree, crosses 420~520 mesh sieves after grinding, standby；
3rd step：It is another take 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- syringol and the processing of the 2nd step after barium nanometer it is micro-
Grain, irradiated after being well mixed using 60Co external exposures, the energy that 60Co external exposures irradiate is 31.363MeV~59.126MeV, agent
It is 43~68 minutes to measure as 79.90kGy~119.270kGy, irradiation time, obtains 1, the 5- diamino-anthraquinones -2- of character change
Sulfonic acid, 3,5- syringol and barium nanoparticle mixture；By 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- dimethoxys
Phenol and barium nanoparticle mixture are placed in another mechanically stirred reactor, start the dual-heated in mechanically stirred reactor
Stove, 42.5 DEG C~88.1 DEG C of design temperature, start the mixer in mechanically stirred reactor, rotating speed is 34rpm~429rpm, pH
It is adjusted between 4.8~8.9, is dehydrated 43~57 minutes, it is standby；
4th step：1,5- diamino-anthraquinone -2- sulfonic acid that the character that 3rd step is obtained changes, 3,5- syringol and
Barium nanoparticle is well mixed, and is added in the 1- amino -4- bromo anthraquinone -2- sulfonic acid that mass concentration is 40.2ppm~220.2ppm,
Cocurrent is added in the mechanically stirred reactor of the 1st step, and flow acceleration is 179.6mL/min~907.9mL/min；Start machinery to stir
Reaction mechanical stirrer is mixed, setting speed is 48rpm~88rpm；Stirring 4~8 minutes；Add chloro- 4- [the 4- [[3- of 2,5- bis-
[(ethylphenyl amino) sulfonyl] -4- aminomethyl phenyls] azo] -4,5- dihydro -3- methyl -5- oxygen -1H- pyrazol-1-yls] benzene
Sulfonic acid, start the Double heating furnace in mechanically stirred reactor, be warming up to 78.1 DEG C~115.2 DEG C, pH is adjusted to 4.8~8.9
Between, it is 33.221m to be passed through xenon throughput3/ min~74.283m3/ min, insulation stand 68~98 minutes；It is again started up machine
Tool stirring reaction mechanical stirrer, rotating speed are 43rpm~88rpm, add melissyl phosphate (salt), make the hydrophilic of its reaction solution
Lipophile balance critical value is 5.748~11.189, and pH is adjusted between 4.8~8.9, and insulation stands 67~107 minutes；
5th step：Start mechanically stirred reactor in mixer, setting speed is 40rpm~107rpm, while stirring to
2- ethyl -1,3- hexylene glycols are added in mechanically stirred reactor, start the Double heating furnace in mechanically stirred reactor, set machine
Temperature in tool stirred reactor is 4.990 × 102DEG C~9.811 × 102DEG C, after being incubated 67~107 minutes, add 4- methyl
THPA, halo decarboxylation are reacted 34~45 minutes；Monododecylphosphate potassium is added afterwards, starts mechanic whirl-nett reaction
Double heating furnace in device, the temperature in mechanically stirred reactor is set as 118.9 DEG C~174.8 DEG C, pH adjusted to 4.8~
Between 8.9, pressure is 0.441MPa~0.479MPa, and the reaction time is 0.4~0.9 hour；0MPa is depressurized to afterwards, is cooled to
