CN107629824A - A kind of vehicle lead-free synthetic fuel - Google Patents
A kind of vehicle lead-free synthetic fuel Download PDFInfo
- Publication number
- CN107629824A CN107629824A CN201610562735.2A CN201610562735A CN107629824A CN 107629824 A CN107629824 A CN 107629824A CN 201610562735 A CN201610562735 A CN 201610562735A CN 107629824 A CN107629824 A CN 107629824A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- synthetic fuel
- acid
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 75
- -1 polyoxypropylene Polymers 0.000 claims abstract description 32
- 239000000654 additive Substances 0.000 claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 230000000996 additive effect Effects 0.000 claims abstract description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 18
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 15
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 9
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 9
- 239000005642 Oleic acid Substances 0.000 claims abstract description 9
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- 229910052788 barium Inorganic materials 0.000 claims abstract description 9
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001273 butane Substances 0.000 claims abstract description 9
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 9
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 9
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 9
- 239000012188 paraffin wax Substances 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 229920002545 silicone oil Polymers 0.000 claims abstract description 9
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims abstract description 9
- 238000004073 vulcanization Methods 0.000 claims abstract description 9
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 8
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 7
- NFIYTPYOYDDLGO-UHFFFAOYSA-N phosphoric acid;sodium Chemical compound [Na].OP(O)(O)=O NFIYTPYOYDDLGO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003502 gasoline Substances 0.000 claims description 28
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- 239000002270 dispersing agent Substances 0.000 claims description 13
- 239000008139 complexing agent Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 5
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 4
- 229930185605 Bisphenol Natural products 0.000 claims description 4
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 4
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000003225 biodiesel Substances 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- CLLSOFHOYCGNJP-UHFFFAOYSA-N carbon monoxide cyclopenta-1,3-diene manganese Chemical compound [Mn].[C]=O.[C]=O.[C]=O.C1C=CC=C1 CLLSOFHOYCGNJP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003610 charcoal Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical group COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims 1
- 241000219000 Populus Species 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- AVVIDTZRJBSXML-UHFFFAOYSA-L calcium;2-carboxyphenolate;dihydrate Chemical compound O.O.[Ca+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O AVVIDTZRJBSXML-UHFFFAOYSA-L 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 229950001362 tebutate Drugs 0.000 claims 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 229960004025 sodium salicylate Drugs 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 239000000295 fuel oil Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 240000000203 Salix gracilistyla Species 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical group COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- ITFCTBFBEKRKDC-UHFFFAOYSA-N [O].OC Chemical compound [O].OC ITFCTBFBEKRKDC-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of vehicle lead-free synthetic fuel, is consisted of the following composition:The methanol of 40~60 parts by weight;The fatty alcohol polyoxypropylene ether of 10~30 parts of parts by weight;The butane of 6.5~17 parts by weight;The aliphatic acid ammonium of 1~5 part of parts by weight;The barium sulfonate of 0.2~1 parts by weight;The stabilizer of 0.8 1.5 parts by weight;The parts by weight of the parts by weight of peracetic acid spy butyl ester 2~3, the parts by weight of oleic acid 5~7, MTBE5~7, the parts by weight of paraffin 3~6;The phosphate of 0.2~1 part of parts by weight;The vulcanization butylene of 0.2~1 parts by weight;The methyl-silicone oil of 1.2~2 parts by weight;1~5 parts by weight of phosphoric acid sodium;The parts by weight of ethylene glycol 1, the hydrogen peroxide of 0.5 0.9 parts by weight, the 2 of 0.5 0.9 parts by weight, 6 BHTs, the compound additive of 1.2~2 parts by weight, the temperature range of preparation is+20 DEG C~20 DEG C.
Description
Technical field
The invention discloses a kind of liquid fuel, specifically a kind of vehicle lead-free synthetic fuel.
