CN107793844A - A kind of water-based organic pigment mill base and preparation method thereof - Google Patents
A kind of water-based organic pigment mill base and preparation method thereof Download PDFInfo
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- CN107793844A CN107793844A CN201610804992.2A CN201610804992A CN107793844A CN 107793844 A CN107793844 A CN 107793844A CN 201610804992 A CN201610804992 A CN 201610804992A CN 107793844 A CN107793844 A CN 107793844A
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- Prior art keywords
- mill base
- weight
- organic pigment
- ether
- parts
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000012860 organic pigment Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title abstract description 7
- -1 alcohol ethers Chemical class 0.000 claims abstract description 46
- 239000003381 stabilizer Substances 0.000 claims abstract description 44
- 239000003973 paint Substances 0.000 claims abstract description 26
- 239000002270 dispersing agent Substances 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- 238000009835 boiling Methods 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 12
- 239000002562 thickening agent Substances 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 8
- 230000007613 environmental effect Effects 0.000 claims description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000013538 functional additive Substances 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 claims description 2
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 claims description 2
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 2
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 19
- 238000000576 coating method Methods 0.000 abstract description 19
- 238000003860 storage Methods 0.000 abstract description 9
- 238000009736 wetting Methods 0.000 abstract description 9
- 239000002585 base Substances 0.000 description 59
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 8
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 7
- 241000894007 species Species 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000004075 alteration Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000000645 desinfectant Substances 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 229940043237 diethanolamine Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 210000003811 finger Anatomy 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- WIFCKLPZYYALGY-UHFFFAOYSA-N 1h-pyrrole-2,3-dione Chemical compound O=C1NC=CC1=O WIFCKLPZYYALGY-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- RNFAKTRFMQEEQE-UHFFFAOYSA-N Tripropylene glycol butyl ether Chemical compound CCCCOC(CC)OC(C)COC(O)CC RNFAKTRFMQEEQE-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 210000005224 forefinger Anatomy 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960003511 macrogol Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000033458 reproduction Effects 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/003—Pigment pastes, e.g. for mixing in paints containing an organic pigment
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water-based organic pigment mill base and preparation method thereof, the mill base includes the organic pigment of 10.0 70 parts by weight, the alcohol ethers stabilizer of 0.1 4.0 parts by weight, the wetting agent of 1.0 8.0 parts by weight, the dispersant of 3.0 15.0 parts by weight, He Shui.The present invention with the addition of a certain amount of alcohol ethers stabilizer in aqueous color paste formula, be advantageous to organic pigment wetting and dispersing in water-based system, improve the tinting strength, tinting power of mill base, improve the storage stability of mill base, there is very excellent compatibility with water paint, be advantageous to the film forming of coating, improve the surface property of paint film.
Description
Technical field
The invention belongs to technical field of fine, in particular it relates to a kind of water-based organic pigment mill base and its
Preparation method, mill base of the present invention are the environment-friendly type mill base with high-compatibility.
Background technology
With the development of society and the enhancing of environmental consciousness, the trend of coating Water-borne modification increasingly strengthens, and color is more
Sample is also the demand of modern social development, and therefore, the use of aqueous color paste is more and more frequent.Aqueous color paste is used in coating
It is more more convenient than using toner toning in production process to be mixed colours, and has the advantage that：(1) environmental protection and economy：Toning process
In do not have dust, and a large amount of clouts will not be produced；(2) it is easy to operate：Aqueous color paste add in coating only need to mix it is several
Minute, without prolonged scattered or grinding；(3) rich in color, colour gamut is broader, several mill bases arbitrarily arrange in pairs or groups can tune
Allot different colors.
Aqueous color paste and water paint are all stable dispersions, if the two different stable dispersion systems are mixed
Together but poor compatibility, it will there are many adverse consequences, for example, the accuracy of toning and uniformity it is poor；Color is not after toning
Bright-coloured, saturation degree is low, and mill base addition is big, increases cost；Flocculate, lump in colored paint placement process, return thick, thickening；Apply
Occurs floating when work, it will be apparent that the bad paint film effect such as joint print；Weatherability, the water resistance of paint film reduce, easily
Fade, efflorescence.