54.4 DEG C~59.4 DEG C discharge into molding press, that is, obtain grating floor 3-2.
Following examples further illustrate present disclosure, but should not be construed as limiting the invention.Without departing substantially from
In the case of spirit and essence of the invention, the modification and replacement made to the inventive method, step or condition, the present invention is belonged to
Scope.Unless otherwise specified, the conventional meanses that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
Grating of the present invention is prepared according to following steps, and is counted in parts by weight：
1st step：In mechanically stirred reactor, 249 parts of softened water, AEO sulfosuccinic acid list are added
41 parts of ester disodium salt, start the mixer in mechanically stirred reactor, setting speed 42rpm, start mechanically stirred reactor
In Double heating furnace, temperature is risen to 57.9 DEG C, add 44 parts of butanedioic acid (ethylhexyl) sodium sulfonate and stir, carry out halogen
Reacted 34 minutes for decarboxylation, add 40 parts of N- butyl para toluene sulfonamide, it is 33.383m to be passed through flow3/ min xenon 0.4
Hour；43 parts of N- ethyl-N- butyl -2,6- dinitro -4- 5-trifluoromethylanilines are added in mechanically stirred reactor afterwards, then
Double heating furnace in secondary startup mechanically stirred reactor, temperature is risen to 74.9 DEG C, be incubated 34 minutes, add 1- amino -4-
46 parts of [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums, adjust mechanical agitation
The pH value of solution is 4.8 in reactor, is incubated 34 minutes；
2nd step：48 parts of barium nanoparticle separately is taken, ultrasonication 0.4 is small in the case where power is 5.748KW by barium nanoparticle
When；Barium nanoparticle is added in another mechanically stirred reactor, adds the bromo- 1- first of 4- that mass concentration is 44.7ppm
41 parts of amino anthraquinones, disperse barium nanoparticle, start the Double heating furnace in mechanically stirred reactor, make solution temperature 4.83
× 10 DEG C, start the mixer in mechanically stirred reactor, and with 4.89 × 102Rpm speed stirring, adjustment pH value 4.8,
Insulated and stirred 0.5 hour；Stop reaction afterwards and stand 5.7 × 10 minutes, go the removal of impurity；Suspension is added into N, (the 2- second of N- bis-
Base hexyl) 43 parts of -1H- BTA -1- methylamines, adjustment pH value forms sediment softening water elution, passes through centrifugation 1.3
Machine is in rotating speed 4.399 × 103Solid content is obtained under rpm, 2.226 × 102Dried at a temperature of DEG C, 420 mesh sieves are crossed after grinding, it is standby
With；
3rd step：After separately taking 43 parts of 1,5- diamino-anthraquinone -2- sulfonic acid, 40 parts of 3,5- syringol and the processing of the 2nd step
48 parts of barium nanoparticle, be well mixed after using 60Co external exposures irradiate, 60Co external exposures irradiation energy for 31.363MeV,
Dosage is 79.90kGy, irradiation time is 43 minutes, obtains 1,5- diamino-anthraquinone -2- sulfonic acid, 3, the 5- diformazans of character change
Epoxide phenol and barium nanoparticle mixture；1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- syringol and barium nanometer is micro-
Grain mixture is placed in another mechanically stirred reactor, starts the Double heating furnace in mechanically stirred reactor, design temperature
42.5 DEG C, start the mixer in mechanically stirred reactor, rotating speed 34rpm, pH are adjusted to 4.8, be dehydrated 43 minutes, standby；
4th step：1,5- diamino-anthraquinone -2- sulfonic acid that the character that 3rd step is obtained changes, 3,5- syringol and
Barium nanoparticle is well mixed, and is added in 50 parts of the 1- amino -4- bromo anthraquinone -2- sulfonic acid that mass concentration is 40.2ppm, cocurrent adds
Into the mechanically stirred reactor of the 1st step, flow acceleration 179.6mL/min；Start mechanically stirred reactor mixer, setting
Rotating speed is 48rpm；Stirring 4 minutes；Add bis- chloro- 4- of 2,5- [4- [[3- [(ethylphenyl amino) sulfonyl] -4- methylbenzenes
Base] azo] -4,5- dihydro -3- methyl -5- oxygen -1H- pyrazol-1-yls] 31 parts of benzene sulfonic acid, start in mechanically stirred reactor
Double heating furnace, 78.1 DEG C are warming up to, pH is adjusted to 4.8, and it is 33.221m to be passed through xenon throughput3/ min, insulation stand 68 points
Clock；Mechanically stirred reactor mixer is again started up, rotating speed 43rpm, 32.603 parts of melissyl phosphate (salt) is added, makes
The hydrophilic-lipophilic balance critical value of its reaction solution is 5.748, and causes pH to be adjusted to 4.8, and insulation stands 67 minutes；
5th step：Start the mixer in mechanically stirred reactor, setting speed 40rpm, while stirring to mechanical agitation
36 parts of 2- ethyls -1,3- hexylene glycol is added in reactor, starts the Double heating furnace in mechanically stirred reactor, setting machinery stirs
It is 4.990 × 10 to mix the temperature in reactor2DEG C, after being incubated 67 minutes, 50 parts of 4- methyl tetrahydro phthalic anhydrides are added, halo is carried out and takes off
Carboxylation reaction 34 minutes；40.6ppm 73 parts of Monododecylphosphate potassium is added afterwards, is started in mechanically stirred reactor
Double heating furnace, the temperature in mechanically stirred reactor is set as 118.9 DEG C, pH is adjusted to 4.8, pressure 0.441MPa, instead
It is 0.4 hour between seasonable；0MPa is depressurized to afterwards, is cooled to 54.4 DEG C and is discharged into molding press, that is, obtains grating floor 3-2.
