CN107613947A

CN107613947A - Spraying cosmetics

Info

Publication number: CN107613947A
Application number: CN201680031032.5A
Authority: CN
Inventors: 小林由佳; 桥本雅俊
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 2015-05-29
Filing date: 2016-05-25
Publication date: 2018-01-19
Also published as: WO2016194734A1; JP2017125003A; JP6730846B2; TW201707675A

Abstract

The present invention provides a kind of spraying cosmetics, and it contains：Stoste is integrally set to 100 mass % and includes following component (A), (B), (C), (D) and (E) stoste；And (F) includes more than the mass % of carbon dioxide 90 propellant, the mass % of finish 1~25 that the viscosity at the mass % of silicone elastomer powder 0.1~1.5 that (A) average grain diameter is 0.01~30 μm, 25 DEG C of (B) is 1~100mPas, the mass % of nonionic surfactant 0.05~6, the mass % of (D) tackifier 0.1~1, (E) water of (C) HLB3~20.

Description

Spraying cosmetics

Technical field

The present invention relates to one kind spraying cosmetics.

Background technology

Industry is in order to be stimulated circulation, warmed effect, massage effect and the atomization of research and utilization carbon dioxide Cosmetic.For example, recording the cosmetics for the blister for being combined with carbon dioxide in patent document 1, recorded in patent document 2 The foam cosmetics with warming effect containing carbon dioxide and solid fat.Also, recorded in patent document 3 using fine Bubble promote the percutaneous absorbtion of carbon dioxide just without sliminess cosmetics after just smearing out, recorded in patent document 4 Easily massage and the good aerosol type cosmetics of sense of touch after being rinsed after massage.

However, cosmetics described in patent document 1, patent document 2 have problem in terms of the extension of bubble, not yet set Want to make the bubble containing carbon dioxide affine with skin rapidly.Although described cosmetics steep fine and smooth and suppressed in patent document 3 It is sliminess but insufficient in terms of the extension in bubble or the infiltration sense to skin.Although described massage agent in patent document 4 Extension for massage is good, but does not contemplate the infiltration sense to skin.

(patent document 1) Japanese Patent Laid 2005-506325 publications

(patent document 2) Japanese Patent Laid-Open 2010-30945 publications

(patent document 3) Japanese Patent Laid-Open 2014-129306 publications

(patent document 4) Japanese Patent Laid-Open 2011-93877 publications

The content of the invention

The present invention relates to one kind spraying cosmetics, it contains：

Stoste is integrally set to 100 mass % and includes following component (A), (B), (C), (D) and (E) stoste；And (F) more than the mass % of carbon dioxide 90 propellant is included,

(A) average grain diameter be 0.01~30 μm the mass % of silicone elastomer powder 0.1~1.5,

The mass % of finish 1~25 that (B) viscosity at 25 DEG C is 1~100mPas,

(C) the mass % of nonionic surfactant 0.05~6 of HLB3~20,

(D) the mass % of tackifier 0.1~1,

(E) water.

Brief description of the drawings

Fig. 1 is to represent to evaluate figure of the toner to the result of the uniform tack of skin in test example 4.

Embodiment

The present invention relates to a kind of extension of bubble is good, carbon dioxide can be made promptly to be applied to skin, and to skin Excellent spraying cosmetics are felt in infiltration.

The present inventors has found, by the way that specific powder and finish, nonionic surfactant, water solubility is applied in combination Tackifier, carbon dioxide, and the spraying cosmetics for the above mentioned problem that achieves a solution.

On the spraying cosmetics of the present invention, the extension of the bubble containing carbon dioxide is good, and carbon dioxide can be made rapid Ground is applied to skin, and the infiltration sense steeped to skin is excellent, and the skin after coating obtains epithelium sense.Also, the spray by the present invention Atomization cosmetic is coated on the infiltration sense raising of used cosmetics after skin.

Furthermore in this manual, spraying cosmetics are recited as " composition " sometimes.

The silicone elastomer of the composition (A) used in the present invention has crosslinking preferably by what the polymerization of monomer was obtained The silicone and its derivative of structure.Such as it is preferably to make selected from dimethyl silicone polymer, vinyldimethicone, phenyl Vinyldimethicone, lauryl dimethicone and lauryl polydimethylsiloxane epoxide ethyl poly dimethyl The silicone and its derivative that monomer in siloxanes etc. polymerize or copolymerization is obtained, just make it be combined with following compositions (C) and carry For the viewpoint of infiltration sense of the height bubble to skin, more preferably (Dimethicone/Vinyl Dimethicone) is handed over Linked polymer, (dimethyl silicone polymer/phenyl vinyl dimethyl silicone polymer) cross-linked polymer, (vinylpolydimethyl Siloxanes/lauryl dimethicone) cross-linked polymer, (vinyldimethicone/polymethyl siloxane silicon times Half oxygen alkane) cross-linked polymer (vinyl dimethicone/methicone silsesquioxane crosspolymer), (PEG-15/ lauryl dimethicones) cross-linked polymer, and then be preferably (dimethyl silicone polymer/vinyl poly- two Methylsiloxane) cross-linked polymer, (vinyldimethicone/lauryl dimethicone) cross-linked polymer, (PEG-15/ lauryl dimethicones) cross-linked polymer, and then more preferably (dimethyl silicone polymer/vinyl gathers Dimethyl siloxane) cross-linked polymer.

Furthermore in the present invention, skin and skin are identical meanings.

The average grain diameter of the silicone elastomer of composition (A) is 0.01~30 μm, it is combined with composition (C) and improves painting For the viewpoint of the epithelium sense of skin after cloth, average grain diameter is preferably 0.1~20 μm, more preferably 1~10 μm.

In the present invention, average grain diameter is by laser diffraction and scattering formula particle size distribution analyzer LA-920 (HORIBA Company manufactures) and determine.

Solid-like can be used directly in the silicone elastomer of composition (A), it is possible to use is equably mixed with water, unthickened fuel Material.Just the dispersiveness in cosmetics, workability, combined with following compositions (C) and improve bubble to skin infiltration feel For viewpoint, used preferably in the form of the dispersion liquid mixed with water or unthickened fuel, more preferably to be mixed with unthickened fuel The form for closing the dispersion liquid formed uses.

As unthickened fuel, for the viewpoint that infiltration of the bubble to skin is felt is improved with regard to being combined with following compositions (C), it is preferably Viscosity at 25 DEG C is below 100mPas, more preferably below 50mPas, and then preferably below 30mPas, and then More preferably below 10mPas.

Herein, viscosity is by Brookfield viscometer (VISCOMETER TVB-10, Dong Ji industry companies manufacture), with rotor No.1,60rpm, 1 minute and determine.

Also, as unthickened fuel, it is excellent for the viewpoint that infiltration of the bubble to skin is felt is improved with regard to being combined with following compositions (C) Elect as selected from least one of silicone oil, hydrocarbon ils, ester oil, more preferably selected from least one of silicone oil, hydrocarbon ils, and then preferably For selected from least one of dimethyl polysiloxane, decamethylcyclopentasiloxane, atoleine, lightweight isomery paraffin, and then More preferably selected from least one of dimethyl polysiloxane, decamethylcyclopentasiloxane.

As (Dimethicone/Vinyl Dimethicone) cross-linked polymer, as the material of solid-like, Trefil E-506S (the mass % of active ingredient 100) (manufacture of Dong Li Dow Corning Corporations) etc. can be enumerated, are mixed as with unthickened fuel The material formed, the KSG-15 (matter of active ingredient 7 as the mixture with decamethylcyclopentasiloxane (KF-995) can be enumerated Measure %), the KSG-16 (matter of active ingredient 25 as the mixture with low viscosity dimethyl polysiloxane (KF-96A-6cs) Measure %) (being manufactured above for chemical industrial company of SHIN-ETSU HANTOTAI), the Trefil E-508 as the mixture with dimethyl silicone polymer (active ingredient 70%) etc., as the material mixed with water, usable BY29-119 (the mass % of active ingredient 63), The commercially available products such as BY29-129 (the mass % of active ingredient 63).

As (dimethyl silicone polymer/phenyl vinyl dimethyl silicone polymer) cross-linked polymer, as with unthickened fuel The material mixed, it can be used as the mixture with the poly- trimethicone of diphenyl silane phenyl (KF-56A) The commercially available products such as KSG-18A (the mass % of active ingredient 15) (manufacture of chemical industrial company of SHIN-ETSU HANTOTAI).

Also, as (vinyldimethicone/lauryl dimethicone) cross-linked polymer, as with liquid The material that shape oil mixes, the KSG-41 (the mass % of active ingredient 30) as the mixture with atoleine can be used, make For the KSG-42 (the mass % of active ingredient 25) of the mixture with lightweight isomery paraffin, as with three -2 ethyl hexanoic acid glyceride The KSG-43 (the mass % of active ingredient 30) of mixture, the KSG-44 (matter of active ingredient 30 as the mixture with saualane Measure %) commercially available product such as (above be chemical industrial company of SHIN-ETSU HANTOTAI manufacture).

As (vinyldimethicone/polymethyl siloxane silsesquioxane) cross-linked polymer, as solid The material of shape, the commercially available products such as KSP-100 (the mass % of active ingredient 100) (manufacture of chemical industrial company of SHIN-ETSU HANTOTAI) can be used.

As (PEG-15/ lauryl dimethicones) cross-linked polymer, as the thing mixed with unthickened fuel Matter, can be used as the mixture with atoleine KSG-310 (the mass % of active ingredient 30), as with lightweight isomery paraffin Mixture KSG-320 (the mass % of active ingredient 25), the KSG- as the mixture with three -2 ethyl hexanoic acid glyceride The commercially available products such as 330 (the mass % of active ingredient 20) (being manufactured above for chemical industrial company of SHIN-ETSU HANTOTAI).

