CN107759078A - A kind of heat-insulated coloured glass of antiultraviolet and its production technology - Google Patents
A kind of heat-insulated coloured glass of antiultraviolet and its production technology Download PDFInfo
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- CN107759078A CN107759078A CN201711250975.XA CN201711250975A CN107759078A CN 107759078 A CN107759078 A CN 107759078A CN 201711250975 A CN201711250975 A CN 201711250975A CN 107759078 A CN107759078 A CN 107759078A
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- parts
- glass
- heat
- antiultraviolet
- insulated
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- 239000005315 stained glass Substances 0.000 title claims abstract description 40
- 238000005516 engineering process Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000011521 glass Substances 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 29
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 23
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 20
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000009413 insulation Methods 0.000 claims abstract description 16
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 14
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000137 annealing Methods 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 229960002594 arsenic trioxide Drugs 0.000 claims abstract description 10
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 10
- 238000004040 coloring Methods 0.000 claims abstract description 9
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 8
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 7
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 6
- 238000005520 cutting process Methods 0.000 claims abstract description 4
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 12
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims description 12
- 239000003086 colorant Substances 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 229910003803 Gold(III) chloride Inorganic materials 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 6
- 235000013539 calcium stearate Nutrition 0.000 claims description 6
- 239000008116 calcium stearate Substances 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 6
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 6
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 238000005058 metal casting Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 abstract description 16
- 235000010344 sodium nitrate Nutrition 0.000 abstract description 8
- 239000004317 sodium nitrate Substances 0.000 abstract description 8
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 abstract description 5
- 238000010924 continuous production Methods 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- COHDHYZHOPQOFD-UHFFFAOYSA-N arsenic pentoxide Chemical compound O=[As](=O)O[As](=O)=O COHDHYZHOPQOFD-UHFFFAOYSA-N 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/10—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce uniformly-coloured transparent products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/085—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for ultraviolet absorbing glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of heat-insulated coloured glass of antiultraviolet and its production technology, is related to coloured glass technology field, is prepared from the following raw materials in parts by weight：80 90 parts of silica,25 parts of potassium feldspar,25 parts of calcium sulfate,28 70 parts of calcium carbonate,24 60 parts of potassium carbonate,20 30 parts of sodium acid carbonate,10 15 parts of saltcake,10 20 parts of soda ash,15 25 parts of barium carbonate,5 15 parts of cerium oxide,5 15 parts of sodium sulphate,5 10 parts of white arsenic,10 15 parts of sodium nitrate,10 12 parts of tin oxide,5 10 parts of ultraviolet light screener,5 10 parts of colouring agent,20 30 parts of insulation agent,The production technology of the coloured glass includes fusing and stirred,Inject mould,Annealing,Heat treatment and cooling five steps of cutting,The stability of the coloured glass is good,Glass surface not easy-weathering,The intensity of glass is high,Quality is good,And there is antiultraviolet and heat-insulated function,The preparation technology of coloured glass of the present invention is simple,It is adapted to industrialized continuous production.
Description
Technical field
The present invention relates to coloured glass technical field, and in particular to a kind of heat-insulated coloured glass of antiultraviolet and its production work
Skill.
Background technology
Glass is a kind of transparent semisolid, semiliquid material, the formation contiguous network structure in melting, in cooling procedure
Viscosity gradually increases and hardened and non crystallized silicates nonmetallic materials.The main component of simple glass is silica,
It has very high chemical stability, heat endurance and good transparency, therefore is widely used in every field.People at present
Widely used glass be mostly individual layer plate glass, it has good translucency, but heat insulating effect is poor, no
It can effectively stop that the heat of outdoor sunshine is got in, so as to cause indoor temperature higher, and can not effectively obstruct ultraviolet
Line, excessive ultraviolet easily cause to damage to human body.
Coloured glass is that colouring agent is added in simple glass, and number, melting time and the glass melting temperature of amount of colorant are all
The depth of color is burnt till in the different degrees of influence of meeting.Using colloidal colorant, such as gold, silver, copper, selenium, sulphur, hang nano sized particles
Float in vitreum, make glass coloration.No matter which kind of colouring agent all adds fluxing agent in sintering procedure.
Accordingly, it is desirable to provide a kind of heat-insulated coloured glass of antiultraviolet, its heat-proof quality is preferable, can effectively stop the sun
Light, so as to ensure the cool place of interior, and can effectively prevent erosion of the ultraviolet to human body, at the same have uniqueness color and
Tone.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of heat-insulated coloured glass of antiultraviolet and its production technology,
So that the stability of coloured glass is good, glass surface not easy-weathering, the intensity of glass is high, quality is good, and with antiultraviolet and
Heat-insulated function.
