CN107285417A - A kind of ozone water apparatus removes ozone mechanism and ozone water apparatus - Google Patents
A kind of ozone water apparatus removes ozone mechanism and ozone water apparatus Download PDFInfo
- Publication number
- CN107285417A CN107285417A CN201710681182.7A CN201710681182A CN107285417A CN 107285417 A CN107285417 A CN 107285417A CN 201710681182 A CN201710681182 A CN 201710681182A CN 107285417 A CN107285417 A CN 107285417A
- Authority
- CN
- China
- Prior art keywords
- ozone
- gas
- ozone water
- water apparatus
- liquid separator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 214
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 127
- 230000007246 mechanism Effects 0.000 title claims abstract description 30
- 239000007788 liquid Substances 0.000 claims abstract description 50
- 239000007789 gas Substances 0.000 claims abstract description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000001301 oxygen Substances 0.000 claims abstract description 33
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 33
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 230000008676 import Effects 0.000 claims abstract description 17
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims description 19
- 238000000967 suction filtration Methods 0.000 claims description 12
- 239000012528 membrane Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- 229960004643 cupric oxide Drugs 0.000 claims description 3
- 238000004332 deodorization Methods 0.000 claims description 3
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(II) nitrate Inorganic materials [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 3
- 229910001923 silver oxide Inorganic materials 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 229920000295 expanded polytetrafluoroethylene Polymers 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims 1
- 239000008246 gaseous mixture Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 7
- 238000007598 dipping method Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Inorganic materials [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/66—Ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/2366—Parts; Accessories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Life Sciences & Earth Sciences (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
The present invention discloses the ozone water apparatus that a kind of ozone water apparatus removes ozone mechanism except ozone mechanism and using the ozone water apparatus.The ozone water apparatus includes pipeline and the gas-liquid separator, ozone decomposed tank and the air-extractor that are sequentially communicated except ozone mechanism, and wherein gas-liquid separator is used to separate Ozone Water with undissolved ozone and oxygen mixed gas in water;Ozone decomposed tank is used to ozone and oxygen mixed gas being decomposed into pure oxygen gas;Air-extractor be used to accelerate in the gas-liquid separator and in the ozone decomposed tank air inlets flow from gas to the air-extractor;The pipeline includes the first import, first import and the Ozone Water outlet of the gas-liquid separator.The ozone water apparatus that the present invention is provided eliminates out the peculiar smell of the ozone of ozone waterpipe, use is more comfortable, safer except ozone mechanism can be converted to the undissolved ozone in water in ozone waterpipe oxygen emptying or be discharged together with Ozone Water.
Description
Technical field
Ozone mechanism is removed the present invention relates to sewage disposal, Ozone Water preparing technical field, more particularly to a kind of ozone water apparatus
And the ozone water apparatus of ozone mechanism is removed using the ozone water apparatus.
Background technology
The ozone water apparatus sold on current market can substantially be divided into following three kinds:The first is using oxygen as gas raw material
Oxygen type ozone water apparatus, be for second the air source ozone water dispenser using air as gas raw material, the third is using water as raw material
Electrolysis type ozone generator.The difference of above-mentioned three kinds of ozone water apparatus is that the raw material for preparing ozone is different with principle, but
It is that ozone is dissolved in into water to obtain Ozone Water, ozone is dissolved in due to water has dissolved efficiency and dissolution rate, the ozone
When being mixed with Ozone Water with water, also the gas such as ozone in pipeline with Ozone Water flow out machine.Make raw material with purity oxygen
With the ozone water apparatus that water is raw material, the Ozone Water come out from the ozone water out of ozone water apparatus also includes the undissolved ozone in water
And oxygen, make the ozone water apparatus of raw material with air, the Ozone Water come out from the ozone water out of ozone water apparatus also includes undissolved
In the ozone, oxygen and oxides of nitrogen gas of water, user's breathing is easily allowed to arrive ozone.Ozone has stink and oxidisability, not
Smelling good, and breathing overrich ozone can also be damaged to healthy.
Therefore, it is practical necessary a kind of improved ozone water apparatus is provided not to be dissolved in the ozone gas of water to eliminate.
