[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN107643275A - A kind of integral type Raman optical-mechanical system - Google Patents

A kind of integral type Raman optical-mechanical system Download PDF

Info

Publication number
CN107643275A
CN107643275A CN201610687390.3A CN201610687390A CN107643275A CN 107643275 A CN107643275 A CN 107643275A CN 201610687390 A CN201610687390 A CN 201610687390A CN 107643275 A CN107643275 A CN 107643275A
Authority
CN
China
Prior art keywords
optical
optical system
raman
integral type
laser light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610687390.3A
Other languages
Chinese (zh)
Inventor
刘玉凤
吉超超
陆怡思
马宁
周颖
周鹏磊
王瑞松
董琳琳
陈博轮
刘荣华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING REALLIGHT TECHNOLOGY Co Ltd
Original Assignee
BEIJING REALLIGHT TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BEIJING REALLIGHT TECHNOLOGY Co Ltd filed Critical BEIJING REALLIGHT TECHNOLOGY Co Ltd
Priority to CN201610687390.3A priority Critical patent/CN107643275A/en
Publication of CN107643275A publication Critical patent/CN107643275A/en
Pending legal-status Critical Current

Links

Landscapes

  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Spectrometry And Color Measurement (AREA)

Abstract

The invention provides a kind of integral type Raman optical-mechanical system, including semiconductor laser light resource, the first optical system, Volume Bragg grating, dichroic mirror, the second optical system, protecting window, long wave pass filter, the 3rd optical system, slit, dispersion compensation module, detector, analysis and processing module, semiconductor cooler, housing, photodetector, light source drive control module.The system of the present invention realizes Raman laser light source, Raman probe, spectrometer it is highly integrated, eliminate the Raman interference that the coupling loss between part and Transmission Fibers introduce, compact-sized, small volume, improve capacity usage ratio and the sensitivity of system.

Description

一种一体式拉曼光机系统An integrated Raman optomechanical system

技术领域technical field

本发明涉及光学设备技术领域,尤其涉及一种一体式的拉曼检测光机系统。The invention relates to the technical field of optical equipment, in particular to an integrated Raman detection optical-mechanical system.

背景技术Background technique

拉曼光谱检测被广泛应用于生物、矿物、化学物质的鉴定与检测。基于拉曼光谱分析技术的拉曼光机系统在食品安全、生物医药、公共安全、材料科学、珠宝鉴定、地质探矿、环境检测等领域具有良好的应用前景。Raman spectroscopy is widely used in the identification and detection of biological, mineral and chemical substances. The Raman optomechanical system based on Raman spectral analysis technology has good application prospects in the fields of food safety, biomedicine, public safety, material science, jewelry identification, geological prospecting, and environmental testing.

随着科学技术的发展和应用需求的扩展,拉曼光机系统的小型化需求越来越强烈。拉曼光机系统中采用的激发光源多为独立封装的光源模块,拉曼信号激发收集模块、拉曼光谱分析模块也通常是彼此分离的,各模块之间采用传输光纤相连接。这种结构限制了拉曼光机系统的小型化,而且传输光纤的耦合、对接会造成光信号的损耗和干扰,降低系统的能量利用率和灵敏度。With the development of science and technology and the expansion of application requirements, the demand for miniaturization of Raman optomechanical systems is becoming stronger and stronger. The excitation light source used in the Raman optomechanical system is mostly an independently packaged light source module. The Raman signal excitation collection module and the Raman spectrum analysis module are usually separated from each other, and the modules are connected by transmission fibers. This structure limits the miniaturization of the Raman optical-mechanical system, and the coupling and docking of transmission fibers will cause loss and interference of optical signals, reducing the energy utilization and sensitivity of the system.