The particle diameter of wherein described barium nanoparticle is 48.6 μm.
Embodiment 2
Grating of the present invention is prepared according to following steps, and is counted in parts by weight：
1st step：In mechanically stirred reactor, 474 parts of softened water, AEO sulfosuccinic acid list are added
83 parts of ester disodium salt, start the mixer in mechanically stirred reactor, setting speed 88rpm, start mechanically stirred reactor
In Double heating furnace, temperature is risen to 58 DEG C, add 153 parts of butanedioic acid (ethylhexyl) sodium sulfonate and stir, carry out halogen
.45 minutes are reacted for decarboxylation, add 57 parts of N- butyl para toluene sulfonamide, it is 74.180m to be passed through flow3/ min xenon
0.1 hour；N- ethyl-N- butyl -2,6- dinitro -4- 5-trifluoromethylanilines 100 are added in mechanically stirred reactor afterwards
Part, the Double heating furnace being again started up in mechanically stirred reactor, temperature is risen to 107.1 DEG C, be incubated 45 minutes, add 1- ammonia
Base -4- [4- (2- chloro acetylaminos) phenylamino] -107 parts of 9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums, adjust machine
The pH value of solution is 8.9 in tool stirred reactor, is incubated 274 minutes；
2nd step：Separately take 103 parts of barium nanoparticle, by barium nanoparticle power be 11.189KW under ultrasonication 0.1
Hour；Barium nanoparticle is added in another mechanically stirred reactor, adds the bromo- 1- of 4- that mass concentration is 274.2ppm
83 parts of methylamino anthraquinone, disperse barium nanoparticle, start the Double heating furnace in mechanically stirred reactor, solution temperature is existed
8.91 × 10 DEG C, start the mixer in mechanically stirred reactor, and with 8.94 × 102Rpm speed stirring, adjustment pH value exist
8.9, insulated and stirred 1.1 hours；Stop reaction afterwards and stand 11.1 × 10 minutes, go the removal of impurity；Suspension is added into N, N- bis-
83 parts of (2- ethylhexyls) -1H- BTA -1- methylamines, adjustment pH value form sediment softening water elution, passed through 2.1
Centrifuge is in rotating speed 9.674 × 103Solid content is obtained under rpm, 3.45 × 102Dried at a temperature of DEG C, 520 mesh sieves crossed after grinding,
It is standby；
3rd step：It is another to take 66. parts of 1,5- diamino-anthraquinone -2- sulfonic acid, 85 parts of 3,5- syringol and the processing of the 2nd step
103 parts of barium nanoparticle afterwards, irradiated after being well mixed using 60Co external exposures, the energy of 60Co external exposures irradiation is
59.126MeV, dosage 119.270kGy, irradiation time are 68 minutes, obtain 1, the 5- diamino-anthraquinone -2- sulphurs of character change
Acid, 3,5- syringol and barium nanoparticle mixture；By 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- dimethoxy benzenes
Phenol and barium nanoparticle mixture are placed in another mechanically stirred reactor, start the dual-heated in mechanically stirred reactor
Stove, 88.1 DEG C of design temperature, start the mixer in mechanically stirred reactor, rotating speed 429rpm, pH are adjusted to 8.9, dehydration
It is 57 minutes, standby；
4th step：1,5- diamino-anthraquinone -2- sulfonic acid that the character that 3rd step is obtained changes, 3,5- syringol and
Barium nanoparticle is well mixed, and is added in 75 parts of the 1- amino -4- bromo anthraquinone -2- sulfonic acid that mass concentration is 220.2ppm, cocurrent
Add in the mechanically stirred reactor of the 1st step, flow acceleration 907.9mL/min；Start mechanically stirred reactor mixer, if
It is 88rpm to determine rotating speed；Stirring 8 minutes；Add bis- chloro- 4- of 2,5- [4- [[3- [(ethylphenyl amino) sulfonyl] -4- methyl
Phenyl] azo] -4,5- dihydro -3- methyl -5- oxygen -1H- pyrazol-1-yls] 74 parts of benzene sulfonic acid, start in mechanically stirred reactor
Double heating furnace, be warming up to 115.2 DEG C, pH is adjusted to 8.9, and it is 74.283m to be passed through xenon throughput3/ min, insulation are stood
