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CN107488406A - Waterproof Quick Response Code braider steel fibre kernmantle - Google Patents

Waterproof Quick Response Code braider steel fibre kernmantle Download PDF

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Publication number
CN107488406A
CN107488406A CN201710789541.0A CN201710789541A CN107488406A CN 107488406 A CN107488406 A CN 107488406A CN 201710789541 A CN201710789541 A CN 201710789541A CN 107488406 A CN107488406 A CN 107488406A
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Prior art keywords
steel fibre
quick response
response code
waterproof quick
component
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Pending
Application number
CN201710789541.0A
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Chinese (zh)
Inventor
桑国海
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Wuhu Performance Number Electronic Science And Technology Co Ltd
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Wuhu Performance Number Electronic Science And Technology Co Ltd
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Priority to CN201710789541.0A priority Critical patent/CN107488406A/en
Publication of CN107488406A publication Critical patent/CN107488406A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • C08K2003/2213Oxides; Hydroxides of metals of rare earth metal of cerium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of waterproof Quick Response Code braider steel fibre kernmantle, waterproof Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, the surface of steel fibre is provided with corrosion resistant coating layer, the corrosion resistant coating layer is formed by dry after the surface coating corrosion-resistant of the steel fibre, and the corrosion resistant coating is prepared by following steps:1) organic siliconresin, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, ethylene glycol is heat-treated so that component I is made;2) chlorinated rubber, mannitol, ethylene-vinyl acetate emulsion, expanded graphite, nano oxidized ruthenium, nano oxidized samarium, propane diols is heat-treated so that component II is made;3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.The waterproof Quick Response Code braider steel fibre kernmantle has excellent decay resistance.