To realize object above, the present invention is achieved by the following technical programs：
A kind of heat-insulated coloured glass of antiultraviolet, is prepared from the following raw materials in parts by weight：
Silica 80-90 parts, potassium feldspar 2-5 parts, calcium sulfate 2-5 parts, calcium carbonate 28-70 parts, potassium carbonate 24-60 parts, carbonic acid
Hydrogen sodium 20-30 parts, saltcake 10-15 parts, soda ash 10-20 parts, barium carbonate 15-25 parts, cerium oxide 5-15 parts, sodium sulphate 5-15 parts,
White arsenic 5-10 parts, sodium nitrate 10-15 parts, tin oxide 10-12 parts, ultraviolet light screener 5-10 parts, colouring agent 5-10 parts, insulation agent
20-30 parts.
Preferably, the coloring agent component includes：Fe2O3、MnO2、Co2O3、K2Cr2O7、SB2S3、AuCl3、Cu2O、CeO2。
Preferably, the ultraviolet light screener is mixed by titanium dioxide, zinc oxide, talcum powder, clay and calcium carbonate.
Preferably, the insulation agent is prepared from the following raw materials in parts by weight：Acrylic resin 20-30 parts, isopropanol 35-
50 parts, calcium stearate 1-2 parts, polyamide wax anti-settling agent 1-2 parts, nano imvite 15-20 parts, cellulose 10-20 parts, attachment increase
Add agent 1-3 parts.
Preferably, the potassium feldspar, calcium sulfate, the mass ratio of calcium carbonate are 1：1：14.
Preferably, the mass ratio of the potassium feldspar and potassium carbonate is 1：1 2.
The production technology of the above-mentioned heat-insulated coloured glass of antiultraviolet, comprises the following steps:
（1）Fusing stirring：Each raw material of formula ratio is weighed, is put into after well mixed in fusing mixer, at 1550-1565 DEG C
Fusing 6-7h is stirred, glass metal is made；
（2）Inject mould：By glass metal casting in a mold, it is pressed；
（3）Annealing：After glass shaping, at 500-600 DEG C, mould is subjected to annealing 1-2h；
（4）Heat treatment：The mould made annealing treatment is directly subjected to heat treatment 1-3h at 650-700 DEG C；
（5）Cooling cutting：Mould after heat treatment is put into cooling bay and cooled down, opens mould after cooling, is made
Glass is taken out with glass special vice, then cuts into the coloured glass of required specification.
Beneficial effect：
The invention provides a kind of heat-insulated coloured glass of antiultraviolet and its production technology, the present invention adds purple in process of production
Outside line screener and insulation agent, ultraviolet light screener can stop ultraviolet, and insulation agent can form one layer of thermal insulation film so that coloured
Glass has antiultraviolet and heat-insulated function；Cerium oxide and sodium sulphate give full play to the cooperative effect of the two and folded in the present invention
Add effect, can reach the effect of lasting clarification, greatly strengthen clarifying ability, increase the clarity of coloured glass, avoid glass
There is blooming；White arsenic and sodium nitrate are used cooperatively, and can reach good clarifying effect, and when white arsenic be heated to 400 DEG C with
When upper, diarsenic pentoxide was generated with the oxygen that sodium nitrate is released in high temperature, when being heated to 1300 DEG C, diarsenic pentoxide decomposes life
Into arsenic trioxide, the partial pressure of gas in glass metal bubble is reduced, is advantageous to growing up for bubble, accelerates the exclusion of bubble, from
And reach the purpose of clarification so that glassware bubble-free, it is ensured that the quality of glass；Potassium feldspar, calcium sulfate, carbonic acid in the present invention
The proportioning that calcium and potassium carbonate pass through science so that thermal decomposition system reaches optimum state, improves heat endurance and the change of glass metal
Stability is learned, the impact resistance and compressive resistance of reinforcing glass, also make it that coloured glass stability is good, glass surface is not easy wind
Change, ensure the quality of glass.
The present invention is also added into annealing and process of thermal treatment in operation, is put into mould after mould molding and moves back
Annealed in stove, mould is heat-treated again after annealing, then cooled down, avoided glass and produced fried because one hot one is cold
Split, improve the production efficiency of glass.
The invention provides a kind of heat-insulated coloured glass of antiultraviolet and its production technology, the stability of the coloured glass
Good, glass surface not easy-weathering, the intensity of glass is high, quality is good, and has antiultraviolet and heat-insulated function, of the invention coloured
The preparation technology of glass is simple, is adapted to industrialized continuous production.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, belongs to the scope of protection of the invention.
