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CN107739176A - A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof - Google Patents

A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof Download PDF

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Publication number
CN107739176A
CN107739176A CN201710937737.XA CN201710937737A CN107739176A CN 107739176 A CN107739176 A CN 107739176A CN 201710937737 A CN201710937737 A CN 201710937737A CN 107739176 A CN107739176 A CN 107739176A
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CN
China
Prior art keywords
parts
antibacterial
artificial slabstone
mould
mouldproof anion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710937737.XA
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Chinese (zh)
Inventor
朱德官
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Shanghai Lead Technology Co Ltd
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Shanghai Lead Technology Co Ltd
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Publication date
Application filed by Shanghai Lead Technology Co Ltd filed Critical Shanghai Lead Technology Co Ltd
Priority to CN201710937737.XA priority Critical patent/CN107739176A/en
Publication of CN107739176A publication Critical patent/CN107739176A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof, it is related to architectural decoration material field, artificial slabstone is a kind of new composite, it can be compared favourably with lithotome, it is non-toxic, "dead", widely used in buildings decoration field, and people have found that it is easily grown germ and mould by moist in use, it is harmful to the health of people, in view of the shortcomings of the prior art, therefore a kind of antibacterial and mouldproof anion artificial slabstone is invented, it is characterised in that:It is made up of the following raw material of mass parts, including 0.5 4 parts of antiseptic, 0.5 4 parts of mould inhibitor, 38 parts of negative ion powder, 20 40 parts of sand particles, 15 25 parts of unsaturated-resin, 20 30 parts of stone flour, 28 parts of white cement, 28 parts of silica flour, 0.1 3 parts of pigment, 0.2 3.5 parts of accelerator, 0.2 1.5 parts of coupling agent, 0.5 3 parts of curing agent, glass fabric, its advantage is:It can effectively play a part of antibacterial, mould proof, release anion, be beneficial to the health of people.

Description

A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof
Technical field
The present invention relates to architectural decoration material field, and in particular to a kind of antibacterial and mouldproof anion artificial slabstone.
Technical background
Artificial slabstone is a kind of new composite, is equipped with different colorants in the fabrication process and can be made into color Color gorgeous, decorative pattern is non-toxic, "dead" naturally, can be compared favourably with lithotome, makes extensively in buildings decoration field With, and people have found that it is easily grown germ and mould by moist in use, are harmful to the health of people, for existing There is the deficiency of technology, therefore invent a kind of antibacterial and mouldproof anion artificial slabstone, its advantage is:Effectively can Play a part of antibacterial, mould proof, release anion, the health of people can be beneficial to.
The content of the invention
The present invention is exactly to solve the problems of the prior art, there is provided a kind of antibacterial and mouldproof anion artificial slabstone.
The technical problems to be solved by the invention are achieved through the following technical solutions.
A kind of antibacterial and mouldproof anion artificial slabstone, it is characterised in that:It is made up of the following raw material of mass parts, including it is anti- Microbial inoculum 0.5-4 parts, mould inhibitor 0.5-4 parts, negative ion powder 3-8 parts, sand particles 20-40 parts, unsaturated-resin 15-25 parts, stone flour 20-30 parts, white cement 2-8 parts, silica flour 2-8 parts, pigment 0.1-3 parts, accelerator 0.2-3.5 parts, coupling agent 0.2-1.5 parts, Curing agent 0.5-3 parts, glass fabric.
Further, the antiseptic be include one kind in carbendazim, Bravo, streptomysin, zinc oxide, silver ion or Person is several.
Further, the mould inhibitor is to include the one or more in OBPA, copper sulphate, sodium fluoride.
Further, the glass fabric is 80-120 gram masses.
Further, the preparation method of a kind of antibacterial and mouldproof anion artificial slabstone, it is characterised in that including with Lower step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, add appropriate amount of water, 20-40 points of moderate-speed mixer Mixed slurry is made in clock, then high-speed stirred 30-50 minutes;
(2) gained mixed slurry is added in vacuum barrel and vacuumizes 20-30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidify 8-16 hours, blank is made;
(4) gained blank room temperature is conserved into 36-48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Further, the preparation method of a kind of antibacterial and mouldproof anion artificial slabstone, it is characterised in that including with The cure under pressure temperature described in (3) described in lower step is 50 DEG C -85 DEG C.
Its advantage of the present invention is:It can effectively play a part of antibacterial, mould proof, release anion, can have Beneficial to the health of people.
Embodiment
Embodiment 1
A kind of antibacterial and mouldproof anion artificial slabstone of the present embodiment, it is characterised in that:There is the following raw material group of mass parts Into, including 0.5 part of antiseptic, 0.8 part of mould inhibitor, 3 parts of negative ion powder, 40 parts of sand particles, 15 parts of unsaturated-resin, stone flour 20 Part, 3 parts of white cement, 2 parts of silica flour, 0.1 part of pigment, 0.2 part of accelerator, 0.2 part of coupling agent, 0.5 part of curing agent, glass fibre Cloth.
The mass parts ratio of antiseptic described in the present embodiment is 1: 1: 1: 1: 1 carbendazim, Bravo, streptomysin, zinc oxide, silver Ion.
The mass parts ratio of mould inhibitor described in the present embodiment is 3: 2: 1 OBPA, copper sulphate, sodium fluoride.
Glass fabric described in the present embodiment is 120 gram masses.
A kind of preparation method of antibacterial and mouldproof anion artificial slabstone described in the present embodiment, it is characterised in that including following Step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, addition appropriate amount of water, moderate-speed mixer 30 minutes, 40 minutes obtained mixed slurries of high-speed stirred again;
(2) gained mixed slurry is added in vacuum barrel and vacuumized 30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidification 16 hours, temperature are 75 DEG C, and blank is made;
(4) gained blank room temperature is conserved 48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Embodiment 2
A kind of antibacterial and mouldproof anion artificial slabstone of the present embodiment, it is characterised in that:There is the following raw material group of mass parts Into, including 0.8 part of antiseptic, 0.9 part of mould inhibitor, 4 parts of negative ion powder, 38 parts of sand particles, 18 parts of unsaturated-resin, stone flour 23 Part, 5 parts of white cement, 3 parts of silica flour, 0.5 part of pigment, 0.3 part of accelerator, 0.3 part of coupling agent, 0.7 part of curing agent, glass fibre Cloth.
The mass parts ratio of antiseptic described in the present embodiment is 1: 1: 1: 1: 1 carbendazim, Bravo, streptomysin, zinc oxide, silver Ion.
The mass parts ratio of mould inhibitor described in the present embodiment is 3: 2: 1 OBPA, copper sulphate, sodium fluoride.
Glass fabric described in the present embodiment is 120 gram masses.
A kind of preparation method of antibacterial and mouldproof anion artificial slabstone described in the present embodiment, it is characterised in that including following Step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, addition appropriate amount of water, moderate-speed mixer 35 minutes, 35 minutes obtained mixed slurries of high-speed stirred again;
(2) gained mixed slurry is added in vacuum barrel and vacuumized 30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidification 12 hours, temperature are 80 DEG C, and blank is made;
(4) gained blank room temperature is conserved 48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Embodiment 3
A kind of antibacterial and mouldproof anion artificial slabstone of the present embodiment, it is characterised in that:There is the following raw material group of mass parts Into, including it is 1 part of antiseptic, 1 part of mould inhibitor, 5 parts of negative ion powder, 36 parts of sand particles, 20 parts of unsaturated-resin, 25 parts of stone flour, white 6 parts of cement, 4 parts of silica flour, 0.5 part of pigment, 0.3 part of accelerator, 0.3 part of coupling agent, 0.7 part of curing agent, glass fabric.
The mass parts ratio of antiseptic described in the present embodiment is 1: 1: 1: 1: 1 carbendazim, Bravo, streptomysin, zinc oxide, silver Ion.
The mass parts ratio of mould inhibitor described in the present embodiment is 3: 1: 1 OBPA, copper sulphate, sodium fluoride.
Glass fabric described in the present embodiment is 120 gram masses.
A kind of preparation method of antibacterial and mouldproof anion artificial slabstone described in the present embodiment, it is characterised in that including following Step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, addition appropriate amount of water, moderate-speed mixer 35 minutes, 35 minutes obtained mixed slurries of high-speed stirred again;
(2) gained mixed slurry is added in vacuum barrel and vacuumized 30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidification 12 hours, temperature are 80 DEG C, and blank is made;
(4) gained blank room temperature is conserved 48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Embodiment 4
A kind of antibacterial and mouldproof anion artificial slabstone of the present embodiment, it is characterised in that:There is the following raw material group of mass parts Into, including 1.5 parts of antiseptic, 1.5 parts of mould inhibitor, 6 parts of negative ion powder, 36 parts of sand particles, 22 parts of unsaturated-resin, stone flour 27 Part, 7 parts of white cement, 6 parts of silica flour, 0.7 part of pigment, 0.5 part of accelerator, 0.5 part of coupling agent, 0.7 part of curing agent, glass fibre Cloth.
The mass parts ratio of antiseptic described in the present embodiment is 1: 1: 1: 1: 1 carbendazim, Bravo, streptomysin, zinc oxide, silver Ion.
The mass parts ratio of mould inhibitor described in the present embodiment is 3: 1: 1 OBPA, copper sulphate, sodium fluoride.
Glass fabric described in the present embodiment is 110 gram masses.
A kind of preparation method of antibacterial and mouldproof anion artificial slabstone described in the present embodiment, it is characterised in that including following Step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, addition appropriate amount of water, moderate-speed mixer 40 minutes, 40 minutes obtained mixed slurries of high-speed stirred again;
(2) gained mixed slurry is added in vacuum barrel and vacuumized 30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidification 12 hours, temperature are 80 DEG C, and blank is made;
(4) gained blank room temperature is conserved 48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Embodiment 5
A kind of antibacterial and mouldproof anion artificial slabstone of the present embodiment, it is characterised in that:There is the following raw material group of mass parts Into, including 1.8 parts of antiseptic, 1.8 parts of mould inhibitor, 7 parts of negative ion powder, 34 parts of sand particles, 23 parts of unsaturated-resin, stone flour 28 Part, 7 parts of white cement, 7 parts of silica flour, 0.9 part of pigment, 0.7 part of accelerator, 0.5 part of coupling agent, 0.9 part of curing agent, glass fibre Cloth.
The mass parts ratio of antiseptic described in the present embodiment is 1: 1: 1: 1: 1 carbendazim, Bravo, streptomysin, zinc oxide, silver Ion.
The mass parts ratio of mould inhibitor described in the present embodiment is 3: 1: 1 OBPA, copper sulphate, sodium fluoride.
Glass fabric described in the present embodiment is 100 gram masses.
A kind of preparation method of antibacterial and mouldproof anion artificial slabstone described in the present embodiment, it is characterised in that including following Step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, addition appropriate amount of water, moderate-speed mixer 40 minutes, 40 minutes obtained mixed slurries of high-speed stirred again;
(2) gained mixed slurry is added in vacuum barrel and vacuumized 30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidification 12 hours, temperature are 80 DEG C, and blank is made;
(4) gained blank room temperature is conserved 48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Embodiment 6
A kind of antibacterial and mouldproof anion artificial slabstone of the present embodiment, it is characterised in that:There is the following raw material group of mass parts Into, including 2.5 parts of antiseptic, 2.5 parts of mould inhibitor, 8 parts of negative ion powder, 40 parts of sand particles, 25 parts of unsaturated-resin, stone flour 30 Part, 8 parts of white cement, 8 parts of silica flour, 0.9 part of pigment, 1.5 parts of accelerator, 1 part of coupling agent, 2 parts of curing agent, glass fabric.
The mass parts ratio of antiseptic described in the present embodiment is 1: 1: 1: 1: 1 carbendazim, Bravo, streptomysin, zinc oxide, silver Ion.
The mass parts ratio of mould inhibitor described in the present embodiment is 3: 1: 1 OBPA, copper sulphate, sodium fluoride.
Glass fabric described in the present embodiment is 90 gram masses.
A kind of preparation method of antibacterial and mouldproof anion artificial slabstone described in the present embodiment, it is characterised in that including following Step:
(1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, face Material, accelerator, coupling agent, curing agent are added in speed stirrer by mass parts, addition appropriate amount of water, moderate-speed mixer 40 minutes, 50 minutes obtained mixed slurries of high-speed stirred again;
(2) gained mixed slurry is added in vacuum barrel and vacuumized 30 minutes;
(3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into vibrating mould and pressurizeed Solidification 18 hours, temperature are 80 DEG C, and blank is made;
(4) gained blank room temperature is conserved 48 hours;
(5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
Above-described embodiment is only that the description of the invention not makes formal limitation to the present invention, is not departing from this hair Within the scope of bright technical scheme any technology contents using the disclosure above make simple change etc. equivalent scheme belong to Protection scope of the present invention.

Claims (6)

  1. A kind of 1. antibacterial and mouldproof anion artificial slabstone, it is characterised in that:It is made up of the following raw material of mass parts, including antibacterial Agent 0.5-4 parts, mould inhibitor 0.5-4 parts, negative ion powder 3-8 parts, sand particles 20-40 parts, unsaturated-resin 15-25 parts, stone flour 20- 30 parts, white cement 2-8 parts, silica flour 2-8 parts, pigment 0.1-3 parts, accelerator 0.2-3.5 parts, coupling agent 0.2-1.5 parts, solidification Agent 0.5-3 parts, glass fabric.
  2. 2. a kind of antibacterial and mouldproof anion artificial slabstone according to claim 1, it is characterised in that the antiseptic is bag Include the one or several kinds in carbendazim, Bravo, streptomysin, zinc oxide, silver ion.
  3. 3. a kind of antibacterial and mouldproof anion artificial slabstone according to claim 1, it is characterised in that the mould inhibitor is bag Include the one or more in OBPA, copper sulphate, sodium fluoride.
  4. A kind of 4. antibacterial and mouldproof anion artificial slabstone according to claim 1, it is characterised in that the glass fabric For 80-120 gram masses.
  5. A kind of 5. preparation method of antibacterial and mouldproof anion artificial slabstone according to claim 1, it is characterised in that including Following steps:
    (1) by the antibacterial mildew inhibitor, negative ion powder, sand particles, unsaturated-resin, stone flour, white cement, silica flour, pigment, rush Enter agent, coupling agent, curing agent are added in speed stirrer by mass parts, add appropriate amount of water, moderate-speed mixer 20-40 minutes, then Mixed slurry is made in high-speed stirred 30-50 minutes;
    (2) gained mixed slurry is added in vacuum barrel and vacuumizes 20-30 minutes;
    (3) glass fabric is laid in the bottom of vibrating mould, gained mixed slurry is poured into cure under pressure in vibrating mould 8-16 hours, blank is made;
    (4) gained blank room temperature is conserved into 36-48 hours;
    (5) cut, polish, polishing, you can a kind of antibacterial and mouldproof anion artificial slabstone of the present invention is made.
  6. A kind of 6. preparation method of antibacterial and mouldproof anion artificial slabstone according to claim 5, it is characterised in that including The cure under pressure temperature described in (3) described in following steps is 50 DEG C -85 DEG C.
CN201710937737.XA 2017-10-09 2017-10-09 A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof Withdrawn CN107739176A (en)

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Application Number Priority Date Filing Date Title
CN201710937737.XA CN107739176A (en) 2017-10-09 2017-10-09 A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863234A (en) * 2018-07-27 2018-11-23 东莞环球经典新型材料有限公司 A kind of negative ion far-infrared inorganic artificial stone slab and preparation method thereof
CN111908814A (en) * 2020-08-12 2020-11-10 高时(厦门)石业有限公司 Preparation method of antibacterial powder, antibacterial powder and antibacterial artificial stone plate using antibacterial powder
CN111919857A (en) * 2020-08-12 2020-11-13 高时(厦门)石业有限公司 Preparation method of sterilization powder, sterilization powder and antibacterial inorganic artificial stone using sterilization powder
CN113716894A (en) * 2021-08-30 2021-11-30 浙江傲邦科技有限公司 Preparation method of GFK (glass fiber reinforced plastic) antibacterial plate

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104496273A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN105884259A (en) * 2016-03-14 2016-08-24 广东中旗新材料科技有限公司 Anti-bacterial artificial quartzite board and preparation method thereof
CN106830757A (en) * 2017-03-22 2017-06-13 佛山市蓝瑞欧特信息服务有限公司 A kind of antibacterial and mouldproof artificial quartz stone plate and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104496273A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN105884259A (en) * 2016-03-14 2016-08-24 广东中旗新材料科技有限公司 Anti-bacterial artificial quartzite board and preparation method thereof
CN106830757A (en) * 2017-03-22 2017-06-13 佛山市蓝瑞欧特信息服务有限公司 A kind of antibacterial and mouldproof artificial quartz stone plate and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863234A (en) * 2018-07-27 2018-11-23 东莞环球经典新型材料有限公司 A kind of negative ion far-infrared inorganic artificial stone slab and preparation method thereof
CN111908814A (en) * 2020-08-12 2020-11-10 高时(厦门)石业有限公司 Preparation method of antibacterial powder, antibacterial powder and antibacterial artificial stone plate using antibacterial powder
CN111919857A (en) * 2020-08-12 2020-11-13 高时(厦门)石业有限公司 Preparation method of sterilization powder, sterilization powder and antibacterial inorganic artificial stone using sterilization powder
CN113716894A (en) * 2021-08-30 2021-11-30 浙江傲邦科技有限公司 Preparation method of GFK (glass fiber reinforced plastic) antibacterial plate
CN113716894B (en) * 2021-08-30 2022-06-03 浙江傲邦科技有限公司 Preparation method of GFK (glass fiber reinforced plastic) antibacterial plate

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Application publication date: 20180227