The content of the invention
The main object of the present invention is to provide a kind of ozone for the ozone gas that can be eliminated and not be dissolved in water in ozone water apparatus
Water deodoring oxygen mechanism.
To achieve the above object, a kind of ozone water apparatus proposed by the present invention removes ozone mechanism, and it includes:Gas-liquid separator,
For Ozone Water to be separated with undissolved ozone and oxygen mixed gas in water;Ozone decomposed tank, with the gas-liquid separator
Outlet side connection, for ozone and oxygen mixed gas to be decomposed into pure oxygen gas;Air-extractor, the air-extractor enters
The pure oxygen gas outlet of gas port and the ozone decomposed tank, for accelerating in the gas-liquid separator and the ozone decomposed
In tank air inlets flow from gas to the air-extractor;Pipeline, the pipeline includes the first import, first import and institute
State the Ozone Water outlet of gas-liquid separator.
Preferably, the gas-liquid separator includes the cylinder of axially vertical setting, is installed on the cylinder inboard wall at least
Two pieces of horizontal baffles, the horizontal baffle be arranged in parallel and interlaced above and below the axis direction along the cylinder.
Preferably, the quantity of the horizontal baffle is two pieces, and the outward flange of two pieces of horizontal baffles exceedes the cylinder
The radial center of body.
Preferably, the gas-liquid import of the gas-liquid knockout and ozone water out are arranged at the cylinder and are located furthest from
The lower section of the horizontal baffle of ozone decomposed tank, the gas-liquid import is used for mixed for Ozone Water and undissolved ozone and oxysome in water
Gas is closed to enter in the cylinder.
Preferably, the outlet side of the gas-liquid separator is located at the top of the cylinder, and it includes the shell for having receiving space
Body, the waterproof ventilated membrane being installed in the receiving space, the air admission hole for connecting the receiving space and the gas-liquid separator
And connect the venthole of the receiving space and the ozone decomposed tank.
Preferably, the waterproof ventilated membrane is ePTFE waterproof ventilated membranes.
Preferably, the ozone decomposed tank includes tank body and is contained in the tank body to be used to accelerate ozone decomposed to be pure oxygen
Filler.
Preferably, the filler includes one kind or two in carrier and the silver oxide and cupric oxide that are deposited on the carrier
The mixture and manganese oxide planted, the carrier are porous mass.
Preferably, the preparation method of the filler is as follows:
Step 1: weighing particle diameter 1~8mm 100g porous masses is dipped in 1.0mol/L Mn (CH3COO)2/Mn(NO3)2It is molten
In liquid, 6~30h is impregnated, suction filtration dries 1~4h in 110 DEG C of baking oven, 1~5h is calcined in 400 DEG C of Muffle furnaces, is cooled to
Room temperature obtains substance A;
Step 2: the substance A prepared in the step one is inserted into 0.5mol/LAgNO3And/or Cu (NO3)2Soaked in solution
6~30h of stain, suction filtration dries 1~4h at 110 DEG C, and 1~5h is calcined in 400 DEG C of Muffle furnaces, is cooled to room temperature and obtains described
Filler.
The present invention also provides a kind of ozone water apparatus, and the ozone water apparatus includes the ozone water preparing machine structure being connected and above
Described ozone water apparatus removes ozone mechanism, wherein, the ozone water preparing machine is configured standby Ozone Water also including undissolved in water
Ozone and oxygen mixed gas, in the ozone water out of the ozone water preparing machine structure and the ozone water apparatus deodorization mechanism
The gas-liquid inlet communication of gas-liquid separator.
Compared to prior art, the ozone water apparatus that the present invention is provided, which removes ozone mechanism and ozone water apparatus, has following beneficial effect
Really:
First, undissolved ozone and oxygen mixed gas in water is separated with Ozone Water by gas-liquid separator, from gas-liquid
The ozone and oxygen mixed gas of separator discharge enter after ozone decomposed tank, and pure oxygen gas is decomposed into by ozone decomposed tank, pure
Carrier of oxygen can the steam vent through ozone water apparatus discharge, also can be together with after the Ozone Water mixing discharged from gas-liquid separator from pipe
Road is discharged, and the Ozone Water that user obtains has been eliminated the stink of the undissolved ozone in water, free from extraneous odour, and uses safer.
