CN107805447A - The preparation method that a kind of wood furniture is painted with flame-proof antibiotic - Google Patents
The preparation method that a kind of wood furniture is painted with flame-proof antibiotic Download PDFInfo
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- CN107805447A CN107805447A CN201711007199.0A CN201711007199A CN107805447A CN 107805447 A CN107805447 A CN 107805447A CN 201711007199 A CN201711007199 A CN 201711007199A CN 107805447 A CN107805447 A CN 107805447A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses the preparation method that a kind of wood furniture is painted with flame-proof antibiotic, and by dispersiveness of the titanate coupling agent modified titanium dioxide carrying silver antimicrobials in alkyd paint, the homogeneous antibacterium paint of performance is prepared；Composite flame-retardant agent is prepared by fire retardant and the compound of mesoporous silicon oxide, so as to improve the fire resistance of paint；The preparation method of the present invention is simple, and the flame-proof antibiotic paint of preparation has preferable fire-retardant and anti-microbial property.
Description
Technical field
The invention belongs to the technical field of furniture paint, and in particular to the system that a kind of wood furniture is painted with flame-proof antibiotic
Preparation Method.
Background technology
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses mixes
Compound coating.Paint is decorating and protect the coating of article made of the raw materials such as iron oxide or resin.It is toughening oil
Property pigment, it is inflammable in the case of not dry, insoluble in fire, fat is slightly soluble in, dissolves in alcohol, aldehyde, ether, benzene, alkane, is soluble in gasoline, coal
Oil, diesel oil.
In place of the paint Shortcomings of existing market：Such as without flameproof effect, the loss such as cause to be difficult to make up running into fire etc.,
And paint making cost of material is higher, can not meet user's economic benefit.Becoming increasingly conspicuous with environmental protection problem simultaneously
And pursuit of the people to health environment, antibacterium paint as a kind of environment-friendly new function material, be social development and
The inevitable outcome of scientific and technological progress.
The content of the invention
It is even by titanate esters it is an object of the invention to provide the preparation method that a kind of wood furniture is painted with flame-proof antibiotic
Join dispersiveness of the agent modifying titanium dioxide carrying silver antimicrobials in alkyd paint, the homogeneous antibacterium paint of performance is prepared；It is logical
Cross fire retardant and composite flame-retardant agent is prepared in the compound of mesoporous silicon oxide, so as to improve the fire resistance of paint；The present invention
Preparation method it is simple, the flame-proof antibiotic of preparation paint has preferable fire-retardant and anti-microbial property.
The present invention is achieved through the following technical solutions：The preparation method that a kind of wood furniture is painted with flame-proof antibiotic,
Mainly include the following steps that：
Step A, using titanate coupling agent modified titanium dioxide carrying silver antimicrobials, modified antiseptic is prepared；
Step B, then flame-retardant direction and APP are added into vacuum drying meso-porous titanium dioxide according to certain mass than preparing solution
Silicon, composite flame-retardant agent is prepared；
Step C, the composite flame-retardant agent of the preparation in modification antiseptic and step B prepared by step A is mixed into alkyd paint,
Flame-proof antibiotic paint is prepared after high-speed stirred.
Organic siliconresin is using silicon oxygen bond as its molecular backbone, and Si-O keys are than C-C keys in common organic high molecular compound
Bond energy and polarity are bigger, can play shielding action to connected alkyl, can improve the oxidation stability of naval stores.And work as Si
After the alkyl connected on atom is oxidized, generation is more stable Si-O-Si keys, can prevent backbone breaking from degrading；Separately
Outside, the stabilized protection course rich in Si-O-Si chains of Organosilicon Polymers Surface Creation, can mitigate external environment to high polymer inside
Influence, organic siliconresin has excellent weatherability, water resistance, heat resistance and resistance to acids and bases.
Alkyd resin mainly using vegetable oil as raw material, have wide material sources, it is cheap, do not influenceed by oil price,
And it is easy to the advantages such as application, paint film be plentiful.But contain more hydroxyl and ester group in alkyd resin molecular structure so that its
There is clearly disadvantageous for film performance.Silicone alkyd refers to be copolymerized with organosilicon and alkyd resin, increases
The strong chemical stability of alkyd resin, and its weatherability, water resistance, heat resistance and resistance to acids and bases can be improved.
Titanium dioxide carrying silver antimicrobials have good antibiotic property, TiO2Series antibacterial agent has very high photocatalytic activity,
With acid and alkali-resistance and the advantages of low and nontoxic photochemical corrosion, cost；Ag series antibacterial agent bactericidal properties are extremely strong, consumed energy pole
Few, good endurance is difficult to assemble in human body, is referred to as permanent bactericide in chemistry；Therefore TiO is utilized2Series antibacterial agent
With the mutual supplement with each other's advantages of Ag series antibacterial agents, Novel Titanium dioxide carrying silver antimicrobials are developed.
