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CN107010975A - A kind of limekiln resistive connection skin wear-resistant castable - Google Patents

A kind of limekiln resistive connection skin wear-resistant castable Download PDF

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Publication number
CN107010975A
CN107010975A CN201710410657.9A CN201710410657A CN107010975A CN 107010975 A CN107010975 A CN 107010975A CN 201710410657 A CN201710410657 A CN 201710410657A CN 107010975 A CN107010975 A CN 107010975A
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CN
China
Prior art keywords
parts
limekiln
dispensing
resistive connection
electric smelting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710410657.9A
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Chinese (zh)
Inventor
王杉杉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiaxing New Building Materials Co Ltd
Original Assignee
Jiaxing New Building Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiaxing New Building Materials Co Ltd filed Critical Jiaxing New Building Materials Co Ltd
Priority to CN201710410657.9A priority Critical patent/CN107010975A/en
Publication of CN107010975A publication Critical patent/CN107010975A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

The present invention discloses a kind of limekiln resistive connection skin wear-resistant castable, including base-material, dispensing and additive, and the principal component of the base-material includes the component of following parts by weight:10 ~ 15 parts of Cr2AlC, 5 ~ 8 parts of Ti2AlC, 20 ~ 25 parts of electric-melting magnesium zirconium spinels, 25 ~ 28 parts of sintering fused alumina zirconias, 20 ~ 30 parts of electrofused mullites, 5 ~ 10 parts of electric smelting calcium magnesites and 3 ~ 8 parts of electric smelting aluminous cements.Castable provided by the present invention, it is particluarly suitable for using in limekiln, with even tissue, the uniform castable internal structure of crystal, the overall performance of castable is kept, not only strengthens anti-erosion and scour resistance, it is important that can effectively prevent skinning, overcome blocking, it is ensured that the system ventilation of kiln is smooth.