2nd, gas-liquid separator includes at least two pieces horizontal baffles of interlaced setting, and horizontal baffle can change air-flow
Direction, so that gas and liquid separation, even if ozone and oxygen mixed gas are separated with Ozone Water, as a result simply, and separation
Effect is good.
3rd, the outlet side of gas-liquid separator is provided with waterproof ventilated membrane, the water that can be filtered out in gas-liquid separator steams
Vapour, it is ensured that the discomposing effect of ozone decomposed tank and the service life for improving ozone decomposed tank.
4th, ozone decomposed tank includes tank body and the filler that is contained in the tank body, by filler by ozone fast decoupled
For pure oxygen gas, have the advantages that simple in construction and cost is low.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Structure according to these accompanying drawings obtains other accompanying drawings.
Fig. 1 is the structural representation that ozone water apparatus of the present invention removes the preferred embodiment of ozone mechanism one.
The realization, functional characteristics and advantage of the object of the invention will be described further referring to the drawings in conjunction with the embodiments.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art obtained under the premise of creative work is not made it is all its
His embodiment, belongs to the scope of protection of the invention.
It is to be appreciated that institute is directional in the embodiment of the present invention indicates that (such as up, down, left, right, before and after ...) is only used
In explaining relative position relation, mobility status under a certain particular pose (as shown in drawings) between each part etc., if should
When particular pose changes, then directionality indicates also correspondingly therewith to change.
In addition, in the present invention such as relating to the description of " first ", " second " etc. be only used for describe purpose, and it is not intended that
Indicate or imply its relative importance or the implicit quantity for indicating indicated technical characteristic.Thus, define " first ",
At least one this feature can be expressed or be implicitly included to the feature of " second ".In the description of the invention, " multiple " contain
Justice is at least two, such as two, three etc., unless otherwise specifically defined.
In the present invention, unless otherwise clearly defined and limited, term " connection ", " fixation " etc. should be interpreted broadly,
For example, " fixation " can be fixedly connected or be detachably connected, or integrally;Can be mechanically connect or
Electrical connection;Can be joined directly together, can also be indirectly connected to by intermediary, can be the connection or two of two element internals
The interaction relationship of individual element, unless otherwise clear and definite restriction.For the ordinary skill in the art, can basis
Concrete condition understands the concrete meaning of above-mentioned term in the present invention.
In addition, the technical scheme between each embodiment of the invention can be combined with each other, but must be general with this area
Logical technical staff can be implemented as basis, when the combination appearance of technical scheme is conflicting or can not realize it will be understood that this
The combination of technical scheme is not present, also not within the protection domain of application claims.
Because there is the technical problem of peculiar smell containing ozone in the Ozone Water prepared for prior art, the present invention proposes a kind of smelly
Oxygen water dispenser removes ozone mechanism, and the ozone water apparatus is arranged except the ozone not being dissolved in Ozone Water is converted into pure oxygen gas by ozone mechanism
Go out, eliminate the peculiar smell that ozone is produced, the Ozone Water free from extraneous odour for obtaining user, rich in more oxygen, use is more comfortable and more
Safety.
Embodiment 1
Refer to Fig. 1, in an embodiment of the present invention, the ozone water apparatus except ozone mechanism 100 include pipeline 70 and according to
Gas-liquid separator 10, ozone decomposed tank 30 and the air-extractor 50 of secondary connection.Wherein, the gas-liquid separator 10 is used for ozone
Water is separated with undissolved ozone and oxygen mixed gas in water, its outlet side 11 and the ozone and oxygen of the ozone decomposed tank 30
Oxygen mixture inlet communication.The ozone decomposed tank 30 is used to the mixed gas of ozone and oxygen being decomposed into pure oxygen gas,
Ozone and oxygen mixed gas are broken down into pure oxygen gas from the pure oxygen gas of ozone decomposed tank 30 after entering ozone decomposed tank 30
Outlet discharge.The pure oxygen gas outlet of the air inlet 51 of the air-extractor 50 and the ozone decomposed tank 30, it is described to take out
Gas equipment 50 be used for speed up gas and liquid separator 10 and the ozone decomposed tank 30 in air inlet from gas to the air-extractor 50
Mouth 51 flows.The pipeline 70 includes the first import 71, and first import 71 and the Ozone Water of the gas-liquid separator 10 go out
Mouth 12 is connected, and it is act as the Ozone Water export of ozone free peculiar smell.The present invention is by gas-liquid separator 10 by undissolved in water
Ozone and oxygen mixed gas separated with Ozone Water, from gas-liquid separator 10 discharge ozone and oxygen mixed gas enter it is smelly
After oxygen solution tank 30, pure oxygen gas is decomposed into by ozone decomposed tank 30, the Ozone Water that user obtains has been eliminated the stink of ozone,
Free from extraneous odour, and using safer.