Titanium dioxide carrying silver antimicrobials in use, Ag+TiO can be prevented2Compound, the promotion of middle electron-hole pair
The separation of electron-hole pair, expand TiO2Photocatalysis excitation wavelength, exciting light is expanded to visible-range, such antibacterial
Performance can be remarkably reinforced；Embedded TiO simultaneously2Ag in crystal defect+Can be realized in sterilization process slowly discharge and prevent by
Oxidation, so as to solve the nigrescence of antiseptic silver and sustained release sex chromosome mosaicism, ensure there are enough Ag in antiseptic+In the presence of reaching dual
The effect of sterilization.
WOOD FIRE RETARDANT FRW is a kind of New Phosphorus-nitrogen-boron-based flame retardant of east Forestry University development, its anti-corrosion, insect prevention
Excellent effect, and environmental protection, flame retarding efficiency height, can be applicable to the flame retardant treatment of the materials such as solid wood, wood-based plate.Fire retardant APP is low
Degree of polymerization APP, because having excellent water solubility and fire resistance, also it is widely used in fire-retarding of wood processing；It is situated between
Hole silica has high specific surface area and pore capacities, orderly pore passage structure and good heat endurance, meso-porous titanium dioxide
Silicon not only has absorption and loading functional, and can keep skeleton stable in combustion, plays a part of protecting layer of charcoal；
There are some researches show two kinds of ignition-proof elements of Si and P can show good flame retardant synergistic effect, P can promote the life of charcoal under hot conditions
Into, Si can increase the heat endurance of layer of charcoal, and this contributes to the protection layer of charcoal of flame-retardant system formation Si-O-C keys and Si-C keys, from
And produce more preferable flame retardant effect.
In order to preferably realize the present invention, further, in the step A first titanate coupling agent is added to organic molten
Stirred in agent, then add titanium dioxide carrying silver antimicrobials and be stirred, turned in 40-75 DEG C of temperature, 300-500r/min
Modified 2-4h under conditions of speed；Suction filtration, washing, modified antiseptic is prepared after drying.
In order to preferably realize the present invention, further, first by flame-retardant direction and APP according to mass ratio in the step B
3:1-4:1 adds in three-neck flask, adds deionized water and prepares solution, after being well mixed, adds vacuum drying mesoporous dioxy
SiClx powder, 2-4h is stirred at 55-70 DEG C, grinding obtains nano level complex antimicrobials in ball mill after vacuum drying.
In order to preferably realize the present invention, further, the model HC-114 of the titanate coupling agent.
In order to preferably realize the present invention, further, the silver carrying amount of the titanium dioxide carrying silver antimicrobials is more than
6.5wt%。
Beneficial effects of the present invention：
（1）The present invention uses dispersiveness of the titanate coupling agent modified titanium dioxide carrying silver antimicrobials in paint, the metatitanic acid
When ester coupling agent is HC-114, titanium dioxide carrying silver antimicrobials dispersion effect is optimal；
（2）The present invention uses mesoporous silicon oxide composite flame-retardant agent, and preparation method is simple, and combines the knot of mesoporous silicon oxide
Structure feature enhances the stability of fire retardant, improves the fire resistance of paint；
（3）The present invention uses titanium dioxide carrying silver antimicrobials, and the titanium dioxide produces antibacterial synergy, antibacterial effect with silver
Preferably；
（4）The present invention uses composite flame-retardant agent, with reference to the advantages of flame-retardant direction and APP, effectively reduces cost, improves fire-retardant effect
Fruit；The present invention has preferable stability, while generate fire-retardant association using mesoporous silicon oxide load flame-retardant direction and APP
Same-action, flame retardant effect is more preferably.
Embodiment
Embodiment 1：
A kind of wood furniture is painted with flame-proof antibiotic, and being calculated according to mass parts mainly includes 12 parts of silicone alkyds, 6
Part acrylonitrile, 3 organic epoxy resins, 20 parts of oil, 8 parts of composite flame-retardant agents, 4 parts of modified antiseptics；The modified antiseptic
For the titanium dioxide carrying silver antimicrobials of HC-114 titanate coupling agent modifieds；The composite flame-retardant agent is pressed by flame-retardant direction and APP
According to mass ratio 4:1 compounding composition；The flame-retardant direction and APP are with mesoporous silicon oxide according to mass ratio 0.7:1 compounding forms.
