CN107075298A - Easy adhesive composition and the optical film and its manufacture method for having used said composition - Google Patents
Easy adhesive composition and the optical film and its manufacture method for having used said composition Download PDFInfo
- Publication number
- CN107075298A CN107075298A CN201580060306.9A CN201580060306A CN107075298A CN 107075298 A CN107075298 A CN 107075298A CN 201580060306 A CN201580060306 A CN 201580060306A CN 107075298 A CN107075298 A CN 107075298A
- Authority
- CN
- China
- Prior art keywords
- film
- weight
- parts
- water
- adhesive composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 62
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 62
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000012788 optical film Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 239000010408 film Substances 0.000 claims abstract description 97
- 239000012790 adhesive layer Substances 0.000 claims abstract description 49
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 43
- -1 water-soluble carbodiimide compound Chemical class 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 13
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 43
- 150000001875 compounds Chemical class 0.000 claims description 30
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
- 230000015572 biosynthetic process Effects 0.000 claims description 14
- 239000004925 Acrylic resin Substances 0.000 claims description 13
- 229920000178 Acrylic resin Polymers 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 125000005647 linker group Chemical group 0.000 claims description 2
- 230000009467 reduction Effects 0.000 abstract description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 97
- 230000006978 adaptation Effects 0.000 description 16
- 239000010410 layer Substances 0.000 description 16
- 239000000126 substance Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 239000012948 isocyanate Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 150000001718 carbodiimides Chemical class 0.000 description 7
- 239000003431 cross linking reagent Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 230000009477 glass transition Effects 0.000 description 7
- 150000002513 isocyanates Chemical class 0.000 description 7
- 210000004379 membrane Anatomy 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 239000007767 bonding agent Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- 150000005846 sugar alcohols Polymers 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002346 layers by function Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 238000007591 painting process Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 229920002284 Cellulose triacetate Polymers 0.000 description 3
- 239000004970 Chain extender Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 210000000713 mesentery Anatomy 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 2
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920005497 Acrypet® Polymers 0.000 description 2
- 101710130081 Aspergillopepsin-1 Proteins 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical class OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 238000006114 decarboxylation reaction Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000002466 imines Chemical group 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000012766 organic filler Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical class O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical class O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical class O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- QGLRLXLDMZCFBP-UHFFFAOYSA-N 1,6-diisocyanato-2,4,4-trimethylhexane Chemical class O=C=NCC(C)CC(C)(C)CCN=C=O QGLRLXLDMZCFBP-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- ZLLVNPWAUPIQPX-UHFFFAOYSA-N 2-(dihydroxymethyl)pentanoic acid Chemical compound CCCC(C(O)O)C(O)=O ZLLVNPWAUPIQPX-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- UDVRROYKHLBOPZ-UHFFFAOYSA-N 3,3-dihydroxy-2-methylpropanoic acid Chemical compound OC(O)C(C)C(O)=O UDVRROYKHLBOPZ-UHFFFAOYSA-N 0.000 description 1
- IPFDALLIRXQJDG-UHFFFAOYSA-N 3,3-dihydroxypropanoic acid Chemical compound OC(O)CC(O)=O IPFDALLIRXQJDG-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- IFFLEFLILATDQZ-UHFFFAOYSA-N but-2-ene methyl 2-methylprop-2-enoate Chemical group CC=CC.COC(C(=C)C)=O IFFLEFLILATDQZ-UHFFFAOYSA-N 0.000 description 1
- QVYARBLCAHCSFJ-UHFFFAOYSA-N butane-1,1-diamine Chemical compound CCCC(N)N QVYARBLCAHCSFJ-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000004990 dihydroxyalkyl group Chemical group 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical group O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000003949 imides Chemical group 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000003402 intramolecular cyclocondensation reaction Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- HTEAGOMAXMOFFS-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C HTEAGOMAXMOFFS-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000005968 oxazolinyl group Chemical group 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- KNCYXPMJDCCGSJ-UHFFFAOYSA-N piperidine-2,6-dione Chemical compound O=C1CCCC(=O)N1 KNCYXPMJDCCGSJ-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polarising Elements (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
The problem of the present invention is to provide the reduction for not only suppressing the initial performance when hot and humid lower long-time is used but also can meet the easy adhesive composition of humidity resistance under more harsh environment and the optical film of the adhesive layer formed by the easy adhesive composition is set at least one surface of thermoplastic resin film.The present invention provides a kind of easy adhesive composition, and it contains：100 parts by weight have the water-dispersible polyurethane resin of carboxyl, 1~25 parts by weight water-soluble carbodiimide compound and 1~25 parts by weight water dispersible carbodiimide compound；A kind of optical film, it is that the adhesive layer formed by the easy adhesive composition is set at least one surface of thermoplastic resin film.
Description
Technical field
The present invention relates to easy adhesive composition and the optical film with the adhesive layer being made up of the easy adhesive composition.
The invention further relates to the manufacture method of the optical film and possesses the polarizer (polarizing plate, Polarizer) of the optical film
And image display device.
Background technology
The acrylic acid series tree that known (methyl) acrylic polymer by by representative of polymethyl methacrylate is formed
The optical characteristics such as adipose membrane light transmittance are excellent, and mechanical strength and shaping processability is harmonious excellent.Therefore, acrylic acid series tree
Adipose membrane has been applied to be assembled in liquid crystal display device (LCD), plasma display panel (PDP), organic EL display
(OLED) optical film of image display device as.
Optical film in the state of the stacking of other functional membranes generally with using.For example, regarding optical film as polaroid
(polarizer) diaphragm is in use, at least one side of polaroid can be laminated in via hydrophilic adhesive layer.Obtain
The polarizer can be used for image display device etc..In this case, the adaptation of optical film and polaroid is well important.
However, for acrylic resin film, it is poor with the cementability of hydrophilic adhesive to exist, close with polaroid
The problem of conjunction property is insufficient such.Therefore, it is proposed to be set on the surface of acrylic resin film with polyester, acrylic acid tree
Fat, polyurethane etc. help the resin of cementability for the adhesive layer of main component, assign easy-adhesion to acrylic resin film
Method.
On the other hand, in recent years, used carrying equipment of the image display devices such as LCD etc. whether indoor or
Used in outdoor various environment, even sometimes requiring that the humidity resistance that hot and humid environment is also resistant to.For being used for
The polarizer of such purposes, it is desirable to also do not occur the high adhesion of splitting under hot and humid.
Therefore, in Japanese Unexamined Patent Publication 2009-193061 publications, as the polarizer of the excellent adhesion under hot and humid,
Describe and the polymer for coordinating Ju You oxazolinyls is formed on the surface of (methyl) acrylic resin film as crosslinking agent
Into adhesive layer scheme.In Japanese Unexamined Patent Publication 2014-35411 publications, describe to improve acrylic acid mesentery and polarisation
The adaptation of piece, and set and be combined with polyester resin, polyvinyl alcohol resin and by isocyanate compound or melamine amination
The adhesive layer of the crosslinking agent of compound formation.