98 minutes；Mechanically stirred reactor mixer is again started up, rotating speed 88rpm, 68 parts of melissyl phosphate (salt) is added, makes
The hydrophilic-lipophilic balance critical value of its reaction solution is 11.189, and causes pH to be adjusted to 8.9, and insulation stands 107 minutes；
5th step：Start the mixer in mechanically stirred reactor, setting speed 107rpm, stirred while stirring to machinery
Mix and 65 parts of 2- ethyls -1,3- hexylene glycol is added in reactor, start the Double heating furnace in mechanically stirred reactor, setting machinery
Temperature in stirred reactor is 9.811 × 102DEG C, after being incubated 107 minutes, 94 parts of 4- methyl tetrahydro phthalic anhydrides are added, carry out halogen
Reacted 45 minutes for decarboxylation；307.4ppm 127 parts of Monododecylphosphate potassium is added afterwards, starts mechanic whirl-nett reaction
Double heating furnace in device, the temperature in mechanically stirred reactor is set as 174.8 DEG C, pH is adjusted to 8.9, and pressure is
0.479MPa, reaction time are 0.9 hour；0MPa is depressurized to afterwards, is cooled to 59.4 DEG C and is discharged into molding press, that is, obtains grid
Bottom plate 3-2.
The particle diameter of wherein described barium nanoparticle is 58.964 μm.
Embodiment 3
Grating of the present invention is prepared according to following steps, and is counted in parts by weight：
1st step：In mechanically stirred reactor, 321 parts of softened water, AEO sulfosuccinic acid list are added
60 parts of ester disodium salt, start the mixer in mechanically stirred reactor, setting speed 62rpm, start mechanically stirred reactor
In Double heating furnace, temperature is risen to 58 DEG C, add 80 parts of butanedioic acid (ethylhexyl) sodium sulfonate and stir, carry out halo
Decarboxylation is reacted 34 minutes, adds 52 parts of N- butyl para toluene sulfonamide, it is 52.938m to be passed through flow3/ min xenon 0.3 is small
When；65 parts of N- ethyl-N- butyl -2,6- dinitro -4- 5-trifluoromethylanilines are added in mechanically stirred reactor afterwards, again
Start the Double heating furnace in mechanically stirred reactor, temperature is risen to 84.9 DEG C, be incubated 39 minutes, add 1- amino -4- [4-
(2- chloro acetylaminos) phenylamino] -66 parts of 9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums, adjust mechanic whirl-nett reaction
The pH value of solution is 6.8 in device, is incubated 54 minutes；
2nd step：69 parts of barium nanoparticle separately is taken, ultrasonication 0.2 is small in the case where power is 8.749KW by barium nanoparticle
When；Barium nanoparticle is added in another mechanically stirred reactor, adds the bromo- 1- first of 4- that mass concentration is 64.9ppm
65 parts of amino anthraquinones, disperse barium nanoparticle, start the Double heating furnace in mechanically stirred reactor, make solution temperature 6.89
× 10 DEG C, start the mixer in mechanically stirred reactor, and with 6.89 × 102Rpm speed stirring, adjustment pH value 6.8,
Insulated and stirred 0.8 hour；Stop reaction afterwards and stand 7.7 × 10 minutes, go the removal of impurity；Suspension is added into N, (the 2- second of N- bis-
Base hexyl) 63 parts of -1H- BTA -1- methylamines, adjustment pH value forms sediment softening water elution 1.938, by from
Scheming is in rotating speed 6.939 × 103Solid content is obtained under rpm, 2.922 × 102Dried at a temperature of DEG C, 500 mesh sieves crossed after grinding,
It is standby；
3rd step：After separately taking 52 parts of 1,5- diamino-anthraquinone -2- sulfonic acid, 63 parts of 3,5- syringol and the processing of the 2nd step
52 parts of barium nanoparticle, be well mixed after using 60Co external exposures irradiate, 60Co external exposures irradiation energy for 41.936MeV,
Dosage is 99.990kGy, irradiation time is 53 minutes, obtains 1,5- diamino-anthraquinone -2- sulfonic acid, 3, the 5- diformazans of character change
Epoxide phenol and barium nanoparticle mixture；1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- syringol and barium nanometer is micro-