Therefore, the compatibility of aqueous color paste and water paint is even more important.Influence compatibility of the mill base in emulsion paint
Factor is a lot, including the species of wetting dispersing agent and dosage, the surface treatment method of color stuffing, the species and dosage of thickener.
And the stability of aqueous color paste relies primarily on electrostatic repulsion and steric hindrance effect in system, when both effect disequilibriums
When, phenomena such as layering divides water, flocculation, precipitation will occurring in aqueous color paste during storage, have a strong impact on the use of mill base.
The dosage that generally use changes wetting dispersing agent solves the compatibility of mill base and coating, but this method has limitation,
And the dosage of wetting dispersing agent is more, cost is not only increased, but also the water resistance of paint film can be influenceed, influences making for coating
Use effect.
Therefore, there is an urgent need to develop the aqueous color paste and its system that a kind of compatibility is good, environmentally friendly, using effect is good for this area
Preparation Method.
The content of the invention
It is an object of the invention to provide a kind of good, environmentally friendly, using effect the is good water-based organic pigment mill base of compatibility, its
Preparation method and application.
First aspect present invention, there is provided a kind of good water-based organic pigment mill base of compatibility, the mill base include 10.0-70
Organic pigment (preferably 20-50 parts by weight, be more preferably 25-48 parts by weight), the alcohol ether of 0.1-4.0 parts by weight of parts by weight
Class stabilizer (preferably 0.5-3.5 parts by weight, be more preferably 1.0-3.0 parts by weight), the wetting agent of 1.0-8.0 parts by weight
(preferably 2.0-6.0 parts by weight, be more preferably 2.5-4.0 parts by weight), the dispersant of 3.0-15.0 parts by weight, He Shui.
In another preference, the alcohol ethers stabilizer boiling spread is 250-350 DEG C of (preferably 280-330
℃)。
≤ 5% (preferably≤2.5%, more in another preference, solubility of the alcohol ethers stabilizer in water is
Goodly≤2%).
In another preference, the alcohol ethers stabilizer weight average molecular weight range is 150-300g/mol.
In another preference, the alcohol ethers stabilizer is colourless, net taste, environmental protection.
In another preference, the alcohol ethers stabilizer is selected from the group：Dipropylene, propylene glycol monomethyl ether, dipropyl
Glycol methyl ether, polyglycol ether, butyl glycol ether, diethylene glycol dimethyl ether, diethylene glycol propyl ether, butyl, diethyl two
Alcohol hexyl ether, propylene glycol monomethyl ether, propylene glycol propyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, DPG fourth
Ether, tripropylene glycol methyl ether, tripropylene glycol butyl ether, ethylene glycol phenyl ether, propane diols phenylate or its combination.
In another preference, the organic pigment is selected from the group：Azo, phthalocyanines, Anthraquinones, quinacridine ketone pyrrole
Simultaneously pyrrole-dione or its combination are coughed up, preferably selected from phthalocyanines, azo, quinacridine ketone or its combination, is more preferably selected
From phthalocyanine blue, phthalocyanine green, You Jihong, organic yellow or its combination.
In another preference, the weight ratio of the stabilizer and the organic pigment is 1.8%-10%, preferably
5%-10%, it is more preferably 6%-9.5%.
In another preference, the wetting agent is selected from the group：Aliphatic acid polyethenoxy ether phosphate, fatty alcohol polyoxy second
Alkene ether phosphate, alkyl polyoxyethylene ether or its combination.
In another preference, the dispersant is selected from the group：Polyester modification acrylic acid, acrylic resin, fragrant adoption
Oxygen vinethene, high molecular weight block copolymer or its combination.
