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CN107287609B - Continuity hydrogen-rich water preparation apparatus for household RO water purification machines - Google Patents

Continuity hydrogen-rich water preparation apparatus for household RO water purification machines Download PDF

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Publication number
CN107287609B
CN107287609B CN201610225834.1A CN201610225834A CN107287609B CN 107287609 B CN107287609 B CN 107287609B CN 201610225834 A CN201610225834 A CN 201610225834A CN 107287609 B CN107287609 B CN 107287609B
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Prior art keywords
water
hydrogen
household
water purification
chamber
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CN201610225834.1A
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CN107287609A (en
Inventor
刘佳
张玉鹏
于观贞
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BEIJING ZHONGQINGYUAN ENGINEERING TECHNOLOGY Co.,Ltd.
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Shanghai Purple Box Biotechnology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The present invention relates to hydrogen-rich water preparation apparatus more particularly to a kind of hydrogen-rich water preparation apparatus of household.A kind of continuity hydrogen-rich water preparation apparatus for household RO water purification machines, it is connected on household RO water purification machine rear class charcoal canisters position, it includes a chamber, middle part is equipped with SPE electrode electrolysers in chamber, chamber is divided into two Room by the SPE electrode electrolysers, its cathode side is equipped with pure water entrance and hydrogen-rich water out, and anode-side is equipped with the oxygen outlet for leading to RO water purification machine wastewater discharge pipes.Structure of the invention is exquisite, can be substituted for " the rear class charcoal canister " of household RO water purification machines so that consumer can produce the hydrogen-rich water that concentration meets hydrogen molecule biomedicine meaning at homeNote is 1.

