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CN107587136A - A kind of brass polish cream of viscosity stabilization - Google Patents

A kind of brass polish cream of viscosity stabilization Download PDF

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Publication number
CN107587136A
CN107587136A CN201710593272.0A CN201710593272A CN107587136A CN 107587136 A CN107587136 A CN 107587136A CN 201710593272 A CN201710593272 A CN 201710593272A CN 107587136 A CN107587136 A CN 107587136A
Authority
CN
China
Prior art keywords
viscosity stabilization
component
thickener
polish cream
brass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710593272.0A
Other languages
Chinese (zh)
Inventor
何宗文
侯伟
何宗俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEFEI PURECHEM ADVANCE MATERIALS SCIENCE AND TECHNOLOGY Co Ltd
Original Assignee
HEFEI PURECHEM ADVANCE MATERIALS SCIENCE AND TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HEFEI PURECHEM ADVANCE MATERIALS SCIENCE AND TECHNOLOGY Co Ltd filed Critical HEFEI PURECHEM ADVANCE MATERIALS SCIENCE AND TECHNOLOGY Co Ltd
Priority to CN201710593272.0A priority Critical patent/CN107587136A/en
Publication of CN107587136A publication Critical patent/CN107587136A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to metal surface clean technologies field, is specifically related to a kind of brass polish cream of viscosity stabilization.It is made up of abrasive material, organic solvent, thickener, Ludox, Ludox stabilizer, essence and water.The brass polish cream of viscosity stabilization is prepared by special preparation technology, for the surface cleaning of the large-scale copper class ornaments such as hotel, hotel, reaches mirror effect.