In the present embodiment, the gas-liquid separator 10 includes the cylinder 15 of axially vertical setting, is installed on the cylinder
At least two pieces horizontal baffles 17 of 15 inwalls, the horizontal baffle 17 be arranged in parallel above and below the axis direction along the cylinder 15 and
It is interlaced.Specifically, refer to horizontal baffle 17 positioned at Different Plane, there is point of height along the axis direction of cylinder 15, and it is adjacent
Horizontal baffle 17 be located on the side wall that is oppositely arranged, that is, be staggered, and be then flat positioned at the horizontal baffle 17 of homonymy side wall
What row was set.
Preferably, the quantity of the horizontal baffle 17 is two pieces, and the outward flange of two pieces of horizontal baffles 17 exceedes institute
State the radial center of cylinder 15.
In the present embodiment, the outlet side 11 of the gas-liquid separator 10 is located at the top of the cylinder 15.The gas-liquid
The gas-liquid import 13 of knockout 10 and ozone water out 12 are arranged at the cylinder 15 and are located furthest from ozone decomposed tank 30
The lower section of horizontal baffle 17 (i.e. the horizontal baffle of bottom in Fig. 1), can specifically be arranged at the cylinder 15 bottom or
On the side wall for connecting bottom and top.The gas-liquid import 13 is used to mix for Ozone Water and undissolved ozone and oxysome in water
Gas enters in the cylinder 15, and the ozone water out 12 is used for the Ozone Water for discharging ozone free peculiar smell.
Preferably, the outlet side 11 of the gas-liquid separator 10 includes tool receiving space 111A housing 111, is installed on institute
State the waterproof ventilated membrane 113 in receiving space 111A, connect air admission hole and the company of the receiving space 111A and the cylinder 15
Lead to the venthole of the receiving space 111A and the ozone decomposed tank 30.In the present embodiment, the waterproof ventilated membrane 113 is
EPTFE waterproof ventilated membranes.
Preferably, the ozone decomposed tank 30 includes tank body 31, is contained in the tank body 31 for accelerating ozone decomposed
For the filler 33 of pure oxygen.The import 35 of the ozone and oxygen mixed gas of the ozone decomposed tank 30 is located at the bottom of the tank body 31
End, it is connected with the venthole of outlet side 11;The outlet 37 of pure oxygen gas is located at the top of the tank body 31.
Specifically, the filler 33 include one kind in carrier and the silver oxide and cupric oxide that are deposited on the carrier or
Two kinds of mixture and manganese oxide, the carrier is porous mass.
The preparation method of the filler is as follows:
Step 1: weighing particle diameter 1~8mm 100g porous masses is dipped in 1.0mol/L Mn (CH3COO)2/Mn(NO3)2It is molten
In liquid, 6~30h is impregnated, suction filtration dries 1~4h in 110 DEG C of baking oven, 1~5h is calcined in 400 DEG C of Muffle furnaces, is cooled to
Room temperature obtains substance A;
Step 2: the substance A prepared in the step one is inserted into 0.5mol/LAgNO3And/or Cu (NO3)2Soaked in solution
6~30h of stain, suction filtration dries 1~4h at 110 DEG C, and 1~5h is calcined in 400 DEG C of Muffle furnaces, is cooled to room temperature and obtains described
Filler.
In the present embodiment, the air-extractor 50 is aspiration pump.The air inlet 51 of the air-extractor 50 with it is described pure
The outlet 37 of carrier of oxygen is connected.
Preferably, the pipeline 70 also includes the second import 73, and second import 73 goes out with the air-extractor 50
Gas port 53 is connected.Decomposing obtained pure oxygen gas through ozone decomposed tank 30 can be by the steam vent on ozone water apparatus or other way
Footpath is vented, and is discharged after can also being mixed through pipeline 70 together with Ozone Water.
The present invention also provides a kind of ozone water apparatus, and the ozone water apparatus includes the ozone water preparing machine structure being connected and above
Described ozone water apparatus removes ozone mechanism 100, wherein, the ozone water preparing machine be configured standby Ozone Water also include it is undissolved in
The ozone and oxygen mixed gas of water, the ozone water out of the ozone water preparing machine structure and the ozone water apparatus deodorization mechanism
The gas-liquid import 13 of gas-liquid separator 10 in 100 is connected.
Embodiment 2
Weigh particle diameter 8mm 100g porous masses and be dipped in 1.0mol/L Mn (CH3COO)2In solution, dipping 30h, suction filtration,
4h is dried in 110 DEG C of baking oven, 3h is calcined in 400 DEG C of Muffle furnaces, room temperature is cooled to and obtains substance A;Then A is inserted
0.5mol/LAgNO322h is impregnated in solution, suction filtration dries 2.5h at 110 DEG C, and 3h is calcined in 400 DEG C of Muffle furnaces, cooled down
The filler is obtained to room temperature, the time that ozone decomposed is pure oxygen is 1 second by the filler.
Embodiment 3
Weigh particle diameter 6mm 100g porous masses and be dipped in 1.0mol/L Mn (NO3)2In solution, dipping 30h, suction filtration,
4h is dried in 110 DEG C of baking oven, 3h is calcined in 400 DEG C of Muffle furnaces, room temperature is cooled to and obtains substance A;Then A is inserted
0.5mol/L Cu(NO3)222h is impregnated in solution, suction filtration dries 2.5h at 110 DEG C, 3h is calcined in 400 DEG C of Muffle furnaces,
It is cooled to room temperature and obtains the filler, the time that ozone decomposed is pure oxygen is 1 second by the filler.
Embodiment 4
Weigh particle diameter 1mm 100g porous masses and be dipped in 1.0mol/L Mn (CH3COO)2In solution, dipping 30h, suction filtration,
4h is dried in 110 DEG C of baking oven, 3h is calcined in 400 DEG C of Muffle furnaces, room temperature is cooled to and obtains substance A;Then A is inserted
0.5mol/L Cu(NO3)2With 0.5mol/L AgNO3Mixed solution in impregnate 22h, suction filtration dries 2.5h at 110 DEG C,
3h is calcined in 400 DEG C of Muffle furnaces, room temperature is cooled to and obtains the filler, the time that ozone decomposed is pure oxygen is 1 by the filler
Second.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the scope of the invention, it is every at this
Under the design of invention, the equivalent structure transformation made using description of the invention and accompanying drawing content, or directly/it is used in indirectly
He is included in the scope of patent protection of the present invention related technical field.
Claims (10)
1. a kind of ozone water apparatus removes ozone mechanism, it is characterised in that it includes:
Gas-liquid separator, for Ozone Water to be separated with undissolved ozone and oxygen mixed gas in water;
Ozone decomposed tank, is connected with the outlet side of the gas-liquid separator, pure for ozone and oxygen mixed gas to be decomposed into
Carrier of oxygen;
Air-extractor, the pure oxygen gas outlet of the air inlet of the air-extractor and the ozone decomposed tank, for accelerating
In the gas-liquid separator and in the ozone decomposed tank air inlets flow from gas to the air-extractor;
Pipeline, the pipeline includes the first import, first import and the Ozone Water outlet of the gas-liquid separator.
2. ozone water apparatus according to claim 1 removes ozone mechanism, it is characterised in that the gas-liquid separator is included axially
Vertically disposed cylinder, at least two pieces horizontal baffles for being installed on the cylinder inboard wall, the horizontal baffle is along the cylinder
It is be arranged in parallel above and below axis direction and interlaced.