The preparation method that a kind of wood furniture is painted with flame-proof antibiotic, is mainly included the following steps that：
Step A, first titanate coupling agent HC-114 is added in organic solvent methanol and stirred, then adds titanium dioxide
Carrying silver antimicrobials are stirred, the modified 4h under conditions of 65 DEG C of temperature, 400r/min rotating speeds；Filter, wash, drying and make afterwards
It is standby to obtain being modified antiseptic；
Step B, first flame-retardant direction and APP are added in three-neck flask, add deionized water and prepare solution, after being well mixed, add
Enter vacuum drying mesoporous silicon dioxide powder, 4h is stirred at 70 DEG C, grinding obtains nanometer in ball mill after vacuum drying
The complex antimicrobials of level；
Step C, the composite flame-retardant agent of the preparation in modification antiseptic and step B prepared by step A is mixed into alkyd paint,
Flame-proof antibiotic paint is prepared after high-speed stirred.
Test the anti-microbial property of paint：By flame-proof antibiotic paint application on print, paint is detected with film adherence method
Anti-microbial property；In order to embody the spectrum antimicrobial properties of nano antibacterial paint, three kinds of representative Staphylococcus aureus are have selected
Bacterium, big field bacillus and Candida albicans；The bacterium solution of preparation is uniformly applied to the surface of print, covered with sterile plastic sheet
Print, it is then placed within 37 DEG C, cultivates 24h in the insulating box that relative humidity is 90%；Then with PBS by the bacterium solution on each print
Elution is got off, and by de- washing lotion inoculated and cultured 24h, is observed result and is calculated antibiotic rate.
Found after test, flame-proof antibiotic paint is after 24h 99.9% to the antibiotic rate of Escherichia coli, to golden yellow grape ball
The antibiotic rate of bacterium is 99.9%, and the antibiotic rate to Candida albicans is 99.7%；Antiseptic manufactured in the present embodiment has higher
Anti-microbial property.
The timber coated compared to the antibacterium paint for being not added with fire retardant, flame-proof antibiotic paint application manufactured in the present embodiment
The average HRR of timber have dropped 62%, illustrate composite flame-retardant agent addition effectively reduce timber thermal degradation generation can
The speed of combustion property volatility product, fire intensity reduce；Show that flame-proof antibiotic paint manufactured in the present embodiment has preferable fire-retardant effect
Fruit.
The present invention carries out surface modification using titanate coupling agent to titanium dioxide carrying silver antimicrobials, improves titanium dioxide
Dispersive property of the carrying silver antimicrobials in paint；Effectively prevent wood furniture from burning by adding composite flame-retardant agent in paint,
The composite flame-retardant agent shows good flame retardant synergistic effect；The resistance to bacterium for effectively improving paint by adding modified antiseptic kills
Bacterium performance, Ag+TiO can be expanded2Photocatalysis excitation wavelength, while embedded TiO2Ag in crystal defect+In sterilization process
It can realize and slowly discharge and prevent from being oxidized, reach the effect of double sterilization；Flame-proof antibiotic prepared by present invention paint can be with
Effectively reduce the occurrence index of wood furniture.
Embodiment 2：
A kind of wood furniture is painted with flame-proof antibiotic, and being calculated according to mass parts mainly includes 15 parts of silicone alkyds, 8
Part acrylonitrile, 3 organic epoxy resins, 25 parts of oil, 10.8 parts of composite flame-retardant agents, 4.5 parts of modified antiseptics；The modification resists
Microbial inoculum is the titanium dioxide carrying silver antimicrobials of HC-114 titanate coupling agent modifieds；The composite flame-retardant agent by flame-retardant direction with
APP is according to mass ratio 4:1 compounding composition；The flame-retardant direction and APP are with mesoporous silicon oxide according to mass ratio 0.8:1 compounding
Form.
The preparation method that a kind of wood furniture is painted with flame-proof antibiotic, is mainly included the following steps that：
Step A, first titanate coupling agent HC-114 is added in organic solvent methanol and stirred, then adds titanium dioxide
Carrying silver antimicrobials are stirred, the modified 2h under conditions of 55 DEG C of temperature, 300r/min rotating speeds；Filter, wash, drying and make afterwards
It is standby to obtain being modified antiseptic；
Step B, first flame-retardant direction and APP are added in three-neck flask, add deionized water to prepare solution, after being well mixed, added
Vacuum drying mesoporous silicon dioxide powder, 4h is stirred at 70 DEG C, grinding obtains nanoscale in ball mill after vacuum drying
Complex antimicrobials；
Step C, the composite flame-retardant agent of the preparation in modification antiseptic and step B prepared by step A is mixed into alkyd paint,
Flame-proof antibiotic paint is prepared after high-speed stirred.
Test the anti-microbial property of paint：By flame-proof antibiotic paint application on print, paint is detected with film adherence method
Anti-microbial property；In order to embody the spectrum antimicrobial properties of nano antibacterial paint, three kinds of representative Staphylococcus aureus are have selected
Bacterium, big field bacillus and Candida albicans；The bacterium solution of preparation is uniformly applied to the surface of print, covered with sterile plastic sheet
Print, it is then placed within 37 DEG C, cultivates 24h in the insulating box that relative humidity is 90%；Then with PBS by the bacterium solution on each print
Elution is got off, and by de- washing lotion inoculated and cultured 24h, is observed result and is calculated antibiotic rate.