Description

Waterproof Quick Response Code braider steel fibre kernmantle
Technical field
The present invention relates to motor, in particular it relates to a kind of waterproof Quick Response Code braider steel fibre kernmantle.
Background technology
Quick Response Code only needs to scan in daily life two-dimentional in many cases as a kind of simply and easily technology Code can be operated a lot, thus its use range is more and more extensive, and the field used is also more and more.And Quick Response Code conduct A kind of pattern, its carrier is also a lot, and yarn fabric is as the necessary article in daily life, although application field is extremely wide, it is made For Quick Response Code carrier when often because Quick Response Code is pattern, thus need to be printed on fabric by printing, and the figure of Quick Response Code Case is also often changing, thus needs often to change the mould of printing, so as to bring great loss to production, greatly increases life Produce cost.And be knitted on fabric then often because two-dimentional code line discoloration change it is complex so that in practical operation often Braider is easily damaged, especially chain wheel rope long term wear, easily causes the damage of chain wheel rope, so as to greatly increase maintenance into This.
The content of the invention
It is an object of the invention to provide a kind of waterproof Quick Response Code braider steel fibre kernmantle, the waterproof Quick Response Code braider Steel fibre kernmantle has excellent decay resistance.
To achieve these goals, the invention provides a kind of waterproof Quick Response Code braider steel fibre kernmantle, waterproof two Dimension code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant coating layer, described resistance to Etching ground layer be by after the surface coating corrosion-resistant of the steel fibre drying form, the corrosion resistant coating by with Lower step is prepared:
1) by organic siliconresin, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second Glycol is heat-treated so that component I is made;
2) by chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano oxidized ruthenium, nano oxidized samarium, Propane diols is heat-treated so that component II is made;
3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.
In the above-mentioned technical solutions, the present invention is resistance to be formed by brushing specific corrosion resistant coating on kernmantle shell Etching ground layer, there is excellent anticorrosion effect by the combination of each component dope layer in corrosion resistant coating, In particular for the corrosion of wet environment, and then play a part of protecting kernmantle, and then cause the kernmantle to be applied to humidity Environment.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The invention provides a kind of waterproof Quick Response Code braider steel fibre kernmantle, the waterproof Quick Response Code braider steel fibre Kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant coating layer, and the corrosion resistant coating layer is to pass through Drying is formed after the surface coating corrosion-resistant of the steel fibre, and the corrosion resistant coating is prepared by following steps:
1) by organic siliconresin, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second Glycol is heat-treated so that component I is made;
2) by chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano oxidized ruthenium, nano oxidized samarium, Propane diols is heat-treated so that component II is made;
3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.
In above-mentioned steps 1) in, the dosage of each material can select in wide scope, but in order that kernmantle has More excellent anticorrosive performance, it is preferable that in step 1), organic siliconresin, epoxy resin, pentaerythritol, trbasic zinc phosphate, hexamethylene Ketone, cobalt naphthenate, alumina silicate fibre, the weight ratio of ethylene glycol are 10:2-5:11-15:0.8-1.2:5-10:1-1.5:0.1- 0.3:10-15.
In above-mentioned steps 1) in, be heat-treated condition can select in wide scope, but in order that kernmantle has More excellent anticorrosive performance, it is preferable that in step 1), heat treatment meets following condition:Temperature is 85-95 DEG C, time 4- 6h, and carried out in the case where rotating speed is 1000-1500rpm stirring condition.
In above-mentioned steps 1) in, the concrete composition and processing mode of organic siliconresin can select in wide scope, But in order that kernmantle has more excellent anticorrosive performance, it is preferable that in step 1), organic siliconresin is by by methyl Trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and dichloromethyl phenylsilane are according to 1:1- 1.2:0.4-0.6:0.8-1.2:0.1-0.4 weight ratio is processed 2-5h under conditions of vacuum condition, 150-180 DEG C and formed.
In above-mentioned steps 2) in, the dosage of each material can select in wide scope, but in order that kernmantle has More excellent anticorrosive performance, it is preferable that in step 2), chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expansion stone Black, nano oxidized ruthenium, nano oxidized samarium, the weight ratio of propane diols are 10:18-22:5-10:0.1-0.4:0.08-0,10: 0.08-0.12:20-25.
In above-mentioned steps 2) in, the condition of heat treatment in wide scope to select, but in order that kernmantle has more Excellent anticorrosive performance, it is preferable that in step 2), heat treatment meets following condition:Temperature is 65-75 DEG C, time 4-6h, And carried out in the case where rotating speed is 1000-1500rpm stirring condition.
In above-mentioned steps 2) in, the average grain diameter of trbasic zinc phosphate in wide scope to select, but in order that kernmantle has There is more excellent anticorrosive performance, it is preferable that in step 2), nano oxidized ruthenium, the average grain diameter of nano oxidized samarium are 5-10nm.
In above-mentioned steps 2) in, the weight average molecular weight of chlorinated rubber in wide scope to select, but in order that braiding Rope has more excellent anticorrosive performance, it is preferable that in step 2), the weight average molecular weight of chlorinated rubber is 3000-5000.
In above-mentioned steps 3) in, the dosage of each material can select in wide scope, but in order that kernmantle has More excellent anticorrosive performance, it is preferable that in step 3), component I and component II weight ratio is 2:1.4-1.7.
