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CN107417129A - Low-thermal conductivity rock wool thermal insulation material and preparation method thereof - Google Patents

Low-thermal conductivity rock wool thermal insulation material and preparation method thereof Download PDF

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Publication number
CN107417129A
CN107417129A CN201710650136.0A CN201710650136A CN107417129A CN 107417129 A CN107417129 A CN 107417129A CN 201710650136 A CN201710650136 A CN 201710650136A CN 107417129 A CN107417129 A CN 107417129A
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China
Prior art keywords
parts
rock wool
thermal conductivity
rock
low thermal
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Withdrawn
Application number
CN201710650136.0A
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Chinese (zh)
Inventor
周青松
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Hefei Zhenxun Low Temperature Technology Co ltd
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Hefei Zhenxun Low Temperature Technology Co ltd
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Priority to CN201710650136.0A priority Critical patent/CN107417129A/en
Publication of CN107417129A publication Critical patent/CN107417129A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/04Manufacture of glass fibres or filaments by using centrifugal force, e.g. spinning through radial orifices; Construction of the spinner cups therefor
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • C03C13/06Mineral fibres, e.g. slag wool, mineral wool, rock wool

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Building Environments (AREA)
  • Floor Finish (AREA)

Abstract

The invention belongs to the technical field of heat insulation materials, and provides a rock wool heat insulation material with a low heat conductivity coefficient and a preparation method thereof, wherein the heat insulation material comprises the following components: slate, zeolite, silicon carbide, waste rock wool, expanded perlite, pumice, volcanic ash, polypropylene fiber, rock mud and zirconium silicide. Compared with the traditional material proportion, the rock wool heat-insulating material takes slate and waste rock wool as main materials, reduces the cost, and improves the strength and the heat-insulating property of the heat-insulating material by being supplemented with zeolite, silicon carbide, expanded perlite, pumice, volcanic ash, rock mud and zirconium silicide. In addition, polypropylene fibers are added to improve the toughness of the insulation. The furfural resin is sprayed in the centrifugation process, so that the hydrophobic rate is better improved. Therefore, the rock wool heat-insulating material has better heat-insulating effect and lower heat conductivity coefficient.