The content of the invention
Invent problem to be solved
However, for the optical film with adhesive layer disclosed in above-mentioned document, although originally show good closely sealed
Property, but in hot and humid lower long-time in use, can not be avoided with the adaptation reduction of polaroid.Due to such adaptation drop
It is low, therefore there is the problem of can not maintaining initial performance (initial adaptation) for a long time so.In addition, disclosed in above-mentioned document
Although humidity resistance of the optical film with adhesive layer in the environment of 40~60 DEG C, 60~90%RH or so is satisfactory,
Humidity resistance under more harsh environment under (for example, 80 DEG C, 90%RH) fails satisfactory.
The present invention be in view of so the problem of and complete, problem, which is to provide, can not only suppress when hot and humid lower long
Between initial performance when using reduction but also can meet humidity resistance under more harsh environment easy adhesive composition,
And the optics of the adhesive layer formed by the easy adhesive composition is set at least one surface of thermoplastic resin film
Film.
Means for solving the problems
By the present invention there is provided：
(1) easy adhesive composition, it contains：100 parts by weight have the water-dispersible polyurethane resin of carboxyl, 1~25 parts by weight
Water-soluble carbodiimide compound and 1~25 parts by weight water dispersible carbodiimide compound.
The present invention is also provided：
(2) the easy adhesive composition described in (1), wherein, foregoing water-soluble carbodiimide compound and foregoing water dispersible carbon two
The weight ratio of group with imine moiety is 30：70~95：5 scope；
(3) the easy adhesive composition described in (1) or (2), wherein, relative to the foregoing weight of water-dispersible polyurethane resin 100
Part, also containing 0.1~15 parts by weight particulate；
(4) optical film, it possesses：Thermoplastic resin film and be arranged at the thermoplastic resin film at least one surface and by
(1) adhesive layer of the easy adhesive composition formation any one of~(3)；
(5) optical film described in (4), wherein, aforementioned thermoplastic resin film is formed by (methyl) acrylic resin；And,
(6) polarizer, it possesses：Polaroid and (4) or (5) that are coated to the surface of the polaroid and are protected to it are described
Optical film.
The present invention and then offer：
(7) manufacture method of optical film, methods described includes following process：
The process that easy adhesive composition is coated at least one surface of thermoplastic resin film and film is formed, the easy bonding
Composition dilutes through water solvent, and has containing 100 parts by weight water-dispersible polyurethane resin, 1~25 parts by weight of carboxyl
Water-soluble carbodiimide compound and 1~25 parts by weight water dispersible carbodiimide compound；And
The process that foregoing dried coating film is formed into adhesive layer.
The effect of invention
Easy adhesive composition of the invention with above-mentioned composition can not only suppress first when hot and humid lower long-time is used
The reduction of beginning performance, and can also maintain under more harsh environment high adhesion.Therefore, have for having used by this
Invention easy adhesive composition formation adhesive layer optical film the polarizer for, it is hot and humid under optical film and polarisation
The excellent adhesion of piece.It should be noted that in this specification, the term of " (methyl) acrylic acid " is used as methacrylic acid, third
Olefin(e) acid or the general designation of both and use.The term of " (methyl) acrylonitrile " is similarly.
Brief description of the drawings
[Fig. 1] is the sectional view of one for schematically showing the optical film of the present invention；
[Fig. 2] is the sectional view of one for schematically showing the polarizer of the present invention.
Embodiment
[easy adhesive composition]
The easy adhesive composition of the present invention contains：Water-dispersible polyurethane resin with carboxyl (is hereinafter sometimes referred to simply as U trees
Fat) and it is sub- as the water-soluble carbodiimide compound (hereinafter sometimes referred to simply as S compounds) and water dispersible carbon two of crosslinking agent
Amines (hereinafter sometimes referred to simply as D compounds).The easy adhesive composition constituted as described above not only suppresses high in high temperature
The reduction of initial performance when wet lower long-time is used, and under more harsh environment, adaptation is also excellent.
For the existing known adhesive layer for the purposes, in hot and humid lower long-time in use, closely sealed
The reduction of property can not be avoided.However, in the present invention, suppress the reduction of the initial performance when hot and humid lower long-time is used,
Excellent adhesion under hot and humid.Though its reason is indefinite, it is presumed as follows：S compounds are from D compounds respectively different
Period forms cross-linked structure, in the following manner function.
That is, S compounds and the compatibility of other hydrophilic resins is good, and cross-linking reaction speed is fast, therefore in adhesive layer
During formation, or earlier stage after its formation, the carboxyl formation cross-linked structure with U resins.On the other hand, D compounds and S chemical combination
Thing is compared, and cross-linking reaction speed is slow, therefore, when adhesive layer is formed, the D compounds of remained unreacted in adhesive layer.
Under hot and humid, when the U resins in adhesive layer are Polyester, polyester is hydrolyzed, and ester bond is cut off, and produces carboxylic acid group.
Herein, it is believed that unreacted D compounds are reacted with the carboxylic acid group produced and form cross-linked structure, will be because easy to stick caused by hydrolysis
The deterioration selfreparing of layer is connect, thus, the strength deterioration of the adhesive layer under suppression is hot and humid.
In addition, there is also the functional groups such as carboxyl in the functional layer or thermoplastic resin film for be laminated in adhesive layer.Recognize
For under hot and humid, carboxyl present in these functional layers or thermoplastic resin film reacts with unreacted D compounds, formed
Cross-linked structure, thus, suppresses the strength deterioration of adhesive layer.
As U resins, as long as there is the polyurethane resin of the water dispersible of carboxyl in intramolecular, you can not limit especially
Use to system.U resins are for example manufactured using following methods.First, it is being inertia and compatible with water relative to isocyanates
Make polyisocyanates and polyol reaction in organic solvent, form NCO end prepolymer.Then, make its with trip
From carboxyl chain extender reaction, obtain wire carbamate prepolymer.Then, in the presence of nertralizer, in water, make
Wire carbamate prepolymer carries out chain extension, while carrying out Water-borne modification, thus obtains U resins.It should be noted that herein
So-called Water-borne modification is to instigate resin stably to disperse or emulsify in water.
As polyisocyanates, for example, tetramethylene diisocyanate, ten dimethylene diisocyanates, 1 can be enumerated,
4- butane diisocyanates (1,4-butanediisocyanate), hexamethylene diisocyanate, 2,2,4- trimethyls six are sub-
Methyl diisocyanate, 2,4,4- trimethyl hexamethylene diisocyanates, lysine diisocyanate, 2- methylpentane -1,
The aliphatic diisocyanates such as 5- diisocyanate, 3- methylpentane -1,5- diisocyanate；IPDI,
Hydrogenate XDI, 4,4 '-diphenylmethane diisocyanate, 1,4- cyclohexane diisocyanates, methyl
The alicyclic diisocyanates such as double (isocyanatomethyl) hexamethylenes of cyclohexylene diisocyanate, 1,3-；Toluene diisocynate
Ester, 2,2 '-methyl diphenylene diisocyanate, 2,4 '-methyl diphenylene diisocyanate, the isocyanide of 4,4 '-diphenyl methane two
Acid esters, 4,4 '-diphenyldimethyhnethane diisocyanate, 4,4 '-dibenzyl diisocyanate, 1,5- naphthalene diisocyanates,
The aromatic diisocyanates such as XDI, 1,3- phenylene diisocyanates, 1,4- phenylene diisocyanates；Dioxane
Base methyl diphenylene diisocyanate, tetraalkyl methyl diphenylene diisocyanate, α, α, α, α-tetramethylxylene two
Araliphatic diisocyanates such as isocyanates etc..They can be used alone or two or more also can be combined and uses.