In above-mentioned steps 3) in, the condition of mixing can select in wide scope, but in order that kernmantle has more Excellent anticorrosive performance, it is preferable that in step 3), mixing meets following condition:Temperature is 45-55 DEG C, time 2-3h, and And carried out in the case where rotating speed is 1000-1500rpm stirring condition.
The present invention will be described in detail by way of examples below.
Preparation example 1
By methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and aminomethyl phenyl two Chlorosilane is according to 1:1.1:0.5:0.9:0.3 weight ratio processes 3h under conditions of vacuum condition, 170 DEG C and organosilicon tree is made Fat A1.
Preparation example 2
By methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and aminomethyl phenyl two Chlorosilane is according to 1:1:0.4:0.8:0.1 weight ratio processes 2h under conditions of vacuum condition, 150 DEG C and organic siliconresin is made A1。
Preparation example 3
By methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and aminomethyl phenyl two Chlorosilane is according to 1:1.2:0.6:1.2:0.4 weight ratio processes 5h under conditions of vacuum condition, 180 DEG C and organosilicon tree is made Fat A1.
Embodiment 1
Waterproof Quick Response Code braider steel fibre kernmantle B1:
The waterproof Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant Dope layer is lost, the corrosion resistant coating layer is formed by dry after the surface coating corrosion-resistant of the steel fibre, institute Corrosion resistant coating is stated to be prepared by following steps:
1) by organic siliconresin A1, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, Ethylene glycol is according to 10:4:13:1.0:8:1.3:0.2:13 weight ratio be heat-treated (temperature be 90 DEG C, time 5h, and Carried out in the case where rotating speed is 1300rpm stirring condition) with obtained component I;
2) by chlorinated rubber (weight average molecular weight 4000), mannitol, ethene-vinyl acetate emulsion, expanded graphite, nanometer Cerium oxide (average grain diameter 8nm), nano silicon oxide (average grain diameter 8nm), propane diols are according to 10:20:8:0.3:0.09: 0.11:23 weight ratio be heat-treated (temperature be 70 DEG C, time 5h, and rotating speed be 120rpm stirring condition under Carry out) with obtained component II;
3) under pressure, by component I and component II according to 2:1.5 weight ratio mixed (temperature be 50 DEG C, Time is 2.5h, and is carried out in the case where rotating speed is 1300rpm stirring condition) with obtained corrosion resistant coating.
Embodiment 2
Waterproof Quick Response Code braider steel fibre kernmantle B2:
The waterproof Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant Dope layer is lost, the corrosion resistant coating layer is formed by dry after the surface coating corrosion-resistant of the steel fibre, institute Corrosion resistant coating is stated to be prepared by following steps:
1) by organic siliconresin A2, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, Ethylene glycol is according to 10:2:11:0.8:5:1:0.1:10 weight ratio be heat-treated (temperature be 85 DEG C, time 4h, and Rotating speed is to be carried out under 1000rpm stirring condition) with obtained component I;
2) by chlorinated rubber (weight average molecular weight 3000), mannitol, ethene-vinyl acetate emulsion, expanded graphite, nanometer Cerium oxide (average grain diameter 5nm), nano silicon oxide (average grain diameter 5nm), propane diols are according to 10:18:5:0.1:0.08: 0.08:20 weight ratio be heat-treated (temperature be 65 DEG C, time 4h, and rotating speed be 1000rpm stirring condition under Carry out) with obtained component II;
3) under pressure, by component I and component II according to 2:1.4 weight ratio mixed (temperature be 45 DEG C, Time is 2h, and is carried out in the case where rotating speed is 1000rpm stirring condition) with obtained corrosion resistant coating.
Embodiment 3
Waterproof Quick Response Code braider steel fibre kernmantle B3:
The waterproof Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant Dope layer is lost, the corrosion resistant coating layer is formed by dry after the surface coating corrosion-resistant of the steel fibre, institute Corrosion resistant coating is stated to be prepared by following steps:
1) by organic siliconresin A3, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, Ethylene glycol is according to 10:5:15:1.2:10:1.5:0.3:15 weight ratio be heat-treated (temperature be 95 DEG C, time 6h, and And carried out in the case where rotating speed is 1500rpm stirring condition) with obtained component I;
2) by chlorinated rubber (weight average molecular weight 5000), mannitol, ethene-vinyl acetate emulsion, expanded graphite, nanometer Cerium oxide (average grain diameter 10nm), nano silicon oxide (average grain diameter 10nm), propane diols are according to 10:22:10:0.4:0, 10:0.12:25 weight ratio is heat-treated, and (temperature is 75 DEG C, time 6h, and the stirring bar in rotating speed for 1500rpm Carried out under part) with obtained component II;
3) under pressure, by component I and component II according to 2:1.7 weight ratio mixed (temperature be 55 DEG C, Time is 3h, and is carried out in the case where rotating speed is 1500rpm stirring condition) with obtained corrosion resistant coating.
Comparative example 1
Waterproof Quick Response Code braider steel fibre kernmantle C1 is made according to the setting of embodiment 1, unlike, in step 3) Component I is not used.
Comparative example 2
Waterproof Quick Response Code braider steel fibre kernmantle C2 is made according to the setting of embodiment 1, unlike, in step 3) Component II is not used.
Detect example 1
Above-mentioned waterproof Quick Response Code braider steel fibre kernmantle is placed at 80 DEG C and dries 5h, note of then weighing W1;Then Above-mentioned kernmantle is placed in 35 DEG C, humidity is to be placed 30 days in 60% environment, note of then weighing W2;Then calculate W2/W1's Ratio, concrete outcome are shown in Table 1.
Table 1
B1 B1 B3 C1 C2
W2/W1 1.012 1.010 1.013 1.133 1.140
By above-described embodiment and comparative example, Quick Response Code braider steel fibre kernmantle provided by the invention has excellent Different corrosion resistance.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should equally be considered as content disclosed in this invention.