Background technology
Conventional gasoline process technology is fractionated using the different boiling of heterogeneity in crude oil, fractionates out different productions
Product, such as:Natural gas, gasoline, diesel oil, heavy oil and pitch etc., or be catalyzed, cracking, the technique productions such as reformation require higher
Fuel oil, such as aviation kerosine.But conventionally produced out different boiling, the product oil of different proportion tend not to meet
The substantial amounts of demand in market simultaneously expends crude oil significantly, increases the cost of cost crude, therefore, gasoline is developed according to this market demand
Additive technology, it is added directly into product oil, generates the label gasoline of daily need, so as to reduces the usage amount of crude oil.
In addition, with the raising of people's environmental protection consciousness, vehicle emission pollution problem is increasingly taken seriously.Europe, the United States,
Japan and China in succession proposes this country new gasoline standard, its to sulfur content, benzene content, arene content, olefin(e) centent and
Oxygen content is proposed strict regulation and limitation.Because motor vehicle emission is one of atmosphere pollution main source, vehicular emission
Contaminant capacity to account for atmosphere pollution ratio in rising trend always, as China's automobile production amount and recoverable amount constantly increase, discharge
Regulation is increasingly strict, and society is to improving fuel oil quality, more and more high using the cry of clean fuel.
In order to further reduce the tail gas pollution brought due to incomplete combustion, people gradually make oxygen containing clean fuel
For the important directions of the research of fuel from now on, it is concentrated mainly on using alcohols and ethers and is used as gasoline addO-on therapy.Because of the methanol amount of being
The industrial chemicals being easy to get greatly, so, methanol turns into main research direction as the utilization of motor vehicle fuel, but a large amount of real
Verify bright:Methanol directly can not be used for automobile engine fuel instead of gasoline, because the lower boiling influence of methanol, directly
Have influence on the startup and acceleration of automobile.Therefore, it is often miscible using methanol and gasoline in the research of high-clean gasoline, and add
Associated additives.
Chinese patent 200410054960.2 discloses a kind of blended gasoline containing methanol, and its component includes:Naphtha,
Mixed xylenes, toluene, methanol, isopropanol, C9+ petroleum hydrocarbons, isopentane, methyl tertiary butyl ether(MTBE) or and tertbutyl ether.It is this
The shortcomings that blended gasoline, is, higher as the content of the naphtha of raw material using oil, is so reducing oil consumption, is reducing to oil
Dependence in terms of effect be not it is obvious that in addition, methyl tertiary butyl ether(MTBE) selected in component, because the characteristic of itself causes
It easily enters underground water through soil, and just has strong peculiar smell containing a small amount of methyl tertiary butyl ether(MTBE) in drinking water, if
Human body, which sucks a small amount of methyl tertiary butyl ether(MTBE), will produce stimulation nose and throat, cause headache, nausea and dizziness.So from
Methyl tertiary butyl ether(MTBE) is very undesirable as the environment protecting of blend component.
Further, since methanol gasoline is usually present immiscible, lamination in configuration, part evaporation when in use causes
Vapour lock makes engine operating intermittency occur, is short of power, and methanol and the mixing of other gasoline it is immiscible, layering etc. is existing
As, it is difficult to produce and promote on a large scale.
The purpose of the present invention is aiming at disadvantage mentioned above, there is provided a kind of methanol usage is big, and production cost is low, not stratified, property
Can be stable, octane number is high, no vapour lock, and the high-clean gasoline that can be used in mixed way with other conventional gasoline arbitrary proportions.
The content of the invention
The purpose of invention be to provide for it is a kind of based on regenerated resources, reduce atmosphere pollution, save national foreign exchange and disappear
Alcohol synthetic fuel consume, used ethanol to be prepared for primary raw material and preparation method thereof.