Description

A kind of low thermal conductivity rock wool heat-preservation material and preparation method
Technical field
The invention belongs to insulation material technical field, in particular it relates to a kind of low thermal conductivity rock wool heat-preservation material and system Preparation Method.
Background technology
Insulation material generally refers to the material that thermal conductivity factor is less than or equal to 0.2.Insulation material have developed rapidly, industry and Good heat preservation technology and material are used in building, can often be played a multiplier effect.Existing market is commonly used to be had Machine insulation material(Such as polystyrene foam plate, polyurathamc)Although with relatively low heat conductivility, intensity is relatively low, also not Enough waterproofs.Inorganic heat preserving and heat insulation material using cement as binding agent(Such as foamed cement material, cement base perlite material, cement Base polyphenyl particle putty), thermal conductivity factor is higher, intensity is high, but energy-saving effect is bad.And some use inorganic material(Such as foam glass Glass, floating bead)The insulation material complex manufacturing technology of production, fragility is big, and difficulty of construction is big, and cost is high.
The present invention proposes a kind of with low thermal conductivity, intensity height, the simple rock wool heat-preservation material of manufacture craft.
The content of the invention
For in the prior art the defects of, the purpose of the present invention on the one hand be to provide a kind of low thermal conductivity rock wool heat-preservation material Material, on the one hand also provide the preparation method of the low thermal conductivity rock wool heat-preservation material.
A kind of low thermal conductivity rock wool heat-preservation material provided according to an aspect of the present invention, the low thermal conductivity rock wool heat-preservation material Material includes the component of following parts by weight:Slate 22-48 parts, zeolite 15-21 parts, carborundum 3-6 parts, discarded rock wool 12-15 parts, Expanded perlite 22-30 parts, float stone 11-15 parts, volcanic ash 4-10 parts, polypropylene fibre 4-9 parts, rock mud 10-13 parts, zirconium silicide 2-7 parts.
Preferably, the low thermal conductivity rock wool heat-preservation material includes the component of following parts by weight:Slate 22-43 parts, Zeolite 17-21 parts, carborundum 3-5 parts, discarded rock wool 12-14 parts, expanded perlite 25-30 parts, float stone 11-14 parts, volcanic ash 5-10 parts, polypropylene fibre 6-9 parts, rock mud 11-13 parts, zirconium silicide 4-7 parts.
Preferably, the low thermal conductivity rock wool heat-preservation material includes the component of following parts by weight:26 parts of slate, zeolite 19 parts, 4 parts of carborundum, discarded 13 parts of rock wool, 27 parts of expanded perlite, 12 parts of float stone, 7 parts of volcanic ash, 7 parts of polypropylene fibre, 12 parts of rock mud, 5 parts of zirconium silicide.
Preferably, the discarded rock wool is the leftover bits and pieces of production rock cotton board.
A kind of preparation method of the low thermal conductivity rock wool heat-preservation material provided according to a further aspect of the invention, the preparation Method comprises the following steps:
(1)Collect leftover bits and pieces during rock cotton board production;
(2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 460-540 DEG C, by powder Compound after broken is plunged into, and keeping temperature is 850-1250 DEG C, untill raw material all fusing;
(3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 38-59:1000;
(4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
(5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
Preferably, the step(3)In the speed of centrifugation be 6100-7200r/h.
Preferably, the step(2)Mixture after middle crushing crosses 200 eye mesh screens.
Preferably, the step(5)The temperature of middle solidification is 250-280 DEG C, and pressure during compression is 0.05MPa.
Compared with prior art, the present invention has following beneficial effect:
The present invention provides a kind of fire prevention low thermal conductivity rock wool heat-preservation material, the rock wool heat-preservation material composition include slate, zeolite, Carborundum, discarded rock wool, expanded perlite, float stone, volcanic ash, polypropylene fibre, rock mud, zirconium silicide.Relative to traditional material Material proportioning, major ingredient is used as using slate and discarded rock wool, reduces cost, while be aided with zeolite, carborundum, expanded perlite, float Stone, volcanic ash, rock mud, zirconium silicide, improve the intensity and heat-insulating property of insulation material.In addition, polypropylene fibre is added to carry The toughness of high insulation material.Furfural resin is sprayed during centrifugation, preferably improves hydrophobic rate.Therefore, it is of the invention Rock wool heat-preservation material, better heat preservation, thermal conductivity factor are lower.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention Rather than limitation the scope of the present invention.
Embodiment 1
On the one hand a kind of low thermal conductivity rock wool heat-preservation material that the present embodiment provides, the low thermal conductivity rock wool heat-preservation material Include the component of following parts by weight:48 parts of slate, 15 parts of zeolite, 6 parts of carborundum, discarded 12 parts of rock wool, expanded perlite 30 Part, 11 parts of float stone, 10 parts of volcanic ash, 4 parts of polypropylene fibre, 13 parts of rock mud, 2 parts of zirconium silicide.
Wherein, the discarded rock wool is the leftover bits and pieces of production rock cotton board.
A kind of preparation method of the low thermal conductivity rock wool heat-preservation material provided according to a further aspect of the invention, the preparation Method comprises the following steps:
(1)Collect leftover bits and pieces during rock cotton board production;
(2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 540 DEG C, after crushing Compound plunge into, keeping temperature be 850 DEG C, to raw material all fusing untill;
(3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 59:1000;
(4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
(5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
Wherein, the step(3)In the speed of centrifugation be 7200r/h.
Wherein, the step(2)Mixture after middle crushing crosses 200 eye mesh screens.
Wherein, the step(5)The temperature of middle solidification is 280 DEG C, and pressure during compression is 0.05MPa.
Embodiment 2
On the one hand a kind of low thermal conductivity rock wool heat-preservation material that the present embodiment provides, the low thermal conductivity rock wool heat-preservation material Include the component of following parts by weight:22 parts of slate, 21 parts of zeolite, 3 parts of carborundum, discarded 15 parts of rock wool, expanded perlite 22 Part, 15 parts of float stone, 4 parts of volcanic ash, 9 parts of polypropylene fibre, 10 parts of rock mud, 7 parts of zirconium silicide.
Wherein, the discarded rock wool is the leftover bits and pieces of production rock cotton board.
A kind of preparation method of the low thermal conductivity rock wool heat-preservation material provided according to a further aspect of the invention, the preparation Method comprises the following steps:
(1)Collect leftover bits and pieces during rock cotton board production;
(2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 460 DEG C, after crushing Compound plunge into, keeping temperature be 1250 DEG C, to raw material all fusing untill;
(3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 38:1000;
(4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
(5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
Wherein, the step(3)In the speed of centrifugation be 6100r/h.
Wherein, the step(2)Mixture after middle crushing crosses 200 eye mesh screens.
Wherein, the step(5)The temperature of middle solidification is 250 DEG C, and pressure during compression is 0.05MPa.
Embodiment 3
On the one hand a kind of low thermal conductivity rock wool heat-preservation material that the present embodiment provides, the low thermal conductivity rock wool heat-preservation material Include the component of following parts by weight:43 parts of slate, 17 parts of zeolite, 5 parts of carborundum, discarded 12 parts of rock wool, expanded perlite 30 Part, 11 parts of float stone, 10 parts of volcanic ash, 6 parts of polypropylene fibre, 13 parts of rock mud, 4 parts of zirconium silicide.
