CN107760117A - A kind of BOPET dumb lights antistatic film - Google Patents
A kind of BOPET dumb lights antistatic film Download PDFInfo
- Publication number
- CN107760117A CN107760117A CN201711146895.XA CN201711146895A CN107760117A CN 107760117 A CN107760117 A CN 107760117A CN 201711146895 A CN201711146895 A CN 201711146895A CN 107760117 A CN107760117 A CN 107760117A
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- CN
- China
- Prior art keywords
- parts
- bopet
- antistatic
- polyester
- antistatic film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of BOPET dumb lights antistatic film, including polyester base material and the functional layer that is laminated on the side surface of polyester base material one, functional layer are compounded by following raw material and formed：10 25 parts of vinyl chloride-vinyl acetate resin, 10 20 parts of polyurethane resin, 7 12 parts of polyester elastomer, 0.5 1 parts of antioxidant, 0.1 0.7 parts of Tissuemat E, 0.3 1 parts of levelling agent, 0.3 0.8 parts of antistatic additive, 10 13 parts of butyl acetate, 58 parts of isobutyl acetate, antistatic additive is copolymerized with DTAC by unsaturated aliphatic polyester and formed, and the mass ratio of unsaturated aliphatic polyester and DTAC is 50 70:50‑30.BOPET dumb lights antistatic film provided by the invention can keep anlistatig characteristic for a long time, and its antistatic effect is good, resistivity≤3.5 × 10 of its polyester film surface9Ohm, meanwhile, BOPET dumb lights antistatic film provided by the invention has the very high transparency, can meet actual use demand.
Description
Technical field
The present invention relates to a kind of membrane material, more particularly to a kind of BOPET dumb lights antistatic film.
Background technology
With the development of the fashions trend such as in the market packages printing, ornament materials, label, dumb light polyester film is this to be had
The specialty polyesters film requirements of texture and soft view effect are increasing year by year, and in rapid growth.Dumb light polyester film master
Apply in thermal transfer film, gilding film, scald cloth, leather, transfer paper, dalle section bar, the products such as color printing packaging, label of aluminizing
On.Dumb light polyester film from the upper size according to glossiness of classification, be generally divided into low and hoarse degree, in mute degree, the mute degree three major types of height.Mesh
Preceding in the market common are low and hoarse degree, in mute degree dumb light polyester film, but lack (the high mute degree film definition of high mute degree product：
Mist degree is more than 95%, 17%) glossiness is less than.
High mute degree Matte film can be applied in cosmetics of super quality packaging, Top Grade Decorative Plank section bar, transfer lining paper of cigarette case
Scald on the transfer product such as leather cloth, these expensive goods generally can all require very low glossiness to patterned surfaces, even
It is matt.
The problem of antistatic property difference generally be present in the Matte film of conventional design.
The content of the invention
For above mentioned problem existing for existing Matte film, a kind of excellent BOPET dumb lights of ageing resistace are now provided and resisted
Electrostatic film.
Concrete technical scheme is as follows：
A kind of BOPET dumb lights antistatic film, has the feature that, including polyester base material and is laminated in polyester base material side
Functional layer on surface, functional layer are compounded by following raw material and formed：Vinyl chloride-vinyl acetate resin 10-25 parts, polyurethane resin 10-20
Part, polyester elastomer 7-12 parts, antioxidant 0.5-1 parts, Tissuemat E 0.1-0.7 parts, levelling agent 0.3-1 parts, antistatic additive
0.3-0.8 parts, butyl acetate 10-13 parts, isobutyl acetate 5-8 parts, antistatic additive is by unsaturated aliphatic polyester and dodecane
Base trimethyl ammonium chloride is copolymerized to be formed, and the mass ratio of unsaturated aliphatic polyester and DTAC is 50-70:
50-30。
Above-mentioned BOPET dumb light antistatic films, also have the feature that, vinyl chloride-vinyl acetate resin is selected from CP450 or CP750 chlorine vinegar
One kind in resin.
Above-mentioned BOPET dumb light antistatic films, also have the feature that, polyurethane resin gathers selected from PM100 or M20S
One kind in urethane resin.
