CN107383970A - A kind of high luster and high weatherability exterior wall latex paint and preparation method thereof - Google Patents
A kind of high luster and high weatherability exterior wall latex paint and preparation method thereof Download PDFInfo
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- CN107383970A CN107383970A CN201710868066.6A CN201710868066A CN107383970A CN 107383970 A CN107383970 A CN 107383970A CN 201710868066 A CN201710868066 A CN 201710868066A CN 107383970 A CN107383970 A CN 107383970A
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- exterior wall
- latex paint
- emulsion
- wall latex
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- 239000003973 paint Substances 0.000 title claims abstract description 53
- 239000004816 latex Substances 0.000 title claims abstract description 28
- 229920000126 latex Polymers 0.000 title claims abstract description 28
- 239000002932 luster Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000013530 defoamer Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 15
- 239000010703 silicon Substances 0.000 claims abstract description 15
- 239000003112 inhibitor Substances 0.000 claims abstract description 14
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920001577 copolymer Polymers 0.000 claims abstract description 13
- 229940008099 dimethicone Drugs 0.000 claims abstract description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 13
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 13
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 12
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 12
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 11
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- -1 polyethylene Polymers 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000003158 alcohol group Chemical group 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 210000000481 breast Anatomy 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 125000005605 benzo group Chemical group 0.000 claims 1
- GTCAXTIRRLKXRU-UHFFFAOYSA-N carbamic acid methyl ester Natural products COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 claims 1
- 239000011258 core-shell material Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000005299 abrasion Methods 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 229940075065 polyvinyl acetate Drugs 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 2
- URANHGZOFVYVJV-UHFFFAOYSA-N 1h-benzimidazole;methyl carbamate Chemical group COC(N)=O.C1=CC=C2NC=NC2=C1 URANHGZOFVYVJV-UHFFFAOYSA-N 0.000 description 2
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 2
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical group [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high luster and high weatherability exterior wall latex paint and preparation method thereof, the emulsion paint includes the composition of following parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：30 ~ 40 parts, styrene-acrylic emulsion：15 ~ 25 parts, hydroxyethyl cellulose：10 ~ 15 parts, nano silicon：10 ~ 15 parts, vinyl acetate：5 ~ 10 parts, dimethicone：1 ~ 5 part, kaolin：5 ~ 10 parts, propane diols：1 ~ 5 part, polyvinyl alcohol：10 ~ 15 parts, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1 ~ 5 part, levelling agent：1 ~ 5 part, dispersant：1 ~ 5 part, deionized water：40 ~ 50 parts.The exterior wall latex paint has excellent weatherability, adhesive force, covering power, water resistance, abrasion resistance, and durability was widely used in hotel, residential building, school, office buildings etc. up to more than 5 years.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of high luster and high weatherability exterior wall latex paint and its preparation side
Method.
Background technology
Emulsion paint is being commonly called as latex paint, is born in the next period in nineteen seventies, is with acrylic ester copolymer
Emulsion is a major class synthetic resin emulsion coating of representative.Emulsion paint is water-dispersible paint, it be using synthetic resin emulsion as
Base-material, filler add the refined coating formed of various auxiliary agents after grinding distribution.Emulsion paint possesses and traditional metope coating
Different many merits, such as it is easy to brush, dries that rapid, paint film is water-fast, scrub resistance is good.In China, people traditionally
Synthetic resin emulsion is base-material, using water as decentralized medium, adds pigment, filler（Also known as extender pigment）And auxiliary agent, through certain work
Coating made of skill process, it is called emulsion paint, is also latex paint.
Emulsion paint is water paint, and their paint film property is more far better than solvent based coating, accounts for solvent based coating half
Organic solvent instead of herein by water, therefore the toxicity problem of organic solvent is substantially thoroughly solved by emulsion paint.
Emulsion paint is to do film forming matter, water removal and safe and harmless different types of polymers or polymer with some aqueous solutions of polymers
Outside, also containing a small amount of emulsifying agents and micro unpolymerized free monomer, free monomer is the small-molecule substance that some can volatilize,
In the presence of different degrees of toxicity problem, the concentration of environmental protection paint free monomer is controlled below 0.1%, more than the dosage of auxiliary agent have 2 ~
3%；Few only accounts between 0.05% to 0.1%.
For emulsion paint, the current country is primarily present following patent document：
Publication No. 107057488A Chinese patent discloses a kind of emulsion paint and preparation method thereof, belongs to emulsion paint technology neck
Domain.The Polyvinyl acetate latex paint of the present invention includes following raw materials by weight：Polyvinyl acetate emulsion 40-50
Part, sodium polymethacrylate 0.05-0.1 parts, dispersant 0.3-0.5 parts, penta sodium pentachlorophenate 0.2-0.4 parts, carboxymethyl cellulose increase
Thick dose of 5-7 part, methyl anyl alcohol 2-4 parts, propane diols 2-3 parts, defoamer 0.05-0.20 parts, deionized water 15-20 parts, titanium dioxide
15-25 parts, lithopone 5-10 parts, precipitated calcium carbonate 10-15 parts, talcum powder 5-10 parts.Of the invention and existing poly vinyl acetate emulsion
Shellac varnish is compared, and has the advantages of production cost is low, and coating is good with coating surface adhesive property, and coating is durable in use.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of high luster and high weatherability exterior wall latex paint and
Its preparation method, the exterior wall latex paint has excellent weatherability, adhesive force, covering power, water resistance, abrasion resistance, durable
Property was widely used in hotel, residential building, school, office buildings etc. up to more than 5 years.
To reach above-mentioned purpose, the technical scheme is that：
A kind of high luster and high weatherability exterior wall latex paint, the emulsion paint include the composition of following parts by weight：Hud typed organosilicon third
Olefin(e) acid ester copolymer emulsion：30 ~ 40 parts, styrene-acrylic emulsion：15 ~ 25 parts, hydroxyethyl cellulose：10 ~ 15 parts, nano silicon：10~
15 parts, vinyl acetate：5 ~ 10 parts, dimethicone：1 ~ 5 part, kaolin：5 ~ 10 parts, propane diols：1 ~ 5 part, polyvinyl alcohol：10~
15 parts, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1 ~ 5 part, levelling agent：1 ~ 5 part, dispersant：1 ~ 5 part, go from
Sub- water：40 ~ 50 parts.
Further, the emulsion paint includes the composition of following parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：35
~ 40 parts, styrene-acrylic emulsion：15 ~ 20 parts, hydroxyethyl cellulose：13 ~ 15 parts, nano silicon：10 ~ 12 parts, vinyl acetate：5~8
Part, dimethicone：1 ~ 3 part, kaolin：6 ~ 10 parts, propane diols：1 ~ 3 part, polyvinyl alcohol：12 ~ 15 parts, mould inhibitor：1 ~ 3 part,
Coalescents：3 ~ 5 parts, defoamer：2 ~ 5 parts, levelling agent：1 ~ 4 part, dispersant：3 ~ 5 parts, deionized water：40 ~ 50 parts.
Preferably, the emulsion paint includes the composition of following parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：35
Part, styrene-acrylic emulsion：20 parts, hydroxyethyl cellulose：13 parts, nano silicon：12 parts, vinyl acetate：7 parts, dimethicone：
2 parts, kaolin：7 parts, propane diols：2 parts, polyvinyl alcohol：13 parts, mould inhibitor：2 parts, coalescents：4 parts, defoamer：3 parts, stream
Flat agent：2 parts, dispersant：4 parts, deionized water：45 parts.
Preferably, the defoamer is amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
Preferably, the mould inhibitor is benzimidazole methyl carbamate.
Preferably, the dispersant is calgon.
Preferably, the levelling agent is polyurethanes levelling agent.
Meanwhile the present invention also provides a kind of preparation method of high luster and high weatherability exterior wall latex paint, it is characterised in that described
Preparation method comprises the following steps：1) mixer is taken, by weight by hud typed organic silicon acrylic ester copolymer emulsion, phenylpropyl alcohol breast
Liquid, hydroxyethyl cellulose, nano silicon, vinyl acetate, dimethicone, kaolin and 50wt% deionized water add
In mixer, stirred 20 ~ 30 minutes under normal temperature, 500 ~ 600 revs/min of rotating speed；2) propane diols, polyvinyl alcohol, mould proof is added
Agent, coalescents, defoamer, levelling agent, dispersant and remaining deionized water, are warming up to 30 ~ 40 DEG C, at 700 ~ 800 revs/min
Stirred 10 ~ 20 minutes under rotating speed, be cooled to room temperature, filtered, stood, produce the high luster and high weatherability exterior wall latex paint.
The invention has the advantages that：
The exterior wall latex paint has excellent weatherability, adhesive force, covering power, water resistance, abrasion resistance, and durability is up to 5
More than year, hotel, residential building, school, office buildings etc. are widely used in.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
A kind of high luster and high weatherability exterior wall latex paint provided by the present invention, the emulsion paint include following parts by weight into
Point：Hud typed organic silicon acrylic ester copolymer emulsion：30 ~ 40 parts, styrene-acrylic emulsion：15 ~ 25 parts, hydroxyethyl cellulose：10~15
Part, nano silicon：10 ~ 15 parts, vinyl acetate：5 ~ 10 parts, dimethicone：1 ~ 5 part, kaolin：5 ~ 10 parts, the third two
Alcohol：1 ~ 5 part, polyvinyl alcohol：10 ~ 15 parts, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1 ~ 5 part, levelling agent：1~5
Part, dispersant：1 ~ 5 part, deionized water：40 ~ 50 parts.
Further, the emulsion paint includes the composition of following parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：35
~ 40 parts, styrene-acrylic emulsion：15 ~ 20 parts, hydroxyethyl cellulose：13 ~ 15 parts, nano silicon：10 ~ 12 parts, vinyl acetate：5~8
Part, dimethicone：1 ~ 3 part, kaolin：6 ~ 10 parts, propane diols：1 ~ 3 part, polyvinyl alcohol：12 ~ 15 parts, mould inhibitor：1 ~ 3 part,
Coalescents：3 ~ 5 parts, defoamer：2 ~ 5 parts, levelling agent：1 ~ 4 part, dispersant：3 ~ 5 parts, deionized water：40 ~ 50 parts.
Preferably, the emulsion paint includes the composition of following parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：35
Part, styrene-acrylic emulsion：20 parts, hydroxyethyl cellulose：13 parts, nano silicon：12 parts, vinyl acetate：7 parts, dimethicone：
2 parts, kaolin：7 parts, propane diols：2 parts, polyvinyl alcohol：13 parts, mould inhibitor：2 parts, coalescents：4 parts, defoamer：3 parts, stream
Flat agent：2 parts, dispersant：4 parts, deionized water：45 parts.
Preferably, the defoamer is amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
Preferably, the mould inhibitor is benzimidazole methyl carbamate.
Preferably, the dispersant is calgon.
Preferably, the levelling agent is polyurethanes levelling agent.
Meanwhile the present invention also provides a kind of preparation method of high luster and high weatherability exterior wall latex paint, it is characterised in that described
Preparation method comprises the following steps：1) mixer is taken, by weight by hud typed organic silicon acrylic ester copolymer emulsion, phenylpropyl alcohol breast
Liquid, hydroxyethyl cellulose, nano silicon, vinyl acetate, dimethicone, kaolin and 50wt% deionized water add
In mixer, stirred 20 ~ 30 minutes under normal temperature, 500 ~ 600 revs/min of rotating speed；2) propane diols, polyvinyl alcohol, mould proof is added
Agent, coalescents, defoamer, levelling agent, dispersant and remaining deionized water, are warming up to 30 ~ 40 DEG C, at 700 ~ 800 revs/min
Stirred 10 ~ 20 minutes under rotating speed, be cooled to room temperature, filtered, stood, produce the high luster and high weatherability exterior wall latex paint.
A kind of high luster and high weatherability exterior wall latex paint provided by the present invention, there is excellent weatherability, adhesive force, covering
Power, water resistance, abrasion resistance, durability were widely used in hotel, residential building, school, office buildings etc. up to more than 5 years.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (9)
1. a kind of high luster and high weatherability exterior wall latex paint, it is characterised in that the emulsion paint includes the composition of following parts by weight：Core
Shell mould organic silicon acrylic ester copolymer emulsion：30 ~ 40 parts, styrene-acrylic emulsion：15 ~ 25 parts, hydroxyethyl cellulose：10 ~ 15 parts, nanometer
Silica：10 ~ 15 parts, vinyl acetate：5 ~ 10 parts, dimethicone：1 ~ 5 part, kaolin：5 ~ 10 parts, propane diols：1 ~ 5 part,
Polyvinyl alcohol：10 ~ 15 parts, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1 ~ 5 part, levelling agent：1 ~ 5 part, disperse
Agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
2. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the emulsion paint includes as follows
The composition of parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：35 ~ 40 parts, styrene-acrylic emulsion：15 ~ 20 parts, hydroxy ethyl fiber
Element：13 ~ 15 parts, nano silicon：10 ~ 12 parts, vinyl acetate：5 ~ 8 parts, dimethicone：1 ~ 3 part, kaolin：6~10
Part, propane diols：1 ~ 3 part, polyvinyl alcohol：12 ~ 15 parts, mould inhibitor：1 ~ 3 part, coalescents：3 ~ 5 parts, defoamer：2 ~ 5 parts, stream
Flat agent：1 ~ 4 part, dispersant：3 ~ 5 parts, deionized water：40 ~ 50 parts.
3. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the emulsion paint includes as follows
The composition of parts by weight：Hud typed organic silicon acrylic ester copolymer emulsion：35 parts, styrene-acrylic emulsion：20 parts, hydroxyethyl cellulose：13
Part, nano silicon：12 parts, vinyl acetate：7 parts, dimethicone：2 parts, kaolin：7 parts, propane diols：2 parts, polyethylene
Alcohol：13 parts, mould inhibitor：2 parts, coalescents：4 parts, defoamer：3 parts, levelling agent：2 parts, dispersant：4 parts, deionized water：45
Part.
4. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the defoamer is amide-type
Defoamer, organic silicon defoamer or mineral oil defoaming agent.
5. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the coalescents are the third two
Alcohol butyl ether, alcohol ester 12 or propane diols phenylate.
6. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the mould inhibitor is benzo miaow
Azoles methyl carbamate.
7. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the dispersant is six inclined phosphorus
Sour sodium.
8. high luster and high weatherability exterior wall latex paint according to claim 1, it is characterised in that the levelling agent is polyurethane
Class levelling agent.
9. a kind of preparation method of high luster and high weatherability exterior wall latex paint as any one of claim 1 ~ 8, its feature
It is, the preparation method comprises the following steps：1) mixer is taken, hud typed organic silicon acrylic ester is copolymerized breast by weight
Liquid, styrene-acrylic emulsion, hydroxyethyl cellulose, nano silicon, vinyl acetate, dimethicone, kaolin and 50wt% go from
Sub- water is added in mixer, is stirred 20 ~ 30 minutes under normal temperature, 500 ~ 600 revs/min of rotating speed；2) propane diols, polyethylene are added
Alcohol, mould inhibitor, coalescents, defoamer, levelling agent, dispersant and remaining deionized water, are warming up to 30 ~ 40 DEG C, 700 ~ 800
Rev/min rotating speed under stir 10 ~ 20 minutes, be cooled to room temperature, filter, stand, produce the high luster and high weatherability exterior wall latex
Paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753090A (en) * | 2018-06-12 | 2018-11-06 | 安徽喜宝高分子材料有限公司 | A kind of wear-resisting freeze proof coating |
| CN108912916A (en) * | 2018-06-25 | 2018-11-30 | 安徽喜宝高分子材料有限公司 | A kind of Emulsion paint for external wall |
| CN108997809A (en) * | 2018-08-29 | 2018-12-14 | 尚晴 | A kind of high durable highly corrosion resistant emulsion paint and preparation method thereof |
| CN113801530A (en) * | 2021-10-15 | 2021-12-17 | 亚士创能科技(上海)股份有限公司 | Emulsion paint and preparation method and application thereof |
| CN115521650A (en) * | 2022-11-02 | 2022-12-27 | 东莞市万科建筑技术研究有限公司 | High weather-resistant stain-resistant water-based exterior wall coating and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108931A (en) * | 2007-08-17 | 2008-01-23 | 深圳市广田环保涂料有限公司 | Aquosity elastic heat preserving insulating paint and its preparing process |
| CN101875804A (en) * | 2010-05-27 | 2010-11-03 | 上海韵霓干粉建材有限公司 | Special paint for external thermal insulation system of outer wall |
| CN104559578A (en) * | 2014-10-25 | 2015-04-29 | 重庆市金渝管道设备有限公司 | Synthesis method of hell-core type organosilicone acrylate water emulsion coating |
| CN105348973A (en) * | 2015-11-24 | 2016-02-24 | 三棵树涂料股份有限公司 | Exterior wall coating containing silicone acrylic emulsion with core-shell structure and preparation method thereof |
| CN105419504A (en) * | 2015-12-03 | 2016-03-23 | 三棵树涂料股份有限公司 | Water-based self-cleaning finish-coat paint and preparation method thereof |
| CN105623403A (en) * | 2014-11-28 | 2016-06-01 | 青岛金智高新技术有限公司 | Fully-functional and environmentally-friendly interior wall emulsion paint |
-
2017
- 2017-09-22 CN CN201710868066.6A patent/CN107383970B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108931A (en) * | 2007-08-17 | 2008-01-23 | 深圳市广田环保涂料有限公司 | Aquosity elastic heat preserving insulating paint and its preparing process |
| CN101875804A (en) * | 2010-05-27 | 2010-11-03 | 上海韵霓干粉建材有限公司 | Special paint for external thermal insulation system of outer wall |
| CN104559578A (en) * | 2014-10-25 | 2015-04-29 | 重庆市金渝管道设备有限公司 | Synthesis method of hell-core type organosilicone acrylate water emulsion coating |
| CN105623403A (en) * | 2014-11-28 | 2016-06-01 | 青岛金智高新技术有限公司 | Fully-functional and environmentally-friendly interior wall emulsion paint |
| CN105348973A (en) * | 2015-11-24 | 2016-02-24 | 三棵树涂料股份有限公司 | Exterior wall coating containing silicone acrylic emulsion with core-shell structure and preparation method thereof |
| CN105419504A (en) * | 2015-12-03 | 2016-03-23 | 三棵树涂料股份有限公司 | Water-based self-cleaning finish-coat paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753090A (en) * | 2018-06-12 | 2018-11-06 | 安徽喜宝高分子材料有限公司 | A kind of wear-resisting freeze proof coating |
| CN108912916A (en) * | 2018-06-25 | 2018-11-30 | 安徽喜宝高分子材料有限公司 | A kind of Emulsion paint for external wall |
| CN108997809A (en) * | 2018-08-29 | 2018-12-14 | 尚晴 | A kind of high durable highly corrosion resistant emulsion paint and preparation method thereof |
| CN113801530A (en) * | 2021-10-15 | 2021-12-17 | 亚士创能科技(上海)股份有限公司 | Emulsion paint and preparation method and application thereof |
| CN115521650A (en) * | 2022-11-02 | 2022-12-27 | 东莞市万科建筑技术研究有限公司 | High weather-resistant stain-resistant water-based exterior wall coating and preparation method thereof |
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