Description

A kind of limekiln resistive connection skin wear-resistant castable
Technical field
The present invention relates to a kind of castable, specifically a kind of limekiln resistive connection skin wear-resistant castable belongs to fire proofed wood Material field.
Background technology
In limekiln, limekiln top, side wall etc., the easy skinning in these places, the damage to castable are very serious, warp Often stop kiln maintenance.These usual positions use steel fiber castable or High-Alumina Low Cement Castable, such as Patent No. A kind of mullite steel fiber castable, is represented with weight percentage disclosed in CN101805198B, and the mullite steel fiber is poured Contain Brown Alundum 29 ~ 40%, bauxite chamotte 10 ~ 15%, fused mullite 18 ~ 32%, electrofused mullite in material feeding raw material proportioning 8 ~ 12%, silicon powder 3 ~ 7%, coagulant 2 ~ 5% and stainless steel fibre 1 ~ 3%, compared with existing common high alumina castable, with higher Compressive resistance and rupture strength, and bulk density is big.Mullite steel fiber castable product of the present invention has good resist Thermal shock performance, scour resistance and volume stability.But, can all there are lime raw material skinning and asking for blocking during use Topic, destroys refractory material interior tissue and interior material structure, while material surface sticks layered skinning, severe patient causes to block up Plug, causes system ventilation not smooth, and thermal regulation is disorderly, and coal consumption is improved.
The content of the invention
The invention aims to overcome the drawbacks described above that existing fire-resisting prefabricated brick exists when limekiln is used, carry For a kind of limekiln resistive connection skin wear-resistant castable, material limekiln castable internal structure composition can be optimized, material is improved Structural homogenity, and then cause material that there is higher resistance to elevated temperatures and preferable alkali resistance, resistive connection skin, wearability and heat resistanceheat resistant Pinking, it is ensured that limekiln system operation is smooth.
In order to achieve the above object, the present invention is adopted the following technical scheme that:A kind of limekiln resistive connection skin wear-resistant pouring Material, including base-material, dispensing and additive, the principal component of the base-material include the component of following parts by weight:10-15 parts of Cr2AlC, 5-8 parts of Ti2AlC, 20~25 parts of electric-melting magnesium zirconium spinels, 25~28 parts of sintering fused alumina zirconias, 20~30 parts of electrofused mullites, 5~ The content of magnesia is more than 80% in 10 parts of electric smelting calcium magnesites and 3~8 parts of electric smelting aluminous cements, the electric smelting calcium magnesite, institute Stating dispensing includes particulate dispensing and fiber dispensing, and the length of the fiber dispensing is 1~2mm, the addition of the fiber dispensing For the base-material and the 30~40% of the particulate ingredients by weight sum;The electric-melting magnesium zirconium spinel is including mass percent The magnesium zirconium spinel and 30 that magnesium zirconium spinel that 16~25% particle diameter is 0.5-2.5mm, 30~65% particle diameter are 2.5-6.5mm ~65% particle diameter is 2.5-6.5mm magnesium zirconium spinel.
Above-mentioned technical proposal, coordinates substrate material by aggregate, forms a kind of limekiln castable, and advantage is the formula Materials microstructure can be optimized, the new thing phase of material is obtained, a kind of even tissue is formed, the uniform internal structure of crystal is kept The overall performance of material, not only strengthens anti-erosion and scour resistance, it is important that can effectively prevent skinning.
Preferably, the particulate dispensing includes ceramic particle, Bubble zirconia particulate and floating bead and colloidal particles.
Preferably, the fiber dispensing includes Zirconium oxide fibre, polypropylene fibre and mullite fiber.
Preferably, the addition parts by weight of the fiber dispensing each component are:10~15 parts of Zirconium oxide fibre, polypropylene are fine Tie up 1~2. part, 55~75 parts of mullite fiber.
Preferably, the electric smelting calcium magnesite include 5~10% 20~15mm electric smelting calcium magnesite, the 15 of 15~20%~ 5mm electric smelting calcium magnesite, 20~70% 5~1mm electric smelting calcium magnesite.
Preferably, the content of alchlor and silica is described more than 65% in the electrofused mullite Cr2AlC granularity 1-0mm, Ti2AlC granularity is 0.5-0mm.
Preferably, the additive includes being melamine, calcium lignosulfonate powder, citric acid, 2 kinds or 3 kinds of mixtures.
By implementing above-mentioned technical proposal, castable provided by the present invention is particluarly suitable for using in limekiln, had Even tissue, the uniform internal structure of crystal keeps the overall performance of material, not only strengthens anti-erosion and scour resistance, important Be that can effectively prevent skinning, overcome blocking, it is ensured that the system operation of kiln is smooth.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1:
A kind of limekiln resistive connection skin wear-resistant castable, including base-material, dispensing and additive.The principal component of base-material includes following weight Measure the component of part:10 parts of Cr2AlC, 8 parts of Ti2AlC, 25 parts of electric-melting magnesium zirconium spinels, 25 parts of sintering fused alumina zirconias, 20 parts of electric smelting are not Carry out the content of magnesia in stone, 5 parts of electric smelting calcium magnesites and 7 parts of electric smelting aluminous cements, the electric smelting calcium magnesite more than 80%, The dispensing includes particulate dispensing and fiber dispensing, and the length of the fiber dispensing is 1~2mm, the addition of the fiber dispensing Measure 30~40% for the base-material and the particulate ingredients by weight sum;The electric-melting magnesium zirconium spinel includes mass percent For 16~25% particle diameter be 0.5-2.5mm magnesium zirconium spinel, 30~65% particle diameter be 2.5-6.5mm magnesium zirconium spinel and 30~65% particle diameter is 2.5-6.5mm magnesium zirconium spinel;Additive is melamine, calcium lignosulfonate powder, is in mass ratio 1:3 mix Close.
Embodiment 2:
A kind of limekiln resistive connection skin wear-resistant castable, including base-material, dispensing and additive.The principal component of base-material includes following weight Measure the component of part:12 parts of Cr2AlC, 8 parts of Ti2AlC, 23 parts of electric-melting magnesium zirconium spinels, 25 parts of sintering fused alumina zirconias, 20 parts of electric smelting are not Carry out the content of magnesia in stone, 5 parts of electric smelting calcium magnesites and 7 parts of electric smelting aluminous cements, the electric smelting calcium magnesite more than 80%, The dispensing includes particulate dispensing and fiber dispensing, and the length of the fiber dispensing is 1~2mm, the addition of the fiber dispensing Measure 30~40% for the base-material and the particulate ingredients by weight sum;The electric-melting magnesium zirconium spinel includes mass percent For 16~25% particle diameter be 0.5-2.5mm magnesium zirconium spinel, 30~65% particle diameter be 2.5-6.5mm magnesium zirconium spinel and 30~65% particle diameter is 2.5-6.5mm magnesium zirconium spinel;Additive is melamine, calcium lignosulfonate powder, is in mass ratio 1:3 mix Close.
Embodiment 3:
A kind of limekiln resistive connection skin wear-resistant castable, castable includes base-material, dispensing and additive.The principal component of base-material includes The component of following parts by weight:11 parts of Cr2AlC, 8 parts of Ti2AlC, 23 parts of electric-melting magnesium zirconium spinels, 25 parts of sintering fused alumina zirconias, 20 parts The content of magnesia is 80% in electrofused mullite, 5 parts of electric smelting calcium magnesites and 8 parts of electric smelting aluminous cements, the electric smelting calcium magnesite More than, the dispensing includes particulate dispensing and fiber dispensing, and the length of the fiber dispensing is 1~2mm, the fiber dispensing Addition is the 30~40% of the base-material and the particulate ingredients by weight sum;The electric-melting magnesium zirconium spinel includes quality hundred Divide the magnesium zirconium point that magnesium zirconium spinel, 30~65% particle diameter that the particle diameter that ratio is 16~25% is 0.5-2.5mm are 2.5-6.5mm brilliant Stone and the magnesium zirconium spinel that 30~65% particle diameter is 2.5-6.5mm;Additive is melamine, calcium lignosulfonate powder, citric acid by quality Than for 1:3:0.05 mixing.
Embodiment 4:
A kind of limekiln resistive connection skin wear-resistant castable, including base-material, dispensing and additive.The principal component of base-material includes following weight Measure the component of part:15 parts of Cr2AlC, 9 parts of Ti2AlC, 23 parts of electric-melting magnesium zirconium spinels, 25 parts of sintering fused alumina zirconias, 20 parts of electric smelting are not Carry out the content of magnesia in stone, 5 parts of electric smelting calcium magnesites and 3 parts of electric smelting aluminous cements, the electric smelting calcium magnesite more than 80%, The dispensing includes particulate dispensing and fiber dispensing, and the length of the fiber dispensing is 1~2mm, the addition of the fiber dispensing Measure 30~40% for the base-material and the particulate ingredients by weight sum;The electric-melting magnesium zirconium spinel includes mass percent For 16~25% particle diameter be 0.5-2.5mm magnesium zirconium spinel, 30~65% particle diameter be 2.5-6.5mm magnesium zirconium spinel and 30~65% particle diameter is 2.5-6.5mm magnesium zirconium spinel;Additive is melamine, calcium lignosulfonate powder, citric acid, and three presses matter Amount is than being 1:3:0.05 mixing.