The object of the present invention is achieved like this, a kind of vehicle lead-free synthetic fuel, consists of the following composition:40~60 weights
Measure the methanol of part;The fatty alcohol polyoxypropylene ether of 10~30 parts of parts by weight;The butane of 6.5~17 parts by weight;1~5 part of parts by weight
Aliphatic acid ammonium;The barium sulfonate of 0.2~1 parts by weight;The stabilizer of 0.8-1.5 parts by weight;The weight of peracetic acid spy butyl ester 2~3
Measure part, the parts by weight of oleic acid 5~7, the parts by weight of MTBE5~7, the parts by weight of paraffin 3~6;The phosphate of 0.2~1 part of parts by weight;0.2
The vulcanization butylene of~1 parts by weight;The methyl-silicone oil of 1.2~2 parts by weight;1~5 parts by weight of phosphoric acid sodium;The parts by weight of ethylene glycol 1,
The hydrogen peroxide of 0.5-0.9 parts by weight, the BHT of 0.5-0.9 parts by weight, 1.2~2 parts by weight it is compound
Additive, the temperature range of preparation are+20 DEG C~-20 DEG C, described compound additive, with the gross weight meter of compound additive,
It is made up of following components by proportioning:The complexing agent 0.5% of 15%~20% benzene-like compounds of multiple-effect energizer 30%~41%~
The higher alcohols 16%~19% of 24% ether compound, 8%~24% detergent-dispersant additive 0.7%~1.2%, its summation are 100%.
Described multiple-effect energizer is dimethoxymethane, cyclopentadiene tricarbonyl manganese, ferrocene, nitric acid lipoid substance
In two or more mixture.
Described benzene-like compounds are toluene, dimethylbenzene, any one in ortho-xylene or two kinds of mixtures.
Described complexing agent is the sub- bigcatkin willow propane diamine of N, N ' two, 4,4- methylene bis-phenols, dimeric dibasic acid, fatty acid ester, carbonic acid
Two or more mixture in fat.
Described ether compound is the mixture of isopropyl ether or methyl tertiary butyl ether(MTBE) or both.
Described detergent-dispersant additive is alkyl sodium salicylate, dichloroethanes, METHYLPYRROLIDONE, gasoline detergent point
Any two kinds of mixtures in powder, the alkyl in described alkyl sodium salicylate are methyl, ethyl, propyl group, appointing in butyl
Meaning is a kind of.
Described more charcoal alcohol are isopropyl acetone, n-butanol, isobutanol, two or more any mixture in acetone.
The preparation method for the synthetic fuel stated, step are as follows:
1st step, by weight, by fat methanol;The fatty alcohol polyoxypropylene ether of 10~30 parts of parts by weight;6.5~17 weights
Measure the butane of part;The aliphatic acid ammonium of 1~5 part of parts by weight;The barium sulfonate of 0.2~1 parts by weight;The stabilizer of 0.8-1.5 parts by weight;
The parts by weight of the parts by weight of peracetic acid spy butyl ester 2~3, the parts by weight of oleic acid 5~7, MTBE5~7, the parts by weight of paraffin 3~6;0.2~
The phosphate of 1 part of parts by weight;The vulcanization butylene of 0.2~1 parts by weight;The methyl-silicone oil of 1.2~2 parts by weight;1~5 parts by weight phosphorus
Sour sodium;The parts by weight of ethylene glycol 1, the hydrogen peroxide of 0.5-0.9 parts by weight, the BHT of 0.5-0.9 parts by weight,
After well mixed, 30~40 DEG C of dissolvings are heated to, are stirred;
2nd step, following components are by proportioning:The complexing agent of 15%~20% benzene-like compounds of multiple-effect energizer 30%~41%
The higher alcohols 16%~19% of 0.5%~24% ether compound, 8%~24% detergent-dispersant additive 0.7%~1.2%, its summation are
100%, it is well mixed, is warming up to 40~50 DEG C, 1~3h is incubated under agitation, after letting cool, you can;The use of described additive
Amount is the 0.5%~1% of biodiesel weight;The material of the 1st step of mixed material and mediation is sufficiently mixed uniformly.
Institute's Pass through above-mentioned technical proposal of the present invention, because the main component in raw material employs reproducible methanol and second
Alcohol, and be incorporated a small amount of industrial chemicals, then synthesis is simply made by science, produced thing fuel after testing, its fuel value
1.1 ten thousand kilocalories are can reach, hydrocarbon and a discharge capacity aoxidized are extremely low, and calorific value is suitable with current gasoline, can directly apply
Used in existing automobile engine as power fuel, raw material needed for the present invention easily obtains, and manufacturing process is simple, has fabulous
Popularizing application prospect.