Composition (A) can be used selected from above-mentioned one kind or two or more, the extension felt and steeped with regard to improving infiltration of the bubble to skin Viewpoint for, content is more than 0.1 mass % in stoste, preferably more than 0.2 mass %, more preferably 0.4 mass % More than, it is below 1.5 mass % for improving the viewpoint of storage stability of composition, preferably below 0.8 mass %, More preferably below 0.6 mass %.Also, the content of composition (A) is 0.1~1.5 mass % in stoste, preferably 0.2~0.8 Quality %, and then preferably 0.4~0.6 mass %.

Also, on composition (A), the infiltration that just raising is steeped to skin is felt, the epithelium sense of skin and the extension of bubble after coating Viewpoint for, content is more than 0.1 mass % in the composition in addition to composition (F), more excellent preferably more than 0.2 mass % Elect as more than 0.4 mass %, be below 1.5 mass % for improving the viewpoint of storage stability of composition, be preferably Below 0.8 mass %, more preferably below 0.6 mass %.Also, the content of composition (A) is in the composition in addition to composition (F) 0.1~1.5 mass %, preferably 0.2~0.8 mass %, more preferably 0.4~0.6 mass %.Composition in addition to composition (F) In the preferable contents of other compositions can also be that the amount of " in the composition in addition to composition (F) " will be replaced with " in stoste ".

In the present invention, the extension of so-called bubble well refers to make it on skin extending when maintaining and steeping, so-called bubble Excellent infiltration sense to skin is represented with blister after skin extension, is absorbed immediately, no cosmetics are residued on skin Sense of touch.The epithelium sense of skin after so-called coating is that the cosmetics for representing blister are absorbed rapidly, and the cuticula of skin is full of change Cosmetic, make the sensation of cuticula swelling, and without constriction.Thus, become the toner applied thereafter or the affine of beautifying liquid Well.In the present invention, it is so-called it is affine be that toner or beautifying liquid are kept when representing toner or beautifying liquid being applied to skin In skin, and the cosmetics of the blister with having applied together are absorbed into the sense of touch in the cuticula of skin.It is also, so-called affine It is to represent infiltration sense.

Also, the spraying cosmetics of the present invention toner that can also make to apply after the coating cosmetics, emulsion, creams etc. are other The affine of cosmetics becomes good.

In the present invention, it is so-called it is affine be represent coating the present invention spraying cosmetics after by other cosmetic applications in skin During skin, other cosmetics are held in skin, and are together absorbed into skin with the spraying cosmetics of the invention applied Sense of touch in cuticula.

On the viscosity of the finish of composition (B) that is used in the present invention at 25 DEG C, infiltration sense of the bubble to skin is just improved Viewpoint for, be more than 1mPas, preferably more than 2mPas, more preferably more than 3mPas, and then be preferably More than 4mPas, and be below 100mPas, preferably below 50mPas, more preferably below 30mPas, Jin Ergeng Preferably below 20mPas.Also, the finish of composition (B) is 1~100mPas, preferably 2~50mPas, more preferably 3 ~30mPas, and then preferably 4~20mPas.

Herein, viscosity be at 25 DEG C by BM viscosimeters (manufacture of Dong Ji industry companies) (rotor No.1,60rpm, 1 point Clock) and determine.

As the finish, if it is then and unrestricted for material used in common cosmetics, such as hydrocarbon ils, silicon can be enumerated Oil, ester oil, ether oil, fluorocarbon oil etc..More specifically, such as can enumerate：Lightweight isomery paraffin, atoleine, liquid isomery paraffin, The hydrocarbon ils of the straight or brancheds such as saualane, squalene；Dimethyl polysiloxane, cyclopolymethyl siloxane, dimethyl silicone polymer, The poly- trimethicone of trisiloxanes methyl, ethyl trisiloxanes, dimethyl cyclopolysiloxane, methyl phenyl silicone, first The silicone oil such as base hydrogen polysiloxanes, higher alcohol modified organopolysiloxane；Isononyl isononanoate, different n-nonanoic acid isotridecyl ester, make For monoester oils such as the benzoic acid alkyl base esters (C12-15) of benzoic acid and the ester of the aliphatic alcohol of carbon number 12~15；Neopentyl glycol Three ester oils such as the diester oils such as dicaprate, three (caprylic/capric) glyceride, 2 ethyl hexanoic acid glyceryl ester；Alkyl -1,3- diformazans The ether oils such as base butyl ether, dicaprylyl ether, dicaprylyl ether；Fluorocarbon oils such as perfluoroalkyl polyether, perfluoroalkyl ethers silicone etc..

As composition (B), for the viewpoint for the extension that bubble is improved with regard to being combined with composition (A), hydrocarbon ils, ester are preferably selected from It is one kind or two or more in oil and silicone oil, more preferably hydrocarbon ils, monoester oil, three ester oils, silicone oil, preferably monoester oil, silicone oil. Also, with regard to improve infiltration sense of the bubble to skin, stability viewpoint for, be preferably and with monoester oil and silicone oil.

One kind or two or more, the epithelium sense with regard to improving the skin after bubble is felt, is coated with to permeating for skin can be used in composition (B) Viewpoint for, content is more than 1 mass % in stoste, preferably more than 2 mass %, more preferably more than 4 mass %, and For below 25 mass %, preferably below 15 mass %, more preferably below 12 mass %.Also, the content of composition (B) is in stoste In be 1~25 mass %, preferably 2~15 mass %, and then preferably 4~12 mass %.

The composition (C) used in the present invention is the nonionic surfactant of HLB3~20, just improves bubble and skin is oozed Feeling thoroughly, for the viewpoint of the storage stability of composition, the HLB of composition (C) is preferably more than 7, and more preferably more than 9, and then Preferably more than 11, with regard to improve be coated with after skin epithelium sense viewpoint for, preferably less than 18, more preferably 16 with Under, and then preferably less than 15.Also, the HLB of composition (C) is preferably 7~18, more preferably 9~16, and then preferably 11~ 15.With regard to meltage of the carbon dioxide in stoste, promote dissolubility and coating when foaming characteristic viewpoint for, contain composition (C) nonionic surfactant.

Furthermore following compositions (G) are free of in composition (C).

Herein, the HLB (balances of hydrophilic-lipophilic<Hydrophilic-Lypophilic Balance>) it is to represent table The molecular weight for the hydrophilic base section occupied in the total molecular weight of face activating agent, nonionic surfactant are to pass through Griffin (Griffin) calculated by formula.

The HLB for the mixed surfactant being made up of nonionic surfactant of more than two kinds is to ask in such a way .The HLB of mixed surfactant is that the HLB value of each nonionic surfactant is based on into its compounding ratio to carry out arithmetic average And obtain.

Mix HLB=Σ (HLBx × Wx)/Σ Wx

HLBx represents nonionic surfactant X HLB value.

Wx represents the nonionic surfactant X of the value with HLBx quality (g).

As composition (C) nonionic surfactant, such as can enumerate：Sorbitan carboxylic esterses, glycerine fatty acid Ester, polyglyceryl fatty acid ester, methyl glycol fatty acid ester, cithrol, sucrose fatty ester, polyoxyethylene fatty acid Ester, polyoxyethylene sorbitan carboxylic ester, polyoxyethylene alkyl ether, Polyoxyethylene Sorbitol Fatty Acid Esters, polyoxyethylene are sweet Oil and fat acid esters, polyoxyethylene methyl glycol fatty acid ester, Emulsifier EL-60, Crodaret, polyoxyethylene Hydrogenated castor oil fatty ester, polyoxyethylene phytostanyl alcohol ether, polyoxyethylene phytosterol ether, polyoxyethylene beta-cholestanol Ether, polyoxyethylene cholesterol ether etc..

Among these, infiltration of the bubble to skin is improved with regard to being combined with composition (A) and is felt, for the viewpoint of stability, preferably For sorbitan carboxylic esterses, fatty acid glyceride, polyoxyethylene sorbitan carboxylic ester, polyoxyethylene alkyl ether, polyoxy Ethylene hydrogenation castor oil, more preferably fatty acid glyceride, polyoxyethylene sorbitan carboxylic ester, polyoxyethylene alkyl ether, Crodaret, and then preferably polyoxyethylene sorbitan carboxylic ester, Crodaret, and then More preferably Crodaret.

Also, for the viewpoint of the epithelium sense of the skin after improving the infiltration sense to skin, coating, preferably sorbitol anhydride It is fatty acid ester, fatty acid glyceride, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan carboxylic ester, polyxyethylated Ether, Crodaret, more preferably sorbitan carboxylic esterses, fatty acid glyceride, polyoxyethylene sorbitol acid anhydride Fatty acid ester, Crodaret, and then preferably sorbitan carboxylic esterses, Crodaret, enter And more preferably Crodaret.

Also, for being coated on the viewpoint of infiltration sense of used cosmetics after skin with regard to improving, sorb is preferably selected from Alcohol acid anhydride fatty acid ester, fatty acid glyceride, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan carboxylic ester, polyoxyethylene It is one kind or two or more in alkyl ether and Crodaret, more preferably selected from sorbitan carboxylic esterses, polyoxy It is one kind or two or more in ethene fatty acid ester, polyoxyethylene alkyl ether and Crodaret.

Improve infiltration of the bubble to skin with regard to combining with composition (A) to feel, for the viewpoint of stability, polyethylene glycol hydrogenated castor Sesame oil is preferably that the average addition molal quantity of oxirane is 20~90, more preferably 30~80, and then preferably 50~70.

Composition (C) can be combined using selected from above-mentioned one kind or two or more, just extension, the infiltration to skin of raising bubble For the viewpoint of the epithelium sense of skin after sense, coating, content is more than 0.05 mass % in stoste, preferably 0.1 matter More than % is measured, more preferably more than 0.3 mass %, and is below 6 mass %, preferably below 2 mass %, more preferably 1 matter Measure below %.Also, the content of composition (C) is 0.05~6 mass %, preferably 0.1~2 mass % in stoste, more preferably 0.3~1 mass %.