Grain mixture is placed in another mechanically stirred reactor, starts the Double heating furnace in mechanically stirred reactor, design temperature
52.9 DEG C, start the mixer in mechanically stirred reactor, rotating speed 64rpm, pH are adjusted to 6.8, be dehydrated 49 minutes, standby；
4th step：1,5- diamino-anthraquinone -2- sulfonic acid that the character that 3rd step is obtained changes, 3,5- syringol and
Barium nanoparticle is well mixed, and is added in 61 parts of the 1- amino -4- bromo anthraquinone -2- sulfonic acid that mass concentration is 50.9ppm, cocurrent adds
Into the mechanically stirred reactor of the 1st step, flow acceleration 279.95mL/min；Start mechanically stirred reactor mixer, if
It is 58rpm to determine rotating speed；Stirring 6 minutes；Add bis- chloro- 4- of 2,5- [4- [[3- [(ethylphenyl amino) sulfonyl] -4- methyl
Phenyl] azo] -4,5- dihydro -3- methyl -5- oxygen -1H- pyrazol-1-yls] 44 parts of benzene sulfonic acid, start in mechanically stirred reactor
Double heating furnace, be warming up to 98.9 DEG C, pH is adjusted to 6.8, and it is 53.922m to be passed through xenon throughput3/ min, insulation stand 78
Minute；Mechanically stirred reactor mixer is again started up, rotating speed 63rpm, 52 parts of melissyl phosphate (salt) is added, makes it
The hydrophilic-lipophilic balance critical value of reaction solution is 7.749, and causes pH to be adjusted to 6.8, and insulation stands 77 minutes；
5th step：Start the mixer in mechanically stirred reactor, setting speed 60rpm, while stirring to mechanical agitation
53 parts of 2- ethyls -1,3- hexylene glycol is added in reactor, starts the Double heating furnace in mechanically stirred reactor, setting machinery stirs
It is 6.999 × 10 to mix the temperature in reactor2DEG C, after being incubated 87 minutes, 70 parts of 4- methyl tetrahydro phthalic anhydrides are added, halo is carried out and takes off
Carboxylation reaction 38 minutes；77 parts of Monododecylphosphate potassium is added afterwards, starts the dual-heated in mechanically stirred reactor
Stove, the temperature in mechanically stirred reactor is set as 138.9 DEG C, pH is adjusted to 5.8, pressure 0.4641MPa, and the reaction time is
0.5 hour；0MPa is depressurized to afterwards, is cooled to 56.4 DEG C and is discharged into molding press, that is, obtains grating floor 3-2.
The particle diameter of wherein described barium nanoparticle is 53.9 μm.
Reference examples:
Reference examples are the grating floor of certain commercially available brand.
Grating floor described in the grating floor 3-2 and reference examples that embodiment 1~3 is prepared carries out using effect pair
Than.The two thermal conductivity, high temperature resistant degree, high pressure resistant degree, corrosion resistant erosion degree are counted, as a result as shown in table 1.
As seen from Table 1, the described grating floor 3-2 prepared by the present invention, it is its thermal conductivity, high temperature resistant degree, high pressure resistant
The indexs such as degree, corrosion resistant erosion degree are superior to the product of prior art production.
In order to improve the injection pressure of flame, and the temperature of flame can be lifted, the quantity of the flame spray remolten port 3-9 is
20-30, flame spray remolten port 3-9 is made up of manganese steel, and it is in up-small and down-big frustum type, in order to realize the spray of flame
Penetrate.
In order to improve guiding effect vortex flame pilot fence 3-6 to the distance of tubaeform wind outlet section 3-5 upper ends be 20-
30mm, vortex flame pilot fence 3-6 are made of manganese steel.
Grating floor 3-2 is disc, diameter 50-60mm, the quantity of Turbogrid plates 20-30, lattice good grating floor 3-2
Screen can carry out angular adjustment, and wherein even number position Turbogrid plates can carry out horizontal displacement with reality relative to the Turbogrid plates of radix position
Now close.
The distance between riser 3-8 and flame rings 3-14 are 20-30mm.