As polyalcohol, as long as having the compound of more than 2 hydroxyls in the molecule, it is not particularly limited, can
Using arbitrary appropriate polyalcohol.For example, polyacrylic polyalcohol, PEPA, PPG, poly- carbon can be enumerated
Acid esters polyalcohol etc..They can be used alone or two or more also can be combined and uses.In addition, in these, preferably using polyester
Polyalcohol, for the Polyester polyurethane resin for having used PEPA, prevent it is hot and humid under adhesive layer
The excellent performance of strength deterioration.
As the chain extender with free carboxyl, for example, dihydroxy carboxylic acids, dihydroxysuccinic acid etc. can be enumerated.As
Dihydroxy carboxylic acids, for example, dihydroxymethyl alkanoic acid can be enumerated (for example, dihydroxymethyl acetic acid, dimethylolpropionic acid, dihydroxymethyl
Propionic acid, dimethylolpropionic acid, dihydroxymethyl valeric acid) etc. dihydroxyalkyl (alkylol) alkanoic acid.They can be used alone or
Two or more can be combined and uses.
As nertralizer, for example, ammonia, N-methylmorpholine, triethylamine, dimethylethanolamine, methyl diethanol can be enumerated
Amine, triethanolamine, morpholine, tripropylamine, monoethanolamine, triisopropanolamine, 2-amino-2-methyl-1-propanol etc..They can be independent
Using or also can be combined two or more and use.
In addition, as other workable chain extenders, can enumerate ethylene glycol, propane diols, BDO, neopentyl glycol,
The low molecular weight diols such as furyl dimethyl carbinol, diethylene glycol (DEG), triethylene glycol, tetraethylene glycol compound and make they and oxirane, epoxy third
Alkane, tetrahydrofuran etc. carry out PTMEG compound obtained from addition polymerization；By above-mentioned low molecular weight diols compound and amber
The polyester two in end with hydroxyl that dicarboxylic acids and their acid anhydrides such as amber acid (acid anhydride), adipic acid, phthalic acid (acid anhydride) are obtained
Alcohol；The polyalcohols such as trimethylolethane, trimethylolpropane；The amino alcohols such as MEA, diethanol amine, triethanolamine；Second two
Two amine compounds such as amine, propane diamine, butanediamine, 1,6- hexamethylene diamines, phenylenediamine, toluenediamine, dimethylphenylene diamine, IPD
Thing；Water, ammonia, hydrazine, binary hydrazides (bis- salt base acid ヒ De ラ ジ De) etc..They can be used alone or two or more also can be combined
And use.
U resins have preferably 5000~600000, further preferred 10000~400000 number-average molecular weight and preferably 10
The above, further preferred 10~50, particularly preferred 20~45 acid number.By making acid number in above range, thus with conduct
Crosslinking agent carbodiimide compound formation cross-linked structure, it is hot and humid under excellent adhesion.It is used as the tool of preferred U resins
Style, can enumerate " Superflex (registration mark) " series, " ADEKA of ADEKA company systems of the first industrial pharmaceutical company system
BONTIGHTER (registration mark) HUX " series, Mitsui Chemicals, Inc.'s system " TAKELAC (registration mark) W, WPB, WS " series,
The commercially available U resins such as " HYDRAN (registration mark) " series of DIC company systems.
Operability consideration when being formed from adhesive layer, can be diluted easy adhesive composition with water solvent.It is used as water system
Solvent, can be used water or water with hydrophilic organic solvent (for example, the alcohol such as methanol, ethanol, isopropanol, ethylene glycol, propane diols system
Solvent；The ester series solvents such as ethyl acetate, butyl acetate, gamma-butyrolacton；The ketone series solvents such as acetone；Tetrahydrofuran, dioxa hexamethylene
The ether series solvents such as alkane；The aprotic polar solvents such as 1-METHYLPYRROLIDONE) mixed solvent, particularly preferably water.
The content of U resins in easy adhesive composition is not particularly limited, it is considered to which painting work etc. is suitably set,
For example, it is preferable to be 1~25 weight %, more preferably more preferably 3~20 weight %, 5~15 weight %.If easily bonding combination
U resins in thing are above range, then operational excellent during adhesive layer formation, thus preferably.In addition, for easy bonding group
For the solid state component amount of compound, it is considered to which painting work etc. is suitably set, preferably 1~30 weight %, more preferably 2
~25 weight %, more preferably 3~20 weight %.
As S compounds, as long as the water miscible compound in intramolecular with the carbodiimide of more than 2 is
Can, it is not particularly limited, for example, the material being dissolved in the water can be enumerated, it is utilized along with organic diisocyanate chemical combination
Then the condensation reaction of the decarboxylation (de- diacid charcoal element) of thing, the poly- carbodiimide in synthesizing isocyanate end, makes itself and hydrophily
Organic compound (hydrophilic organic compound includes the functional group for having reactivity with NCO) reaction, uses hydrophily
Segment poly- carbodiimide system resin obtained from terminal isocyanate is blocked.As S compounds, Nisshinbo can be used
Chemical Inc. systems " Carbodilite (registration mark) SV-02 ", " Carbodilite (registration mark) V-02 ",
" Carbodilite (registration mark) V-04 ", " Carbodilite (registration mark) V-10 ", " Carbodilite (registrars
Mark) the commercially available product such as V-02-L2 ".
For the usage amount of S compounds, in terms of solid state component conversion, relative to the parts by weight of U resins 100, preferably 1
~25 parts by weight, more preferably 3~20 parts by weight, more preferably 5~15 parts by weight.
As D compounds, as long as the compound in intramolecular with the water dispersible of the carbodiimide of more than 2 is
Can, it is not particularly limited, for example, it is not dissolving but the material of differential scattered (emulsion) that can enumerate in water, it is using adjoint
The condensation reaction of the decarboxylation of organic diisocyanate compound, the poly- carbodiimide in synthesizing isocyanate end, then, make its with
Hydrophilic organic compound (hydrophilic organic compound includes the functional group for having reactivity with NCO) reaction, is used
Hydrophilic segment poly- carbodiimide system resin obtained from terminal isocyanate is blocked.It is used as water dispersible carbodiimide chemical combination
Thing, can be used Nisshinbo Chemical Inc. systems " Carbodilite (registration mark) E-01 ", " Carbodilite (notes
Volume trade mark) the commercially available product such as E-02 ".
