CN107460779A - Decorative panel that a kind of glass synthetic resin is modified and preparation method thereof - Google Patents
Decorative panel that a kind of glass synthetic resin is modified and preparation method thereof Download PDFInfo
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- CN107460779A CN107460779A CN201710768860.3A CN201710768860A CN107460779A CN 107460779 A CN107460779 A CN 107460779A CN 201710768860 A CN201710768860 A CN 201710768860A CN 107460779 A CN107460779 A CN 107460779A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/47—Condensation polymers of aldehydes or ketones
- D21H17/48—Condensation polymers of aldehydes or ketones with phenols
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Finishing Walls (AREA)
Abstract
Decorative panel being modified the invention discloses a kind of glass synthetic resin and preparation method thereof, by weight, the decorative panel includes：30~55 parts of brown paper body paper, 19~40 parts of phenolic resin, 19~35 parts of glass fibre, 12~25 parts of graphene, 12~28 parts of silane coupler, 18~35 parts of ethyl acetate, 8~19 parts of sodium carbonate, 5~22 parts of calcium carbonate, 15~28 parts of alundum (Al2O3), 2~11 parts of kaolin, 1~5 part of montmorillonite.The decorative panel viscosity that glass synthetic resin of the present invention is modified is good, is not easy moisture absorption unsticking；The decorative panel peel strength that glass synthetic resin of the present invention is modified is high, and mechanical property is preferable.
Description
Technical field
The invention belongs to technical field of material chemistry, is related to a kind of ornament materials, what specially a kind of glass synthetic resin was modified
Decorative panel and preparation method thereof.
Background technology
By the glass of fusing at a terrific speed pull into trickle silk, glass fibre., can due to its soft texture
To be woven into the fabrics such as glass cloth, glass tape.Although glass fibre is different with glass appearance, their combination is the same.
The characteristics of glass fibre is that cost is low, source is wide, and tensile strength and impact strength height, chemical resistance are good, and fracture is stretched
Long rate is small, and density is similar to aluminium, about 1/3rd of steel, and it is that a kind of high intensity, high elastic modulus and specific strength are higher
Widely composite is made as reinforcing material in material, therefore, glass fibre and its product.
Nineteen fifty, China's fiber glass industry just start to walk, and can only produce at that time.After nineteen fifty-five, China's frp industry hair
Exhibition gets up just to enable fiber glass industry to develop by leaps and bounds.It is developed so far, due to its property, is widely used in oil, changes
The industrial departments such as work, smelting, traffic, electric industry, electronics, communication, space flight, and each neck of military engineering, people's lives articles for use
Domain.Glass fibre is often used as the reinforcing material of fiberboard and particieboard in timber industry, meanwhile, glass fibre is also a kind of
Refractory material.
Coupling agent refers to improve a kind of material of interfacial characteristics between filler and high polymer material.It is in the molecular structure
Liang Zhong functional groups be present:With macromolecule matrix chemical reaction or at least good compatibility can occur for a kind of functional group；It is another
Functional group can form chemical bond with inorganic filler.Coupling agent can improve the interface performance between high polymer material and filler, carry
The cohesive at high interface, improve the performance of filling or enhanced high polymer material.
Decorative panel of the prior art is placed in moisture for a long time, and resin has unsticking phenomenon with glass fibre.
The content of the invention
The purpose of the present invention is：The defects of in order to overcome prior art, obtain that a kind of viscosity is good, be not easy moisture absorption unsticking or
The decorative panel of expansion, the decorative panel being modified the invention provides a kind of glass synthetic resin and preparation method thereof.
Technical scheme：The decorative panel that a kind of glass synthetic resin is modified, by weight, the decorative panel includes：Ox-hide
30~55 parts of paper body paper, 19~40 parts of phenolic resin, 19~35 parts of glass fibre, 12~25 parts of graphene, silane coupler 12
~28 parts, 18~35 parts of ethyl acetate, 8~19 parts of sodium carbonate, 5~22 parts of calcium carbonate, 15~28 parts of alundum (Al2O3), kaolin
2~11 parts, 1~5 part of montmorillonite.
Preferably, by weight, the decorative panel includes：48 parts of brown paper body paper, 34 parts of phenolic resin, glass fibre
29 parts, 22 parts of graphene, 23 parts of silane coupler, 32 parts of ethyl acetate, 15 parts of sodium carbonate, 17 parts of calcium carbonate, alundum (Al2O3)
23 parts, 8 parts of kaolin, 4 parts of montmorillonite.