Using the present invention of as above technical scheme, had the advantages that relative to prior art:
1. the product belongs to universal high-cleanness fuel oil, do not need to adjust engine, can be random as regular gasoline
Use.I.e. operation is easy, easy to use.
2. explosive force is strong, octane number is high, the capability of antidetonance is good, so as to improve the power performance of engine.
3. energy-conserving and environment-protective, methanol oxygen content are up to 50%, promote full combustion of fuel complete, make motor vehicle exhaust emission has
Evil material reduces by 20 " --- -50%, atmosphere pollution can be reduced, is advantageous to energy-conserving and environment-protective.
4. good economy performance, methanol fuel are lower than oil-fired cost, the alternative 1 ton of common gasoline product of 1.5 tons of methanol,
Its efficiency ratio improves about 5-8 times using coal, than reducing 20-----'50% using the cost of regular gasoline.
5. the raw material used are mostly cheap twice laid, very objective with waste becoming treasure, economic benefit!
6. intersolubility is good, capability and performance is stable, holding time length, is adapted to long-distance transport.
Embodiment
It is as follows for the more detailed elaboration present invention, the one embodiment of the invention:
Embodiment 1
A kind of vehicle lead-free synthetic fuel, is consisted of the following composition:The methanol of 60 parts by weight;The fatty alcohol of 30 parts of parts by weight
Polyethenoxy ether;The butane of 17 parts by weight;The aliphatic acid ammonium of 5 parts of parts by weight;The barium sulfonate of 1 parts by weight;The stabilization of 1.5 parts by weight
Agent;The parts by weight of peracetic acid spy butyl ester 3, the parts by weight of oleic acid 7, MTBE7 parts by weight, the parts by weight of paraffin 6;The phosphorus of 1 part of parts by weight
Acid esters;The vulcanization butylene of 1 parts by weight;The methyl-silicone oil of 2 parts by weight;5 parts by weight of phosphoric acid sodium;The parts by weight of ethylene glycol 1,0.9 weight
The hydrogen peroxide of part, the BHT of 0.9 parts by weight, the compound additive of 2 parts by weight, the temperature range of preparation
For+20 DEG C~-20 DEG C, described compound additive, with the gross weight meter of compound additive, it is made up of following components by proportioning:
The ether compound 8%~24% of 15%~20% benzene-like compounds of multiple-effect energizer, 30%~41% complexing agent 0.5%~24%
The higher alcohols 16%~19% of detergent-dispersant additive 0.7%~1.2%, its summation are 100%.
Described multiple-effect energizer is dimethoxymethane, cyclopentadiene tricarbonyl manganese, ferrocene, nitric acid lipoid substance
In two or more mixture.
Described benzene-like compounds are toluene, dimethylbenzene, any one in ortho-xylene or two kinds of mixtures.
Described complexing agent is the sub- bigcatkin willow propane diamine of N, N ' two, 4,4- methylene bis-phenols, dimeric dibasic acid, fatty acid ester, carbonic acid
Two or more mixture in fat.
Described ether compound is the mixture of isopropyl ether or methyl tertiary butyl ether(MTBE) or both.
Described detergent-dispersant additive is alkyl sodium salicylate, dichloroethanes, METHYLPYRROLIDONE, gasoline detergent point
Any two kinds of mixtures in powder, the alkyl in described alkyl sodium salicylate are methyl, ethyl, propyl group, appointing in butyl
Meaning is a kind of.
Described more charcoal alcohol are isopropyl acetone, n-butanol, isobutanol, two or more any mixture in acetone.
