CN107297213A - A kind of method for preparing quaternary sulfide quantum dots photochemical catalyst - Google Patents
A kind of method for preparing quaternary sulfide quantum dots photochemical catalyst Download PDFInfo
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- 239000003054 catalyst Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 11
- 125000000101 thioether group Chemical group 0.000 title claims abstract description 7
- 239000010949 copper Substances 0.000 claims abstract description 22
- 229910052802 copper Inorganic materials 0.000 claims abstract description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 16
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 claims abstract description 9
- XURCIPRUUASYLR-UHFFFAOYSA-N Omeprazole sulfide Chemical compound N=1C2=CC(OC)=CC=C2NC=1SCC1=NC=C(C)C(OC)=C1C XURCIPRUUASYLR-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000004246 zinc acetate Substances 0.000 claims abstract description 6
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005864 Sulphur Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 239000002096 quantum dot Substances 0.000 abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 16
- 239000001257 hydrogen Substances 0.000 abstract description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 13
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 238000006555 catalytic reaction Methods 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000003426 co-catalyst Substances 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 238000012546 transfer Methods 0.000 abstract description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005275 alloying Methods 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 238000005457 optimization Methods 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- 230000001699 photocatalysis Effects 0.000 description 8
- 238000007146 photocatalysis Methods 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229910003373 AgInS2 Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 150000004770 chalcogenides Chemical class 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000012869 ethanol precipitation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Catalysts (AREA)
Abstract
The present invention relates to metal of alloying sulfide, refer in particular to a kind of method for preparing quaternary sulfide quantum dots photochemical catalyst, with copper acetate, zinc acetate, indium nitrate, thioacetamide is the method that raw material prepares I III VI race CuInZnS quantum dot light catalyst, and its preparation technology is simple, and product is the photochemical catalyst with good visible light catalysis activity.The valence band of the quantum dot system is made up of the 2p tracks of sulphur and the 3d tracks of copper, by regulating and controlling amount of copper, to influence the band gap of material, i.e. to the absorbability of light, copper defect effect is reduced with co-catalyst Pt simultaneously, greatly promote the separation and transfer in nanocrystalline photoexcited electron hole, optimization production hydrogen activity.
Description
Technical field
The present invention relates to metal of alloying sulfide, refers in particular to one kind with copper acetate, zinc acetate, indium nitrate, thioacetamide
The method that I-III-VI race CuInZnS quantum dot light catalyst is prepared for raw material, its preparation technology is simple, and product is that have well
The photochemical catalyst of visible light catalysis activity.
Background technology
At present, light hydrogen production by water decomposition technology can realize that substantial amounts of solar energy is changed to chemical energy, be energy conversion
Good mode, and the Hydrogen Energy prepared, are a kind of clean energy resourcies of sustainable high fuel value, can solve simultaneously increasingly
Severe environmental problem and problem of energy crisis.The key of the high activity of photochemical catalyzing is the band structure of catalyst, right
The absorbability of light and the separation of photogenerated charge and transfer.Therefore photochemical catalyst of the research with high catalytic activity is to decomposition water
With vital influence.
Compared to body phase material, Colloidal Quantum Dots can regulate and control band gap by component, so as to influence the absorption model to light
Enclose and intensity, quantum size effect causes quantum dot to have specific surface area big, and surface dangling bonds are more so that photocatalytic activity site
It is many, the short extensive concern for waiting unique optical characteristics to cause researcher of distance that photo-generated carrier spreads to catalytic surface.Newly
I-III-VI without Cd2Race ternary chalcogenide thing (I=Cu, Ag；III=Ga, In；VI=S, Se) such as CuInS2、
CuInSe2、CuGaS2、AgInS2And AgGaS2Nano material is direct band gap material and the quantum dot of environmental protection, with larger
The excellent property such as Stokes shift, longer fluorescence lifetime by numerous studies.ZnS is incorporated into by the research such as Tsuji
CuInS2Mischcrystal photocatalyst (Cu In) is formed in crystalxZn2(1-x)S2, by the regulation of component, obtain 1.75eV-
The photochemical catalyst of 2.67eV bandgap ranges, Zn introducing causes the light abstraction width of material greatly to increase, and is effectively improved
The utilization ratio of solar energy.Typically by broad-band gap ZnS (Eg=2.5eV) and narrow band gap AgInS2(Eg=1.8eV) synthesize
(Ag In)xZn2(1-2x)S2Photochemical catalyst, and control ZnS and AgInS2Ratio can adjust (Ag In)xZn2(1-2x)S2
Energy gap, with very high photocatalysis hydrogen production efficiency.(the Ag In) of 3wt%Pt loads0.22Znl.56S2At 420nm
The sub- efficiency of hydrogen output reaches 20%.The research such as Zhijun Ning applies the AgInZnS of zero dimension in different solutions pH value, catalysis
Photocatalyzed Hydrogen Production situation under the concentration of agent, the concentration of sacrifice agent and the production hydrogen condition of cocatalyst concentration, optimizes light point
Xie Shui condition.However, regulation and control of the application study also not on CuInZnS quantum dot component copper influence on Photocatalyzed Hydrogen Production.