Preferably, flame rings 3-14 and gas service pipe 3-10 are made of brass.
The course of work：Air enters from horizontal air channel 3-1, and pneumatic nested regulating valve 3-4 controls grating floor 3-2 to air
The angle of entrance, flow are adjusted；After imflammable gas methane is pressurized by Pneumatic booster pump 3-12, room is handed over into microwave is mixed
3-13, mixed by a certain percentage with indicative gaseous sulfur dioxide in mixed hand in the 3-13 of room of microwave；In the mixed friendship room 3-13 of microwave
Rotary valve 3-11 is adjusted provided with combustion gas, it controls sulfur dioxide, methane blended source of the gas to enter gas service pipe 3-10 flow, enters
And sprayed by flame spray remolten port 3-9；At the same time, High-voltage metallized pulse capacitor 3-3 produces high-voltage pulse spark, promotees
Make the imflammable gas burning sprayed from flame spray remolten port 3-9；Positioned at flame spray remolten port 3-9 tops be provided with riser 3-8,
Tubaeform air outlet 3-5, vortex flame pilot fence 3-6, it guides the direction of motion arranged outside tail gas；At the top of gas outlet
Security closure 3-7, by the regulation of opening angle, realize totally-enclosed to outlet tail gas, full open control.
Claims (9)
1. a kind of burning-point burner, including horizontal air channel (3-1), High-voltage metallized pulse capacitor (3-3), it is characterised in that
Also include pneumatic nested regulating valve (3-4), flame rings (3-14), riser (3-8) and vortex flame pilot fence (3-6)；
The left end of the horizontal air channel (3-1) is folded upward at forming elbow；The lower end of the pneumatic nested regulating valve (3-4) and institute
The upper end connection of elbow is stated, pneumatic junction of the nested regulating valve (3-4) between elbow is provided with grating floor (3-2), lattice
Grid bottom plate (3-2) is cell structure；The upper end connection combuster (3-15) of pneumatic nested regulating valve (3-4)；
The flame rings (3-14) are fixedly installed on combustion chamber (3-15) middle part, flame rings (3-14) by hollow tubular metal
Material is made, and its upper surface is circumferentially equably fixedly connected with multiple and its intracavity inter-connection flame spray remolten port (3-9)；Flame
Ring (3-14) is fixedly connected with one end of gas service pipe (3-10), and the intracavity inter-connection of the two；Gas service pipe (the 3-
10) the other end adjusts rotary valve (3-11) by combustion gas after passing combustion chamber (3-15) and microwave mixes the outlet of friendship room (3-13)
End connection；Mixed hand in room (3-13) of the microwave is provided with microwave oscillator；The mixed inlet end for handing over room (3-13) of microwave is connected with
Pneumatic booster pump (3-12)；
The High-voltage metallized pulse capacitor (3-3) is arranged on the combustion chamber (3-15) bottom and is located at flame rings (3-14)
Inner side, High-voltage metallized pulse capacitor (3-3) is made up of high voltage power supply and electric discharge device；
The riser (3-8) is fixedly installed on the surface of flame rings (3-14) and straight length and the loudspeaker on top with bottom
Shape wind outlet section (3-5)；
The vortex flame pilot fence (3-6) is fixedly installed on tubaeform wind outlet section (3-5) top, vortex flame pilot grid
Column (3-6) is cell structure；
Isolation type safety screen (3-7) is hingedly connected with the top of combustion chamber (3-15), isolation type safety screen (3-7) is
Cell structure.