Wherein, the discarded rock wool is the leftover bits and pieces of production rock cotton board.
A kind of preparation method of the low thermal conductivity rock wool heat-preservation material provided according to a further aspect of the invention, the preparation Method comprises the following steps:
(1)Collect leftover bits and pieces during rock cotton board production;
(2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 490 DEG C, after crushing Compound plunge into, keeping temperature be 950 DEG C, to raw material all fusing untill;
(3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 44:1000;
(4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
(5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
Wherein, the step(3)In the speed of centrifugation be 6500r/h.
Wherein, the step(2)Mixture after middle crushing crosses 200 eye mesh screens.
Wherein, the step(5)The temperature of middle solidification is 260 DEG C, and pressure during compression is 0.05MPa.
Embodiment 4
On the one hand a kind of low thermal conductivity rock wool heat-preservation material that the present embodiment provides, the low thermal conductivity rock wool heat-preservation material Include the component of following parts by weight:22 parts of slate, 21 parts of zeolite, 3 parts of carborundum, discarded 14 parts of rock wool, expanded perlite 25 Part, 14 parts of float stone, 5 parts of volcanic ash, 9 parts of polypropylene fibre, 11 parts of rock mud, 7 parts of zirconium silicide.
Wherein, the discarded rock wool is the leftover bits and pieces of production rock cotton board.
A kind of preparation method of the low thermal conductivity rock wool heat-preservation material provided according to a further aspect of the invention, the preparation Method comprises the following steps:
(1)Collect leftover bits and pieces during rock cotton board production;
(2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 490 DEG C, after crushing Compound plunge into, keeping temperature be 890 DEG C, to raw material all fusing untill;
(3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 43:1000;
(4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
(5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
Wherein, the step(3)In the speed of centrifugation be 6500r/h.
Wherein, the step(2)Mixture after middle crushing crosses 200 eye mesh screens.
Wherein, the step(5)The temperature of middle solidification is 270 DEG C, and pressure during compression is 0.05MPa.
Embodiment 5
On the one hand a kind of low thermal conductivity rock wool heat-preservation material that the present embodiment provides, the low thermal conductivity rock wool heat-preservation material Include the component of following parts by weight:26 parts of slate, 19 parts of zeolite, 4 parts of carborundum, discarded 13 parts of rock wool, expanded perlite 27 Part, 12 parts of float stone, 7 parts of volcanic ash, 7 parts of polypropylene fibre, 12 parts of rock mud, 5 parts of zirconium silicide.
Wherein, the discarded rock wool is the leftover bits and pieces of production rock cotton board.
A kind of preparation method of the low thermal conductivity rock wool heat-preservation material provided according to a further aspect of the invention, the preparation Method comprises the following steps:
(1)Collect leftover bits and pieces during rock cotton board production;
(2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 540 DEG C, after crushing Compound plunge into, keeping temperature be 1250 DEG C, to raw material all fusing untill;
(3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 59:1000;
(4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
(5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
Wherein, the step(3)In the speed of centrifugation be 7200r/h.
Wherein, the step(2)Mixture after middle crushing crosses 200 eye mesh screens.
Wherein, the step(5)The temperature of middle solidification is 280 DEG C, and pressure during compression is 0.05MPa.
Performance test:
The performance of embodiment 1-5 rock wool heat-preservation material is tested, maximum operation (service) temperature is 690 DEG C, maximum hydrophobic rate 99.7%, the maximum tensile strength 9.7kpa, the minimum 0.0032W/ of thermal conductivity factor(m·k)(25 DEG C of mean temperature).
As can be seen here, the performance of rock wool heat-preservation material of the invention is more superior.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