The preparation method for the synthetic fuel stated, step are as follows:
1st step, by weight, by fat methanol;The fatty alcohol polyoxypropylene ether of 10~30 parts of parts by weight;6.5~17 weights
Measure the butane of part;The aliphatic acid ammonium of 1~5 part of parts by weight;The barium sulfonate of 0.2~1 parts by weight;The stabilizer of 0.8-1.5 parts by weight;
The parts by weight of the parts by weight of peracetic acid spy butyl ester 2~3, the parts by weight of oleic acid 5~7, MTBE5~7, the parts by weight of paraffin 3~6;0.2~
The phosphate of 1 part of parts by weight;The vulcanization butylene of 0.2~1 parts by weight;The methyl-silicone oil of 1.2~2 parts by weight;1~5 parts by weight phosphorus
Sour sodium;The parts by weight of ethylene glycol 1, the hydrogen peroxide of 0.5-0.9 parts by weight, the BHT of 0.5-0.9 parts by weight,
After well mixed, 30~40 DEG C of dissolvings are heated to, are stirred;
2nd step, following components are by proportioning:The complexing agent of 15%~20% benzene-like compounds of multiple-effect energizer 30%~41%
The higher alcohols 16%~19% of 0.5%~24% ether compound, 8%~24% detergent-dispersant additive 0.7%~1.2%, its summation are
100%, it is well mixed, is warming up to 40~50 DEG C, 1~3h is incubated under agitation, after letting cool, you can;The use of described additive
Amount is the 0.5%~1% of biodiesel weight;The material of the 1st step of mixed material and mediation is sufficiently mixed uniformly.
Embodiment 2
A kind of vehicle lead-free synthetic fuel, is consisted of the following composition:The methanol of 40 parts by weight;The fatty alcohol of 10 parts of parts by weight
Polyethenoxy ether;6.5 the butane of parts by weight;The aliphatic acid ammonium of 1 part of parts by weight;The barium sulfonate of 0.2 parts by weight;0.8 parts by weight
Stabilizer;The parts by weight of peracetic acid spy butyl ester 2, the parts by weight of oleic acid 5, MTBE5 parts by weight, the parts by weight of paraffin 3;0.2 part of weight
The phosphate of part;The vulcanization butylene of 0.2 parts by weight;The methyl-silicone oil of 1.2 parts by weight;1 parts by weight of phosphoric acid sodium;The weight of ethylene glycol 1
Part, the hydrogen peroxide of 0.5 parts by weight, the BHT of 0.5 parts by weight, the compound additive of 1.2 parts by weight, match somebody with somebody
The temperature range of system is+20 DEG C~-20 DEG C, described compound additive, with the gross weight meter of compound additive, by following components
Formed by proportioning:The ethers chemical combination of 15%~20% benzene-like compounds of multiple-effect energizer, 30%~41% complexing agent 0.5%~24%
The higher alcohols 16%~19% of 8%~24% detergent-dispersant additive of thing 0.7%~1.2%, its summation are 100%.
Described multiple-effect energizer is dimethoxymethane, cyclopentadiene tricarbonyl manganese, ferrocene, nitric acid lipoid substance
In two or more mixture.
Described benzene-like compounds are toluene, dimethylbenzene, any one in ortho-xylene or two kinds of mixtures.
Described complexing agent is the sub- bigcatkin willow propane diamine of N, N ' two, 4,4- methylene bis-phenols, dimeric dibasic acid, fatty acid ester, carbonic acid
Two or more mixture in fat.
Described ether compound is the mixture of isopropyl ether or methyl tertiary butyl ether(MTBE) or both.
Described detergent-dispersant additive is alkyl sodium salicylate, dichloroethanes, METHYLPYRROLIDONE, gasoline detergent point
Any two kinds of mixtures in powder, the alkyl in described alkyl sodium salicylate are methyl, ethyl, propyl group, appointing in butyl
Meaning is a kind of.
Described more charcoal alcohol are isopropyl acetone, n-butanol, isobutanol, two or more any mixture in acetone.