In another preference, the molecular weight ranges of the high molecular weight block copolymer are 5000-20000.
In another preference, the mill base also includes the filler of 5.0-25.0 parts by weight.
In another preference, the filler is selected from the group：Talcum powder, kaolin or its combination.
In another preference, the mesh number of the filler (is preferably 3000-4000 mesh, more preferably for 3000-5000 mesh
For 4000-5000 mesh).
In another preference, the oil absorption of the filler is 20.0-50.0g/100g (preferably 20.0-40.0g/
100g, it is more preferably 40.0-50.0g/100g).
In another preference, for 6.0-10.0, (preferably 8.0-10.0, is more preferably 6.0- to the pH of the filler
8.0)。
In another preference, the mill base also includes the NMF of 8.0-15.0 parts by weight.
In another preference, the NMF is relative molecular weight in 200-600 polyethylene glycol, preferably poly- second
Glycol 300, polyethylene glycol 400 or its combination.
In another preference, the mill base also includes the functional additive of 2.0-6.0 parts by weight.
In another preference, the functional additive is selected from the group：Antimildew disinfectant, pH value regulator, defoamer or
It is combined.
In another preference, the antimildew disinfectant is selected from the group：1,2- benzisothiazole-3-ketones, 2- methyl -4-
Isothiazoline -3- ketone, sodium benzoate or its combination.
In another preference, the pH value regulator is selected from the group：Potassium hydroxide, sodium hydroxide, ammoniacal liquor, an ethanol
Amine, diethanol amine, triethanolamine or its combination.
In another preference, the defoamer is selected from the group：Organic silicon, mineral oils or its combination, preferably
Organic silicon.
In another preference, the defoamer is selected from the group：ADEKA NATE B-199, SN-DEFOAMER 326 or
It is combined.
In another preference, the mill base also includes the thickener of 0.5-3.0 parts by weight.
In another preference, the thickener is selected from the group：Hydrophobically-modified alkali swelling class, hydrophobically modified polyurethane class,
Cellulose family or its combination (preferably hydrophobically-modified alkali swelling class, hydrophobically modified polyurethane class or its combination).
In another preference, the thickener is selected from the group：ACRYSOL TT-935 (being purchased from ROHM AND HAAS),
ACRYSOL RM-8W or its combination.
In another preference, the mill base is free of or is substantially free of formaldehyde, it is preferred that contained content of formaldehyde≤10ppm,
More preferably≤5ppm, most preferably≤2ppm.
In another preference, the mill base is free of or is substantially free of VOC (it is preferred that contained VOC content≤10g/L, more
Goodly≤5g/L, most preferably≤2g/L).
In another preference, the mill base is free of or is substantially free of APEO.
Second aspect of the present invention, there is provided a kind of material combination for being used to form mill base as described in the first aspect of the invention, institute
Stating material combination includes the organic pigment of 10.0-50.0 parts by weight, the alcohol ethers stabilizer of 0.5-4.0 parts by weight, 2.0-6.0 weights
Measure the wetting agent, the dispersant of 3.0-15.0 parts by weight of part.
In another preference, the material combination is free of or is substantially free of VOC, it is preferred that contained VOC content≤10g/
L, more preferably≤5g/L, most preferably≤2g/L.
In another preference, the alcohol ethers stabilizer boiling spread is 250-350 DEG C, preferably 280-330 DEG C.
≤ 5% (preferably≤2.5%, more in another preference, solubility of the alcohol ethers stabilizer in water is
Goodly≤2%).
In another preference, the weight average molecular weight range of the alcohol ethers stabilizer is 150-300g/mol.
Third aspect present invention, there is provided a kind of method for preparing mill base as described in the first aspect of the invention, including step：
(1) water, alcohol ethers stabilizer, wetting agent, dispersant, NMF are added in dispersion cylinder, with 500-800r/min
Rotating speed disperses 15-20min, obtains mixed liquor I；
(2) mixed liquor I is mixed with organic pigment, filler, stirred under 300-400r/min, obtain mixed liquor I I；
(3) mixed liquor I I is mixed with thickener, defoamer, the mill base is made.