In the present invention, with regard to improve bubble to skin infiltration feel viewpoint for, composition (A) relative to composition (C) matter Measure ratio [(A)/(C)] be preferably more than 0.05, more preferably more than 0.2, and then preferably more than 0.5, and preferably 3 with Under, more preferably less than 2.2, and then preferably less than 1.4.Also, composition (A) relative to composition (C) quality ratio [(A)/ (C) it is preferably] 0.05~3, more preferably 0.2~2.2, and then preferably 0.5~1.4.

As composition (D) tackifier, as long as being material used in common cosmetics, such as can arrange Lift：It is antler glue, dextrin, methylcellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol, poly- Acrylic acid, polymethylacrylic acid, carboxyl vinyl polymer, acrylic acid-methacrylic acid alkyl ester copolymer, xanthans, carboxylic Methyl chitin, chitosan etc..These have the viscosity for improving stoste and make stability-enhanced effect.

Among these, just combined with composition (A) and improve the epithelium sense of the skin after bubble is felt, is coated with to permeating for skin For viewpoint, preferably carboxyl vinyl polymer, acrylic acid-methacrylic acid alkyl ester copolymer, more preferably acrylic acid- Methacrylate copolymer.

Herein, so-called acrylic acid-methacrylic acid alkyl ester copolymer is C10-30 alkyl acrylics and acrylic acid, methyl The copolymer of acrylic acid or these lower alkyl esters, and be by the allyl ether of the allyl ether of sucrose or pentaerythrite be crosslinked and Into material, can be used PEMULEN TR-1, PEMULEN TR-2, Carbopol ETD2020, Carbopol 1342, The commercially available products such as Carbopol1382 (being above Lubrizol Advanced Materials companies).

Also, the acid type such as polyacrylic acid, carboxyl vinyl polymer, acrylic acid-methacrylic acid alkyl ester copolymer is water-soluble Property tackifier be preferably use alkali as nertralizer, and by water solubility or water dispersible salt in the form of use.As alkali, can arrange Lift：The alkali metal hydroxide of sodium, potassium etc.；Ammonium；From alkanolamines such as MEA, diethanol amine, triethanolamine, amine butantriols Ammonium；The basic amino acids such as spermine acid, lysine；The preferably alkali metal hydroxide of sodium, potassium etc., more preferably hydroxide Potassium, sodium hydroxide.

Composition (D) can be combined using selected from above-mentioned one kind or two or more, just improves and steeps to skin into subassembly with other For the viewpoint of the infiltration sense of skin, content is more than 0.1 mass % in stoste, preferably more than 0.15 mass %, more preferably For more than 0.2 mass %, and it is below 1 mass %, preferably below 0.8 mass %, more preferably below 0.5 mass %.Also, The content of composition (D) is 0.1~1 mass %, preferably 0.15~0.8 mass %, more preferably 0.2~0.5 matter in stoste Measure %.

In the present invention, for improving the viewpoint of infiltration sense and stability of the bubble to skin, composition (A) is relative to composition (D) quality ratio [(A)/(D)] is preferably more than 0.2, and more preferably more than 0.6, and then preferably more than 1, and be preferably Less than 10, more preferably less than 4, and then preferably less than 2.5.Also, composition (A) relative to composition (D) quality ratio [(A)/ (D) it is preferably] 0.2~10, more preferably 0.6~4, and then preferably 1~2.5.

The water of the composition (E) used in the present invention plays the effect as solvent, turns into the surplus of other compositions.Composition (E) content of water is preferably more than 55 mass % in stoste, more preferably more than 65 mass %, and then preferably 75 matter More than % is measured, and preferably below 95 mass %, more preferably below 93 mass %, and then preferably below 90 mass %.Also, The content of water preferably 55~95 mass %, more preferably 65~93 mass %, and then preferably 75~90 matter in stoste Measure %.

The cosmetics of the present invention and then can contain (G) in alkyl glycerylether modified silicone and polyoxyalkylene-modified silicone It is one kind or two or more, can be combined with composition (A) and improve bubble extension, coating after skin epithelium sense, be coated on skin The infiltration sense of used cosmetics afterwards.

As composition (G), just combined with composition (A) and improve the epithelium sense of the skin after the extension of bubble, coating, be coated on After skin for the infiltration sense of used cosmetics, the viewpoint of stability, preferably polyoxyalkylene-modified silicone.

As alkyl glycerylether modified silicone, such as the material represented by below general formula (1) can be enumerated.

[in formula, R¹~R¹²In at least one base for represented by following formula (2)；

(in formula, Q represents the bivalent hydrocarbon radical of carbon number 3~20, R¹³And R¹⁴Represent respectively hydrogen atom or carbon number 1~ 5 alkyl, wherein at least one represent hydrogen atom), remaining represents the alkyl of the straight chain of carbon number 1~30, side chain or ring-type Or the base represented by following formula (2-1)；

-Y-R¹⁵(2-1)

(in formula, Y represents the bivalent hydrocarbon radical of the carbon number 1~10 of ether-containing key or ester bond, R¹⁵Represent carbon number 1~30 Straight chain, the alkyl of side chain or ring-type), a, b and c represent 0~2000 number, during a+b+c=0, R¹~R³And R¹⁰~R¹²In extremely A few expression base (2).]

As alkyl glycerylether modified silicone, just combined with composition (A) and improve the skin of the skin after the extension of bubble, coating Film sense, it is coated on for the viewpoint of infiltration sense of used cosmetics after skin, preferably in formula (1), R¹~R¹²'s One is formula (2), the R of formula (2)¹³With R¹⁴For hydrogen atom, remaining is methyl, and then more preferably using Japan Patent Described method in Unexamined Patent 4-108795 publications and manufacture in below general formula (3), j=60, k=4.

As alkyl glycerylether modified silicone, such as " Penetrol the SI-U " (glycerine that KAO. Corp. SA can be used to be sold Undecyl dimethyl silicone polymer) etc. commercially available product.

Also, as polyoxyalkylene-modified silicone, can enumerate polyoxyethylene-methyl polysiloxane copolymer, it is poly- (oxygen ethene- Oxypropylene)-methyl polysiloxane copolymer, as polyoxyethylene-methyl polysiloxane copolymer, such as below general formula can be enumerated (4) material represented by.

[in formula, R¹⁷~R¹⁹And R²¹~R²²Methyl or phenyl, R are represented respectively¹⁶、R²⁰And R²³Respectively represent methyl, phenyl, Or group R²⁴(OC₃H₆)_f(OC₂H₄)_gO(CH₂)_h-(R²⁴The alkyl of hydrogen atom or carbon number 1~12 is represented, f and g are average Value, and 0~35 number is represented respectively, h represents 1~5 number).Wherein, R¹⁶、R²⁰And R²³In at least one expression group R²⁴ (OC₃H₆)_f(OC₂H₄)_gO(CH₂)_h-.D and e is average value, and d represents 1~200 number, and e represents 0~50 number.]

As polyoxyalkylene-modified silicone, preferably polyoxyethylene-methyl polysiloxane copolymer, poly- (oxygen ethene-oxygen third Alkene)-methyl polysiloxane copolymer, just combines with composition (A) and improves the epithelium sense of the skin after the extension of bubble, coating, applies It is distributed in for the viewpoint of infiltration sense of used cosmetics after skin, polyoxyethylene-first more preferably represented by formula (4) Based polysiloxane copolymer.As polyoxyethylene-methyl polysiloxane copolymer represented by formula (4), SHIN-ETSU HANTOTAI can be used Learn " KF-6015 " (PEG-3 dimethyl silicone polymers), " KF-6019 " (the PEG-9 polydimethylsiloxanes that available from industrial group Alkane)；" SH-3775M " (PEG-12 dimethyl silicone polymers), " SH-3771M " that available from the beautiful DOW CORNING/silicone company in east The commercially available products such as (PEG-12 dimethyl silicone polymers), " SS-2804 " (PEG-12 dimethyl silicone polymers).

Composition (G), which can be combined, to be used selected from above-mentioned one kind or two or more, just epithelium sense, the painting of the skin after raising coating It is distributed in for the viewpoint of infiltration sense of used cosmetics after skin, content is preferably more than 0.05 mass % in stoste, More preferably more than 0.1 mass %, and then preferably more than 0.2 mass %, and preferably below 1.5 mass %, more preferably 1 Below quality %, and then preferably below 0.7 mass %.Also, the content of composition (G) is preferably 0.05~1.5 matter in stoste Measure %, more preferably 0.1~1 mass %, and then preferably 0.2~0.7 mass %.

In the present invention, (H) divalence polyalcohol and then can be contained in stoste, can be combined with composition (A) and improve coating after Skin epithelium sense.

As the divalence polyalcohol of composition (H), as long as being material used in common cosmetics, such as can arrange Lift：Ethylene glycol, propane diols (propylene glycol), propane diols (propandiol), 1,3 butylene glycol, 1,3- propane diols, DPG, polyethylene glycol, polypropylene glycol etc., just combined with composition (A) and improve the epithelium sense of the skin after coating, also, making For skin after coating moistens and obtains the viewpoint of not tacky sense of touch, preferably propane diols (propylene Glycol), propane diols (propandiol), 1,3-BDO, 1,3-PD, DPG, more preferably 1,3-PD, DPG.Also, and then it is preferably and uses 1,3-PD and DPG.

Composition (H) can be combined using selected from above-mentioned one kind or two or more, just infiltration of the extension, bubble of raising bubble to skin The epithelium sense of skin after sense, coating, it is coated on for the viewpoint of infiltration sense of used cosmetics after skin, content is in original It is preferably more than 1 mass % in liquid, more preferably more than 3 mass %, and then preferably more than 5 mass %, and preferably 20 matter Below % is measured, more preferably below 15 mass %, and then preferably below 10 mass %.Also, the content of composition (G) is in stoste Preferably 1~20 mass %, more preferably 3~15 mass %, and then preferably 5~10 mass %.

In the spraying cosmetics of the present invention, stoste and then can contain composition used in common cosmetics, such as：It is anti- It is the finish of liquid at 25 DEG C beyond rotten agent, the composition (B) in addition to preservative, at 25 DEG C in addition to preservative is beyond liquid The finish, surfactant beyond composition (C), the powder beyond composition (A), ethanol, the polyalcohol beyond composition (H), anti- Oxidant, pigment, pH value regulator, spices, NMF, blood circulation accelerant, cooling agent, antiperspirant, bactericide, whitening Agent, anti-inflammatory agent, activating skin agent etc..