The preparation method for the synthetic fuel stated, step are as follows:
1st step, by weight, by fat methanol;The fatty alcohol polyoxypropylene ether of 10~30 parts of parts by weight;6.5~17 weights
Measure the butane of part;The aliphatic acid ammonium of 1~5 part of parts by weight;The barium sulfonate of 0.2~1 parts by weight;The stabilizer of 0.8-1.5 parts by weight;
The parts by weight of the parts by weight of peracetic acid spy butyl ester 2~3, the parts by weight of oleic acid 5~7, MTBE5~7, the parts by weight of paraffin 3~6;0.2~
The phosphate of 1 part of parts by weight;The vulcanization butylene of 0.2~1 parts by weight;The methyl-silicone oil of 1.2~2 parts by weight;1~5 parts by weight phosphorus
Sour sodium;The parts by weight of ethylene glycol 1, the hydrogen peroxide of 0.5-0.9 parts by weight, the BHT of 0.5-0.9 parts by weight,
After well mixed, 30~40 DEG C of dissolvings are heated to, are stirred;
2nd step, following components are by proportioning:The complexing agent of 15%~20% benzene-like compounds of multiple-effect energizer 30%~41%
The higher alcohols 16%~19% of 0.5%~24% ether compound, 8%~24% detergent-dispersant additive 0.7%~1.2%, its summation are
100%, it is well mixed, is warming up to 40~50 DEG C, 1~3h is incubated under agitation, after letting cool, you can;The use of described additive
Amount is the 0.5%~1% of biodiesel weight;The material of the 1st step of mixed material and mediation is sufficiently mixed uniformly.
The product high-performance clean methanol gasoline of the present invention, raw material are easy to get, and wide material sources, cost is low, and oxygen content is high, calorific value
Height, octane number is high, can fully meet the power demand of automobile, by the high-performance clean methanol vapour of the above-mentioned several embodiments of the present invention
Oil is used as vehicle fuel, can reach the unleaded petrochemical industry gasoline requirements of more than 93#, and compared with gasoline, power improves 8%~12%,
Oil consumption save 3~5%, due to can fully burn, not coking, exhaust emissions carbon monoxide, nitrogen oxides, hydrocarbon compare vapour
Oil reduces 30%~90%, meets environmental requirement.The high-performance methanol gasoline of the present invention not only can be independent as vehicle fuel
Use, can also be used in mixed way, not limited by ratio with gasoline, and using when be not required to refiting engine.
Claims (8)
1. a kind of vehicle lead-free synthetic fuel, is consisted of the following composition:The methanol of 40~60 parts by weight;10~30 parts of parts by weight
Fatty alcohol polyoxypropylene ether;The butane of 6.5~17 parts by weight;The aliphatic acid ammonium of 1~5 part of parts by weight;The sulphur of 0.2~1 parts by weight
Sour barium;The stabilizer of 0.8-1.5 parts by weight;The parts by weight of peracetic acid spy butyl ester 2~3, the parts by weight of oleic acid 5~7, MTBE5~7
Parts by weight, the parts by weight of paraffin 3~6;The phosphate of 0.2~1 part of parts by weight;The vulcanization butylene of 0.2~1 parts by weight;1.2~2 weights
Measure the methyl-silicone oil of part;1~5 parts by weight of phosphoric acid sodium;The parts by weight of ethylene glycol 1, the hydrogen peroxide of 0.5-0.9 parts by weight, 0.5-0.9
The BHT of parts by weight, the compound additive of 1.2~2 parts by weight, the temperature range of preparation for+20 DEG C~-
20 DEG C, described compound additive, with the gross weight meter of compound additive, it is made up of following components by proportioning:Multiple-effect energizer
The detergent-dispersant additive of 15%~20% benzene-like compounds, 30%~41% complexing agent, 0.5%~24% ether compound 8%~24%
0.7%~1.2% higher alcohols 16%~19%, its summation are 100%.
2. vehicle lead-free synthetic fuel according to claim 1, it is characterised in that described multiple-effect energizer is dimethoxy
Methylmethane, cyclopentadiene tricarbonyl manganese, ferrocene, two or more mixture in nitric acid lipoid substance.
3. vehicle lead-free synthetic fuel according to claim 1, it is characterised in that described benzene-like compounds are toluene,
Dimethylbenzene, any one in ortho-xylene or two kinds of mixtures.
4. vehicle lead-free synthetic fuel according to claim 1, it is characterised in that described complexing agent is the sub- water of N, N ' two
Raise propane diamine, 4,4- methylene bis-phenols, dimeric dibasic acid, fatty acid ester, two or more mixture in carbonic ether.