Found after test, flame-proof antibiotic paint is after 24h 99.9% to the antibiotic rate of Escherichia coli, to golden yellow grape ball
The antibiotic rate of bacterium is 99.9%, and the antibiotic rate to Candida albicans is 99.9%；Antiseptic manufactured in the present embodiment has higher
Anti-microbial property.
The timber coated compared to the antibacterium paint for being not added with fire retardant, flame-proof antibiotic paint application manufactured in the present embodiment
The average HRR of timber have dropped 56.8%, illustrate that the addition of composite flame-retardant agent effectively reduces timber thermal degradation generation
The speed of flammable volatility product, fire intensity reduce；It is preferably fire-retardant to show that flame-proof antibiotic paint manufactured in the present embodiment has
Effect.
The present invention carries out surface modification using titanate coupling agent to titanium dioxide carrying silver antimicrobials, improves titanium dioxide
Dispersive property of the carrying silver antimicrobials in paint；Effectively prevent wood furniture from burning by adding composite flame-retardant agent in paint,
The composite flame-retardant agent shows good flame retardant synergistic effect；The resistance to bacterium for effectively improving paint by adding modified antiseptic kills
Bacterium performance, Ag+TiO can be expanded2Photocatalysis excitation wavelength, while embedded TiO2Ag in crystal defect+In sterilization process
It can realize and slowly discharge and prevent from being oxidized, reach the effect of double sterilization；Flame-proof antibiotic prepared by present invention paint can be with
Effectively reduce the occurrence index of wood furniture.
It is described above, be only presently preferred embodiments of the present invention, any formal limitation not done to the present invention, it is every according to
Any simply modification, the equivalent variations made according to the technical spirit of the present invention to above example, each fall within the protection of the present invention
Within the scope of.
Claims (5)
1. the preparation method that a kind of wood furniture is painted with flame-proof antibiotic, it is characterised in that mainly include the following steps that：
Step A, using titanate coupling agent modified titanium dioxide carrying silver antimicrobials, modified antiseptic is prepared；
Step B, then flame-retardant direction and APP are added into vacuum drying meso-porous titanium dioxide according to certain mass than preparing solution
Silicon, composite flame-retardant agent is prepared；
Step C, the composite flame-retardant agent of the preparation in modification antiseptic and step B prepared by step A is mixed into alkyd paint,
Flame-proof antibiotic paint is prepared after high-speed stirred.
2. the preparation method that a kind of wood furniture according to claim 1 is painted with flame-proof antibiotic, it is characterised in that described
First titanate coupling agent is added in organic solvent in step A and stirred, titanium dioxide carrying silver antimicrobials is then added and enters
Row stirring, the modified 2-4h under conditions of 40-75 DEG C of temperature, 300-500r/min rotating speeds；Filter, wash, drying preparation afterwards
Obtain being modified antiseptic.
3. the preparation method that a kind of wood furniture according to claim 1 is painted with flame-proof antibiotic, it is characterised in that described
First by flame-retardant direction and APP according to mass ratio 3 in step B:1-4:1 adds in three-neck flask, and it is molten to add deionized water preparation
Liquid, be well mixed after, add vacuum drying mesoporous silicon dioxide powder, 2-4h stirred at 55-70 DEG C, after vacuum drying
Grinding obtains nano level complex antimicrobials in ball mill.
4. the preparation method that a kind of wood furniture according to claim 1 is painted with flame-proof antibiotic, it is characterised in that described
The model HC-114 of titanate coupling agent.
5. the preparation method that a kind of wood furniture according to claim any one of 1-4 is painted with flame-proof antibiotic, its feature
It is, the silver carrying amount of the titanium dioxide carrying silver antimicrobials is more than 6.5wt%.
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| CN201711007199.0A CN107805447A (en) | 2017-10-25 | 2017-10-25 | The preparation method that a kind of wood furniture is painted with flame-proof antibiotic |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982431A (en) * | 2019-12-18 | 2020-04-10 | 广东鸿业家具制造有限公司 | Preparation method of odorless environment-friendly paint |
| CN112625566A (en) * | 2020-12-18 | 2021-04-09 | 合众（佛山）化工有限公司 | Tripolyindenone derivative modified alkyd resin water-based paint |
| CN113265186A (en) * | 2021-05-26 | 2021-08-17 | 深圳市华必达科技有限公司 | Flame-retardant molecular chain grafted mesoporous silica modified epoxy resin coating and preparation method thereof |
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