The content of the invention
It is an object of the present invention to provide one kind with zinc acetate, copper acetate, indium nitrate, thioacetamide, Cys, hydrogen-oxygen
Change sodium to be raw material to synthesize the hydro-thermal being simply easily controlled of the quantum dot light catalyst with good visible photocatalysis water activity
Method.
The present invention is realized by following steps：
(1) the Cys aqueous solution is added in copper acetate, indium nitrate and zinc acetate mixed aqueous solution, then adjusts mixing
The pH of liquid, adds sulphur source, stirring ultrasound, then mixed liquor is poured into water heating kettle, is placed in 110 DEG C of baking ovens and reacts 4 hours.Use water
Precipitation is washed with ethanol, obtained CuInZnS quantum dot light catalyst is stored in water, and controls the accounting of copper acetate, Cu/
In/Zn mol ratios are 0.05/10/5-2.5/10/5, and CIZS-0.05-CIZS-2.5 are designated as respectively.Optimal mole of photocatalysis performance
Than for 1/10/5, i.e. CIZS-1.
The pH value of the regulation mixed liquor refers to：Use concentration for 1 mole every liter sodium hydroxide adjust mixed liquor pH be
8.5。
The mole of thioacetamide and Cys is fixed as 2.4 and 3.7 mMs in building-up process.
(2) the CuInZnS quantum dot light catalyst prepared by the present invention, size is 3-5 nanometers, in aqueous in clarification
Transparent solution, and the accounting containing different Cu sample under same concentrations solution colour fade to red from glassy yellow.
(3) instrument such as X-ray diffractometer (XRD), Flied emission 300kV high-resolution-ration transmission electric-lens, ultraviolet specrophotometer are utilized
Device carries out structural analysis to product, is catalytically decomposed using vulcanized sodium and sodium sulfite as sacrifice agent and platinum as co-catalyst
Water, its photocatalysis performance is assessed with photochemical catalyzing analysis system.
The present invention relates to quaternary CuInZnS is nanocrystalline, CuInZnS is nanocrystalline to can be by component regulation and control bandgap structure
Visible light-responded n-type quaternary semiconductor, size is small, and specific surface area is larger, and such avtive spot is more, extremely beneficial to photocatalysis
Produce hydrogen, and narrower charge migration distance so that electron hole pair quickly can be migrated and separated.The quantum dot system
Valence band is made up of the 2p tracks of sulphur and the 3d tracks of copper, by regulating and controlling amount of copper, to influence the band gap of material, improves the absorption to light
Ability, while reduce copper defect effect with co-catalyst Pt, greatly promote nanocrystalline photoexcited electron hole separation and
Transfer, optimization production hydrogen activity.
Brief description of the drawings
Fig. 1 is the XRD diffraction spectrograms of prepared CuInZnS quantum dot light catalyst；
Fig. 2 is the transmission plot and high-resolution transmission plot of prepared CuInZnS quantum dot light catalyst；
Fig. 3 is the solid UV absorption figure of prepared CuInZnS quantum dot light catalyst；
Fig. 4 is the Photocatalyzed Hydrogen Production performance map of prepared CuInZnS quantum dot light catalyst.
Embodiment
The preparation of embodiment 1CuInZnS quantum dot light catalyst
Weigh copper acetate, 0.139 gram of zinc acetate, 0.4867 gram of indium nitrate, mixing is dissolved in 4.125 milliliters of water, here for
The CuInZnS photochemical catalysts of the different accounting amount of copper of synthesis, are separately added into different amounts of copper acetate 0.0127g-0.0635g
(CIZS-0.05-CIZS-2.5), 0.4537 gram of Cys aqueous solution is added after uniform mixing.Again with 1 mole of every liter of concentration
Sodium hydroxide regulation pH be 8.5, add 0.183 gram of thioacetyl amine aqueous solution, ultrasonic mixing is uniform, hydro-thermal in 110 DEG C of baking ovens
Reaction 4 hours, is cooled to room temperature.During washing centrifugation, first adding a small amount of water dissolves it, is adding ethanol precipitation to centrifuge, so
Repeat two to three times.Finally by the preservation soluble in water of obtained CuInZnS quantum, it is easy to the test point of later structure and performance
Analysis.
The phenetic analysis of embodiment 2CuInZnS quantum dot light catalyst
As shown in figure 1, as can be seen from the figure with the increase of copper content, the diffraction of CuInZnS quantum dot light catalyst
Main peak type does not change substantially, but main peak is moved slightly towards big wave number, can be due to that copper is further acted on quantum dot
As a result.
As shown in Fig. 2 it can be seen that we are successfully prepared out the quantum dot of 3-5 nanosizeds, and between lattice
Away from 0.31 nanometer it is corresponding be chalcopyrite CuInZnS quantum dots (112) crystal face.
As shown in figure 3, as can be seen from the figure with the increase of copper content, the increasing of red shift, i.e. amount of copper occurs for the absorption of light
Plus the band gap of quantum dot is reduced, add the absorption to light.