3. ozone water apparatus according to claim 2 removes ozone mechanism, it is characterised in that the quantity of the horizontal baffle is two
Block, and radial center of the outward flange more than the cylinder of two pieces of horizontal baffles.
4. ozone water apparatus according to claim 2 removes ozone mechanism, it is characterised in that the gas-liquid of the gas-liquid knockout is entered
Mouth and ozone water out are arranged at the cylinder and are located furthest from the lower section of the horizontal baffle of the ozone decomposed tank, the gas
Liquid import is used to enter in the cylinder for Ozone Water and undissolved ozone and oxysome gaseous mixture in water.
5. ozone water apparatus according to claim 4 removes ozone mechanism, it is characterised in that the outlet side of the gas-liquid separator
Positioned at the top of the cylinder, it includes the housing for having receiving space, is installed on waterproof ventilated membrane in the receiving space, even
Lead to the air admission hole of the receiving space and the cylinder and connect the venthole of the receiving space and the ozone decomposed tank.
6. ozone water apparatus according to claim 5 removes ozone mechanism, it is characterised in that the waterproof ventilated membrane is ePTFE
Waterproof ventilated membrane.
7. ozone mechanism is removed according to any one of claim 1 to 6 ozone water apparatus, it is characterised in that the ozone decomposed tank
Including tank body and be contained in the tank body be used for accelerate ozone decomposed be pure oxygen filler.
8. ozone water apparatus according to claim 7 removes ozone mechanism, it is characterised in that the filler includes carrier and deposition
In the mixture and manganese oxide of one or both of the silver oxide and cupric oxide on the carrier, the carrier is porosity
Matter.
9. ozone water apparatus according to claim 8 removes ozone mechanism, it is characterised in that the preparation method of the filler is such as
Under:
Step 1: weighing particle diameter 1~8mm 100g porous masses is dipped in 1.0mol/L Mn (CH3COO)2/Mn(NO3)2In solution,
6~30h is impregnated, suction filtration dries 1~4h in 110 DEG C of baking oven, 1~5h is calcined in 400 DEG C of Muffle furnaces, room temperature is cooled to
Obtain substance A;
Step 2: the substance A prepared in the step one is inserted into 0.5mol/LAgNO3And/or Cu (NO3)26 are impregnated in solution
~30h, suction filtration dries 1~4h at 110 DEG C, and 1~5h is calcined in 400 DEG C of Muffle furnaces, is cooled to room temperature and obtains described fill out
Material.
10. a kind of ozone water apparatus, it is characterised in that it includes the ozone water preparing machine structure being connected and claim 1 to 9 is any
Ozone water apparatus described in removes ozone mechanism, wherein, the ozone water preparing machine be configured standby Ozone Water also include it is undissolved in
In the ozone and oxygen mixed gas of water, the ozone water out of the ozone water preparing machine structure and the ozone water apparatus deodorization mechanism
Gas-liquid separator gas-liquid inlet communication.
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Citations (5)
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EP0711731A2 (en) * | 1994-11-11 | 1996-05-15 | KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. | Ozone water production apparatus |
CN101052460A (en) * | 2004-10-07 | 2007-10-10 | 株式会社成长 | Ozonidate prepn. plant |
CN103272612A (en) * | 2013-05-16 | 2013-09-04 | 陈和平 | Preparation method of room-temperature ozone-removing catalyst |
JP2013212485A (en) * | 2012-04-03 | 2013-10-17 | Amemiya Kiki Kk | Ozone water generating apparatus |
CN204380328U (en) * | 2015-01-05 | 2015-06-10 | 河北科技大学 | A kind of gas-liquid separator |
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2017
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EP0711731A2 (en) * | 1994-11-11 | 1996-05-15 | KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. | Ozone water production apparatus |
CN101052460A (en) * | 2004-10-07 | 2007-10-10 | 株式会社成长 | Ozonidate prepn. plant |
JP2013212485A (en) * | 2012-04-03 | 2013-10-17 | Amemiya Kiki Kk | Ozone water generating apparatus |
CN103272612A (en) * | 2013-05-16 | 2013-09-04 | 陈和平 | Preparation method of room-temperature ozone-removing catalyst |
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