A kind of preparation method for the decorative panel that glass synthetic resin is modified, the described method comprises the following steps：
(1) disperse graphene in sulfuric acid solution, then add glass fibre, magnetic agitation 1~4 hour, stirring temperature
Spend for 30~45 DEG C, obtain modification liquid；
(2) silane coupler is scattered in ethyl acetate, then adds product made from step (1), stirred when adding
Mix, until being uniformly dispersed, be placed in 55~65 DEG C of environment and dehydrate, by 0.1mm square hole screens, modified glass-fiber powder is made
End；
(3) modified glass fibre for obtaining sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2)
Tie up powder to mix, in mass ratio 1:1~1.2 adds deionized water to be adjusted to body of paste, obtains glass fibre gel；
(4) brown paper body paper is cut into 10cm × 10cm test specimen, it is 1% to be dried under the conditions of 55~65 DEG C to moisture content
~5%, brown paper body paper is immersed in phenolic resin, discharges the bubble of paper, immersion takes out drying after 1~5 hour；
(5) glass fibre gel made from the brown paper body paper surface coating step (3) after step (4) processing, first exists
Dry at room temperature, be subsequently placed in 55~65 DEG C of environment and dry；
(6) the brown paper body paper after step (5) processing is immersed in phenolic resin, discharges paper bubble, immersion 2~10
Hour, then it can be prepared by decorative panel through drying, assembly, hot pressing.
Preferably, dispersed graphene in step (1) in sulfuric acid solution, then add glass fibre, magnetic agitation 2.5
Hour, whipping temp is 40 DEG C, obtains modification liquid.
Preferably, silane coupler is scattered in ethyl acetate in step (2), then adds the obtained production of step (1)
Thing, stir while adding, until being uniformly dispersed, be placed in 60 DEG C of environment and dehydrate, by 0.1mm square hole screens, be made and be modified
Glass fibre powder.
Preferably, sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2) are obtained in step (3)
Modified glass-fiber powder mixing, in mass ratio 1:1 adds deionized water to be adjusted to body of paste, obtains glass fibre gel.
Preferably, brown paper body paper is cut into 10cm × 10cm test specimen in step (4), dried under the conditions of 62 DEG C to containing
Water rate is 4%, and brown paper body paper is immersed in phenolic resin, discharges the bubble of paper, and immersion takes out drying after 4 hours.
Preferably, glass made from the brown paper body paper surface coating step (3) in step (5) after step (4) processing
Fiber gel, first dry at room temperature, be subsequently placed in 62 DEG C of environment and dry.
Preferably, the brown paper body paper after step (5) processing is immersed in phenolic resin in step (6), discharges paper
Bubble, soak 7 hours, then can be prepared by decorative panel through drying, assembly, hot pressing.
Beneficial effect：(1) the decorative panel viscosity that glass synthetic resin of the present invention is modified is good, is not easy moisture absorption unsticking；(2)
The decorative panel peel strength that glass synthetic resin of the present invention is modified is high, and mechanical property is preferable.
Embodiment
Embodiment 1
The decorative panel that a kind of glass synthetic resin is modified, by weight, the decorative panel includes：Brown paper body paper 30
Part, 19 parts of phenolic resin, 19 parts of glass fibre, 12 parts of graphene, 12 parts of silane coupler, 18 parts of ethyl acetate, sodium carbonate 8
Part, 5 parts of calcium carbonate, 15 parts of alundum (Al2O3), 2 parts of kaolin, 1 part of montmorillonite.
A kind of preparation method for the decorative panel that glass synthetic resin is modified, the described method comprises the following steps：
(1) disperse graphene in sulfuric acid solution, then add glass fibre, magnetic agitation 1 hour, whipping temp is
30 DEG C, obtain modification liquid；
(2) silane coupler is scattered in ethyl acetate, then adds product made from step (1), stirred when adding
Mix, until being uniformly dispersed, be placed in 55 DEG C of environment and dehydrate, by 0.1mm square hole screens, modified glass-fiber powder is made；
(3) modified glass fibre for obtaining sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2)
Tie up powder to mix, in mass ratio 1:1 adds deionized water to be adjusted to body of paste, obtains glass fibre gel；
(4) brown paper body paper is cut into 10cm × 10cm test specimen, it is 1% to be dried under the conditions of 55 DEG C to moisture content, will
Brown paper body paper is immersed in phenolic resin, discharges the bubble of paper, and immersion takes out drying after 1 hour；
(5) glass fibre gel made from the brown paper body paper surface coating step (3) after step (4) processing, first exists
Dry at room temperature, be subsequently placed in 55 DEG C of environment and dry；
(6) the brown paper body paper after step (5) processing is immersed in phenolic resin, discharges paper bubble, immersion 2 is small
When, then it can be prepared by decorative panel through drying, assembly, hot pressing.