As shown in figure 4, as can be seen from the figure with the increase of copper content, the increase of photocatalysis Decomposition aquatic products hydrogen activity is said
Bright copper has the reduction to be probably due to the appearance of copper defect production hydrogen activity important, rear activity so that light induced electron is multiple
Conjunction center increases.
The visible light catalysis activity experiment of embodiment 3CuInZnS quantum dot light catalyst
(1) platinum acid chloride solution for weighing 100 milligrams of CuInZnS quantum dot lights catalyst and 2wt% is placed in photocatalysis hydrogen production
In reactor, add 100 milliliters of water and appropriate sacrifice agent is ultrasonic 15 minutes.
(2) amount of the hydrogen of generation is measured with gas-chromatography within every 1 hour.
(3) the high visible light catalysis activity of prepared photochemical catalyst, especially CIZS-1 sample as seen from Figure 4, it is living
Property than CIZS-0.05 production hydrogen it is high about 11 times.
Claims (4)
1. a kind of method for preparing quaternary sulfide quantum dots photochemical catalyst, it is characterised in that：The Cys aqueous solution is added
Enter in copper acetate, indium nitrate and zinc acetate mixed aqueous solution, then adjust the pH of mixed liquor, add sulphur source, stirring ultrasound, then will mix
Close liquid to pour into water heating kettle, be placed in 110 DEG C of baking ovens and react 4 hours, wash precipitation with water and ethanol, obtained CuInZnS quantum
Point photochemical catalyst is stored in water, controls the accounting of copper acetate, and Cu/In/Zn mol ratios are 0.05/10/5-2.5/10/5, are passed through
Regulate and control amount of copper, to influence the band gap of material, improve the absorbability to light.
2. a kind of method for preparing quaternary sulfide quantum dots photochemical catalyst as claimed in claim 1, it is characterised in that：Cu/
In/Zn mol ratios are 1/10/5.
3. a kind of method for preparing quaternary sulfide quantum dots photochemical catalyst as claimed in claim 1, it is characterised in that described
The pH value of regulation mixed liquor refers to：It is 8.5 for the pH value that 1 mole every liter of sodium hydroxide adjusts mixed liquor to use concentration.
4. a kind of method for preparing quaternary sulfide quantum dots photochemical catalyst as claimed in claim 1, it is characterised in that：Synthesis
During the moles of thioacetamide and Cys be fixed as 2.4 and 3.7 mMs.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276987A (en) * | 2018-01-30 | 2018-07-13 | 吉林大学 | A kind of preparation and its application of the reinforced electric chemiluminescent agent based on CuInZnS/ZnS quantum dots |
| CN110124697A (en) * | 2019-04-12 | 2019-08-16 | 江苏大学 | A kind of 0D/2D composite photocatalyst material and preparation method and purposes |
| CN110354903A (en) * | 2019-08-29 | 2019-10-22 | 南昌航空大学 | A kind of preparation method of photocatalysis Decomposition aquatic products hydrogen material |
| CN111285396A (en) * | 2020-03-16 | 2020-06-16 | 常州大学 | Preparation method of Cu-In-Zn-S nanosphere and application of nanosphere In photoresponse detector |
| WO2021135089A1 (en) * | 2019-12-31 | 2021-07-08 | 肇庆市华师大光电产业研究院 | Cu2znbi2s3 nano-rod and use thereof |
| CN113893839A (en) * | 2021-11-11 | 2022-01-07 | 周口师范学院 | Preparation method of photocatalytic material for indoor air purification |
| CN114042446A (en) * | 2021-12-23 | 2022-02-15 | 江苏大学 | Preparation method and application of phthalocyanine-derived functional carbon quantum dot modified CIZS quantum dot composite photocatalyst |
| CN115337949A (en) * | 2022-08-01 | 2022-11-15 | 云南大学 | Heterojunction composite material, preparation method thereof and application of heterojunction composite material as photocatalyst |
| CN115532284A (en) * | 2022-10-14 | 2022-12-30 | 东莞理工学院 | Multi-element sulfide heterojunction microsphere, preparation method and application thereof, and photocatalytic hydrogen production method |
| WO2023108948A1 (en) * | 2021-12-17 | 2023-06-22 | 公元股份有限公司 | Preparation method for cu2s/cuins2/znin2s4 composite photocatalyst and use thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276987A (en) * | 2018-01-30 | 2018-07-13 | 吉林大学 | A kind of preparation and its application of the reinforced electric chemiluminescent agent based on CuInZnS/ZnS quantum dots |
| CN108276987B (en) * | 2018-01-30 | 2020-04-28 | 吉林大学 | Preparation and application of enhanced electrochemical luminescent agent based on CuInZnS/ZnS quantum dots |
| CN110124697A (en) * | 2019-04-12 | 2019-08-16 | 江苏大学 | A kind of 0D/2D composite photocatalyst material and preparation method and purposes |
| CN110354903A (en) * | 2019-08-29 | 2019-10-22 | 南昌航空大学 | A kind of preparation method of photocatalysis Decomposition aquatic products hydrogen material |
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