Description

Continuity hydrogen-rich water preparation apparatus for household RO water purification machines
Technical field
The present invention relates to hydrogen-rich water preparation apparatus more particularly to a kind of hydrogen-rich water preparation apparatus of household.
Background technology
Biomedical scientific research shows that hydrogen-rich water has prodigious biological significance to promoting health, in the market therewith Start various pre-packaged hydrogen-rich waters, hydrogen-rich cup and equipment occur, but ordinary consumer is limited to price reasons, and to hydrogen The scarcity of biological medical effect knowledge, which is difficult to which kind of product be applicable in, forms decision.
Sun Xuejun professors'《Hydrogen molecule biology》It mentions and being roughly divided into the method for production hydrogen-rich water:
(One), water electrolysis method
Electrolysis water is to be used for the hydrogen water of human body earliest, and electrolysis water is drunk for the purpose of health care and originates from Japan earliest.Through It crosses several years application to summarize, Japanese government's labour Health and human services department approval electrolyzed water machine of new generation is medical apparatus, pays close attention to and drinks electricity The medical health effect of Xie Shui.
The basic reason that electrolysis water treats disease is that electrolysis water contains hydrogen.The certain density hydrogen of content in electrolysis water, Trying to meet the deadline for the project for this concentration reaches the oxidation resistant level of hydrogen enough.Alkalescent water is neutralized into neutrality, its antioxygen is not influenced and is turned into With.
(Two), magnesium metal react hydrogen
The slow chemical reaction for being generated hydrogen and magnesium hydroxide under long article using magnesium metal and water, is prepared easy to use Hydrogen water.Main problem existing for this hydrogen water is the stability that hydrogen generates, and is beginning to use the stage effectiveness may It is more satisfactory, but after a period of use, the generation meeting of hydrogen
It gradually decreases.About the safety issue of magnesium ion, since magnesium ion belongs to human body needs as calcium ion Metallic element, will not generally lead to the harm of body, but have the patient of kidney failure that must be drunk under physician guidance.
Therefore, electrolysis is safer, also complies with the definition of food additives standard GB31633-2014 but is limited to electricity Solve some drawbacks of aquatic products:Anode metal is easily precipitated;It is also easy to produce ozone, chlorine;Regular pickling is needed to safeguard electrode;Hydrogen molecule Content is extremely low;Water ph value etc. is drunk in change, and family is widely available more difficult.
CN104968608A discloses a kind of hydrogen water preparation apparatus, which includes being configured to electrolysis water Electrolysis installation, and the electrolysis installation includes the electricity formed by anode, cathode, solid polyelectrolyte membrane and auxiliary electrode Pole module, wherein the electrolysis installation is divided into the first Room and second Room centered on the electrode module;It is configured to lead to Setting is crossed in first interior, discharges the hydrogen water discharge port of hydrogen water, the hydrogen water is included in the cathode of first Room Locate the reactive hydrogen generated;It is configured to through setting in first interior, to the injection tip of cathode injection water;It is configured To discharge the Ozone Water discharge port of the water containing the ozone generated in the second Room anode;It is disposed therein portion space Store hydrogen water and disinfectant holding tank, by be connected to the first flow channel being connect with the hydrogen water discharge port and with The second flow path of first flow channel connection, and receive the hydrogen water in the described first indoor generation, and by with 4th flow channel of the Ozone Water discharge port connection, receives the disinfectant generated in the second Room;And comprising The pump of output end and input terminal, the output end are connected to the third flow channel being connect with the injection tip, the input End is connected to the 5th flow channel being connect with the storage groove bottom, wherein the injection tip is sprayed using the pump pressure The hydrogen water being stored in the holding tank, the flow velocity than discharging hydrogen water by the hydrogen water discharge port are fast.According to analysis, the skill The hydrogen-rich water pH of art scheme
Value changes, and can generate ozone.
Invention content
Present invention seek to address that drawbacks described above, provides a kind of continuity hydrogen-rich water preparation dress for household RO water purification machines It sets.Structure of the invention is small and exquisite, simple, can be substituted for " the rear class charcoal canister " of household RO water purification machines so that consumer can be Concentration is produced in family meets the hydrogen-rich water note of hydrogen molecule biomedicine meaning 1..
The present invention is mounted on household RO water purification machine rear class charcoal canisters position, it includes a chamber, during chamber is interior Portion is equipped with SPE electrode electrolysers, which is divided into mutual disconnected two chamber, cathode side chamber by chamber Room lower part is equipped with pure water entrance, top is equipped with hydrogen-rich water out, and anode side room, which is equipped with, leads to RO water purification machine waste water outlet sides Oxygen outlet, it is 0.6mM (± 0.1mM) to prepare in the hydrogen-rich water of generation density of hydrogen.
The continuity hydrogen-rich water preparation apparatus for household RO water purification machines, there are one monitoring for the cathode side band The flow sensing meter of pure water.
The present invention need to cannot be used alone together with the device that household RO water purification machines work;It can replace household RO water purification machines " rear class charcoal canister ".The original pure water for flowing into " rear class charcoal canister " flows into the present invention.It is filled by flow sensing It sets(Can be preposition, it can also postposition)Enter SPE electric tank cathodes side afterwards, is hydrogen-rich water after outflow, and anode-side detaches The oxygen gone out is incorporated to the waste discharge end discharge of RO water purification machines.Judge RO water purification machine working conditions by flow sensing device, and SPE electric tank workings are controlled accordingly.The present invention not output ozone, will not change the acid-base value of water, consumer is allowed to stay at home Reliably and effectively hydrogen-rich water can be produced.It is different from other electrolytic hydrogen production water modes, following features of the present invention:First, only Suitable for being used in conjunction with the equipment for meeting QB/T4144-2010 (household or similar applications reverse osmosis water purifier).Second, drinking water Only contact SPE cathode sides, wholesomeness meet《Drinking Water water quality treater is safe and healthy to advise with functional evaluation Model --- reverse osmosis treatment device》It is required that.Third does not change and drinks water ph value.4th, it is low in energy consumption, ozone is not generated, no Generate sour water.5th, this product meets GB4706.1-2005 households and similar applications security appliance relevant criterion.And it is equipped with Alarm design, can pass through sound(Buzzer), light(LED indicator lights)Clear information is provided the consumer with, has EMC certifications, it can The automatic protection when breaking down;6th, can concentration without interruption 0.6mM or so hydrogen-rich water, be suitble to family in more people It uses;7th, without consumables, Maintenance free.
Description of the drawings
Fig. 1 is the structural schematic diagram of the present invention;
Fig. 2 is moment flow pulse characteristic figure.
Specific implementation mode
As shown in Figure 1, a kind of continuity hydrogen-rich water preparation apparatus for household RO water purification machines, it is connected on household RO On water purification machine rear class charcoal canister position, it includes a chamber 1, and the interior middle part of chamber is equipped with SPE electrode electrolysers 2, should Chamber is divided into mutual disconnected two chamber by SPE electrode electrolysers, and cathode side chamber lower portion is equipped with pure water entrance 3, top Hydrogen-rich water out 4, anode-side are equipped with the oxygen outlet 5 for leading to RO water purification machine waste water drains.Described is used for household The continuity hydrogen-rich water preparation apparatus of RO water purification machines, there are one the flow sensing meters 6 of monitoring pure water for the cathode side band.This hair It is bright to control and generation hydrogen water concentration be maintained 0.6mM(±0.1mM)Used method is as follows:Known flow gauge is special Property is shown in Fig. 2:Umber of pulse corresponds to flow velocity in figure, and flow velocity is obtained by flow sensing meter.
From Fig. 2 it is found that it is about the corresponding 7ml of 1A that electrolyzing pure water, which generates its current strength of hydrogen and gas production,.Therefore, exist Step-by-step counting is combined with current regulation in control, adjustment is changed to the output current intensity of SPE according to flow velocity, passes through production The change of tolerance maintains the homogeneity of hydrogen molecule concentration in solution.
Such as:It is required according to QT/4144-2010 standards, household or similar applications reverse osmosis water purifier net water flux are 0.8L/min, but actually this flow velocity and unstable, can slow down in the overall process of production water because of the rising of system pressure, because This, detects flow velocity, and it is the way for realizing concentration control that change in flow this objective circumstances, which are reacted in the change of current strength, Diameter.
The present invention is that prepared hydrogen solution concentration is adjusted using this principle.
Note is 1.:Term and explanation:
1, concentration meets the hydrogen-rich water of biological medical effect:
Density of hydrogen is the hydrogen-rich water of 0.6mM (± 0.1mM) in solution.
2, say that the hydrogen-rich water of a concentration of 0.6mM (± 0.1mM) is that have the representative of biological medical effect why:
Because clinical scholar is proved by the clinical random-stringent check experiment of doubleblind-placebo of newest people, this concentration With specific biological medical effect.(Hydrogen activates ATP-binding cassette transporter A1-dependent efflux ex vivo and improves highdensity lipoprotein function in patients with hypercholesterolemia: adouble-blinded, randomized and placebo- controlled trial.
(J Clin Endocrinol Metab:May 15, 2015)
3, hydrogen solution Concentration Testing method
It is detected using Denmark Unisense microelectrode systems according to document.

Claims (1)

1. a kind of continuity hydrogen-rich water preparation apparatus for household RO water purification machines, it is mounted on household RO water purification machine rear classes On charcoal canister position, which is characterized in that it includes a chamber, and the interior middle part of chamber is equipped with SPE electrode electrolysers, the SPE Chamber is divided into mutual disconnected two chamber by electrode electrolyser, and cathode side chamber lower portion is equipped with pure water entrance, top is equipped with richness Hydrogen water out, anode side cavity are equipped with the oxygen outlet for leading to RO water purification machine waste water outlet sides, and the cathode side also carries The flow sensing meter of one monitoring pure water;The pure water of household RO water purification machines outflow enters SPE after the flow sensing meter Electric tank cathode side is hydrogen-rich water after outflow, and the oxygen that anode-side is isolated is incorporated to the waste discharge end discharge of RO water purification machines; Judge RO water purification machine working conditions by flow sensing meter, and controls SPE electric tank workings accordingly.
CN201610225834.1A 2016-04-13 2016-04-13 Continuity hydrogen-rich water preparation apparatus for household RO water purification machines Active CN107287609B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102186781A (en) * 2008-10-17 2011-09-14 有限会社春天 Apparatus for producing hydrogen-dissolved drinking water and process for producing the dissolved drinking water
CN103101994A (en) * 2011-10-05 2013-05-15 三星电子株式会社 Apparatus for producing reducing water
CN205603687U (en) * 2016-04-13 2016-09-28 上海紫盒生物科技有限公司 A continuity hydrogen -rich water preparation facilities for domestic RO water purification machine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102186781A (en) * 2008-10-17 2011-09-14 有限会社春天 Apparatus for producing hydrogen-dissolved drinking water and process for producing the dissolved drinking water
CN103101994A (en) * 2011-10-05 2013-05-15 三星电子株式会社 Apparatus for producing reducing water
CN205603687U (en) * 2016-04-13 2016-09-28 上海紫盒生物科技有限公司 A continuity hydrogen -rich water preparation facilities for domestic RO water purification machine

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Effective date of registration: 20210427

Address after: 100124 room 950, 9th floor, building 10, huashanyuan Cultural Media Industrial Park, 1376 folk culture street, Gaobeidian village, Gaobeidian Township, Chaoyang District, Beijing

Patentee after: BEIJING ZHONGQINGYUAN ENGINEERING TECHNOLOGY Co.,Ltd.

Address before: 200434, room 2, zone 2, zone 249, West Cen street, No. 216, Qingpu District, Shanghai,

Patentee before: SHANGHAI PURPLE-BOX BIOLOGICAL TECHNOLOGY Co.,Ltd.

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