Above-mentioned BOPET dumb light antistatic films, also have the feature that, polyester elastomer is selected from T1180P or T1185P
One kind in elastomer.
Above-mentioned BOPET dumb light antistatic films, also have the feature that, antioxidant resists selected from phosphite ester, 1010
One kind in oxidant or 1076 antioxidants.
Above-mentioned BOPET dumb light antistatic films, also have the feature that, levelling agent is 440 levelling agents.
The beneficial effect of such scheme is：
BOPET dumb lights antistatic film provided by the invention can keep anlistatig characteristic for a long time, and its is antistatic
Effect is good, resistivity≤3.5 × 10 of its polyester film surface9Ohm, meanwhile, BOPET dumb lights provided by the invention are antistatic
Film has the very high transparency, can meet actual use demand.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below in conjunction with the embodiment of the present invention,
Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained on the premise of creative work is not made,
Belong to the scope of protection of the invention.
It should be noted that in the case where not conflicting, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
With reference to specific embodiment, the invention will be further described, but not as limiting to the invention.
Embodiment 1
A kind of BOPET dumb lights antistatic film, including base material and the functional layer that is laminated on the side surface of base material one, functional layer by
Following raw material compounds to be formed：15 parts of CP750 types vinyl chloride-vinyl acetate resin, 11 parts of M20S type polyurethane resins, T1185P type polyester
It is 8.5 parts of elastomer, 0.6 part of phosphite-based antioxidant, 0.2 part of 440 type Tissuemat E, 0.45 part of 440 type levelling agent, anti-quiet
Electric 0.5 part of agent, 10.7 parts of butyl acetate, 6 parts of isobutyl acetate, antistatic additive is by unsaturated aliphatic polyester and dodecyl three
Ammonio methacrylate is copolymerized to be formed, and the mass ratio of unsaturated aliphatic polyester and DTAC is 50:50.
Embodiment 2
A kind of BOPET dumb lights antistatic film, including base material and the functional layer that is laminated on the side surface of base material one, functional layer by
Following raw material compounds to be formed：13 parts of CP450 types vinyl chloride-vinyl acetate resin, 15 parts of M20S type polyurethane resins, T1180P type polyester
8 parts of elastomer, 0.7 part of phosphite-based antioxidant, 0.5 part of Tissuemat E, 0.85 part of 440 type levelling agent, antistatic additive 0.4
Part, 11 parts of butyl acetate, 7 parts of isobutyl acetate, antistatic additive is by unsaturated aliphatic polyester and trimethyl chlorination
Ammonium is copolymerized to be formed, and the mass ratio of unsaturated aliphatic polyester and DTAC is 70:30.
Embodiment 3
A kind of BOPET dumb lights antistatic film, including base material and the functional layer that is laminated on the side surface of base material one, functional layer by
Following raw material compounds to be formed：22 parts of CP750 types vinyl chloride-vinyl acetate resin, 15 parts of PM100 type polyurethane resins, T1185P type polyester
9 parts of elastomer, 0.9 part of 1010 type antioxidant, 0.6 part of Tissuemat E, 0.7 part of 440 type levelling agent, 0.5 part of antistatic additive, vinegar
13 parts of acid butyl ester, 8 parts of isobutyl acetate, antistatic additive are copolymerized by unsaturated aliphatic polyester and DTAC
Formed, the mass ratio of unsaturated aliphatic polyester and DTAC is 60:40.
The matte release film that above-described embodiment 1-3 is prepared carries out performance test, as a result as shown in the table：
| Sample | Sheet resistance (Ω) | Mist degree (%) | Light transmittance (%) | Outward appearance |
| Embodiment 1 | 3.5×109 | 2.7 | 81 | Uniformly, frosted, dumb light |
| Embodiment 2 | 3.4×109 | 2.7 | 80 | Uniformly, frosted, dumb light |
| Embodiment 3 | 3.4×109 | 2.6 | 85 | Uniformly, frosted, dumb light |
| Comparative example | 7.0×109 | 4.0 | 90 | Uniformly, frosted, dumb light |
Comparative example is commercially available BOPET dumb lights film.