Claims (10)

  1. A kind of 1. waterproof Quick Response Code braider steel fibre kernmantle, it is characterised in that the waterproof Quick Response Code braider steel fibre Kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant coating layer, and the corrosion resistant coating layer is to pass through Drying is formed after the surface coating corrosion-resistant of the steel fibre, and the corrosion resistant coating is prepared by following steps:
    1) by organic siliconresin, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, ethylene glycol It is heat-treated so that component I is made;
    2) by chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano oxidized ruthenium, nano oxidized samarium, the third two Alcohol is heat-treated so that component II is made;
    3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.
  2. 2. waterproof Quick Response Code braider steel fibre kernmantle according to claim 1, it is characterised in that in step 1), The organic siliconresin, epoxy resin, pentaerythritol, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, the weight of ethylene glycol Amount is than being 10:2-5:11-15:0.8-1.2:5-10:1-1.5:0.1-0.3:10-15.
  3. 3. waterproof Quick Response Code braider steel fibre kernmantle according to claim 1, it is characterised in that in step 1), The heat treatment meets following condition:Temperature is 85-95 DEG C, time 4-6h, and is stirring for 1000-1500rpm in rotating speed Carried out under the conditions of mixing.
  4. 4. waterproof Quick Response Code braider steel fibre kernmantle according to claim 1, it is characterised in that in step 1), The organic siliconresin is by by methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane With dichloromethyl phenylsilane according to 1:1-1.2:0.4-0.6:0.8-1.2:0.1-0.4 weight ratio is in vacuum condition, 150- 2-5h is processed under conditions of 180 DEG C to form.
  5. 5. the waterproof Quick Response Code braider steel fibre kernmantle according to any one in claim 1-4, it is characterised in that It is the chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano oxidized ruthenium, nano oxidized in step 2) Samarium, the weight ratio of propane diols are 10:18-22:5-10:0.1-0.4:0.08-0,10:0.08-0.12:20-25.
  6. 6. waterproof Quick Response Code braider steel fibre kernmantle according to claim 5, it is characterised in that in step 2), The heat treatment meets following condition:Temperature is 65-75 DEG C, time 4-6h, and is stirring for 1000-1500rpm in rotating speed Carried out under the conditions of mixing.
  7. 7. waterproof Quick Response Code braider steel fibre kernmantle according to claim 5, it is characterised in that in step 2), The nano oxidized ruthenium, the average grain diameter of nano oxidized samarium are 5-10nm.
  8. 8. waterproof Quick Response Code braider steel fibre kernmantle according to claim 5, it is characterised in that the chlorinated rubber Weight average molecular weight be 3000-5000.
  9. 9. the waterproof Quick Response Code braider steel fibre kernmantle according to any one in claim 1-4,6-8, its feature It is, in step 3), the component I and component II weight ratio is 2:1.4-1.7.
  10. 10. waterproof Quick Response Code braider steel fibre kernmantle according to claim 9, it is characterised in that in step 3), The mixing meets following condition:Temperature is 45-55 DEG C, time 2-3h, and in the stirring that rotating speed is 1000-1500rpm Under the conditions of carry out.
CN201710789541.0A 2017-09-05 2017-09-05 Waterproof Quick Response Code braider steel fibre kernmantle Pending CN107488406A (en)

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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54127436A (en) * 1978-03-27 1979-10-03 Dainippon Ink & Chem Inc Resin composition for coating compound
CN1374357A (en) * 2001-03-10 2002-10-16 海洋化工研究院 Epoxy ester emulsion and water-thinned antirust primer with the said emulsion as base material
CN103965776A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 High-temperature resistant insulating anticorrosive coating
CN104845501A (en) * 2015-05-15 2015-08-19 北京金汇利应用化工制品有限公司 Coating containing water-based acrylic fatty acid modified epoxy resin and preparation method of coating
CN104847845A (en) * 2015-05-07 2015-08-19 芜湖品度电子科技有限公司 High-strength rigid pulley rope for two-dimensional code knitting machine and preparation method thereof
CN106349904A (en) * 2016-08-27 2017-01-25 安徽省金盾涂料有限责任公司 Waterproof flame-retardant coating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54127436A (en) * 1978-03-27 1979-10-03 Dainippon Ink & Chem Inc Resin composition for coating compound
CN1374357A (en) * 2001-03-10 2002-10-16 海洋化工研究院 Epoxy ester emulsion and water-thinned antirust primer with the said emulsion as base material
CN103965776A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 High-temperature resistant insulating anticorrosive coating
CN104847845A (en) * 2015-05-07 2015-08-19 芜湖品度电子科技有限公司 High-strength rigid pulley rope for two-dimensional code knitting machine and preparation method thereof
CN104845501A (en) * 2015-05-15 2015-08-19 北京金汇利应用化工制品有限公司 Coating containing water-based acrylic fatty acid modified epoxy resin and preparation method of coating
CN106349904A (en) * 2016-08-27 2017-01-25 安徽省金盾涂料有限责任公司 Waterproof flame-retardant coating

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Application publication date: 20171219