In the present invention, as preservative, methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate can be used, to hydroxyl The p-hydroxybenzoates such as butyl benzoate, phenoxetol etc..

The content of preservative in stoste is preferably 0.05~1 mass %.

In the present invention, with regard to improve be coated with after skin epithelium sense viewpoint for, in stoste in addition to preservative The content of finish at 25 DEG C beyond composition (B) for liquid is preferably more than 1 mass %, and preferably below 9 mass %, more Preferably below 7.5 mass %.Furthermore the ultra-violet absorber of the liquid beyond composition (B) is also contained in addition to preservative For in the finish of liquid at 25 DEG C beyond composition (B).

It is that finish beyond liquid is to represent at 25 DEG C to be solid-like at 25 in addition to preservative DEG C used in stoste Wax, paste or solid fat, the higher alcohol of carbon number 12~24, the higher fatty acids of carbon number 12~24, stone can be enumerated Wax etc..Also, it is that also to be included at 25 DEG C in the finish beyond liquid be that ultraviolet beyond liquid is inhaled at 25 DEG C in addition to preservative Receive agent.

Also, for the flexibility for improving bubble, the viewpoint to extend, it is at 25 in addition to preservative DEG C used in stoste The content of finish beyond liquid is below 3 mass % preferably in stoste, more preferably below 1 mass %, and then preferably For below 0.5 mass %, and then more preferably below 0.3 mass %, preferably below 0.1 mass %.

At 25 in addition to preservative DEG C in stoste be liquid beyond finish relative to the composition (B) in addition to preservative with It is the mass ratio [(being the finish beyond liquid at 25 DEG C in addition to preservative)/(remove preservative of the finish of liquid at outer 25 DEG C It is the finish of liquid at 25 DEG C beyond outer composition (B))] it is preferably less than 0.1, more preferably less than 0.07, and then preferably For less than 0.03.

And then in the present invention, for improving the extension of bubble, the affine viewpoint of bubble, contained anion in stoste The content of surfactant is preferably below 1 mass %, more preferably below 0.1 mass %.

Also, containing the powder beyond composition (A), also containing the powder containing metal, any of metal-free powder Powder, more preferably preferably metal-free powder, resin powder.It is excellent as the average grain diameter of the powder beyond composition (A) Elect less than 30 μm, more preferably less than 10 μm, and then preferably less than 5 μm as.

For the viewpoint of the epithelium sense of the skin after improving the extension of bubble, be coated with, the content of the powder beyond composition (A) Preferably below 3 mass %, more preferably below 1 mass %.

For improving the viewpoint of foaming, the content of the ethanol in stoste is preferably more preferably 1 matter below 3 mass % Below % is measured, is preferably substantially free of.

In the spraying cosmetics of the present invention, stoste is made by mixing mentioned component (A)~(E) and other compositions It is standby.For the viewpoint felt with regard to improving the infiltration of stability, the ejection of bubble, bubble to skin, stoste is preferably the viscosity at 25 DEG C For more than 500mPas, more preferably more than 1000mPas, and then preferably more than 1500mPas, and be preferably Below 20000mPas, more preferably below 10000mPas, and then preferably below 7000mPas.Stoste is preferably 25 Viscosity at DEG C is 500~20000mPas, more preferably 1000~10000mPas, and then preferably 1500~ 7000mPa·s。

Herein, viscosity is at 25 DEG C, using BM viscosimeters (manufacture of Dong Ji industry companies), with rotor No.3,12rpm, 1 Minute is determined, and when viscosity exceedes 10000mPas situation, with rotor No.3,6rpm, 1 minute value determined.

The spraying cosmetics of the present invention can be by the way that stoste as described above and (F) propellant be filled to pressure vessel (spray Mist container) in and manufacture.As the form of its injection, the foam type sprayed with blister is preferably set to.

The propellant of composition (F) is comprising more than the mass % of carbon dioxide 90, preferably more than 95 mass %, is more preferably More than 98 mass %, and then preferably 100 mass %.

For improving the viewpoint of extension of bubble, stoste and the quality ratio of (F) propellant are preferably 94:6~99.5: 0.5, more preferably 95:5~99:1, and then preferably 96.5:3.5~98.5:1.5.

In the present invention, with regard to improve bubble to skin infiltration feel viewpoint for, composition (A) relative to composition (F) matter Measure ratio [(A)/(F)] be preferably more than 0.05, more preferably more than 0.1, and then preferably more than 0.12, and preferably 1 with Under, more preferably less than 0.4, and then preferably less than 0.3.Also, composition (A) relative to composition (F) quality ratio [(A)/ (F) it is preferably] 0.05~1, more preferably 0.1~0.4, and then preferably 0.12~0.3.

The spraying cosmetics of the present invention can be used as cosmetics with no particular limitation, but be obtained with regard to carbon dioxide by percutaneous absorbtion For the effect to stimulate circulation that must be higher than existing cosmetics, as to improve the colour of skin (brightness, obscure etc.), improve The cosmetics for skin of moisturizing sense etc. is preferred.Again, it is possible to increase be coated with used cosmetics after the spraying cosmetics of the present invention Permeability.

Also, in the present invention, the cosmetics containing composition (A), (B), (C), (D), (E) and (F) can be filled in spraying Cosmetic product is made in container.

The spraying cosmetics of the present invention can be applied to skin, the skin especially in addition to hair, be preferably face, body, hand Pin etc. any one, used preferably by coating.

And then by applying or being coated on application by the cosmetics (being referred to as other cosmetics) beyond the present invention or be coated with The skin of the spraying cosmetics of the present invention, and the infiltration sense for improving other cosmetics has been given play to, improve prolonging for other cosmetics The special effect of exhibition.The reasons why its is detailed fail to understand, but thinks the reason is that by by the spraying cosmetic applications of the present invention Or skin is coated on, the cosmetics make the surface state of skin change.

Therefore, it is of the invention so disclose it is a kind of for use before other cosmetics cosmetics, application method.

That is, by the spraying cosmetic applications of the present invention or after being coated on such as skin, by other cosmetic applications or It is coated on application or is coated with the application method of the skin of the spraying cosmetics.

If in this way, before other cosmetics by the present invention spraying cosmetic applications or be coated on skin, can The infiltration sense and extension for the other cosmetics applied or be coated with after raising.

Furthermore more specifically the content of carbon dioxide is preferably the cosmetics (other cosmetics) beyond the invention described above It is below 10 mass % in cosmetics, more preferably below 5 mass %, and then preferably below 1 mass %, and then more preferably Especially preferably it is essentially 0 mass % for below 0.1 mass %.

As the spraying cosmetic applications or be coated on after skin of the present invention are being coated on into application or are being coated with the spraying There is no particular restriction for other cosmetics of the skin of cosmetics, can be used in the form of toner, emulsion, creams etc., just making Cosmetic is equably for the viewpoint that dermal application is opened, preferably toner or emulsion, more preferably toner.

And then other cosmetics are preferably to contain water, and the content in the total composition of preferably other cosmetics be 65~ 93 mass %, more preferably 70~92 mass %.

Also, other cosmetics are preferably containing polyalcohols such as glycerine, DPGs, and in the total composition of other cosmetics Content is preferably 3~40 mass %, more preferably 5~30 mass %, and then preferably 7~25 mass %.

Also, other cosmetics are preferably containing polyoxyalkylene-modified silicone such as polyoxyethylene-methyl polysiloxane copolymers, And the content in the total composition of other cosmetics is preferably 0.005~2 mass %, more preferably 0.010~1.0 mass %, enter And preferably 0.015~0.5 mass %, and then more preferably 0.02~0.2 mass %.

Also, other cosmetics are preferably to contain that alkyl-modified carboxyl vinyl polymer, pulullan polysaccharide etc. can be carried out Tackifier, and the content in the total composition of other cosmetics is preferably 0.001~1.0 mass %, more preferably 0.01 ~0.5 mass %, and then preferably 0.05~0.3 mass %.

, will be other used for cosmetic in applying or be coated with by the spraying cosmetic applications of the present invention or after being coated on skin During the situation of the skin of the spraying cosmetics, just improve other cosmetics it is affine, extend, to the uniform tack of skin For viewpoint, spraying cosmetics relative to the usage amount of other cosmetics usage rate [usage amounts of cosmetics (spraying)/ (usage amounts of other cosmetics)] it is preferably 0.2~6, more preferably 0.3~5, and then preferably 0.4~4.

Also, with regard to improve other cosmetics it is affine, extend, for the viewpoint of the uniform tack of skin, will spray Cosmetic applications are coated on after skin to starting other cosmetic material applications in the skin for applying or being coated with the spraying cosmetics The time of skin is preferably 0 second~5 minutes, more preferably 3 seconds~3 minutes, and then preferably 5 seconds~1 minute.

The spraying cosmetics of the present invention can improve the infiltration sense to skin by being coated on skin.

Also, the spraying cosmetics of the present invention can obtain the epithelium sense of skin by being coated on skin.

The spraying cosmetics of the present invention are as described above, can be by the cosmetic applications or after being coated on skin, by otherization Cosmetic is used to applying or being coated with the skin of the spraying cosmetics, therefore can be made into comprising spraying cosmetics and other cosmetics Make up and be set with.

After the spraying cosmetics of the present invention are by being coated on skin, certain time is placed, it is possible to increase stimulate circulation Effect, the active ingredient in cosmetics can also permeate in the lump, it is believed that be highly profitable.

Can by the present invention spraying cosmetics be coated on skin and place certain time and with skin it is affine, wipe or Rinse etc., used according to service condition.

The spraying cosmetics of the present invention can utilize usual way and manufacture, such as can obtain in the following way：Make Original liquid component is mixed to uniform, after the stoste obtained is filled into pressure vessel and sealed, by adding to composition (F) Press and fill.