5. vehicle lead-free synthetic fuel according to claim 1, it is characterised in that described ether compound is isopropyl ether
Or the mixture of methyl tertiary butyl ether(MTBE) or both.
6. vehicle lead-free synthetic fuel according to claim 1, it is characterised in that described detergent-dispersant additive is alkyl water
Poplar acid calcium, dichloroethanes, METHYLPYRROLIDONE, any two kinds of mixtures in cleaning dispersant for gasoline, described alkyl
Alkyl in calcium salicylate is methyl, ethyl, propyl group, any one in butyl.
7. vehicle lead-free synthetic fuel according to claim 1, it is characterised in that described more charcoal alcohol are isopropyl acetone, positive fourth
Alcohol, isobutanol, two or more any mixture in acetone.
8. the preparation method of the synthetic fuel described in claim 1, it is characterised in that step is as follows:
1st step, by weight, by fat methanol;The fatty alcohol polyoxypropylene ether of 10~30 parts of parts by weight;6.5~17 parts by weight
Butane;The aliphatic acid ammonium of 1~5 part of parts by weight;The barium sulfonate of 0.2~1 parts by weight;The stabilizer of 0.8-1.5 parts by weight;Peroxide
Change the parts by weight of tebutate 2~3 parts by weight, the parts by weight of oleic acid 5~7, MTBE5~7, the parts by weight of paraffin 3~6;0.2~1 part
The phosphate of parts by weight;The vulcanization butylene of 0.2~1 parts by weight;The methyl-silicone oil of 1.2~2 parts by weight;1~5 parts by weight of phosphoric acid
Sodium;The parts by weight of ethylene glycol 1, the hydrogen peroxide of 0.5-0.9 parts by weight, the BHT of 0.5-0.9 parts by weight, mix
After closing uniformly, 30~40 DEG C of dissolvings are heated to, are stirred;
2nd step, following components are by proportioning:The complexing agent 0.5% of 15%~20% benzene-like compounds of multiple-effect energizer 30%~41%
The higher alcohols 16%~19% of 8%~24% detergent-dispersant additive of~24% ether compound 0.7%~1.2%, its summation are
100%, it is well mixed, is warming up to 40~50 DEG C, 1~3h is incubated under agitation, after letting cool, you can;The use of described additive
Amount is the 0.5%~1% of biodiesel weight;The material of the 1st step of mixed material and mediation is sufficiently mixed uniformly.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610562735.2A CN107629824A (en) | 2016-07-18 | 2016-07-18 | A kind of vehicle lead-free synthetic fuel |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610562735.2A CN107629824A (en) | 2016-07-18 | 2016-07-18 | A kind of vehicle lead-free synthetic fuel |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107629824A true CN107629824A (en) | 2018-01-26 |
Family
ID=61112713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610562735.2A Pending CN107629824A (en) | 2016-07-18 | 2016-07-18 | A kind of vehicle lead-free synthetic fuel |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107629824A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109609215A (en) * | 2019-01-04 | 2019-04-12 | 顺德职业技术学院 | A kind of diesel engine exhaust gas purification additive and manufacturing method |
CN109609216A (en) * | 2019-01-04 | 2019-04-12 | 顺德职业技术学院 | A kind of additive for reducing diesel engine exhaust particulate matter emission and manufacturing method |
CN111732978A (en) * | 2020-06-02 | 2020-10-02 | 上海中太行之光能源有限公司 | Liquid nano combustion material and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1687325A (en) * | 2005-05-12 | 2005-10-26 | 吴家友 | Clean fuel of alcohol hydrocarbon for vehicle and preparation method |
CN101914394A (en) * | 2010-08-20 | 2010-12-15 | 李东升 | High-performance clean methanol gasoline |
CN103627446A (en) * | 2013-12-02 | 2014-03-12 | 济南开发区星火科学技术研究院 | Environment-friendly clean fuel oil and preparation method thereof |
CN103725332A (en) * | 2013-11-26 | 2014-04-16 | 沃太能源南通有限公司 | Preparation method of blend biodiesel applicable to alpine regions |
CN104403707A (en) * | 2014-09-26 | 2015-03-11 | 甘肃中奥石化有限公司 | Methanol fuel additive for cold plateau region and methanol fuel containing the additive |
CN105296018A (en) * | 2015-10-28 | 2016-02-03 | 杨金伟 | Preparation method of blend biodiesel suitable for use in high and cold areas |
-
2016
- 2016-07-18 CN CN201610562735.2A patent/CN107629824A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1687325A (en) * | 2005-05-12 | 2005-10-26 | 吴家友 | Clean fuel of alcohol hydrocarbon for vehicle and preparation method |
CN101914394A (en) * | 2010-08-20 | 2010-12-15 | 李东升 | High-performance clean methanol gasoline |
CN103725332A (en) * | 2013-11-26 | 2014-04-16 | 沃太能源南通有限公司 | Preparation method of blend biodiesel applicable to alpine regions |
CN103627446A (en) * | 2013-12-02 | 2014-03-12 | 济南开发区星火科学技术研究院 | Environment-friendly clean fuel oil and preparation method thereof |
CN104403707A (en) * | 2014-09-26 | 2015-03-11 | 甘肃中奥石化有限公司 | Methanol fuel additive for cold plateau region and methanol fuel containing the additive |
CN105296018A (en) * | 2015-10-28 | 2016-02-03 | 杨金伟 | Preparation method of blend biodiesel suitable for use in high and cold areas |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109609215A (en) * | 2019-01-04 | 2019-04-12 | 顺德职业技术学院 | A kind of diesel engine exhaust gas purification additive and manufacturing method |
CN109609216A (en) * | 2019-01-04 | 2019-04-12 | 顺德职业技术学院 | A kind of additive for reducing diesel engine exhaust particulate matter emission and manufacturing method |
CN111732978A (en) * | 2020-06-02 | 2020-10-02 | 上海中太行之光能源有限公司 | Liquid nano combustion material and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101121901A (en) | Methanol gasoline for vehicle | |
CN102660337A (en) | Method for preparing novel clean synthetic diesel oil | |
JP6428994B2 (en) | Clean, highly efficient and environmentally friendly gasoline and fuel products | |
CN101550363A (en) | Novel carbinol gasoline fuel | |
CN107629824A (en) | A kind of vehicle lead-free synthetic fuel | |
US20110232165A1 (en) | Fuel or fuel additive composition and method for its manufacture and use | |
US4300912A (en) | Synthetic fuel containing methanol and butanol | |
CN104726149A (en) | Bio-based methanol gasoline composite auxiliary and bio-based high-proportion methanol gasoline | |
CN101787309B (en) | Direct automobile-used M85 methanol gasoline | |
CN102827654A (en) | Cleaning fuel for vehicle | |
CN100577777C (en) | Alcohol ether for vehicles to replace clean fuel | |
CN101195769B (en) | Low-carbon mixed alcohol gasoline | |
CN104974804B (en) | A kind of preparation method of alcohol radical liquid fuel and alcohol radical liquid fuel additive | |
CN102051237B (en) | Preparation formula of high-cleanliness gasoline | |
CN115678623A (en) | Biomass liquid fuel | |
WO2011085659A1 (en) | Ether-based fuel | |
CN101760258A (en) | Component oil capable of reducing saturated vapor pressure of methanol gasoline | |
CN102585942B (en) | Concentration emulsified diesel fuel and preparation method thereof | |
CN107099347B (en) | A kind of ether diesel oil of clean and environmental protection and preparation method thereof | |
Mohsin et al. | Effect of Biodiesel Blend on Exhaust Emission and Engine Performance of Diesel Dual Fuel Engine (Research Note) | |
CN101012393A (en) | Biological liquid fuel and preparation method thereof | |
WO2011085662A1 (en) | Ether-based fuel | |
CN109705932A (en) | A kind of environmental protection and energy saving standard increasing agent | |
CN102127472A (en) | Ether fuel | |
WO2011085655A1 (en) | Ether-based fuel |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180126 |
|
RJ01 | Rejection of invention patent application after publication |