For the usage amount of D compounds, in terms of solid state component conversion, relative to the parts by weight of U resins 100, preferably 1
~25 parts by weight, more preferably 1~20 parts by weight, more preferably 1~10 parts by weight.S chemical combination in easy adhesive composition
The weight ratio (S/D) of thing and D compounds is usually 30：70~95：5 scope, preferably 40：60~90：10, more preferably
50：50~80：20.
For easy adhesive composition, according to required function, arbitrary appropriate particulate, preferably moisture can be contained
Dissipate the particulate of property.As particulate, inorganic system's particulate, organic system particulate can be used.As inorganic system's particulate, for example, can enumerate
The inorganic oxides such as silica, titanium dioxide, aluminum oxide, zirconium oxide, calcium carbonate, talcum, clay, calcined kaolin, calcining
Calcium silicates, afwillite, alumina silicate, magnesium silicate, calcium phosphate etc..As organic system particulate, for example, silicon-type tree can be enumerated
Fat, fluorine resin, (methyl) acrylic resin, (methyl) Chelate resin etc..In these, preferred (methyl) acrylic
Resin.For the particulate comprising (methyl) Chelate resin, the ability for suppressing caking (blocking) is more excellent, and
The transparency is excellent, and muddy (haze) is not produced, is not coloured, therefore, influence of the easy bonding layer to optical characteristics is smaller yet.Separately
Outside, although the intensity and adaptation of adhesive layer are reduced due to coordinating particulate, but are combined with comprising (methyl) acrylic tree
The adhesive layer of the particulate of fat can suppress the reduction of the intensity and adaptation of adhesive layer, thus preferably.
The average grain diameter of particulate is not particularly limited, from the viewpoint of the transparency for maintaining adhesive layer, preferably 1~
500nm, more preferably 50~350nm, more preferably 100~300nm.By using the particulate of such particle diameter, so that
Be properly formed bumps on adhesive layer surface, can be effectively reduced thermoplastic resin film and adhesive layer contact surface and/
Or the frictional force of the mutual contact surface of adhesive layer, in addition, caking can be suppressed.Above-mentioned average grain diameter refers to, is spread out using laser
Penetrate/the median particle diameter (d50) that measures of the formula particle size distribution of scattering.
For the content of particulate, in terms of solid state component conversion, relative to the parts by weight of U resins 100, preferably 0.1~
15 parts by weight.More preferably 0.3~5 parts by weight, more preferably 0.5~3 parts by weight.
For easy adhesive composition, in order to improve coating strength, it can contain different from above-mentioned S and D compounds
Crosslinking agent or the resin with crosslinking group.As crosslinking agent, can enumerate urea system, epoxy, melamine series, isocyanates system,
Oxazoline system, silanol system etc..In addition, in order to promote cross-linking reaction, as needed, can be suitably using catalyst etc..
Easy adhesive composition can also contain arbitrary appropriate additive.As additive, for example, stably dispersing can be enumerated
Agent, thixotropic agent, antioxidant, ultra-violet absorber, defoamer, thickener, dispersant, surfactant, catalyst, lubrication
Agent, antistatic agent etc..
[optical film]
One of the optical film of the present invention is shown in Fig. 1.For the optical film 1 shown in Fig. 1, in thermoplastic resin film 2
A surface on there is the adhesive layer 3 that is formed by above-mentioned easy adhesive composition.It should be noted that the optics of the present invention
Film also can form adhesive layer on two surfaces of thermoplastic resin film.
As the thermoplastic resin for constituting thermoplastic resin film, for example, the cellulose-based tree such as triacetyl cellulose can be enumerated
Fat, polyester based resin, polyether sulfone system resin, polycarbonate-based resin, polyamide series resin, polyimides system resins, polyolefin
It is resin, cyclic polyolefin hydrocarbon system resin, (methyl) acrylic resin, polyarylate system resin, polystyrene resin, polyethylene
Alcohol system resin etc..They can be used alone or two or more also can be combined and uses.In these, for (methyl) acrylic acid series
For resin (hereinafter sometimes referred to simply as ACR), due to poor with the cementability of hydrophilic adhesive, therefore, when using ACR,
The effect of invention is particularly significant.
ACR glass transition temperature (hereinafter referred to as Tg) is preferably more than 115 DEG C, more preferably more than 120 DEG C, enters one
Step is preferably more than 125 DEG C.It is used as main component for more than 115 DEG C of ACR by making thermoplastic resin film comprising Tg, can be formed
The thermoplastic resin film of excellent in te pins of durability.In addition, above-mentioned Tg higher limit is not particularly limited, consider from viewpoints such as formabilities,
Usually less than 170 DEG C.
As ACR, for example, can enumerate poly- (methyl) acrylate such as polymethyl methacrylate, methyl methacrylate-
(methyl) acrylic copolymer, methyl methacrylate-(methyl) acrylate copolymer, methyl methacrylate-acrylic acid
Ester-(methyl) acrylic copolymer, (methyl) acrylate-styrene copolymer (MS resins etc.), with alicyclic alkyl
Polymer (for example, methyl methacrylate-cyclohexyl methacrylate copolymer, methyl methacrylate-(methyl) propylene
Sour norborny ester copolymer etc.).In above-mentioned substance, poly- (methyl) the acrylic acid C1-6 alkane such as preferably poly- (methyl) methyl acrylate
Base ester, more preferably using methyl methacrylate as main component (50~100 weight %, preferably 70~100 weight %) methyl
Methyl acrylate system resin.
As ACR concrete example, for example, " ACRYPET (the registrations of Mitsubishi Rayon Co., Ltd.s system can be enumerated
Trade mark) VH ", " ACRYPET (registration mark) VRL20A ", pass through high Tg obtained from intramolecular crosslinking, intramolecular cyclization reaction
(methyl) acrylic resin.
For ACR, from the aspect of with high-fire resistance, high transparency, high mechanical properties, have preferably in main chain
Circular structure.As the ACR in main chain with ring structure, for example, can enumerate with glutaric anhydride structure or glutarimide
The resin (WO2007/26659 publications, WO2005/108438 publications) of structure, with maleic anhydride structure or N- substitution horse
Carry out the resin (Japanese Unexamined Patent Application 57-153008 publications, Japanese Unexamined Patent Publication 2007-31537 publications) of imide structure, with interior
Resin (Japanese Unexamined Patent Publication 2006-96960 publications, Japanese Unexamined Patent Publication 2006-171464 publications, the Japanese Unexamined Patent Publication of ester ring structure
2007-63541 publications, Japanese Unexamined Patent Publication 2008-191426 publications).