In another preference, also include step (3-1) before the step (3)：
(3-1) disperses mixed liquor I I 20min-2h (preferably 30min- under 800-1000r/min rotating speed
1.5h), mixtures III is formed；
(3-2) milled mixtures III, obtains composition IV.
In another preference, in the step (3-2), the abrasive media is zirconium oxide bead, ceramic bead or its group
Close.
In another preference, in the step (3-2), a diameter of 0.4-0.8mm of abrasive media.
In another preference, in the step (3-2), the milling time is 20min-2h (preferably 30min-
1.5h)。
Fourth aspect present invention, there is provided a kind of product, the product include：
(1) mill base as described in the first aspect of the invention；With
(2) emulsion paint.
In another preference, the emulsion paint is selected from the group：Pure Class C emulsion paint, EVA class emulsion paints, styrene acrylic latex
Paint, vinegar Class C emulsion paint, polyurethane acroleic acid class emulsion paint, silicon Class C emulsion paint or its combination.
It should be understood that within the scope of the present invention, above-mentioned each technical characteristic of the invention and have in below (eg embodiment)
It can be combined with each other between each technical characteristic of body description, so as to form new or preferable technical scheme.As space is limited, exist
This no longer tires out one by one states.
Embodiment
The present inventor and in-depth study, is surprised to find that a kind of environment-friendly type mill base of high-compatibility first by extensive,
The aqueous color paste of the present invention uses specific alcohol ethers stabilizer, high with the paint compatibility of various emulsion types, stable storing
Property it is good, moisture retention is high, and meets the requirement of environmental protection well, is substantially free of VOC, APEO and formaldehyde, resists dry and hard property good, very
It is adapted to colour mixer to use.The present invention is completed on this basis.
Term explanation
Unless otherwise defined, otherwise whole technologies used herein are respectively provided with such as art of the present invention with scientific terminology
The identical meanings that are generally understood that of those of ordinary skill.
As used herein, in use, term " about " means that the value can be from enumerating in the numerical value specifically enumerated is mentioned
Value, which changes, is not more than 1%.For example, as used herein, statement " about 100 " include 99 and 101 and between whole values (for example,
99.1st, 99.2,99.3,99.4 etc.).
As used herein, term " containing " or " including (including) " can be open, semi-enclosed and enclosed.Change
Yan Zhi, the term also include " substantially by ... form " or " by ... form ".
Water-based organic pigment mill base
Water-based organic pigment mill base of the present invention include organic pigment, alcohol ethers stabilizer, wetting agent, dispersant and
Water.
Alcohol ethers stabilizer
Alcohol ethers stabilizer of the present invention has the one or more features being selected from the group：
(1) environmentally friendly, net taste；
(2) there is excellent hydrophobic structure, be dissolved on a small quantity water (solubility≤5% in water, preferably≤2.5%,
More preferably≤2%)；
(3) boiling spread is 250-350 DEG C (preferably 280-330 DEG C)；And/or
(4) weight average molecular weight range is 150-300g/mol.
The special hydrophobic structure of alcohol ethers stabilizer of the invention and water-soluble make it be easier to absorption in organic pigment
Surface, contribute to organic pigment wetting and dispersing in water, improve the tinting strength, tinting power of organic pigment mill base, improve the storage of mill base
Stability；Meanwhile, it is capable to adjust the hydrophile-lipophile balance between mill base and coating, improve the compatibility of mill base and coating, and not
The water resistance of paint film can be influenceed.Compared to the alcohol ethers stabilizer of low boiling (for example, boiling point is less than 250 DEG C of ＜), higher boiling
Alcohol ethers stabilizer make it that mill base is free of or be substantially free of VOC in product, meets the requirement of environment-friendly type aqueous color paste.