Claims (7)

1. a kind of limekiln resistive connection skin wear-resistant castable, including base-material, dispensing and additive, the principal component of the base-material include The component of following parts by weight:10-15 parts of Cr2AlC, 5-8 parts of Ti2AlC, 20~25 parts of electric-melting magnesium zirconium spinels, 25~28 parts of sintering Fused alumina zirconia, 20~30 parts of electrofused mullites, 5~10 parts of electric smelting calcium magnesites and 3~8 parts of electric smelting aluminous cements, the electric-melting magnesium The content of magnesia is more than 80% in calcium sand, and the dispensing includes particulate dispensing and fiber dispensing, the length of the fiber dispensing For 1~2mm, the addition of the fiber dispensing is the base-material and the 30~40% of the particulate ingredients by weight sum;The electricity Molten magnesium zirconium spinel includes the magnesium zirconium spinel that the particle diameter that mass percent is 16~25% is 0.5-2.5mm, 30~65% grain The magnesium zirconium spinel that the magnesium zirconium spinel and 30~65% particle diameter that footpath is 2.5-6.5mm are 2.5-6.5mm.
2. a kind of limekiln resistive connection skin wear-resistant castable according to claim 1, it is characterised in that the particulate dispensing bag Include ceramic particle, Bubble zirconia particulate and floating bead and colloidal particles.
3. a kind of limekiln resistive connection skin wear-resistant castable according to claim 1, it is characterised in that the fiber dispensing bag Include Zirconium oxide fibre, polypropylene fibre and mullite fiber.
4. a kind of limekiln resistive connection skin wear-resistant castable according to claim 1, it is characterised in that the fiber dispensing is each The addition parts by weight of component are:10~15 parts of Zirconium oxide fibre, 1~2. part of polypropylene fibre, 55~75 parts of mullite fiber.
5. a kind of limekiln resistive connection skin wear-resistant castable according to claim 1, it is characterised in that the electric smelting calcium magnesite Electric smelting calcium magnesite, 20~70% 5~1mm of electric smelting calcium magnesite, 15~20% 15~5mm including 5~10% 20~15mm Electric smelting calcium magnesite.
6. a kind of limekiln resistive connection skin wear-resistant castable according to claim 1, it is characterised in that the electrofused mullite The content of middle alchlor and silica is more than 68%.
7. a kind of limekiln resistive connection skin wear-resistant castable according to claim 1, it is characterised in that the additive includes For 2 kinds in melamine, calcium lignosulfonate powder, citric acid or 3 kinds of mixtures.
CN201710410657.9A 2017-06-03 2017-06-03 A kind of limekiln resistive connection skin wear-resistant castable Pending CN107010975A (en)

Priority Applications (1)

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CN201710410657.9A CN107010975A (en) 2017-06-03 2017-06-03 A kind of limekiln resistive connection skin wear-resistant castable

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Application Number Priority Date Filing Date Title
CN201710410657.9A CN107010975A (en) 2017-06-03 2017-06-03 A kind of limekiln resistive connection skin wear-resistant castable

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CN107010975A true CN107010975A (en) 2017-08-04

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101607827A (en) * 2009-07-20 2009-12-23 卫辉熔金高温材料有限责任公司 Steel ladle using casting material prefabricated lower casting nozzle brick and production method thereof
WO2011148614A1 (en) * 2010-05-27 2011-12-01 出光興産株式会社 Sintered oxide material, target comprising same, and oxide semiconductor thin film
CN104876598A (en) * 2015-05-14 2015-09-02 武汉钢铁(集团)公司 Max phase-boron nitride composite ceramic side seal plate for thin-strip casting and manufacturing method of Max phase-boron nitride composite ceramic side seal plate
CN105367095A (en) * 2015-11-19 2016-03-02 长兴兴鹰新型耐火建材有限公司 Fireproof pouring material used for cement kiln tertiary air duct and preparation method thereof
CN105541352A (en) * 2015-12-21 2016-05-04 洛阳利尔耐火材料有限公司 Chromium-alumina-carbon bricks and preparation method therefor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101607827A (en) * 2009-07-20 2009-12-23 卫辉熔金高温材料有限责任公司 Steel ladle using casting material prefabricated lower casting nozzle brick and production method thereof
WO2011148614A1 (en) * 2010-05-27 2011-12-01 出光興産株式会社 Sintered oxide material, target comprising same, and oxide semiconductor thin film
CN104876598A (en) * 2015-05-14 2015-09-02 武汉钢铁(集团)公司 Max phase-boron nitride composite ceramic side seal plate for thin-strip casting and manufacturing method of Max phase-boron nitride composite ceramic side seal plate
CN105367095A (en) * 2015-11-19 2016-03-02 长兴兴鹰新型耐火建材有限公司 Fireproof pouring material used for cement kiln tertiary air duct and preparation method thereof
CN105541352A (en) * 2015-12-21 2016-05-04 洛阳利尔耐火材料有限公司 Chromium-alumina-carbon bricks and preparation method therefor

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Application publication date: 20170804