Thermoplastic resin film can contain additive.As additive, resist for example, hindered phenol series, phosphorus system, sulphur system etc. can be enumerated
Oxidant；The stabilizers such as resistance to light stabilizer, weathering stabilizers, heat stabilizer；The reinforcing materials such as glass fibre, carbon fiber；It is ultraviolet
Light absorbers；Near infrared ray absorption；Fire retardant；The antistatics such as anion system, cation system, the surfactant of nonionic system
Agent；The colouring agents such as inorganic pigment, organic pigment, dyestuff；Organic filler, inorganic filler；Modifier；Organic filler, nothing
Machine filler；Plasticizer；Lubricant；Fire retardant；Phase difference depressant etc..
As the manufacture method of thermoplastic resin film, it is not particularly limited, for example, using arbitrary appropriate mixing side
Thermoplastic resin and other polymers, additive etc. are sufficiently mixed by method, and thermoplastic resin composition is made in advance, then by it
Carry out film shaping.Or also respective solution can be respectively prepared in thermoplastic resin and other polymer, additive etc., so
Mixed afterwards, uniform mixed liquor is made, then carry out film shaping.
In order to manufacture thermoplastic resin composition, for example, being mixed using homogenizer (omni-mixer) etc. is arbitrary appropriate
Conjunction machine, above-mentioned film raw material is pre-mixed, and is then extruded obtained mixture and is kneaded.In this case, it is mixed available for extrusion
The kneading machine of refining is not particularly limited, for example, the extruders such as single screw extrusion machine, double screw extruder, pressurization can be used to mediate
The arbitrary appropriate mixer such as machine.
The method shaped as film, for example, solution casting method (the tape casting), extrusion by melting, rolling process, compression can be enumerated
The arbitrary appropriate film forming process such as forming process.In these film forming processes, preferred molten extrusion molding.
As extrusion by melting, for example, T modulus methods, inflation method etc. can be enumerated.Forming temperature is preferably 150~350 DEG C, more
Preferably 200~300 DEG C.
When carrying out film shaping using T modulus methods, by the leading section of known single screw extrusion machine, double screw extruder
T moulds are installed, film forming is moulded using the T, then by film roll around can obtain the film of web-like.
Thermoplastic resin film can be any of unstretching film or stretched film.In the case of for stretched film, Ke Yishi
Monadic stretching membrane or biaxially-stretched film it is any.In the case of for biaxially-stretched film, can be synchronous double-shaft stretching or
Successively biaxial drawing film it is any.Carried out it is biaxial stretch-formed in the case of, mechanical strength improve, film properties improve.
Draft temperature is preferably near glass transition temperature as the thermoplastic resin composition of film raw material, it is specific and
Speech, preferably in the range of (- 30 DEG C of glass transition temperature)~(+100 DEG C of glass transition temperature), more preferably in (glass
Change -20 DEG C of transition temperature)~(+80 DEG C of glass transition temperature) in the range of.Draft temperature less than (glass transition temperature-
30 DEG C) when, sufficient stretching ratio may be cannot get.Conversely, when draft temperature is higher than (+100 DEG C of glass transition temperature),
Cause the flowing (flow) of resin combination, it may not be possible to the stretching stablized.
Than the stretching ratio of definition it is preferably 1.1~25 times with area, more preferably 1.3~10 times.Stretching ratio is less than
At 1.1 times, it may not be possible to obtain being improved by the toughness for stretching and bringing.When stretching ratio is more than 25 times, it may not be possible to obtain with
Improve the corresponding effect of stretching ratio (raising of toughness).
For draw speed, in one direction, preferably 10~20,000%/min, more preferably 100~10,
000%/min.When draw speed is less than 10%/min, the consuming time is needed in order to obtain sufficient stretching ratio, manufacturing cost can
It can increase.When draw speed is more than 20,000%/min, fracture of stretched film etc. may be caused.
For thermoplastic resin film, in order that its optical isotropy, mechanical property are stabilized, can be in stretch processing
It is heat-treated afterwards (annealing) etc..The condition of heat treatment can be using arbitrary appropriate condition.
The thickness of thermoplastic resin film is preferably 5~200 μm, more preferably 10~100 μm., may when thickness is less than 5 μm
Cannot as optical film sufficient intensity.When thickness is more than 200 μm, transparency reduction may be not suitable anymore for as optics
Film is used.
The thickness of adhesive layer can be set as to arbitrary appropriate value.Preferably 0.1~10 μm, more preferably
0.1~5 μm, particularly preferably 0.2~1.0 μm.By being set as such scope, so that the adaptation with other functional membranes
It is excellent, it can suppress occur phase difference in adhesive layer.
As needed, it can form various on the surface of the opposite side in the surface with being formed with adhesive layer of optical film
Functional layer.On functional layer, for example, antistatic backing, bond layer, adhesive linkage, adhesive layer, anti-dazzle (nonglare) can be enumerated
The stain-proofing layers such as layer, photocatalysis layer, anti-reflection layer, hard conating, ultraviolet blocking layer, infrared ray barrier layer, blocking electromagnetic waves layer, resistance
Gas-bearing formation etc..
Optical film can be used as such as polarizing plate protective film, phase retardation film, compensation film for angular field of view, optical diffusion film, reflectance coating, counnter attack
Film, antiglare film, brightness raising film, touch panel is penetrated to be used with conducting film.In addition, in these, being protected particularly preferable as polaroid
Cuticula is used.
[polarizer]
Next, one of the polarizer of the explanation present invention.The polarizer 10 shown in Fig. 2 has following structures：In thermoplastic resin
Have on one surface of adipose membrane 2 and optical film 1 is obtained by the adhesive layer 3 that above-mentioned easy adhesive composition is formed, described
On the surface of the adhesive layer side of optical film 1, via bonding agent 5, polaroid 6 is laminated with.It should be noted that, although not scheming
Show, but the polarizer 10 can have the diaphragm being laminated via bond layer on the side opposite with optical film 1 of polaroid 6.
, can be using arbitrary appropriate polaroid according to purpose as polaroid.For example, can enumerate in polyethenol series
The hydrophilic macromolecule films such as film, part formalizing polyvinyl alcohol mesentery, the partly-hydrolysed film of vinyl-vinyl acetate copolymer system
The upper absorption dichroic material such as iodine or dichroic dyestuff, and polaroid, the dehydration of polyvinyl alcohol obtained from carrying out uniaxial tension
The polyolefin (polyene) such as processed material, sour (dechlorination) processed material of desalination of polyvinyl chloride are alignment films etc..In these, in poly- second
The polarisation dichroic of polaroid, than high, is special obtained from the dichroic materials such as iodine are adsorbed on enol mesentery and uniaxial tension is carried out
It is not preferred.The thickness of these polaroids is not particularly limited, usually 1~80 μm or so.
, can be using arbitrary appropriate bonding agent as the bonding agent for forming bond layer.It is preferred that bond layer by comprising
The adhesive composite of polyvinyl alcohol resin is formed.
, can be using arbitrary appropriate protection as the diaphragm for the side opposite with optical film 1 for being arranged at polaroid 6
Film, is formed using the material same with above-mentioned thermoplastic resin.