Functional aid
Functional aid of the present invention includes antimildew disinfectant, pH value regulator, defoamer etc..
In particular cases, the growth of mould occurs in aqueous color paste, or occurs distributing evil caused by a large amount of bacterial reproductions
Phenomena such as smelly, phosphate dispersing aid is degraded, appropriate antimildew disinfectant can prevent the generation of this kind of phenomenon.
Antimildew disinfectant used in the present invention can be the bactericide without formaldehyde generally in the art, include but is not limited to
1,2- benzisothiazole-3-ketones, MIT, sodium benzoate etc..
PH value regulator used in the present invention is the industrially conventional material that pH value can be adjusted in water-based system, including
But it is not limited to potassium hydroxide, sodium hydroxide, ammoniacal liquor, monoethanolamine, diethanol amine, triethanolamine etc..
The organic silicon defoamer with hydrophobic units may be selected in the defoamer of the present invention, can not only eliminate mill base in life
Foam during production, additionally it is possible to ensure that mill base does not produce bubble during storage and use, there is certain suds effect,
It is especially suitable for preparing colour mixer mill base.
The thickener of the present invention is swelled class, hydrophobically modified polyurethane class, cellulose family or its combination for hydrophobically-modified alkali.
Thickener can ensure that mill base can have good viscosity, can successfully be added so as to ensure that mill base is placed in colour mixer, storage
Do not precipitated regardless of water during depositing.
NMF
NMF is favorably improved the anti-dry and hard property of aqueous color paste, ensures when prepared mill base uses in colour mixer not
Block the nozzle of colour mixer.
NMF of the present invention be relative molecular weight 200-600 polyethylene glycol, preferably Liquid Macrogol,
Polyethylene glycol 400 or its combination.
VOC (VOC)
As used herein, the VOC content refers to, under 101.3kPa normal pressures, any initial boiling point is less than or equal to
250 DEG C of organic compound.
Main advantages of the present invention are：
(1) water-based organic pigment mill base and water paint compatibility made of various types of emulsions of the invention are good, storage
Stability height, and environmental protection are deposited, is substantially free of VOC, APEO and formaldehyde, resists dry and hard property good, is especially suitable for colour mixer use.
(2) alcohol ethers stabilizer (the especially high boiling alcohol ether of small-molecular-weight is added in paste formula of the invention
Class stabilizer), it has excellent hydrophobic structure, minimal amount of to be dissolved in the water, this special hydrophobic structure and water dissolving
Property it is easier to absorption on the surface of organic pigment, contribute to organic pigment wetting and dispersing in water, improve color
The tinting strength, tinting power of slurry, improve the storage stability of mill base；On the other hand the hydrophilic and oleophilic that can be adjusted between mill base and coating is put down
Weighing apparatus, improve the compatibility of mill base and coating.
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.The experimental method of unreceipted actual conditions in the following example, generally according to conventional strip
Part, or according to the condition proposed by manufacturer.Unless otherwise indicated, otherwise percentage and number are percentage by weight and weight
Number.
Experiment material and reagent used can obtain from commercially available channel unless otherwise instructed in following examples.
Method of testing
1. viscosity：According to GB/T 9269-2009, the i.e. measure of dope viscosity, stormer viscosity meter method measure building coating
Viscosity.In the present invention, at 25 DEG C of test temperature, measure prepare 1 day after organic pigment compositions viscosity, and it is 25
At DEG C it is closed place 90 days after viscosity.
2. stability：Visual observations.At 25 DEG C it is closed place 90 days after, see whether that obvious granules of pigments occur sinks
Shallow lake, flocculation etc. have a strong impact on the situation of stability.
3. tinting strength, tinting power：Relative color strength is tested according to HG/T 3951-2007 Appendix B.