Embodiment 1：
A kind of heat-insulated coloured glass of antiultraviolet, is prepared from the following raw materials in parts by weight：
80 parts of silica, 2 parts of potassium feldspar, 2 parts of calcium sulfate, 28 parts of calcium carbonate, 24 parts of potassium carbonate, 30 parts of sodium acid carbonate, saltcake
15 parts, 10 parts of soda ash, 25 parts of barium carbonate, 5 parts of cerium oxide, 15 parts of sodium sulphate, 5 parts of white arsenic, 10 parts of sodium nitrate, 12 parts of tin oxide,
5 parts of ultraviolet light screener, 10 parts of colouring agent, 20 parts of insulation agent.
Wherein, coloring agent component includes：Fe2O3、MnO2、Co2O3、K2Cr2O7、SB2S3、AuCl3、Cu2O、CeO2；Ultraviolet
Screener is mixed by titanium dioxide, zinc oxide, talcum powder, clay and calcium carbonate；Insulation agent by following parts by weight original
Material is made：20 parts of acrylic resin, 50 parts of isopropanol, 1 part of calcium stearate, 2 parts of polyamide wax anti-settling agent, nano imvite 15
1 part part, 20 parts of cellulose, attachment of dose.
The production technology of the above-mentioned heat-insulated coloured glass of antiultraviolet, comprises the following steps:
（1）Fusing stirring：Each raw material of formula ratio is weighed, is put into after well mixed in fusing mixer, at 1550-1565 DEG C
Fusing 6-7h is stirred, glass metal is made；
（2）Inject mould：By glass metal casting in a mold, it is pressed；
（3）Annealing：After glass shaping, at 500-600 DEG C, mould is subjected to annealing 1-2h；
（4）Heat treatment：The mould made annealing treatment is directly subjected to heat treatment 1-3h at 650-700 DEG C；
（5）Cooling cutting：Mould after heat treatment is put into cooling bay and cooled down, opens mould after cooling, is made
Glass is taken out with glass special vice, then cuts into the coloured glass of required specification.
Embodiment 2：
A kind of heat-insulated coloured glass of antiultraviolet, is prepared from the following raw materials in parts by weight：
90 parts of silica, 5 parts of potassium feldspar, 5 parts of calcium sulfate, 70 parts of calcium carbonate, 60 parts of potassium carbonate, 20 parts of sodium acid carbonate, saltcake
10 parts, 20 parts of soda ash, 15 parts of barium carbonate, 15 parts of cerium oxide, 5 parts of sodium sulphate, 10 parts of white arsenic, 15 parts of sodium nitrate, 10 parts of tin oxide,
10 parts of ultraviolet light screener, 5 parts of colouring agent, 30 parts of insulation agent.
Wherein, coloring agent component includes：Fe2O3、MnO2、Co2O3、K2Cr2O7、SB2S3、AuCl3、Cu2O、CeO2；Ultraviolet
Screener is mixed by titanium dioxide, zinc oxide, talcum powder, clay and calcium carbonate；Insulation agent by following parts by weight original
Material is made：30 parts of acrylic resin, 35 parts of isopropanol, 2 parts of calcium stearate, 1 part of polyamide wax anti-settling agent, nano imvite 20
3 parts part, 10 parts of cellulose, attachment of dose；The production technology of the heat-insulated coloured glass of the antiultraviolet is the same as embodiment 1.
Embodiment 3：
A kind of heat-insulated coloured glass of antiultraviolet, is prepared from the following raw materials in parts by weight：
85 parts of silica, 3 parts of potassium feldspar, 3 parts of calcium sulfate, 52 parts of calcium carbonate, 36 parts of potassium carbonate, 25 parts of sodium acid carbonate, saltcake
12 parts, 15 parts of soda ash, 20 parts of barium carbonate, 10 parts of cerium oxide, 10 parts of sodium sulphate, 7 parts of white arsenic, 13 parts of sodium nitrate, 11 parts of tin oxide,
8 parts of ultraviolet light screener, 7 parts of colouring agent, 25 parts of insulation agent.
Wherein, coloring agent component includes：Fe2O3、MnO2、Co2O3、K2Cr2O7、SB2S3、AuCl3、Cu2O、CeO2；Ultraviolet
Screener is mixed by titanium dioxide, zinc oxide, talcum powder, clay and calcium carbonate；Insulation agent by following parts by weight original
Material is made：25 parts of acrylic resin, 40 parts of isopropanol, 1.5 parts of calcium stearate, 1.5 parts of polyamide wax anti-settling agent, nano imvite
17 parts, 15 parts of cellulose, attachment 2 parts of dose；The production technology of the heat-insulated coloured glass of the antiultraviolet is the same as embodiment 1.
Embodiment 4：
A kind of heat-insulated coloured glass of antiultraviolet, is prepared from the following raw materials in parts by weight：
88 parts of silica, 4 parts of potassium feldspar, 4 parts of calcium sulfate, 56 parts of calcium carbonate, 48 parts of potassium carbonate, 27 parts of sodium acid carbonate, saltcake
14 parts, 17 parts of soda ash, 23 parts of barium carbonate, 11 parts of cerium oxide, 9 parts of sodium sulphate, 8 parts of white arsenic, 14 parts of sodium nitrate, 11 parts of tin oxide,
7.5 parts of ultraviolet light screener, 6 parts of colouring agent, 28 parts of insulation agent.