[image display device]
The image display device of the present invention possesses the above-mentioned polarizer.As the concrete example of image display device, it can enumerate electroluminescent
Luminous (EL) display, plasma display (PD), field-emitter display (FED：Field Emission Display) this
Self-luminous display device, the liquid crystal display device (LCD) of sample.
[manufacture method of optical film]
In the preferred manufacture method of the optical film of the present invention, the moisture that will be diluted and contained with water solvent has carboxyl dissipates
Property polyurethane resin, water-soluble carbodiimide compound and water dispersible carbodiimide compound easy adhesive composition coating
In at least one surface of thermoplastic resin film, film (painting process) is formed, next by dried coating film, easily bonding is formed
Layer (drying process).
, can be using arbitrary appropriate method as the method that easy adhesive composition is coated with painting process.For example, can lift
Go out scraping article rubbing method, rolling method, gravure coating process, bar type rubbing method, gap nozzle rubbing method (slot orifice
Coating), curtain coating method, jetting type rubbing method (fountain coating) etc..The coated film formed in painting process
Thickness thickness required when can form adhesive layer according to the coated film is suitably adjusted.
Implement surface treatment in the surface of the easy adhesive composition of coating of preferred pair thermoplastic resin film.As surface treatment,
Preferably Corona discharge Treatment, corona treatment.By implementing Corona discharge Treatment, can improve thermoplastic resin film with it is easy to stick
Connect the adaptation of layer.
Drying process is not particularly limited, using known method.It is 50 typically as drying temperature
More than DEG C, preferably more than 90 DEG C, more preferably more than 110 DEG C.By making drying temperature be above range, color can be made into
The excellent optical film of fastness (color resistance) (especially hot and humid under).The upper limit of drying temperature is preferably less than 200 DEG C, enters one
Step is preferably less than 180 DEG C.
Using the manufacture method of the optical film of the present invention, by light of the non-stretched thermoplastic resin film manufacture as stretched film
When learning film, and, it is necessary to a certain when manufacturing the optical film as biaxially-stretched film by the thermoplastic resin film through uniaxial tension
Time point stretches to these thermoplastic resin films.The stretching of thermoplastic resin film can be carried out before the formation of adhesive layer,
Also it can be carried out after the formation of adhesive layer.In addition, can also carry out the formation of adhesive layer and the drawing of thermoplastic resin film simultaneously
Stretch.
When the formation of progress adhesive layer simultaneously and the stretching of thermoplastic resin film, such as after painting process, in heating
The thermoplastic resin film of coated film under atmosphere to being formed with easy adhesive composition is stretched.By in order to be stretched
And to the heat of film application so that the coated film of the easy adhesive composition formed on the surface of thermoplastic resin film is dried, shape
Into adhesive layer.If so operated, the stretch processing of film and the drying of easy adhesive composition can be carried out simultaneously, productivity ratio is excellent
It is different, thus preferably.
Embodiment
Hereinafter, the present invention is illustrated by embodiment in further detail.It should be noted that the present invention is not by following reality
Apply the limitation of example.
As raw material, following materials is used：
＜ U resins ＞
Emulsion [the first industrial pharmaceutical company system, Superflex (registration mark) of water-dispersible polyurethane resin with carboxyl
210, solid state component amount is 35 weight %]
＜ S compounds (1) ＞
The aqueous solution [Nisshinbo Chemical Inc. systems, Carbodilite (notes containing water-soluble carbodiimide compound
Volume trade mark) V-02-L2, solid state component amount is 40 weight %]
＜ S compounds (2) ＞
The aqueous solution [Nisshinbo Chemical Inc. systems, Carbodilite (notes containing water-soluble carbodiimide compound
Volume trade mark) V-10, solid state component amount is 40 weight %]
＜ D compounds ＞
Emulsion [the Nisshinbo Chemical Inc. systems, Carbodilite (registrars of water dispersible carbodiimide compound
Mark) E-02, solid state component amount is 40 weight %]
＜ particulates ＞
[ponding chemical industrial company system, ADVANCELL NS K-001 are put down emulsion containing acrylic particulate (PAN particulates)
Equal particle diameter is 150nm, and solid state component amount is 20 weight %].
Embodiment 1~5 and comparative example 1~10
1. the manufacture of easy adhesive composition
In the way of as the solid state component amount (unit is parts by weight) shown in table 1 and 2, each composition shown in mixture table 1 and 2,
Manufacture easy adhesive composition.It should be noted that using ion exchange water as the water solvent of easy adhesive composition, with solid-state
It is prepared by the mode that component amount turns into 8 weight %.
2. the manufacture of optical film
Using single screw extrusion machine (φ=20.0mm, L/D=25) and clothes hanger type T moulds (wide 150mm), in 280 DEG C, by acrylic acid
Based resin composition [Tg：135 DEG C, melt viscosity：700Pa s (temperature be 270 DEG C, shear rate be 100 (1/sec))]
Grain melting extrusion, to the chill roll for remain 110 DEG C on discharge molten condition above-mentioned resin combination, is formed thickness be 100 μ
M acrylic resin film.Next, using scraping strip coating machine, be coated with a surface of acrylic resin film according to
The easy adhesive composition that aforesaid way is obtained, then puts into air drier, is dried 90 seconds in 100 DEG C.Then, using platform
Formula stretching-machine, by the film uniaxial tension (stretching ratio：2.5 times), manufacture on the surface of the acrylic resin film of 40 μm of thickness
The optical film of the upper adhesive layer with 0.3 μm of thickness.
3. the manufacture of the polarizer
In the adhesive layer side pva coating system adhesive composite of the optical film obtained in the manner described above.In addition,
Implement unilateral pva coating system bonding agent of the thickness of saponification process for 40 μm of tri acetyl cellulose membrane (diaphragm)
Composition.Next, being coated with layer stackup light via polyethenol series bonding agent respectively in thickness for the both sides of 30 μm of polaroid
Film and diaphragm are learned, obtained layered product is put into air drier (70 DEG C), drying in 5 minutes is carried out, the polarizer is manufactured.
In addition, the both sides for being similarly formed in polaroid are provided with the benchmark of the evaluation of the diaphragm formed by triacetyl cellulose
Inclined device.
For the polarizer obtained in the manner described above, evaluation as follows is carried out.Evaluation result is shown in table 1 and 2.