Embodiment 2
The decorative panel that a kind of glass synthetic resin is modified, by weight, the decorative panel includes：Brown paper body paper 48
Part, 34 parts of phenolic resin, 29 parts of glass fibre, 22 parts of graphene, 23 parts of silane coupler, 32 parts of ethyl acetate, sodium carbonate 15
Part, 17 parts of calcium carbonate, 23 parts of alundum (Al2O3), 8 parts of kaolin, 4 parts of montmorillonite.
A kind of preparation method for the decorative panel that glass synthetic resin is modified, the described method comprises the following steps：
(1) disperse graphene in sulfuric acid solution, then add glass fibre, magnetic agitation 2.5 hours, whipping temp
For 40 DEG C, modification liquid is obtained；
(2) silane coupler is scattered in ethyl acetate, then adds product made from step (1), stirred when adding
Mix, until being uniformly dispersed, be placed in 60 DEG C of environment and dehydrate, by 0.1mm square hole screens, modified glass-fiber powder is made；
(3) modified glass fibre for obtaining sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2)
Tie up powder to mix, in mass ratio 1:1 adds deionized water to be adjusted to body of paste, obtains glass fibre gel；
(4) brown paper body paper is cut into 10cm × 10cm test specimen, it is 4% to be dried under the conditions of 62 DEG C to moisture content, will
Brown paper body paper is immersed in phenolic resin, discharges the bubble of paper, and immersion takes out drying after 4 hours；
(5) glass fibre gel made from the brown paper body paper surface coating step (3) after step (4) processing, first exists
Dry at room temperature, be subsequently placed in 62 DEG C of environment and dry；
(6) the brown paper body paper after step (5) processing is immersed in phenolic resin, discharges paper bubble, immersion 7 is small
When, then it can be prepared by decorative panel through drying, assembly, hot pressing.
Embodiment 3
The decorative panel that a kind of glass synthetic resin is modified, by weight, the decorative panel includes：Brown paper body paper 55
Part, 40 parts of phenolic resin, 35 parts of glass fibre, 25 parts of graphene, 28 parts of silane coupler, 35 parts of ethyl acetate, sodium carbonate 19
Part, 22 parts of calcium carbonate, 28 parts of alundum (Al2O3), 11 parts of kaolin, 5 parts of montmorillonite.
A kind of preparation method for the decorative panel that glass synthetic resin is modified, the described method comprises the following steps：
(1) disperse graphene in sulfuric acid solution, then add glass fibre, magnetic agitation 4 hours, whipping temp is
45 DEG C, obtain modification liquid；
(2) silane coupler is scattered in ethyl acetate, then adds product made from step (1), stirred when adding
Mix, until being uniformly dispersed, be placed in 65 DEG C of environment and dehydrate, by 0.1mm square hole screens, modified glass-fiber powder is made；
(3) modified glass fibre for obtaining sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2)
Tie up powder to mix, in mass ratio 1:1.2 add deionized water to be adjusted to body of paste, obtain glass fibre gel；
(4) brown paper body paper is cut into 10cm × 10cm test specimen, it is 5% to be dried under the conditions of 65 DEG C to moisture content, will
Brown paper body paper is immersed in phenolic resin, discharges the bubble of paper, and immersion takes out drying after 5 hours；
(5) glass fibre gel made from the brown paper body paper surface coating step (3) after step (4) processing, first exists
Dry at room temperature, be subsequently placed in 65 DEG C of environment and dry；
(6) the brown paper body paper after step (5) processing is immersed in phenolic resin, discharges paper bubble, immersion 10 is small
When, then it can be prepared by decorative panel through drying, assembly, hot pressing.
The decorative panel that the glass synthetic resin prepared to embodiment 1~3 is modified carries out performance test, as a result such as following table
It is shown：
Claims (9)
1. the decorative panel that a kind of glass synthetic resin is modified, it is characterised in that by weight, the decorative panel includes：Ox-hide
30~55 parts of paper body paper, 19~40 parts of phenolic resin, 19~35 parts of glass fibre, 12~25 parts of graphene, silane coupler 12
~28 parts, 18~35 parts of ethyl acetate, 8~19 parts of sodium carbonate, 5~22 parts of calcium carbonate, 15~28 parts of alundum (Al2O3), kaolin
2~11 parts, 1~5 part of montmorillonite.
2. the decorative panel that a kind of glass synthetic resin according to claim 1 is modified, it is characterised in that by weight,
The decorative panel includes：48 parts of brown paper body paper, 34 parts of phenolic resin, 29 parts of glass fibre, 22 parts of graphene, silane coupler
23 parts, 32 parts of ethyl acetate, 15 parts of sodium carbonate, 17 parts of calcium carbonate, 23 parts of alundum (Al2O3), 8 parts of kaolin, 4 parts of montmorillonite.