Also, just improve infiltration of the bubble of dispersiveness and the cosmetics that are obtained of the composition (A) in cosmetics to skin For the viewpoint of the epithelium sense of skin after sense, coating and the extension of bubble, the stoste of spraying cosmetics of the invention it is preferable Manufacture method is to include the manufacture method of following processes 1,2.

Process 1：Composition (D) is mixed with part or all of (E) and prepares the work of the solution of containing water-soluble tackifier Sequence,

Process 2：Into the solution of the containing water-soluble tackifier obtained in process 1 addition in addition to composition (F) it is other into Point, the process that composition (A), (B), (C), (D) and (E) is mixed and prepares stoste.

Furthermore composition (A) can also mix in process 1.

Process 1 is preferably that the process comprising the mixing for carrying out process 1 under heating is increased with improving obtained containing water-soluble The dispersiveness of composition (D) in the solution of stick, and the temperature heated is preferably 20~80 DEG C, more preferably 40~60 DEG C.

Furthermore in situation of the composition (D) for the tackifier of acid type, preferably add alkali in process 1.

Also, for identical viewpoint, process 2 is preferably the process comprising the mixing for carrying out process 2 under heating to carry The dispersiveness of high composition (C), and the temperature heated is preferably 20~80 DEG C, more preferably 40~60 DEG C.Work is carried out under heating During the situation of the mixing of sequence 2, preferably there is refrigerating work procedure upon mixing, specifically, the temperature of cooling is cooled to preferably 20~30 DEG C, more preferably 20~25 DEG C of temperature.

It is of the invention and then disclose following composition on above-mentioned embodiment.Also, of the invention and then open following makes With method etc..

<1>One kind spraying cosmetics, wherein, contain：

The mass % of finish 1~25 that (B) viscosity at 25 DEG C is 1~100mPas,

(C) the mass % of nonionic surfactant 0.05~6 of HLB3~20,

(D) the mass % of tackifier 0.1~1,

(E) water.

<2>As described above<1>Described in spraying cosmetics, wherein, the silicone elastomer of composition (A) is preferably to make selected from poly- Dimethyl siloxane, vinyldimethicone, phenyl vinyl dimethyl silicone polymer, lauryl polydimethylsiloxanes Monomer polymerization or the obtained silicone of copolymerization in alkane and lauryl polydimethylsiloxane epoxide ethyl dimethyl silicone polymer and Its derivative, more preferably (Dimethicone/Vinyl Dimethicone) cross-linked polymer, (poly dimethyl silicon Oxygen alkane/phenyl vinyl dimethyl silicone polymer) cross-linked polymer, (vinyldimethicone/lauryl poly dimethyl Siloxanes) cross-linked polymer, (vinyldimethicone/polymethyl siloxane silsesquioxane) cross-linked polymer, (PEG-15/ lauryl dimethicones) cross-linked polymer, and then be preferably (dimethyl silicone polymer/vinyl poly- two Methylsiloxane) cross-linked polymer, (vinyldimethicone/lauryl dimethicone) cross-linked polymer, (PEG-15/ lauryl dimethicones) cross-linked polymer, and then more preferably (dimethyl silicone polymer/vinyl gathers Dimethyl siloxane) cross-linked polymer.

<3>As described above<1>Or<2>Described in spraying cosmetics, wherein, the silicone elastomer of composition (A) is preferably flat Equal 0.1~20 μm of particle diameter, more preferably 1~10 μm.

<4>As described above<1>Extremely<3>Any one of record spraying cosmetics, wherein, the silicone elastomer of composition (A) is excellent Elect as and used in the form of the dispersion liquid mixed with water or unthickened fuel, it is more preferably scattered to be mixed with unthickened fuel The form of liquid uses.

<5>As described above<4>Described in spraying cosmetics, wherein, unthickened fuel is preferably that the viscosity at 25 DEG C is Below 100mPas, more preferably below 50mPas, and then preferably below 30mPas, and then more preferably 10mPa Below s.

<6>As described above<1>Extremely<5>Any one of the spraying cosmetics recorded, wherein, the content of composition (A) is preferably to exist It is more than 0.2 mass % in stoste, more preferably more than 0.4 mass %, and preferably below 0.8 mass %, more preferably 0.6 Below quality %.

<7>As described above<1>Extremely<6>Any one of record spraying cosmetics, wherein, the finish of composition (B) is preferably 25 Viscosity at DEG C is more than 2mPas, more preferably more than 3mPas, and then preferably more than 4mPas, and is preferably Below 50mPas, more preferably below 30mPas, and then more preferably below 20mPas.

<8>As described above<1>Extremely<7>Any one of the spraying cosmetics recorded, wherein, the finish of composition (B) is preferably to select From one kind or two or more in hydrocarbon ils, ester oil and silicone oil, more preferably hydrocarbon ils, monoester oil, three ester oils, silicone oil, and then be preferably Monoester oil, silicone oil, and then be more preferably and use monoester oil and silicone oil.

<9>As described above<1>Extremely<8>Any one of the spraying cosmetics recorded, wherein, the content of composition (B) is preferably to exist It is more than 2 mass % in stoste, more preferably more than 4 mass %, and preferably below 15 mass %, more preferably 12 mass % Below.

<10>As described above<1>Extremely<9>Any one of the spraying cosmetics recorded, wherein, the non-ionic surface of composition (C) is lived Property agent is preferably more than HLB7, more preferably more than 9, and then preferably more than 11, and preferably less than 18, more preferably 16 with Under, and then preferably less than 15.

<11>As described above<1>Extremely<10>Any one of record spraying cosmetics, wherein, the non-ionic surface of composition (C) Activating agent is preferably sorbitan carboxylic esterses, fatty acid glyceride, polyoxyethylene sorbitan carboxylic ester, polyoxyethylene alkane Base ether, Crodaret, more preferably fatty acid glyceride, polyoxyethylene sorbitan carboxylic ester, polyoxy second Allylic alkylation ether, Crodaret, and then preferably polyoxyethylene sorbitan carboxylic ester, polyethylene glycol hydrogenated castor Sesame oil, and then more preferably Crodaret.

<12>As described above<1>Extremely<11>Any one of record spraying cosmetics, wherein, the content of composition (C) is preferably It is more than 0.1 mass % in stoste, more preferably more than 0.3 mass %, and preferably below 2 mass %, more preferably 1 matter Measure below %.

<13>As described above<1>Extremely<12>Any one of record spraying cosmetics, wherein, composition (A) is relative to composition (C) Quality ratio [(A)/(C)] be preferably more than 0.05, more preferably more than 0.2, and then preferably more than 0.5, and preferably 3 Hereinafter, more preferably less than 2.2, and then preferably less than 1.4.

<14>As described above<1>Extremely<13>Any one of the spraying cosmetics recorded, wherein, the water-soluble thickening of composition (D) Agent is preferably carboxyl vinyl polymer, acrylic acid-methacrylic acid alkyl ester copolymer, more preferably acrylic acid-methyl-prop Olefin(e) acid alkyl ester copolymer.

<15>As described above<1>Extremely<14>Any one of record spraying cosmetics, wherein, the content of composition (D) is preferably It is more than 0.15 mass % in stoste, more preferably more than 0.2 mass %, and preferably below 0.8 mass %, more preferably Below 0.5 mass %.

<16>As described above<1>Extremely<15>Any one of record spraying cosmetics, wherein, composition (A) is relative to composition (D) Quality ratio [(A)/(D)] be preferably more than 0.2, more preferably more than 0.6, and then preferably more than 1, and preferably 10 with Under, more preferably less than 4, and then preferably less than 2.5.

<17>As described above<1>Extremely<16>Any one of record spraying cosmetics, wherein, the content of the water of composition (E) is excellent It is more than 55 mass % to elect as in stoste, more preferably more than 65 mass %, and then preferably more than 75 mass %, and preferably For below 95 mass %, more preferably below 93 mass %, and then preferably below 90 mass %.

<18>As described above<1>Extremely<17>Any one of the spraying cosmetics recorded, wherein, and then be selected from alkyl containing (G) It is one kind or two or more in glycerin ether modified silicone and polyoxyalkylene-modified silicone.

<19>As described above<18>Described in spraying cosmetics, wherein, composition (G) is preferably polyoxyalkylene-modified silicone, More preferably polyoxyethylene-methyl polysiloxane copolymer, poly- (oxyethylene-oxypropylene)-methyl polysiloxane copolymer, and then Polyoxyethylene-methyl polysiloxane copolymer preferably represented by formula (4)：

[in formula, R¹⁷~R¹⁹And R²¹~R²²Methyl or phenyl, R are represented respectively¹⁶、R²⁰And R²³Respectively represent methyl, phenyl, Or group R²⁴(OC₃H₆)_f(OC₂H₄)_gO(CH₂)_h-(R²⁴The alkyl of hydrogen atom or carbon number 1~12 is represented, f and g are average Value, and 0~35 number is represented respectively, h represents 1~5 number).Wherein, R¹⁶、R²⁰And R²³In at least one expression group R²⁴ (OC₃H₆)_f(OC₂H₄)_gO(CH₂)_h-.D and e is average value, and d represents 1~200 number, and e represents 0~50 number].

<20>As described above<18>Or<19>Described in spraying cosmetics, wherein, the content of composition (G) is preferably in stoste In be more than 0.05 mass %, more preferably more than 0.1 mass %, and then preferably more than 0.2 mass %, and preferably 1.5 Below quality %, more preferably below 1 mass %, and then preferably below 0.7 mass %.

<21>As described above<1>Extremely<20>Any one of record spraying cosmetics, wherein, and then containing (H) divalence it is polynary Alcohol.

<22>As described above<21>Described in spraying cosmetics, wherein, composition (H) is preferably propane diols (propylene Glycol), propane diols (propandiol), 1,3-BDO, 1,3-PD, DPG, more preferably 1,3-PD, DPG, and then be preferably and use 1,3-PD and DPG.