(1) initial adaptation
The test film of 25mm × 250mm size is cut out from the polarizer obtained in the manner described above, to the optics of test film
Bonding processing is implemented on the surface of film, then, is fitted in glass plate, obtains test sample.Then, in the polaroid of sample
Otch is cut out between optical film, polaroid and diaphragm is held, according to the floating of Japanese bonding agent industrial standard JAI 13-1996
Roller method (Floating-roller method), determines the stripping adhesive strength under the conditions of 90 degree.It should be noted that for base
The quasi- polarizer, also determines stripping adhesive strength under identical condition.It is viscous to peeling off according to measurement result according to following standard
Intensity is connect to be evaluated；
○：Compared with the benchmark polarizer, stripping adhesive strength is more preferable or is equal extent,
△：Compared with the benchmark polarizer, stripping adhesive strength is worse,
×：It is not closely sealed, it is impossible to determine；
(2) humidity resistance (60 DEG C, 90%RH)
It is permanent that test sample obtained from operating as described above is put into the constant temperature that temperature is 60 DEG C, humidity is 90%RH
In wet machine, implement to place the heat treatment of 250 hours and 500 hours, in addition, grasped in the same manner as the evaluation with initial adaptation
Make, determine and peel off adhesive strength.According to following standard, evaluated according to measurement result peeling off adhesive strength；
◎：Compared with the benchmark polarizer, adhesive strength is peeled off more preferably,
○：Stripping adhesive strength with the benchmark polarizer is equal extent,
△：Compared with the benchmark polarizer, stripping adhesive strength is worse,
×：It is not closely sealed, it is impossible to determine；
(3) humidity resistance (80 DEG C, 90%RH)
It is permanent that test sample obtained from operating as described above is put into the constant temperature that temperature is 80 DEG C, humidity is 90%RH
In wet machine, implement to place the heat treatment of 100 hours, in addition, operated in the same manner as the evaluation with initial adaptation, determine and peel off
Adhesive strength.According to following standard, evaluated according to measurement result peeling off adhesive strength；
◎：Compared with the benchmark polarizer, adhesive strength is peeled off more preferably,
○：Stripping adhesive strength with the benchmark polarizer is equal extent,
△：Compared with the benchmark polarizer, stripping adhesive strength is worse,
×：It is not closely sealed, it is impossible to determine.
[table 1]
。
[table 2]
。
As shown in table 1, for using containing the water-dispersible polyurethane resin (U resins) with carboxyl, water-soluble carbon two
The implementation that the easy adhesive composition of group with imine moiety (S compounds) and water dispersible carbodiimide compound (D compounds) is made
For the optical film of example 1~5, not only show that the reduction of the initial performance under hot and humid (60 DEG C, 90%RH) is suppressed, it is high
When being used for a long time under warm high humidity and polaroid excellent adhesion result, and show even in harsh hot and humid
Adaptation also excellent result under environment (80 DEG C, 90%RH).On the other hand, as shown in table 2, for without crosslinking agent or only
For the optical film of comparative example 1~7 containing S compounds, the knot that the hot and humid lower adaptation with polaroid is reduced is shown
Really.In addition, for the optical film of the comparative example 8~10 only containing D compounds, showing that hot and humid lower long-time is used
When excellent adhesion, but the result of initial adaptation difference.
Claims (7)
1. easy adhesive composition, it contains：
100 parts by weight have carboxyl water-dispersible polyurethane resin,
1~25 parts by weight water-soluble carbodiimide compound and
1~25 parts by weight water dispersible carbodiimide compound.
2. easy adhesive composition according to claim 1, wherein, foregoing water-soluble carbodiimide compound and foregoing moisture
The weight ratio for dissipating property carbodiimide compound is 30：70~95：5 scope.
3. easy adhesive composition according to claim 1 or 2, wherein, relative to the poly- ammonia of the foregoing water dispersible of 100 parts by weight
Ester resin, also containing 0.1~15 parts by weight particulate.
4. optical film, it possesses：
Thermoplastic resin film and
It is arranged at least one surface of the thermoplastic resin film and as the easy bonding group any one of claim 1 ~ 3
The adhesive layer of compound formation.
5. optical film according to claim 4, wherein, aforementioned thermoplastic resin film is by (methyl) acrylic resin shape
Into.
6. the polarizer, it possesses：
Polaroid and
The optical film described in claim 4 or 5 for being coated to the surface of the polaroid and being protected to it.
7. the manufacture method of optical film, this method includes following process：
The process that easy adhesive composition is coated at least one surface of thermoplastic resin film and film is formed, the easy bonding
Composition dilutes through water solvent, and has containing 100 parts by weight water-dispersible polyurethane resin, 1~25 parts by weight of carboxyl
Water-soluble carbodiimide compound and 1~25 parts by weight water dispersible carbodiimide compound；And
The process that foregoing dried coating film is formed into adhesive layer.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-225730 | 2014-11-06 | ||
| JP2014225730 | 2014-11-06 | ||
| PCT/JP2015/081116 WO2016072437A1 (en) | 2014-11-06 | 2015-11-05 | Highly adhesive composition, optical film using same and method for producing said optical film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107075298A true CN107075298A (en) | 2017-08-18 |
| CN107075298B CN107075298B (en) | 2019-09-10 |
Family
ID=55909161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580060306.9A Active CN107075298B (en) | 2014-11-06 | 2015-11-05 | Easy adhesive composition and the optical film and its manufacturing method for having used the composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6527878B2 (en) |
| KR (1) | KR102394207B1 (en) |
| CN (1) | CN107075298B (en) |
| TW (1) | TWI661021B (en) |
| WO (1) | WO2016072437A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111890762A (en) * | 2018-07-25 | 2020-11-06 | 日东电工株式会社 | Easy-to-adhere film, method for producing the same, polarizing plate, and image display device |
| CN114730032A (en) * | 2019-11-06 | 2022-07-08 | 日东电工株式会社 | Polarizing plate, image display device, method for designing polarizing plate, method for producing polarizing plate, and method for producing image display device |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2835300T3 (en) * | 2016-08-02 | 2021-06-22 | Tokuyama Corp | Adhesive composition, laminate and optical article including said laminate |
| JP7122830B2 (en) * | 2017-02-06 | 2022-08-22 | 株式会社日本触媒 | OPTICAL FILM MANUFACTURING METHOD AND OPTICAL FILM |
| JP6580769B2 (en) * | 2018-02-07 | 2019-09-25 | 日東電工株式会社 | Polarizing plate and image display device |
| CN118671871A (en) * | 2018-02-07 | 2024-09-20 | 日东电工株式会社 | Polarizing plate and image display device |