Description

A kind of brass polish cream of viscosity stabilization
Technical field
The present invention relates to metal surface clean technologies field, is specifically related to a kind of brass polish cream of viscosity stabilization
Background technology
Copper and its alloy polishing are also known as bright dipped finish, substantially have three acid cleanings and are cleaned containing chromium, three acid formula speed Degree is fast, and pickling light extraction bright property is good, therefore application surface is most wide.But the disadvantage of three acid formulas is strong reaction, is soaked in workpiece Enter the moment of polishing fluid, i.e., can produce the largely tobacco with pungent taste, pollution air, poison environment, influence worker's health. And cleaned containing chromium in inorganic agent used and contain Cr6+, hexavalent chromium compound belongs to extremely toxic and carcinogenicity material, has mutagenesis. European Union successively promulgates in January, 2003《On limiting the instruction using some harmful substances in electronic and electrical equipment》And 《Instructed on waste electronic andelectrical equipment》, it is desirable to each member state works out corresponding standard regulation in before the part of in August, 2004 have The specific requirement of evil material, such as lead, Cr VI.It, which is sought unity of standard, put into effect in 2005 and was forced from 1 day July in 2006 real OK.
Such cleaning agent is liquid simultaneously, needs soaking and washing, clear for the surface of the large-scale copper class ornaments such as hotel, hotel It is clean to have certain difficulty, it is even more impossible for large-scale statue in bronze, therefore, it is necessary to develop a kind of brass polish cream of stabilization, simplification is clear Clean technique, mirror effect is can reach by wiping by hand, the cleaning for the ornaments of large-scale copper has certain application market.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to a kind of brass polish cream of stabilization is provided, by abrasive material, You Jirong Agent, thickener, Ludox, Ludox stabilizer, essence and water composition.Viscosity stabilization is prepared by special preparation technology Brass polish cream, for the surface cleaning of the large-scale copper class ornaments such as hotel, hotel, minute surface effect is just can reach only by simple wiping Fruit.
To achieve the above object, present invention employs following technical scheme:
A kind of brass polish cream of viscosity stabilization, it is characterised in that be made up of the raw material of following parts by weight:
Described thickener includes:Component (a) is in carboxymethyl cellulose, methylcellulose, hydroxyethyl cellulose It is a kind of;Component (b) is selected from polyvinyl alcohol.The weight ratio of the component (a) and the component (b) is 5:5~9:1.
The alcoholysis degree of component polyvinyl alcohol in the thickener is 60-90%, degree of polymerization 500-3000.
Described Ludox is 40-60nm cataloids selected from particle diameter.
Described Ludox stabilizer is selected from KBM-602.
The one kind of described organic solvent in ethanol, ethylene glycol, glycol monoethyl ether, ethylene glycol monobutyl ether.
The preparation method of the brass polish cream of described viscosity stabilization, it is characterised in that:
(1) first the component (b) of the thickener component (a) of weighing and 50% is incorporated in water, is heated to 60 DEG C, 800- 10-20min is stirred under 1000rpm, it is standby to obtain viscosity stabilization, uniform solubilizer solution A.
(2) under 800-1000rpm stirrings, it is stable that abrasive material, Ludox, Ludox are sequentially added in thickener soln A Agent, organic solvent and essence, stirring at normal temperature uniformly obtain mixture B.Often plus a kind of raw material must assure that and add again after being well mixed Enter another raw material.
(3) in the case where 800-1000rpm is stirred, it is molten that remaining 50% component (b) thickener is added into mixture B Liquid carries out viscosity fine setting, and obtains the product.
The application process of the brass polish cream of described viscosity stabilization:Take out part brass polish cream to be applied on clean rag, by hand Mode is wiped on the surface of copper, is wiped with clean step remove unnecessary dosage component afterwards.
The present invention prepares the brass polish cream of viscosity stabilization by special preparation technology, is answered using two kinds of different thickeners With stable brass polish cream is prepared, mode of operation is simple and convenient, and mirror effect is can reach by simple wiping, for hotel, guest The oily certain market of the surface cleaning of the large-scale copper class ornaments such as shop.
Embodiment
Below with reference to embodiment, the present invention is described in detail.But embodiment content is only to this hair Bright example and explanation, affiliated those skilled in the art do various repair to described specific embodiment Change or supplement or substituted using similar mode, design without departing from invention or surmount defined in the claims Scope, protection scope of the present invention all should be belonged to.
Thickener soln A preparation:
Total amount/g Component (a) Dosage/g 50% component (b) Dosage/g
Thickener A1 0.5 Carboxymethyl cellulose 0.25 Polyvinyl alcohol 0.125
Thickener A2 2 Methylcellulose 1.8 Polyvinyl alcohol 0.1
Thickener A3 3 Hydroxyethyl cellulose 2.7 Polyvinyl alcohol 1.5
Preparation method:First the component (b) of the thickener component (a) of metering and 50% is incorporated in water, is heated to 60 DEG C, 10-20min is stirred under 800-1000rpm, it is standby to obtain viscosity stabilization, uniform solubilizer solution A.
Embodiment preparation method:
(1) under 800-1000rpm stirrings, it is stable that abrasive material, Ludox, Ludox are sequentially added in thickener soln A Agent, organic solvent and essence, stirring at normal temperature uniformly obtain mixture B.Often plus a kind of raw material must assure that and add again after being well mixed Enter another raw material.
(3) in the case where 800-1000rpm is stirred, it is molten that remaining 50% component (b) thickener is added into mixture B Liquid carries out viscosity fine setting, and obtains the product.
Performance test:According to the copper surface after wiping, surface cleanliness and brightness are estimated, respectively according to such as the following grading Row judges:
1 grade of surface free from dust and oxide skin, reach mirror effect
2 grades of surface free from dust and oxide skin, but brightness is not good enough
3 grades of surfaces are poor without greasy dirt, visible a small amount of selective oxidation skin, brightness
4 grades of surfaces do not clean up, hence it is evident that visible oxide skin, brightness are poor
Embodiment Embodiment 1 Embodiment 2 Embodiment 3
Grade 1 1 1

Claims (8)