3. the preparation method for the decorative panel that a kind of glass synthetic resin described in claim 1 is modified, it is characterised in that the side
Method comprises the following steps：
(1) disperse graphene in sulfuric acid solution, then add glass fibre, magnetic agitation 1~4 hour, whipping temp is
30~45 DEG C, obtain modification liquid；
(2) silane coupler is scattered in ethyl acetate, then product made from addition step (1), is stirred while adding, directly
To being uniformly dispersed, it is placed in 55~65 DEG C of environment and dehydrates, by 0.1mm square hole screens, modified glass-fiber powder is made；
(3) the modified glass-fiber powder for obtaining sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2)
End mixing, in mass ratio 1:1~1.2 adds deionized water to be adjusted to body of paste, obtains glass fibre gel；
(4) brown paper body paper is cut into 10cm × 10cm test specimen, under the conditions of 55~65 DEG C dry to moisture content be 1%~
5%, brown paper body paper is immersed in phenolic resin, discharges the bubble of paper, immersion takes out drying after 1~5 hour；
(5) glass fibre gel made from the brown paper body paper surface coating step (3) after step (4) processing, first in room temperature
Under dry, be subsequently placed in 55~65 DEG C of environment and dry；
(6) the brown paper body paper after step (5) processing is immersed in phenolic resin, discharges paper bubble, immersion 2~10 is small
When, then it can be prepared by decorative panel through drying, assembly, hot pressing.
4. the preparation method for the decorative panel that a kind of glass synthetic resin according to claim 3 is modified, it is characterised in that step
Suddenly dispersed graphene in (1) in sulfuric acid solution, then add glass fibre, magnetic agitation 2.5 hours, whipping temp 40
DEG C, obtain modification liquid.
5. the preparation method for the decorative panel that a kind of glass synthetic resin according to claim 3 is modified, it is characterised in that step
Suddenly silane coupler is scattered in ethyl acetate in (2), then product made from addition step (1), is stirred while adding, directly
To being uniformly dispersed, it is placed in 60 DEG C of environment and dehydrates, by 0.1mm square hole screens, modified glass-fiber powder is made.
6. the preparation method for the decorative panel that a kind of glass synthetic resin according to claim 3 is modified, it is characterised in that step
Suddenly the modified glass-fiber powder obtained sodium carbonate, calcium carbonate, alundum (Al2O3), kaolin, montmorillonite and step (2) in (3)
End mixing, in mass ratio 1:1 adds deionized water to be adjusted to body of paste, obtains glass fibre gel.
7. the preparation method for the decorative panel that a kind of glass synthetic resin according to claim 3 is modified, it is characterised in that step
Brown paper body paper is cut into 10cm × 10cm test specimen suddenly, it is 4% to be dried under the conditions of 62 DEG C to moisture content, by ox-hide in (4)
Paper body paper is immersed in phenolic resin, discharges the bubble of paper, and immersion takes out drying after 4 hours.
8. the preparation method for the decorative panel that a kind of glass synthetic resin according to claim 3 is modified, it is characterised in that step
Suddenly glass fibre gel made from the brown paper body paper surface coating step (3) in (5) after step (4) processing, first in room temperature
Under dry, be subsequently placed in 62 DEG C of environment and dry.
9. the preparation method for the decorative panel that a kind of glass synthetic resin according to claim 3 is modified, it is characterised in that step
Suddenly the brown paper body paper after step (5) processing is immersed in phenolic resin in (6), discharge paper bubble, immersion 7 hours, so
Decorative panel is can be prepared by by drying, assembly, hot pressing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710768860.3A CN107460779B (en) | 2017-08-31 | 2017-08-31 | Glass fiber synthetic resin modified decorative plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710768860.3A CN107460779B (en) | 2017-08-31 | 2017-08-31 | Glass fiber synthetic resin modified decorative plate and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107460779B CN107460779B (en) | 2020-04-21 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094092A (en) * | 2019-06-17 | 2020-12-18 | 南京倍立达欧陆装饰艺术工程有限公司 | Chopped strand mat reinforcing plate and preparation method thereof |
| CN113619245A (en) * | 2021-07-21 | 2021-11-09 | 今创集团股份有限公司 | Compound decoration panel of high strength |
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| CN1809454A (en) * | 2003-05-23 | 2006-07-26 | 特里斯帕国际公司 | Decorative panel for outdoor use and method for manufacturing the same |
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| CN112094092A (en) * | 2019-06-17 | 2020-12-18 | 南京倍立达欧陆装饰艺术工程有限公司 | Chopped strand mat reinforcing plate and preparation method thereof |
| CN113619245A (en) * | 2021-07-21 | 2021-11-09 | 今创集团股份有限公司 | Compound decoration panel of high strength |
| CN113619245B (en) * | 2021-07-21 | 2023-06-09 | 今创集团股份有限公司 | High-strength composite decoration panel |
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