2. a kind of burning-point burner according to claim 1, it is characterised in that the grating floor (3-2) is by with the following group
Divide proportioning composition in parts by weight：
249~474 parts of softened water, 41~83 parts of disodium alkyl polyoxyethylene sulfosuccinate, butanedioic acid (ethyl
Base) 44~153 parts of sodium sulfonate, 40~57 parts of N- butyl para toluene sulfonamide, N- ethyl-N- butyl -2,6- dinitros -4- three
43~100 parts of methyl fluoride aniline, 1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxos
46~107 parts of anthracene -2- sulfonate sodiums, 1,5- 43~66 parts of diamino-anthraquinone -2- sulfonic acid, 3,5- syringol 40~85
Part, 48~103 parts of barium nanoparticle, mass concentration is the 44.7ppm~274.2ppm bromo- 1- methylaminos anthraquinones 41~83 of 4-
Part, 2,5- bis- chloro- 4- [4- [[3- [(ethylphenyl amino) sulfonyl] -4- aminomethyl phenyls] azo] -4,5- dihydro -3- methyl -
5- oxygen -1H- pyrazol-1-yls] 31~74 parts of benzene sulfonic acid, 32~68 parts of melissyl phosphate (salt), (the 2- ethyl hexyls of N, N- bis-
Base) 43~83 parts of -1H- BTA -1- methylamines, 50~94 parts of 4- methyl tetrahydro phthalic anhydrides, mass concentration be 40.6ppm~
73~127 parts of 307.4ppm Monododecylphosphate potassium；Mass concentration is 40.2ppm~220.2ppm 1- amino -4-
50~75 parts of bromo anthraquinone -2- sulfonic acid；36~65 parts of 2- ethyl -1,3- hexylene glycols.
3. a kind of burning-point burner according to claim 2, it is characterised in that the particle diameter of the barium nanoparticle is 48.6
μm~58.9 μm.
4. a kind of burning-point burner according to claim 3, it is characterised in that the grating floor (3-2) is by following step
Suddenly it is prepared：
1st step：In mechanically stirred reactor, softened water and AEO sulfosuccinic acid monoesters disodium are added
Salt, start the mixer in mechanically stirred reactor, setting speed is 42rpm~88rpm, is started in mechanically stirred reactor
Double heating furnace, temperature is risen to 57.9 DEG C~58.1 DEG C, add butanedioic acid (ethylhexyl) sodium sulfonate and stir, carry out halogen
Reacted 34~45 minutes for decarboxylation, add N- butyl para toluene sulfonamides, it is 33.383m to be passed through flow3/ min~
74.180m3/ min xenon 0.4~0.1 hour；N- ethyl-N- butyl -2,6- two is added in mechanically stirred reactor afterwards
Nitro -4- 5-trifluoromethylanilines, the Double heating furnace being again started up in mechanically stirred reactor, make temperature rise to 74.9 DEG C~
107.1 DEG C, 34~45 minutes are incubated, adds 1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydros -9,10-
Dioxo anthracene -2- sulfonate sodiums, the pH value for adjusting solution in mechanically stirred reactor are 4.8~8.9, are incubated 34~274 minutes；
2nd step：Separately take barium nanoparticle, by barium nanoparticle power be 5.748KW~11.189KW under ultrasonication 0.4
~0.1 hour；Barium nanoparticle is added in another mechanically stirred reactor, addition mass concentration be 44.7ppm~
The 274.2ppm bromo- 1- methylaminos anthraquinones of 4- disperse barium nanoparticle, start the Double heating furnace in mechanically stirred reactor, make
Solution temperature starts the mixer in mechanically stirred reactor between 4.83 × 10 DEG C~8.91 × 10 DEG C, and with 4.89 ×
102Rpm~8.94 × 102Rpm speed stirring, adjustment pH value is between 4.8~8.9, insulated and stirred 0.5~1.1 hour；It
Stop reaction afterwards and stand 5.7 × 10~11.1 × 10 minutes, go the removal of impurity；Suspension is added into N, N- bis- (2- ethylhexyls)-
1H- BTA -1- methylamines, adjustment pH value form sediment softening water elution, existed by centrifuge between 1.3~2.1
Rotating speed 4.399 × 103Rpm~9.674 × 103Solid content is obtained under rpm, 2.226 × 102DEG C~3.45 × 102At a temperature of DEG C
Dry, 420~520 mesh sieves are crossed after grinding, it is standby；
3rd step：Another barium nanoparticle after taking 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- syringol and the processing of the 2nd step,
Irradiated after well mixed using 60Co external exposures, the energy of 60Co external exposures irradiation is 31.363MeV~59.126MeV, dosage
It is 43~68 minutes for 79.90kGy~119.270kGy, irradiation time, obtains 1, the 5- diamino-anthraquinone -2- sulphurs of character change
Acid, 3,5- syringol and barium nanoparticle mixture；By 1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- dimethoxy benzenes