<23>As described above<21>Or<22>Described in spraying cosmetics, wherein, the content of composition (H) is preferably in stoste In be more than 1 mass %, more preferably more than 3 mass %, and then preferably more than 5 mass %, and preferably 20 mass % with Under, more preferably below 15 mass %, and then preferably below 10 mass %.

<24>As described above<1>Extremely<23>Any one of the spraying cosmetics recorded, wherein, and then containing in addition to preservative It is the finish of liquid at 25 DEG C beyond composition (B), at 25 DEG C in addition to preservative is finish beyond liquid.

<25>As described above<24>Described in spraying cosmetics, wherein, at 25 DEG C beyond composition (B) in addition to preservative Finish for liquid is preferably hydrocarbon ils, ester oil, silicone oil, more preferably hydrocarbon ils, monoester oil, three ester oils, silicone oil, and then is preferably single Ester oil, silicone oil, and then be more preferably and use monoester oil and silicone oil.

<26>As described above<24>Or<25>Described in spraying cosmetics, wherein, the composition in addition to preservative in stoste (B) content of the finish at 25 DEG C beyond for liquid is preferably more than 1 mass %, and preferably below 9 mass %, more preferably For below 7.5 mass %.

<27>As described above<24>Extremely<26>Any one of record spraying cosmetics, wherein, at 25 DEG C in addition to preservative Content for the finish beyond liquid is preferably to be below 3 mass % in stoste, more preferably below 1 mass %, Jin Eryou Elect as below 0.5 mass %, and then more preferably below 0.3 mass %, preferably below 0.1 mass %.

<28>As described above<24>Extremely<27>Any one of record spraying cosmetics, wherein, in stoste in addition to preservative 25 DEG C at be matter of the finish beyond liquid relative to the finish for being liquid at 25 DEG C beyond the composition (B) in addition to preservative Amount is than [(being the finish beyond liquid at 25 DEG C in addition to preservative)/(be at 25 DEG C beyond composition (B) in addition to preservative The finish of liquid)] it is preferably less than 0.1, more preferably less than 0.07, and then preferably less than 0.03.

<29>As described above<1>Extremely<28>Any one of the spraying cosmetics recorded, wherein, contained anion table in stoste The content of face activating agent is preferably below 1 mass %, more preferably below 0.1 mass %.

<30>As described above<1>Extremely<29>Any one of the spraying cosmetics recorded, wherein, powder beyond composition (A) Content is preferably below 3 mass %, more preferably below 1 mass %.

<31>As described above<1>Extremely<30>Any one of the spraying cosmetics recorded, the content of the wherein ethanol in stoste is excellent Elect as below 3 mass %, more preferably below 1 mass %, and then be preferably to be substantially free of.

<32>As described above<1>Extremely<31>Any one of record spraying cosmetics, wherein, the viscosity at 25 DEG C of stoste is excellent Elect more than 500mPas, more preferably more than 1000mPas, and then preferably more than 1500mPas as, and be preferably Below 20000mPas, more preferably below 10000mPas, and then preferably below 7000mPas.

<33>As described above<1>Extremely<32>Any one of record spraying cosmetics, wherein, the propellant of composition (F) is preferred For comprising more than the mass % of carbon dioxide 95, more preferably more than 98 mass %, and then preferably 100 mass %.

<34>As described above<1>Extremely<33>Any one of the spraying cosmetics recorded, wherein, the matter of stoste and (F) propellant It is preferably 94 to measure ratio:6~99.5:0.5, more preferably 95:5~99:1, and then preferably 96.5:3.5~98.5:1.5.

<35>As described above<1>Extremely<34>Any one of record spraying cosmetics, wherein, composition (A) is relative to composition (F) Quality ratio [(A)/(F)] be preferably more than 0.05, more preferably more than 0.1, and then preferably more than 0.12, and be preferably Less than 1, more preferably less than 0.4, and then preferably less than 0.3.

<36>One kind spraying cosmetics, wherein, contain following component (A), (B), (C), (D), (E) and (F)：

(A) average grain diameter be 0.01~30 μm silicone elastomer powder,

Finish that (B) viscosity at 25 DEG C is 1~100mPas,

(C) nonionic surfactant of HLB3~20,

(D) tackifier,

(E) water and

(F) more than the mass % of carbon dioxide 90 propellant is included, and

In the composition in addition to composition (F),

The content of mentioned component (A) is 0.1~1.5 mass %,

The content of mentioned component (B) is 1~25 mass %,

The content of mentioned component (C) is 0.05~6 mass %, and

The content of mentioned component (D) is 0.1~1 mass %.

<37>As described above<1>Extremely<36>Any one of record spraying cosmetics, wherein, composition (C) is preferably sorbierite Acid anhydride fatty acid ester, fatty acid glyceride, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan carboxylic ester, polyoxyethylene alkane Base ether, Crodaret, more preferably sorbitan carboxylic esterses, fatty acid glyceride, polyoxyethylene sorbitol Acid anhydride fatty acid ester, Crodaret, and then preferably sorbitan carboxylic esterses, Crodaret, And then more preferably Crodaret.

<38>A kind of application method for cosmetics of spraying, wherein, will as described above<1>Extremely<37>Any one of record spraying Cosmetic applications in, more preferably be coated on skin, be preferably face, body, trick any one.

<39>One kind is as described above<1>Extremely<37>Any one of record spraying cosmetics stoste manufacture method, wherein, Including following process 1,2.

Process 1：Composition (D) is mixed with part or all of (E) and prepares the work of the solution of containing water-soluble tackifier Sequence；

<40>As described above<39>Described in manufacture method, wherein, process 1 is preferably comprising being mixed under heating Process, and the temperature heated is preferably 20~80 DEG C, more preferably 40~60 DEG C.

<41>As described above<39>Or<40>Described in manufacture method, wherein, composition (D) for acid type water-soluble thickening Agent, preferably add alkali in process 1.

<42>As described above<39>Extremely<41>Any one of record manufacture method, wherein, process 2 be preferably be contained in heating The lower process mixed, and the temperature heated is preferably 20~80 DEG C, more preferably 40~60 DEG C.

<43>As described above<39>Extremely<42>Any one of record cooling manufacture method, wherein, process 2 be included in heating The lower process mixed, it is preferably that there is refrigerating work procedure after mixing, is preferably cooled to 20~30 DEG C, is more preferably cooled to 20~25 DEG C.

<44>A kind of method that infiltration improved to skin is felt, wherein, will as described above<1>Extremely<37>Any one of record Spraying cosmetics are coated on skin.

<45>A kind of method for the epithelium sense for obtaining skin, wherein, will as described above<1>Extremely<37>Any one of record spray Atomization cosmetic is coated on skin.

<46>One kind, which is made up, to be set with, and it is included as described above<1>Extremely<37>Any one of the spraying cosmetics and above-mentioned recorded Cosmetics beyond spraying cosmetics, preferably comprising toner or emulsion, more preferably comprising toner.

<47>A kind of application method for cosmetics of spraying, wherein, will as described above<1>Extremely<37>Any one of record spray Mist cosmetic applications or after being coated on skin, the cosmetics (other cosmetics) beyond the spraying cosmetics are applied or are coated on Using or be coated with the skin of the spraying cosmetics.

<48>As described above<47>Described in application method, wherein, other cosmetics are preferably that the content of carbon dioxide exists It is below 10 mass % in cosmetics, more preferably below 5 mass %, and then preferably below 1 mass %, and then more preferably Below 0.1 mass %, especially preferably it is essentially 0 mass %.

<49>As described above<47>Or<48>Described in application method, wherein, other cosmetics are preferably toner, breast Liquid, creams, more preferably toner or emulsion, and then preferably toner.

<50>As described above<47>Extremely<49>Any one of record application method, wherein, other cosmetics be preferably contain Water, and the content of water is 65~93 mass %, more preferably 70~92 mass % preferably in the total composition of other cosmetics.

<51>As described above<47>Extremely<50>Any one of record application method, wherein, other cosmetics be preferably contain Polyalcohol, and content is 3~40 mass %, more preferably 5~30 mass % preferably in the total composition of other cosmetics, is entered And preferably 7~25 mass %.

<52>As described above<47>Extremely<51>Any one of record application method, wherein, other cosmetics be preferably contain Polyoxyalkylene-modified silicone, and content is 0.005~2 mass % preferably in the total composition of other cosmetics, more preferably 0.01~1.0 mass %, and then preferably 0.015~0.5 mass %, and then more preferably 0.02~0.2 mass %.

<53>As described above<47>Extremely<52>Any one of record application method, wherein, other cosmetics be preferably contain Tackifier, and content is 0.001~1.0 mass % preferably in the total composition of other cosmetics, more preferably 0.01~0.5 mass %, and then preferably 0.05~0.3 mass %.

<54>As described above<47>Extremely<53>Any one of record application method, wherein, spraying cosmetics relative to other The usage rate [(usage amounts of spraying cosmetics)/(usage amounts of other cosmetics)] of the usage amount of cosmetics is preferably 0.2 ~6, more preferably 0.3~5, and then preferably 0.4~4.

<55>As described above<47>Extremely<54>Any one of record application method, wherein, will spraying cosmetic applications or It is coated on to starting that other cosmetic material applications are preferred in the time for the skin for applying or being coated with the spraying cosmetics after skin For 0 second~5 minutes, more preferably 3 seconds~3 minutes, and then preferably 5 seconds~1 minute.

<56>A kind of purposes of cosmetics in automiser spray, wherein, the cosmetics contain：

The mass % of finish 1~25 that (B) viscosity at 25 DEG C is 1~100mPas,

(C) the mass % of nonionic surfactant 0.05~6 of HLB3~20,

(D) the mass % of tackifier 0.1~1,

(E) water.

<57>A kind of purposes of cosmetics in automiser spray, wherein, the cosmetics contain following component (A), (B), (C), (D), (E) and (F)：

(A) average grain diameter be 0.01~30 μm silicone elastomer powder,

Finish that (B) viscosity at 25 DEG C is 1~100mPas,

(C) nonionic surfactant of HLB3~20,

(D) tackifier,

(E) water and

(F) more than the mass % of carbon dioxide 90 propellant is included, and

In the composition in addition to composition (F),

The content of mentioned component (A) is 0.1~1.5 mass %,

The content of mentioned component (B) is 1~25 mass %,

The content of mentioned component (C) is 0.05~6 mass %, and

The content of mentioned component (D) is 0.1~1 mass %.