4. compatibility：According to referring to, to grind the experiment test organic pigment aqueous color paste compatible from the coating of different emulsion types
Property.A certain amount of mill base is added in coating, after mixing, takes appropriate colored paint to be placed in art post paperboard and is coated with 150 μm of wet film
Device be film-made, treat when paint film is half-dried with forefinger finger pulp on paint film it is same place grinding 20 circle, be careful not to it is firmly excessive,
Prevent that paint film is show-through, be then placed in inside 50 DEG C of baking oven and dry 10min, cooling.
Observation, which refers to, grinds the color distinction that part grinds part with not referring to：
(1) if color distinction is bigger, show that the compatibility of mill base and coating is poorer；
(2) part is ground without obvious color distinction with not referring to if referring to and grinding part, show that the compatibility of mill base and coating is good.
5. content of formaldehyde is tested：
GB18582-2008：Content of formaldehyde method of testing, i.e.,《Harmful substance limits in indoor decorating and refurnishing materials interior wall coating
Amount》.
6.VOC content measurings：
GB18582-2008：VOC content method of testing, i.e.,《Harmful substance limits in indoor decorating and refurnishing materials interior wall coating
Amount》.Also button water law estimation VOC content can be used：
Raw material used in embodiment is as follows.
1. polyethylene glycol
It is purchased from：Clariant chemical industry (China) Co., Ltd
Species：PEG 300, PEG 400
2. wetting agent
It is purchased from：Clariant chemical industry (China) Co., Ltd
Species：Alkyl polyoxyethylene ether class
3. dispersant
It is purchased from：Clariant chemical industry (China) Co., Ltd
Species：Aromatic series polyethenoxy ether class, high molecular weight block copolymer (carry pigment affinity groups)
4. alcohol ethers stabilizer
It is purchased from：Graceful international chemical industry (Beijing) Co., Ltd of Hensel
Composition：Alcohol ethers (solubility is about 2% in water, 250 DEG C of boiling point ＞)
5. organic silicon defoamer
It is purchased from：Asahi Denka Co., Ltd., Sheng Nuopuke (Shanghai) Co., Ltd.
Composition：Organosiloxane class
Species：ADEKA NATE B-199、SN-DEFOAMER 326
6. triethanolamine
It is purchased from：ROHM AND HAAS international trade (Shanghai) Co., Ltd.
7. kaolin
It is purchased from：Datong District's coal industry gold space kaolin
8. talcum powder
It is purchased from：The factory of Haicheng City stone flour two
9. thickener
It is purchased from：ROHM AND HAAS international trade (Shanghai) Co., Ltd.
Species：ACRYSOL TT-935、ACRYSOL RM-8W
Embodiment 1-8
(1) 10% deionized water is reserved, by 90% deionized water, wetting agent, dispersant, alcohol ethers stabilizer and guarantor
The all materials in addition to organic pigment, kaolin, talcum powder, thickener such as humectant PEG300 or PEG400 are sequentially added into point
Dissipate in cylinder, 15-20min is disperseed with 500-800r/min rotating speeds, obtains mixed liquor 1；
(2) rotating speed is transferred to 300~400r/min, organic pigment and filler is added in mixed liquor 1, are sufficiently stirred
To organic pigment compositions mixed liquor 2；
(3) organic pigment compositions mixed liquor 2 is carried out to scattered at a high speed be not less than under 800-1000r/min rotating speed
20min, and 10% deionized water reserved in step (1) is added in dispersion process, obtain being pre-mixed organic pigment compositions
3；
(4) organic pigment compositions of premixing are subjected to horizontal grinding, abrasive media be 0.4-0.8mm zirconium oxide beads or
Ceramic bead, continuously grinding 30min, obtain color compositions 4；
(5) color compositions 4 are weighed, then proportionally adds thickener and the water of surplus etc. and carry out viscosity tune
Whole, deaeration, finally give the good water-based organic pigment mill base of compatibility.
Each component content table (g) in the embodiment 1-8 of table 1
Comparative example 1-8
With embodiment 1-8, difference is：Alcohol ethers stabilizer is not added.
Each component content table (g) in the comparative example 1-8 of table 2.
The water-based organic pigment mill base performance prepared respectively according to preceding method testing example 1-8 and comparative example 1-8：
Table 3 and table 4 are respectively the test result of water-based organic pigment mill base prepared by embodiment 1-8 and comparative example 1-8.
Water-based organic pigment mill base the performance test results prepared by the embodiment 1-8 of table 3.
Remarks：Finger grind 5 points it is best, 1 point is worst, 5 points without obvious aberration, 4 points of slight color differences, 3 points of slightly obvious aberration, 2 points
Obvious aberration, 1 color separation difference are larger.
Water-based organic pigment mill base the performance test results prepared by the comparative example 1-8 of table 4.
Remarks：Finger grind 5 points it is best, 1 point is worst, 5 points without obvious aberration, 4 points of slight color differences, 3 points of slightly obvious aberration, 2 points
Obvious aberration, 1 color separation difference are larger.Tinting strength, tinting power (%) in table 4 is on the basis of corresponding embodiment.
It can be drawn by embodiment 1-8 and comparative example 1-8 test result, alcohol ethers stabilizer of the invention contributes to
Wetting and dispersing of the machine pigment in water, the tinting strength, tinting power of organic pigment mill base is improved, improve the storage stability of mill base；Together
When, the hydrophile-lipophile balance between mill base and coating can be adjusted, improves the compatibility of mill base and coating, and does not interfere with paint film
Water resistance.
Comparative example 9-10
With embodiment 2, difference is：Add different types of stabilizer.Comparative example 9 employs alcohol lipid stabilizer
(alcohol ester -12, not soluble in water, 250 DEG C of boiling point ＜, about 247 DEG C), comparative example 10 employs ether lipid stabilizer (diethylene glycol fourth
Ether alcohol acid esters, is slightly soluble in water, 250 DEG C of boiling point ＜, about 246.4 DEG C).
The testing partial performances result of water-based organic pigment mill base prepared by comparative example 9-10 is as shown in table 5.
Water-based organic pigment mill base the performance test results prepared by the embodiment 2 of table 5. and comparative example 9-10
As can be seen from Table 5, prepared using other kinds of stabilizer (for example, alkoxide, ether lipid etc., non-ether alcohol class)
Color paste viscosity significantly improve, tinting strength, tinting power reduce, illustrate that its wetting and dispersing effect is poorer than alcohol ethers stabilizer, and prepare mill base
VOC content it is very high.
Compared to stabilizer used in above-mentioned comparative example 9-10, it is unsuitable to apply in the formula of environment-friendly type aqueous color paste.
Using the ether alcohol class stabilizer (in particular, boiling point is higher than 250 DEG C) of the present invention, contribute to organic pigment wetting and dispersing in water,
The tinting strength, tinting power of organic pigment mill base is improved, improves the storage stability of mill base, the mill base environment protection health of preparation.
All it is incorporated as referring in this application in all documents that the present invention refers to, it is independent just as each document
It is incorporated as with reference to such.In addition, it is to be understood that after the above-mentioned instruction content of the present invention has been read, those skilled in the art can
To be made various changes or modifications to the present invention, these equivalent form of values equally fall within the model that the application appended claims are limited
Enclose.
Claims (10)
1. the good water-based organic pigment mill base of a kind of compatibility, it is characterised in that the mill base includes having for 10.0-70 parts by weight
Machine pigment, the alcohol ethers stabilizer of 0.1-4.0 parts by weight, the wetting agent of 1.0-8.0 parts by weight, 3.0-15.0 parts by weight it is scattered
Agent and water.
2. organic pigment mill base as claimed in claim 1, it is characterised in that the alcohol ethers stabilizer has what is be selected from the group
One or more features：
(1) the alcohol ethers stabilizer boiling spread is 250-350 DEG C；And/or
(2) solubility of the alcohol ethers stabilizer in water is≤5%；And/or
(3) the alcohol ethers stabilizer weight average molecular weight range is 150-300g/mol；And/or
(4) the alcohol ethers stabilizer is colourless, net taste, environmental protection；And/or
(5) the alcohol ethers stabilizer is selected from the group：Dipropylene, propylene glycol monomethyl ether, dipropylene glycol methyl ether, polyethylene glycol
Ether, butyl glycol ether, diethylene glycol dimethyl ether, diethylene glycol propyl ether, butyl, diethylene glycol hexyl ether, propylene glycol monomethyl ether,
Propylene glycol propyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, dipropylene, tripropylene glycol methyl ether, three
Propandiol butyl ether, ethylene glycol phenyl ether, propane diols phenylate or its combination.
3. organic pigment mill base as claimed in claim 1, it is characterised in that the alcohol ethers stabilizer and the organic pigment
Weight ratio be 1.8%-10%.
4. organic pigment mill base as claimed in claim 1, it is characterised in that the wetting agent is selected from the group：Aliphatic acid polyoxy
Ethene ether phosphate, aliphatic alcohol polyoxyvinethene phosphate, alkyl polyoxyethylene ether or its combination.
5. organic pigment mill base as claimed in claim 1, it is characterised in that the dispersant is selected from the group：Polyester modification third
Olefin(e) acid, acrylic resin, aromatic series APEO, high molecular weight block copolymer or its combination.
6. organic pigment mill base as claimed in claim 1, it is characterised in that the mill base has one or more be selected from the group
Individual feature：
(1) mill base also includes the filler of 5.0-25.0 parts by weight；And/or
(2) mill base also includes the NMF of 8.0-15.0 parts by weight；And/or
(3) mill base also includes the functional additive of 2.0-6.0 parts by weight；And/or
(4) mill base also includes the thickener of 0.5-3.0 parts by weight.
7. organic pigment mill base as claimed in claim 1, it is characterised in that the mill base has one or more be selected from the group
Individual feature：
(1) mill base is free of or is substantially free of VOC；And/or
(2) mill base is free of or is substantially free of formaldehyde；And/or
(3) mill base is free of or is substantially free of APEO.
8. a kind of material combination for being used to form mill base as claimed in claim 1, it is characterised in that the material combination includes
The organic pigment of 10.0-50.0 parts by weight, the alcohol ethers stabilizer of 0.5-4.0 parts by weight, 2.0-6.0 parts by weight wetting agent,
3.0-15.0 the dispersant of parts by weight.
9. a kind of method for preparing mill base as claimed in claim 1, including step：
(1) water, alcohol ethers stabilizer, wetting agent, dispersant, NMF are added in dispersion cylinder, with 500-800r/min rotating speeds
Scattered 15-20min, obtains mixed liquor I；
(2) mixed liquor I is mixed with organic pigment, filler, stirred under 300-400r/min, obtain mixed liquor I I；
(3) mixed liquor I I is mixed with thickener, defoamer, the mill base is made.
10. a kind of product, it is characterised in that the product includes：
(1) mill base as claimed in claim 1；With
(2) emulsion paint.
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| CN111100506A (en) * | 2018-10-25 | 2020-05-05 | 立邦涂料（中国）有限公司 | Mildew-proof environment-friendly water-based color paste suitable for color mixing of automatic color mixer and preparation method thereof |
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| CN115216183B (en) * | 2022-08-25 | 2023-11-07 | 杭州映山花颜料化工有限公司 | Storage-stable organic yellow pigment and preparation method thereof |
| CN117866469A (en) * | 2023-12-29 | 2024-04-12 | 广州市美帮祈富文仪有限公司 | Environment-friendly easy-to-clean pigment for children painting and preparation method thereof |
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Application publication date: 20180313 |