Phenol and barium nanoparticle mixture are placed in another mechanically stirred reactor, start the dual-heated in mechanically stirred reactor
Stove, 42.5 DEG C~88.1 DEG C of design temperature, start the mixer in mechanically stirred reactor, rotating speed is 34rpm~429rpm, pH
It is adjusted between 4.8~8.9, is dehydrated 43~57 minutes, it is standby；
4th step：1,5- diamino-anthraquinone -2- sulfonic acid, 3,5- syringol and barium that the character that 3rd step obtains changes are received
Rice particulate is well mixed, and is added in the 1- amino -4- bromo anthraquinone -2- sulfonic acid that mass concentration is 40.2ppm~220.2ppm, cocurrent
Add in the mechanically stirred reactor of the 1st step, flow acceleration is 179.6mL/min~907.9mL/min；It is anti-to start mechanical agitation
Mechanical stirrer is answered, setting speed is 48rpm~88rpm；Stirring 4~8 minutes；Add 2,5- bis- chloro- 4- [4- [[3- [(ethyls
Phenyl amino) sulfonyl] -4- aminomethyl phenyls] azo] -4,5- dihydro -3- methyl -5- oxygen -1H- pyrazol-1-yls] benzene sulfonic acid, is opened
Double heating furnace in dynamic mechanically stirred reactor, is warming up to 78.1 DEG C~115.2 DEG C, and pH is adjusted between 4.8~8.9, leads to
It is 33.221m to enter xenon throughput3/ min~74.283m3/ min, insulation stand 68~98 minutes；It is anti-to be again started up mechanical agitation
Mechanical stirrer is answered, rotating speed is 43rpm~88rpm, adds melissyl phosphate (salt), makes the hydrophilic-lipophilic balance of its reaction solution
Critical value is 5.748~11.189, and pH is adjusted between 4.8~8.9, and insulation stands 67~107 minutes；
5th step：Start the mixer in mechanically stirred reactor, setting speed is 40rpm~107rpm, while stirring to machinery
2- ethyl -1,3- hexylene glycols are added in stirred reactor, start the Double heating furnace in mechanically stirred reactor, setting machinery stirs
It is 4.990 × 10 to mix the temperature in reactor2DEG C~9.811 × 102DEG C, after being incubated 67~107 minutes, add 4- methyl tetrahydrochysenes
Phthalic anhydride, halo decarboxylation are reacted 34~45 minutes；Monododecylphosphate potassium is added afterwards, is started in mechanically stirred reactor
Double heating furnace, set the temperature in mechanically stirred reactor as 118.9 DEG C~174.8 DEG C, pH adjust to 4.8~8.9 it
Between, pressure is 0.441MPa~0.479MPa, and the reaction time is 0.4~0.9 hour；0MPa is depressurized to afterwards, is cooled to 54.4
DEG C~59.4 DEG C discharge into molding press, that is, obtain grating floor (3-2).
A kind of 5. burning-point burner according to any one of Claims 1-4, it is characterised in that the flame spray remolten port
The quantity of (3-9) is 20-30, and flame spray remolten port (3-9) is made up of manganese steel, and it is in up-small and down-big frustum type.
6. a kind of burning-point burner according to claim 5, it is characterised in that vortex flame pilot fence (3-6) arrives loudspeaker
The distance of shape wind outlet section (3-5) upper end is 20-30mm, and vortex flame pilot fence (3-6) is made of manganese steel.
7. a kind of burning-point burner according to claim 6, it is characterised in that grating floor (3-2) is disc, diameter
50-60mm, the quantity of Turbogrid plates 20-30.
8. a kind of burning-point burner according to claim 7, it is characterised in that riser (3-8) and flame rings (3-14)
The distance between be 20-30mm.
9. a kind of burning-point burner according to claim 8, it is characterised in that flame rings (3-14) and gas service pipe
(3-10) is made of brass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710889668.XA CN107830520A (en) | 2017-09-27 | 2017-09-27 | A kind of burning-point burner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710889668.XA CN107830520A (en) | 2017-09-27 | 2017-09-27 | A kind of burning-point burner |
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| Publication Number | Publication Date |
|---|---|
| CN107830520A true CN107830520A (en) | 2018-03-23 |
Family
ID=61643620
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710889668.XA Pending CN107830520A (en) | 2017-09-27 | 2017-09-27 | A kind of burning-point burner |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108724481A (en) * | 2018-05-22 | 2018-11-02 | 徐州工程学院 | A kind of waste water deposit cutter device with agent mixer |
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Application publication date: 20180323 |