<58>A kind of cosmetic product, wherein, cosmetics are filled in automiser spray, and the cosmetics contain：

The mass % of finish 1~25 that (B) viscosity at 25 DEG C is 1~100mPas,

(C) the mass % of nonionic surfactant 0.05~6 of HLB3~20,

(D) the mass % of tackifier 0.1~1,

(E) water.

<59>A kind of cosmetic product, wherein, cosmetics are filled in automiser spray, and the cosmetics contain following component (A), (B), (C), (D), (E) and (F)：

(A) average grain diameter be 0.01~30 μm silicone elastomer powder,

Finish that (B) viscosity at 25 DEG C is 1~100mPas,

(C) nonionic surfactant of HLB3~20,

(D) tackifier,

(E) water and

(F) more than the mass % of carbon dioxide 90 propellant is included, and

In the composition in addition to composition (F),

The content of mentioned component (A) is 0.1~1.5 mass %,

The content of mentioned component (B) is 1~25 mass %,

The content of mentioned component (C) is 0.05~6 mass %, and

The content of mentioned component (D) is 0.1~1 mass %.

[embodiment]

Production Example 1 (resin powder A manufacture)

Added into beaker lauryl methacrylate 82g, methacrylic acid 3g, ethylene glycol dimethacrylate 15g, Lauroyl peroxide 2g is simultaneously mixed and is made its dissolving.N- stearyl-N- methyl the oxen dissolved with 0.75g are added thereto The ion exchange water 400g of sodium sulfonate (SMT), make it scattered by homogenizer until average grain diameter turns into 2.2 μm.This is disperseed Liquid is injected into four-hole boiling flask, nitrogen displacement is carried out when stirring 30 minutes.The temperature of flask interior is added by oil bath Heat carries out polymerization 5 hours, is cooled to room temperature afterwards to 80 DEG C after reaching 80 DEG C.It is added dropwise into the dispersion liquid of the particle of polymerization After 1N NaOH 3.9g are neutralized, the dispersion liquid is freeze-dried, and reclaims particle, is derived from resin powder A (first Base lauryl acrylate, ethylene glycol dimethacrylate, Sodium methacrylate).The degree of neutralization of resin powder A carboxyl is 11.2%.

Embodiment 1~2 and comparative example 1~4

The spraying cosmetics of the composition shown in table 1 are manufactured, stoste viscosity, and extension to bubble, bubble pair are determined at 25 DEG C Skin infiltration sense, coating after skin epithelium sense and the affine of toner evaluated.Result is shown in table 1 in the lump.

(manufacture method)

Composition (A), (D) and (E) is stirred at 60 DEG C, and then mixed base and is stirred.And then adding ingredient thereafter, (B) and (C) and remaining composition, stir, and be cooled to 25 DEG C, obtain stoste.The stoste obtained is filled to pressure-resistant In container, after sealing, filling component (F), so as to obtain spraying cosmetics.

(evaluation method)

(1) extension of bubble：

Each cosmetics 0.2g is ejected on the black backing plate for the big polypropylene of A4 for being placed in plane, and with the backing plate Major axis mode perpendicular to the ground and erect, place 30 seconds, determine the length of cosmetics drip, carried out according to following benchmark Evaluation.Result is shown with total point of 5 times.

5；Extension is longer than 20cm.

4；Extension is longer than 18cm to below 20cm.

3；Extension is longer than 16cm to below 18cm.

2；Extension is longer than 14cm to below 16cm.

1；Only extend into below 14cm.

(2) infiltration sense (quantitative assessment) of the bubble to skin：

Each cosmetics 0.1g is ejected to the skin of inner forearm, in diameter 3cm circular size with 1 second 2 circle speed Degree massage 10 seconds.

Friction (a), its friction (b) after 1 minute of measure thereafter at once, calculate (b)-(a) value.Friction is to use The handy rub tester of trilab companies manufacture, apply 10N load and determine.

On friction, if remaining cosmetics on skin, resistance is less, therefore turns into less value, if not Cosmetics are remained, then resistance becomes big, therefore turns into larger value.Therefore, by calculating (b)-(a) value, according to cosmetics Residual condition infiltrates into that skin which kind of degree is evaluated to cosmetics.(b)-(a) value is bigger, represents that infiltration sense is better.

(3) infiltration sense (sensory evaluation) of the bubble to skin：

Each cosmetics 0.1g is ejected to the skin of inner forearm by 5 professional group members, in diameter 3cm size with The speed of 1 second 2 circle is massaged 1 minute, touches skin at once thereafter, the infiltration sense to bubble is evaluated.Benchmark, which will turn into, " substantially to be had The infiltration sense of bubble " is set to 5, and " the infiltration sense for not feeling bubble completely " is set into 15 grades.Furthermore so-called infiltration sense, is table Show that the solution of cosmetics does not residue in coated skin.Result is shown with total point of 5.

(4) the epithelium sense of the skin after being coated with：

Each cosmetics 0.1g is ejected to the skin of inner forearm by 5 professional group members, in diameter 3cm size with The speed of 1 second 2 circle is massaged 1 minute, touches skin at once thereafter, film sense is evaluated.Benchmark, which will turn into, " substantially to have epithelium Sense " is set to 5, " will not feel epithelium sense completely " and be set to 15 grades.Result is shown with total point of 5.

(5) toner is affine：

Each cosmetics 0.1g is ejected to the skin of inner forearm by 5 professional group members, in diameter 5cm size with The speed of 1 second 2 circle is massaged 1 minute, thereafter, is coated with commercially available toner (being set to toner 1) 0.2g, is similarly massaged 20 seconds, Thereafter skin is touched at once, and easy affinity is evaluated.Toner does not residue in skin after easy affinity represents massage.Benchmark 5 are set to as by " toner substantially disappears ", " toner substantially remains " is set to 15 grades.By result with the conjunction of 5 Score is shown.

[table 1]

* 1KSG-16 active ingredient, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI

KSG-16 is (Dimethicone/Vinyl Dimethicone) cross-linked polymer/KF-96A-6CS= 25/75

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 3Emalex OD-25, the manufacture of Nihon Emulsion companies：HLB14

* 4 silicone SH3775M, Dong Li Dow Corning Corporations manufacture：HLB5

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 6KELDENT, DSP five assists the manufacture of food ＆ chemical companies

* 7KF-96A-6CS, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI：Viscosity 6mPas

* 8Finsolv-TN, Innospec Active Chemicals LLC are manufactured：Viscosity 13mPas

Embodiment 3~24

The spraying cosmetics of the composition shown in 2~table of table 4 are manufactured in the same manner as embodiment 1~2, extension, bubble pair to bubble The epithelium sense of skin after the infiltration sense and coating of skin is evaluated.Result is shown in 2~table of table 4 in the lump.

[table 2]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 3Emalex OD-25, Nihon Emulsion companies：HLB14

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 9RHEODOL SP-S10V, KAO. Corp. SA's manufacture：HLB4.7

* 10EMANON 3199, KAO. Corp. SA's manufacture：HLB：19.4

* 11RHEODOL TW-S120V, KAO. Corp. SA's manufacture：HLB14.9

* 12Emalex SEG12, the manufacture of Nihon Emulsion companies：HLB11

[table 3]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 4SH3775M, Dong Li Dow Corning Corporation manufacture：HLB5

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 8Finsolv-TN, the manufacture of Innospec Active Chemicals LLC companies：Viscosity 13mPas

* 13TSF405, the manufacture of Co., Ltd of figure new high-tech material Japan advanced in years：Viscosity 5.9mPas

* 14KF56A, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI：Viscosity 15mPas

* 15PARLEAM EX, the manufacture of You companies：Viscosity 15m Pas

* 16Marukazol R, the manufacture of Wan Shan petrochemistry company：Viscosity 5mPas

* 17Nikkol saualanes, the manufacture of Nikko Chemicals companies：Viscosity 30mPas

* 18COCONARD MT, KAO. Corp. SA's manufacture：Viscosity 26mPas

[table 4]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 4SH3775M, Dong Li Dow Corning Corporation manufacture：HLB5

* 5PEMULEN TR-1, the manufacture of Lubrizol Advanced Materials, Inc. companies

* 7KP-96A-6cs, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI：Viscosity 6mPas

* 15PARLEAM EX, the manufacture of You companies：Viscosity 15mPas

* 19KSG-320 active ingredient, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI

KSG-320 is (PEG-15/ lauryl dimethicones) cross-linked polymer/Permethyl 99A=25/75

* 20KSG-41A active ingredient, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI

KSG-41A is (vinyldimethicone/lauryl dimethicone) cross-linked polymer/mineral oil =30/75

Test example 1

The viscosity of stoste to being used in embodiment 1 and embodiment 3 is measured.

That is, stoste 50g is filled in 50mL glass containers, passes through BM viscosimeters (manufacture of Dong Ji industry companies) (rotor No.3,12rpm, 1 minute) at 25 DEG C determine viscosity.Show the result in following.

Embodiment 1：2130mPa·s

Embodiment 3：3920mPa·s

Test example 2

To the spraying cosmetic evaluation " toner affine " of embodiment 4,11,12 and 24.Show the result in table 5.

(the affine evaluation method of toner)

Each spraying cosmetics 0.1g is set to be ejected to the skin of inner forearm by 5 professional group members, in the big of diameter 5cm The small speed with 1 second 2 circle is massaged 1 minute, is coated with 0.2g toner (Sofina core U.S. face (SOFINA beaute) change thereafter Adornment water (moist type), KAO. Corp. SA's manufacture), similarly massage 20 seconds, touch skin at once thereafter, easy affinity is commented Valency.Easy affinity is that toner does not residue in skin after representing massage.Benchmark turns into is set to 5 by " toner substantially disappears ", will " toner substantially remains " is set to 15 grades.Result is shown with total point of 5.