Wherein, coloring agent component includes：Fe2O3、MnO2、Co2O3、K2Cr2O7、SB2S3、AuCl3、Cu2O、CeO2；Ultraviolet
Screener is mixed by titanium dioxide, zinc oxide, talcum powder, clay and calcium carbonate；Insulation agent by following parts by weight original
Material is made：27 parts of acrylic resin, 45 parts of isopropanol, 2 parts of calcium stearate, 1.5 parts of polyamide wax anti-settling agent, nano imvite 18
2.5 parts part, 13 parts of cellulose, attachment of dose；The production technology of the heat-insulated coloured glass of the antiultraviolet is the same as embodiment 1.
The embodiment of the present invention has the advantages that：Coloured glass bright color, nothing made from 1-4 of the embodiment of the present invention
Bubble, quality are good, and have antiultraviolet and heat-insulated function.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply and deposited between these entities or operation
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Nonexcludability includes, so that process, method, article or equipment including a series of elements not only will including those
Element, but also the other element including being not expressly set out, or it is this process, method, article or equipment also to include
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Other identical element also be present in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (7)
1. a kind of heat-insulated coloured glass of antiultraviolet, it is characterised in that be prepared from the following raw materials in parts by weight：Silica
80-90 parts, potassium feldspar 2-5 parts, calcium sulfate 2-5 parts, calcium carbonate 28-70 parts, potassium carbonate 24-60 parts, sodium acid carbonate 20-30 parts,
Saltcake 10-15 parts, soda ash 10-20 parts, barium carbonate 15-25 parts, cerium oxide 5-15 parts, sodium sulphate 5-15 parts, white arsenic 5-10 parts, nitre
Sour sodium 10-15 parts, tin oxide 10-12 parts, ultraviolet light screener 5-10 parts, colouring agent 5-10 parts, insulation agent 20-30 parts.
2. the heat-insulated coloured glass of antiultraviolet as claimed in claim 1, it is characterised in that the coloring agent component includes：
Fe2O3、MnO2、Co2O3、K2Cr2O7、SB2S3、AuCl3、Cu2O、CeO2。
3. the heat-insulated coloured glass of antiultraviolet as claimed in claim 1, it is characterised in that the ultraviolet light screener is by dioxy
Change titanium, zinc oxide, talcum powder, clay and calcium carbonate to mix.
4. the heat-insulated coloured glass of antiultraviolet as claimed in claim 1, it is characterised in that the insulation agent is by following parts by weight
Several raw materials are made：Acrylic resin 20-30 parts, isopropanol 35-50 parts, calcium stearate 1-2 parts, polyamide wax anti-settling agent 1-2
Part, nano imvite 15-20 parts, cellulose 10-20 parts, attachment dose 1-3 parts.
5. the heat-insulated coloured glass of antiultraviolet as claimed in claim 1, it is characterised in that the potassium feldspar, calcium sulfate, carbonic acid
The mass ratio of calcium is 1：1：14.
6. the heat-insulated coloured glass of antiultraviolet as claimed in claim 1, it is characterised in that the matter of the potassium feldspar and potassium carbonate
Amount is than being 1：1 2.
7. the production technology of the heat-insulated coloured glass of antiultraviolet as claimed in claim 1, it is characterised in that including following step
Suddenly:
（1）Fusing stirring：Each raw material of formula ratio is weighed, is put into after well mixed in fusing mixer, at 1550-1565 DEG C
Fusing 6-7h is stirred, glass metal is made；
（2）Inject mould：By glass metal casting in a mold, it is pressed；
（3）Annealing：After glass shaping, at 500-600 DEG C, mould is subjected to annealing 1-2h；
（4）Heat treatment：The mould made annealing treatment is directly subjected to heat treatment 1-3h at 650-700 DEG C；
（5）Cooling cutting：Mould after heat treatment is put into cooling bay and cooled down, opens mould after cooling, is made
Glass is taken out with glass special vice, then cuts into the coloured glass of required specification.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711250975.XA CN107759078A (en) | 2017-12-01 | 2017-12-01 | A kind of heat-insulated coloured glass of antiultraviolet and its production technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711250975.XA CN107759078A (en) | 2017-12-01 | 2017-12-01 | A kind of heat-insulated coloured glass of antiultraviolet and its production technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113149434A (en) * | 2021-05-12 | 2021-07-23 | 斯卡特(北京)新材料技术有限公司 | Medium-light-transmission high-heat-insulation energy-saving float glass and preparation method thereof |
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