Illustrate that the polyester film that the present embodiment provides has excellent antistatic property by upper table, meanwhile, have very high
The transparency and mist degree, can meet actual use demand.
Preferred embodiments of the present invention are these are only, not thereby limit embodiments of the present invention and protection domain, it is right
For those skilled in the art, all equivalent substitutions with made by present specification should be can appreciate that and shown
And the scheme obtained by the change being clear to, it should be included in protection scope of the present invention.
Claims (6)
1. a kind of BOPET dumb lights antistatic film, it is characterised in that including polyester base material and be laminated in polyester base material side table
Functional layer on face, the functional layer are compounded by following raw material and formed：Vinyl chloride-vinyl acetate resin 10-25 parts, polyurethane resin 10-
20 parts, it is polyester elastomer 7-12 parts, antioxidant 0.5-1 parts, Tissuemat E 0.1-0.7 parts, levelling agent 0.3-1 parts, antistatic
Agent 0.3-0.8 parts, butyl acetate 10-13 parts, isobutyl acetate 5-8 parts, the antistatic additive by unsaturated aliphatic polyester with
DTAC is copolymerized to be formed, the unsaturated aliphatic polyester and the DTAC
Mass ratio is 50-70:50-30.
2. BOPET dumb lights antistatic film according to claim 1, it is characterised in that the vinyl chloride-vinyl acetate resin be selected from CP450 or
One kind in CP750 vinyl chloride-vinyl acetate resins.
3. BOPET dumb lights antistatic film according to claim 1, it is characterised in that the polyurethane resin is selected from PM100
Or one kind in M20S polyurethane resins.
4. BOPET dumb lights antistatic film according to claim 1, it is characterised in that the polyester elastomer is selected from
One kind in T1180P or T1185P elastomers.
5. BOPET dumb lights antistatic film according to claim 1, it is characterised in that the antioxidant is selected from phosphorous acid
One kind in ester, 1010 antioxidants or 1076 antioxidants.
6. BOPET dumb lights antistatic film according to claim 1, it is characterised in that the levelling agent is 440 levelling agents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711146895.XA CN107760117A (en) | 2017-11-17 | 2017-11-17 | A kind of BOPET dumb lights antistatic film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711146895.XA CN107760117A (en) | 2017-11-17 | 2017-11-17 | A kind of BOPET dumb lights antistatic film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107760117A true CN107760117A (en) | 2018-03-06 |
Family
ID=61279507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711146895.XA Pending CN107760117A (en) | 2017-11-17 | 2017-11-17 | A kind of BOPET dumb lights antistatic film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107760117A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225281A (en) * | 2007-12-17 | 2008-07-23 | 河南省联合磨料磨具有限公司 | Polishing film and method for making same |
| CN102219965A (en) * | 2011-05-20 | 2011-10-19 | 潍坊胜达科技股份有限公司 | Antistatic flame-resistant environmentally stable peelable protective film and preparation method thereof |
| CN105348946A (en) * | 2015-10-29 | 2016-02-24 | 保定乐凯新材料股份有限公司 | Matt release film |
| CN106313923A (en) * | 2015-07-03 | 2017-01-11 | 禹辉（上海）转印材料股份有限公司 | Method for producing high abrasion-resistant solvent-resistant heat transfer film |
-
2017
- 2017-11-17 CN CN201711146895.XA patent/CN107760117A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225281A (en) * | 2007-12-17 | 2008-07-23 | 河南省联合磨料磨具有限公司 | Polishing film and method for making same |
| CN102219965A (en) * | 2011-05-20 | 2011-10-19 | 潍坊胜达科技股份有限公司 | Antistatic flame-resistant environmentally stable peelable protective film and preparation method thereof |
| CN106313923A (en) * | 2015-07-03 | 2017-01-11 | 禹辉（上海）转印材料股份有限公司 | Method for producing high abrasion-resistant solvent-resistant heat transfer film |
| CN105348946A (en) * | 2015-10-29 | 2016-02-24 | 保定乐凯新材料股份有限公司 | Matt release film |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180306 |