[table 5]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 3Emalex OD-25, Nihon Emulsion companies：HLB14

* 4SH3775M, Dong Li Dow Corning Corporation manufacture：HLB5

* 5PEMULEN TR-1Lubrizol Advanced Materials, Inc. are manufactured

* 9RHEODOL SP-S10V, KAO. Corp. SA's manufacture：HLB4.7

* 10EMANON 3199, KAO. Corp. SA's manufacture：HLB：19.4

* 11RHEODOL TW-S120V, KAO. Corp. SA's manufacture：HLB14.9

* 12Emalex SEG12, the manufacture of Nihon Emulsion companies：HLB11

Test example 3

To the spraying cosmetic evaluation " toner affine " of embodiment 3,5~10,13~23 in the same manner as test example 2. Show the result in 6~table of table 8.

[table 6]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 3Emalex OD-25, Nihon Emulsion companies：HLB14

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 7KF-96A-6CS, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI：Viscosity：6mPa·s

* 9RHEODOL SP-S10V, KAO. Corp. SA's manufacture：HLB4.7

* 10EMANON 3199, KAO. Corp. SA's manufacture：HLB：19.4

* 11RHEODOL TW-S120V, KAO. Corp. SA's manufacture：HLB14.9

* 12Emalex SEG12, the manufacture of Nihon Emulsion companies：HLB11

[table 7]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 4SH3775M, Dong Li Dow Corning Corporation manufacture：HLB5

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 7KF-98A-6cs, the manufacture of chemical industrial company of SHIN-ETSU HANTOTAI：Viscosity 6mPas

* 15PARLEAM EX, the manufacture of You companies：Viscosity 15mPas

* 18COCONARD MT, KAO. Corp. SA's manufacture：Viscosity 26mPas

[table 8]

KSG-16 is Dimethicone/Vinyl Dimethicone) cross-linked polymer/KF-96A-6CS= 25/75

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 4SH3775M, Dong Li Dow Corning Corporation manufacture：HLB5

* 5PEMULEN TR-1, the manufacture of Lubrizol Advanced Materials, Inc. companies

* 15PARLEAM EX, the manufacture of You companies：Viscosity 15mPas

Test example 4 (embodiment 25,26, comparative example 5~8)

The spraying cosmetics of the composition shown in table 9 are manufactured in the same manner as embodiment 1~2, the extension, bubble to bubble are to skin The epithelium sense of skin after infiltration sense and coating is evaluated.Also, evaluate " toner affine " in the same manner as test example 2.Will As a result table 9 is shown in the lump.

[table 9]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 3Emalex OD-25, the manufacture of Nihon Emulsion companies：HLB14

* 4 silicone SH3775M, Dong Li Dow Corning Corporations manufacture：HLB5

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 6KELDENT, DSP five assists the manufacture of food ＆ chemical companies

Test example 5

On and with the spraying cosmetics of embodiment 1 and the situation (side of commercially available toner (hereinafter referred to as toner 2) Method 1) and situation (method 2) using only toner 2, extension easness to toner, to the uniform tack of skin and The affine of toner is evaluated.Show the result in table 10.

(evaluation method)

(1) the extension easness of toner：

(method 1)

The spraying cosmetics 0.1g of embodiment 1 is ejected to the skin of inner forearm by 5 professional group members, in diameter 5cm size is massaged 1 minute with the speed of 1 second 2 circle, is coated with 0.2g toner 2 afterwards, is similarly massaged 20 seconds, now right The extension easness of the toner 2 of coating is evaluated.Benchmark, which turns into " easily to extend ", is set to 5, and " not ductile " is set into 1 5 grades.Result is shown with total point of 5.

(method 2)

In addition to the spraying cosmetics of embodiment 1 are not used, evaluated in the same manner as method 1.

(2) to the uniform tack of skin：

(method 1)

The spraying cosmetics 0.03g of embodiment 1 is ejected to 3 × 7cm of skin of inner forearm²Size, equably apply Cloth.Thereafter, it is coated with the 0.01g stilbene biphenyl disulfonate as water soluble fluorescence agent for being mixed with 100ppm The toner 2 of (Tinopal CBS-X, the manufacture of Ciba Specialty Chemicals companies), in black light lamp (Blacklight 27 watts of Blue FPL27BLB, three common-battery gas companies manufacture) under use digital S.L.R (machine：EOS 60D, lens： EF100mm F2.8micro USM, Canon Inc. manufacture) shooting coating part photo.By 5 professional group members according to the photograph The distribution of piece visual valuation toner 2.Benchmark, which turns into " equably to adhere to ", is set to 5, " will unevenly adhere to " and be set to the 5 of 1 Individual grade.Result is shown with total point of 5.

(method 2)

Furthermore the image of the photo of shooting is shown in Fig. 1.

(3) toner is affine：

(method 1)

In addition to using toner 2 as toner, evaluated in the same manner as test example 2.

(method 2)

[table 10]

Embodiment 27 and 28

The spraying cosmetics of table 11 and the composition shown in table 12 are manufactured in the same manner as embodiment 1~2.

The extension of the bubble of the spraying cosmetics obtained is good, and the infiltration sense steeped to skin is excellent, skin after coating Obtain epithelium sense.Also, the spraying cosmetics of the present invention are coated on to the infiltration sense raising of used other cosmetics after skin.

[table 11]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 4 silicone SH3775M, Dong Li Dow Corning Corporations manufacture：HLB5

* 21Carbopol 980, Lubrizol Advanced Materials, Inc. manufactures

* 22HEC Daicel SE850K, the manufacture of Daicel FineChem companies

* 23ESTEMOL NO1, the manufacture of Nisshin OilliO Group companies：Viscosity 19mPas

* 24CROPURE OL-LQ- (JP), the manufacture of Croda International companies：Viscosity 71mPas

* 25Cosmol 42V, the manufacture of Nisshin OilliO Group companies

[table 12]

* 2EMANON CH60K, KAO. Corp. SA's manufacture：HLB14

* 4 silicone SH3775M, Dong Li Dow Corning Corporations manufacture：HLB5

* 5PEMULEN TR-1, Lubrizol Advanced Materials, Inc. manufactures

* 6KELDENT, DSP five assists the manufacture of food ＆ chemical companies

* 26SALACOS 913, the manufacture of Nisshin OilliO Group companies：Viscosity 11mPas

* 27 Japanese Patent Laid-Open 9-67241 publications are recorded, the cetyl -1,3- dimethyl butyl ether of synthesis example 3： Viscosity 8mPas

Reference example 1

The present invention spraying cosmetics be by applying or being coated on skin after, by other cosmetics beyond the present invention should With or be coated on application or be coated with the skin of the spraying cosmetics, and improve the infiltration sense of other cosmetics, and improve other The extension of cosmetics.

In this way, as used other cosmetics after the spraying cosmetics of the present invention, there is no particular restriction, as one Example, the toner of the composition shown in table 13 can be enumerated.

[table 13]

Composition (quality %)	Reference example 1
		Glycerine	8
DPG	2
		Sodium dihydrogen phosphate	0.036
Dibastic sodium phosphate	0.029
		Polyethylene glycol 1540	1
Pulullan polysaccharide * 28	0.2
		Polyoxyethylene-methyl polysiloxane copolymer * 29	0.1
Sodium Hyaluronate * 30	0.001
		Phenoxetol	0.4
Purified water	Surplus
		It is total	100

* 28 pulullan polysaccharides used for cosmetic, the manufacture of Lin Yuan companies

* 29 silicone SS-2804, Dong Li Dow Corning Corporations manufacture

* 30 hyalomitome acid solution HA-LQ1E, Yong Guangtang head store companies manufacture

Claims

1. one kind spraying cosmetics, wherein,

Contain：Stoste is integrally set to 100 mass % and includes following component (A), (B), (C), (D) and (E) stoste；And (F) more than the mass % of carbon dioxide 90 propellant is included,

The mass % of finish 1~25 that (B) viscosity at 25 DEG C is 1~100mPas,

(C) the mass % of nonionic surfactant 0.05~6 of HLB3~20,

(D) the mass % of tackifier 0.1~1,

(E) water.

2. spraying cosmetics as claimed in claim 1, wherein,

Composition (B) is one kind or two or more in hydrocarbon ils, ester oil and silicone oil.

3. spraying cosmetics as claimed in claim 1 or 2, wherein,

Composition (A) is 0.05~3 relative to composition (C) quality ratio (A)/(C).

4. such as spraying cosmetics according to any one of claims 1 to 3, wherein,

Composition (A) is 0.2~10 relative to composition (D) quality ratio (A)/(D).

5. such as spraying cosmetics according to any one of claims 1 to 4, wherein,

Composition (A) is 0.05~1 relative to composition (F) quality ratio (A)/(F).

6. such as spraying cosmetics according to any one of claims 1 to 5, wherein,

Composition (D) for a kind or 2 kinds in carboxyl vinyl polymer, acrylic acid-methacrylic acid alkyl ester copolymer with On.

7. such as spraying cosmetics according to any one of claims 1 to 6, wherein,

It is and then one kind or two or more in alkyl glycerylether modified silicone and polyoxyalkylene-modified silicone containing composition (G).

8. such as spraying cosmetics according to any one of claims 1 to 7, wherein,

It is and then one kind or two or more in divalence polyalcohol containing composition (H).

9. one kind spraying cosmetics, wherein,

Contain following component (A), (B), (C), (D), (E) and (F)：

(A) average grain diameter be 0.01~30 μm silicone elastomer powder,

Finish that (B) viscosity at 25 DEG C is 1~100mPas,

(C) nonionic surfactant of HLB3~20,

(D) tackifier,

(E) water and

(F) more than the mass % of carbon dioxide 90 propellant is included, and

In the composition in addition to composition (F),

The content of mentioned component (A) is 0.1~1.5 mass %,

The content of mentioned component (B) is 1~25 mass %,

The content of mentioned component (C) is 0.05~6 mass %, and

The content of mentioned component (D) is 0.1~1 mass %.