  1. A kind of 1. low thermal conductivity rock wool heat-preservation material, it is characterised in that:The low thermal conductivity rock wool heat-preservation material is included such as The component of lower parts by weight:Slate 22-48 parts, zeolite 15-21 parts, carborundum 3-6 parts, discarded rock wool 12-15 parts, expanded pearlite Rock 22-30 parts, float stone 11-15 parts, volcanic ash 4-10 parts, polypropylene fibre 4-9 parts, rock mud 10-13 parts, zirconium silicide 2-7 parts.
  2. 2. low thermal conductivity rock wool heat-preservation material according to claim 1, it is characterised in that:The low thermal conductivity rock wool Insulation material includes the component of following parts by weight:Slate 22-43 parts, zeolite 17-21 parts, carborundum 3-5 parts, discarded rock wool 12-14 parts, expanded perlite 25-30 parts, float stone 11-14 parts, volcanic ash 5-10 parts, polypropylene fibre 6-9 parts, rock mud 11-13 Part, zirconium silicide 4-7 parts.
  3. 3. low thermal conductivity rock wool heat-preservation material according to claim 1, it is characterised in that:The low thermal conductivity rock wool Insulation material includes the component of following parts by weight:26 parts of slate, 19 parts of zeolite, 4 parts of carborundum, discarded 13 parts of rock wool, expansion 27 parts of perlite, 12 parts of float stone, 7 parts of volcanic ash, 7 parts of polypropylene fibre, 12 parts of rock mud, 5 parts of zirconium silicide.
  4. 4. low thermal conductivity rock wool heat-preservation material according to claim 1, it is characterised in that:The discarded rock wool is production The leftover bits and pieces of rock cotton board.
  5. 5. the preparation method of the low thermal conductivity rock wool heat-preservation material as described in claim any one of 1-4, it is characterised in that:Institute Preparation method is stated to comprise the following steps:
    (1)Collect leftover bits and pieces during rock cotton board production;
    (2)Slate, zeolite, carborundum, discarded rock wool, expanded perlite, float stone, coconut palm chaff, volcanic ash, poly- third are weighed according to proportioning Alkene fiber, rock mud, zirconium silicide, pulverizer is put into after mixing and is crushed, furnace cupola is opened, when being preheating to 460-540 DEG C, by powder Compound after broken is plunged into, and keeping temperature is 850-1250 DEG C, untill raw material all fusing;
    (3)Will(2)The solution of middle fusing sprays furfural resin, the fiber by being centrifuged into threadiness during centrifugation Amount ratio with furfural resin is 38-59:1000;
    (4)Will(3)The fiber of middle collection is overlapped, and is changed into superimposed type ribbon;
    (5)By step(4)In superimposed type ribbon solidification, solidification while superimposed type ribbon is compressed, obtain Rock wool heat-preservation material.
  6. 6. low thermal conductivity rock wool heat-preservation material according to claim 5, it is characterised in that:The step(3)In from The speed of the heart is 6100-7200r/h.
  7. 7. low thermal conductivity rock wool heat-preservation material according to claim 5, it is characterised in that:The step(2)Middle crushing Mixture afterwards crosses 200 eye mesh screens.
  8. 8. low thermal conductivity rock wool heat-preservation material according to claim 5, it is characterised in that:The step(5)Middle solidification Temperature be 250-280 DEG C, pressure during compression is 0.05MPa.
CN201710650136.0A 2017-08-02 2017-08-02 Low-thermal conductivity rock wool thermal insulation material and preparation method thereof Withdrawn CN107417129A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107901529A (en) * 2017-12-20 2018-04-13 马鞍山市宏达保温材料有限公司 A kind of press fastening type rock wool-steel plywood and preparation method thereof
CN108503228A (en) * 2018-05-25 2018-09-07 合肥昂诺新材料有限公司 A kind of Novel rock wool thermal insulation material and preparation method thereof
CN111423201A (en) * 2020-04-01 2020-07-17 河南建筑材料研究设计院有限责任公司 Light heat-insulating material and preparation method thereof
CN111875343A (en) * 2020-08-05 2020-11-03 安徽恒创环保建材有限公司 Combined heat insulation brick for building external wall
CN113800775A (en) * 2021-10-22 2021-12-17 天长市康美达新型绝热材料有限公司 Preparation method of low-density rock wool board
CN114436565A (en) * 2020-11-02 2022-05-06 福建省德锐新材有限公司 Preparation method of tailing powder composite synthetic material
CN115029862A (en) * 2022-08-10 2022-09-09 江苏省苏安能节能建材科技有限公司 Gypsum-based heat-preservation rock wool material and preparation method and application thereof
CN115365261A (en) * 2022-02-14 2022-11-22 河北华利岩棉制造有限公司 Solid waste recycling processing method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107901529A (en) * 2017-12-20 2018-04-13 马鞍山市宏达保温材料有限公司 A kind of press fastening type rock wool-steel plywood and preparation method thereof
CN108503228A (en) * 2018-05-25 2018-09-07 合肥昂诺新材料有限公司 A kind of Novel rock wool thermal insulation material and preparation method thereof
CN111423201A (en) * 2020-04-01 2020-07-17 河南建筑材料研究设计院有限责任公司 Light heat-insulating material and preparation method thereof
CN111423201B (en) * 2020-04-01 2021-12-31 河南建筑材料研究设计院有限责任公司 Light heat-insulating material and preparation method thereof
CN111875343A (en) * 2020-08-05 2020-11-03 安徽恒创环保建材有限公司 Combined heat insulation brick for building external wall
CN114436565A (en) * 2020-11-02 2022-05-06 福建省德锐新材有限公司 Preparation method of tailing powder composite synthetic material
CN113800775A (en) * 2021-10-22 2021-12-17 天长市康美达新型绝热材料有限公司 Preparation method of low-density rock wool board
CN115365261A (en) * 2022-02-14 2022-11-22 河北华利岩棉制造有限公司 Solid waste recycling processing method
CN115029862A (en) * 2022-08-10 2022-09-09 江苏省苏安能节能建材科技有限公司 Gypsum-based heat-preservation rock wool material and preparation method and application thereof

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