1. a kind of brass polish cream of viscosity stabilization, it is characterised in that be made up of the raw material of following parts by weight:
2. the brass polish cream of viscosity stabilization as claimed in claim 1, it is characterised in that:Described thickener includes:Component (a) is selected One kind from carboxymethyl cellulose, methylcellulose, hydroxyethyl cellulose;Component (b) is selected from polyvinyl alcohol.
3. the brass polish cream of the viscosity stabilization as described in claim 1 or 2, it is characterised in that:Described group in the thickener It is 5 to divide (a) and the weight ratio of the component (b):5~9:1.
4. the brass polish cream of the viscosity stabilization as described in claim 1 and 2, it is characterised in that:Component in the thickener is gathered The alcoholysis degree of vinyl alcohol is 60-90%, degree of polymerization 500-3000.
5. the brass polish cream of viscosity stabilization as claimed in claim 1, it is characterised in that:Described Ludox is 40- selected from particle diameter 60nm cataloids.
6. the brass polish cream of viscosity stabilization as claimed in claim 1, it is characterised in that:Described Ludox stabilizer is selected from KBM- 602。
7. the brass polish cream of viscosity stabilization as claimed in claim 1, it is characterised in that:Described organic solvent is selected from ethanol, second One kind in glycol, glycol monoethyl ether, ethylene glycol monobutyl ether.
A kind of 8. preparation method of the brass polish cream of viscosity stabilization as described in claim 1-7, it is characterised in that:
(1) first the component (b) of the thickener component (a) of weighing and 50% is incorporated in water, is heated to 60 DEG C, 800- 10-20min is stirred under 1000rpm, it is standby to obtain viscosity stabilization, uniform solubilizer solution A.
(2) under 800-1000rpm stirrings, abrasive material, Ludox is sequentially added in thickener soln A, Ludox stabilizer, is had Solvent and essence, stirring at normal temperature uniformly obtain mixture B.Often plus a kind of raw material must assure that and be added in addition after being well mixed A kind of raw material.
(3) in the case where 800-1000rpm is stirred, remaining 50% component (b) thickener soln is added into mixture B and is entered Row viscosity is finely tuned, and obtains the product.
CN201710593272.0A 2017-07-19 2017-07-19 A kind of brass polish cream of viscosity stabilization Pending CN107587136A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710593272.0A CN107587136A (en) 2017-07-19 2017-07-19 A kind of brass polish cream of viscosity stabilization

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710593272.0A CN107587136A (en) 2017-07-19 2017-07-19 A kind of brass polish cream of viscosity stabilization

Publications (1)

Publication Number Publication Date
CN107587136A true CN107587136A (en) 2018-01-16

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CN201710593272.0A Pending CN107587136A (en) 2017-07-19 2017-07-19 A kind of brass polish cream of viscosity stabilization

Country Status (1)

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CN (1) CN107587136A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112552874A (en) * 2020-12-03 2021-03-26 北京华夏非遗襄阳文化产业有限公司 Noble metal surface cleaning paste and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510091A (en) * 2002-12-23 2004-07-07 陈宝福 Producing method for stone mirror effect polishing paste
US20130313225A1 (en) * 2012-05-22 2013-11-28 Cabot Microelectronics Corporation Cmp composition containing zirconia particles and method of use
CN104263248A (en) * 2014-09-26 2015-01-07 深圳市力合材料有限公司 Weakly acidic copper polishing solution applicable to low downforce
CN106283061A (en) * 2015-05-15 2017-01-04 新昌县金声铜业有限公司 A kind of novel environment friendly brass work polishing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510091A (en) * 2002-12-23 2004-07-07 陈宝福 Producing method for stone mirror effect polishing paste
US20130313225A1 (en) * 2012-05-22 2013-11-28 Cabot Microelectronics Corporation Cmp composition containing zirconia particles and method of use
CN104263248A (en) * 2014-09-26 2015-01-07 深圳市力合材料有限公司 Weakly acidic copper polishing solution applicable to low downforce
CN106283061A (en) * 2015-05-15 2017-01-04 新昌县金声铜业有限公司 A kind of novel environment friendly brass work polishing

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘云等: "《日用化学品原材料技术手册》", 31 October 2003, 化学工业出版社化学与应用化学出版中心 *
李东光等: "《实用化工产品配方与制备(九)》", 31 August 2013, 中国纺织出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112552874A (en) * 2020-12-03 2021-03-26 北京华夏非遗襄阳文化产业有限公司 Noble metal surface cleaning paste and preparation method and application thereof
CN112552874B (en) * 2020-12-03 2021-10-15 北京华夏非遗襄阳文化产业有限公司 Noble metal surface cleaning paste and preparation method and application thereof
WO2022117048A1 (en) * 2020-12-03 2022-06-09 北京华夏非遗襄阳文化产业有限公司 Noble metal surface cleaning paste, and preparation method therefor and application thereof

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