| WO2022239648A1 (en) * | 2021-05-08 | 2022-11-17 | 大倉工業株式会社 | Optical film, polarizing plate, image display device, and method for manufacturing optical film |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5856014A (en) * | 1996-02-29 | 1999-01-05 | Nisshinbo Industries, Inc. | Aqueous coating composition for the manufacture of precoated metal |
| US20030104216A1 (en) * | 2001-08-16 | 2003-06-05 | Toshihiro Koda | Coated film |
| CN1637106A (en) * | 2003-12-17 | 2005-07-13 | 拜尔材料科学有限责任公司 | Two-component water-borne adhesive |
| JP2005206970A (en) * | 2004-01-23 | 2005-08-04 | Dai Ichi Kogyo Seiyaku Co Ltd | Method for producing fiber laminate, fiber laminate and synthetic leather |
| JP2008209877A (en) * | 2007-01-31 | 2008-09-11 | Fujifilm Corp | Optical multilayer film and image display device |
| CN101313020A (en) * | 2005-11-22 | 2008-11-26 | 日本油漆株式会社 | Carbodiimide compound and aqueous curable resin composition containing the same |
| JP2009193061A (en) * | 2008-01-17 | 2009-08-27 | Nitto Denko Corp | Polarizing plate and image display device using polarizing plate |
| JP2011026460A (en) * | 2009-07-27 | 2011-02-10 | Yokohama Rubber Co Ltd:The | Set of aqueous curable composition and aqueous primer composition and sealed body using the same |
| JP2011140216A (en) * | 2009-12-07 | 2011-07-21 | Toyobo Co Ltd | Easy-to-adhere thermoplastic resin film |
| CN102648094A (en) * | 2009-12-04 | 2012-08-22 | 东洋纺织株式会社 | Highly adhesive thermoplastic resin film |
| JP2014083800A (en) * | 2012-10-25 | 2014-05-12 | Dic Corp | Laminate and image display apparatus |
| JP2014177135A (en) * | 2014-06-16 | 2014-09-25 | Mitsubishi Plastics Inc | Laminated polyester film |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08332706A (en) * | 1995-06-06 | 1996-12-17 | Teijin Ltd | Layered film |
| US20110045219A1 (en) * | 2009-08-18 | 2011-02-24 | Bayer Materialscience Llc | Coating compositions for glass substrates |
| KR101390545B1 (en) * | 2010-03-05 | 2014-04-30 | 닛토덴코 가부시키가이샤 | Adhesive for polarizing plate, polarizing plate, method for producing same, optical film, and image display device |
| KR101265311B1 (en) * | 2010-09-20 | 2013-05-16 | 주식회사 엘지화학 | Aqueous primer composition, polarizing plate comprising the same and method for preparing an optical film having a primer layer |
| KR101482406B1 (en) * | 2012-05-30 | 2015-01-14 | 주식회사 엘지화학 | Aqueous Primer Composition, Optical Film comprising the same, Polarizing Plate and Liquid Crystal Display Device used thereof |
-
2015
- 2015-11-04 TW TW104136320A patent/TWI661021B/en active
- 2015-11-05 WO PCT/JP2015/081116 patent/WO2016072437A1/en active Application Filing
- 2015-11-05 CN CN201580060306.9A patent/CN107075298B/en active Active
- 2015-11-05 KR KR1020177012048A patent/KR102394207B1/en active IP Right Grant
- 2015-11-05 JP JP2016557787A patent/JP6527878B2/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5856014A (en) * | 1996-02-29 | 1999-01-05 | Nisshinbo Industries, Inc. | Aqueous coating composition for the manufacture of precoated metal |
| US20030104216A1 (en) * | 2001-08-16 | 2003-06-05 | Toshihiro Koda | Coated film |
| CN1637106A (en) * | 2003-12-17 | 2005-07-13 | 拜尔材料科学有限责任公司 | Two-component water-borne adhesive |
| JP2005206970A (en) * | 2004-01-23 | 2005-08-04 | Dai Ichi Kogyo Seiyaku Co Ltd | Method for producing fiber laminate, fiber laminate and synthetic leather |
| CN101313020A (en) * | 2005-11-22 | 2008-11-26 | 日本油漆株式会社 | Carbodiimide compound and aqueous curable resin composition containing the same |
| JP2008209877A (en) * | 2007-01-31 | 2008-09-11 | Fujifilm Corp | Optical multilayer film and image display device |
| JP2009193061A (en) * | 2008-01-17 | 2009-08-27 | Nitto Denko Corp | Polarizing plate and image display device using polarizing plate |
| JP2011026460A (en) * | 2009-07-27 | 2011-02-10 | Yokohama Rubber Co Ltd:The | Set of aqueous curable composition and aqueous primer composition and sealed body using the same |
| CN102648094A (en) * | 2009-12-04 | 2012-08-22 | 东洋纺织株式会社 | Highly adhesive thermoplastic resin film |
| JP2011140216A (en) * | 2009-12-07 | 2011-07-21 | Toyobo Co Ltd | Easy-to-adhere thermoplastic resin film |
| JP2014083800A (en) * | 2012-10-25 | 2014-05-12 | Dic Corp | Laminate and image display apparatus |
| JP2014177135A (en) * | 2014-06-16 | 2014-09-25 | Mitsubishi Plastics Inc | Laminated polyester film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111890762A (en) * | 2018-07-25 | 2020-11-06 | 日东电工株式会社 | Easy-to-adhere film, method for producing the same, polarizing plate, and image display device |
| CN111890762B (en) * | 2018-07-25 | 2022-08-02 | 日东电工株式会社 | Easy-to-adhere film, method for producing the same, polarizing plate, and image display device |
| CN114730032A (en) * | 2019-11-06 | 2022-07-08 | 日东电工株式会社 | Polarizing plate, image display device, method for designing polarizing plate, method for producing polarizing plate, and method for producing image display device |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016072437A1 (en) | 2016-05-12 |
| KR102394207B1 (en) | 2022-05-03 |
| KR20170084060A (en) | 2017-07-19 |
| JP6527878B2 (en) | 2019-06-05 |
| TWI661021B (en) | 2019-06-01 |
| JPWO2016072437A1 (en) | 2017-08-24 |
| TW201623537A (en) | 2016-07-01 |
| CN107075298B (en) | 2019-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107075298B (en) | Easy adhesive composition and the optical film and its manufacturing method for having used the composition | |
| CN107001853A (en) | Easy adhesive composition and the optical film and its manufacture method for having used said composition | |
| CN107033647A (en) | Polarization plates comprising aqueous primer composition and the method for preparing the optical film comprising primer layer | |
| CN106660352B (en) | Gas-barrier Multilayer Film | |
| KR101265311B1 (en) | Aqueous primer composition, polarizing plate comprising the same and method for preparing an optical film having a primer layer | |
| WO2009090932A1 (en) | Polarizing plate, and image display device having polarizing plate | |
| CN103314317A (en) | Double-sided polarizing plate and optical device including same | |
| CN105378516B (en) | Diaphragm and the Polarizer containing the diaphragm | |
| KR20110038680A (en) | Polarizer-protecting film, and polarizing plate and image display device each comprising polarizer-protecting film | |
| JP5366765B2 (en) | Polarizing plate and image display device | |
| CN104303083A (en) | Polarizing plate | |
| CN104136949A (en) | Method for manufacturing double-sided polarizing plate and double-sided polarizing plate manufactrured by same | |
| EP3053946B1 (en) | Acrylic optical film, and polarizing plate comprising same | |
| JP6024271B2 (en) | Acrylic film for protecting polarizer, polarizing plate, and liquid crystal display device | |
| KR20140146391A (en) | Aqueous primer composition, optical film and polarizing plate comprising the same | |
| CN105593706B (en) | Optical film with excellent solvent resistance and the Polarizer comprising the optical film | |
| WO2022239648A1 (en) | Optical film, polarizing plate, image display device, and method for manufacturing optical film | |
| TW202306780A (en) | Optical film, method for manufacturing optical film, optical member, and image display device | |
| KR101612082B1 (en) | Stacked and biaxially stretched polyester film for optical use |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |