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CN107299001A - A kind of production technology of low oil smoke sunflower oil - Google Patents

A kind of production technology of low oil smoke sunflower oil Download PDF

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Publication number
CN107299001A
CN107299001A CN201710683374.1A CN201710683374A CN107299001A CN 107299001 A CN107299001 A CN 107299001A CN 201710683374 A CN201710683374 A CN 201710683374A CN 107299001 A CN107299001 A CN 107299001A
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China
Prior art keywords
oil
production technology
sunflower oil
temperature
sunflower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710683374.1A
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Chinese (zh)
Inventor
刘昌树
余俊颖
王赛
刘增革
刘建国
丛洋
唐伟伦
迟华忠
游倩华
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Standard (china) Investment Co Ltd
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Standard (china) Investment Co Ltd
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Priority to CN201710683374.1A priority Critical patent/CN107299001A/en
Publication of CN107299001A publication Critical patent/CN107299001A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/001Refining fats or fatty oils by a combination of two or more of the means hereafter
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings or cooking oils
    • A23D9/02Other edible oils or fats, e.g. shortenings or cooking oils characterised by the production or working-up
    • A23D9/04Working-up
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/008Refining fats or fatty oils by filtration, e.g. including ultra filtration, dialysis
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/12Refining fats or fatty oils by distillation
    • C11B3/14Refining fats or fatty oils by distillation with the use of indifferent gases or vapours, e.g. steam

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Fats And Perfumes (AREA)

Abstract

The invention discloses a kind of production technology of low oil smoke sunflower oil, comprise the following steps:Degumming, depickling, washing, centrifugation, vacuum drying, winterization, decolouring, deodorization, cooling, refined filtration, wherein deodorizing technology comprise the following steps:Vacuum no more than 2.0mbar is evacuated to, plate column ramp cycle is carried out, when oil temperature reaches 180 DEG C in plate column, stripped vapor in plate column is opened, is stirred, aliphatic acid trapping is carried out, trapping temperature is 40 DEG C~60 DEG C;When the oil temperature in plate column reaches 220 DEG C~260 DEG C, sunflower oil is first pumped into packed tower, plate column is entered back into, is deodorized.By the improvement to process conditions especially deodorizing technology, the quality of obtained sunflower oil is substantially increased.The oil smoke amount produced when producing the sunflower oil obtained through high-temperature heating by the production technology is low, and contained nutritional ingredient is high in sunflower oil.Content of trans fatty acids is few.

Description

A kind of production technology of low oil smoke sunflower oil
Technical field
The present invention relates to a kind of production technology of edible oil, more particularly to a kind of production technology of sunflower seeds edible oil.
Background technology
At present, in the prior art the preparation technology of sunflower oil exist it is many need solve the problem of, for example:
1) in order to ensure that process conditions are harsh in produced sunflower oil quality, refinery practice, once process conditions are not Meet, obtained sunflower oil quality can be caused to reduce, for example:Prior art is deodorized using single column structure, during deodorization heating High-pressure boiler control it is improper so that the excessive high temperature of deodorization, then causing the trans-fatty acid numerical value of obtained sunflower oil is 4~5 times of normal value;In another example:Deodorization equipment or finished product storage tank equipment use carbon steel material, and grease cooling is improper, causes to add Plus unnecessary antioxidant, cause grease to preserve quality not good.
2) shortcoming of plate column single column:Flexible modulation can not be accomplished in the control of deodorization time.It is deodorized for a long time stagnant Stay, easily cause neutral oil micro hydrolysis in deodorizing tower, free fatty acid content is gone up, it is also possible to produce new grease and gather Compound, more seriously causes the gradually increase of the content of trans fatty acids of deodorised oil.
3) shortcoming of material filling type single column:Major function is physical deacidification, and deodorising effect is simultaneously not so good as tray column significantly, by It is very thin in the liquid film of grease, treat that deodorised oil holdup time in tower is short, the thermal sensitivity pigment in bleached oil can not be decomposed completely, heat Decolorizing effect is good not as plate column effect, and deacidification effect is not also obvious.
4) sunflower seeds crude oil is refined into during sunflower oil, and refining is operated by rule of thumb by operator more, to improve cigarette Point, causes grease in excessive temperature, crosses under high vacuum, produce trans-fatty acid, do harm to huamn body on the contrary.In addition, sunflower Nutritional ingredient such as vitamin E in seed crude oil can excessively be deviate under excessive production and processing.
Because of this it may be desirable to obtain a kind of production technology, by controlling each Parameter Conditions in process conditions, improve what is obtained The quality of sunflower oil.The oil smoke amount produced when the sunflower oil that the production technology is obtained is through high-temperature heating is significantly less than existing The sunflower oil that technology is produced.In addition, nutritional ingredient such as vitamin E contained by the sunflower oil that the production technology is obtained Content is higher than the sunflower oil that prior art is produced, and the content of trans-fatty acid is significantly reduced.
The content of the invention
It is an object of the invention to provide a kind of production technology of low oil smoke sunflower oil, by process conditions especially The improvement of deodorizing technology, substantially increases the quality of obtained sunflower oil.The sunflower seeds obtained is produced by the production technology The oil smoke amount produced when oil is through high-temperature heating is low, and contained nutritional ingredient is high in sunflower oil.Content of trans fatty acids is few.
To achieve these goals, the present invention proposes a kind of production technology of low oil smoke sunflower oil, including following step Suddenly:
Degumming, depickling, washing, centrifugation, vacuum drying, winterization, decolouring, deodorization, cooling, refined filtration, wherein deodorizing technology bag Include following steps:
Vacuum no more than 2.0mbar is evacuated to, plate column ramp cycle is carried out, when oil temperature reaches 180 in plate column DEG C when, open plate column in stripped vapor, stir, carry out aliphatic acid trapping, trapping temperature be 40 DEG C~60 DEG C;When in plate column Oil temperature when reaching 220 DEG C~260 DEG C, sunflower oil is first pumped into packed tower, plate column is entered back into, is deodorized.
Compared to single column structure of the prior art, deodorization is taken off using two separate types in technical solutions according to the invention Smelly tower is deodorized, one of packed tower, and another is plate column.When carrying out deodorizing technology, sunflower oil, which is initially entered, to be filled out Expect tower, subsequently enter plate column progress deodorizing system and vacuumize.
After vacuum is not more than 2.0mbar, plate column ramp cycle is carried out.When oil temperature reaches 180 DEG C in plate column, Stripped vapor in plate column is opened, is stirred, (for example starts fatty acid cycle pump while carrying out aliphatic acid trapping and carries out fat Acid trapping), trapping temperature control is between 40~60 DEG C;After oil temperature reaches 220~260 DEG C in plate column, by sunflower oil Packed tower is pumped into, plate column is entered back into, is deodorized.
Further, in the production technology of low oil smoke sunflower oil of the present invention, the winterization technique include with Lower step:Dried oil is pumped out from basin, temperature adjustment, into crystallizing tank and maturator, cooling, temperature of the regulation oil in tank Degree at 2 DEG C~12 DEG C, add mass percent be 0.3%~0.8% filter aid, be pumped into filter, filter out clarified oil and Wax, clarified oil is pumped into winterization edible vegetable oil tank, first refined filtration.
In such scheme, dried oily temperature adjustment can carry out temperature adjustment using plate type heat exchanger, if then sequentially entering dry and hard In brilliant tank and maturator, according to the concrete condition of each embodiment, the quantity of setting crystallizing tank and maturator, such as setting 5~ 10 crystallizing tanks and 5~10 maturators.
By controlling the cold water flow in crystallizing tank and maturator, so as to adjust oil in each crystallizing tank and maturator Cooldown rate so that temperature of the oil in tank is at 2 DEG C~12 DEG C.
Further, it is board-like in the deodorizing technology in the production technology of low oil smoke sunflower oil of the present invention Vapor flow of stripper is 0.3%~1.0% in tower.
In such scheme, during deodorization, the temperature difference between the heating-up temperature and steam of sunflower oil is controlled to be less than 25 DEG C.This Outside, vapor flow of stripper in control plate column, heating-up temperature when being deodorized according to sunflower oil, control vapor flow of stripper and deodorised oil Mass percent is 0.3%~1.0%.
Further, in the production technology of low oil smoke sunflower oil of the present invention, the temperature control of degumming and depickling System is at 69 DEG C~81 DEG C.
Further, in the production technology of low oil smoke sunflower oil of the present invention, washed using acid water, Acid water addition is the 5%~8% of oily weight.
Further, in the production technology of low oil smoke sunflower oil of the present invention, vacuum drying vacuum is not More than 100mbar.
Further, in the production technology of low oil smoke sunflower oil of the present invention, the filtering of winterization step is used Horizontal blade filter.
Further, in the production technology of low oil smoke sunflower oil of the present invention, with oil in deodorization, cooling step The equipment directly contacted is made up of 304 stainless steels, it is not necessary to use antioxidant.
In such scheme, it is commonly used in the prior art anti-oxidant that antioxidant includes citric acid, BHA, BHT and TBHQ etc. Agent.
Further, in the production technology of low oil smoke sunflower oil of the present invention, cooling step temperature is not more than 45℃。
Further, in the production technology of low oil smoke sunflower oil of the present invention, bleaching tower in decolorization process Vacuum is not more than 100mbar, and bleaching temperature is 100 DEG C~120 DEG C.
In such scheme, decolorising agent uses low in acidity or neutral clay and activated carbon.
Further, in the production technology of the described low oil smoke sunflower oil of this hair, the oil after decolouring is pumped to vertical Leaf-type filter, then refined filtration.
The low oil smoke sunflower oil that the production technology of low oil smoke sunflower oil of the present invention is obtained, FFA values< 0.05%th, POV values≤0.8mmol/kg, the chilled experiment of sunflower oil, test period is small more than 48 at present at a temperature of 0 DEG C, Sunflower oil still clear.
In addition, the nutrition for the low oil smoke sunflower oil that the production technology of low oil smoke sunflower oil of the present invention is obtained Value is high, content of trans fatty acids is low, and the oil smoke amount produced by high-temperature heating is low.
Embodiment
The production technology to low oil smoke sunflower oil of the present invention is done further below in conjunction with specific embodiments Explanation and illustration, but the explanation and illustration to technical scheme constitute it is not improper limit.
Embodiment 1-10
FFA value≤4%, moisture and volatile content≤0.5%, insoluble for the sunflower seeds crude oil that embodiment 1-10 is selected Impurity content≤0.5%, phosphorus content≤500ppm, residual molten≤100ppm.
Above-mentioned sunflower seeds crude oil is produced and processed into low oil smoke sunflower oil, comprised the following steps:
(1) degumming:The temperature control of degumming is at 69 DEG C~81 DEG C;
(2) depickling:The temperature control of depickling is at 69 DEG C~81 DEG C;
(3) wash:Washed using acid water, acid water addition is the 5%~8% of oily weight;
(4) centrifuge:Centrifuged after washing;
(5) it is dried in vacuo:Vacuum drying vacuum is not more than 100mbar;
(6) winterization:Dried oil is pumped out from basin, temperature adjustment, into crystallizing tank and maturator, cooling, regulation oil Temperature in tank adds the filter aid that mass percent is 0.3%~0.8%, is pumped into filter, filter at 2 DEG C~12 DEG C Go out clarified oil and wax, clarified oil is pumped into winterization edible vegetable oil tank, first refined filtration;The filtering of winterization step uses horizontal blade filter;
(7) decolourize:The vacuum of bleaching tower is not more than 100mbar in decolorization process, and bleaching temperature is 100 DEG C~120 DEG C; Oil after decolouring is pumped to vertical blade filter, then refined filtration;Refined filtration aperture is 5 μ again;
(8) it is deodorized:Vacuum no more than 2.0mbar is evacuated to, plate column ramp cycle is carried out, when oil temperature in plate column When reaching 180 DEG C, stripped vapor in plate column is opened, is stirred, carry out aliphatic acid trapping, trapping temperature is 40 DEG C~60 DEG C;When When oil temperature in plate column reaches 220 DEG C~260 DEG C, sunflower oil is first pumped into packed tower, plate column is entered back into, is taken off It is smelly;Vapor flow of stripper is 0.3%~1.0% in plate column in deodorizing technology.
(9) cool:Cooling step temperature is not more than 45 DEG C;
(10) refined filtration:Refined filtration aperture is 1 μ, and the sunflower oil of low oil smoke amount is obtained after refined filtration.
It should be noted that:The equipment directly contacted with oil in deodorization, cooling step is made up of 304 stainless steels, it is not necessary to Use antioxidant.
In addition, after the decolorising agent in embodiment 1-10 is pre-mixed using low in acidity or neutral clay with activated carbon, being stirred with oil Enter bleaching tower after mixing to decolourize, carclazyte mass percent is 0.3%~1.2%.
Table 1 lists specific process parameter in step involved by embodiment 1-10 production technology.
Table 1.
Table 2 lists the oil quality index contrast of the sunflower seeds crude oil before refining and the sunflower oil after refining.
Table 2.
Project Before refining After refining
FFA values % 0.78 0.05
POV values (mmol/kg) 7.48 0
Phosphorus content (mg/kg) 94 0
Color and luster -- Y:4;R:0.4;G:0.1
Smoke point (DEG C) -- 225
0 DEG C of refrigeration test -- Clear
Moisture (%) 0.05 0.01
Impurity (%) 0.08 0.005
As can be seen from Table 2, the sunflower oil produced using the production method of the low oil smoke sunflower oil described in this case, FFA value≤0.05%, peroxide value POV values≤0.8mmol/kg, it is small that the chilled 0 DEG C of test period of experiment of sunflower oil is more than 48 When, sunflower oil still clear.
Table 3 lists the survey of the vitamin E, trans-fatty acid and oil smoke amount of embodiment 1-10 low oil smoke sunflower oil Test result.
Table 3.
Sequence number Vitamin E (mg/kg) Trans-fatty acid (g/100g) Oil smoke amount (mg/m3)
Embodiment 1 617 0.06 1
Embodiment 2 585 0.09 1
Embodiment 3 561 0.13 1
Embodiment 4 573 0.15 1
Embodiment 5 575 0.15 1
Embodiment 6 566 0.16 1
Embodiment 7 551 0.18 1
Embodiment 8 543 0.19 1
Embodiment 9 546 0.20 1
Embodiment 10 550 0.21 1
As can be seen from Table 3, the sunflower oil produced using the production method of the low oil smoke sunflower oil described in this case, oil Smoke is low, rationally saves nutritional ingredient, and content of vitamin E is high, and content of trans fatty acids is low.
With reference to table 1 to table 3 as can be seen that the production technology of this case substantially increases institute by the optimization to process conditions The quality of the sunflower oil of acquisition.For example, being produced when producing the sunflower oil obtained through high-temperature heating by described production technology Oil smoke amount it is low, while in turn ensure that the composition of the vitamin E in sunflower oil keeps higher level, content of trans fatty acids Seldom, product oil acid value is less than 0.05mgKOH/g, and the peroxide value of product oil, which is less than in 0.8mmol/kg, refrigeration test, to be freezed Time still kept clear more than 48 hours oil products.
It should be noted that prior art part is not limited to given by present specification in protection scope of the present invention Embodiment, all prior arts not contradicted with the solution of the present invention, including but not limited to first patent document, formerly Public publication, formerly openly use etc., it can all include protection scope of the present invention.
In addition, in this case the combination of each technical characteristic do not limit in this case claim described combination or It is the combination described in specific embodiment, all technical characteristics that this case is recorded can carry out independent assortment in any way Or combine, unless produced contradiction each other.
In addition, it is also to be noted that listed above is only specific embodiment of the invention, it is clear that the invention is not restricted to Above example, the similar change for having many therewith.If those skilled in the art is direct from present disclosure All deformations for exporting or associating, all should belong to protection scope of the present invention.

Claims (11)

1. a kind of production technology of low oil smoke sunflower oil, it is characterised in that comprise the following steps:
Degumming, depickling, washing, centrifugation, vacuum drying, winterization, decolouring, deodorization, cooling, refined filtration, wherein deodorizing technology include with Lower step:
Vacuum no more than 2.0mbar is evacuated to, plate column ramp cycle is carried out, when oil temperature reaches 180 DEG C in plate column, Stripped vapor in plate column is opened, is stirred, aliphatic acid trapping is carried out, trapping temperature is 40 DEG C~60 DEG C;When the oil in plate column When temperature reaches 220 DEG C~260 DEG C, sunflower oil is first pumped into packed tower, plate column is entered back into, is deodorized.
2. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that the winterization technique include with Lower step:Dried oil is pumped out from basin, temperature adjustment, into crystallizing tank and maturator, cooling, temperature of the regulation oil in tank Degree at 2 DEG C~12 DEG C, add mass percent be 0.3%~0.8% filter aid, be pumped into filter, filter out clarified oil and Wax, clarified oil is pumped into winterization edible vegetable oil tank, first refined filtration.
3. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that board-like in the deodorizing technology The mass percent of vapor flow of stripper and deodorised oil is 0.3%~1.0% in tower.
4. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that the temperature control of degumming and depickling System is at 69 DEG C~81 DEG C.
5. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that enter water-filling using acid water Wash, acid water addition is the 5%~8% of oily weight.
6. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that vacuum drying vacuum is not More than 100mbar.
7. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that the filtering of winterization step is used Horizontal blade filter.
8. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that in deodorization, cooling step with The equipment that oil is directly contacted is made up of 304 stainless steels, it is not necessary to use antioxidant.
9. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that cooling step temperature is not more than 45℃。
10. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that bleaching tower in decolorization process Vacuum be not more than 100mbar, bleaching temperature is 100 DEG C~120 DEG C.
11. the production technology of low oil smoke sunflower oil as claimed in claim 1, it is characterised in that the oil after decolouring is pumped to Vertical blade filter, then refined filtration.
CN201710683374.1A 2017-08-09 2017-08-09 A kind of production technology of low oil smoke sunflower oil Pending CN107299001A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116042310A (en) * 2022-12-28 2023-05-02 中粮营养健康研究院有限公司 Processing method of sunflower seed oil and grease obtained by processing method
WO2023081983A1 (en) * 2021-11-12 2023-05-19 Intreft Pty Ltd A process for refining a vegetable oil
US11717003B2 (en) 2020-10-10 2023-08-08 Nanjing Agricultural University Grilling method for controlling content of polycyclic aromatic hydrocarbons in charcoal-grilled meat
WO2024229520A1 (en) * 2023-05-11 2024-11-14 Intreft Pty Ltd A process and apparatus for refining a vegetable oil

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CN102517142A (en) * 2011-12-20 2012-06-27 山东渤海实业股份有限公司 Zero trans-fatty acid multi-vitamin first-grade soybean oil and preparation method thereof
CN104450181A (en) * 2014-12-31 2015-03-25 山东玉生源油脂有限公司 Production process for original fragrance corn oil

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11717003B2 (en) 2020-10-10 2023-08-08 Nanjing Agricultural University Grilling method for controlling content of polycyclic aromatic hydrocarbons in charcoal-grilled meat
WO2023081983A1 (en) * 2021-11-12 2023-05-19 Intreft Pty Ltd A process for refining a vegetable oil
CN116042310A (en) * 2022-12-28 2023-05-02 中粮营养健康研究院有限公司 Processing method of sunflower seed oil and grease obtained by processing method
CN116042310B (en) * 2022-12-28 2023-11-03 中粮营养健康研究院有限公司 Processing method of sunflower seed oil and grease obtained by processing method
WO2024229520A1 (en) * 2023-05-11 2024-11-14 Intreft Pty Ltd A process and apparatus for refining a vegetable oil

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