发明内容Contents of the invention

为了克服现有技术的不足,本发明的目的是提供一种结构紧凑、高集成度、小型化的一体式拉曼光机系统。它采用将半导体激光光源直接通过光学系统与长波通滤光片、色散模块安装在壳体中的方式,简化了系统结构,消除了传输光纤的影响和干扰,有利于设备的小型化,提高了拉曼光机系统的性能。In order to overcome the deficiencies of the prior art, the object of the present invention is to provide a compact, highly integrated and miniaturized integrated Raman optical-mechanical system. It adopts the method of installing the semiconductor laser light source directly through the optical system and the long-wave pass filter and dispersion module in the housing, which simplifies the system structure and eliminates the influence and interference of the transmission fiber, which is beneficial to the miniaturization of the equipment and improves the efficiency. Performance of Raman optomechanical systems.

为实现上述目的,本发明采用的技术方案是,它包括:半导体激光光源、第一光学系统、体布拉格光栅、双色镜、第二光学系统、保护窗口、长波通滤光片、第三光学系统、狭缝、色散模块、探测器、分析处理模块、半导体制冷器TEC、壳体,光电探测器,光源驱动控制模块。In order to achieve the above object, the technical solution adopted in the present invention is that it includes: semiconductor laser light source, first optical system, volume Bragg grating, dichroic mirror, second optical system, protective window, long-wave pass filter, third optical system , slit, dispersion module, detector, analysis and processing module, semiconductor cooler TEC, housing, photoelectric detector, light source drive control module.

进一步的,所述第一光学系统、体布拉格光栅、双色镜、第二光学系统、保护窗口依次共轴设置构成激发光路,激光光源共轴设置在激发光路的前端;所述长波通滤光片、第三光学系统、狭缝共轴设置构成收集光路,与激发光路垂直放置,所述色散模块、探测器构成光谱分析光路,位于收集光路的末端。Further, the first optical system, the volume Bragg grating, the dichroic mirror, the second optical system, and the protection window are sequentially arranged coaxially to form an excitation light path, and the laser light source is coaxially arranged at the front end of the excitation light path; the long-wave pass filter , the third optical system, and the coaxial arrangement of the slit constitute a collection optical path, which is placed perpendicular to the excitation optical path, and the dispersion module and the detector constitute a spectrum analysis optical path, which are located at the end of the collection optical path.

进一步的,所述半导体激光光源不经过光纤耦合,直接通过光学系统与长波通滤光片、色散模块一起安装在壳体中。Further, the semiconductor laser light source is directly installed in the casing together with the long-wave filter and the dispersion module through the optical system without optical fiber coupling.

进一步的,所述第一光学系统可实现所述半导体激光光源的准直或光斑整形,所述第二光学系统(将激发光耦合、聚焦到被测空间,所述第三光学系统将收集到的拉曼散射光汇聚到所述狭缝,所述色散模块实现拉曼光谱的色散,并将分离后的光谱信息传递到所述探测器。Further, the first optical system can realize collimation or spot shaping of the semiconductor laser light source, the second optical system (coupling and focusing the excitation light into the measured space, and the third optical system collects The Raman scattered light converges to the slit, and the dispersion module realizes the dispersion of the Raman spectrum, and transmits the separated spectral information to the detector.

进一步的,所述第一光学系统与体布拉格光栅的位置可以互换。Further, the positions of the first optical system and the volume Bragg grating can be interchanged.

进一步的,所述半导体制冷器(TEC)可同时控制所述半导体激光光源和所述探测器,也可使用两个所述TEC分别控制。Further, the semiconductor refrigerator (TEC) can control the semiconductor laser light source and the detector at the same time, or use the two TECs to control them separately.

进一步的,所述光源驱动控制模块用于驱动所述半导体激光光源,并通过所述光电探测器组成的反馈系统,控制所述半导体激光光源输出功率的稳定性。所述光电探测器带有窄带滤波功能,可以消除拉曼散射光谱对探测器接收信号的影响。Further, the light source drive control module is used to drive the semiconductor laser light source, and control the stability of the output power of the semiconductor laser light source through a feedback system composed of the photodetectors. The photodetector has a narrow-band filtering function, which can eliminate the influence of the Raman scattering spectrum on the signal received by the detector.

进一步的,所述分析处理模块用于控制探测器,并分析处理所述探测器接收到的信息用于系统输出。Further, the analysis and processing module is used to control the detector, and analyze and process the information received by the detector for system output.

本发明的工作原理是:光源驱动控制模块驱动控制激光光源产生激发光,激发光依次通过第一光学系统、体布拉格光栅、双色镜、第二光学系统、保护窗口,第二光学系统将激发光聚焦于被测样品,被测样品被激发光激发后发生拉曼散射,所产生的拉曼散射光连同瑞利散射光一起反方向透过保护窗口进入拉曼光机系统,由第二光学系统收集,再经过双色镜后,通过长波通滤光片滤除瑞利散射光,所剩的拉曼散射光通过第三光学系统汇聚到狭缝上。经狭缝滤波之后进入色散模块实现光谱分离,在经由探测器接收,通过后续的分析处理模块对接收信号进行分析处理。壳体中安装的半导体制冷器实现对整个系统的温度控制。The working principle of the present invention is: the light source drive control module drives and controls the laser light source to generate excitation light, and the excitation light passes through the first optical system, volume Bragg grating, dichromatic mirror, second optical system, and protective window in sequence, and the second optical system converts the excitation light Focusing on the measured sample, Raman scattering occurs after the measured sample is excited by the excitation light, and the generated Raman scattered light and Rayleigh scattered light pass through the protective window in the opposite direction and enter the Raman optical-mechanical system. The second optical system After being collected and passed through a dichroic mirror, the Rayleigh scattered light is filtered out by a long-wave pass filter, and the remaining Raman scattered light is converged onto the slit through a third optical system. After slit filtering, it enters the dispersion module to realize spectral separation, and after being received by the detector, the received signal is analyzed and processed by the subsequent analysis and processing module. The semiconductor refrigerator installed in the casing realizes the temperature control of the whole system.

采用上述结构后,本发明的有益效果为:减少了激光光源、激发接收模块及光谱分析模块的前期封装工艺和结构,显著缩小光机系统的体积,并降低了拉曼光机系统的成本;它采用光源、激接收模块,光谱分析模块统一的结构,提高了光源的能量利用率,并减少设备中的器件,进一步简化设备结构,降低成本,非常有利于设备的小型化和性能的提高。After adopting the above-mentioned structure, the beneficial effects of the present invention are: reducing the pre-packaging process and structure of the laser light source, the excitation receiving module and the spectrum analysis module, significantly reducing the volume of the optical-mechanical system, and reducing the cost of the Raman optical-mechanical system; It adopts a unified structure of light source, excitation receiving module, and spectral analysis module, which improves the energy utilization rate of the light source, reduces the components in the equipment, further simplifies the equipment structure, reduces the cost, and is very conducive to the miniaturization of the equipment and the improvement of performance.

附图说明Description of drawings

图1所示为根据本发明的实施例的一体式拉曼光机系统的示意图。FIG. 1 is a schematic diagram of an integrated Raman optomechanical system according to an embodiment of the present invention.

具体实施方式detailed description

根据本发明的一体式拉曼光机系统,结构包括:半导体激光光源、第一光学系统、体布拉格光栅、双色镜、第二光学系统、保护窗口、长波通滤光片、第三光学系统、狭缝、色散模块、探测器、分析处理模块、半导体制冷器TEC、壳体、光电探测器、光源驱动控制模块。According to the integrated Raman optical-mechanical system of the present invention, the structure includes: a semiconductor laser light source, a first optical system, a volume Bragg grating, a dichroic mirror, a second optical system, a protective window, a long-wave pass filter, a third optical system, Slit, dispersion module, detector, analysis and processing module, semiconductor cooler TEC, shell, photodetector, light source drive control module.

所述第一光学系统、体布拉格光栅、双色镜、第二光学系统、保护窗口依次共轴设置构成激发光路,激光光源共轴设置在激发光路的前端;所述长波通滤光片、第三光学系统、狭缝共轴设置构成收集光路,与激发光路垂直放置,所述色散模块、探测器构成光谱分析光路,位于收集光路的末端。The first optical system, the volume Bragg grating, the dichroic mirror, the second optical system, and the protection window are arranged coaxially in sequence to form an excitation light path, and the laser light source is coaxially arranged at the front end of the excitation light path; the long-wave pass filter, the third The coaxial arrangement of the optical system and the slit constitutes a collection light path, which is placed perpendicularly to the excitation light path, and the dispersion module and the detector constitute a spectral analysis light path, which are located at the end of the collection light path.

所述的激光光源为半导体激光器或能产生激发光的光源。The laser light source is a semiconductor laser or a light source capable of generating excitation light.

所述的双色镜对激发光具有高透过率,对被测样品产生的拉曼散射光具有高反射率,它在光路中正向透过激发光,背向透过瑞利散射光并反射拉曼散射光。The dichroic mirror has a high transmittance to the excitation light and a high reflectance to the Raman scattered light generated by the sample to be measured. It transmits the excitation light forward in the optical path, transmits the Rayleigh scattered light back and reflects the Raman Scattered light.

所述的第一光学系统、第二光学系统、第三光学系统可以是球面透镜、非球面透镜或球面、非球面透镜、柱面镜、棱镜等组成的镜组;所述第一光学系统的作用是实现所述半导体激光光源的准直或光斑整形;所述第二光学系统的作用是将激发光耦合、聚焦到被测空间,并收集拉曼散射信号;所述第三光学系统的作用是将收集到的拉曼散射光汇聚到所述狭缝。所述色散模块实现拉曼光谱的色散,并将分离后的光谱信息传递到所述探测器。The first optical system, the second optical system, and the third optical system can be spherical lenses, aspheric lenses, or spherical, aspheric lenses, cylindrical mirrors, prisms, etc.; The function is to realize the collimation or spot shaping of the semiconductor laser light source; the function of the second optical system is to couple and focus the excitation light to the measured space, and collect Raman scattering signals; the function of the third optical system is to converge the collected Raman scattered light to the slit. The dispersion module realizes the dispersion of the Raman spectrum, and transmits the separated spectrum information to the detector.

所述的保护窗口上镀有对激发光和被测样品产生的拉曼散射光都具有高透过率的增透膜;它的作用是对拉曼光机系统进行密封和保护。The protective window is coated with an anti-reflection film with high transmittance for both the excitation light and the Raman scattered light generated by the measured sample; its function is to seal and protect the Raman optical-mechanical system.

所述第一光学系统与体布拉格光栅的位置可以互换。The positions of the first optical system and the volume Bragg grating can be interchanged.

所述半导体制冷器(TEC)可同时控制所述半导体激光光源和所述探测器,也可使用两个所述TEC分别控制。The semiconductor refrigerator (TEC) can control the semiconductor laser light source and the detector at the same time, or use the two TECs to control them separately.

进一步的,所述光源驱动控制模块用于驱动所述半导体激光光源,并通过所述光电探测器组成的反馈系统,控制所述半导体激光光源输出功率的稳定性。所述光电探测器带有窄带滤波功能,可以消除拉曼散射光谱对探测器接收信号的影响。Further, the light source drive control module is used to drive the semiconductor laser light source, and control the stability of the output power of the semiconductor laser light source through a feedback system composed of the photodetectors. The photodetector has a narrow-band filtering function, which can eliminate the influence of the Raman scattering spectrum on the signal received by the detector.

进一步的,所述分析处理模块用于控制探测器,并分析处理所述探测器接收到的信息用于系统输出。Further, the analysis and processing module is used to control the detector, and analyze and process the information received by the detector for system output.

本实施例的工作原理是:光源驱动控制模块控制激光光源产生的激发光依次通过第一光学系统、体布拉格光栅、双色镜、第二光学系统、保护窗口,第二光学系统将激发光聚焦于被测样品,被测样品被激发光激发后发生拉曼散射,所产生的拉曼散射光连同瑞利散射光一起反方向透过保护窗口进入拉曼光机系统,由第二光学系统收集,再经过双色镜后,通过长波通滤光片滤除瑞利散射光,所剩的拉曼散射光通过第三光学系统汇聚到狭缝上。经狭缝滤波之后进入色散模块,色散模块实现拉曼光谱的分离和传递,经由探测器接收,通过后续的分析处理模块对接收信号进行处理。壳体中安装的半导体制冷器实现对整个系统的温度控制。 本实施例可实现高性能,小型化的拉曼光机系统。The working principle of this embodiment is: the light source driving control module controls the excitation light generated by the laser light source to pass through the first optical system, the volume Bragg grating, the dichroic mirror, the second optical system, and the protective window in sequence, and the second optical system focuses the excitation light on The sample to be tested, Raman scattering occurs after the sample is excited by the excitation light, and the generated Raman scattered light together with the Rayleigh scattered light enters the Raman optical mechanical system through the protective window in the opposite direction, and is collected by the second optical system. After passing through the dichroic mirror, the Rayleigh scattered light is filtered out by a long-wave pass filter, and the remaining Raman scattered light is converged onto the slit through a third optical system. After slit filtering, it enters the dispersion module. The dispersion module realizes the separation and transmission of the Raman spectrum, receives it through the detector, and processes the received signal through the subsequent analysis and processing module. The semiconductor refrigerator installed in the casing realizes the temperature control of the whole system. This embodiment can realize a high-performance, miniaturized Raman optical-mechanical system.

以上所述仅为本发明专利的优选实施例,并不用于限制本发明专利,对于本领域的技术人员,本发明专利可以有各种更改和变化。凡在本发明专利的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明专利的保护范围之内。The above descriptions are only preferred embodiments of the patent of the present invention, and are not intended to limit the patent of the present invention. For those skilled in the art, the patent of the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the patent for the present invention shall be included within the protection scope of the patent for the present invention.

Claims (8)

1. a kind of integral type Raman optical-mechanical system, it is characterised in that it includes semiconductor laser light resource(101), the first optical system (102), Volume Bragg grating(103), dichroic mirror (104), the second optical system (105), protecting window (106), the logical filter of long wave Mating plate (107), the 3rd optical system (108), slit(109), dispersion compensation module(110), detector(111), analysis and processing module (112)、TEC(113), housing(114), photodetector(115), light source drive control module(116).
A kind of 2. integral type Raman optical-mechanical system according to claim 1, it is characterised in that first optical system (102), Volume Bragg grating(103), dichroic mirror (104), the second optical system (105), protecting window (106) is coaxial successively sets Put composition excitation light path, the coaxial front end for being arranged on excitation light path of LASER Light Source (101);Long wave pass filter (107), the 3rd light System (108), slit(109), it is coaxial set form collect light path, be disposed vertically with excitation light path, dispersion compensation module(110)、 Detector(111)Spectrum analysis light path is formed, positioned at the end for collecting light path.
A kind of 3. integral type Raman optical-mechanical system according to claim 1, it is characterised in that the semiconductor laser light resource (101)Without fiber coupling, directly pass through optical system and long wave pass filter (107), dispersion compensation module(110)Integrate together In housing(114)In, dry gas is full of in housing and is sealed.
A kind of 4. integral type Raman optical-mechanical system according to claim 1, it is characterised in that first optical system (102)The semiconductor laser light resource can be achieved(101)Collimation or spot shaping, second optical system(105)It will swash Luminous coupling, focus on detected space, the 3rd optical system(108)The Raman diffused light being collected into is converged to described narrow Seam(109), the dispersion compensation module(110)The dispersion of Raman spectrum is realized, and the spectral information after separation is delivered to the spy Survey device(111).
A kind of 5. integral type Raman optical-mechanical system according to claim 1, it is characterised in that first optical system (102)With Volume Bragg grating(103)Position can exchange.
6. a kind of integral type Raman optical-mechanical system according to claim 1, it is characterised in that it also includes being used for temperature control The semiconductor cooler of system(TEC)(113), the semiconductor laser light resource can be controlled simultaneously(101)With the detector (111), it is possible to use two TEC are controlled respectively.
A kind of 7. integral type Raman optical-mechanical system according to claim 1, it is characterised in that the light source drive control mould Block(116)For driving the semiconductor laser light resource(101), and pass through the photodetector(115)The feedback system of composition System, controls the semiconductor laser light resource(101)The stability of power output;The photodetector(115)Filtered with arrowband Wave energy, influence of the raman scattering spectrum to detector reception signal can be eliminated.
A kind of 8. integral type Raman optical-mechanical system according to claim 1, it is characterised in that the analysis and processing module (112)For controlling detector(111), and analyze and process the detector(111)The information received exports for system.
CN201610687390.3A 2016-08-19 2016-08-19 A kind of integral type Raman optical-mechanical system Pending CN107643275A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610687390.3A CN107643275A (en) 2016-08-19 2016-08-19 A kind of integral type Raman optical-mechanical system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610687390.3A CN107643275A (en) 2016-08-19 2016-08-19 A kind of integral type Raman optical-mechanical system

Publications (1)

Publication Number Publication Date
CN107643275A true CN107643275A (en) 2018-01-30

Family

ID=61110080

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610687390.3A Pending CN107643275A (en) 2016-08-19 2016-08-19 A kind of integral type Raman optical-mechanical system

Country Status (1)

Country Link
CN (1) CN107643275A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108489613A (en) * 2018-02-05 2018-09-04 中国科学院长春光学精密机械与物理研究所 A kind of volume holographic grating type space heterodyne Raman spectroscopy instrument light channel structure
CN112834480A (en) * 2020-12-31 2021-05-25 中国科学院合肥物质科学研究院 A confocal Raman system for high-pressure, room-temperature and low-temperature experiments and its measurement method
WO2021134129A1 (en) 2019-12-31 2021-07-08 Tornado Spectral Systems Inc. Apparatus and method for reducing interference in an optical spectroscopy probe having a collimated sample beam

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05273081A (en) * 1992-03-27 1993-10-22 Nkk Corp Measurement method and device using otdr
US20050248758A1 (en) * 2004-05-07 2005-11-10 Carron Keith T Raman spectrometer
CN101968381A (en) * 2009-06-11 2011-02-09 必达泰克光电设备(上海)有限公司 Raman spectroscopic apparatus and method for measuring raman spectrum containing fluorescent materials
US20130162989A1 (en) * 2010-06-25 2013-06-27 Nuctech Company Limited Method for Automatically Calibrating a Raman Spectrum Detection System and Raman Spectrum Detection System
CN103196889A (en) * 2013-04-16 2013-07-10 许春 Portable raman spectrometer based on spectral analysis of micro electro mechanical system
CN103776815A (en) * 2014-02-24 2014-05-07 南京派光信息技术有限公司 Portable adjustable Raman probe
CN104949958A (en) * 2015-06-26 2015-09-30 北京杏林睿光科技有限公司 Novel Raman probe based on optical fiber beam splitter
CN105092560A (en) * 2015-09-14 2015-11-25 哈尔滨工业大学 Device and method for detecting signal intensity of frequency-shift excitation raman spectrum based on tunable laser
US20150346102A1 (en) * 2014-06-03 2015-12-03 Innovative Photonic Solutions, Inc. Compact Raman Probe Integrated with Wavelength Stabilized Diode Laser Source
CN205426795U (en) * 2016-03-23 2016-08-03 北京杏林睿光科技有限公司 From novel raman probe who takes light source
CN206038538U (en) * 2016-08-19 2017-03-22 北京杏林睿光科技有限公司 Integral type raman ray apparatus system

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05273081A (en) * 1992-03-27 1993-10-22 Nkk Corp Measurement method and device using otdr
US20050248758A1 (en) * 2004-05-07 2005-11-10 Carron Keith T Raman spectrometer
CN101968381A (en) * 2009-06-11 2011-02-09 必达泰克光电设备(上海)有限公司 Raman spectroscopic apparatus and method for measuring raman spectrum containing fluorescent materials
US20130162989A1 (en) * 2010-06-25 2013-06-27 Nuctech Company Limited Method for Automatically Calibrating a Raman Spectrum Detection System and Raman Spectrum Detection System
CN103196889A (en) * 2013-04-16 2013-07-10 许春 Portable raman spectrometer based on spectral analysis of micro electro mechanical system
CN103776815A (en) * 2014-02-24 2014-05-07 南京派光信息技术有限公司 Portable adjustable Raman probe
US20150346102A1 (en) * 2014-06-03 2015-12-03 Innovative Photonic Solutions, Inc. Compact Raman Probe Integrated with Wavelength Stabilized Diode Laser Source
CN104949958A (en) * 2015-06-26 2015-09-30 北京杏林睿光科技有限公司 Novel Raman probe based on optical fiber beam splitter
CN105092560A (en) * 2015-09-14 2015-11-25 哈尔滨工业大学 Device and method for detecting signal intensity of frequency-shift excitation raman spectrum based on tunable laser
CN205426795U (en) * 2016-03-23 2016-08-03 北京杏林睿光科技有限公司 From novel raman probe who takes light source
CN206038538U (en) * 2016-08-19 2017-03-22 北京杏林睿光科技有限公司 Integral type raman ray apparatus system

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
方祖捷等: "单频半导体激光器-原理、技术和应用", 30 September 2015, 上海交通大学出版社, pages: 118 - 123 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108489613A (en) * 2018-02-05 2018-09-04 中国科学院长春光学精密机械与物理研究所 A kind of volume holographic grating type space heterodyne Raman spectroscopy instrument light channel structure
CN108489613B (en) * 2018-02-05 2019-11-05 中国科学院长春光学精密机械与物理研究所 A kind of volume holographic grating type space heterodyne Raman spectroscopy instrument light channel structure
WO2021134129A1 (en) 2019-12-31 2021-07-08 Tornado Spectral Systems Inc. Apparatus and method for reducing interference in an optical spectroscopy probe having a collimated sample beam
EP4085237A4 (en) * 2019-12-31 2024-05-08 Tornado Spectral Systems, Inc. Apparatus and method for reducing interference in an optical spectroscopy probe having a collimated sample beam
CN112834480A (en) * 2020-12-31 2021-05-25 中国科学院合肥物质科学研究院 A confocal Raman system for high-pressure, room-temperature and low-temperature experiments and its measurement method
CN112834480B (en) * 2020-12-31 2023-02-03 中国科学院合肥物质科学研究院 A confocal Raman system and measurement method for high-pressure room temperature and low temperature experiments

Similar Documents

Publication Publication Date Title
CN101514964B (en) A material detector based on Raman spectroscopy
CN106225926B (en) One kind miniaturization laser Raman spectrometer
CN102998295A (en) Miniature Raman spectrometer
CN110763671B (en) Small-sized frequency shift excitation Raman detection device
CN101701913B (en) A multi-probe optical fiber evanescent wave biosensor with all-fiber structure
CN103196889A (en) Portable raman spectrometer based on spectral analysis of micro electro mechanical system
CN113624644B (en) Optical detection system and blood cell analyzer
CN104251819A (en) Photoacoustic spectrometry gas detection apparatus based on infrared light source
CN212845402U (en) Optical detection system for analyzing blood cells and blood cell analyzer
CN201045610Y (en) Visible light, near infrared light spectral analysis measuring instrument
CN104422681A (en) Raman spectrometer
CN110530793B (en) Integrated Fourier transform photoluminescence spectrometer
CN107643275A (en) A kind of integral type Raman optical-mechanical system
CN102590156A (en) In-situ integrated multi-spectrum measurement system and detection method
EP1159588A1 (en) Compact and robust spectrograph
CN110320197A (en) Microminiature Raman blood specialized analyzer based on Raman spectrum analysis
CN102495040B (en) Raman spectrometer chip adopting arrayed waveguide grating
CN109520944A (en) A kind of universal spectroscopic analysis system
CN105675581A (en) Raman scattering collection device for gas in free space
US20100294951A1 (en) Sensitive gas-phase flourimeter at ambient pressure for nitrogen dioxide
CN108254075A (en) A kind of micro integrated CMOS fiber spectrometers
CN110530783B (en) Lateral beam collection method and device for flow cytometer and flow cytometer
CN213275352U (en) Raman signal collecting probe based on off-axis parabolic reflector
CN102507004A (en) Raman spectrometer chip capable of improving spectral resolution near characteristic peak
CN207215699U (en) A kind of universal spectroscopic analysis system

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180130

RJ01 Rejection of invention patent application after publication